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JP5115041B2 - Molten metal plating equipment - Google Patents
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JP5115041B2 - Molten metal plating equipment - Google Patents

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JP5115041B2
JP5115041B2 JP2007152360A JP2007152360A JP5115041B2 JP 5115041 B2 JP5115041 B2 JP 5115041B2 JP 2007152360 A JP2007152360 A JP 2007152360A JP 2007152360 A JP2007152360 A JP 2007152360A JP 5115041 B2 JP5115041 B2 JP 5115041B2
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molten metal
ingot
dross
weir
pump
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JP2008303431A (en
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功一 高橋
秀行 高橋
博巳 国守
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JFE Steel Corp
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Description

本発明は、溶融金属めっき浴中ドロスを効率よく除去し、かつ製品へのドロス付着を低減できる溶融金属めっき装置に関するものである。   The present invention relates to a molten metal plating apparatus that can efficiently remove dross in a molten metal plating bath and reduce adhesion of dross to a product.

代表的な鋼板の溶融金属めっき方法としては、鋼板を脱脂などの予備処理を行った後、所定の加熱パターンで加熱し、冷却した後、めっきする金属が溶融しためっき浴に浸漬させ、めっき付着量を制御した後、所定の冷却パターンで常温まで冷却する方法がある。 As a typical hot-dip metal plating method for steel plates, after pre-treatment such as degreasing, the steel plates are heated with a predetermined heating pattern, cooled, and then immersed in a plating bath in which the metal to be plated is melted to adhere to the plating. After controlling the amount, there is a method of cooling to room temperature with a predetermined cooling pattern.

めっきによる消耗成分を浴内へ補給するインゴットを溶融金属めっき浴に投入すると、インゴット溶解に伴って低温のインゴット溶解流が発生してインゴット周囲で温度低下が起こる。一般にインゴットは溶融金属浴と成分が異なるので、インゴット周囲では成分組成も変わる。このようにインゴット周囲での温度・成分濃度の急変が生ずると、ドロスと呼ばれる金属化合物の微粒子が発生しやすい。 When an ingot for replenishing a consumable component due to plating into the bath is introduced into the molten metal plating bath, a low temperature ingot dissolving flow is generated along with the ingot melting, and the temperature is lowered around the ingot. In general, the composition of an ingot is different from that of a molten metal bath, so that the composition of the component also changes around the ingot. Thus, when a sudden change in temperature and component concentration around the ingot occurs, metal compound fine particles called dross are likely to be generated.

例えば、溶融金属めっきの代表例である溶融亜鉛めっきの場合には、鋼板のFeと亜鉛浴のZn、亜鉛浴中に添加されているAlなどが反応してドロスが発生する。このうちFeZn7を主成分とする比重の重いドロスはボトムドロスと呼ばれ、溶融亜鉛ポット底に堆積する。このボトムドロスは、数十μm〜1mmと小さいため、容易に溶融亜鉛流動によって巻き上げられ、鋼板に付着し欠陥を引き起こしやすい。 For example, in the case of hot dip galvanization which is a typical example of hot metal plating, Fe in the steel sheet reacts with Zn in the zinc bath, Al added in the zinc bath, etc., and dross is generated. Of these, heavy dross composed mainly of FeZn 7 is called bottom dross and is deposited on the bottom of the molten zinc pot. Since this bottom dross is as small as several tens of μm to 1 mm, it is easily wound up by molten zinc flow, and adheres to the steel sheet and easily causes defects.

これに対処するため、例えば、特許文献1に開示されている方法がある。この方法は、インゴット投入領域を覆う堰(以下インゴット堰)を設けて温度・成分の急激な変化を抑制し、ドロス生成を抑制するものである。
以下に、先行する特許文献を記す。なお、特許文献2については、以下の発明の開示の項で参照するものである。
特開平5−186857号公報 特開平7−207418号公報
In order to cope with this, for example, there is a method disclosed in Patent Document 1. In this method, a weir (hereinafter referred to as an ingot weir) that covers the ingot input region is provided to suppress rapid changes in temperature and components, thereby suppressing dross generation.
The prior patent documents are described below. Note that Patent Document 2 is referred to in the disclosure section below.
JP-A-5-186857 JP-A-7-207418

上述した特許文献1に開示されている方法は、インゴット堰がインゴット投入時の浴温度・成分濃度の急激な変化を抑制できるため、ドロスの発生を抑制して欠陥の少ない製品を製造できる優れた方法であるものの、しかしながら、インゴット堰を用いてもドロス発生を完全に止めることはできず、ある程度のボトムドロスが発生することは避けられない。   The method disclosed in Patent Document 1 described above is excellent in that the ingot weir can suppress drastic changes in bath temperature and component concentration at the time of charging the ingot, thereby suppressing the generation of dross and producing a product with few defects. Although it is a method, however, dross generation cannot be completely stopped even if an ingot weir is used, and it is inevitable that a certain amount of bottom dross is generated.

