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JP5155286B2 - Paper feed roller - Google Patents
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JP5155286B2 - Paper feed roller - Google Patents

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JP5155286B2
JP5155286B2 JP2009273653A JP2009273653A JP5155286B2 JP 5155286 B2 JP5155286 B2 JP 5155286B2 JP 2009273653 A JP2009273653 A JP 2009273653A JP 2009273653 A JP2009273653 A JP 2009273653A JP 5155286 B2 JP5155286 B2 JP 5155286B2
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sbr
rubber
paper feed
mass
paper
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JP2011116480A (en
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靖時 伊藤
浩一 西森
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Sumitomo Rubber Industries Ltd
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Sumitomo Rubber Industries Ltd
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Priority to JP2009273653A priority Critical patent/JP5155286B2/en
Priority to EP10009085.1A priority patent/EP2330153B1/en
Priority to CN201010531456.2A priority patent/CN102079833B/en
Priority to US12/955,647 priority patent/US20110130259A1/en
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Description

本発明は、静電式複写機や各種プリンタ等において紙送りに用いられる紙送りローラに関するものである。   The present invention relates to a paper feed roller used for paper feed in an electrostatic copying machine, various printers, and the like.

例えば静電式複写機、レーザープリンタ、普通紙ファクシミリ装置、インクジェットプリンタ、自動現金預払機(ATM)等の機器類における紙送り機構には、各種の紙送りローラが組み込まれている。前記紙送りローラとしては、紙(プラスチックフィルム等を含む。以下同様。)と接触しながら回転して摩擦によって紙を搬送する、例えば給紙ローラ、搬送ローラ、プラテンローラ、排紙ローラ等が挙げられる。   For example, various paper feed rollers are incorporated in a paper feed mechanism in devices such as an electrostatic copying machine, a laser printer, a plain paper facsimile machine, an ink jet printer, and an automatic cash dispenser (ATM). Examples of the paper feed roller include a paper feed roller, a transport roller, a platen roller, and a paper discharge roller that rotate while contacting paper (including a plastic film, etc.) and convey the paper by friction. It is done.

前記紙送りローラとして、従来は、例えば天然ゴム(NR)、ウレタンゴム、エチレンプロピレンジエンゴム(EPDM)、ポリノルボネンゴム、シリコーンゴム、塩素化ポリエチレンゴム等の各種ゴムからなるローラが一般的に用いられている。
しかし前記紙送りローラの外周面には紙から発生する紙粉が付着しやすく、紙と繰り返し接触するうちに前記外周面に紙粉が蓄積されることで紙に対する紙送りローラの摩擦係数が低下して、比較的早期に紙の搬送不良を生じる場合がある。
Conventionally, as the paper feeding roller, for example, a roller made of various rubbers such as natural rubber (NR), urethane rubber, ethylene propylene diene rubber (EPDM), polynorbornene rubber, silicone rubber, chlorinated polyethylene rubber and the like is generally used. It is used for.
However, paper dust generated from the paper is likely to adhere to the outer peripheral surface of the paper feed roller, and the paper feed roller accumulates on the outer peripheral surface while repeatedly contacting the paper, thereby reducing the friction coefficient of the paper feed roller against the paper. As a result, a paper conveyance failure may occur relatively early.

特に灰分の多い紙を使用した際に前記紙粉が発生しやすいため、前記紙粉の蓄積とそれによる紙の搬送不良を生じやすい。
紙送りローラの耐久性、耐熱老化性等を向上するため、前記紙送りローラを形成するゴム分としてEPM、EPDM等のエチレン−α−オレフィン系共重合ゴムとジエン系ゴムとを併用したり(例えば特許文献1〜3等参照)、前記EPDM等の耐オゾン性ゴムと、イソプレンゴムとを併用したり(例えば特許文献4等参照)することが検討されている。
In particular, when paper with a high ash content is used, the paper dust is likely to be generated. Therefore, the accumulation of the paper dust and the resulting paper conveyance failure are likely to occur.
In order to improve the durability, heat aging resistance, etc. of the paper feed roller, ethylene-α-olefin copolymer rubber such as EPM, EPDM and diene rubber may be used in combination as the rubber component forming the paper feed roller ( For example, the use of ozone-resistant rubber such as EPDM and isoprene rubber in combination (for example, see Patent Document 4) has been studied.

しかし発明者の検討によると、前記従来のゴムの併用系では、紙と繰り返し接触させた際に紙の搬送不良を生じにくい紙送りローラを得ることはできなかった。   However, according to the inventor's study, the conventional rubber combined system cannot provide a paper feed roller that is unlikely to cause poor paper conveyance when repeatedly brought into contact with paper.

特開2007−131806号公報JP 2007-131806 A 特開2007−131808号公報JP 2007-131808 A 特開2007−154178号公報JP 2007-154178 A 特許第3947809号公報Japanese Patent No. 3947809

本発明の目的は、紙粉の蓄積による摩擦係数の低下とそれに伴う紙の搬送不良とを生じにくく、これまでより長期に亘って良好な紙送りを維持できる紙送りローラを提供することにある。   An object of the present invention is to provide a paper feed roller that is less likely to cause a decrease in a coefficient of friction due to accumulation of paper dust and a paper conveyance failure associated therewith, and can maintain good paper feed for a longer period of time. .

発明者の検討によると、紙粉の主成分は紙に含まれる充填剤であり、前記紙粉の付着は、前記紙に含まれている有機成分(脂肪族、芳香族に分類される)の影響によって発生する。そこで発明者は、全体がゴム組成物の架橋物からなるローラ本体を備えた紙送りローラについて、当該ローラ本体を形成するゴム組成物中に含まれるゴム分の組み合わせ検討した。すなわちゴム分を複数組み合わせることで脂肪族、芳香族の、紙に含まれる各種有機成分に対する紙送りローラ表面のSP値(kcal1/2/cm3/2)を調整して、前記有機成分のローラ表面への付着を低減することで紙粉の付着を抑制することを検討した。 According to the inventor's study, the main component of paper dust is a filler contained in paper, and the adhesion of the paper dust is an organic component (classified as aliphatic or aromatic) contained in the paper. Caused by influence. Therefore, the inventor examined a combination of rubber components contained in the rubber composition forming the roller main body with respect to the paper feed roller provided with the roller main body made of a crosslinked product of the rubber composition . That is, by combining a plurality of rubber components, the SP value (kcal1 / 2 / cm3 / 2) of the paper feed roller surface for various organic components contained in aliphatic and aromatic paper is adjusted, and the roller surface of the organic component is adjusted. We studied to suppress the adhesion of paper dust by reducing the adhesion to the paper.

