JP5062913B2 - リセス化された仕事関数金属を含む装置およびその製造方法 - Google Patents
リセス化された仕事関数金属を含む装置およびその製造方法 Download PDFInfo
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- JP5062913B2 JP5062913B2 JP2009506646A JP2009506646A JP5062913B2 JP 5062913 B2 JP5062913 B2 JP 5062913B2 JP 2009506646 A JP2009506646 A JP 2009506646A JP 2009506646 A JP2009506646 A JP 2009506646A JP 5062913 B2 JP5062913 B2 JP 5062913B2
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/013—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator
- H10D64/01302—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon
- H10D64/01304—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H10D64/01318—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the conductor comprising a layer of alloy material, compound material or organic material contacting the insulator, e.g. TiN
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/018—Spacers formed inside holes at the prospective gate locations, e.g. holes left by removing dummy gates
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/667—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of alloy material, compound material or organic material contacting the insulator, e.g. TiN workfunction layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/671—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor having lateral variation in doping or structure
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/013—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator
- H10D64/01302—Manufacture or treatment of electrodes having a conductor capacitively coupled to a semiconductor by an insulator the insulator being formed after the semiconductor body, the semiconductor being silicon
- H10D64/01332—Making the insulator
- H10D64/01336—Making the insulator on single crystalline silicon, e.g. chemical oxidation using a liquid
- H10D64/01342—Making the insulator on single crystalline silicon, e.g. chemical oxidation using a liquid by deposition, e.g. evaporation, ALD or laser deposition
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/691—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator comprising metallic compounds, e.g. metal oxides or metal silicates
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- Insulated Gate Type Field-Effect Transistor (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Electrodes Of Semiconductors (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Description
Claims (20)
- 基板と、
前記基板の表面上に配置された一対のスペーサと、
前記一対のスペーサ間で前記基板の前記表面上と前記一対のスペーサの側壁上にコンフォーマルに堆積された高k誘電体層と、
前記一対のスペーサ間で前記基板の前記表面に沿って、且つ、前記一対のスペーサの前記側壁の一部に沿って前記高k誘電体層上にコンフォーマルに堆積された、リセスされた仕事関数金属層と、
前記高k誘電体層に直接接触し、前記リセスされた仕事関数金属層上にコンフォーマルに堆積された第2の仕事関数金属層と、
前記第2の仕事関数金属層上に堆積された電極金属層と、
を含む装置。 - 前記基板は、半導体材料を含み、
前記一対のスペーサは、窒化ケイ素を含む、請求項1に記載の装置。 - 前記高k誘電体層は、酸化ハフニウム、ケイ酸ハフニウム、酸化ランタン、アルミン酸ランタン、酸化ジルコニウム、ケイ酸ジルコニウム、酸化タンタル、酸化チタン、チタン酸バリウムストロンチウム、チタン酸バリウム、チタン酸ストロンチウム、酸化イットリウム、酸化アルミニウム、タンタル酸鉛スカンジウム、又はニオブ酸鉛亜鉛を含む、請求項1に記載の装置。
- 前記リセスされた仕事関数金属層は、「U」字型である、請求項1に記載の装置。
- 前記リセスされた仕事関数金属層及び前記第2の仕事関数金属層は、それぞれ、ルテニウム、パラジウム、プラチナ、コバルト、ニッケル、導電性金属酸化物、酸化ルテニウム、ハフニウム、ジルコニウム、チタン、タンタル、アルミニウム、炭化ハフニウム、炭化ジルコニウム、炭化チタン、炭化タンタル、及び炭化アルミニウムからなる群から選択される少なくとも1つの金属を含む、請求項1に記載の装置。
- 前記電極金属は、タングステン、アルミニウム、銅、又は低抵抗率の金属を含む、請求項1に記載の装置。