例えば、インゴット堰を持つ溶融金属めっき装置では、インゴット溶解時にインゴット周りで発生したボトムドロスがインゴット堰下部に堆積する。また、鋼板を通板することにより、鋼板から溶出するFeによって不可避的にボトムドロスが発生する。インゴット堰を配置すると堰下部の領域はよどみやすくなるため、これらボトムドロスはインゴット堰の下部で最も堆積しやすい。以上の理由により、溶融金属ポット内の他の位置に比べて、インゴット堰下部にはボトムドロスが堆積しやすくなる。   For example, in a molten metal plating apparatus having an ingot weir, bottom dross generated around the ingot when the ingot is melted accumulates in the lower part of the ingot weir. Further, when the steel plate is passed, bottom dross is inevitably generated by Fe eluted from the steel plate. When the ingot weir is arranged, the area under the weir becomes easy to stagnate, so these bottom drosses are most likely to accumulate at the bottom of the ingot weir. For the reasons described above, bottom dross is likely to be deposited in the lower portion of the ingot weir compared to other positions in the molten metal pot.

一般に、ボトムドロスは定期的に掻き出し作業を行って除去するものの、近年は製品の品質要求が厳しくなってきているため、わずかなボトムドロスが堆積しているだけでも厳しい品質要求を満足することが難しくなっている。さらに、インゴット堰を設置した溶融金属めっき装置では、インゴット堰が邪魔になり、インゴット堰下部のボトムドロス掻き出し作業自体も難しい状況である。このため、インゴット堰下部はドロス掻きが不十分となりやすく、浴中に巻き上げられるドロスの発生源となりうる問題がある。   In general, the bottom dross is removed by periodically scraping it, but in recent years the quality requirements of products have become stricter, making it difficult to satisfy the strict quality requirements even if only a few bottom dross accumulates. ing. Furthermore, in the molten metal plating apparatus provided with the ingot weir, the ingot weir becomes an obstacle, and the bottom dross scraping work itself under the ingot weir is difficult. For this reason, there is a problem that the lower part of the ingot weir tends to be insufficiently scraped, and can become a source of dross that is rolled up in the bath.

本発明は、このような問題を鑑みなされたものであり、インゴット堰使用時でもボトムドロスを十分に除去でき、ボトムドロス巻き上げによる欠陥を低減できる溶融金属めっき装置を提供することを目的とする。   The present invention has been made in view of such a problem, and an object of the present invention is to provide a molten metal plating apparatus that can sufficiently remove a bottom dross even when an ingot weir is used, and can reduce defects due to winding up the bottom dross.

上記課題は、以下の手段によって解決される。
[1]めっきによる消耗成分を溶融ポットの溶融金属浴内へ補給するインゴット装入領域を覆うインゴット堰を備えた溶融金属めっき装置において、
前記インゴット堰は、開口部を持たない側板と溶融ポットにつながる開口部を持つ底板とからなり、
該インゴット堰の下部に位置する、溶融ポットのドロス堆積部に配置したポンプ吸引口と、
該ポンプ吸引口から溶融金属浴内のドロスを溶融金属ごと吸引する溶融金属ポンプと、
該溶融金属ポンプで吸引された溶融金属中のドロスを分離・除去する除去手段と
スナウト後部に配置した、前記除去手段でドロス除去後の清浄な溶融金属を溶融金属浴へ戻す溶融金属戻し口を備えることを特徴とする溶融金属めっき装置。
The above problem is solved by the following means.
[1] In a molten metal plating apparatus including an ingot weir that covers a charging region of an ingot for replenishing a consumable component due to plating into a molten metal bath of a melting pot ,
The ingot weir consists of a side plate having no opening and a bottom plate having an opening connected to the melting pot,
A pump suction port located in the dross accumulation part of the melting pot , located at the bottom of the ingot weir;
A molten metal pump for sucking the dross in the molten metal bath together with the molten metal from the pump suction port;
Removing means for separating and removing dross in the molten metal sucked by the molten metal pump ;
Snout was placed in the rear, the molten metal plating equipment, characterized in that it comprises a molten metal return port for returning the clean molten metal after dross removal into the molten metal bath in said removal means.

