JP5092437B2 - Floor construction method and floor - Google Patents
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- JP5092437B2 JP5092437B2 JP2007031838A JP2007031838A JP5092437B2 JP 5092437 B2 JP5092437 B2 JP 5092437B2 JP 2007031838 A JP2007031838 A JP 2007031838A JP 2007031838 A JP2007031838 A JP 2007031838A JP 5092437 B2 JP5092437 B2 JP 5092437B2
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本発明は、戸建て住宅やマンション、アパート、保養所、オフィスビル、店舗等の建築物における室内床面に使用するための床材の施工方法、および、その施工方法により施工される床面に関する。 The present invention relates to a flooring construction method for use on an indoor floor surface in a building such as a detached house, a condominium, an apartment, a recreational facility, an office building, or a store, and a floor surface constructed by the construction method.
現在、戸建て住宅等の建築物における室内床面用の床材としては、木質系フローリング材が最も広く流行している。この木質系フローリング材とは、厚み5mm〜15mm程度の天然木材の無垢板や、厚み5mm〜15mm程度の積層合板等の木質基材上に厚み数百μm〜数mm程度の天然木材の突板を貼着したもの、あるいはそれらの塗装品等である。 At present, wood flooring materials are most prevalent as floor materials for indoor floors in buildings such as detached houses. This wood flooring material is a natural wood veneer with a thickness of about 5 mm to 15 mm or a natural wood veneer with a thickness of about several hundred μm to several mm on a wooden substrate such as a laminated plywood with a thickness of about 5 mm to 15 mm. They are pasted or painted products.
これらの天然木材を使用した木質系フローリング材は、その表面の意匠が天然木材の木目という、最も自然で親しみやすく美麗な意匠であることから、従来広く消費者に受け容れられている。 These wooden flooring materials using natural wood have been widely accepted by consumers since the design of the surface is the most natural, familiar and beautiful design of natural wood.
しかし、日光に当たると変色し易いことや、水に濡れると膨れや割れ、反り、腐食、突板の剥離等を起こし易く、特に浴室脱衣所や洗面所、厨房等の様な水廻りの部位への使用には問題があること、天然素材なので色調や木目形状などの品質や価格、供給量などが不安定であることなどの問題点も指摘されている。 However, it can easily discolor when exposed to sunlight, and can easily swell, crack, warp, corrode, peel off the veneer, etc. when it gets wet with water. It has been pointed out that there are problems in use, and that the quality, price, and supply amount of color tone and grain shape are unstable because it is a natural material.
特に近年では、地球環境保護問題への社会的関心が高まるにつれて、環境破壊に繋がる天然木材の大量消費は白眼視されるようになり、床材などの建築材料の分野においても、資源のリサイクル利用への取り組みが求められる様になっている。 In recent years, in particular, as social interest in the global environmental protection issue has increased, mass consumption of natural wood that leads to environmental destruction has become more common, and in the field of building materials such as flooring, the use of recycled resources The approach to has come to be required.
しかし、木質系フローリング材を再度床材としてリサイクル利用することは、技術的にも経済的にも極めて困難であり、せいぜい粉砕してパーティクルボード用原料としてリサイクル利用される程度に留まっているが、これも近年の急激な供給増に見合った用途開発が進まないために過剰在庫を抱え、リサイクル利用は行き詰まりの状況にあり、大半は埋め立てや焼却による最終処分が行われているのが現状である。 However, it is extremely difficult to recycle the wood flooring material as a flooring material, both technically and economically, and at most it is only crushed and recycled as a raw material for particleboard. This is also due to the lack of progress in application development in response to the rapid increase in supply in recent years, so there is an excess inventory, and recycling is in a deadlock situation. Most of the final disposal is done by landfill or incineration. .
そこで、床材を使用後に再度、同種の床材の原料として再利用可能な、リサイクル適性のある床材の開発が、社会的に強く要望されるようになっている。こうした要望に応えるものとして、本発明者等は既に、熱可塑性樹脂と木質系フィラーを含有する木質樹脂成形体の表面に、該木質樹脂成形体に含有される熱可塑性樹脂と同系の熱可塑性樹脂を主体とする化粧シートを積層してなる床材を提案した(特許文献1参照)。 Therefore, there is a strong social demand for the development of a recyclable flooring that can be reused as a raw material for the same kind of flooring after use. In order to meet these demands, the present inventors have already made a thermoplastic resin similar to the thermoplastic resin contained in the wooden resin molded body on the surface of the wooden resin molded body containing the thermoplastic resin and the wooden filler. A flooring made by laminating a decorative sheet mainly composed of a sheet was proposed (see Patent Document 1).
この床材は、熱可塑性樹脂を主成分とするので耐水性や耐候性に優れ、物性的にも意匠的にも品質の安定した製品を安価に大量供給可能であり、切削や釘打ち等の加工性も木質系フローリング材と同等であり、しかも、使用後はそのまま粉砕して前記木質樹脂成形体の成形材料として再利用できるという、優れたリサイクル適性を備えたものである。 Since this flooring is mainly composed of thermoplastic resin, it has excellent water resistance and weather resistance, and it can supply a large quantity of products with stable quality in terms of physical properties and design, such as cutting and nailing. The processability is equivalent to that of the wood-based flooring material, and it has excellent recyclability such that it can be pulverized as it is after use and reused as a molding material for the wood resin molding.
また、本発明者等はさらに、水系又は溶剤系接着剤による接着性や、天然木材に似た暖かい触感を与える断熱性、快い歩行感を与える弾力性等の改善を目的として、前記木質樹脂成形体を発泡させてなる木質樹脂発泡成形体を基材として使用した床材をも、既に提案した(特許文献2参照)。 In addition, the present inventors have further said wood resin molding for the purpose of improving adhesiveness with water-based or solvent-based adhesives, heat insulation that gives a warm touch similar to natural wood, elasticity that gives a pleasant walking feeling, etc. A floor material using a wood resin foam molded body obtained by foaming the body as a base material has also been proposed (see Patent Document 2).
しかしながら、その後の試作検討の結果、前記した木質樹脂発泡成形体を使用した樹脂系床材について、改善の必要性があることが判明した。
本発明者等が既に提案してきた木質系樹脂の成形体において、いわゆる板形状の発泡成形体を連続的に押出し、引取方向に対して垂直にカットし基材を生産する。通常、床材の線膨張係数は配合する木質系フィラー充填量、生産条件などにより決まり、連続生産している床材に関して均一な線膨張係数を示す。
However, as a result of the subsequent trial production, it has been found that there is a need for improvement in the resin-based flooring using the above-described wood resin foam molded article.
In the wood-based resin molded body that the present inventors have already proposed, a so-called plate-shaped foam molded body is continuously extruded and cut perpendicularly to the take-off direction to produce a base material. Usually, the linear expansion coefficient of the flooring material is determined by the amount of the wood filler to be blended, the production conditions, etc., and shows a uniform linear expansion coefficient for the flooring material produced continuously.
