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JP5160926B2 - Method of peeling gold leaf from gold leaf-attached product and method of collecting gold - Google Patents
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JP5160926B2 - Method of peeling gold leaf from gold leaf-attached product and method of collecting gold - Google Patents

Method of peeling gold leaf from gold leaf-attached product and method of collecting gold Download PDF

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JP5160926B2
JP5160926B2 JP2008056508A JP2008056508A JP5160926B2 JP 5160926 B2 JP5160926 B2 JP 5160926B2 JP 2008056508 A JP2008056508 A JP 2008056508A JP 2008056508 A JP2008056508 A JP 2008056508A JP 5160926 B2 JP5160926 B2 JP 5160926B2
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康弘 今井
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株式会社今井金箔
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この発明は、廃棄される金箔貼付品(表面に金箔を貼り付けた祭祀用具や置物など)から金箔を剥離して金を回収する方法に関するものである。   The present invention relates to a method for recovering gold by peeling a gold foil from a discarded gold foil patch (a ritual instrument or figurine with a gold foil attached to the surface).

わが国では神社や仏閣の調度品、仏壇や神棚などの祭祀用具、各種の置物、漆器の文箱など、種々の物品の装飾に金箔が古くから用いられている。金は高価であり、かつ貴重な資源であるから、これらの金箔貼付品が廃棄されるときは、表面に貼付した金箔を剥離して回収し、金地金に再生するのが望ましい。しかし、金箔は非常に薄く、剥離する手間に比較して回収される金の量が微量であるため、不要になった金箔貼付品は、金箔を貼付したまま廃棄されているのが現状である。   In Japan, gold leaf has long been used to decorate various items such as furniture from shrines and temples, ritual tools such as Buddhist altars and shrines, various figurines, and lacquerware boxes. Since gold is an expensive and valuable resource, it is desirable to peel and collect the gold foil affixed to the surface and recycle it into a gold bullion when these gold foil affixed products are discarded. However, the gold leaf is very thin and the amount of gold collected is very small compared to the time and effort required to peel off, so the gold leaf patch that is no longer needed is discarded with the gold leaf attached. .

この発明は、金が貴重資源であることに鑑み、廃棄される金箔貼付品から金(金箔)を経済的に回収して、金地金として再生することができる技術手段を得ることを課題としている。 The present invention, in view of the fact the gold is a valuable resource, gold (gold) from gold foil patch products which are discarded economically recovered, as a problem to obtain a technical means which can be reproduced as gold bullion Yes.

この発明の金箔貼付品からの金の回収方法は、金箔貼付品5の表面から金箔を剥離する手段に特徴があり、金箔貼付品5の表面から金箔を水に分散した小さな金箔片にして剥離する第1工程と、水に分散した金箔を分離する第2工程とを備えている。第1工程では、金箔貼付品5の金箔貼付面に水溶性粉体を混入した高圧空気を噴射すると共に、当該噴射する空気に高圧水を混合して霧状に噴出して、粉体の粒子が金箔貼付面に衝突するときの衝撃で金箔を微細片にして剥離する。水溶性粉体と共に噴射される高圧水は、水溶性粉体が高速で金箔貼付面に衝突するのを助け、また剥離した金箔片が空中に飛散するのを防いでいる。剥離した金箔片は、噴射された水に分散した状態で流下する。 The method for recovering gold from a gold foil patch according to the present invention is characterized by means for peeling the gold foil from the surface of the gold foil patch 5 and peels the gold foil from the surface of the gold foil patch 5 as small gold foil pieces dispersed in water. And a second step of separating the gold foil dispersed in water. In the first step, high-pressure air in which water-soluble powder is mixed is sprayed onto the gold-foil-bonded surface of the gold-foil-bonded product 5, and high-pressure water is mixed into the sprayed air and sprayed in the form of mist. The gold foil is made into fine pieces and peeled off by the impact when it collides with the gold foil application surface. The high-pressure water sprayed together with the water-soluble powder helps the water-soluble powder to collide with the gold foil application surface at a high speed, and prevents the peeled gold foil pieces from scattering into the air. The peeled gold foil pieces flow down while being dispersed in the sprayed water.