本発明は、インゴット堰使用時にボトムドロスが集中して堆積するインゴット堰下部に溶融金属ポンプの吸引口を配置して、ボトムドロスを溶融金属ごと吸引した後、ボトムドロスのみを除去し、清浄な溶融金属を溶融金属浴内へ戻すようにしたので、ポット内のボトムドロスを効率よく除去できるようになった。また、本発明によりポット底に堆積したボトムドロス量が減少するので、溶融金属浴の流れによってボトムドロスが巻き上げられて製品に付着し欠陥となるトラブルを防止できるようになった。   In the present invention, a suction port of a molten metal pump is disposed under the ingot weir where the bottom dross concentrates and accumulates when the ingot weir is used, and after the bottom dross is sucked together with the molten metal, only the bottom dross is removed and clean molten metal is removed. Since it was made to return to the molten metal bath, the bottom dross in the pot could be removed efficiently. In addition, since the amount of bottom dross deposited on the pot bottom is reduced according to the present invention, it is possible to prevent trouble that the bottom dross is wound up by the flow of the molten metal bath and adheres to the product to cause defects.

以下、図面を参照しながら、本発明を具体的に説明してゆく。図1は、本発明に係る溶融金属めっき装置の一例を示す図である。図中、1は溶融ポット、2は溶融金属浴、3は被めっき材、4はシンクロール、5はサポートロール、6はスナウト、7はインゴット、8は堰、9はボトムドロス、10はポンプ吸引口、11は溶融金属ポンプ、12は除去手段、13は溶融金属戻し口、および14はドロスポットをそれぞれ表す。   Hereinafter, the present invention will be specifically described with reference to the drawings. FIG. 1 is a view showing an example of a molten metal plating apparatus according to the present invention. In the figure, 1 is a melting pot, 2 is a molten metal bath, 3 is a material to be plated, 4 is a sink roll, 5 is a support roll, 6 is a snout, 7 is an ingot, 8 is a weir, 9 is a bottom dross, 10 is a pump suction Mouth, 11 is a molten metal pump, 12 is a removing means, 13 is a molten metal return port, and 14 is a dross spot.

被めっき材3を、溶融ポット1内の溶融金属浴2中にスナウト6を経由して連続的に導入し、シンクロール4により上方に方向転換してサポートロール5を経由して浴外へ引き出す。   The material 3 to be plated is continuously introduced into the molten metal bath 2 in the melting pot 1 via the snout 6, turned upward by the sink roll 4, and drawn out of the bath via the support roll 5. .

本発明では、めっきによる消耗成分を浴内へ補給するインゴット7の装入部周辺を囲う堰8を有する溶融金属めっき装置を対象にしている。図1に示すように、インゴット堰を備えた溶融金属めっき装置では、インゴット堰底にボトムドロス9が集中的に堆積する。   The present invention is directed to a molten metal plating apparatus having a weir 8 surrounding a charging portion of an ingot 7 for supplying a consumable component due to plating into the bath. As shown in FIG. 1, in a molten metal plating apparatus provided with an ingot weir, bottom dross 9 is concentrated on the bottom of the ingot weir.

本発明では、このボトムドロス9を溶融金属ごとポット系外へ排出するポンプ吸引口10をインゴット堰の下部に配置し、溶融金属ポンプ11で吸引する。さらに、除去手段12で、ボトムドロス9を分離してドロスポット14に送るとともに、残った清浄な溶融金属を溶融金属浴2へ戻す。この際、溶融金属戻し口13をスナウト6の後部に配置したものである。   In the present invention, the pump suction port 10 for discharging the bottom dross 9 together with the molten metal to the outside of the pot system is disposed at the lower part of the ingot weir and is sucked by the molten metal pump 11. Further, the removing means 12 separates the bottom dross 9 and sends it to the dross spot 14, and returns the remaining clean molten metal to the molten metal bath 2. At this time, the molten metal return port 13 is disposed at the rear portion of the snout 6.

インゴット堰下部にポンプ吸引口10を配置したことにより、インゴット堰下部に集中したボトムドロス9を効率よく排出できるようになった。また、ボトムドロスが浴中流れによって巻き上げられる前にポンプで吸引除去できるため、鋼板付近のドロス濃度を小さく押さえることができ、ドロス欠陥を低減できるようになった。 By arranging the pump suction port 10 in the lower part of the ingot weir, the bottom dross 9 concentrated in the lower part of the ingot weir can be efficiently discharged. In addition, since the bottom dross can be sucked and removed by a pump before being rolled up by the flow in the bath, the dross concentration in the vicinity of the steel sheet can be kept small, and dross defects can be reduced.