その結果、ゴム分としてエチレンプロピレンジエンゴム(EPDM)、イソプレンゴム(IR)、およびスチレンブタジエンゴム(SBR)の3種を併用するとともに、前記3種のゴム分の質量比を所定の範囲内に設定すると、後述する実施例、比較例の結果からも明らかなように紙と繰り返し接触させた際に、紙粉の蓄積による摩擦係数の低下とそれに伴う搬送不良とを生じにくく、これまでより長期に亘って良好な紙送りを維持できる紙送りローラを提供できることを見出した。   As a result, ethylene propylene diene rubber (EPDM), isoprene rubber (IR), and styrene butadiene rubber (SBR) are used in combination as rubber components, and the mass ratio of the three rubber components is within a predetermined range. When set, when it is repeatedly brought into contact with paper as is clear from the results of Examples and Comparative Examples described later, it is difficult to cause a decrease in the coefficient of friction due to accumulation of paper dust and the accompanying conveyance failure, which is longer than before. It has been found that it is possible to provide a paper feed roller that can maintain a good paper feed over a wide range.

すなわち本発明は、全体がゴム組成物の架橋物からなるローラ本体を備え、前記ゴム組成物は、実質的にゴム分、架橋剤、補強剤・充填剤、および加工助剤からなるとともに、前記ゴム分は、エチレンプロピレンジエンゴム(EPDM)、イソプレンゴム(IR)、およびスチレンブタジエンゴム(SBR)の3種からなり、かつ前記3種のゴム分の、式(1):
=MEPDM/(MIR+MSBR) (1)
〔式中MEPDMはEPDM、MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
で表される質量比Rが25/75以上、75/25以下であることを特徴とするものである。
That is, the present invention is entirely provided with a crosslinked product Tona Ru roller body of the rubber composition, the rubber composition is substantially rubber component, a crosslinking agent, a reinforcing agent or filler, and with consists processing aids, The rubber component comprises three types of ethylene propylene diene rubber (EPDM), isoprene rubber (IR), and styrene butadiene rubber (SBR) , and the three types of rubber components are represented by the formula (1):
R 1 = M EPDM / (M IR + M SBR ) (1)
[Wherein M EPDM is EPDM, M IR is IR, and M SBR is SBR, respectively. ]
The mass ratio R 1 represented by the formula is 25/75 or more and 75/25 or less.

また本発明の紙送りローラのもとになる前記ゴム組成物は、紙と繰り返し接触させた際の摩擦係数の低下とそれに伴う搬送不良とをさらに良好に抑制して、より一層長期に亘って良好な紙送りを維持しうる紙送りローラを提供することを考慮すると、イソプレンゴム(IR)とスチレンブタジエンゴム(SBR)の質量部が式(2):
IR>MSBR (2)
〔式中MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
を満足しているのが好ましい。
In addition, the rubber composition that is the basis of the paper feed roller of the present invention further suppresses the reduction in the coefficient of friction and the accompanying conveyance failure when repeatedly brought into contact with the paper, for a longer period of time. In consideration of providing a paper feed roller capable of maintaining good paper feed, the mass parts of isoprene rubber (IR) and styrene butadiene rubber (SBR) are represented by the formula (2):
M IR > M SBR (2)
[In the formula, M IR represents IR, and M SBR represents SBR, respectively. ]
Is preferably satisfied.

また前記ゴム組成物は、紙と繰り返し接触させた際の摩擦係数の低下とそれに伴う搬送不良とをさらに良好に抑制して、より一層長期に亘って良好な紙送りを維持しうる紙送りローラを提供することを考慮すると、過酸化物架橋剤によって架橋されているのが好ましい。   Further, the rubber composition further suppresses a decrease in the coefficient of friction when repeatedly contacted with paper and the accompanying conveyance failure, and can maintain a good paper feed for a longer period of time. Is preferably crosslinked by a peroxide crosslinking agent.

本発明によれば、紙粉の蓄積による摩擦係数の低下とそれに伴う紙の搬送不良とを生じにくく、これまでより長期に亘って良好な紙送りを維持できる紙送りローラを提供することができる。   According to the present invention, it is possible to provide a paper feed roller that is less likely to cause a decrease in the coefficient of friction due to accumulation of paper dust and a paper conveyance failure associated therewith, and can maintain good paper feed for a longer period of time. .

本発明の紙送りローラの、実施の形態の一例を示す斜視図である。It is a perspective view which shows an example of embodiment of the paper feed roller of this invention.

〈ゴム組成物〉
本発明の紙送りローラのローラ本体を形成するゴム組成物は、実質的にゴム分、架橋剤、補強剤・充填剤、および加工助剤からなるとともに、前記ゴム分は、EPDM、IR、およびSBRの3種からなり、かつ前記3種のゴム分の、式(1):
=MEPDM/(MIR+MSBR) (1)
〔式中MEPDMはEPDM、MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
で表される質量比R 25/75以上、75/25以下であることを特徴とするものである。
<Rubber composition>
The rubber composition forming the roller body of the paper feed roller of the present invention substantially comprises a rubber component, a crosslinking agent, a reinforcing agent / filler, and a processing aid, and the rubber component includes EPDM, IR, and Formula (1) consisting of three types of SBR and the three types of rubber components:
R 1 = M EPDM / (M IR + M SBR ) (1)
[Wherein M EPDM is EPDM, M IR is IR, and M SBR is SBR, respectively. ]
In the mass ratio R 1 represented is 25/75 or more, characterized in that it is 75/25 or less.

これにより、紙と繰り返し接触させた際に、紙粉の蓄積による摩擦係数の低下とそれに伴う搬送不良とを生じにくく、これまでより長期に亘って良好な紙送りを維持できる紙送りローラを提供することができる。
本発明において、前記3種のゴム分の質量比Rが前記範囲に限定されるのは、下記の理由による。
This makes it possible to provide a paper feed roller that is less likely to cause a reduction in the coefficient of friction due to the accumulation of paper dust and associated conveyance failure when repeatedly brought into contact with paper, and that can maintain good paper feed over a longer period of time. can do.
In the present invention, the mass ratio R 1 of the three kinds of rubber is limited to the above range for the following reason.

