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JP5117680B2 - Edible extract with improved quality of food and method for producing the same - Google Patents
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JP5117680B2 - Edible extract with improved quality of food and method for producing the same - Google Patents

Edible extract with improved quality of food and method for producing the same Download PDF

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JP5117680B2
JP5117680B2 JP2006043853A JP2006043853A JP5117680B2 JP 5117680 B2 JP5117680 B2 JP 5117680B2 JP 2006043853 A JP2006043853 A JP 2006043853A JP 2006043853 A JP2006043853 A JP 2006043853A JP 5117680 B2 JP5117680 B2 JP 5117680B2
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extract
edible
acid
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chelating agent
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隆生 木田
智佐 小林
由治 白須
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キリンフードテック株式会社
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Description

本発明は、食品の品質改良効果を併せ持つ呈味用の食用エキスおよびその製造法に関する。   The present invention relates to a edible extract for taste that also has an effect of improving the quality of food and a method for producing the same.

食品の呈味に使用される食用エキス、例えば、酵母エキスの副生成物として発生する滓は、カルシウムやマグネシウムのリン酸塩が主体であることが分かっている。これらのリン酸塩は、その素材に本来含有されるリン由来の組成物であるが、殆ど有効利用されていない。
一方、食品添加物であるリン酸塩は、高い食品の品質改良効果を奏するが、その殆どが合成品であって(例えば、特許文献1参照)、天然または食品素材由来のリン酸塩は、未だ市場にない。しかし、最近は、天然志向が高まり、天然または食品素材由来の品質改良剤が求められている。
特許第2607587号明細書
It has been found that edible extracts used for the taste of foods, for example, koji generated as a by-product of yeast extract, are mainly composed of phosphates of calcium and magnesium. These phosphates are phosphorus-derived compositions originally contained in the material, but are hardly used effectively.
On the other hand, phosphate as a food additive has a high food quality improvement effect, but most of them are synthetic products (see, for example, Patent Document 1), and phosphates derived from natural or food materials are: Not yet on the market. Recently, however, natural orientation has increased and a quality improving agent derived from natural or food materials has been demanded.
Patent No. 2,607,587

本発明は、食品素材由来のリン酸塩を食品の品質改良に使用することを目的とする。   An object of this invention is to use the phosphate derived from a foodstuff material for the quality improvement of a foodstuff.

本発明者らは、食用エキス製造時に副生する滓の析出を抑制し、可溶性のリン酸をエキス中に高含有化させることによって、上記の目的が達成され、食品の品質改良効果を奏するリン酸含有エキスを製造できることを見出し、本発明を完成するに至った。
すなわち、本発明は、
(1)食用エキスにキレート剤を存在させ、不溶性リン酸塩の生成抑制または可溶化をしてなることを特徴とする食品の品質改良効果を奏する食用エキス、
(2)キレート剤が有機酸である上記(1)記載の食用エキス、
(3)有機酸が、クエン酸、リンゴ酸またはコハク酸である上記(1)記載の食用エキス、
(4)食用エキスの製造に際し、キレート剤を添加することを特徴とする上記(1)記載の食用エキスの製造法、
(5)キレート剤が、有機酸である上記(4)記載の食用エキスの製造法、
(6)有機酸が、クエン酸、リンゴ酸またはコハク酸である上記(4)記載の食用エキスの製造法、および
(7)不溶性リン酸塩の析出前にキレート剤を添加する上記(4)記載の食用エキスの製造法を提供するものである。
The present inventors suppress the precipitation of koji produced as a by-product during the production of an edible extract, and increase the content of soluble phosphoric acid in the extract, thereby achieving the above-described object and improving the quality of food. It has been found that an acid-containing extract can be produced, and the present invention has been completed.
That is, the present invention
(1) An edible extract having an effect of improving the quality of food, characterized by having a chelating agent present in the edible extract and suppressing or solubilizing the formation of insoluble phosphate,
(2) The edible extract according to the above (1), wherein the chelating agent is an organic acid,
(3) The edible extract according to the above (1), wherein the organic acid is citric acid, malic acid or succinic acid,
(4) A method for producing an edible extract according to (1) above, wherein a chelating agent is added in the production of the edible extract,
(5) The method for producing an edible extract according to the above (4), wherein the chelating agent is an organic acid,
(6) The method for producing an edible extract according to (4) above, wherein the organic acid is citric acid, malic acid or succinic acid, and (7) The chelating agent is added before precipitation of the insoluble phosphate (4) A method for producing the described edible extract is provided.

