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JP5056489B2 - Insulation reliability evaluation structure of printed circuit board interlayer connection circuit and its insulation reliability evaluation test method - Google Patents
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JP5056489B2 - Insulation reliability evaluation structure of printed circuit board interlayer connection circuit and its insulation reliability evaluation test method - Google Patents

Insulation reliability evaluation structure of printed circuit board interlayer connection circuit and its insulation reliability evaluation test method Download PDF

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JP5056489B2
JP5056489B2 JP2008058068A JP2008058068A JP5056489B2 JP 5056489 B2 JP5056489 B2 JP 5056489B2 JP 2008058068 A JP2008058068 A JP 2008058068A JP 2008058068 A JP2008058068 A JP 2008058068A JP 5056489 B2 JP5056489 B2 JP 5056489B2
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insulating layer
interlayer connection
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富男 福田
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Resonac Corp
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Hitachi Chemical Co Ltd
Showa Denko Materials Co Ltd
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Description

本発明は、プリント配線板層間接続回路部の絶縁信頼性評価構造体とそれを用いる絶縁信頼性評価試験方法に関する。さらに詳しくは、貫通ビア間の壁間絶縁距離が0.1mm以下の狭い位置で形成される層間接続回路部のエレクトロマイグレーション試験を行うために有効な絶縁信頼性評価構造体と、それを用いる絶縁信頼性評価試験方法に関する。   The present invention relates to an insulation reliability evaluation structure of a printed wiring board interlayer connection circuit portion and an insulation reliability evaluation test method using the same. More specifically, an insulation reliability evaluation structure effective for conducting an electromigration test of an interlayer connection circuit portion formed in a narrow position where the inter-wall insulation distance between through vias is 0.1 mm or less, and insulation using the same The present invention relates to a reliability evaluation test method.

近年、電子機器の高性能化や小型化に伴って、プリント基板の回路設計に対する精密化の要求がますます高まっている。
このような精密化に伴い、プリント基板の微細回路形成やビアなどの狭ピッチ設計が要求されると共に、基板の高い絶縁信頼性も必要になりつつある。
このような基板の一例として、ガラスクロス等を原材料とするガラスエポキシ積層板をあげることができる。しかし、この基板を採用すると、絶縁物である樹脂中にガラスフィラメントが存在し、その繊維に沿って陽極から陰極側に向かってCAF(Conductive Anodic Filament)が発生し、絶縁劣化を引き起こすことがある。
そのため、電子機器等に使用される基板が、このような絶縁劣化を引き起こさないかどうかを性能評価するための絶縁信頼性評価試験方法が提案されている。
In recent years, with the improvement in performance and miniaturization of electronic devices, there has been an increasing demand for precision in circuit design of printed circuit boards.
Along with such refinement, a fine pitch circuit design of a printed circuit board and a narrow pitch design such as a via are required, and high insulation reliability of the circuit board is also required.
As an example of such a substrate, a glass epoxy laminate using glass cloth or the like as a raw material can be given. However, when this substrate is employed, glass filaments are present in the resin, which is an insulator, and CAF (Conductive Anodic Filament) occurs along the fibers from the anode toward the cathode, which may cause insulation deterioration. .
Therefore, an insulation reliability evaluation test method for evaluating whether or not a substrate used for an electronic device or the like does not cause such insulation deterioration has been proposed.

一般に、銅張り積層板に対して、プリント配線板層間接続回路部の絶縁信頼性を評価する場合は、図8〜図11に示すようなプリント配線板層間接続回路の絶縁信頼性評価構造体(以下、評価構造体と言うことがある。)を用い、適当な湿度と温度に設定された吸湿環境の下で配線に電圧を印加し、絶縁抵抗を測定することが行われている。
ここで、図8は従来例の評価構造体の透視平面図、図9は図8に示したd断面位置線に該当する評価構造体の断面図、図10は図8に示したe断面位置線に該当する評価構造体の断面図、及び図11は図8に示したf断面位置線に該当する評価構造体の断面図である。
In general, when evaluating the insulation reliability of the printed wiring board interlayer connection circuit portion with respect to the copper-clad laminate, the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit as shown in FIGS. Hereinafter, an insulation structure is measured by applying a voltage to the wiring under a moisture absorption environment set to an appropriate humidity and temperature.
8 is a perspective plan view of the conventional evaluation structure, FIG. 9 is a cross-sectional view of the evaluation structure corresponding to the d-section position line shown in FIG. 8, and FIG. 10 is the e-section position shown in FIG. 11 is a cross-sectional view of the evaluation structure corresponding to the line, and FIG. 11 is a cross-sectional view of the evaluation structure corresponding to the f cross-section position line shown in FIG.

これらの図を用いて、従来の評価構造体を説明すると、図8に示される評価構造体の透視平面図でわかるように、上部側の第一導体層11(実線部)と下部側の第二導体層12(鎖線部)(以下、併せて外層導体層11、12と言うことがある。)とに、それぞれ設けられた電気回路用の配線(以下、電気配線と言う。)が貫通ビア14の内壁に設けられた導体層15を介して、直列のチェーン配線となって平行に設けられている。この評価構造体を図9及び図10で見ると、内部絶縁層10を有し、その一方の面に第一導体層11、及び他方の面に第二導体層12とに、それぞれ電気配線が設けられた銅張り積層板に、前記導体層15を有する層間接続回路用の貫通ビア14が設けられており、その結果、外層導体層11、12に設けられた各電気配線は、貫通ビア14を介して、直列のチェーン配線を形成している。この直列のチェーン配線は、図11に示すように、貫通ビア間の壁間絶縁距離Hを保って平行に設けられている。
この従来の評価構造体の製造方法は、前記銅張り積層板に貫通ビア14を形成し、この貫通ビア14の内壁と外層導体層上にめっき等によって導体層を形成させ、次いで、前記外層導体層上に耐エッチング性のレジスト層(図示せず)を形成して焼付け、現像して、所定のパターンに形成後、エッチング、剥離等の工程を経て、外層導体層にそれぞれ電気配線(以下、併せて外層回路と言うことがある。)を形成させるものである。なお、符号16、17は端子となる部位である。
この外層導体層のエッチング工程では、貫通ビア14の内壁に設けられた導体層15がエッチングされるのを防止するため、外層導体層上に形成したレジスト層に外層回路をパターンニングする際、貫通ビア14の入口をマスクする方法が採られている。
このような態様では、外層回路における層間接続回路の接続部分は、貫通ビア14の開口径よりも大きな径を有するランド13が形成されるが、隣り合う直列のチェーン配線に設けられた最近接の貫通ビア14間の壁間絶縁距離Hが0.15mm〜0.5mm程度設けることができる場合は、プリント配線板の作製時に注意深く穴あけを行えば、絶縁信頼性評価は可能であった。
しかし、近年の精密化に伴ってこの壁間絶縁距離Hがもっと狭い場合の絶縁信頼性を評価しようとすると、該ランド13部分で絶縁距離を確保することが困難となる。
The conventional evaluation structure will be described with reference to these drawings. As can be seen from the perspective plan view of the evaluation structure shown in FIG. 8, the upper first conductor layer 11 (solid line portion) and the lower first structure are shown. Wirings for electric circuits (hereinafter referred to as electric wirings) respectively provided on the two conductor layers 12 (chain line portions) (hereinafter also referred to as outer layer conductor layers 11 and 12) are through vias. Through a conductor layer 15 provided on the inner wall of 14, a serial chain wiring is provided in parallel. When this evaluation structure is seen in FIGS. 9 and 10, it has an internal insulating layer 10, and electric wiring is provided on the first conductor layer 11 on one side and the second conductor layer 12 on the other side, respectively. The provided copper-clad laminate is provided with a through via 14 for an interlayer connection circuit having the conductor layer 15. As a result, each electrical wiring provided in the outer conductor layers 11 and 12 is connected to the through via 14. A chain wiring in series is formed via As shown in FIG. 11, the series chain wirings are provided in parallel while maintaining the inter-wall insulation distance H between the through vias.
In this conventional evaluation structure manufacturing method, a through via 14 is formed in the copper-clad laminate, a conductor layer is formed on the inner wall and the outer conductor layer of the through via 14 by plating or the like, and then the outer conductor is formed. An etching-resistant resist layer (not shown) is formed on the layer, baked, developed, formed into a predetermined pattern, and then subjected to processes such as etching, peeling, etc. It may also be referred to as an outer layer circuit). Reference numerals 16 and 17 are portions to be terminals.
In this outer conductor layer etching process, in order to prevent the conductor layer 15 provided on the inner wall of the through via 14 from being etched, when the outer layer circuit is patterned on the resist layer formed on the outer conductor layer, the through layer 14 is not penetrated. A method of masking the entrance of the via 14 is employed.
In such an embodiment, the land 13 having a diameter larger than the opening diameter of the through via 14 is formed in the connection portion of the interlayer connection circuit in the outer layer circuit, but the nearest land line provided in the adjacent serial chain wiring is formed. When the insulation distance H between the walls between the through vias 14 can be set to about 0.15 mm to 0.5 mm, the insulation reliability can be evaluated by carefully drilling holes when producing the printed wiring board.
However, with the recent refinement, if it is attempted to evaluate the insulation reliability when the insulation distance H between the walls is narrower, it becomes difficult to secure the insulation distance at the land 13 portion.