第2工程は、流下した水から金箔片を分離する工程である。この工程では、フィルター8が用いられ、水とこれに溶融した粉体はフィルター8を通過し、水に分散している金箔片は、フィルター8に捕捉されるので、剥離した微細な金箔を水及び粉体から分離することができる。この第2工程は、遠心分離機などで金箔片を分離する工程としてもよい。分離した金箔片には接着剤が付着しているので、精製してこれらの不純物を除去し、金地金を得る。   A 2nd process is a process of isolate | separating a gold-foil piece from the water which flowed down. In this process, the filter 8 is used, and water and the powder melted therein pass through the filter 8, and the gold foil pieces dispersed in the water are captured by the filter 8. And can be separated from the powder. This 2nd process is good also as a process of isolate | separating a gold foil piece with a centrifuge. Since the adhesive is adhered to the separated gold foil pieces, these impurities are removed by purification to obtain gold bullion.

水溶性粉体としては、炭酸水素ナトリウム(重炭酸ソーダ、重曹)の粉体を用いるのが好適である。比較的比重が高くて剥離機能に優れ、安価でもある。水溶性粉体と高圧水は、1本のノズルから混合状態で噴射されるが、水溶性粉体を圧縮空気でノズルまで搬送して、当該ノズルで水溶性粉体を含んだ圧縮空気と共に高圧水を噴射するようにすれば、ノズルまでの水溶性粉体の搬送及び高速での水溶性粉体の噴射が容易に可能になる。 As the water-soluble powder, it is preferable to use sodium bicarbonate (sodium bicarbonate, sodium bicarbonate) powder. It has a relatively high specific gravity, an excellent peeling function, and is inexpensive. Soluble powder and high pressure water is ejected in a mixed state from one nozzle, to convey the soluble powder to the nozzle with compressed air, high pressure together with the compressed air containing water-soluble powder in the nozzle If water is jetted, the water-soluble powder can be transported to the nozzle and the water-soluble powder can be jetted at high speed.

本願の請求項1に係る発明は、本願の金箔貼付品からの金の回収方法の第1工程となる金箔の剥離方法の発明であり、ノズル2の噴射口24から金箔貼付品5の金箔貼付面に水溶性粉体を混入した高圧空気を噴射すると共に、当該噴射する空気に前記噴射口24の周縁から供給した高圧水を混合して霧状に噴出することを特徴とする金箔貼付品からの金箔の剥離方法である。 The invention according to claim 1 of the present application is an invention of a gold foil peeling method, which is a first step of a method of recovering gold from the gold foil patch of the present application, and the gold foil patch of the gold foil patch 5 from the nozzle 24 of the nozzle 2. From the gold foil patch characterized by injecting high-pressure air mixed with water-soluble powder on the surface, mixing high-pressure water supplied from the peripheral edge of the injection port 24 into the air to be injected, and spraying it in the form of a mist This is a method for peeling gold leaf.

本願の請求項2の発明に係る金箔貼付品からの金の回収方法は、ノズル2の噴射口24から金箔貼付品5の金箔貼付面に水溶性粉体を混入した高圧空気を噴射すると共に、当該噴射する空気に前記噴射口24の周縁から供給した高圧水を混合して霧状に噴出し、当該金箔貼付面から流下した水をフィルターに通し、当該フィルターに捕捉された剥離金箔片を収集することを特徴とする、金箔貼付品からの金の回収方法である。 The method for recovering gold from the gold foil patch according to the invention of claim 2 of the present application, injects high-pressure air mixed with water-soluble powder from the injection port 24 of the nozzle 2 onto the gold foil paste surface of the gold foil patch 5 , The high-pressure water supplied from the periphery of the injection port 24 is mixed with the air to be jetted and jetted in the form of a mist . The water flowing down from the gold foil sticking surface is passed through the filter 8 and the peeled gold foil pieces captured by the filter are removed. It is the collection method of the gold | metal | money from a gold-foil sticking goods characterized by collecting.

