JP5065576B2 - Artificial hair fiber - Google Patents

Description

The present invention relates to a novel artificial hair fiber. More specifically, the present invention relates to a novel artificial hair fiber made of polyester fiber and having excellent durability.

  Conventionally, various synthetic fibers have been used as materials for artificial hair used in wigs, hair wigs, extensions, hair bands, and the like. However, since the polyvinyl chloride fiber that has been frequently used has a low strength, there is a problem that when the hair is subjected to a waving treatment and is conditioned, it is easily cut with a slight catch.

  Furthermore, since the dyeing fastness is low, there is also a problem that even those dyed with a cationic dye having relatively excellent light resistance are easily discolored by light received while wearing a wig. For this reason, in the case of black artificial hair, a method in which a black pigment is mixed with a fiber raw material and then produced is used, but the resulting fiber has a large surface reflected light, so the blackness like natural hair is not high. The actual situation is not obtained.

  In addition, since the polyvinyl chloride fiber has low durability against the heating set, curls and waves tend to disappear under conditions such as bathing, showering, sauna and sunlight. For this reason, when artificial hair is partially worn, only artificial hair is discolored, so that there is also a problem that it can be seen at first glance that it is artificial hair. In addition, since static electricity is easily generated due to friction during hair shaping, reverse hairs and dust are easily attached.

  In order to solve such problems, various fibers made of a saturated polyester represented by polyethylene terephthalate, which are excellent in properties such as tensile strength, heat resistance, and set retention, have been studied. Certainly, artificial hair fibers made of saturated polyester have excellent properties such as easy setability, set retention, combability, and light discoloration, but the surface of the yarn is not affected by polyester fibers produced by ordinary methods. Since it is flat and the refractive index of polyester itself is high, the surface gloss is strong, and the appropriate matteness and color close to human hair required for artificial hair have not been sufficiently obtained.

In order to improve such defects, various techniques for matting the surface of polyester fibers have been proposed. For example, a method has been proposed in which a number of scratches are formed on the surface of a polyester fiber to roughen the surface. However, the fiber obtained by this method has a problem that the fiber strength is reduced due to scratches formed on the fiber surface. As another method, Japanese Patent Application Laid-Open No. 63-127716 (Patent Document 1) discloses that a fiber made of polyester containing fine particles such as silicon oxide is treated with an alkaline aqueous solution, and specific fine irregularities are formed on the fiber surface. There has been proposed a method for forming the film. Certainly, according to this method, artificial hair having a certain level of matteness and color tone can be obtained, but satisfactory hair has not yet been obtained.
JP 63-12716 A

  The present invention has been made based on the above background, and an object thereof is to provide a novel fiber for artificial hair excellent in durability.

  As a result of intensive studies to achieve the above object, the inventors of the present invention can obtain a practical and excellent artificial hair fiber when a concave portion having a specific size is formed on the surface of the polyester fiber. Investigated.

Thus, according to the present invention, a fiber for artificial hair comprising a polyester fiber, wherein the polyester fiber contains an organic sulfonic acid compound as a micropore forming agent on the fiber surface, and is then subjected to an alkali weight loss treatment. It is obtained that the opening has a maximum length of 2.0 to 20 μm and has 12 to 30 recesses per 100 square μm , the cross-sectional shape is a glasses type, and the degree of necking is 2.5 to 8 A featured artificial hair fiber is provided.

The artificial hair fiber of the present invention has a concave portion of a specific size formed by adding an organic sulfonic acid compound as a micropore forming agent to the polyester fiber surface, and then subjected to an alkali weight loss treatment , and has a cross section. shape glasses type, the constricted degree Ri Contact closely resembles the feel human hair because it is 2.5 to 8, and has a durability level to withstand for real. Therefore, it is extremely useful as various artificial hair products to be worn on the hair part or the head for the purpose of supplementing hair such as wigs, hair wigs, extensions, hair bands, or the like.

  The polyester constituting the fiber for artificial hair of the present invention is a polyester having terephthalic acid as the main bifunctional carboxylic acid and ethylene glycol, 1,3-propanediol or 1,4-butanediol as the main glycol component, specifically For these, polyethylene terephthalate, polypropylene terephthalate or polybutylene terephthalate is preferable. These polyesters have a copolymer component of 15 mol% or less, preferably 10 mol% or less, particularly preferably 5 mol% or less, based on the total acid component, within a range not impairing the object of the present invention. It may be copolymerized. The copolymer components preferably used include 2,6-naphthalenedicarboxylic acid, 4,4′-dicarboxyphenoxymethane, isophthalic acid, phosphoric acid, phosphonic acid and other acid components, diethylene glycol, bisphenol-A ethylene oxide (EO) ) Diol components such as adducts can be exemplified. Among these, phosphorus compounds such as phosphoric acid and phosphonic acid are preferable from the viewpoint of flame retardancy. Further, as long as the amount is small, a trifunctional compound such as trimesic acid, trimellitic acid, boric acid, glycerin, trimethylolpropane and the like may be copolymerized.

