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JP4999956B2 - Method for producing mineral activated water - Google Patents
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JP4999956B2 - Method for producing mineral activated water - Google Patents

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JP4999956B2
JP4999956B2 JP2010092572A JP2010092572A JP4999956B2 JP 4999956 B2 JP4999956 B2 JP 4999956B2 JP 2010092572 A JP2010092572 A JP 2010092572A JP 2010092572 A JP2010092572 A JP 2010092572A JP 4999956 B2 JP4999956 B2 JP 4999956B2
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健市 鶴
剛 久保田
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本発明は、ミネラル活性水の製造方法に関するものであり、より詳細には、水を特殊なミネラルセラミックスフィルターに通すことにより、その天然鉱石群に含まれる成分と作用させて活性化する、ミネラル活性水の製造方法に関するものである。   The present invention relates to a method for producing mineral activated water, and more specifically, mineral activity that is activated by allowing water to pass through a special mineral ceramics filter and reacting with components contained in the natural ore group. The present invention relates to a method for producing water.

従来より、水をミネラルセラミックスフィルターに通すことにより、その天然鉱石群に含まれる成分と作用させて活性化するための、種々のミネラル活性水の製造方法が提唱されている。これらの多くは、水を多数の多孔質セラミックスボールを充填した槽に通し、その鉱石のミネラル成分を溶出させることにより、酸化体質の改善に有効と考えられている、マイナスイオンの一種である活性水素を豊富に含むミネラル活性水を生成するものである。   Conventionally, various methods for producing mineral active water have been proposed in which water is passed through a mineral ceramics filter to activate it by reacting with components contained in the natural ore group. Many of these activities are a kind of negative ions that are thought to be effective in improving the oxidants by passing water through a tank filled with many porous ceramic balls and eluting the mineral components of the ore. It produces mineral activated water that is rich in hydrogen.

一般に、物質が酸素と結合することが酸化と呼ばれ、酸化物が酸素を失うことが還元と呼ばれており、それらの活性を表す尺度として、酸化還元電位(ORP)が用いられている(その単位はmV)。このORP値のプラス値が高いほど酸化力が大きく、そのマイナス値が大きいほど還元力が強くて活性水素量が豊富なものと評価される。一般の水道水のORP値は、+300mV〜+600mVであり、活性水のORP値は、−200mV以下である。   In general, the combination of a substance with oxygen is called oxidation, and the loss of oxygen by an oxide is called reduction, and a redox potential (ORP) is used as a measure of their activity (ORP) ( The unit is mV). It is evaluated that the higher the ORP value, the higher the oxidizing power, and the higher the negative value, the stronger the reducing power and the richer the amount of active hydrogen. The ORP value of general tap water is +300 mV to +600 mV, and the ORP value of active water is −200 mV or less.

しかるに、従来の活性水の生成装置によって作られる活性水の場合、その効用性及び効用持続時間の点において難点がある。即ち、従来の活性水の場合は、短時間の内にORP値が上昇してpH値が酸性方向に戻ってしまい、その活性水としての効用はせいぜい5時間程度しか持続せず、生成後短時間の内に使用しない限り、その効用を享受することができないという問題があるのである。   However, in the case of active water produced by a conventional active water generator, there are difficulties in terms of its utility and duration. That is, in the case of conventional active water, the ORP value rises within a short time and the pH value returns to the acidic direction, and its effect as active water lasts only for about 5 hours at most. There is a problem that the utility cannot be enjoyed unless it is used in time.

特開平11−35472号公報JP-A-11-35472 特開2002−192171号公報JP 2002-192171 A 特開2004−160386号公報JP 2004-160386 A 特開2004−321982号公報JP 2004-321982 A

上述したように、従来の活性水の生成装置によって作られる活性水の場合、その効用持続性に難点があり、生成後短時間の内に使用しなければ、その効用を享受することができないという問題があった。本発明は、このような従来技術における問題を解決するためになされたもので、ミネラル活性水としての効用が、生成後従来のものより格段に長時間持続するミネラル活性水の製造方法を提供することを課題とする。   As described above, in the case of active water produced by a conventional device for generating active water, there is a drawback in its sustainability, and if it is not used within a short time after generation, it cannot be enjoyed. There was a problem. The present invention has been made to solve such problems in the prior art, and provides a method for producing mineral active water whose utility as mineral active water lasts much longer than that of the conventional one after generation. This is the issue.