一方、表層にランドを設けないランドレススルーホールの製造方法としては、例えば、特許文献1及び特許文献2が提案されている。
これらの製造方法は、スルーホールと外層回路を確実に接続するための高度な印刷位置合せ技術を必要としており、これらの製造方法では容易に評価構造体を作製することは困難であった。
On the other hand, for example, Patent Document 1 and Patent Document 2 have been proposed as a method of manufacturing a landless through hole in which no land is provided on the surface layer.
These manufacturing methods require an advanced printing alignment technique for reliably connecting the through-hole and the outer layer circuit, and it has been difficult to easily produce an evaluation structure with these manufacturing methods.

又、絶縁信頼性試験の精度を高めるために、外層回路部をソルダーレジスト層で覆い、結露や表面汚染が原因で生じる層間接続回路部以外の絶縁劣化を抑制することが行われている。しかし、この方法ではソルダーレジストの絶縁信頼性が基板より劣っている場合や、ソルダーレジストと基板の相性が適当でなかった場合には、絶縁信頼性試験結果に影響を及ぼすために高精度の試験結果が得られない。   In order to increase the accuracy of the insulation reliability test, the outer layer circuit portion is covered with a solder resist layer to suppress insulation deterioration other than the interlayer connection circuit portion caused by condensation or surface contamination. However, with this method, if the insulation reliability of the solder resist is inferior to that of the substrate, or if the compatibility between the solder resist and the substrate is not appropriate, a high-accuracy test will affect the insulation reliability test results. The result is not obtained.

特許第2583365号公報Japanese Patent No. 2583365 特開平8−288644号公報JP-A-8-288644

本発明は、上記評価構造体における層間接続回路部の絶縁信頼性評価試験が従来よりも狭い、例えば0.1mm以下の隣り合う貫通ビア間の壁間絶縁距離であっても、高精度、高信頼度の絶縁評価試験が可能である評価構造体、及びそれを用いた評価試験方法を提供することを目的とする。   Even if the insulation reliability evaluation test of the interlayer connection circuit portion in the evaluation structure is narrower than before, for example, the insulation distance between adjacent vias of 0.1 mm or less, high accuracy and high It is an object of the present invention to provide an evaluation structure capable of performing a reliable insulation evaluation test, and an evaluation test method using the same.

本発明者は、チェーン配線の幅をチェーン配線に設けられる貫通ビア径以下とし、外層導体層上にプリプレグからなる表面絶縁層を設け、かつ前記貫通ビアの内壁に設けられた導体層の端部が前記表面絶縁層の表面よりも内層側にある評価構造体が前記目的を達成しうることを見い出した。本発明はかかる知見に基づいて完成されたものである。   The inventor sets the width of the chain wiring to be equal to or smaller than the diameter of the through via provided in the chain wiring, provides a surface insulating layer made of prepreg on the outer conductive layer, and ends of the conductive layer provided on the inner wall of the through via It has been found that an evaluation structure having an inner layer side of the surface insulating layer can achieve the object. The present invention has been completed based on such findings.

すなわち、本発明は、
1.内部に絶縁層を有する銅張り積層板の一方の面の第一導体層に電気配線が、他方の面の第二導体層に電気配線がそれぞれ複数形成され、前記両導体層の上層にプリプレグからなる表面絶縁層が設けられた内層回路含有基板の前記第一導体層と第二導体層との電気配線が、内壁に導体層を有する貫通ビアを介して交互に接続された直列のチェーン配線を形成してなるプリント配線板層間接続回路評価構造体であって、前記貫通ビアと接続する各電気配線幅は、前記貫通ビア径以下であり、かつ、前記貫通ビアの内壁に設けられた導体層の端部が前記表面絶縁層の表面よりも内層側にあることを特徴とするプリント配線板層間接続回路部の絶縁信頼性評価構造体、
2.前記直列のチェーン配線に設けられた貫通ビアと、隣り合う直列のチェーン配線に設けられた最近接の貫通ビアとの壁間絶縁距離が0.03mm〜0.1mmである上記1に記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体、
3.前記貫通ビアの直径が0.15mm以下である上記1又は2に記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体、
4.前記内部の絶縁層はガラスクロスを含み、前記ガラスクロスの厚みが0.05mm以下であって、前記絶縁層厚みが0.1mm以下である上記1〜3のいずれかに記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体、
5.前記表面絶縁層はガラスクロスを含み、前記絶縁層の厚みが0.1mm以下であって、前記ガラスクロスの厚みが0.05mm以下である上記1〜4のいずれかに記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体、
6.上記1〜5のいずれかに記載の絶縁信頼性評価構造体の複数の直列のチェーン配線に、電源のプラス極とマイナス極を交互に接続し、吸湿条件下で電圧をかけて、前記チェーン配列間の吸湿絶縁抵抗を測定することを特徴とするプリント配線板層間接続回路部の絶縁信頼性評価試験方法、
7.CAFによる絶縁劣化を測定するものである上記6記載のプリント配線板層間接続回路部の絶縁信頼性評価試験方法、
に関するものである。
That is, the present invention
1. A plurality of electrical wirings are formed on the first conductor layer on one side of the copper-clad laminate having an insulating layer inside, and a plurality of electrical wirings are formed on the second conductor layer on the other side. A series chain wiring in which the electrical wiring of the first conductor layer and the second conductor layer of the inner layer circuit-containing substrate provided with the surface insulating layer is alternately connected through through vias having a conductor layer on the inner wall. A printed wiring board interlayer connection circuit evaluation structure formed, wherein each electric wiring width connected to the through via is equal to or smaller than the diameter of the through via, and a conductor layer provided on an inner wall of the through via An insulating reliability evaluation structure of a printed wiring board interlayer connection circuit portion, wherein the end portion of the printed wiring board is on the inner layer side of the surface of the surface insulating layer,
2. 2. The print according to 1 above, wherein an insulation distance between walls of a through via provided in the serial chain wiring and a nearest through via provided in an adjacent serial chain wiring is 0.03 mm to 0.1 mm. Insulation reliability evaluation structure of wiring board interlayer connection circuit part,
3. Insulation reliability evaluation structure of printed wiring board interlayer connection circuit part according to 1 or 2, wherein the diameter of the through via is 0.15 mm or less,
4). The printed wiring board interlayer according to any one of the above items 1 to 3, wherein the inner insulating layer includes a glass cloth, and the thickness of the glass cloth is 0.05 mm or less, and the insulating layer thickness is 0.1 mm or less. Insulation reliability evaluation structure of connection circuit section,
5. The printed wiring board interlayer according to any one of the above 1 to 4, wherein the surface insulating layer includes a glass cloth, the insulating layer has a thickness of 0.1 mm or less, and the glass cloth has a thickness of 0.05 mm or less. Insulation reliability evaluation structure of connection circuit section,
6). The chain arrangement is formed by alternately connecting a positive electrode and a negative electrode of a power source to a plurality of series chain wires of the insulation reliability evaluation structure according to any one of the above 1 to 5, and applying a voltage under moisture absorption conditions. Insulation reliability evaluation test method for printed circuit board interlayer connection circuit part, characterized by measuring moisture absorption insulation resistance between,
7). The insulation reliability evaluation test method for a printed wiring board interlayer connection circuit portion according to the above 6, which measures insulation deterioration due to CAF,
It is about.