本発明における樹脂系床材は熱可塑性樹脂を用いた床材であるため、環境温度変化に対する熱変形が生じるが、このように線膨張係数が均一な樹脂系床材を実際に施工した際に、樹脂系床材の変形も均一に起こり、床面全体としても均一な変形を起こすため、例えば壁際や柱等の障害物により、変形による応力集中が発生し、これにともない突き上げ現象を起こす可能性がある。
本発明は、従来の技術における、前記のような問題点を解決するためになされたものであり、その課題とするところは、木質感やリサイクル適性に優れた木質樹脂発泡成形体を基材とした床材において、環境温度変化に起因する突き上げ現象を抑えるための樹脂系床材の施工方法、および、その施工方法により施工される床面を提供することである。 The present invention has been made in order to solve the above-described problems in the prior art, and the problem is that the base material is a wood resin foam molded article excellent in wood texture and recyclability. It is providing the floor surface constructed by the construction method of the resin-type floor material for suppressing the pushing-up phenomenon resulting from environmental temperature change, and the construction method.
請求項1に記載の発明は、少なくとも、熱可塑性樹脂および木質系フィラーを含む木質樹脂組成物を発泡成形してなる木質樹脂発泡成形体、並びに、化粧シートを積層してなる樹脂系床材の施工方法において、該樹脂系床材の長手方向の一部および該樹脂系床材の巾方向の全部が、該樹脂系床材とは長手方向および巾方向の線膨張係数が0.2×10−5以上5.0×10−5(1/℃)以下の範囲で異なる異種の樹脂系床材と接するように配列させることを特徴とする樹脂系床材の施工方法である。 The invention according to claim 1 is a resin-based flooring formed by laminating a woody resin foam molded body formed by foaming a woody resin composition containing at least a thermoplastic resin and a woody filler, and a decorative sheet. In the construction method, a part of the resin floor material in the longitudinal direction and the entire width direction of the resin floor material have a linear expansion coefficient of 0.2 × 10 in the longitudinal direction and the width direction of the resin floor material. -5 to 5.0 × 10 -5 (1 / ℃ ) is a construction method of a resin-based flooring, characterized in that to arrange so as to be in contact with different heterogeneous resin flooring in the following range.
請求項2に記載の発明は、前記異種の樹脂系床材が、前記樹脂系床材の木質系フィラー配合量と同量の木質系フィラーを含有することを特徴とする請求項1に記載の樹脂系床材の施工方法である。 The invention according to claim 2 is characterized in that the dissimilar resin flooring contains the same amount of wood filler as the wood filler content of the resin flooring. This is a construction method for resin-based flooring.
請求項3に記載の発明は、請求項1および2のいずれかに記載の樹脂系床材の施工方法により施工されることを特徴とする床面である。 Invention of Claim 3 is constructed | assembled by the construction method of the resin-type flooring in any one of Claim 1 and 2, It is a floor surface characterized by the above-mentioned.
請求項1に記載の発明は、少なくとも、熱可塑性樹脂および木質系フィラーを含む木質樹脂組成物を発泡成形してなる木質樹脂発泡成形体、並びに、化粧シートを積層してなる樹脂系床材の施工方法において、該樹脂系床材の長手方向の一部および該樹脂系床材の巾方向の全部が、該樹脂系床材とは長手方向および巾方向の線膨張係数が0.2×10−5以上5.0×10−5(1/℃)以下の範囲で異なる異種の樹脂系床材と接するように配列させることを特徴とする樹脂系床材の施工方法である。長手方向および巾方向の線膨張係数が異なる樹脂系床材同士を、該樹脂系床材の長手方向の一部および該樹脂系床材の巾方向の全部が接するように配列させる施工方法により、環境温度変化にともなう床面全体の変形による応力集中を緩和することが可能となり、突き上げ現象を防ぐことが可能となる。 The invention according to claim 1 is a resin-based flooring formed by laminating a woody resin foam molded body formed by foaming a woody resin composition containing at least a thermoplastic resin and a woody filler, and a decorative sheet. In the construction method, a part of the resin floor material in the longitudinal direction and the entire width direction of the resin floor material have a linear expansion coefficient of 0.2 × 10 in the longitudinal direction and the width direction of the resin floor material. -5 to 5.0 × 10 -5 (1 / ℃ ) is a construction method of a resin-based flooring, characterized in that to arrange so as to be in contact with different heterogeneous resin flooring in the following range. By a construction method in which resin-based flooring materials having different linear expansion coefficients in the longitudinal direction and the width direction are arranged so that a part of the resin-based flooring material in the longitudinal direction and the entire width direction of the resin-based flooring material are in contact with each other. It is possible to alleviate stress concentration due to deformation of the entire floor surface due to environmental temperature change, and to prevent the push-up phenomenon.
請求項2に記載の発明は、前記異種の樹脂系床材が、前記樹脂系床材の木質系フィラー配合量と同量の木質系フィラーを含有することを特徴とする請求項1に記載の樹脂系床材の施工方法である。木質系フィラーの配合量は、線膨張係数だけでなく、樹脂系床材の表面硬度や、耐へこみ性などの基礎物性にも強い相関がある。木質系フィラーの配合量が同量である樹脂系床材を用いて施工することにより、基礎物性の統一された床面を得ることが可能となる。 The invention according to claim 2 is characterized in that the dissimilar resin flooring contains the same amount of wood filler as the wood filler content of the resin flooring. This is a construction method for resin-based flooring. The compounding amount of the wood filler has a strong correlation with not only the linear expansion coefficient but also the basic physical properties such as the surface hardness of the resin floor material and the dent resistance. It is possible to obtain a floor surface with unified basic physical properties by using a resin-based flooring with the same amount of wood-based filler.
請求項3に記載の発明は、請求項1および2のいずれかに記載の樹脂系床材の施工方法により施工されることを特徴とする床面である。請求項1および2のいずれかに記載の樹脂系床材の施工方法により施工されることにより、突き上げ現象が生じず、表面硬度や、耐へこみ性などの基礎物性が統一された床面を得ることが可能となる。 Invention of Claim 3 is constructed | assembled by the construction method of the resin-type flooring in any one of Claim 1 and 2, It is a floor surface characterized by the above-mentioned. By being constructed by the construction method for a resin-based flooring according to any one of claims 1 and 2, a floor surface in which basic properties such as surface hardness and dent resistance are unified is obtained without causing a push-up phenomenon. It becomes possible.
本発明の樹脂系床材の施工方法について、図1を参照して説明する。 The construction method of the resin-type flooring of this invention is demonstrated with reference to FIG.