本発明によれば、食品の品質改良効果を奏する食用エキスを提供することができる。本発明の食用エキスを食品に添加すると、蛋白の溶解促進や畜肉の結着性を高める等の品質改良効果を得ることができるだけでなく、食品の呈味性も向上できる。これらの効果を発揮せしめることを目的とする食品であれば、どのような食品にも応用が可能である。   ADVANTAGE OF THE INVENTION According to this invention, the edible extract which show | plays the quality improvement effect of foodstuff can be provided. When the edible extract of the present invention is added to foods, not only the quality improvement effects such as the promotion of protein dissolution and the binding property of livestock meat can be obtained, but also the taste of foods can be improved. The present invention can be applied to any food as long as it aims to exert these effects.

本発明に係る食用エキスとしては、その原料にリンが含まれていれば、いずれの素材のエキスであってもよく、例えば、酵母エキス、ポークやチキン等の畜肉エキス、ボーンエキス、魚介エキス等が挙げられる。特に本発明においては、リンを高含有する酵母、または畜肉エキスであれば、豚骨、鶏がら、魚のアラ等の骨を含む原料からのエキスが好ましい。原料に骨と肉を含む場合、その比率は特に限定されない。   The edible extract according to the present invention may be an extract of any material as long as the raw material contains phosphorus, such as a yeast extract, a meat extract such as pork or chicken, a bone extract, a seafood extract, etc. Is mentioned. In particular, in the present invention, an extract from a raw material containing bones such as pork bones, chicken bones, fish ara, etc. is preferable if it is a yeast or animal meat extract containing a high amount of phosphorus. When the raw material includes bone and meat, the ratio is not particularly limited.

本発明の食用エキスは、エキス製造時にキレート剤を添加すること以外は、公知の方法によって得られるものでよく、原料からのエキスの抽出法は、通常の水抽出、温水抽出、熱水抽出、酸分解法、酵素分解法等のいずれであってもよい。特に、pHが弱酸性から酸性領域での酸分解および酵素分解によるエキスが好ましい。
酵素分解に用いる酵素の種類は、特に限定するものではなく、例えば、プロテアーゼ等の蛋白分解酵素を用いるのがよい。また、酵母エキスの場合、蛋白分解酵素と、細胞壁分解酵素のグルカナーゼ、マンナナーゼ等を組み合わせてもよい。
弱酸から酸性領域での分解を行うことによって、骨を含む原料からエキスを抽出する場合には、骨の溶解が促進されるため、エキス中のリン酸含有量を高めることができる。
弱酸から酸性の範囲は特に限定するものではないが、骨の溶解が促進されるpH1.5〜4.5が好ましく、より好ましくは2.0〜4.5、さらに好ましくは2.5〜4である。
The edible extract of the present invention may be obtained by a known method except that a chelating agent is added at the time of producing the extract, and the extraction method of the extract from the raw material includes normal water extraction, hot water extraction, hot water extraction, Any of an acid decomposition method, an enzyme decomposition method and the like may be used. In particular, an extract obtained by acid decomposition and enzymatic decomposition in a pH range from weakly acidic to acidic regions is preferable.
The type of enzyme used for the enzymatic degradation is not particularly limited, and for example, a proteolytic enzyme such as a protease may be used. In the case of yeast extract, a proteolytic enzyme may be combined with a cell wall degrading enzyme such as glucanase or mannanase.
When the extract is extracted from the raw material containing bone by performing decomposition in an acidic region from weak acid, the dissolution of bone is promoted, so that the phosphoric acid content in the extract can be increased.
The range from weak acid to acidic is not particularly limited, but is preferably pH 1.5 to 4.5 where bone dissolution is promoted, more preferably 2.0 to 4.5, and still more preferably 2.5 to 4. It is.

本発明に用いるキレート剤は、分解時における酸性状態の維持に貢献できるクエン酸、リンゴ酸またはコハク酸等の有機酸が好ましい。とりわけ、クエン酸またはリンゴ酸が、さらにはクエン酸が好ましい。
キレート効果を有する上記有機酸を添加することにより、エキス中のリン酸が不溶性の塩として析出することを抑制し、あるいは不溶性塩を可溶化して、エキスのリン酸高含有化が図れる。
The chelating agent used in the present invention is preferably an organic acid such as citric acid, malic acid or succinic acid that can contribute to maintaining an acidic state during decomposition. In particular, citric acid or malic acid is preferable, and citric acid is more preferable.
By adding the organic acid having a chelating effect, precipitation of phosphoric acid in the extract as an insoluble salt can be suppressed, or the insoluble salt can be solubilized to increase the content of phosphoric acid in the extract.