本発明は、最近接の隣り合う貫通ビア壁間絶縁距離が従来よりも狭い、例えば、0.1mm以下であっても、高精度、高信頼度の絶縁評価試験が可能である評価構造体、及びそれを用いた評価試験方法を提供することができる。   The present invention provides an evaluation structure capable of performing a high-accuracy and high-reliability insulation evaluation test even when the insulation distance between adjacent through via walls adjacent to each other is narrower than before, for example, 0.1 mm or less. And an evaluation test method using the same.

図を用いて、本発明を説明する。
先ず、図1は本発明における用語を説明する図で、本発明における壁間絶縁距離とは、ドリル穴あけした時の内壁間絶縁距離のことであり(図1のH)、穴の直径とは、ドリル穴(貫通ビア)の直径のことである(図1のM)。さらに、本発明におけるピッチ間隔とは、ドリル穴あけしたときの穴の中心間の距離のことである(図1のN)。
図2〜7は、本発明の評価構造体を示す図である。
図2は、本発明の評価構造体の透視平面図、図3は図2に示したa断面位置線に該当する本発明の評価構造体の断面図、図4は図2に示したb断面位置線に該当する本発明の評価構造体の断面図、図5は図2に示したc断面位置線に該当する本発明の評価構造体の断面図、図6は図3の○部の拡大図、及び図7は図3の部分断面斜視図である。
本発明の評価構造体を図2の透視平面図で説明すると、実線部で示された上部側の第一導体層4に設けられた電気配線と、鎖線部で示された下部側の第二導体層5に設けられた電気配線とが、導体層7を内壁に有する貫通ビア6を介して直列のチェーン配線を形成し、それらが平行に設けられている。本発明においては、第一導体層4及び第二導体層5(以下。外層導体層4、5と言うことがある。)の各電気配線幅は、貫通ビア6の径と同等以下とされる。
本発明の評価構造体を図3及び図4の断面図から見ると、銅張り積層板の内部絶縁層1の外層導体層4、5に電気配線が設けられ、それら外層導体層4、5は上部をプリプレグからなる表面絶縁層2で被覆されている。その電気配線は、貫通ビア6によって接続された直列のチェーン配線を形成している。
さらに本発明の構造体は、図5に示したように、直列のチェーン配線が貫通ビア間の壁間絶縁距離Hを保って平行に設けられている。その結果、評価試験時に、それぞれの直列のチェーン配線に異種の電源を交互に接続することにより、この部分での絶縁評価試験が可能となる。
図6は、図3の○部の拡大図であり、前記貫通ビア6の内壁に設けられた導体層7の端部は、表面絶縁層2の表面3よりも距離Lだけ、内層側にある。この距離Lとしては、
表面絶縁層の厚みの1/3〜2/3程度が好ましく、通常20〜40μm程度とするが、これに限られない。
貫通ビアの内壁に設けられた導体層7の端部を表面絶縁層2の表面3より内層側に設けたことにより、ソルダーレジスト層を設けなくても、結露や表面汚染の影響を防止することができる。
図3の部分断面斜視図である図7から、外層導体層4、5の電気配線が、内壁に導体層7を有する貫通ビア6を介して、直列のチェーン配線を形成するように設けられていることがわかる。又、前記貫通ビア6の内壁に設けられた導体層7の端部は表面絶縁層2の表面3よりも内層側にあることもわかる。
The present invention will be described with reference to the drawings.
First, FIG. 1 is a diagram for explaining terms in the present invention. In the present invention, the insulation distance between walls is the insulation distance between inner walls when drilling (H in FIG. 1), and the diameter of the hole is The diameter of a drill hole (through via) (M in FIG. 1). Furthermore, the pitch interval in the present invention is the distance between the centers of the holes when drilling (N in FIG. 1).
2-7 is a figure which shows the evaluation structure of this invention.
2 is a perspective plan view of the evaluation structure of the present invention, FIG. 3 is a cross-sectional view of the evaluation structure of the present invention corresponding to the a cross-section position line shown in FIG. 2, and FIG. 4 is a b cross-section shown in FIG. 5 is a cross-sectional view of the evaluation structure of the present invention corresponding to the position line, FIG. 5 is a cross-sectional view of the evaluation structure of the present invention corresponding to the c-section position line shown in FIG. 2, and FIG. 7 and 7 are partial sectional perspective views of FIG.
The evaluation structure of the present invention will be described with reference to the perspective plan view of FIG. 2. The electrical wiring provided on the first conductor layer 4 on the upper side indicated by the solid line part and the second on the lower side indicated by the chain line part. The electrical wiring provided in the conductor layer 5 forms a chain wiring in series via the through via 6 having the conductor layer 7 on the inner wall, and these are provided in parallel. In the present invention, each electric wiring width of the first conductor layer 4 and the second conductor layer 5 (hereinafter, sometimes referred to as outer conductor layers 4 and 5) is equal to or less than the diameter of the through via 6. .
When the evaluation structure of the present invention is viewed from the cross-sectional views of FIGS. 3 and 4, electrical wiring is provided on the outer conductor layers 4 and 5 of the inner insulating layer 1 of the copper-clad laminate, and the outer conductor layers 4 and 5 are The upper part is covered with a surface insulating layer 2 made of prepreg. The electric wiring forms a series chain wiring connected by the through via 6.
Furthermore, in the structure of the present invention, as shown in FIG. 5, serial chain wirings are provided in parallel while maintaining an inter-wall insulating distance H between through vias. As a result, it is possible to perform an insulation evaluation test in this portion by alternately connecting different types of power supplies to the respective series chain wirings during the evaluation test.
FIG. 6 is an enlarged view of a circled portion in FIG. 3, and the end portion of the conductor layer 7 provided on the inner wall of the through via 6 is on the inner layer side by a distance L from the surface 3 of the surface insulating layer 2. . As this distance L,
It is preferably about 1/3 to 2/3 of the thickness of the surface insulating layer and is usually about 20 to 40 μm, but is not limited thereto.
By providing the end portion of the conductor layer 7 provided on the inner wall of the through via on the inner layer side from the surface 3 of the surface insulating layer 2, it is possible to prevent the influence of condensation and surface contamination without providing a solder resist layer. Can do.
From FIG. 7, which is a partial sectional perspective view of FIG. 3, the electrical wiring of the outer conductor layers 4 and 5 is provided so as to form a serial chain wiring via a through via 6 having the conductor layer 7 on the inner wall. I understand that. It can also be seen that the end portion of the conductor layer 7 provided on the inner wall of the through via 6 is on the inner layer side of the surface 3 of the surface insulating layer 2.