図1は、本発明による樹脂系床材の施工例の一実施例を示す。樹脂系床材1〜4は、木質系フィラーの配合量は同一であるが、長手方向および巾方向の線膨張係数が異なる樹脂系床材である。具体的な線膨張係数の差としては,線膨張係数が0.2×10−5〜5.0×10−5(1/℃)の範囲で異なる事が必要である。本発明における樹脂系床材では,木質系フィラーを添加していることで,床材としての線膨張係数を,熱可塑性樹脂単体に比べ小さくしているが,木質系フィラーが長手方向(引取り方向)配向する関係から,巾方向の線膨張係数は,長手方向の線膨張係数に比較して大きい。配向を抑える事により,巾方向の線膨張を小さくすることが可能であるが,それにともない長手方向の線膨張係数は大きくなる。このように巾方向と長手方向の線膨張係数には相関性があることから,同一量の木質系フィラーを添加した場合には,巾方向の線膨張係数が異なれば,長手方向の線膨張係数も異なることとなる。本発明において,巾方向の線膨張係数が0.2×10−5(1/℃)未満の範囲で線膨張係数が異なっていても,突き上げ防止の効果を得ることができず,また,5.0×10―5(1/℃)を超えて線膨張係数を変動させることは,木質系フィラーの配合量を同一の条件では製造が困難である。本発明の樹脂系床材の施工方法は、長手方向および巾方向の線膨張係数が異なる樹脂系床材同士を、該樹脂系床材の長手方向の一部および/または全部、および/または、該樹脂系床材の巾方向の一部および/または全部が接するように配列させることを特徴とする。例えば、図1に示すように、樹脂系床材1〜4から適宜選ばれる異なる樹脂系床材同士の巾方向の全部が接し、かつ、長手方向の一部が接するように配列する施工方法である。このように配列することにより、施工した床全体としての線膨張係数(熱による変形量)に分布をもたせることで、線膨張係数が均一な場合と比較して、環境温度の変化にともなう樹脂系床材の変形による応力集中が軽減され、樹脂系床材の突き上げ現象を改善することが可能となる。 FIG. 1 shows an embodiment of a resin flooring construction example according to the present invention. The resin-based flooring materials 1 to 4 are resin-based flooring materials having the same blending amount of the wooden filler, but having different linear expansion coefficients in the longitudinal direction and the width direction. As a specific difference in linear expansion coefficient, it is necessary that the linear expansion coefficient be different in the range of 0.2 × 10 −5 to 5.0 × 10 −5 (1 / ° C.). In the resin-based flooring of the present invention, the addition of the wood-based filler reduces the linear expansion coefficient of the flooring material compared to the thermoplastic resin alone, but the wood-based filler is in the longitudinal direction (take-off). From the relationship of orientation, the linear expansion coefficient in the width direction is larger than the linear expansion coefficient in the longitudinal direction. Although the linear expansion in the width direction can be reduced by suppressing the orientation, the linear expansion coefficient in the longitudinal direction increases accordingly. Thus, since the linear expansion coefficient in the width direction and the longitudinal direction have a correlation, when the same amount of wood filler is added, if the linear expansion coefficient in the width direction is different, the linear expansion coefficient in the longitudinal direction is different. Will also be different. In the present invention, even if the linear expansion coefficient is different within the range where the linear expansion coefficient in the width direction is less than 0.2 × 10 −5 (1 / ° C.), the effect of preventing push-up cannot be obtained. It is difficult to produce a linear expansion coefficient exceeding 0.0 × 10 −5 (1 / ° C.) under the same condition of the wood filler. The construction method of the resin-based flooring of the present invention is a method in which resin-based flooring having different linear expansion coefficients in the longitudinal direction and the width direction is partly and / or entirely in the longitudinal direction of the resin-based flooring, and / or The resin-based flooring is arranged so that part and / or all of the width direction of the resin-based flooring is in contact. For example, as shown in FIG. 1, a construction method in which all of the width directions of different resin-based floor materials appropriately selected from resin-based floor materials 1 to 4 are in contact with each other and a part in the longitudinal direction is in contact with each other. is there. By arranging in this way, the distribution of the coefficient of linear expansion (the amount of deformation due to heat) of the entire floor that has been constructed, compared with the case where the coefficient of linear expansion is uniform, the resin system with changes in environmental temperature Stress concentration due to deformation of the flooring material is reduced, and it becomes possible to improve the push-up phenomenon of the resin-based flooring material.
また、本発明では木質樹脂発泡成形体に化粧シートを積層させた樹脂系床材を用いるため、図2に示すように、線膨張係数の異なる樹脂系床材1〜4を前述のように配列させた際にも、施工された床面に関しては見栄えの差はなく、意匠性に優れた床面を提供することができる。また、後述するように、同一金型を用いて木質樹脂発泡成形体の成形を行うことで、線膨張係数は異なっていても同一の寸法にて木質樹脂発泡成形体を成形することが可能であり、また、木質系フィラーの配合量を同一にしていることから、床面内における基礎物性のばらつきも生じない。 Further, in the present invention, since the resin floor material in which the decorative sheet is laminated on the wood resin foam molded article is used, as shown in FIG. 2, the resin floor materials 1 to 4 having different linear expansion coefficients are arranged as described above. Even when it is made, there is no difference in appearance with respect to the constructed floor surface, and a floor surface excellent in design can be provided. In addition, as will be described later, by molding a wood resin foam molded body using the same mold, it is possible to mold a wood resin foam molded body with the same dimensions even if the linear expansion coefficients are different. In addition, since the blending amount of the wood filler is the same, there is no variation in basic physical properties in the floor surface.
線膨張係数の異なる樹脂系床材1〜4の成形方法に関して、木質系フィラーの配合量による線膨張係数の調整は、木質系フィラーの配合量が樹脂系床材の表面高度や耐へこみ性などの基礎物性にも強い相関があるため好ましくなく、また、成形条件、例えば引取りスピードの変更による調整は、発泡適性や生産の安定性などの点より好ましくない。これらの点をふまえ、本発明に用いる線膨張係数の異なる樹脂系床材の製造方法としては、以下の手法が有効であるが、その手法に限定されるものではない。 Regarding the molding method of resin-based flooring materials 1 to 4 having different linear expansion coefficients, the adjustment of the linear expansion coefficient by the amount of wood-based filler is such that the amount of wood-based filler is the surface height of the resin-based flooring, dent resistance, etc. There is also a strong correlation with the basic physical properties, and it is not preferable to adjust the molding conditions, for example, by changing the take-up speed, from the viewpoint of foamability and production stability. Based on these points, the following method is effective as a method for producing a resin-based flooring material having a different coefficient of linear expansion used in the present invention, but is not limited to that method.