本発明者らは種々試験研究を重ねた結果、従来の活性水の生成装置によって作られる活性水の効用が短時間しか持続しないのは、水の活性化、換言すれば、クラスターの細分化が十分でないことに起因することを突き止め、この問題を解決するには、クラスターの細分化を十分に行う必要があるとの知見を得て本発明を完成させたものである。   As a result of repeated studies and studies by the present inventors, the effect of the active water produced by the conventional active water generator lasts only for a short time because water activation, in other words, cluster fragmentation. The present invention has been completed with the knowledge that it is necessary to sufficiently subdivide the cluster in order to find out that this is not sufficient and to solve this problem.

即ち、上記課題を解決するための請求項1に記載の発明は、1280℃〜1300℃の温度で13時間前後焼成して均一な細孔を多数有する多孔質ミネラルセラミックスフィルターを製造する工程と、水を前記多孔質ミネラルセラミックスフィルターに通して超微粒子化した状態にて前記多孔質ミネラルセラミックスフィルターのミネラル成分を溶出させる工程と、前記水に溶出させたミネラル成分によって前記水のpH値及びORP値を低下させる工程とから成ることを特徴とするミネラル活性水の製造方法である。   That is, the invention according to claim 1 for solving the above-mentioned problem is a step of producing a porous mineral ceramic filter having a large number of uniform pores by baking around 13 hours at a temperature of 1280 ° C. to 1300 ° C., The step of eluting the mineral component of the porous mineral ceramics filter in a state where the water is passed through the porous mineral ceramics filter to make ultrafine particles, and the pH value and ORP value of the water by the mineral component eluted in the water A process for lowering the amount of mineral active water.

好ましい実施形態においては、前記多孔質ミネラルセラミックスフィルターの細孔分布測定による中央細孔直径は約2μmとなるようにされ、前記多孔質ミネラルセラミックスフィルターの気孔率は約53%となるようにされ、また、前記多孔質ミネラルセラミックスフィルターの遠赤外線放射率は、約81%となるようにされる。   In a preferred embodiment, the median pore diameter measured by pore distribution measurement of the porous mineral ceramic filter is set to about 2 μm, and the porosity of the porous mineral ceramic filter is set to about 53%. The far infrared emissivity of the porous mineral ceramic filter is set to about 81%.

本発明は上述したとおりであり、本発明に係るミネラル活性水の製造方法においては、水を、1280℃〜1300℃の温度で13時間前後焼成して得た均一な細孔を多数有する多孔質ミネラルセラミックスフィルターに通すことにより超微粒子化することができ、その状態で多孔質ミネラルセラミックスフィルターに接触させるためにミネラル成分が十分に溶出し、その溶出したミネラル成分の作用により、水のpH値及びORP値を長時間低く保つことが可能となり、以て、ミネラル活性水の効用を長時間持続させ得る効果がある。   The present invention is as described above, and in the method for producing mineral activated water according to the present invention, the porous material has a large number of uniform pores obtained by baking water for about 13 hours at a temperature of 1280 ° C to 1300 ° C. Ultrafine particles can be made by passing through a mineral ceramic filter, and the mineral component is sufficiently eluted to contact the porous mineral ceramic filter in that state. It becomes possible to keep the ORP value low for a long time, and therefore, there is an effect that the effect of mineral active water can be maintained for a long time.

本発明に係る方法によって製造された多孔質ミネラルセラミックスフィルターについて行った、細孔分布測定試験の結果を示すグラフである。It is a graph which shows the result of the pore distribution measurement test done about the porous mineral ceramics filter manufactured by the method concerning the present invention. 本発明に係る方法によって製造された多孔質ミネラルセラミックスフィルターにおける、遠赤外線放射率の試験結果を示すグラフである。It is a graph which shows the test result of a far-infrared emissivity in the porous mineral ceramic filter manufactured by the method based on this invention.