本発明においては、図3及び図4のように、外層導体層4、5に電気配線が形成された銅張り積層板の上層に、プリプレグからなる表面絶縁層2が設けられた内層回路含有基板に対して、内壁に導体層7を有する貫通ビア6を形成して、前記外層導体層4、5の各電気配線を貫通ビア6の内壁に設けられた導体層7で接続する構成となるので、各電気配線幅は貫通ビア6の径以下とすることができ、これによりランドレス接続が容易となる。その結果、複数の直列のチェーン配線間の最小絶縁距離は、そのまま隣り合う貫通ビア間の壁間絶縁距離Hとなり、Hが0.03〜0.1mmの層間接続回路を形成することができるようになる。
壁間絶縁距離Hがこの範囲内であると、外層導体層4、5の各電気配線が比較的容易に形成可能で、かつ、CAFによる絶縁劣化を精度良く評価することが可能となる。
又、前記貫通ビア6の直径は、好ましくは0.15mm以下とすると、高い穴位置精度で貫通ビアを形成することが可能であり、上記の壁間絶縁距離Hを容易に確保することができる。
又、本発明では、前記外層回路層上にプリプレグからなる表面絶縁層2を設け、かつ貫通ビア6の内壁に設けられた導体層7の端部は、前記表面絶縁層2の表面3よりも距離Lだけ、内層側に設けることで、結露や表面汚染を防ぐためのソルダーレジスト層を設ける必要を無くし、かつCAF以外の絶縁劣化因子が生じるのを抑制することができる。この距離Lとしては、前述の通り、表面絶縁層の厚みの1/3〜2/3程度が好ましく、通常20〜40μm程度とするが、この距離Lを設ける手順を次に説明する。
上記の通り、貫通ビア6を設けた後、内層回路含有基板全体をめっきする。その結果、貫通ビア6の内壁と表面絶縁層2の上に導体層7が形成されるので、次いで、貫通ビア6内を耐エッチング性穴埋め剤で充填し、前記基板を加熱して前記穴埋め剤を硬化させる。次いで前記基板両面を研磨して、表面絶縁層2の上の導体層表面と穴埋め剤の端部を研磨により同一平面とした後、塩化第二鉄溶液等のエッチング剤でエッチングを行い、前記導体層を除去する。この際、表面絶縁層2の上の導体層は、表面からエッチングが進行するのに対して、貫通ビア6内の穴埋め剤と導体層7との界面では、表面からのエッチングにサイドエッチングが加わるため、貫通ビア6の内壁方向にエッチングが進む。このため、表面絶縁層2上の前記導体層が全てエッチングされた段階で、穴埋め剤と接する部分の導体層7のエッチング深度は、表面絶縁層2の表面3よりも深くなり、その結果、貫通ビア6の内壁に設けられた導体層7の端部は表面絶縁層2の表面3よりも内層側に形成される。
この距離Lは、表面絶縁層2の上の導体層表面と穴埋め剤の端部を整面機等を用いて研磨して同一平面としたときに表面絶縁層2の上の厚みを5〜15μmとすることで制御することができる。
In the present invention, as shown in FIGS. 3 and 4, the inner layer circuit-containing substrate in which the surface insulating layer 2 made of prepreg is provided on the upper layer of the copper-clad laminate in which the electric wiring is formed on the outer conductor layers 4 and 5. On the other hand, the through via 6 having the conductor layer 7 is formed on the inner wall, and the electric wirings of the outer conductor layers 4 and 5 are connected by the conductor layer 7 provided on the inner wall of the through via 6. The width of each electric wiring can be made equal to or smaller than the diameter of the through via 6, thereby facilitating landless connection. As a result, the minimum insulation distance between a plurality of serial chain wirings becomes the insulation distance H between adjacent vias as it is, so that an interlayer connection circuit having H of 0.03 to 0.1 mm can be formed. become.
When the insulation distance H between the walls is within this range, the electric wirings of the outer conductor layers 4 and 5 can be formed relatively easily, and it is possible to accurately evaluate the insulation deterioration due to CAF.
Further, if the diameter of the through via 6 is preferably 0.15 mm or less, the through via can be formed with high hole position accuracy, and the above-described insulation distance H between the walls can be easily secured. .
In the present invention, the surface insulating layer 2 made of prepreg is provided on the outer layer circuit layer, and the end portion of the conductor layer 7 provided on the inner wall of the through via 6 is more than the surface 3 of the surface insulating layer 2. By providing only the distance L on the inner layer side, it is not necessary to provide a solder resist layer for preventing dew condensation and surface contamination, and it is possible to suppress the occurrence of insulation deterioration factors other than CAF. As described above, the distance L is preferably about 1/3 to 2/3 of the thickness of the surface insulating layer and is usually about 20 to 40 μm. The procedure for providing this distance L will be described below.
As described above, after the through via 6 is provided, the entire inner layer circuit-containing substrate is plated. As a result, the conductor layer 7 is formed on the inner wall of the through via 6 and the surface insulating layer 2. Then, the inside of the through via 6 is filled with an etching resistant filling agent, and the substrate is heated to fill the filling agent. Is cured. Next, both surfaces of the substrate are polished so that the surface of the conductor layer on the surface insulating layer 2 and the end of the filling agent are made flat by polishing, and then etched with an etching agent such as a ferric chloride solution. Remove the layer. At this time, the conductor layer on the surface insulating layer 2 is etched from the surface, whereas side etching is added to the etching from the surface at the interface between the filling agent in the through via 6 and the conductor layer 7. Therefore, etching proceeds in the direction of the inner wall of the through via 6. For this reason, at the stage where all the conductor layers on the surface insulating layer 2 are etched, the etching depth of the conductor layer 7 in the portion in contact with the hole filling agent becomes deeper than the surface 3 of the surface insulating layer 2, resulting in penetration The end portion of the conductor layer 7 provided on the inner wall of the via 6 is formed on the inner layer side of the surface 3 of the surface insulating layer 2.
This distance L is such that the thickness of the surface insulating layer 2 is 5 to 15 μm when the surface of the conductor layer on the surface insulating layer 2 and the end of the hole-filling agent are polished to the same plane by using a leveling machine or the like. Can be controlled.