樹脂系床材の製造方法としては,木質樹脂組成物を押出機により発泡成形することで断面が矩形の第1の発泡成形体を押し出し,第1の発泡成形体を,入口の巾方向の寸法よりも出口の巾方向の寸法を大きくしたサイジングに供給することにより形状および寸法を整形しながら冷却して断面が矩形の第2の発泡成形体を得,第2の発泡成形体を引き取り機で引き取ることにより木質樹脂組成物からなる木質樹脂発泡成形体を得るものである。
図3は本実施の形態の床材の製造方法で用いるサイジング10の概略図である。サイジング10の入口12の巾方向の寸法L1に対して,サイジング10の出口14の巾方向の寸法L2を大きくしている。また,サイジング10の入口12と出口14との樹脂量を合わせるために,巾方向の寸法の増加にともない厚み方向の寸法は減少する設計である。具体的には,サイジング10の入口12の厚み方向の寸法をD1,サイジング10の出口14の厚み方向の寸法をD2とすると,L1×D1=L2×D2としている。
図3に示すように,入口12の巾方向の寸法L1から出口14の巾方向の寸法L2まで連続的に変化する設計とすることで,サイジング10内での樹脂流動は引取方向に加えて,巾方向にも流動することになる。このことにより,引取方向への木質系フィラーの配向を制御することが可能となり,成形性や床物性を落とすことなく、木質樹脂発泡成形体の長手方向および巾方向の線膨張係数を調整することができる。
As a method for producing a resin floor material, a wood resin composition is foam-molded by an extruder to extrude a first foam-molded body having a rectangular cross section, and the first foam-molded body is dimensioned in the width direction of the inlet. The second foam molded body having a rectangular cross section is obtained by cooling while shaping the shape and dimensions by supplying to a sizing having a larger dimension in the width direction of the outlet than the second foam molded body with a take-up machine. A wood resin foam molded article made of the wood resin composition is obtained by pulling.
FIG. 3 is a schematic view of the sizing 10 used in the flooring manufacturing method of the present embodiment. The dimension L2 in the width direction of the outlet 14 of the sizing 10 is made larger than the dimension L1 in the width direction of the inlet 12 of the sizing 10. Further, in order to match the amount of resin at the inlet 12 and the outlet 14 of the sizing 10, the dimension in the thickness direction is designed to decrease as the dimension in the width direction increases. Specifically, when the dimension in the thickness direction of the inlet 12 of the sizing 10 is D1, and the dimension in the thickness direction of the outlet 14 of the sizing 10 is D2, L1 × D1 = L2 × D2.
As shown in FIG. 3, the resin flow in the sizing 10 is not only in the take-up direction by continuously changing from the dimension L1 in the width direction of the inlet 12 to the dimension L2 in the width direction of the outlet 14. It will also flow in the width direction. This makes it possible to control the orientation of the wood filler in the take-off direction, and to adjust the linear expansion coefficient in the longitudinal direction and width direction of the wood resin foam molded product without degrading the moldability and floor physical properties. Can do.
図5は樹脂系床材の一実施例の断面の構造を示す図である。図5に示すように,床材5は,熱可塑性樹脂4と,木質系フィラー3との混合物を,発泡内部に気泡2が存在させつつ成形してなる,木質樹脂発泡成形層に,前記熱可塑性樹脂と同系の熱可塑性樹脂からなる化粧シート1が積層されてなるものである。 FIG. 5 is a diagram showing a cross-sectional structure of an embodiment of a resin flooring. As shown in FIG. 5, the flooring 5 is formed on the wood resin foam molding layer formed by molding a mixture of a thermoplastic resin 4 and a wood filler 3 while bubbles 2 are present inside the foam. A decorative sheet 1 made of a thermoplastic resin similar to the plastic resin is laminated.
本発明における熱可塑性樹脂4としては,ポリオレフィン系の例えばポリエチレン,ポリプロピレン,ポリブテン,ポリイソプレン,エチレン−プロピレン共重合体,エチレン−酢酸ビニル共重合体,エチレン−α−オレフィン共重合体,プロピレン−α−オレフィン共重合体,エチレン−エチルアクリレート共重合体や,これらを接着性の向上の目的で酸変性したもの,あるいはアイオノマー等から適宜選択が可能で,単一でも複数種の混合でも構わない。 Examples of the thermoplastic resin 4 in the present invention include polyolefins such as polyethylene, polypropylene, polybutene, polyisoprene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, ethylene-α-olefin copolymer, propylene-α. An olefin copolymer, an ethylene-ethyl acrylate copolymer, an acid-modified one of these for the purpose of improving adhesiveness, an ionomer or the like can be selected as appropriate, and a single type or a mixture of plural types may be used.
中でも,樹脂系床材5として要求される剛性や表面硬度,寸法安定性などの面で,ホモポリプロピレン,ランダムポリプロピレン,ブロックポリプロピレン,プロピレン−α−オレフィン共重合体などのポリプロピレン系樹脂が最も適している。 Among them, polypropylene resins such as homopolypropylene, random polypropylene, block polypropylene, and propylene-α-olefin copolymer are most suitable in terms of rigidity, surface hardness, dimensional stability, etc. required for the resin-based flooring 5. Yes.
しかし,ポリプロピレンは熱膨張や熱収縮という温度に対しての寸法変化,いわゆる線膨張係数が大きい材料である。我々の提案する樹脂系床材5は,熱可塑性樹脂と木質系フィラーを複合しているため,熱可塑性樹脂単体と比較すれば,線膨張係数は小さくなっている。しかし,樹脂系床材5を施工した時の温度に比べ,室温が著しく高くなった場合には木質樹脂発泡成形体の熱膨張による応力は巾方向および引取方向に蓄積され,施工面積が広くなった場合に,これらの応力が一部分に集中する事により突き上げが発生する可能性がある。また,前述のように,木質系フィラーを充填した場合には引取方向に木質系フィラーが配向する事により,基材巾方向の線膨張係数が大きい傾向がある。 However, polypropylene is a material having a large dimensional change with respect to temperature such as thermal expansion and contraction, that is, a so-called linear expansion coefficient. Since the resin-based flooring 5 proposed by the present invention is a composite of a thermoplastic resin and a wooden filler, the coefficient of linear expansion is smaller than that of a thermoplastic resin alone. However, when the room temperature is significantly higher than the temperature when the resin-based flooring 5 is constructed, the stress due to thermal expansion of the wooden resin foam molded body is accumulated in the width direction and the take-up direction, and the construction area is increased. In such a case, there is a possibility that the thrust may occur due to the concentration of these stresses in a part. Further, as described above, when the wood filler is filled, the linear expansion coefficient in the substrate width direction tends to be large due to the orientation of the wood filler in the take-up direction.
本発明の施工方法に用いる樹脂系床材の製造方法において,熱可塑性樹脂が冷却固化されるサイジング10内に巾方向のテーバーを設けている事が重要である。例えば,押出機ダイにこのような巾方向のテーパーを組み込んだとしても,溶融状態とサイジング10内での樹脂の粘度を考えると,引取方向への木質系フィラーの配向を抑える効果は得ることはできない。 In the method for producing a resin floor material used in the construction method of the present invention, it is important to provide a widthwise taber in the sizing 10 in which the thermoplastic resin is cooled and solidified. For example, even if such a taper in the width direction is incorporated in the extruder die, considering the molten state and the viscosity of the resin in the sizing 10, the effect of suppressing the orientation of the wood filler in the take-up direction is obtained. Can not.