すなわち、質量比Rが前記範囲未満であってEPDMが少ない場合には、紙送りローラの耐候性が低下して、長期に亘って使用した際に亀裂を生じたり破断したりしやすくなる。また耐摩耗性も低下するため、紙と繰り返し接触させた際に摩耗しやすくなり、前記摩耗によって摩擦係数が低下して紙の搬送不良を生じやすくなる。
一方、質量比Rが前記範囲を超える場合には相対的にIRおよびSBRが少なくなるため、前記3種のゴム分を併用したことによる、紙と繰り返し接触させた際に、紙粉の蓄積による摩擦係数の低下とそれに伴う搬送不良とを生じにくくして、より長期に亘って良好な紙送りを維持する効果が得られない。
That is, when the mass ratio R 1 is less EPDM be less than the range is reduced weather resistance of the paper feed roller becomes easily or break or crack when used for a long period of time. In addition, since wear resistance is also reduced, it is likely to be worn when repeatedly brought into contact with paper, and the friction coefficient is lowered due to the wear, and paper conveyance is likely to occur.
Meanwhile, since the relative IR and SBR is less in the case where the mass ratio R 1 is greater than the above range, due to the fact that in combination the rubber content of the three, when obtained by paper and repeated contact, accumulation of paper dust The effect of maintaining good paper feeding over a longer period of time is less likely to occur due to the lowering of the friction coefficient due to, and the accompanying conveyance failure.

なお前記3種のゴム分の質量比Rは、前記各種の問題点が生じるのを防止してさらに長期に亘って良好な紙送りを維持することを考慮すると、前記範囲内でも45/55以上であるのが好ましい。
また前記3種のゴム分のうちIRとSBRの質量部は式(2):
IR>MSBR (2)
〔式中MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
を満足しているのが好ましい。これにより、後述する実施例、比較例の結果からも明らかなように紙と繰り返し接触させた際の摩擦係数の低下とそれに伴う搬送不良とをさらに良好に抑制して、より一層長期に亘って良好な紙送りを維持しうる紙送りローラを提供することができる。
The mass ratio R 1 of the three kinds of rubbers is 45/55 even within the above range in consideration of preventing various problems and maintaining good paper feeding for a long period of time. The above is preferable.
Of the three types of rubber, the mass parts of IR and SBR are represented by formula (2):
M IR > M SBR (2)
[In the formula, M IR represents IR, and M SBR represents SBR, respectively. ]
Is preferably satisfied. As a result, as will be apparent from the results of Examples and Comparative Examples described later, the decrease in the coefficient of friction when repeatedly contacted with paper and the accompanying conveyance failure are further effectively suppressed, and even longer. A paper feed roller capable of maintaining good paper feed can be provided.

なおIRとSBRは、式(3):
=MIR/MSBR (3)
〔式中MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
で表される質量比Rが3.0以下であるのが好ましい。
前記3種のゴム分のうちEPDMとしては、エチレン、プロピレン、およびジエンを共重合させた種々の共重合体がいずれも使用可能である。前記ジエンとしては、エチリデンノルボルネン(ENB)、ジシクロペンタジエン(DCPD)等が挙げられる。
IR and SBR are represented by the formula (3):
R 2 = M IR / M SBR (3)
[In the formula, M IR represents IR, and M SBR represents SBR, respectively. ]
Preferably in the mass ratio R 2 represented it is 3.0 or less.
Of the three types of rubber components, any of various copolymers obtained by copolymerizing ethylene, propylene, and diene can be used as EPDM. Examples of the diene include ethylidene norbornene (ENB) and dicyclopentadiene (DCPD).

またEPDMとしては伸展油で伸展したいわゆる油展EPDM、および伸展油で伸展していない非油展EPDMのいずれを用いてもよい。前記3種のゴム分に架橋剤等の添加剤を配合し、混練してゴム組成物を調製する際や、前記ゴム組成物を紙送りローラの形状に成形する際の加工性等を向上することを考慮すると油展EPDMが好ましい。
ジエンがENBであるENB系の油展EPDMとしては、例えば住友化学(株)製のエスプレン(登録商標)670F〔ゴム分:伸展油=100:100(質量比)〕、671F〔ゴム分:伸展油=100:70(質量比)〕、三井化学(株)製の三井EPT3042E〔ゴム分:伸展油=100:120(質量比)〕等の1種または2種以上が挙げられる。
As the EPDM, any of so-called oil-extended EPDM extended with an extending oil and non-oil-extended EPDM not extended with an extending oil may be used. Additives such as cross-linking agents to the three rubber components and knead to improve the rubber composition, and improve the workability when molding the rubber composition into the shape of a paper feed roller Considering this, oil-extended EPDM is preferable.
Examples of the ENB-based oil-extended EPDM in which the diene is ENB are, for example, Esprene (registered trademark) 670F manufactured by Sumitomo Chemical Co., Ltd. (rubber: extended oil = 100: 100 (mass ratio)), 671F [rubber: extended Oil = 100: 70 (mass ratio)], Mitsui Chemicals, Inc. Mitsui EPT3042E [rubber content: extended oil = 100: 120 (mass ratio)] and the like.

またジエンがDCPDであるDCPD系の油展EPDMとしては、例えば住友化学(株)製のエスプレン400〔ゴム分:伸展油=100:100(質量比)〕等が挙げられる。
EPDMは前記例示のものを1種単独で用いてもよいし2種以上を併用してもよい。
EPDMとして油展EPDMを用いる場合、前記式(1)中のMEPDMは、前記油展EPDM中に含まれるゴム分(EPDM)の質量部である。
Examples of the DCPD-based oil-extended EPDM in which the diene is DCPD include, for example, Esprene 400 [rubber content: extended oil = 100: 100 (mass ratio)] manufactured by Sumitomo Chemical Co., Ltd.
As the EPDM, those exemplified above may be used singly or in combination of two or more.
When oil-extended EPDM is used as the EPDM, M EPDM in the formula (1) is a part by mass of a rubber component (EPDM) contained in the oil-extended EPDM.

IRとしては、ポリイソプレン構造を有する種々の重合体がいずれも使用可能である。
前記IRとしては、例えば日本ゼオン(株)製のニポール(登録商標)IR2200、IR2200L等が挙げられる。
IRは前記例示のものを1種単独で用いてもよいし2種以上を併用してもよい。
SBRとしては、スチレンとブタジエンとを乳化重合法、溶液重合法等によって共重合させた種々の共重合体がいずれも使用可能である。
またSBRとしては伸展油で伸展したいわゆる油展SBR、および伸展油で伸展していない非油展SBRのいずれを用いてもよい。
As the IR, any of various polymers having a polyisoprene structure can be used.
Examples of the IR include Nipol (registered trademark) IR2200 and IR2200L manufactured by Nippon Zeon Co., Ltd.
As the IR, those exemplified above may be used alone or in combination of two or more.
As the SBR, any of various copolymers obtained by copolymerizing styrene and butadiene by an emulsion polymerization method, a solution polymerization method, or the like can be used.
Further, as the SBR, either a so-called oil-extended SBR extended with an extension oil or a non-oil-extended SBR not extended with an extension oil may be used.