本発明の評価構造体においては、銅張り積層板用の積層板として、ガラスクロス、フェルト等の織布や紙等と、エポキシ樹脂、ポリイミド樹脂、フェノール樹脂、メラニン樹脂等の熱硬化樹脂よりなるプリプレグを含む積層板を使用することができる。
又、本発明で使用する表面絶縁層2に使用するプリプレグも、前記同様のものを採用することができる。特に、CAFによる影響を測定する場合には、表面絶縁層のプリプレグに用いる樹脂は、出来るだけ他の影響因子を排除するために、内部絶縁層と同じ樹脂組成物を用いることが好ましい。
このような積層板やプリプレグは1枚だけ使用してもよく、又必要により、複数枚積層させて使用してもよい。
前記の好ましい積層板として、ガラスエポキシ積層板やガラスコンポジット積層板が挙げられる。
これらの積層板やプリプレグのガラスクロスの厚みは、0.05mm以下とし、さらに各々の絶縁層の厚みを0.1mm以下とすると、貫通ビア6を設ける際、貫通ビア6の壁面からガラスクロスと熱硬化性樹脂との界面に生じるクラックを小さくすることができるうえ、層間接続回路形成時のめっき等の染み込みによる絶縁不良の発生を抑制することができるので好ましい。
前記表面絶縁層を含む積層板を採用することにより、特にCAFによる絶縁劣化を測定することが可能となる。特にCAFによる絶縁劣化を測定する場合、1)早く結果を知ることができる、2)基板の厚みの影響が小さい、といった理由から、本発明の評価構造体は、表面絶縁層がプリプレグを備えている。
In the evaluation structure of the present invention, the laminated plate for the copper-clad laminate is made of woven fabric or paper such as glass cloth or felt, and thermosetting resin such as epoxy resin, polyimide resin, phenol resin, or melanin resin. Laminates containing prepregs can be used.
Moreover, the same thing as the above can also be employ | adopted for the prepreg used for the surface insulating layer 2 used by this invention. In particular, when measuring the influence of CAF, it is preferable to use the same resin composition as that of the internal insulating layer as the resin used for the prepreg of the surface insulating layer in order to eliminate other influencing factors as much as possible.
Only one such laminate or prepreg may be used, or a plurality of such laminates or prepregs may be laminated if necessary.
Examples of the preferable laminate include a glass epoxy laminate and a glass composite laminate.
When the thickness of the glass cloth of these laminated plates and prepregs is 0.05 mm or less, and the thickness of each insulating layer is 0.1 mm or less, when the through via 6 is provided, the glass cloth is separated from the wall surface of the through via 6. This is preferable because cracks generated at the interface with the thermosetting resin can be reduced and the occurrence of insulation failure due to permeation such as plating when forming the interlayer connection circuit can be suppressed.
By adopting a laminate including the surface insulating layer, it is possible to measure insulation deterioration due to CAF in particular. In particular, when measuring insulation degradation due to CAF, the evaluation structure of the present invention has a prepreg on the surface insulating layer for the reasons that 1) the result can be obtained quickly and 2) the influence of the thickness of the substrate is small. Yes.

次に、本発明の評価構造体を用いた評価試験方法を説明する。
図2〜4に示す通り、本発明の評価構造体の内層に設けられた直列の各チェーン配線端部に電源接続用の端子8、9となる部分が、片方の端部に交互に設けられているので、それらを露出させた後、いずれか一つのチェーン配線の端子に電源のプラス極、又はマイナス極を接続する。次に、その直列チェーン配線に隣り合う直列チェーン配線の端子には、電源のマイナス極、又はプラス極を接続する。このようにして、通常、内層回路を構成するすべての直列のチェーン配線に、隣り合うチェーン配線毎に逆性の電源を接続する。
次に、この電源から電圧を印加し、絶縁抵抗値が一定以下になる時間を計測する。その結果から試験に供した評価構造体の寿命を計算することができる。
評価試験の際、劣化加速条件となるように、評価試験雰囲気は吸湿条件下とする。具体的には、温度85℃、湿度85%RH、又は40℃、90〜95%RH等の定常加湿試験等が採用される。さらに、半導体実装基板では、半導体デバイスの評価試験を想定した温度110〜130℃、湿度85%RH等の高度加速寿命試験(HAST)も採用することができる。
Next, an evaluation test method using the evaluation structure of the present invention will be described.
As shown in FIGS. 2 to 4, power supply connection terminals 8 and 9 are alternately provided at one end of each chain wiring end provided in the inner layer of the evaluation structure of the present invention. Therefore, after exposing them, the positive or negative pole of the power source is connected to the terminal of any one of the chain wirings. Next, the negative pole or positive pole of the power supply is connected to the terminal of the serial chain wiring adjacent to the serial chain wiring. In this way, normally, an inverse power supply is connected to every series of chain wirings constituting the inner layer circuit for each adjacent chain wiring.
Next, a voltage is applied from this power source, and the time during which the insulation resistance value is below a certain value is measured. From the result, the lifetime of the evaluation structure subjected to the test can be calculated.
In the evaluation test, the evaluation test atmosphere is a moisture absorption condition so that the deterioration acceleration condition is satisfied. Specifically, a steady humidification test such as a temperature of 85 ° C. and a humidity of 85% RH or 40 ° C. and 90 to 95% RH is adopted. Furthermore, the semiconductor mounting substrate can employ a high accelerated life test (HAST) such as a temperature of 110 to 130 ° C. and a humidity of 85% RH assuming an evaluation test of a semiconductor device.

以上のとおり、本発明の評価構造体は、貫通ビア間の壁間絶縁距離Hが0.03〜0.1mmの層間接続回路部であっても、十分実用的な評価構造体であり、それを用いた絶縁信頼性評価試験、特にCAFによる絶縁劣化性能試験を高精度、高信頼度で行うことが可能となる。   As described above, the evaluation structure of the present invention is a sufficiently practical evaluation structure even if it is an interlayer connection circuit portion having an inter-wall insulation distance H of 0.03 to 0.1 mm between through vias. It is possible to perform an insulation reliability evaluation test using the above, particularly an insulation deterioration performance test by CAF with high accuracy and high reliability.

以下に、本発明を実施例によって具体的に説明するが、本発明はこれらの実施例に限定されるものではない。   EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.

実施例1
内部にクレゾールノボラック型エポキシ樹脂(東都化成株式会社の商品名YDCN703)100質量部とビスフェノールA型エポキシ樹脂(ジャパンエポキシレジン株式会社の商品名エポコート828)64質量部とビスフェノールA型ノボラック樹脂(大日本インキ化学工業株式会社の商品名VH−4150)94質量部と2−エチルー4−メチルイミダゾール0.8質量部からなるハロゲンフリーエポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなる絶縁層(厚さ0.07mm)を含む銅張り積層板を用いて、外層導体層上に耐エッチング性のレジスト層(図示せず)を形成して焼付け、現像して、所定のパターンに形成後、エッチング、剥離等の工程を経て、前記積層板の一方の面に配線幅0.1mmでピッチ間隔が0.15mm、長さ1mm、厚さ0.018mmの鎖線状の第一導体層の電気配線を、0.05mmの壁間絶縁距離で平行に複数個形成した。又、異なる他方の面にも、図2〜4に示すように内壁に導体を有する貫通ビアを設けたときに、これら外層導体層の電気配線が相互に繋がって直列のチェーン配線となるように、上記第一導体層の配線と対向する所に、第一導体層の電気配線と同様に、第二導体層の電気配線を平行に複数個形成した。
次いで、前記外層導体層の電気配線の各上層に前記ハロゲンフリーエポキシ樹脂組成物と厚さ0.05mmのガラスクロスからなるプリプレグ各1枚を表面絶縁層として積層し、外層導体層の電気配線が内層となる内層回路含有基板を作製した。
次に、該内層回路含有基板に、外層導体層の各電気配線を接続する貫通ビア(直径0.1mm)を、壁間絶縁距離が0.05mm、となるように設けた後、めっきして貫通ビア内壁面と表面絶縁層表面に導体層(厚さ0.02mm)を形成した。
次いで、スキージを用いて、耐エッチング性穴埋め剤(メーカー名:クラリアントジャパン、商品名:AZ10XT)で貫通ビアを充填した後、前記基板を加熱して前記穴埋め剤を硬化させた。次に前記基板の両面を研磨して、表面絶縁層の上の前記導体層と前記穴埋め剤の端部とを同一平面とした。そのとき、表面絶縁層の表面から表面絶縁層の上の導体層の表面までの距離は整面機を用いて10μmに調整した。その後、塩化第二鉄溶液でエッチングを行い、前記表面導体層の除去を行った。その結果、貫通ビア内壁の導体層端部は、表面絶縁層の表面よりも20μm内層側に形成された。
その後、前記穴埋め剤を剥離液(メーカー名:クラリアントジャパン、商品名:AZリムーバー)で除去して、外層導体層の各電気配線が内壁に導体層を有する貫通ビアを介して交互に接続された直列のチェーン配線を形成している評価構造体を作製した。
Example 1
Inside, 100 parts by mass of cresol novolac type epoxy resin (trade name YDCN703 of Toto Kasei Co., Ltd.) and 64 parts by mass of bisphenol A type epoxy resin (trade name Epocoat 828 of Japan Epoxy Resin Co., Ltd.) and bisphenol A type novolak resin (Dainippon) Ink Chemical Industries, Ltd., trade name VH-4150) consisting of 94 parts by mass of halogen-free epoxy resin composition consisting of 0.8 parts by mass of 2-ethyl-4-methylimidazole and one glass cloth having a thickness of 0.05 mm. Using a copper-clad laminate including an insulating layer (thickness 0.07 mm), an etching-resistant resist layer (not shown) is formed on the outer conductor layer, baked, developed, and formed into a predetermined pattern Then, after passing through processes such as etching and peeling, a pitch interval of 0.1 mm is provided on one side of the laminate. 0.15 mm, length 1 mm, the electrical wiring of the chain linear first conductor layer having a thickness of 0.018 mm, in parallel to a plurality formed in walls insulation distance 0.05 mm. In addition, when through vias having conductors are provided on the inner wall as shown in FIGS. 2 to 4 on the other different surface, the electric wirings of these outer conductor layers are connected to each other to form a serial chain wiring. In the same manner as the electrical wiring of the first conductor layer, a plurality of electrical wirings of the second conductor layer were formed in parallel with the wiring of the first conductor layer.
Next, on each upper layer of the electric wiring of the outer conductor layer, each prepreg made of the halogen-free epoxy resin composition and a glass cloth having a thickness of 0.05 mm is laminated as a surface insulating layer, and the electric wiring of the outer conductor layer is An inner layer circuit-containing substrate to be an inner layer was produced.
Next, a through via (diameter of 0.1 mm) for connecting each electric wiring of the outer layer conductor layer is provided on the inner layer circuit-containing substrate so that the insulation distance between walls is 0.05 mm, and then plated. A conductor layer (thickness 0.02 mm) was formed on the inner wall surface of the through via and the surface insulating layer surface.
Next, using a squeegee, the through-via was filled with an etching-resistant filling agent (manufacturer name: Clariant Japan, trade name: AZ10XT), and then the substrate was heated to cure the filling agent. Next, both surfaces of the substrate were polished so that the conductor layer on the surface insulating layer and the end portion of the filling agent were flush with each other. At that time, the distance from the surface of the surface insulating layer to the surface of the conductor layer on the surface insulating layer was adjusted to 10 μm using a leveling machine. Thereafter, etching was carried out with a ferric chloride solution to remove the surface conductor layer. As a result, the conductor layer end portion of the inner wall of the through via was formed on the inner layer side of 20 μm from the surface of the surface insulating layer.
Thereafter, the hole filling agent was removed with a stripping solution (manufacturer name: Clariant Japan, product name: AZ remover), and each electric wiring of the outer layer conductor layer was alternately connected via through vias having a conductor layer on the inner wall. An evaluation structure in which series chain wiring is formed was produced.