サイジング10の入口12の巾方向の寸法L1と,出口14の巾方向の寸法L2の比は,L2がL1の2倍以上が望ましく,木質系フィラーの配向制御の効果をより得るためには3倍以上が望ましい。2倍以下では,サイジング10内の巾方向への樹脂流動が小さく,結果として成形した床材5の長手方向の線膨張係数と,巾方向の線膨張係数を制御することが困難となる。 The ratio of the dimension L1 in the width direction of the inlet 12 of the sizing 10 and the dimension L2 in the width direction of the outlet 14 is preferably 2 or more than L1, and 3 to obtain the effect of controlling the orientation of the wood filler. More than double is desirable. If it is twice or less, the resin flow in the width direction in the sizing 10 is small, and as a result, it becomes difficult to control the linear expansion coefficient in the longitudinal direction and the linear expansion coefficient in the width direction of the molded flooring 5.
また,入口12の巾方向の寸法L1と,出口14の巾方向の寸法L2の比に関して,L2はL1の10倍以下が望ましく,5倍以下であることがより望ましい。L2とL1の比が大きくなると,前述のようにD2とD1の比も大きくなるため,サイジング10の入口12と出口14でこれらアスペクト比L:Dが急激に変化することになる。この急激な形状変化により,サイジング10の寸法を大きくせざるを得ない,基材成形の安定性が悪くなるなどのデメリットから,前述の範囲内であることが望ましい。 Further, regarding the ratio between the width direction dimension L1 of the inlet 12 and the width direction dimension L2 of the outlet 14, L2 is desirably 10 times or less of L1, and more desirably 5 times or less. As the ratio of L2 and L1 increases, the ratio of D2 and D1 also increases as described above, so that the aspect ratio L: D changes abruptly at the inlet 12 and outlet 14 of the sizing 10. Due to such a sudden change in shape, the size of the sizing 10 must be increased, and the stability of the base material molding is deteriorated.
従来の木質系樹脂発泡成形体において,いわゆる床形状の発泡成形体を連続的に押出し,引取方向に対して垂直にカットし基材を生産する。例えば異形押出の場合には,溶融した樹脂をサイジングにおいて冷却し,これを引取機で所望のスピードにて引き取るというプロセスをとることになる。木質系樹脂発泡成形体においては,木質系フィラーを充填することにより,基材の線膨張係数を改善しているが,木質系フィラーがアスペクト比の高い,いわゆる繊維状の構造をしていることにより,長手方向に木質系フィラーが配向する傾向がある。この木質系フィラーの配向に起因し,生産した床基材においては長手方向の線膨張係数と比較し,巾方向の熱寸法安定性は大きい(悪い)という不均一性が生まれる。 In a conventional wood-based resin foam molding, a so-called floor-shaped foam molding is continuously extruded and cut perpendicularly to the take-off direction to produce a base material. For example, in the case of profile extrusion, the molten resin is cooled in sizing, and this is taken out at a desired speed by a take-up machine. In the wood-based resin foam molding, the linear expansion coefficient of the base material is improved by filling the wood-based filler, but the wood-based filler has a so-called fibrous structure with a high aspect ratio. Therefore, the wood filler tends to be oriented in the longitudinal direction. Due to this orientation of the wood filler, the produced floor base material has a non-uniformity that the thermal dimensional stability in the width direction is large (bad) compared to the linear expansion coefficient in the longitudinal direction.
樹脂系床材の製造方法においては,冷却サイジングの入口巾寸法L1に対し,サイジング出口巾寸法L2を広く設計したサイジングを用いることが特徴であり,このような設計とすることで,サイジング内での樹脂の流動方向が引取方向に支配的な流動から,巾方向にも流動するように変化し,結果として木質系フィラーの引取方向への配向度を制御することができる。 The manufacturing method of resin-based flooring is characterized by the use of sizing that is designed with a wide sizing outlet width dimension L2 with respect to the inlet width dimension L1 of cooling sizing. The flow direction of the resin changes from the flow dominant in the take-up direction to the width direction, and as a result, the degree of orientation of the wood filler in the take-up direction can be controlled.
また、成形に用いるサイジングにおいて,サイジング出口巾寸法L2がサイジング入口寸法L1の2倍以上,10倍以下であることを特徴とし,この範囲内でサイジングを設計することにより,木質系フィラーの引取方向への配向度のコントロールを達成でき,かつ,成形に関しての不具合を併発することがない。 In the sizing used for molding, the sizing outlet width dimension L2 is not less than 2 times and not more than 10 times the sizing inlet dimension L1, and by taking the sizing within this range, the direction of taking the wood filler The degree of orientation can be controlled, and there are no problems with molding.
図4(A)は本実施の形態の樹脂系発泡成形体の製造方法で用いるサイジング10の構成を示す説明図,(B)は(A)のa断面図,(C)は(A)のb断面図である。一般的なサイジングでは,サイジング内に冷却水などを配管し,サイジング全体を均一に冷却するが,本実施の形態におけるサイジング10では,サイジング10の冷却部26がサイジング10の入口12側から出口14側にむけて,巾方向に連続的に増加する設計となっている。このような設計とすることで,樹脂がサイジング10内を引取方向に移動する際に,中央部から連続的に冷却される。 4A is an explanatory view showing the configuration of the sizing 10 used in the method for producing a resin-based foamed molded article of the present embodiment, FIG. 4B is a sectional view of FIG. 4A, and FIG. It is b sectional drawing. In general sizing, cooling water or the like is piped in the sizing to uniformly cool the entire sizing. However, in the sizing 10 in the present embodiment, the cooling part 26 of the sizing 10 is connected to the outlet 14 from the inlet 12 side of the sizing 10. It is designed to continuously increase in the width direction toward the side. By adopting such a design, when the resin moves in the sizing 10 in the take-up direction, the resin is continuously cooled from the central portion.
図4(B),(C)に示すように,サイジング10の冷却部26はサイジング10の出口14部分では,冷却部の厚みD2まで入り込んだ設計となっている。サイジング10の入口12より入った樹脂(第1の発泡成形体)は,引取方向に進むにともない樹脂中央部から冷却されることになり,また,冷却部の厚みはD2であるため,樹脂中央部からD2の厚みで冷却固化されていくことになる。 As shown in FIGS. 4B and 4C, the cooling part 26 of the sizing 10 is designed to enter the cooling part thickness D2 at the outlet 14 part of the sizing 10. The resin (first foamed molded product) that has entered from the inlet 12 of the sizing 10 is cooled from the center of the resin as it proceeds in the take-off direction, and since the thickness of the cooling section is D2, the resin center From the part, it is cooled and solidified with a thickness of D2.
樹脂中央部が冷却固化されると,樹脂粘度の違いから,サイジング10内で樹脂の流動は外側に進むことになる。この巾方向への樹脂の流動により,木質系フィラーの引取方向への配向をより効率的に抑えることが可能となる。すなわち,冷却部26により冷却され出口14から引き取り機によって引き取られた樹脂(第2の発泡成形体)は,木質系フィラーの引取方向への配向が抑えられたものとなっている。この冷却条件により木質系フィラーの配向を制御することが可能となり,本発明に用いる,長手方向および巾方向の線膨張係数の異なる樹脂系床材を得ることができる。 When the resin center is cooled and solidified, the flow of the resin proceeds outward in the sizing 10 due to the difference in resin viscosity. This resin flow in the width direction makes it possible to more efficiently suppress the orientation of the wood filler in the take-up direction. That is, the resin (second foamed molded product) cooled by the cooling unit 26 and taken out from the outlet 14 by the take-up machine has a suppressed orientation of the wood filler in the take-up direction. This cooling condition makes it possible to control the orientation of the wood filler, and it is possible to obtain resin-based flooring materials having different linear expansion coefficients in the longitudinal direction and the width direction used in the present invention.