前記乳化重合法による油展SBRとしては、例えば日本ゼオン(株)製のニポール1723〔ゴム分:伸展油=100:37.5(質量比)〕、1739〔ゴム分:伸展油=100:37.5(質量比)〕、9548〔ゴム分:伸展油=100:37.5(質量比)〕等が挙げられる。
また乳化重合法による非油展SBRとしては、例えば日本ゼオン(株)製のニポール1500、1502等が挙げられる。
Examples of the oil-extended SBR by the emulsion polymerization method include Nipol 1723 (rubber content: extended oil = 100: 37.5 (mass ratio)) and 1739 (rubber content: extended oil = 100: 37) manufactured by Nippon Zeon Co., Ltd. .5 (mass ratio)], 9548 [rubber content: extended oil = 100: 37.5 (mass ratio)].
Examples of non-oil-extended SBR by the emulsion polymerization method include Nipol 1500 and 1502 manufactured by Nippon Zeon Co., Ltd.

また溶液重合法による油展SBRとしては、例えば日本ゼオン(株)製のニポールNS460〔ゴム分:伸展油=100:37.5(質量比)〕、NS522〔ゴム分:伸展油=100:37.5(質量比)〕等が挙げられる。
さらに溶液重合法による非油展SBRとしては、例えば日本ゼオン(株)製のニポールNS116R、NS210、NS310S、NS616等が挙げられる。
Moreover, as oil-extended SBR by the solution polymerization method, for example, Nipol NS460 [rubber content: extended oil = 100: 37.5 (mass ratio)] manufactured by Nippon Zeon Co., Ltd., NS522 [rubber content: extended oil = 100: 37]. .5 (mass ratio)] and the like.
Furthermore, examples of non-oil-extended SBR by the solution polymerization method include Nipol NS116R, NS210, NS310S, NS616 manufactured by Nippon Zeon Co., Ltd.

SBRは前記例示のものを1種単独で用いてもよいし2種以上を併用してもよい。
SBRとして油展SBRを用いる場合、前記式(1)〜(3)中のMSBRは、前記油展SBR中に含まれるゴム分(SBR)の質量部である。
ゴム組成物には、前記ゴム分を架橋させるための架橋剤を含有させる。
前記架橋剤としては、通常の硫黄加硫系(硫黄または含硫黄化合物と、加硫促進剤、加硫促進助剤等との併用系)の架橋剤を使用してもよいが、特に過酸化物架橋剤が好ましい。
As the SBR, those exemplified above may be used singly or in combination of two or more.
When oil-extended SBR is used as SBR, M SBR in the formulas (1) to (3) is a part by mass of a rubber component (SBR) contained in the oil-extended SBR.
The rubber composition contains a crosslinking agent for crosslinking the rubber component.
As the crosslinking agent, a conventional sulfur vulcanizing system (a combined system of sulfur or a sulfur-containing compound and a vulcanization accelerator, a vulcanization acceleration aid, etc.) may be used. A product cross-linking agent is preferred.

これにより、後述する実施例、比較例の結果からも明らかなように紙と繰り返し接触させた際の摩擦係数の低下とそれに伴う搬送不良とをさらに良好に抑制して、より一層長期に亘って良好な紙送りを維持しうる紙送りローラを提供することができる。
過酸化物架橋剤としては、例えばベンゾイルパーオキサイド、1,1−ビス(tert−ブチルパーオキシ)−3,3,5−トリメチルシクロヘキサン、2,5−ジメチル−2,5−ジ(ベンゾイルパーオキシ)ヘキサン、ジ(tert−ブチルパーオキシ)ジイソプロピルベンゼン、1,4−ビス[(tert−ブチル)パーオキシイソプロピル]ベンゼン、ジ(tert−ブチルパーオキシ)ベンゾエート、tert−ブチルパーオキシベンゾエート、ジクミルパーオキシド、tert−ブチルクミルパーオキシド、2,5−ジメチル−2,5−ジ(tert−ブチルパーオキシ)ヘキサン、ジtert−ブチルパーオキシドおよび2,5−ジメチル−2,5−ジ(tert−ブチルパーオキシ)−3−ヘキセン等の1種または2種以上が挙げられる。
As a result, as will be apparent from the results of Examples and Comparative Examples described later, the decrease in the coefficient of friction when repeatedly contacted with paper and the accompanying conveyance failure are further effectively suppressed, and even longer. A paper feed roller capable of maintaining good paper feed can be provided.
Examples of the peroxide crosslinking agent include benzoyl peroxide, 1,1-bis (tert-butylperoxy) -3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di (benzoylperoxy). ) Hexane, di (tert-butylperoxy) diisopropylbenzene, 1,4-bis [(tert-butyl) peroxyisopropyl] benzene, di (tert-butylperoxy) benzoate, tert-butylperoxybenzoate, dicumyl Peroxide, tert-butylcumyl peroxide, 2,5-dimethyl-2,5-di (tert-butylperoxy) hexane, ditert-butyl peroxide and 2,5-dimethyl-2,5-di (tert -Butylperoxy) -3-hexene, etc. And the like.

またゴム組成物には、カーボンブラック等の補強剤・充填剤、およびオイル、可塑剤等の加工助剤を適宜選択して含有させ
〈紙送りローラ〉
図1は、本発明の紙送りローラ1の、実施の形態の一例を示す斜視図である。
図1を参照して、この例の紙送りローラ1は、全体が前記ゴム組成物からなる円筒状のローラ本体2と、前記ローラ本体2の中心の通孔3に挿通されたシャフト4とを含んでいる。シャフト4は、例えば金属、セラミック、硬質樹脂等によって形成される。
Also the rubber composition, a reinforcing agent or filler such as carbon black, and oil, Ru is contained by appropriately selecting the processing aid such as a plasticizer.
<Paper feed roller>
FIG. 1 is a perspective view showing an example of an embodiment of a paper feed roller 1 of the present invention.
Referring to FIG. 1, a paper feed roller 1 of this example includes a cylindrical roller body 2 made entirely of the rubber composition, and a shaft 4 inserted through a through hole 3 in the center of the roller body 2. Contains. The shaft 4 is made of, for example, metal, ceramic, hard resin, or the like.