  These polyesters include other thermoplastic synthetic resins for modification purposes, such as polyamides such as nylon 6 and nylon 6 and 6, polyolefins such as polyethylene and polypropylene, polytetrafluoroethylene, polyvinylidene fluoride, ethylene Fluorine-containing polymers such as tetrafluoroethylene copolymer may be mixed in the range of 0.5 to 50% by weight.

  Further, the above polyester may contain a known ultraviolet absorber for the purpose of preventing discoloration of the artificial hair being used. As an ultraviolet absorber preferably used, for example, 2,2-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6- (2H-benzotriazol-2-yl) phenol, 2- [ 2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole, 2- (5-methyl-2-hydroxyphenyl) benzotriazole, 2- [3,5-bis (2 , 2-Dimethylpropyl) -2-hydroxyphenyl] benzotriazole, 2- (3-tertiarybutyl-5-methyl-2-hydroxyphenyl) -5-chlorobenzotriazole, 2- (3,5-tertiarybutyl) Benzotriazol such as 2-hydroxyphenyl) -5-chlorobenzotriazole, 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole UV absorber, 2-hydroxy-4- (methacryloyloxyethoxy) benzophenone 30-50 mol% and methyl methacrylate 70-30 mol% random copolymer, 2,4-dihydroxybenzophenone, 2,2 ', 4 Benzophenone UV absorbers such as 4'-tetrahydroxybenzophenone, 2-hydroxy-4- (β-hydroxyethoxy) -benzophenone, bis (5-benzoyl-4-hydroxy-2-methoxyphenyl) methane, iron oxide fine particles, etc. Can be illustrated.

  Among them, bis (5-benzoyl-4-hydroxy-2-methoxyphenyl) methane, 2,2-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6- (2H-benzotriazole- When 2-yl) phenol, 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole, iron oxide fine particles, etc. are added to and mixed with molten polyester The heat resistance is favorable and high light resistance is obtained, which is preferable. In addition, a random copolymer of 2-hydroxy-4- (methacryloyloxyethoxy) benzophenone 30-50 mol% and methyl methacrylate 70-30 mol% has a high molecular weight, so there is little bleed out from the polyester fiber and stable light resistance. It is preferable because of its property. Two or more of these various ultraviolet absorbers may be used in combination.

  Moreover, in order to protect a human body from the danger by the fire in use, you may include well-known organic or inorganic flame retardants, such as phosphorus type | system | group, halogen type | system | group, and antimony trioxide, in polyester. Further, for the purpose of preventing fiber clinging and entanglement or adhesion of dust, the polyester itself may be modified, or an antistatic agent may be blended in the polyester.

Then, polyester fibers according to the present invention, the maximum length (longitudinal diameter) of the opening on the fiber surface a recess in the range of 2~20μm have 1 2-30 per yarn surface area 100 square μm Need to be. When the maximum length of the opening forming the recess is less than 2 μm, the matte effect is reduced. On the other hand, if it exceeds 30 μm, not only the roughness of the fiber surface can be seen with the naked eye, but also the physical properties of the yarn are lowered, which is not preferable. In particular, a concave portion in the range of 5 to 15 μm is preferable. Further, the number matting effect is reduced if the number of the concave portion is less than 1 2 per 100 square [mu] m, preferably for the dead hair tone and the too there is no gloss when exceeding 30 reversed Absent. Especially 1 2 to twenty preferably present.

Here, the maximum length of the opening and the number of existence per unit area are the average values measured from photographs obtained by taking 10 fields of view of the fiber surface at a magnification of 1000 using a scanning electron microscope. Even if the number of recesses present on the fiber surface is 1 2 to 30 per 100 square μm, good gloss cannot be obtained unless the maximum length of the opening is in the range of 2 to 20 μm. Even if the maximum length of the opening is in the range of 2 to 30 μm, if the number of recesses present on the fiber surface is not in the range of 12 to 30 per 100 square μm, the gloss is preferably as far away as human hair. Absent.

A method of forming a recess having such a shape on the polyester fiber surface, by caustic treatment of the fibers which contains a fine pore-forming agent in the port Riesuteru, a method of forming micropores in the fiber surface is preferred. The micropore forming agent is required to be organic sulfonic acid compounds, their average particle diameter, the addition amount, it is possible to control the shape of the recess by appropriately selecting the caustic treatment conditions. Especially, when a micropore formation agent is a compound containing a metal, since the recessed part of a favorable shape can be formed by an alkali weight reduction process, it is especially preferable.

Incidentally, the fiber cross sectional shape of the fiber for artificial hair of the present invention, it is necessary in terms of combability and gloss neck of a main Gane-shaped cross section is 2.5 to 8. Here, the degree of necking is a value represented by the length of the thickest part / the length of the narrowest part in the glasses-type cross-sectional shape. In use, a plurality of cross-sectional fibers can be used in appropriate combination.

  Next, it is desirable that the single fiber fineness of the fiber for artificial hair of the present invention is in the range of 20 to 110 dtex, preferably 30 to 90 dtex from the viewpoint of expressing a natural effect. Further, the single fiber fineness is not one type, and it is also possible to mix several types of fibers such as a mixture of two single fiber finenesses of 30 dtex and 70 dtex.