上記各方法における水溶性粉体としては、上記及び請求項3、4に記載のように、質量、安定性、無毒性、経済性などの点で、炭酸水素ナトリウム(重炭酸ソーダ、重曹)の粉体が適している。   As the water-soluble powder in each of the above methods, as described above and in claims 3 and 4, sodium bicarbonate (sodium bicarbonate, sodium bicarbonate) powder in terms of mass, stability, non-toxicity, economy, etc. Is suitable.

本願発明者らが行った実験によれば、水溶性粉体(重曹を用いた。)を圧縮空気でノズルへ搬送し、同時に当該ノズルに高圧水を供給して、金箔貼付面に向けて噴射したところ、当該金箔貼付面の金箔を容易かつ短時間で除去することができた。除去された金箔は、噴射された水に分散して流下する。一方、水と共に噴射された水溶性粉体は、水に溶融する。従って、金箔貼付面から流下した水をフィルターで濾過することにより、当該水中に含まれる金箔を捕捉して収集することができる。   According to experiments conducted by the inventors of the present application, water-soluble powder (using baking soda) was transported to a nozzle with compressed air, and at the same time, high-pressure water was supplied to the nozzle and sprayed toward the gold foil application surface. As a result, the gold foil on the surface where the gold foil was applied could be removed easily and in a short time. The removed gold foil is dispersed in the sprayed water and flows down. On the other hand, the water-soluble powder injected with water melts in water. Therefore, the gold foil contained in the water can be captured and collected by filtering the water flowing down from the gold foil application surface with a filter.

発明者らの実験においては重曹を用いたが、ある程度比重があり、かつ水に容易に溶融する物質の粉体を用いることで、同様な効果が得られると考えられる。実験に用いた重曹の比重は2.2、モースコード2.5、粒度は60〜110μm及び(150〜250μm)である。大きめの粒度のものを用いる方が剥離した後の金箔片の大きさが大きくなり、第2工程での水からの金箔片の分離がより容易になると考えられる。噴射空気の圧力は0.3〜0.5メガパスカル、噴射水の圧力は5〜10メガパスカル程度である。   In the experiments conducted by the inventors, sodium bicarbonate was used, but it is considered that the same effect can be obtained by using a powder of a substance that has a specific gravity to some extent and easily melts in water. The specific gravity of the baking soda used in the experiment is 2.2, the Morse code is 2.5, and the particle size is 60 to 110 μm and (150 to 250 μm). It is considered that the use of the one having a larger particle size increases the size of the gold foil piece after peeling, and it becomes easier to separate the gold foil piece from the water in the second step. The pressure of the jet air is about 0.3 to 0.5 megapascal, and the pressure of the jet water is about 5 to 10 megapascal.

この発明の方法によれば、金箔貼付面から剥離した金箔片を飛散させないで水に分散した状態で回収することができるので、屋外で使用することができ、大型の金箔貼付品からの金箔の剥離が容易にできる。また、粉体と水と空気とを噴射することにより、金箔を剥離するので、仏壇や置物など細かく入り組んだ表面に貼付された金箔も簡単に剥離して回収することが可能である。また、この発明の方法を実施するのに必要な装置である粉体と空気と水とを混合して噴射する装置及びフィルターや遠心分離機などの分離装置も比較的安価であり、金箔の剥離と回収も短時間で行うことができるので、各種の金箔貼付品からの金箔の回収を経済的に行うことができるという効果がある。   According to the method of the present invention, the gold foil pieces peeled off from the gold foil sticking surface can be collected in a dispersed state in water without being scattered, so that it can be used outdoors, and the gold foil from a large gold foil sticking product can be used. Peeling can be done easily. Further, since the gold foil is peeled off by spraying powder, water, and air, it is possible to easily peel off and collect the gold foil stuck on the intricate surface of a Buddhist altar or figurine. In addition, the device necessary for carrying out the method of the present invention is a device for mixing and injecting powder, air, and water, and a separation device such as a filter or a centrifuge, which is relatively inexpensive, and the gold foil is peeled off. And the collection can be performed in a short time, and there is an effect that it is possible to economically collect the gold foil from various kinds of gold foil-attached products.