以下に、本発明を実施するための形態について、図面を参照して説明する。本発明に係るミネラル活性水の製造方法は、1280℃〜1300℃の温度で13時間前後焼成して均一な細孔を多数有する多孔質ミネラルセラミックスフィルターを製造する工程と、水を前記多孔質ミネラルセラミックスフィルターに通すことにより、超微粒子化すると共に前記多孔質ミネラルセラミックスフィルターのミネラル成分を溶出させる工程と、前記水に溶出させたミネラル成分によって前記水のpH値及びORP値を低下させる工程とから成ることを特徴とする。   EMBODIMENT OF THE INVENTION Below, the form for implementing this invention is demonstrated with reference to drawings. The method for producing mineral activated water according to the present invention comprises a step of producing a porous mineral ceramic filter having a large number of uniform pores by baking at a temperature of 1280 ° C. to 1300 ° C. for about 13 hours, and water for the porous mineral. By passing through a ceramics filter, the step of making ultrafine particles and eluting the mineral components of the porous mineral ceramics filter, and the step of lowering the pH value and ORP value of the water by the mineral components eluted in the water It is characterized by comprising.

本発明に係る方法においては、均一な細孔を多数有する多孔質ミネラルセラミックスフィルターを製造することが最も重要である。そのような多孔質ミネラルセラミックスフィルターは、例えば、酸化アルミニウム(アルミナ)等の鉱物を1280℃〜1300℃の温度で13時間前後焼成することにより得られる。   In the method according to the present invention, it is most important to produce a porous mineral ceramic filter having a large number of uniform pores. Such a porous mineral ceramic filter can be obtained, for example, by firing a mineral such as aluminum oxide (alumina) at a temperature of 1280 ° C. to 1300 ° C. for about 13 hours.

ここで、1280℃〜1300℃の温度で焼成することとしたのは、1280℃以下で焼成した場合は、細孔のサイズが不均一となり、また、1300℃以上で焼成した場合は、セラミックスが大きく収縮して細孔のサイズが小さくなり過ぎ、気孔率も低下するからである。また、13時間前後焼成することとしたのは、焼成時間がこれより短いと、セラミックスの強度が十分なものとなり得ないからであり、焼成時間がこれより長いと、セラミックスが大きく収縮して細孔のサイズが小さくなり過ぎ、気孔率も低下するからである。   Here, the reason for firing at a temperature of 1280 ° C. to 1300 ° C. is that the pore size becomes non-uniform when fired at 1280 ° C. or lower, and when fired at 1300 ° C. or higher, the ceramics It is because it shrinks greatly and the size of the pore becomes too small, and the porosity also decreases. Moreover, the reason for firing around 13 hours is that if the firing time is shorter than this, the strength of the ceramics cannot be sufficient, and if the firing time is longer than this, the ceramics will shrink greatly and become finer. This is because the pore size becomes too small and the porosity is also lowered.

図1は、上記焼成条件で焼成した多孔質ミネラルセラミックスフィルターの場合に均一な細孔が形成されることを実証するために行った、水銀圧入法による細孔分布測定試験の結果を示す、log微分細孔容積分布図である。この分布図から明らかなように、本多孔質ミネラルセラミックスフィルターにおけるピークの幅は非常に狭いものとなっている。このことは、本多孔質ミネラルセラミックスフィルターには、均一な細孔が多数存在することを意味する。そして、このピークの幅が広くなればなるほど細孔は不均一ということになり、不均一の程度が大きくなると、ピークは現われなくなる。   FIG. 1 is a log showing the results of a pore distribution measurement test by mercury porosimetry performed to demonstrate that uniform pores are formed in the case of a porous mineral ceramic filter fired under the above firing conditions. It is a differential pore volume distribution map. As is apparent from this distribution map, the peak width in the present porous mineral ceramic filter is very narrow. This means that the present porous mineral ceramic filter has a large number of uniform pores. As the width of the peak becomes wider, the pores become non-uniform. When the degree of non-uniformity increases, the peak does not appear.