図3,図4を参照してサイジング10についてさらに詳細に説明する。 図3,図4(A)に示すように,入口12と出口14はサイジング冷却用整形路16で接続されている。図4(B),(C)に示すように,サイジング冷却用整形路16の巾方向の両側に位置する側壁18は,入口12から出口14に向けて矩形の巾が次第に大きくなるように設けられている。サイジング冷却用整形路16の高さ方向の両側に位置する上下の壁20は,入口12の高さ方向における両側に接続する平面壁22と,平面壁22の巾方向の中央にサイジング冷却用整形路16内に突出するように設けられた突出壁24とを有している。突出壁24の巾は入口12から出口14に向かうにつれて次第に大きくなり出口14において出口14の巾と一致している。突出壁20は例えば水などの冷却用媒体により冷却され,突出壁20が前記の冷却部26を構成している。 The sizing 10 will be described in more detail with reference to FIGS. As shown in FIGS. 3 and 4A, the inlet 12 and the outlet 14 are connected by a shaping passage 16 for sizing cooling. As shown in FIGS. 4B and 4C, the side walls 18 located on both sides in the width direction of the sizing cooling shaping path 16 are provided so that the rectangular width gradually increases from the inlet 12 toward the outlet 14. It has been. The upper and lower walls 20 positioned on both sides in the height direction of the sizing cooling shaping path 16 are a flat wall 22 connected to both sides in the height direction of the inlet 12 and a sizing cooling shaping at the center in the width direction of the flat wall 22. And a projecting wall 24 provided so as to project into the passage 16. The width of the protruding wall 24 gradually increases from the inlet 12 toward the outlet 14, and matches the width of the outlet 14 at the outlet 14. The protruding wall 20 is cooled by a cooling medium such as water, and the protruding wall 20 constitutes the cooling unit 26.
本発明において,木質樹脂発泡成形体に使用される木質系フィラー3の素材としては,特に制限されることなく選択が可能であるが,一般的には木材をカッターミルなどによって破断し,これをボールミルやインペラーミルなどにより粉砕して,微粉状にした木粉などを用いる。 In the present invention, the material of the wood filler 3 used for the wood resin foam molded body can be selected without any particular restriction, but generally, the wood is broken by a cutter mill or the like, Use finely pulverized wood powder by ball mill or impeller mill.
木質系フィラー3の平均粒径は,1μm〜200μmが好ましく,10μm〜150μmがより好ましい。平均粒径が1μm未満のものは取り扱いが困難であるうえに,特に木質系フィラーの配合量が多い場合は,樹脂への分散が悪く,木質樹脂発泡成形体に機械強度の低下が発生する。また,200μmより大きいと,成形品の均質性,平面性,機械的強度が低下する。 The average particle diameter of the wood filler 3 is preferably 1 μm to 200 μm, and more preferably 10 μm to 150 μm. Those having an average particle size of less than 1 μm are difficult to handle, and particularly when the amount of the wood filler is large, the dispersion into the resin is poor and the mechanical strength of the wood resin foam molded article is lowered. On the other hand, if it is larger than 200 μm, the homogeneity, flatness and mechanical strength of the molded product are lowered.
また,木質系フィラー3の配合量については,熱可塑性樹脂4の100重量部に対して,10重量部から300重量部まで適宜選択が可能であるが,成形性や均質性を高めるために,木質系フィラー3は,熱可塑性樹脂4の100重量部に対して20〜200重量部,より好ましくは30〜150重量部の配合量とすることが望ましい。木質系フィラー3の配合量が多すぎると,床材5の曲げ弾性率が上がり,しなやかさが失われるために,施工性が悪化したり,特に隅部への施工時や一枚交換時に,床材5を撓ませて施工することが難しくなり,曲げた時に割れ易くなる。一方,少なすぎると,線膨張係数が大きくなり,寸法安定性が低下するために,温度変化によって,床材5同士の間の目隙きや,床材5同士の突き上げによる浮き等を発生したりする原因となる。 Moreover, about the compounding quantity of the wood type filler 3, although it can select suitably from 10 weight part to 300 weight part with respect to 100 weight part of the thermoplastic resin 4, in order to improve a moldability and homogeneity, The wood filler 3 is desirably 20 to 200 parts by weight, more preferably 30 to 150 parts by weight based on 100 parts by weight of the thermoplastic resin 4. If the amount of the wood filler 3 is too large, the flexural modulus of the flooring 5 will increase and the flexibility will be lost, so the workability will deteriorate, especially at the time of construction in the corner or when replacing one piece, It becomes difficult to work by bending the flooring 5, and it is easy to break when bent. On the other hand, if the amount is too small, the coefficient of linear expansion will increase and the dimensional stability will decrease. Therefore, due to temperature changes, gaps between the flooring materials 5 and floating due to the thrusting up of the flooring materials 5 will occur. Cause it.
本発明において,木質樹脂発泡成形体を成形するための木質樹脂組成物には,前記熱可塑性樹脂4と木質系フィラー3の他に,発泡剤が添加されて,成形過程において発泡される。 In the present invention, a foaming agent is added to the wood resin composition for molding the wood resin foam molded body in addition to the thermoplastic resin 4 and the wood filler 3 and foamed in the molding process.
本発明において,熱可塑性樹脂4には,必要に応じ熱安定剤,酸中和剤,紫外線吸収剤,ブロッキング防止剤,脱水剤,半透明化のための光散乱剤,艶調整剤等を添加することもできる。 In the present invention, the thermoplastic resin 4 is optionally added with a heat stabilizer, an acid neutralizer, an ultraviolet absorber, an antiblocking agent, a dehydrating agent, a light scattering agent for translucency, a gloss adjusting agent, and the like. You can also
これらの添加剤のうち熱安定剤としてはヒンダードフェノール系,硫黄系,リン系等,酸中和剤としてはステアリン酸金属塩,ハイドロタルサイト等,紫外線吸収剤としてはベンゾトリアゾール系,ベンゾエート系,ベンゾフェノン系,トリアジン系等があり,光安定剤としてはヒンダードアミン系等がある。 Of these additives, heat stabilizers include hindered phenols, sulfur and phosphorus, acid neutralizers include stearic acid metal salts, hydrotalcite, etc., ultraviolet absorbers such as benzotriazole and benzoate. Benzophenone, triazine, etc., and light stabilizers include hindered amines.