キレート剤のエキスへの添加時期は、抽出または分解時、濃縮後や製品直前、あるいは製品等のいずれの状態であっても構わないが、エキス中のリン酸が不溶性の塩として析出する前であることが好ましい。特に、原料の酸分解または酵素分解時に、分解を酸性領域で行う目的で、pH調整剤として添加するのが最も好ましい。
キレート剤の添加量は、エキスのリン酸含有量により異なり、リン酸を不溶性の塩として析出するのを抑制できる量であれば、特に限定されないが、リン含有量の1〜50倍、好ましくは5〜50倍、さらに好ましくは5〜30倍である。
また、キレート剤の添加量は、本発明に係る食用エキスを食品に添加する場合、食品の味に影響を与えない量であることが好ましいが、添加する食品に酸味を付与するなどの目的で、キレート剤の有機酸の量を増加することもできる。
The timing of adding the chelating agent to the extract may be any state such as during extraction or decomposition, after concentration, immediately before the product, or in the product, but before the phosphate in the extract is precipitated as an insoluble salt. Preferably there is. In particular, it is most preferable to add it as a pH adjuster for the purpose of performing decomposition in the acidic region during acid decomposition or enzymatic decomposition of the raw material.
The addition amount of the chelating agent varies depending on the phosphoric acid content of the extract and is not particularly limited as long as it can suppress precipitation of phosphoric acid as an insoluble salt, but is preferably 1 to 50 times the phosphorus content, preferably 5 to 50 times, more preferably 5 to 30 times.
In addition, when the edible extract according to the present invention is added to the food, the amount of the chelating agent is preferably an amount that does not affect the taste of the food, but for the purpose of adding sourness to the food to be added. The amount of chelating agent organic acid can also be increased.

本発明の製造法を実施するに際しては、上記のキレート剤の添加を行う以外は、常法が採用でき、通常のエキス製造過程である濃縮、ろ過、加熱、脱色等の精製工程を施してよい。その条件は、エキスの固形分濃度、不要物除去および殺菌の要否等に応じて任意に決定してよい。   When carrying out the production method of the present invention, a conventional method can be adopted except that the above-mentioned chelating agent is added, and purification steps such as concentration, filtration, heating, decolorization, etc., which are normal extract production processes, may be performed. . The conditions may be arbitrarily determined according to the solid content concentration of the extract, the need for unnecessary material removal and sterilization, and the like.

本発明の食用エキスの形態は、特に限定するものではなく、液体でも、粉末または顆粒等の固形としてもよい。固形への加工法は、その形状に形成するに適した方法であれば、いずれでもよい。
スプレードライ等により粉末化する場合、グリセリン等の賦形剤を添加するのも任意である。
The form of the edible extract of the present invention is not particularly limited, and may be a liquid or a solid such as a powder or a granule. As long as the processing method to solid is a method suitable for forming in the shape, any may be sufficient.
When powdered by spray drying or the like, it is optional to add an excipient such as glycerin.

本発明の食用エキスは、蛋白溶解促進剤、乳化剤、アルカリ剤(かんすい)、結着剤、保水剤、膨張剤、強化剤等としての利用が可能であるが、特に畜肉の結着剤、加工食品の保水剤としての用途に適している。
また、原料由来の呈味成分を有するため、食品に添加した場合、同時に食品の呈味改善効果も奏することができる。
食品への添加量は、添加する食品および添加目的により異なるが、食品中で品質改良効果を奏する量であれば、特に限定されない。
以下に実施例を挙げて本発明をさらに詳しく説明するが、本発明はこれに限定されるものではない。
The edible extract of the present invention can be used as a protein dissolution promoter, emulsifier, alkaline agent, binder, water retention agent, swelling agent, reinforcing agent, etc. Suitable for use as a water retention agent for foods.
Moreover, since it has a taste component derived from a raw material, when it is added to food, it can also have an effect of improving the taste of food.
The amount added to the food varies depending on the food to be added and the purpose of the addition, but is not particularly limited as long as it has an effect of improving quality in the food.
Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