ローラ本体2のゴム厚みは特に限定されないが、例えば静電式複写機等の紙送りローラの場合に良好な紙送りを実現するためには、前記ゴム厚みが1mm以上、20mm以下、特に2mm以上、15mm以下程度であるのが好ましい。
前記ローラ本体2は、先に説明したゴム組成物を射出成形法、押出成形法等の任意の成形法によって円筒状に成形したのち、例えばプレス架橋等によって架橋させて形成される。
The rubber thickness of the roller body 2 is not particularly limited. For example, in the case of a paper feed roller such as an electrostatic copying machine, the rubber thickness is 1 mm or more, 20 mm or less, particularly 2 mm or more. It is preferably about 15 mm or less.
The roller body 2 is formed by molding the rubber composition described above into a cylindrical shape by an arbitrary molding method such as an injection molding method or an extrusion molding method, and then crosslinking the rubber composition by, for example, press crosslinking.

ローラ本体2とシャフト4とは、例えば前記シャフト4の外径をローラ本体2の通孔3の内径よりも大きめに形成して前記通孔3内にシャフト4を圧入したり、前記両者を接着剤によって接着したり、ローラ本体2の架橋時に加硫接着剤によって加硫接着したりすることで一体化される。
また前記一体化の前後の任意の時点で、必要に応じてさらにローラ本体2の外周面5を所定の表面粗さになるように研磨したり、前記外周面5をローレット加工、シボ加工等したり、あるいはローラ本体2の軸方向の長さ、すなわち紙送りローラ1の幅が所定値となるようにローラ本体2の両端をカットしたりする。これにより図1に示す紙送りローラ1が製造される。
The roller body 2 and the shaft 4 are formed by, for example, forming the outer diameter of the shaft 4 larger than the inner diameter of the through hole 3 of the roller body 2 and press-fitting the shaft 4 into the through hole 3 or bonding the both together They are integrated by adhering with an agent or by vulcanizing and adhering with a vulcanizing adhesive when the roller body 2 is crosslinked.
Further, at any time before and after the integration, the outer peripheral surface 5 of the roller body 2 is further polished to a predetermined surface roughness as necessary, or the outer peripheral surface 5 is subjected to knurling or embossing. Alternatively, both ends of the roller body 2 are cut so that the length of the roller body 2 in the axial direction, that is, the width of the paper feed roller 1 becomes a predetermined value. Thereby, the paper feed roller 1 shown in FIG. 1 is manufactured.

お紙送りローラ1の用途によっては、通孔3はローラ本体2の中心から偏心した位置に設けてもよい。またローラ本体2は円筒状でなく異形形状、例えば外周面5の一部が平面状に切り欠かれた形状等であってもよい。かかる異形形状を有するローラ本体2を形成するには、射出成形法、押出成形法等によって、ローラ本体2を前記異形形状に直接に成形してもよいし、円筒状に形成したローラ本体2の外周面5を後加工して前記異形形状としてもよい。 Depending on your sheet conveying roller 1 of the applications, hole 3 may be provided at a position eccentric from the center of the roller body 2. Further, the roller body 2 may have an irregular shape instead of a cylindrical shape, for example, a shape in which a part of the outer peripheral surface 5 is cut out into a flat shape. In order to form the roller body 2 having such an irregular shape, the roller body 2 may be directly molded into the irregular shape by an injection molding method, an extrusion molding method, or the like, or the roller body 2 formed in a cylindrical shape may be formed. The outer peripheral surface 5 may be post-processed to have the irregular shape.

また円筒状に形成したローラ本体2の通孔3に、断面形状が前記異形形状に対応する変形形状とされたシャフト4を圧入することでローラ本体2を変形させて前記異形形状とすることもできる。この場合、外周面5の研磨やローレット加工、シボ加工等は変形前の円筒状のローラ本体2に対して行なうことができるため加工性を向上できる。
本発明の紙送りローラ1は、例えば静電式複写機、レーザービームプリンタ、普通紙ファクシミリ装置、インクジェットプリンタ、自動現金預払機(ATM)等の機器類における紙送り機構に組み込まれる、給紙ローラ、搬送ローラ、プラテンローラ、排紙ローラ等の種々の紙送りローラとして用いることができる。
Alternatively, the roller body 2 may be deformed to have the deformed shape by press-fitting a shaft 4 having a deformed shape corresponding to the deformed shape into the through hole 3 of the roller body 2 formed in a cylindrical shape. it can. In this case, polishing, knurling, embossing, etc. of the outer peripheral surface 5 can be performed on the cylindrical roller body 2 before deformation, so that workability can be improved.
The paper feed roller 1 of the present invention is a paper feed roller incorporated in a paper feed mechanism in equipment such as an electrostatic copying machine, a laser beam printer, a plain paper facsimile machine, an ink jet printer, and an automatic cash dispenser (ATM). It can be used as various paper feed rollers such as a transport roller, a platen roller, and a paper discharge roller.

以下の実施例、比較例におけるゴム組成物の調製、紙送りローラの製造、および試験を、特記した以外は温度23±1℃、相対湿度55±1%の環境下で実施した。
〈実施例1〉
ゴム分としての油展EPDM〔前出の住友化学(株)製のエスプレン670F、ゴム分:伸展油=100:100(質量比)〕60質量部(ゴム分としてのEPDMは30質量部)、IR〔前出の日本ゼオン(株)製のニポールIR2200〕50質量部、およびSBR〔前出の日本ゼオン(株)製のニポール1502〕20質量部と、過酸化物架橋剤としてのジクミルパーオキシド〔日油(株)製のパークミル(登録商標)D〕3質量部と、補強剤・充填剤としてのカーボンブラック〔HAF、東海カーボン(株)製の商品名シースト3〕5質量部と、パラフィンオイル〔出光興産(株)製のダイアナ(登録商標)プロセスオイルPW−380〕20質量部とを混練してゴム組成物を調製した。
In the following examples and comparative examples, the preparation of rubber compositions, the production of paper feed rollers, and tests were carried out in an environment with a temperature of 23 ± 1 ° C. and a relative humidity of 55 ± 1%, unless otherwise specified.
<Example 1>
Oil-extended EPDM as a rubber component [Esprene 670F manufactured by Sumitomo Chemical Co., Ltd., rubber component: extended oil = 100: 100 (mass ratio)] 60 parts by mass (EPDM as a rubber component is 30 parts by mass), 50 parts by mass of IR [Nipol IR2200 manufactured by Nippon Zeon Co., Ltd.] and 20 parts by mass of SBR [Nipol 1502 manufactured by Nippon Zeon Co., Ltd.] and Dicumylper as a peroxide cross-linking agent 3 parts by mass of oxide [Park Mill (registered trademark) D manufactured by NOF Corporation] and 5 parts by mass of carbon black [HAF, trade name Seast 3 manufactured by Tokai Carbon Co., Ltd.] as a reinforcing agent / filler, A rubber composition was prepared by kneading 20 parts by mass of paraffin oil [Diana (registered trademark) process oil PW-380 manufactured by Idemitsu Kosan Co., Ltd.].