本発明において,木質樹脂発泡成形体の成形としては通常の異形押出法を用いることができる。なかでも,連続的かつ安定的に発泡成形可能はセルカ成形法が好ましい。 In the present invention, an ordinary profile extrusion method can be used for forming the wood resin foam molded article. Among these, the SELKA molding method is preferable so that continuous and stable foam molding is possible.
また,発泡の手法についても公知の手法がいずれも利用できる。一般的には,熱分解や化学反応によってガスを発生する化学発泡と,低沸点の液体に熱をかけて気化させる物理発泡とに分類でき,化学発泡剤としては無機系の重炭酸ナトリウム,炭酸アンモニウム,重炭酸アンモニウム,亜硝酸アンモニウム,ホウ化水素ナトリウム,軽金属,アジド化合物等,また有機発泡剤としてはアゾ系,ニトロソ系,ヒドラジド系等が,任意の組み合わせで使用できる。 Also, any known method can be used for the foaming method. In general, chemical foaming can be classified into chemical foaming, which generates gas by thermal decomposition or chemical reaction, and physical foaming, which heats and vaporizes low boiling point liquids. Ammonium, ammonium bicarbonate, ammonium nitrite, sodium borohydride, light metals, azide compounds, etc., and organic foaming agents such as azo, nitroso, hydrazide, etc. can be used in any combination.
また,特に2倍を越える高発泡倍率での発泡には主に物理発泡が用いられ,発泡剤としては炭酸ガスや脂肪族炭化水素が主に用いられる。また,物理発泡に際しても発泡体のセル形状を整えるため化学発泡剤を併用することが多い。 In particular, physical foaming is mainly used for foaming at a high foaming ratio exceeding 2 times, and carbon dioxide gas or aliphatic hydrocarbons are mainly used as foaming agents. In addition, chemical foaming agents are often used in combination with physical foaming to adjust the cell shape of the foam.
本発明において,木質樹脂組成物を構成する熱可塑性樹脂4,木質系フィラー3,発泡剤およびその他の添加剤の混練については,特に方法を問わないが,バンバリーミキサーによって混練し,ペレタイザーでペレット化する方法や,2軸押出混練機によって混合,ペレット化する方法などが一般的である。また,木質系フィラー3は,含水率が大きいと,ペレタイズ時に発泡の原因となるために,混練前に予め乾燥機やホッパードライヤーで含水率を8%以下に抑えることが望ましい。 In the present invention, the kneading of the thermoplastic resin 4, the wood filler 3, the foaming agent and other additives constituting the wood resin composition is not particularly limited, but it is kneaded with a Banbury mixer and pelletized with a pelletizer. And a method of mixing and pelletizing with a twin-screw extrusion kneader. Moreover, since the wood filler 3 causes foaming during pelletization when the moisture content is large, it is desirable to suppress the moisture content to 8% or less in advance by using a dryer or a hopper dryer before kneading.
本発明の床材5は,木質樹脂発泡成形体の表面に,熱可塑性樹脂4と同系の熱可塑性樹脂を主体とする化粧シート1を積層することが好ましい。前記同系の熱可塑性樹脂とすることで,リサイクル処理時に混合しても大きな物性変化を伴わずにリサイクルが可能となる。 In the flooring 5 of the present invention, a decorative sheet 1 mainly composed of a thermoplastic resin similar to the thermoplastic resin 4 is preferably laminated on the surface of the wood resin foam molded body. By using the same thermoplastic resin, recycling is possible without significant change in physical properties even when mixed during the recycling process.
具体的には,例えばポリエチレン,ポリプロピレン,ポリブテン,ポリイソプレン,エチレン−プロピレン共重合体,エチレン−酢酸ビニル共重合体,エチレン−α−オレフィン共重合体,プロピレン−α−オレフィン共重合体,エチレン−エチルアクリレート共重合体や,これらを接着性の向上を目的として酸変性したもの,アイオノマー等,或いはそれらの混合物,共重合体等,各種のポリオレフィン系樹脂の中から適宜選択が可能であり,これらの中から選ばれる同種又は異種の樹脂を,木質樹脂発泡成形層用4および化粧シート用1の熱可塑性樹脂として使用することができる。 Specifically, for example, polyethylene, polypropylene, polybutene, polyisoprene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, ethylene-α-olefin copolymer, propylene-α-olefin copolymer, ethylene- Ethyl acrylate copolymers, those modified with acids for the purpose of improving adhesiveness, ionomers, etc., or mixtures and copolymers thereof, can be selected as appropriate from various polyolefin resins. The same kind or different kinds of resins selected from the above can be used as the thermoplastic resin for the wood resin foam molding layer 4 and the decorative sheet 1.
さらに,本発明の床材5には,木質樹脂発泡成形体の裏面に,前記木質樹脂発泡成形体に含有される熱可塑性樹脂4と同系の熱可塑性樹脂を主体とする発泡層(図示せず)が積層されていてもよい。例えば,床材5の裏面側に発泡層を積層しておくと,床下地面の不陸を吸収してがたつきを防止したり,床面への物品の衝突音や歩行音を吸収して騒音を防止したりするなどの効果がある。 Furthermore, the flooring 5 of the present invention has a foam layer (not shown) mainly composed of a thermoplastic resin similar to the thermoplastic resin 4 contained in the wood resin foam molded body on the back surface of the wood resin foam molded body. ) May be laminated. For example, if a foam layer is laminated on the back side of the flooring 5, it absorbs unevenness of the floor base surface to prevent rattling, or absorbs impact sounds and walking sounds of articles on the floor surface. There are effects such as preventing noise.
前記発泡層の積層手法については公知の手法が利用でき,例えば木質樹脂発泡成形体1の成形用の木質樹脂組成物に用いた熱可塑性樹脂4と同系の熱可塑性樹脂に,前記熱分解や化学反応によってガスを発生する化学発泡剤又は低沸点の液体に熱をかけて気化させる物理発泡剤のいずれかの発泡剤によりシート状に発泡成形した発泡成形体を,木質樹脂発泡成形体の化粧シート1を積層していない裏面に貼り合わせることにより形成できる。 As a method for laminating the foamed layer, a known method can be used. For example, the thermoplastic resin 4 used in the woody resin composition for molding the woody resin foam molded body 1 is converted into a thermoplastic resin similar to the thermoplastic resin 4 or the like. A foamed molded article formed by foaming a sheet with a foaming agent that is either a chemical foaming agent that generates gas by reaction or a physical foaming agent that vaporizes by applying heat to a low-boiling point liquid. It can be formed by bonding 1 to the back surface which is not laminated.
以上説明したように本実施の形態によれば,木質感やリサイクル適性に優れた木質樹脂発泡成形体を基材とした床材を用いた施工方法において,環境温度変化に起因する突き上げ現象を抑えることができ,また,本発明による施工方法に用いられる樹脂系床材の施工方法を実現するための,樹脂系床材を製造することができる。 As described above, according to the present embodiment, in a construction method using a flooring material based on a wood resin foam molded article excellent in wood texture and recyclability, a push-up phenomenon caused by environmental temperature change is suppressed. In addition, it is possible to manufacture a resin-based flooring material for realizing the method of installing a resin-based flooring material used in the construction method according to the present invention.