  The polyester fiber according to the present invention may not be colored, but is dyed as necessary. Although a disperse dye may be used as the dye, it is preferable to use a dye having a light fastness of 5 or higher from the viewpoint of discoloration of the artificial hair being used. As a dyeing method, a known dyeing carrier agent may be used in combination, but a high-pressure dyeing method that does not require a dyeing carrier agent is more preferable. In addition, various pigments such as carbon black may be added to the polyester fiber before dyeing. In this case, not only can the dye at the time of dyeing be saved, but it is preferable because it is not necessary to dye depending on the use. .

  Since the fiber for artificial hair of the present invention described above is a polyester fiber having a specific number of recesses of a specific size on the fiber surface, it is possible to easily obtain artificial hair very similar to human hair. became.

  Hereinafter, the present invention will be described more specifically with reference to examples.

[Example 1]
Sodium benzenesulfonate-3,5-di (carboxylic acid Mg _1/2 ) A polyethylene terephthalate chip with an intrinsic viscosity of 0.64 (measured at 25 ° C. in a mixed solvent of phenol and tetrachloroethane 1: 1) dispersed in a weight of 5% (0.34 mol% with respect to the terephthalic acid component) under a vacuum of 160 Dry at 8 ° C. for 8 hours.

  The chip was melted and discharged from a spinneret having 30 holes of spinning holes at 290 ° C. using an extruder-type kneader, a metering gear pump, and a spinning machine having a filtration layer made of 50 mesh glass beads and a 150 mesh wire mesh, After being cooled with 40 ° C. hot water at a position 5 cm below the spinneret, a wound spinning yarn was obtained. Next, the film was stretched 4.0 times in warm water at 70 ° C., further subjected to tension heat treatment at 150 ° C., and then wound as a stretched yarn of 3000 dtex / 30 fil.

  N treatment (treatment at 98 ° C. for 30 minutes in a 50 g / liter aqueous solution of NaOH) was added to the obtained drawn yarn to obtain a polyester fiber having a weight loss rate of 10% by weight. On the surface of the obtained polyester fiber, there were 12 recesses having a maximum length of 2 μm or more and 20 μm or less per 100 square μm of fiber surface area. The fiber strength was 3.36 cN / dtex, and the single fiber fineness was 58 dtex.

This fiber was dyed using a high-pressure Smith dyeing machine with a dyeing solution shown below at a bath ratio of 20: 1 at 130 ° C. for 60 minutes, and then hydrosulfite 1.5 g / liter, caustic soda 1 g. Reductive washing was performed at 80 ° C. for 20 minutes in a bath ratio of 20: 1 in an aqueous solution containing 1 g / liter of amylazine / liter. The resulting artificial hair was planted on a net with 20,000 hairs to form a wig.
The above wig was excellent in gloss, combing and the like. Also, no change was seen after wearing this wig for 6 months.
(Staining solution)
Sumikasen Brown 2.5% owf
Miketon Polyster Black 0.3% owf
Dianix Fast Yellow 1.5% owf
Dianix Fast Dark Green 1.0% owf

[Example 2]
An artificial hair fiber was obtained in the same manner as in Example 1 except that the N treatment time was 50 minutes. On the surface of the obtained polyester fiber, 22 recesses having a maximum opening length of 2 μm or more and 20 μm or less existed per 100 square μm of fiber surface area. The resulting artificial hair was planted on a net with 20,000 hairs to form a wig.
The above wig was excellent in gloss, combing and the like. Also, no change was seen after wearing this wig for 6 months.

[Comparative Example 1]
A fiber for artificial hair was obtained in the same manner as in Example 1 except that the polyethylene terephthalate chip did not contain sodium benzenesulfonate-3,5-di (carboxylate Mg _1/2 ). The fiber surface was flat and no recess was observed. The resulting artificial hair was implanted into a net with 20,000 hairs to make a wig, but it had a plastic-like luster, and the wig was not practically usable.

[Comparative Example 2]
Artificial hair was obtained in the same manner as in Example 1 except that the N treatment time was 120 minutes. On the surface of the obtained polyester fiber, 50 concave portions having a maximum opening length of 2 μm or more and 20 μm or less were present per 100 square μm of fiber surface area. The resulting artificial hair was planted on a net with 20,000 hairs to form a wig.
The above-mentioned wig had a lustrous white-brown tone of a cat, and the wig was unusable for practical use.

  The fiber for artificial hair of the present invention can be used very suitably for various artificial hair-related products to be attached to the hair part or head such as wigs, hair wigs, extensions and hair bands.

Claims (2)

A fiber for artificial hair made of a polyester fiber, the polyester fiber containing an organic sulfonic acid compound as a micropore forming agent on the fiber surface, and then obtained by subjecting to an alkali weight loss treatment, the maximum opening length. A fiber for artificial hair, characterized in that it has 12 to 30 recesses per 100 square μm with a length of 2.0 to 20 μm, has a cross-sectional shape of glasses, and has a necking degree of 2.5 to 8 . The fiber for artificial hair according to claim 1, wherein the single fiber fineness of the polyester fiber is 20 to 110 dtex .