(1)エキス製造法
豚骨(エイワ物産)200gと水800gを混合し、クエン酸でpH3に調製した。プロテアーゼ製剤(武田キリン食品(株)製)を3.85g添加し、50℃で19時間酵素分解した(分解中、クエン酸でpHを3に制御した)。得られた分解物を90℃、10分間加熱後、金網でろ過して骨等の残渣を除去した。回収液を遠心分離(10,000rpm、10分)し、上清を得た。上清を更にろ過(ろ紙:ADVANTEC、No.2)し、ろ液のpHを酸化ナトリウムでpH 5.5に調整後、エバポレーターで固形分含量30%になるように濃縮した。90℃で10分間加熱後、冷却し、遠心分離(8,000rpm×10min)で上清を得た。上清を、スプレードライヤーで乾燥し、リン酸含有ポークエキス粉末約84gを得た。得られたエキス(実施例1エキス)のリン含有量を、HACH LANGE GMBH製LCK350を用いて測定したところ、5.7%であった。
(2)モデルハムの調製法
豚ロースミンチ肉(6mmチョッパー)167gをポリ袋に充填し、表1記載のピックル液100g(対肉重量60%)をそれぞれ添加した。ピックル液のpHは、水酸化ナトリウムでpH7.5に調整した。ポリ袋をヒートシール後、肉とピックル液をなじませ、押し広げて5℃で15時間保存した。フードプロセッサーで1分間混合後、φ30mm塩化ビニリデンケーシングチューブに充填し、密封した。75℃で60分間加熱後、流水で冷却した。

Figure 0005117680
(1) Extract production method 200 g of pork bone (Eiwa product) and 800 g of water were mixed and adjusted to pH 3 with citric acid. 3.85 g of protease preparation (manufactured by Takeda Kirin Foods Co., Ltd.) was added and enzymatically decomposed at 50 ° C. for 19 hours (pH was controlled at 3 with citric acid during decomposition). The obtained decomposition product was heated at 90 ° C. for 10 minutes and then filtered through a wire mesh to remove residues such as bone. The collected liquid was centrifuged (10,000 rpm, 10 minutes) to obtain a supernatant. The supernatant was further filtered (filter paper: ADVANTEC, No. 2), the pH of the filtrate was adjusted to pH 5.5 with sodium oxide, and then concentrated with an evaporator to a solid content of 30%. After heating at 90 ° C. for 10 minutes, the mixture was cooled, and a supernatant was obtained by centrifugation (8,000 rpm × 10 min). The supernatant was dried with a spray dryer to obtain about 84 g of phosphoric acid-containing pork extract powder. The phosphorus content of the obtained extract (Example 1 extract) was measured using LCK350 manufactured by HACH LANGE GMBH and found to be 5.7%.
(2) Model Ham Preparation Method 167 g of pork loin minced meat (6 mm chopper) was filled in a plastic bag, and 100 g of pickle liquid described in Table 1 (60% meat weight) was added thereto. The pH of the pickle solution was adjusted to pH 7.5 with sodium hydroxide. After heat-sealing the plastic bag, the meat and the pickle solution were blended, spread and stored at 5 ° C. for 15 hours. After mixing with a food processor for 1 minute, it was filled in a φ30 mm vinylidene chloride casing tube and sealed. After heating at 75 ° C. for 60 minutes, it was cooled with running water.
Figure 0005117680

(3)試験法
離水率を以下の式により求めた。
[数1]
離水率%=〔全重量*1−(肉重量*2+ケーシングチューブ重量)〕/〔全重量−ケーシングチューブ重量〕×100
*1:ケーシングチューブに充填されたままのハムの重量
*2:ケーシングチューブから取り出したハムの重量
また、断面を観察し、4名のパネルによりオープンパネル法で官能評価を行った。
結果を表2に示す。

Figure 0005117680
(3) Test method The water separation rate was calculated | required with the following formula | equation.
[Equation 1]
Water separation% = [total weight * 1− (meat weight * 2 + casing tube weight)] / [total weight−casing tube weight] × 100
* 1: Weight of ham as filled in casing tube * 2: Weight of ham taken out from casing tube Also, the cross section was observed and sensory evaluation was performed by four panels using the open panel method.
The results are shown in Table 2.
Figure 0005117680