以下、図面を参照して、この発明の好ましい実施形態の一例について説明する。図1は、この発明の方法を模式的に示した図である。図中、1は空気と水と粉体とを噴射する装置(以下「混合噴射装置」という)、2は噴射ノズル、3はエアホース、4は水ホース、5は金箔貼付品、6は噴射ノズル2から噴射された粉体と水(粉体は水に捕捉されている)の飛散を防止するカバー、7は金箔貼付品5やカバー6から流下する水の水受け、8はフィルター、9は排水容器である。   Hereinafter, an example of a preferred embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a diagram schematically showing the method of the present invention. In the figure, 1 is an apparatus for injecting air, water and powder (hereinafter referred to as “mixed injection apparatus”), 2 is an injection nozzle, 3 is an air hose, 4 is a water hose, 5 is a gold-foiled product, and 6 is an injection nozzle. Cover for preventing scattering of powder and water sprayed from 2 (powder is trapped in water), 7 for receiving water flowing down from gold foil patch 5 and cover 6, 8 for filter, 9 for It is a drainage container.

混合噴射装置1は、コンプレッサ11、空気流路12、水溶性粉体のホッパ13、このホッパ内の粉体を所定量ずつ粉体供給管14に送り出す定量供給装置(スクリュコンベア)15、水タンク16、水タンク16への給水口17、高圧水ポンプ18、水タンク16と高圧水ポンプ18とを連結する吸入水路19及び高圧水ポンプ16とホース接続口21を連結する吐出水路22とを有している。図の給水口17は水道の蛇口である。粉体供給管14は、その下端が空気流路12に開口している。エアホース接続口23に接続されたエアホース3は、ノズル2の後端(噴射口24の反対側の端部)に接続され、粉体を含んだ空気は、ノズル2内を直線的に通過して噴射口24から噴射される。水ホース4の水は、ノズルの噴射口24の周縁から供給され、噴射空気と混合して霧状に噴出する。   The mixed injection device 1 includes a compressor 11, an air flow path 12, a water-soluble powder hopper 13, a fixed amount supply device (screw conveyor) 15 for sending a predetermined amount of powder in the hopper to a powder supply pipe 14, and a water tank. 16, a water supply port 17 to the water tank 16, a high-pressure water pump 18, a suction water channel 19 that connects the water tank 16 and the high-pressure water pump 18, and a discharge water channel 22 that connects the high-pressure water pump 16 and the hose connection port 21. doing. The water supply port 17 in the figure is a water tap. The lower end of the powder supply pipe 14 opens into the air flow path 12. The air hose 3 connected to the air hose connection port 23 is connected to the rear end of the nozzle 2 (the end on the opposite side of the injection port 24), and the air containing the powder passes through the nozzle 2 linearly. It is injected from the injection port 24. Water in the water hose 4 is supplied from the peripheral edge of the nozzle outlet 24, mixed with the jet air, and jetted in a mist form.

実験に用いた混合噴射装置1のコンプレッサ11の吐出圧は最大0.49メガパスカル、使用空気量は最大2.5Nm3/分、高圧水ポンプ18の吐出圧力は最大13.7メガパスカル、吐出水量は最大10リットル/分であり、噴射ノズル2のノズル内径は8mmである。 The discharge pressure of the compressor 11 of the mixed injection device 1 used in the experiment is a maximum of 0.49 megapascals, the amount of air used is a maximum of 2.5 Nm 3 / min, the discharge pressure of the high-pressure water pump 18 is a maximum of 13.7 megapascals, the discharge The maximum amount of water is 10 liters / minute, and the nozzle inner diameter of the injection nozzle 2 is 8 mm.