なお、溶融金属ポンプ単独でボトムドロスを吸引除去する方法としてはいくつか提案されており、たとえば特許文献2に開示された技術などがある。しかし、これらの技術は、インゴット堰がない条件でポンプのみを使用するとしており、インゴット投入時発生するドロスがポット底に堆積する前に鋼板に付着して欠陥となる恐れがある。また、インゴット堰を持たない溶融金属めっき装置では、ボトムドロスがポット底全体に堆積してしまい、一般的なポンプの能力では吸引口近傍のボトムドロスしか吸引できないため、堆積しているボトムドロスの一部しか吸引除去できない問題がある。以上より、ポンプ吸引口はインゴット堰下部に配置するのが好ましい。   Several methods have been proposed for sucking and removing the bottom dross by using a molten metal pump alone. For example, there is a technique disclosed in Patent Document 2. However, these technologies use only the pump under the condition that there is no ingot weir, and the dross generated when the ingot is charged may adhere to the steel plate before it accumulates on the bottom of the pot, resulting in a defect. In addition, in a molten metal plating apparatus that does not have an ingot weir, the bottom dross accumulates on the entire pot bottom, and with the ability of a general pump, only the bottom dross near the suction port can be sucked. There is a problem that cannot be removed by suction. From the above, it is preferable that the pump suction port is disposed below the ingot weir.

また、溶融金属戻し口から放出される溶融金属は、ドロスを除去した清浄な溶融金属である。そのため、溶融金属戻し口を被めっき材に近接した場所、すなわちスナウトの後部に配置して、溶融金属戻し口から放出された清浄な溶融金属で被めっき材周りを満たすようにすることが好ましい。   The molten metal discharged from the molten metal return port is a clean molten metal from which dross has been removed. Therefore, it is preferable to arrange the molten metal return port in the vicinity of the material to be plated, that is, in the rear portion of the snout so that the periphery of the material to be plated is filled with clean molten metal released from the molten metal return port.

溶融金属ポンプは、高温の溶融金属を吸引できるものならばどのようなタイプのポンプでもよい。たとえば、ガスリフトポンプやセラミックポンプなどを用いるようにすればよい。また、ドロスを分離する除去手段としては、たとえば、沈殿槽による沈降分離、多孔質状のフィルターなどを用いるようにすればよい。   The molten metal pump may be any type of pump that can suck high-temperature molten metal. For example, a gas lift pump or a ceramic pump may be used. Moreover, as a removing means for separating dross, for example, sedimentation separation by a sedimentation tank, a porous filter, or the like may be used.

ライン速度150mpmとし、ボトムドロス掻き出し作業直前の最もドロスが堆積した条件で、本発明に係る溶融金属めっき装置を適用した実施例と、他の溶融金属めっき装置を適用した2例との比較を行った。   Comparison was made between an example in which the molten metal plating apparatus according to the present invention was applied and two examples in which another molten metal plating apparatus was applied under the conditions where the line speed was 150 mpm and dross was deposited most immediately before the bottom dross scraping operation. .

上述したように本発明を適用した実施例は、溶融亜鉛めっきポットの鋼板入側にインゴット堰を持つ溶融亜鉛めっき装置に対し、ポンプ吸引口をインゴット堰下部に、溶融金属戻し口をスナウト後部に配置したものである。これに対し、比較例1はポンプを用いない条件すなわちドロス除去をしなかった場合であり、比較例2は、図2(図中の符号は、図1と同じ)に示すような鋼板出側の底にポンプ吸引口10を配置した条件であり、本発明を適用した実施例とはポンプ吸引口の配置位置のみが異なる。なお、本実施例、および比較例2では、ポンプとして400L/分のガスリフトポンプを用いた。   As described above, the embodiment in which the present invention is applied to the hot dip galvanizing apparatus having the ingot weir on the steel sheet entrance side of the hot dip galvanizing pot, the pump suction port at the lower part of the ingot weir and the molten metal return port at the rear part of the snout. It is arranged. On the other hand, Comparative Example 1 is a condition in which no pump is used, that is, when dross removal is not performed, and Comparative Example 2 is a steel sheet outlet side as shown in FIG. 2 (the reference numerals in FIG. 1 are the same as those in FIG. 1). This is a condition in which the pump suction port 10 is arranged at the bottom of the pump, and only the arrangement position of the pump suction port is different from the embodiment to which the present invention is applied. In this example and comparative example 2, a gas lift pump of 400 L / min was used as the pump.