次いで、前記ゴム組成物を筒状に押出成形したのち160℃×30分間プレス加硫して、内径φ12.6、外径φ25、長さ60mmの筒状体(コット)を形成し、前記筒状体を、円筒研削盤を用いて外径φ24に研磨したのち長さ30mmにカットして円筒状のローラ本体を形成した。
そして前記ローラ本体の通孔にφ14の樹脂製のシャフト(専用樹脂コア)を圧入して紙送りローラを製造した。
Next, the rubber composition is extruded into a cylindrical shape and then press vulcanized at 160 ° C. for 30 minutes to form a cylindrical body (cot) having an inner diameter φ12.6, an outer diameter φ25, and a length of 60 mm. The cylindrical body was ground to an outer diameter of φ24 using a cylindrical grinder and then cut to a length of 30 mm to form a cylindrical roller body.
Then, a φ14 resin shaft (dedicated resin core) was press-fitted into the through hole of the roller body to manufacture a paper feed roller.

前記ゴム組成物における、前記式(1)で表される質量比Rは30/70であった。またIRとSBRの質量部は式(2)を満足し、式(3)で表される質量比Rは2.5であった。
〈実施例2〉
油展EPDMの量を100質量部(ゴム分としてのEPDMは50質量部)、IRの量を30質量部、SBRの量を20質量部とし、かつパラフィンオイルの量を20質量部としたこと以外は実施例1と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 30/70. The parts by weight of IR and SBR will satisfy equation (2), the mass ratio R 2 of the formula (3) was 2.5.
<Example 2>
The amount of oil-extended EPDM was 100 parts by mass (EPDM as a rubber component was 50 parts by mass), the amount of IR was 30 parts by mass, the amount of SBR was 20 parts by mass, and the amount of paraffin oil was 20 parts by mass. A rubber composition was prepared in the same manner as in Example 1 except that a paper feed roller was produced.

前記ゴム組成物における、前記式(1)で表される質量比Rは50/50であった。またIRとSBRの質量部は式(2)を満足し、式(3)で表される質量比Rは1.5であった。
〈実施例3〉
油展EPDMの量を100質量部(ゴム分としてのEPDMは50質量部)、IRの量を20質量部、SBRの量を30質量部とし、かつパラフィンオイルの量を20質量部としたこと以外は実施例1と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 50/50. The parts by weight of IR and SBR will satisfy equation (2), the mass ratio R 2 of the formula (3) was 1.5.
<Example 3>
The amount of oil-extended EPDM was 100 parts by mass (EPDM as a rubber component was 50 parts by mass), the amount of IR was 20 parts by mass, the amount of SBR was 30 parts by mass, and the amount of paraffin oil was 20 parts by mass. A rubber composition was prepared in the same manner as in Example 1 except that a paper feed roller was produced.

前記ゴム組成物における、前記式(1)で表される質量比Rは50/50であった。またIRとSBRの質量部は式(2)を満足せず、式(3)で表される質量比Rは0.67であった。
〈実施例4〉
油展EPDMの量を140質量部(ゴム分としてのEPDMは70質量部)、IRの量を20質量部、SBRの量を10質量部とし、かつパラフィンオイルを配合しなかったこと以外は実施例1と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 50/50. The parts by weight of IR and SBR are not satisfy the equation (2), the mass ratio R 2 of the formula (3) was 0.67.
<Example 4>
Implemented except that the amount of oil-extended EPDM was 140 parts by weight (EPDM as rubber was 70 parts by weight), the amount of IR was 20 parts by weight, the amount of SBR was 10 parts by weight, and no paraffin oil was added. A rubber composition was prepared in the same manner as in Example 1 to produce a paper feed roller.

前記ゴム組成物における、前記式(1)で表される質量比Rは70/30であった。またIRとSBRの質量部は式(2)を満足し、式(3)で表される質量比Rは2.0であった。
〈実施例5〉
過酸化物架橋剤に代えて、粉末硫黄〔鶴見化学工業(株)製〕1質量部、テトラエチルチウラムジスルフィド〔加硫促進助剤、大内新興化学工業(株)製のノクセラー(登録商標)TET〕2質量部、ジ−2−ベンゾチアゾリルジスルフィド〔加硫促進助剤、大内新興化学工業(株)製のノクセラーDM〕1質量部、ステアリン酸〔日油(株)製の商品名つばき〕1質量部、および酸化亜鉛2種〔三井金属鉱業(株)製〕5質量部を配合したこと以外は実施例4と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 70/30. The parts by weight of IR and SBR will satisfy equation (2), the mass ratio R 2 of the formula (3) was 2.0.
<Example 5>
In place of the peroxide cross-linking agent, 1 part by mass of powdered sulfur (manufactured by Tsurumi Chemical Co., Ltd.), tetraethylthiuram disulfide (vulcanization accelerator, NOCELLER (registered trademark) TET manufactured by Ouchi Shinsei Chemical Co., Ltd.) ] 2 parts by mass, di-2-benzothiazolyl disulfide [vulcanization accelerating aid, Noxeller DM made by Ouchi Shinsei Chemical Co., Ltd.], stearic acid [trade name made by NOF Corporation Tsubaki] A rubber composition was prepared in the same manner as in Example 4 except that 1 part by mass and 5 parts by mass of zinc oxide 2 types (Mitsui Metal Mining Co., Ltd.) were blended to produce a paper feed roller.

前記ゴム組成物における、前記式(1)で表される質量比Rは70/30であった。またIRとSBRの質量部は式(2)を満足し、式(3)で表される質量比Rは2.0であった。
〈比較例1〉
油展EPDMの量を40質量部(ゴム分としてのEPDMは20質量部)、IRの量を50質量部、SBRの量を30質量部、パラフィンオイルの量を50質量部とし、かつカーボンブラックを配合しなかったこと以外は実施例1と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 70/30. The parts by weight of IR and SBR will satisfy equation (2), the mass ratio R 2 of the formula (3) was 2.0.
<Comparative example 1>
The amount of oil-extended EPDM is 40 parts by mass (EPDM as a rubber component is 20 parts by mass), the amount of IR is 50 parts by mass, the amount of SBR is 30 parts by mass, the amount of paraffin oil is 50 parts by mass, and carbon black A rubber composition was prepared in the same manner as in Example 1 except that was not blended to produce a paper feed roller.