上記細孔分布測定試験結果の主なデータを以下に示す。
(1)全細孔容積 0.3057cm/g
(2)気孔率 53.25%
(3)中央細孔直径 21.81μm
The main data of the pore distribution measurement test results are shown below.
(1) Total pore volume 0.3057 cm 3 / g
(2) Porosity 53.25%
(3) Median pore diameter 21.81 μm

また、遠赤外線は水を活性化させる、即ち、クラスターを細分化させることが知られている。従って、遠赤外線放射率の高いフィルターを用いれば、クラスターの細分化が促進されるであろうと考えられる。   Further, it is known that far infrared rays activate water, that is, subdivide clusters. Therefore, it is considered that the use of a filter having a high far-infrared emissivity will promote cluster fragmentation.

図2のグラフは、本多孔質ミネラルセラミックスフィルターについての遠赤外線放射率の試験結果を示すものであり(放射率100%を最大とした場合の相対評価)、このグラフから明らかなように、本多孔質ミネラルセラミックスフィルターの場合は、幅広い波長帯(横軸が波長)において高い遠赤外線放射率を有しているので、この多孔質ミネラルセラミックスフィルターを用いれば、クラスターの細分化が促進されるであろうことは容易に理解できる。なお、上記遠赤外線放射率の試験は、日本電子株式会社製遠赤外線分光放射計(JIR−E500)を用い、ヒーター温度100℃で行ったもので、その結果は、被検資料の表面温度が89.5℃で、積分放射率が81.6%であった。   The graph of FIG. 2 shows the test result of the far-infrared emissivity of the present porous mineral ceramic filter (relative evaluation when the emissivity is 100% as the maximum). In the case of a porous mineral ceramic filter, since it has a high far-infrared emissivity in a wide wavelength band (the horizontal axis is a wavelength), the use of this porous mineral ceramic filter promotes the fragmentation of clusters. It's easy to understand. The far-infrared emissivity test was conducted at a heater temperature of 100 ° C. using a JIR-E far infrared spectroradiometer (JIR-E500). At 89.5 ° C., the integrated emissivity was 81.6%.

水を多孔質ミネラルセラミックスフィルターに通した場合、鉱石に含まれるミネラル成分(主にカルシウムやカリウム等の金属元素)が水に溶けて陽イオン(Ca 、K)になり、この陽イオン群が、水のpH値及びORP値を変化させるように作用する。本発明に係る方法においては、水を上記のようにして製造した多孔質ミネラルセラミックスフィルターに通すことにより超微粒子化し、その超微粒子化した状態で多孔質ミネラルセラミックスフィルターに接触させてミネラル成分を溶出させる。このように超微粒子化した水にミネラル成分を溶出させるため、そこには、水のpH値及びORP値を低下させるように作用するミネラル成分が十分に含有されることになる。 When water was passed through a porous mineral ceramics filter, cation (Ca 2 +, K +) minerals contained in the ore (metal element such as mainly calcium and potassium) is dissolved in water becomes, the cationic Groups act to change the pH and ORP values of water. In the method according to the present invention, ultrafine particles are formed by passing water through the porous mineral ceramic filter produced as described above, and the mineral components are eluted by contacting the porous mineral ceramic filter with the ultrafine particles. Let Thus, in order to elute a mineral component in the water | fine-particle-ized water, the mineral component which acts so that the pH value and ORP value of water may be contained enough is contained there.

上述したように、従来のミネラル活性水の場合は、一旦pHやORPが変化しても、時間の経過と共にそれらの数値が原水の数値に戻ってしまう傾向がある。これに対して本発明に係る方法により製造されたミネラル活性水の場合は、水は多孔質ミネラルセラミックスフィルターを通過することにより活性化(クラスターの細分化)された状態で鉱石と接触するために、その効果が長時間持続するのである。   As described above, in the case of conventional mineral activated water, even if pH and ORP change once, those values tend to return to those of raw water as time passes. On the other hand, in the case of the mineral activated water produced by the method according to the present invention, the water is activated by passing through the porous mineral ceramics filter (in order to make contact with the ore in a clustered state). The effect lasts for a long time.