実施例2
複数の直列のチェーン配線の貫通ビア間の壁間絶縁間隔を0.075mmとした以外は、実施例1と同様にして評価構造体を作製した。
Example 2
An evaluation structure was produced in the same manner as in Example 1 except that the inter-wall insulation interval between through vias of a plurality of serial chain wirings was set to 0.075 mm.

実施例3
複数の直列のチェーン配線の貫通ビア間の壁間絶縁間隔を0.1mmとした以外は、実施例1と同様にして評価構造体を作製した。
Example 3
An evaluation structure was produced in the same manner as in Example 1 except that the inter-wall insulation interval between through vias of a plurality of serial chain wirings was set to 0.1 mm.

実施例4
銅張り積層板がクレゾールノボラック型エポキシ樹脂(東都化成株式会社の商品名YDCN703)100質量部とテトラブロモビスフェノールA型エポキシ樹脂(大日本インキ化学工業株式会社の商品名エピクリン153)135質量部とビスフェノールA型ノボラック樹脂(大日本インキ化学工業株式会社の商品名VH−4150)94質量部と2−エチルー4−メチルイミダゾール0.8質量部からなる臭素含有エポキシ樹脂組成物(臭素含有率20質量%)と厚さ0.05mmのガラスクロス1枚とからなるものに変更し、外層導体層の各電気配線上に形成した表面絶縁層を前記臭素含有エポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなるプリプレグに変更した以外は、実施例1と同様に評価構造体を作製した。
Example 4
Copper-clad laminate is 100 parts by mass of cresol novolac type epoxy resin (trade name YDCN703 of Toto Kasei Co., Ltd.) and 135 parts by mass of tetrabromobisphenol A type epoxy resin (trade name Epiclin 153 of Dainippon Ink & Chemicals, Inc.) and bisphenol. Bromine-containing epoxy resin composition consisting of 94 parts by mass of type A novolac resin (trade name VH-4150, Dainippon Ink and Chemicals, Inc.) and 0.8 parts by mass of 2-ethyl-4-methylimidazole (bromine content 20% by mass) ) And one glass cloth having a thickness of 0.05 mm, and the surface insulating layer formed on each electric wiring of the outer conductor layer is composed of the bromine-containing epoxy resin composition and a glass having a thickness of 0.05 mm. An evaluation structure was produced in the same manner as in Example 1 except that the prepreg was made of one cloth.

実施例5
銅張り積層板が前記臭素含有エポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなるものに変更し、外層導体層の各電気配線上に形成した表面絶縁層を前記臭素含有エポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなるプリプレグに変更した以外は、実施例2と同様に評価構造体を作製した。
Example 5
The copper-clad laminate was changed to the one containing the bromine-containing epoxy resin composition and one glass cloth having a thickness of 0.05 mm, and the surface insulating layer formed on each electric wiring of the outer conductor layer was replaced with the bromine-containing epoxy. An evaluation structure was produced in the same manner as in Example 2 except that the prepreg was composed of a resin composition and one glass cloth having a thickness of 0.05 mm.

実施例6
銅張り積層板が前記臭素含有エポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなるものに変更し、外層導体層の各電気配線上に形成した表面絶縁層を前記臭素含有エポキシ樹脂組成物と厚さ0.05mmのガラスクロス1枚とからなるプリプレグに変更した以外は、実施例3と同様に評価構造体を作製した。
Example 6
The copper-clad laminate was changed to the one containing the bromine-containing epoxy resin composition and one glass cloth having a thickness of 0.05 mm, and the surface insulating layer formed on each electric wiring of the outer conductor layer was replaced with the bromine-containing epoxy. An evaluation structure was produced in the same manner as in Example 3 except that the prepreg was changed to a resin composition and one glass cloth having a thickness of 0.05 mm.