- 前記一対のスペーサのうち一方に隣接するソース領域と、
前記一対のスペーサのうち他方に隣接するドレイン領域と、
前記高k誘電体層の下のチャネル領域と、
を更に含む、請求項1から6のいずれか一項に記載の装置。 - トレンチにより離間される一対のスペーサを有する基板を提供することと、
前記一対のスペーサ間の前記トレンチ内に高k誘電体層をコンフォーマルに堆積することと、
前記トレンチ内で前記高k誘電体層上に第1の仕事関数金属層をコンフォーマルに堆積することと、
前記トレンチ内で前記第1の仕事関数金属層上に犠牲マスキング材料を堆積することと、
前記第1の仕事関数金属層の一部を露出すべく前記トレンチの高さの2分の1乃至4分の3となるまで前記犠牲マスキング材料の一部をエッチングすることと、
リセスされた仕事関数金属層を形成すべく前記第1の仕事関数金属層の前記露出された一部をエッチングすることと、
残っている犠牲マスキング材料をエッチングすることと、
前記リセスされた仕事関数金属層および前記高k誘電体層上に第2の仕事関数金属層をコンフォーマルに堆積することと、
前記第2の仕事関数金属層上に電極金属層を堆積することと、
少なくとも前記電極金属層を平坦化することと、
を含む装置の製造方法。 - 前記第1の仕事関数金属層及び前記第2の仕事関数金属層は、それぞれ、ルテニウム、パラジウム、プラチナ、コバルト、ニッケル、導電性金属酸化物、酸化ルテニウム、ハフニウム、ジルコニウム、チタン、タンタル、アルミニウム、炭化ハフニウム、炭化ジルコニウム、炭化チタン、炭化タンタル、及び炭化アルミニウムからなる群から選択される少なくとも1つの金属を含む、請求項8に記載の製造方法。
- 前記犠牲マスキング材料は、SOG材料、SLAM材料、又はBARC材料を含む、請求項8に記載の製造方法。
- 前記犠牲マスキング材料の前記エッチングは、前記犠牲マスキング材料にフッ素系ウェットエッチング化学反応を施すことを含む、請求項8に記載の製造方法。
- 前記犠牲マスキング材料の前記エッチングは、前記犠牲マスキング材料にドライエッチング化学反応を施すことを含み、
前記ドライエッチング化学反応は、CH2F2ドライエッチング化学反応、SF6ドライエッチング化学反応、又はNF3ドライエッチング化学反応を含む、請求項8に記載の製造方法。 - 前記第1の仕事関数金属層の前記エッチングは、前記第1の仕事関数金属層にウェットエッチング化学反応を施すことを含み、
前記ウェットエッチング化学反応は、蒸留水、NH4OH、及びH2O2の組み合わせと、硫酸、過酸化物、及び蒸留水の組み合わせと、リン酸、酢酸、及び硝酸の組み合わせと、塩酸、H2O2、及び水の組み合わせと、塩酸、硝酸、及び水の組み合わせのうちの少なくとも1つを含む、請求項8に記載の製造方法。 - 前記第1の仕事関数金属層の前記エッチングは、前記第1の仕事関数金属層にドライエッチング化学反応を施すことを含む、請求項8に記載の製造方法。
- 基板を提供することと、
前記基板上に高k誘電体層を形成することと、
高kゲート誘電体層を形成すべく前記高k誘電体層をエッチングすることと、
前記高kゲート誘電体層の両端に一対のスペーサを形成することと、
前記一対のスペーサ間のトレンチ内及び前記高kゲート誘電体層上に第1の仕事関数金属層をコンフォーマルに堆積することと、
前記トレンチ内で前記第1の仕事関数金属層上に犠牲マスキング材料を堆積することと、
前記第1の仕事関数金属層の一部を露出すべく前記犠牲マスキング材料の一部をエッチングすることと、
リセスされた仕事関数金属層を形成すべく前記第1の仕事関数金属層の前記露出された一部をエッチングすることと、
残っている犠牲マスキング材料をエッチングすることと、
前記リセスされた仕事関数金属層および前記一対のスペーサ上に第2の仕事関数金属層をコンフォーマルに堆積することと、
前記第2の仕事関数金属層上に電極金属層を堆積することと、
少なくとも前記電極金属層を平坦化することと、
を含む装置の製造方法。 - 前記第1の仕事関数金属層及び前記第2の仕事関数金属層は、それぞれ、ルテニウム、パラジウム、プラチナ、コバルト、ニッケル、導電性金属酸化物、酸化ルテニウム、ハフニウム、ジルコニウム、チタン、タンタル、アルミニウム、炭化ハフニウム、炭化ジルコニウム、炭化チタン、炭化タンタル、及び炭化アルミニウムのうち少なくとも1つを含む、請求項15に記載の製造方法。
- 前記犠牲マスキング材料の前記エッチングは、フッ素系ウェットエッチング化学反応を施すことを含む、請求項15に記載の製造方法。
- 前記犠牲マスキング材料の前記エッチングは、CH2F2ドライエッチング化学反応、SF6ドライエッチング化学反応、又はNF3ドライエッチング化学反応を施すことを含む、請求項15に記載の製造方法。
- 前記第1の仕事関数金属層の前記エッチングは、蒸留水、NH4OH、及びH2O2の組み合わせと、硫酸、過酸化物、及び蒸留水の組み合わせと、リン酸、酢酸、及び硝酸の組み合わせと、塩酸、H2O2、及び水の組み合わせと、塩酸、硝酸、及び水の組み合わせのうちの少なくとも1つを施すことを含む、請求項15に記載の製造方法。
- 前記第1の仕事関数金属層の前記エッチングは、前記第1の仕事関数金属層にドライエッチング化学反応を施すことを含む、請求項15に記載の製造方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/431,388 | 2006-05-09 | ||
| US11/431,388 US8193641B2 (en) | 2006-05-09 | 2006-05-09 | Recessed workfunction metal in CMOS transistor gates |
| PCT/US2007/010482 WO2007133440A2 (en) | 2006-05-09 | 2007-05-01 | Recessed workfunction metal in cmos transistor gates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009534847A JP2009534847A (ja) | 2009-09-24 |
| JP5062913B2 true JP5062913B2 (ja) | 2012-10-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009506646A Active JP5062913B2 (ja) | 2006-05-09 | 2007-05-01 | リセス化された仕事関数金属を含む装置およびその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US8193641B2 (ja) |
| JP (1) | JP5062913B2 (ja) |
| KR (1) | KR101332104B1 (ja) |
| CN (1) | CN101438389A (ja) |
| DE (1) | DE112007001134B4 (ja) |
| GB (1) | GB2450836B (ja) |
| TW (1) | TWI354374B (ja) |
| WO (1) | WO2007133440A2 (ja) |
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