(床材1〜4の製造)
次に本発明における床材の製造方法について,具体的な実施例を挙げて説明するが,本発明は実施例によって制限されるものではない。熱可塑性樹脂としてホモポリプロピレン樹脂にマレイン酸変性ポリプロピレン樹脂が20重量%添加されてなるホモポリプロピレン系樹脂100重量部と,木質系フィラーとして木材をカッターミルで破断し,これをボールミルにより粉砕して微粉状にした平均粒径100μmのものを用い,この100重量部とを,2軸押出混練機によって混合し,ペレット化して,木質樹脂組成物を作製した。この木質樹脂組成物100重量部に対して,トリアリルイソシアヌレートおよび重曹−クエン酸系発泡剤を3重量部添加し,1軸押出機により押出成形を実施した。押出機付帯の冷却サイジング10として,図3,4に示す寸法設計,冷却部設計のサイジング10を用いた。L1=50mm,D1=24mm,L2=200mm,D2=6mmのサイジング10寸法により,発泡倍率1.4倍,厚さ6mm,幅200mmの断面長方形状に成形し,さらに表面にコロナ放電処理をして,木質樹脂発泡成形体である床材1を作製した。また,同様の金型を用い,サイジング冷却温度設定を変えることにより,長手方向および巾方向の線膨張係数の異なる床材2〜4を作成した。床材1〜4の線膨張係数に関して,0℃から60℃まで環境温度を変化させた際の,床材寸法変化を測定し,長手方向および基材巾方向の線膨張係数を測定した結果を表1に示す。また,床材1〜4成形におけるサイジング冷却設定温度も表1に示す。また,それぞれの床材の表面硬度をゴム硬度計にて測定した値を併せて示すが,木質系フィラー配合量が同一のため大きな差はなく,また,押出成形時の成形性に関しても特に差はなかった。
(Manufacture of flooring materials 1-4)
Next, although the manufacturing method of the flooring material in this invention is demonstrated with a specific Example, this invention is not restrict | limited by an Example. 100 parts by weight of homopolypropylene resin in which 20% by weight of maleic acid-modified polypropylene resin is added to homopolypropylene resin as a thermoplastic resin, and wood as a wood filler is broken by a cutter mill, which is pulverized by a ball mill and finely divided. A wood resin composition having a mean particle diameter of 100 μm was mixed with 100 parts by weight using a twin-screw extrusion kneader and pelletized to prepare a woody resin composition. 3 parts by weight of triallyl isocyanurate and baking soda-citric acid foaming agent were added to 100 parts by weight of this wood resin composition, and extrusion molding was carried out by a single screw extruder. As the cooling sizing 10 attached to the extruder, the sizing 10 shown in FIGS. Based on sizing 10 dimensions of L1 = 50mm, D1 = 24mm, L2 = 200mm, D2 = 6mm, it is molded into a rectangular cross section with a foaming ratio of 1.4 times, a thickness of 6mm, and a width of 200mm, and further subjected to corona discharge treatment Thus, a floor material 1 which is a wood resin foam molded body was produced. In addition, floor materials 2 to 4 having different linear expansion coefficients in the longitudinal direction and the width direction were prepared by using the same mold and changing the sizing cooling temperature setting. Regarding the linear expansion coefficient of flooring materials 1 to 4, the floor material dimensional change was measured when the environmental temperature was changed from 0 ° C. to 60 ° C., and the linear expansion coefficient in the longitudinal direction and the substrate width direction was measured. Table 1 shows. Table 1 also shows the sizing cooling set temperatures in the molding of floor materials 1 to 4. In addition, the surface hardness of each flooring material is shown together with the value measured with a rubber hardness meter, but there is no significant difference because the amount of wood filler is the same, and there is also a particular difference in formability during extrusion molding. There was no.
一方,ランダムポリプロピレンに酸化鉄,酸化チタン等の顔料を配合して製膜した厚さ100μmの着色ポリプロピレンシートにウレタン系インキで木目印刷をして,エクストルージョンラミネート法にてホモポリプロピレン樹脂を100μmの厚みでエンボス同時ラミネートし,この裏面にプライマーコートを,表面にトップコートを施して,ポリプロピレン系樹脂製の化粧シートを作製した。しかる後,この化粧シートを前記木質樹脂発泡成形体の表面にラッピング加工法にて貼り合わせて連続で作製し,本発明の樹脂系床材を作製した。 On the other hand, 100 μm thick colored polypropylene sheet formed by blending random polypropylene with pigments such as iron oxide and titanium oxide is printed with urethane ink, and homopolypropylene resin is 100 μm by extrusion lamination method. A laminated sheet made of polypropylene resin was prepared by laminating simultaneously with embossing in thickness, applying a primer coat on the back side and a top coat on the surface. Thereafter, the decorative sheet was continuously produced by laminating the decorative sheet on the surface of the wood resin foam molded body by a lapping method, and the resin flooring of the present invention was produced.
(性能評価)
作成した床材1〜4を,図1に示すように配列し,環境試験室内に5℃の環境下にて3m×3mの面積に施工した。環境試験室内の温度を5℃から40℃までサイクル的に変化させ,床面における突き上げの有無を確認した。
(Performance evaluation)
The prepared flooring materials 1 to 4 were arranged as shown in FIG. 1, and were constructed in an environmental test chamber in an area of 3 m × 3 m under an environment of 5 ° C. The temperature in the environmental test chamber was cyclically changed from 5 ° C. to 40 ° C., and the presence or absence of push-up on the floor surface was confirmed.
<比較例>
前記実施例で作成した床材1のみを用いて環境試験室内での施工およびサイクル試験を実施し,床面における突上げの有無を確認した。
<Comparative example>
Using only the flooring 1 prepared in the above-mentioned example, construction in an environmental test chamber and a cycle test were carried out, and the presence or absence of a push-up on the floor surface was confirmed.
実施例および比較例に関して,化粧シートを積層していることから,当然ながら外観上の違いは観られない。また,サイクル試験の結果として,比較例において突き上げ現象が確認されたのに対し,実施例において突き上げ現象は確認されなかった。 Regarding the examples and comparative examples, since the decorative sheets are laminated, the difference in appearance is naturally not observed. Further, as a result of the cycle test, a push-up phenomenon was confirmed in the comparative example, whereas a push-up phenomenon was not confirmed in the examples.
1 化粧シート
2 気泡
3 木質充填剤
4 熱可塑性樹脂
5 床材
10 サイジング
12 入口
14 出口
L1 入口の巾方向の寸法
L2 出口の巾方向の寸法
26 冷却部
DESCRIPTION OF SYMBOLS 1 Decorative sheet 2 Air bubble 3 Wood filler 4 Thermoplastic resin 5 Floor material 10 Sizing 12 Inlet 14 Outlet L1 Inlet width direction dimension L2 Outlet width direction dimension 26 Cooling part
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