前記ゴム組成物における、前記式(1)で表される質量比Rは20/80であった。またIRとSBRの質量部は式(2)を満足し、式(3)で表される質量比Rは1.7であった。
〈比較例2〉
油展EPDMの量を160質量部(ゴム分としてのEPDMは80質量部)、IRの量を10質量部、SBRの量を10質量部とし、かつパラフィンオイルを配合しなかったこと以外は実施例1と同様にしてゴム組成物を調製し、紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 20/80. The parts by weight of IR and SBR will satisfy equation (2), the mass ratio R 2 of the formula (3) was 1.7.
<Comparative example 2>
Implemented except that the amount of oil-extended EPDM was 160 parts by mass (EPDM as rubber was 80 parts by mass), the amount of IR was 10 parts by mass, the amount of SBR was 10 parts by mass, and no paraffin oil was added. A rubber composition was prepared in the same manner as in Example 1 to produce a paper feed roller.

前記ゴム組成物における、前記式(1)で表される質量比Rは80/20であった。またIRとSBRの質量部は式(2)を満足せず、式(3)で表される質量比Rは1.0であった。
〈比較例3〉
実施例1で使用したのと同じ油展EPDM200質量部(ゴム分としてのEPDMは100質量部)と、粉末硫黄〔鶴見化学工業(株)製〕1質量部、テトラエチルチウラムジスルフィド〔加硫促進助剤、大内新興化学工業(株)製のノクセラーTET〕2質量部、ジ−2−ベンゾチアゾリルジスルフィド〔加硫促進助剤、大内新興化学工業(株)製のノクセラーDM〕1質量部、ステアリン酸〔日油(株)製の商品名つばき〕1質量部、および酸化亜鉛2種〔三井金属鉱業(株)製〕5質量部と、補強剤・充填剤としてのカーボンブラック〔HAF、東海カーボン(株)製の商品名シースト3〕1質量部、酸化珪素〔東ソー・シリカ(株)製のNipsil(登録商標)VN3〕10質量部、炭酸カルシウム〔備北粉化工業(株)製のBF300〕、および酸化チタン〔チタン工業(株)製の商品名クロノスKR−380〕15質量部と、パラフィンオイル〔出光興産(株)製のダイアナプロセスオイルPW−380〕20質量部とを混練してゴム組成物を調製した。そして前記ゴム組成物を用いたこと以外は実施例1と同様にして紙送りローラを製造した。
In the rubber composition, the mass ratio R 1 represented by the formula (1) was 80/20. The parts by weight of IR and SBR are not satisfy the equation (2), the mass ratio R 2 of the formula (3) was 1.0.
<Comparative Example 3>
200 parts by weight of the same oil-extended EPDM as used in Example 1 (100 parts by weight of EPDM as a rubber component), 1 part by weight of powdered sulfur (manufactured by Tsurumi Chemical Co., Ltd.), tetraethylthiuram disulfide [vulcanization acceleration aid Agent, 2 parts by weight of Nouchira TET made by Ouchi Shinsei Chemical Co., Ltd., di-2-benzothiazolyl disulfide [vulcanization accelerator, Noxeller DM made by Ouchi Shinsei Chemical Co., Ltd.] 1 mass Parts, 1 part by mass of stearic acid [trade name Tsubaki manufactured by NOF Corporation], 5 parts by mass of zinc oxide 2 types [manufactured by Mitsui Kinzoku Mining Co., Ltd.], and carbon black [HAF as a reinforcing agent / filler , 1 part by mass of Tokai Carbon Co., Ltd. trade name Seast 3], 10 parts by mass of silicon oxide [Nipsil (registered trademark) VN3 made by Tosoh Silica Co., Ltd.], calcium carbonate [manufactured by Bihoku Flour Industries BF300], and oxidized chi A rubber composition is obtained by kneading 15 parts by mass of Tan [trade name Kronos KR-380 manufactured by Titanium Industry Co., Ltd.] and 20 parts by mass of paraffin oil [Diana Process Oil PW-380 manufactured by Idemitsu Kosan Co., Ltd.]. Prepared. A paper feed roller was produced in the same manner as in Example 1 except that the rubber composition was used.

〈比較例4〉
実施例1で使用したのと同じ油展EPDM150質量部(ゴム分としてのEPDMは75質量部)、および非油展EPDM〔住友化学(株)製のエスプレン586〕25質量部と、補強剤・充填剤としてのカーボンブラック〔HAF、東海カーボン(株)製の商品名シースト3〕5質量部と、過酸化物架橋剤としてのジクミルパーオキシド〔日油(株)製のパークミルD〕1.5質量部とを混練してゴム組成物を調製した。そして前記ゴム組成物を用いたこと以外は実施例1と同様にして紙送りローラを製造した。
<Comparative example 4>
150 parts by mass of the same oil-extended EPDM used in Example 1 (75 parts by mass of EPDM as a rubber component), 25 parts by mass of non-oil-extended EPDM (Esprene 586 manufactured by Sumitomo Chemical Co., Ltd.), 5 parts by mass of carbon black (HAF, trade name 3 manufactured by Tokai Carbon Co., Ltd.) as a filler and dicumyl peroxide (Park Mill D manufactured by NOF Corporation) as a peroxide crosslinking agent A rubber composition was prepared by kneading 5 parts by mass. A paper feed roller was produced in the same manner as in Example 1 except that the rubber composition was used.

〈摩擦係数試験および通紙状況評価〉
各実施例、比較例の紙送りローラを、テフロン(登録商標)板の上に載置した幅60mm×長さ210mmの紙〔ゼロックス社製のXerox Business4200〕の上に340gfの鉛直荷重をかけながら圧接させた状態で、前記紙送りローラを周速度105mm/秒で回転させた際に、前記紙に加わる搬送力Fを、ロードセルを用いて測定して、式(4):
μ=F/340 (4)
により摩擦係数μを求めた。
<Friction coefficient test and paper passing status evaluation>
While applying a vertical load of 340 gf on a paper 60 mm wide × 210 mm long (Xerox Business 4200 manufactured by Xerox Co., Ltd.) placed on a Teflon (registered trademark) plate, the paper feed roller of each example and comparative example was placed. When the paper feed roller is rotated at a peripheral speed of 105 mm / sec in the pressed state, the conveyance force F applied to the paper is measured using a load cell, and the formula (4):
μ = F / 340 (4)
Was used to determine the friction coefficient μ.