上記装置を用い、粉体ホッパ13に炭酸水素ナトリウムの粉体を入れ、コンプレッサ11、高圧水ポンプ18及び定量供給装置15を運転してノズル2から噴射する混合ジェット25を金箔貼付品5の金箔貼付面に噴射する。ノズル2を移動するか、又は金箔貼付品5を移動及び回転させて混合ジェット25を金箔貼付面全体に当るようにする。混合ジェット25が噴射された面からは、金箔が速やかに除去されて、除去された金箔は、金箔貼付面から流下する水に分散して水受け7へと流れ落ちる。流れ落ちた水がフィルター8を通過するときに、当該水に分散した金箔はフィルターで捕捉されて分離し、水及びこれに溶解した炭酸水素ナトリウムは排水容器9へと流下する。   Using the above apparatus, powder of sodium hydrogen carbonate is put into the powder hopper 13, and the compressor 11, the high-pressure water pump 18, and the metering supply device 15 are operated and the mixed jet 25 injected from the nozzle 2 is used as the gold foil of the gold foil patch 5. Spray onto the sticking surface. The nozzle 2 is moved or the gold foil patch 5 is moved and rotated so that the mixed jet 25 hits the entire gold foil sticking surface. The gold foil is quickly removed from the surface where the mixed jet 25 is jetted, and the removed gold foil is dispersed in the water flowing down from the gold foil sticking surface and flows down to the water receiver 7. When the water that has flowed down passes through the filter 8, the gold foil dispersed in the water is captured and separated by the filter, and the water and sodium bicarbonate dissolved therein flow down to the drainage container 9.

金箔貼付品5から剥離した金箔の大きさは一定ではないので、フィルター8はできるだけ細かい目のものを用いるのが好ましい。しかし、目の細かいフィルターを用いると、水の通過抵抗が大きくなるので、大きな濾過面積を必要とし、またフィルター8に捕捉された金箔の回収を頻繁に行う必要がある。好ましくは、回転ベルト式や回転円筒式のフィルターを用いて、フィルターに捕捉された金箔を連続的にフィルター面から剥離して回収するようにするのがよい。   Since the size of the gold foil peeled off from the gold-foil-attached product 5 is not constant, it is preferable to use a filter 8 having the finest possible size. However, if a fine filter is used, the water passage resistance increases, so a large filtration area is required, and the gold foil captured by the filter 8 must be frequently collected. Preferably, a rotating belt type or rotating cylinder type filter is used to continuously peel and collect the gold foil captured by the filter from the filter surface.

この発明の方法を模式的に示したブロック図Block diagram schematically showing the method of the present invention

符号の説明Explanation of symbols

1 混合噴射装置
2 噴射ノズル
5 金箔貼付品
8 フィルター
11 コンプレッサ
13 水溶性粉体のホッパ
15 定量供給装置
18 高圧水ポンプ
25 混合ジェット
DESCRIPTION OF SYMBOLS 1 Mixed injection apparatus 2 Injection nozzle 5 Gold-foil sticking goods 8 Filter
11 Compressor
13 Water-soluble powder hopper
15 Metering device
18 High pressure water pump
25 mixing jets

Claims (4)

ノズルの噴射口から金箔貼付面に水溶性粉体を混入した高圧空気を噴射すると共に、当該噴射する空気に前記噴射口の周縁から供給した高圧水を混合して霧状に噴出することを特徴とする、金箔貼付品からの金箔の剥離方法。 Injecting high-pressure air mixed with water-soluble powder onto the gold foil sticking surface from the injection port of the nozzle, and mixing the high-pressure water supplied from the periphery of the injection port into the sprayed air and spraying it in the form of a mist The peeling method of the gold foil from a gold foil sticking article. ノズルの噴射口から金箔貼付面に水溶性粉体を混入した高圧空気を噴射すると共に、当該噴射する空気に前記噴射口の周縁から供給した高圧水を混合して霧状に噴出し、当該金箔貼付面から流下した水をフィルターに通し、当該フィルターに捕捉された剥離金箔片を収集することを特徴とする、金箔貼付品からの金の回収方法。 Injecting high-pressure air mixed with water-soluble powder onto the gold foil application surface from the nozzle injection port , mixing the high-pressure water supplied from the periphery of the injection port into the sprayed air, and spraying it in the form of a mist. A method for recovering gold from a gold foil-attached product, characterized in that the water flowing down from the sticking surface is passed through a filter and the separated gold foil pieces captured by the filter are collected. 水溶性粉体が炭酸水素ナトリウムの粉体である、請求項1記載の金箔の剥離方法。 Water-soluble powder is a powder of sodium hydrogen carbonate, peeling method gilt claim 1. 水溶性粉体が炭酸水素ナトリウムの粉体である、請求項2記載の金の回収方法。 Water-soluble powder is a powder of sodium hydrogen carbonate, a method for recovering gold claim 2.
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