表2に示すごとく、実施例1エキス添加区は、すべて、無添加区に比べて離水率が低下した。単位肉重量当たりのリン含量(%)が同じ場合、実施例1エキス添加区の離水率は、対照の複合リン酸塩添加区を下回った。図1に示すごとく、実施例1エキス添加区における離水率は、エキス添加量の上昇とともに低下した。
断面を観察したところ、複合リン酸塩および実施例1エキス添加区ともに、添加濃度の上昇とともに、断面の状態はなめらかで、均質になる傾向にあった。色の変化はなかった。
官能評価の結果、複合リン酸塩および実施例1エキス添加区は、硬さ、ジューシー感およびしなやかさ等の点で、無添加区よりも優れており、その傾向は、添加量の上昇とともに高まった。実施例1エキスに、ポーク由来の旨味成分が含まれるため、実施例1エキス添加区のハムは、呈味性が増した。
したがって、リン酸含有ポークエキスは、複合リン酸塩と同等またはそれ以上の保水効果を有することが示された。リン酸含有ポークエキスは、肉重量に対して約1%の添加で、顕著な保水効果を奏した。
As shown in Table 2, the water separation rate in all of the Example 1 extract-added sections was lower than that in the non-added section. When the phosphorus content (%) per unit meat weight was the same, the water separation rate in the extract addition group of Example 1 was lower than the control complex phosphate addition group. As shown in FIG. 1, the water separation rate in the extract addition section of Example 1 decreased as the extract addition amount increased.
As a result of observing the cross section, both the complex phosphate and the Example 1 extract-added section tended to have a smooth and homogeneous cross-section as the addition concentration increased. There was no color change.
As a result of sensory evaluation, the complex phosphate and Example 1 extract-added group is superior to the non-added group in terms of hardness, juiciness and suppleness, and the tendency increases with the increase in the amount of addition. It was. Since the umami component derived from pork was contained in the Example 1 extract, the taste of the ham in the Example 1 extract addition group increased.
Accordingly, it was shown that the phosphoric acid-containing pork extract has a water retention effect equal to or higher than that of the complex phosphate. Phosphoric acid-containing pork extract showed a remarkable water retention effect when added at about 1% based on meat weight.

以上記載したごとく、本発明によれば、合成のリン酸塩を必要としない食品の品質改良効果を奏する食用エキスを提供することができる。   As described above, according to the present invention, an edible extract having an effect of improving the quality of food that does not require a synthetic phosphate can be provided.

実施例1における保水性試験における離水率と、リン含量との関係を示すグラフである。3 is a graph showing a relationship between a water separation rate and a phosphorus content in a water retention test in Example 1. FIG.

Claims (8)

食用エキス(白子エキス、卵白エキスを除く)にキレート剤を存在させ、不溶性リン酸塩の生成抑制または可溶化をしてなることを特徴とする、畜肉加工食品の保水性、硬さ、ジューシー感またはしなやかさの改良用の食用エキス。 Water retention, hardness, and juiciness of processed meat products, characterized in that chelating agents are present in edible extracts (excluding white child extracts and egg white extracts) to suppress or solubilize the formation of insoluble phosphate. Or an edible extract for improving suppleness. キレート剤が有機酸である請求項1記載の食用エキス。   The edible extract according to claim 1, wherein the chelating agent is an organic acid. 有機酸が、クエン酸、リンゴ酸またはコハク酸である請求項1記載の食用エキス。   The edible extract according to claim 1, wherein the organic acid is citric acid, malic acid or succinic acid. 食用エキス(白子エキス、卵白エキスを除く)の製造に際し、キレート剤を添加することを特徴とする請求項1記載の食用エキスの製造法。 The method for producing an edible extract according to claim 1, wherein a chelating agent is added in the production of the edible extract (excluding the white child extract and egg white extract) . キレート剤が、有機酸である請求項4記載の食用エキスの製造法。   The method for producing an edible extract according to claim 4, wherein the chelating agent is an organic acid. 有機酸が、クエン酸、リンゴ酸またはコハク酸である請求項4記載の食用エキスの製造法。   The method for producing an edible extract according to claim 4, wherein the organic acid is citric acid, malic acid or succinic acid. 不溶性リン酸塩の析出前にキレート剤を添加する請求項4記載の食用エキスの製造法。   The method for producing an edible extract according to claim 4, wherein a chelating agent is added before precipitation of the insoluble phosphate. 食用エキス(白子エキス、卵白エキスを除く)の製造に際し、キレート剤を添加することを特徴とする、不溶性リン酸塩の生成抑制または可溶化方法。 A method for inhibiting or solubilizing the formation of insoluble phosphate, characterized by adding a chelating agent in the production of edible extracts (excluding white child extract and egg white extract) .
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