比較例1
内部にクレゾールノボラック型エポキシ樹脂(東都化成株式会社の商品名YDCN703)100質量部とビスフェノールA型エポキシ樹脂(ジャパンエポキシレジン株式会社の商品名エポコート828)64質量部とビスフェノールA型ノボラック樹脂(大日本インキ化学工業株式会社の商品名VH−4150)94質量部と2−エチルー4−メチルイミダゾール0.8質量部からなるハロゲンフリーエポキシ樹脂組成物と厚さ0.05mmのガラスクロス3枚とからなる絶縁層厚み0.21mmの銅張り積層板に貫通ビア(直径0.1mm)を壁間絶縁距離が0.1mmとなるように複数個、平行に所定の位置に形成した後、めっきで貫通ビア壁面及び銅張り積層板表面に厚さ0.02mmの金属導体層を形成した。次いで外層導体層の上に耐エッチング性のレジスト層を形成して焼付け、現像して、所定のパターンを形成し、貫通ビア入口をマスクした後、エッチング、及び剥離等の工程を経て、該銅張り積層板の一方の面に、配線幅0.1mm、ランド径0.15mm、及び隣り合う最近接のチェーン配線の貫通ビアのランド間が0.05mmの絶縁距離で並行して前記貫通ビアと接続するように、実施例1同様、鎖線状の第一導体層の電気配線を形成し、該銅張り積層板の他方の面にも、前記同様にして貫通ビアを介して交互に接続された直列のチェーン配線となるように第二導体層の電気配線を形成して外層回路接続型となる評価構造体を作製した。
Comparative Example 1
Inside, 100 parts by mass of cresol novolac type epoxy resin (trade name YDCN703 of Toto Kasei Co., Ltd.) and 64 parts by mass of bisphenol A type epoxy resin (trade name Epocoat 828 of Japan Epoxy Resin Co., Ltd.) and bisphenol A type novolac resin (Dainippon) Ink Chemical Industries, Ltd., trade name VH-4150) consisting of 94 parts by mass of halogen-free epoxy resin composition consisting of 0.8 parts by mass of 2-ethyl-4-methylimidazole and 3 pieces of glass cloth having a thickness of 0.05 mm. A plurality of through vias (diameter: 0.1 mm) are formed in parallel at a predetermined position in a copper-clad laminate with an insulating layer thickness of 0.21 mm so that the insulation distance between the walls is 0.1 mm, and then through vias are plated. A metal conductor layer having a thickness of 0.02 mm was formed on the wall surface and the surface of the copper-clad laminate. Next, an etching-resistant resist layer is formed on the outer conductor layer, baked and developed to form a predetermined pattern, and after masking the through-via entrance, the copper is subjected to etching, peeling, and the like. On one surface of the laminated laminate, the through-via is parallel to the wiring width of 0.1 mm, the land diameter of 0.15 mm, and the distance between the adjacent via vias of the nearest chain wiring is 0.05 mm. In the same manner as in Example 1, an electrical wiring of a chain-line-shaped first conductor layer was formed so as to be connected, and the other surface of the copper-clad laminate was also alternately connected through through vias in the same manner as described above. An electric wiring of the second conductor layer was formed so as to form a series chain wiring, and an evaluation structure body of an outer layer circuit connection type was produced.

比較例2
隣り合う直列チェーン配線の貫通ビア間の壁間絶縁距離が0.15mmとなるように形成し、チェーン配線の貫通ビアのランド間が0.1mmの絶縁距離で平行に並び、貫通ビアと接続するように形成した以外は、比較例1と同様に外層回路接続型となる評価構造体を作製した。
Comparative Example 2
It is formed so that the insulation distance between the walls between the through vias of adjacent series chain wirings is 0.15 mm, and the lands of the through vias of the chain wiring are arranged in parallel with an insulation distance of 0.1 mm and connected to the through vias. An evaluation structure that is an outer layer circuit connection type was produced in the same manner as in Comparative Example 1 except that it was formed as described above.

上記のようにして製作した実施例1〜6及び比較例1〜2の評価構造体の各端子を露出させ、電極のプラス極とマイナス極とを交互に接続して6Vの電圧を印加し、湿度85%RH、温度110℃の吸湿条件下で、チェーン配線間の吸湿絶縁抵抗を絶縁抵抗計で測定した。
結果を表1の絶縁劣化開始時間、絶縁劣化状態の欄に示す。なお、絶縁劣化の判定は吸湿絶縁抵抗値が106Ω以下とした。
Exposing the terminals of the evaluation structures of Examples 1 to 6 and Comparative Examples 1 and 2 manufactured as described above, applying a voltage of 6 V by alternately connecting the positive and negative electrodes of the electrodes, The moisture absorption insulation resistance between the chain wires was measured with an insulation resistance meter under the moisture absorption conditions of a humidity of 85% RH and a temperature of 110 ° C.
The results are shown in the column of insulation deterioration start time and insulation deterioration state in Table 1. In addition, the determination of insulation deterioration was made such that the moisture absorption insulation resistance value was 10 6 Ω or less.

Figure 0005056489
Figure 0005056489

表1の比較例の結果に見られるように、壁間絶縁距離0.15mm(ランド間の最小絶縁距離0.1mm)では、500時間まで絶縁劣化は生じなかったものの、壁間絶縁距離0.1mm(ランド間の最小絶縁距離0.05mm)では、73時間が経過したところで第一導体回路のランド部にデンドライトによる絶縁劣化が生じた。これに対して比較例と同じハロゲンフリー樹脂が内部絶縁層を構成する実施例1〜3では、壁間絶縁距離が0.05〜0.1mmでも、500時間まで絶縁劣化は生じなかった。又、絶縁層がハロゲン含有樹脂の実施例をみると、壁間絶縁距離0.05mmの実施例4では、165時間経過したとろでCAFによる絶縁劣化が生じ、壁間絶縁距離が0.075mmの実施例5では、346時間経過したところでCAFによる絶縁劣化が生じ、壁間絶縁距離が0.1mmの実施例6では、480時間経過したとろでCAFによる絶縁劣化が生じた。これらのことから、本発明が、層間接続回路部に生じるCAFのレベルを評価するのに適しており、ハロゲンフリー樹脂とハロゲン含有樹脂とでは、CAFの発生し易さに差があることが確認できた。又、本発明は比較例1のようなCAF以外の絶縁劣化要因を生じ難くいことが確認できた。   As can be seen from the results of the comparative examples in Table 1, the insulation distance between the walls was 0.15 mm (the minimum insulation distance between the lands was 0.1 mm). At 1 mm (minimum insulation distance between lands of 0.05 mm), insulation deterioration due to dendrite occurred in the land portion of the first conductor circuit after 73 hours had passed. On the other hand, in Examples 1 to 3 in which the same halogen-free resin as that in the comparative example constitutes the inner insulating layer, the insulation deterioration did not occur until 500 hours even when the insulation distance between the walls was 0.05 to 0.1 mm. Moreover, when the insulating layer is an example of a halogen-containing resin, in Example 4 where the insulation distance between walls is 0.05 mm, insulation deterioration occurs due to CAF after 165 hours, and the insulation distance between walls is 0.075 mm. In Example 5, the insulation deterioration due to CAF occurred when 346 hours passed, and in Example 6 where the insulation distance between the walls was 0.1 mm, the insulation deterioration caused by CAF occurred after 480 hours. From these facts, it is confirmed that the present invention is suitable for evaluating the level of CAF generated in the interlayer connection circuit portion, and it is confirmed that there is a difference in the ease of CAF generation between the halogen-free resin and the halogen-containing resin. did it. In addition, it was confirmed that the present invention hardly causes an insulation deterioration factor other than CAF as in Comparative Example 1.

以上のように、本発明は、電気回路となる直列のチェーン配線に設けられた貫通ビアと接続する電気配線幅を前記貫通ビア径以下とし、かつ、外層導体層上にプリプレグからなる表面絶縁層を設けると共に、前記貫通ビアの内壁に設けられた導体層の端部が、前記表面絶縁層の表面よりも内層側にある評価構造体とすることによって、プリント配線板層間接続回路部の前記貫通ビア間の壁間絶縁距離が、例えば0.1mm以下といったきわめて小さい値に設定することができ、加えて、銅張り積層板の上層にプリプレグからなる表面絶縁層を設けたので、ソルダーレジスト層を形成する必要がない。又、貫通ビア内壁の導体層端部は前記表面絶縁層の表面よりも内層側に設けたので、結露や表面汚染にも評価試験が影響されることはない。
その結果、本発明の評価構造体を用いた絶縁信頼性評価試験では、特にCAFによる絶縁劣化を、高精度、高信頼度に評価することができる。
As described above, the present invention provides a surface insulating layer made of a prepreg on the outer conductor layer, wherein the width of the electric wiring connected to the through via provided in the serial chain wiring serving as an electric circuit is equal to or smaller than the diameter of the through via. And the end of the conductor layer provided on the inner wall of the through via is an evaluation structure that is on the inner layer side of the surface of the surface insulating layer. The insulation distance between the walls between the vias can be set to a very small value, for example, 0.1 mm or less. In addition, since the surface insulating layer made of prepreg is provided on the upper layer of the copper-clad laminate, the solder resist layer is provided. There is no need to form. Further, since the end portion of the conductor layer on the inner wall of the through via is provided on the inner layer side with respect to the surface of the surface insulating layer, the evaluation test is not affected by condensation or surface contamination.
As a result, in the insulation reliability evaluation test using the evaluation structure of the present invention, insulation deterioration due to CAF can be evaluated with high accuracy and high reliability.