測定は紙送りローラの製造直後(初期)と、前記紙送りローラを日本ヒューレットパッカード(株)製のレーザープリンタHP Laser Jet 4350nに給紙ローラとして組み込んで前記と同じ紙〔ゼロックス社製のXerox Business4200〕を1万枚通紙した後(耐久後)に実施した。
またこの通紙時の通紙状況を観察して、1万枚までの間に紙送りの不良が生じたものを×(通紙状況不良)、1万枚の通紙をしても紙送りの不良が生じなかったものを○(通紙状況良好)と評価した。
The measurement is performed immediately after the manufacture of the paper feed roller (initial stage), and the paper feed roller is incorporated as a paper feed roller in a laser printer HP Laser Jet 4350n manufactured by Hewlett-Packard Japan Co., Ltd. The same paper (Xerox Business 4200 manufactured by Xerox Corporation). ] After passing 10,000 sheets (after endurance).
In addition, by observing the paper passing status at the time of passing the paper, if the paper feeding failure occurred up to 10,000 sheets, × (paper feeding fault), paper feeding even if 10,000 sheets are passed Those in which no defects occurred were evaluated as ◯ (good paper passing condition).

〈耐候性試験〉
各実施例、比較例の紙送りローラの耐候性を、日本工業規格JIS K6259:2004「加硫ゴム及び熱可塑性ゴム−耐オゾン性の求め方」に所載の静的オゾン劣化試験に則って評価した。
すなわち各実施例、比較例で調製したのと同じゴム組成物を用いて、前記規格において規定された寸法、形状の試験片を作製し、前記試験片に引張ひずみ(10%伸長)を加えながら温度40℃、オゾン濃度50ppm、試験時間96時間の条件でオゾンに曝露した際に、前記試験片に亀裂が発生したか否かを確認した。
<Weather resistance test>
The weather resistance of the paper feed roller of each example and comparative example was determined in accordance with the static ozone deterioration test described in Japanese Industrial Standard JIS K6259: 2004 “Vulcanized rubber and thermoplastic rubber-How to determine ozone resistance”. evaluated.
That is, using the same rubber composition prepared in each example and comparative example, a test piece having the dimensions and shape specified in the standard was prepared, and tensile strain (10% elongation) was applied to the test piece. When exposed to ozone under conditions of a temperature of 40 ° C., an ozone concentration of 50 ppm, and a test time of 96 hours, it was confirmed whether or not cracks occurred in the test piece.

そして亀裂が発生しなかったものを○(耐候性良好)、発生したものを×(耐候性不良)と評価した。
以上の結果を表1、表2に示す。
And the thing which did not generate | occur | produce a crack was evaluated as (circle) (good weather resistance), and the thing which generate | occur | produced was evaluated as x (bad weather resistance).
The above results are shown in Tables 1 and 2.

Figure 0005155286
Figure 0005155286

Figure 0005155286
Figure 0005155286

両表の実施例1〜5、比較例1〜4の結果から、ゴム分としてEPDM、IR、およびSBRの3種を併用するとともに、前記3種のゴム分を、式(1)で表される質量比Rが25/75以上、75/25以下となるように配合したゴム組成物を用いて形成することにより、紙粉の蓄積による摩擦係数の低下とそれに伴う紙の搬送不良とを生じにくく、しかも耐候性にも優れるため、これまでより長期に亘って良好な紙送りを維持できる紙送りローラを提供できることが判った。 From the results of Examples 1 to 5 and Comparative Examples 1 to 4 in both tables, EPDM, IR, and SBR are used in combination as rubber components, and the three rubber components are represented by formula (1). that the mass ratio R 1 25/75 or more, 75/25 by forming with the rubber composition containing such a composed or less, a decrease and paper conveyance and defective associated therewith friction coefficient due to the accumulation of paper dust It has been found that a paper feeding roller that can maintain good paper feeding for a longer period than before can be provided because it hardly occurs and has excellent weather resistance.

また実施例1〜5の結果から、前記質量比Rは、前記範囲内でも45/55以上であるのが好ましいこと、IRとSBRの質量部は式(2)を満足しているのが好ましいこと、さらにゴム組成物は過酸化物架橋剤によって架橋されているのが好ましいことが判った。 From the results of Examples 1 to 5, it is preferable that the mass ratio R 1 is 45/55 or more even within the above range, and that the mass parts of IR and SBR satisfy the formula (2). It has been found that the rubber composition is preferably crosslinked with a peroxide crosslinking agent.

1 紙送りローラ
2 ローラ本体
3 通孔
4 シャフト
5 外周面
DESCRIPTION OF SYMBOLS 1 Paper feed roller 2 Roller main body 3 Through-hole 4 Shaft 5 Outer peripheral surface

Claims (3)

全体がゴム組成物の架橋物からなるローラ本体を備え、前記ゴム組成物は、実質的にゴム分、架橋剤、補強剤・充填剤、および加工助剤からなるとともに、前記ゴム分は、エチレンプロピレンジエンゴム(EPDM)、イソプレンゴム(IR)、およびスチレンブタジエンゴム(SBR)の3種からなり、かつ前記3種のゴム分の、式(1):
=MEPDM/(MIR+MSBR) (1)
〔式中MEPDMはEPDM、MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
で表される質量比Rが25/75以上、75/25以下であり、 式(3):
=M IR /M SBR (3)
〔式中、M IR はIR、M SBR はSBRの、それぞれ質量部を示す。〕
で表される質量比R が0.67以上、3.0以下であることを特徴とする紙送りローラ。
The roller body is entirely composed of a crosslinked product of a rubber composition, and the rubber composition is substantially composed of a rubber component, a crosslinking agent, a reinforcing agent / filler, and a processing aid. Formula (1) comprising three types of propylene diene rubber (EPDM), isoprene rubber (IR), and styrene butadiene rubber (SBR), and the three types of rubber components:
R 1 = M EPDM / (M IR + M SBR ) (1)
[Wherein M EPDM is EPDM, M IR is IR, and M SBR is SBR, respectively. ]
In represented by the mass ratio R 1 is 25/75 to state, and are 75/25 or less, equation (3):
R 2 = M IR / M SBR (3)
[Wherein, M IR represents IR, and M SBR represents part by mass of SBR. ]
In represented by the mass ratio R 2 is 0.67 or more, the paper feed roller, characterized in that is 3.0 or less.
前記ゴム組成物は、イソプレンゴム(IR)とスチレンブタジエンゴム(SBR)の質量部が式(2):
IR>MSBR (2)
〔式中MIRはIR、MSBRはSBRの、それぞれ質量部を示す。〕
を満足している請求項1に記載の紙送りローラ。
In the rubber composition, parts by mass of isoprene rubber (IR) and styrene butadiene rubber (SBR) are represented by the formula (2):
M IR > M SBR (2)
[In the formula, M IR represents IR, and M SBR represents SBR, respectively. ]
The paper feed roller according to claim 1, wherein:
前記ゴム組成物は、過酸化物架橋剤によって架橋されている請求項1または2に記載の紙送りローラ。   The paper feed roller according to claim 1, wherein the rubber composition is crosslinked by a peroxide crosslinking agent.
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