図3は、比較結果の一例を示す図である。それぞれの条件に対し、スナウト下1000mmの位置における溶融亜鉛浴を調べ、溶融亜鉛浴中のドロス質量濃度で評価した。比較例1の場合のドロス濃度で規格化した結果を、比較したものである。比較例2が比較例1より10%しかドロス濃度が減少していないのに比べて、本発明では、70%ものドロス濃度減少を達成している。これにより、本発明による被めっき材近傍のドロス濃度低減効果、ならびにボトムドロスの巻き上げ抑制効果を確認できた。   FIG. 3 is a diagram illustrating an example of the comparison result. For each condition, a molten zinc bath at a position of 1000 mm under the snout was examined and evaluated by the dross mass concentration in the molten zinc bath. The results normalized by the dross concentration in the case of Comparative Example 1 are compared. Compared to Comparative Example 2 where the dross concentration is reduced by only 10% compared to Comparative Example 1, the present invention achieves a dross concentration reduction of as much as 70%. Thereby, the dross concentration reduction effect of the to-be-plated material vicinity by this invention and the raising suppression effect of bottom dross were confirmed.

本発明に係る溶融金属めっき装置の一例を示す図である。It is a figure which shows an example of the molten metal plating apparatus which concerns on this invention. 比較例2に係る溶融金属めっき装置を示す図である。It is a figure which shows the molten metal plating apparatus which concerns on the comparative example 2. FIG. 比較結果の一例を示す図である。It is a figure which shows an example of a comparison result.

符号の説明Explanation of symbols

1 溶融ポット
2 溶融金属浴
3 被めっき材
4 シンクロール
5 サポートロール
6 スナウト
7 インゴット
8 堰
9 ボトムドロス
10 ポンプ吸引口
11 溶融金属ポンプ
12 除去手段
13 溶融金属戻し口
14 ドロスポット
DESCRIPTION OF SYMBOLS 1 Melting pot 2 Molten metal bath 3 Material to be plated 4 Sink roll 5 Support roll 6 Snout 7 Ingot 8 Weir 9 Bottom dross 10 Pump suction port 11 Molten metal pump 12 Removal means 13 Molten metal return port 14 Dro spot

Claims (1)

めっきによる消耗成分を溶融ポットの溶融金属浴内へ補給するインゴット装入領域を覆うインゴット堰を備えた溶融金属めっき装置において、
前記インゴット堰は、開口部を持たない側板と溶融ポットにつながる開口部を持つ底板とからなり、
該インゴット堰の下部に位置する、溶融ポットのドロス堆積部に配置したポンプ吸引口と、
該ポンプ吸引口から溶融金属浴内のドロスを溶融金属ごと吸引する溶融金属ポンプと、
該溶融金属ポンプで吸引された溶融金属中のドロスを分離・除去する除去手段と
スナウト後部に配置した、前記除去手段でドロス除去後の清浄な溶融金属を溶融金属浴へ戻す溶融金属戻し口を備えることを特徴とする溶融金属めっき装置。
In a molten metal plating apparatus including an ingot weir that covers a charging region of an ingot for replenishing a consumable component due to plating into a molten metal bath of a melting pot ,
The ingot weir consists of a side plate having no opening and a bottom plate having an opening connected to the melting pot,
A pump suction port located in the dross accumulation part of the melting pot , located at the bottom of the ingot weir;
A molten metal pump for sucking the dross in the molten metal bath together with the molten metal from the pump suction port;
Removing means for separating and removing dross in the molten metal sucked by the molten metal pump ;
A molten metal plating apparatus, comprising a molten metal return port disposed at the rear of the snout and configured to return clean molten metal after dross removal by the removing means to the molten metal bath.
JP2007152360A 2007-06-08 2007-06-08 Molten metal plating equipment Expired - Fee Related JP5115041B2 (en)

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CA2714475C (en) * 2008-02-08 2015-06-30 Siemens Vai Metals Technologies Sas Hot-dip galvanizing installation for steel strip

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JPH01147046A (en) * 1987-12-03 1989-06-08 Sumitomo Metal Ind Ltd Controlling method for galvanizing bath
JPH01177345A (en) * 1988-01-07 1989-07-13 Kawasaki Steel Corp Method and apparatus for uniformizing concentration in plating bath
JP2808334B2 (en) * 1989-12-15 1998-10-08 川崎製鉄株式会社 Plating bath used for continuous hot metal plating
JPH0598405A (en) * 1991-10-04 1993-04-20 Sumitomo Metal Ind Ltd Method and apparatus for manufacturing hot-dip galvanized steel sheet
JPH11286761A (en) * 1998-04-01 1999-10-19 Nkk Corp Hot-dip galvanizing apparatus and method
JP3463635B2 (en) * 1999-12-09 2003-11-05 住友金属工業株式会社 Method for reducing dross in hot dip galvanizing bath and hot dip galvanizing method

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