本発明の用語を説明する図The figure explaining the terminology of the present invention 本発明のプリント配線板層間接続回路の絶縁信頼性評価構造体の透視平面図Perspective plan view of insulation reliability evaluation structure of printed wiring board interlayer connection circuit of the present invention 図2に示したa断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to a cross-section position line shown in FIG. 図2に示したb断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to b cross-section position line shown in FIG. 図2に示したc断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to c cross-section position line shown in FIG. 図2の○部の拡大図Enlarged view of ○ in Figure 2 図2の部分断面斜視図Partial cross-sectional perspective view of FIG. 従来例のプリント配線板層間接続回路の絶縁信頼性評価構造体の透視平面図Perspective plan view of insulation reliability evaluation structure of printed wiring board interlayer connection circuit of conventional example 図8に示したd断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to d cross-section position line shown in FIG. 図8に示したe断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to e cross-section position line shown in FIG. 図8に示したf断面位置線に該当するプリント配線板層間接続回路の絶縁信頼性評価構造体の断面図Sectional drawing of the insulation reliability evaluation structure of the printed wiring board interlayer connection circuit applicable to the f cross-section position line shown in FIG.

符号の説明Explanation of symbols

1 銅張り積層板の内部絶縁層
2 表面絶縁層
3 表面絶縁層の表面
4 第一導体層
5 第二導体層
6 貫通ビア
7 導体層
8 端子
9 端子
a プラス側となるチェーン配線断面図位置線
b マイナス側となるチェーン配線断面図位置線
c プラス側となる貫通ビア、マイナス側となる貫通ビアの狭ピッチ部断面図位置線
10 内部絶縁層
11 第一導体層
12 第二導体層
13 ランド
14 貫通ビア
15 導体層
16 端子
17 端子
d プラス側となるチェーン配線断面図位置線
e マイナス側となるチェーン配線断面図位置線
f プラス側となる貫通ビア、マイナス側となる貫通ビアの狭ピッチ部断面図位置線
DESCRIPTION OF SYMBOLS 1 Inner insulating layer 2 of copper clad laminated board 2 Surface insulating layer 3 Surface insulating layer surface 4 First conductor layer 5 Second conductor layer 6 Through-via 7 Conductor layer 8 Terminal 9 Terminal a Position side line of chain wiring on the positive side b Chain wiring sectional view position line on the negative side c Penetration via on the positive side, narrow pitch section sectional view of the through via on the negative side 10 Inner insulating layer 11 First conductor layer 12 Second conductor layer 13 Land 14 Through-via 15 Conductor layer 16 Terminal 17 Terminal d Chain wiring cross-sectional view position line e on the positive side Chain wiring cross-sectional view position line f on the negative side Through-via on the positive side, narrow pitch section cross-section of the through via on the negative side Figure position line

Claims (7)

内部に絶縁層を有する銅張り積層板の一方の面の第一導体層に電気配線が、他方の面の第二導体層に電気配線がそれぞれ複数形成され、前記両導体層の上層にプリプレグからなる表面絶縁層が設けられた内層回路含有基板の前記第一導体層と第二導体層との電気配線が、内壁に導体層を有する貫通ビアを介して交互に接続された直列のチェーン配線を形成してなるプリント配線板層間接続回路評価構造体であって、前記貫通ビアと接続する各電気配線幅は、前記貫通ビア径以下であり、かつ、前記貫通ビアの内壁に設けられた導体層の端部が前記表面絶縁層の表面よりも内層側にあることを特徴とするプリント配線板層間接続回路部の絶縁信頼性評価構造体。   A plurality of electrical wirings are formed on the first conductor layer on one side of the copper-clad laminate having an insulating layer inside, and a plurality of electrical wirings are formed on the second conductor layer on the other side. A series chain wiring in which the electrical wiring of the first conductor layer and the second conductor layer of the inner layer circuit-containing substrate provided with the surface insulating layer is alternately connected through through vias having a conductor layer on the inner wall. A printed wiring board interlayer connection circuit evaluation structure formed, wherein each electric wiring width connected to the through via is equal to or smaller than the diameter of the through via, and a conductor layer provided on an inner wall of the through via An insulating reliability evaluation structure for a printed wiring board interlayer connection circuit section, wherein an end of the printed wiring board is on the inner layer side of the surface of the surface insulating layer. 前記直列のチェーン配線に設けられた貫通ビアと、隣り合う直列のチェーン配線に設けられた最近接の貫通ビアとの壁間絶縁距離が0.03mm〜0.1mmである請求項1に記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体。   The inter-wall insulation distance between a through via provided in the series chain wiring and a nearest through via provided in an adjacent series chain wiring is 0.03 mm to 0.1 mm. Insulation reliability evaluation structure of printed circuit board interlayer connection circuit section. 前記貫通ビアの直径が0.15mm以下である請求項1又は2に記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体。   The insulation reliability evaluation structure for a printed wiring board interlayer connection circuit part according to claim 1 or 2, wherein the diameter of the through via is 0.15 mm or less. 前記内部の絶縁層はガラスクロスを含み、前記ガラスクロスの厚みが0.05mm以下であって、前記絶縁層厚みが0.1mm以下である請求項1〜3のいずれかに記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体。   The printed wiring board according to claim 1, wherein the inner insulating layer includes a glass cloth, and the thickness of the glass cloth is 0.05 mm or less, and the insulating layer thickness is 0.1 mm or less. Insulation reliability evaluation structure of interlayer connection circuit. 前記表面絶縁層はガラスクロスを含み、前記絶縁層の厚みが0.1mm以下であって、前記ガラスクロスの厚みが0.05mm以下である請求項1〜4のいずれかに記載のプリント配線板層間接続回路部の絶縁信頼性評価構造体。   5. The printed wiring board according to claim 1, wherein the surface insulating layer includes a glass cloth, the insulating layer has a thickness of 0.1 mm or less, and the glass cloth has a thickness of 0.05 mm or less. Insulation reliability evaluation structure of interlayer connection circuit. 請求項1〜5のいずれかに記載の絶縁信頼性評価構造体の複数の直列のチェーン配線に、電源のプラス極とマイナス極を交互に接続し、吸湿条件下で電圧をかけて、前記チェーン配線間の吸湿絶縁抵抗を測定することを特徴とするプリント配線板層間接続回路部の絶縁信頼性評価試験方法。   The chain of the insulation reliability evaluation structure according to any one of claims 1 to 5, wherein a positive electrode and a negative electrode of a power source are alternately connected to each other, and a voltage is applied under a moisture absorption condition, thereby the chain. An insulation reliability evaluation test method for a printed wiring board interlayer connection circuit portion, characterized by measuring a hygroscopic insulation resistance between wirings. CAFによる絶縁劣化を測定するものである請求項6記載のプリント配線板層間接続回路部の絶縁信頼性評価試験方法。   The insulation reliability evaluation test method for printed wiring board interlayer connection circuit portions according to claim 6, wherein the insulation deterioration due to CAF is measured.
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