下記表は、このような本発明の効果を確認するために行った計量試験の結果を示すものである。この計量試験は、原水と、本発明に係る方法によって得た水の生成直後及び24時間後におけるpH値及びORP値を測定したものである。なお、この試験において、pH測定には上水試験法VI−1 9.2ガラス電極法を用い、ORP測定には白金電極法を用いた。   The following table shows the results of a measurement test conducted to confirm the effects of the present invention. This measurement test is a measurement of the pH value and ORP value of raw water and immediately after the production of water obtained by the method according to the present invention and after 24 hours. In this test, the water test method VI-1 9.2 glass electrode method was used for pH measurement, and the platinum electrode method was used for ORP measurement.

(表1)

Figure 0004999956
(Table 1)
Figure 0004999956

上記表1から明らかなように、pH値は生成直後に9.1(21.6℃)であり、24時間後には8.6(20.0℃)であってその間に大きな変化はなく、ORP値は、生成直後に170mVであり、24時間後には140mVであって、やはりその間に大きな変化はない。このことから、本発明に係る方法においては、水の物性変化が急速に進行し、且つ、その変化した状態、換言すれば、そのミネラル活性水としての効用が長時間持続するものであることが確認された。   As apparent from Table 1 above, the pH value was 9.1 (21.6 ° C.) immediately after production, and 8.6 (20.0 ° C.) after 24 hours, with no significant change during The ORP value is 170 mV immediately after generation and 140 mV after 24 hours, again with no significant change. From this, in the method according to the present invention, the physical property change of water proceeds rapidly, and the changed state, in other words, the effect as the mineral active water is sustained for a long time. confirmed.

この発明をある程度詳細にその最も好ましい実施形態について説明してきたが、この発明の精神と範囲に反することなしに広範に異なる実施形態を構成することができることは明白なので、この発明は添付請求の範囲において限定した以外はその特定の実施形態に制約されるものではない。   Although the present invention has been described in some detail with respect to its most preferred embodiments, it will be apparent that a wide variety of different embodiments can be constructed without departing from the spirit and scope of the invention, the invention being defined by the appended claims. It is not restricted to the specific embodiment other than limiting in.

Claims (2)

1280℃〜1300℃の温度で13時間前後焼成して均一な細孔を多数有する多孔質ミネラルセラミックスフィルターを製造する工程と、
水を前記多孔質ミネラルセラミックスフィルターに通すことにより、超微粒子化すると共に前記多孔質ミネラルセラミックスフィルターのミネラル成分を溶出させる工程と、
前記水に溶出させたミネラル成分と前記多孔質ミネラルセラミックスフィルターからの遠赤外線放射との相乗作用により、前記水のpH値を上昇させORP値を低下させる工程と、を含み、
前記多孔質ミネラルセラミックスフィルターの全細孔容積が、0.3057cm /gであり、
前記多孔質ミネラルセラミックスフィルターの気孔率が、53.25%であり、
前記多孔質ミネラルセラミックスフィルターの中央細孔直径が、21.81μmであることを特徴とするミネラル活性水の製造方法。
A step of producing a porous mineral ceramics filter having a large number of uniform pores by firing for about 13 hours at a temperature of 1280 ° C to 1300 ° C;
Passing water through the porous mineral ceramic filter to make ultrafine particles and eluting the mineral component of the porous mineral ceramic filter;
A step of increasing the pH value of the water and decreasing the ORP value by a synergistic action of the mineral component eluted in the water and the far infrared radiation from the porous mineral ceramic filter ,
The total pore volume of the porous mineral ceramic filter is 0.3057 cm 3 / g;
The porosity of the porous mineral ceramic filter is 53.25%;
The method for producing mineral activated water, wherein the porous mineral ceramic filter has a median pore diameter of 21.81 μm .
前記多孔質ミネラルセラミックスフィルターの遠赤外線放射率が、81.6%であることを特徴とする請求項1に記載のミネラル活性水の製造方法。

The porous mineral ceramics filter of the far-infrared emissivity The method for producing a mineral active water according to claim 1, characterized in that 81.6%.

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