JP5207697B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP5207697B2 JP5207697B2 JP2007248219A JP2007248219A JP5207697B2 JP 5207697 B2 JP5207697 B2 JP 5207697B2 JP 2007248219 A JP2007248219 A JP 2007248219A JP 2007248219 A JP2007248219 A JP 2007248219A JP 5207697 B2 JP5207697 B2 JP 5207697B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- mass
- silicone
- poe
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003676 hair preparation Substances 0.000 title claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 31
- 239000002537 cosmetic Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003093 cationic surfactant Substances 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
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- 150000007524 organic acids Chemical class 0.000 claims description 4
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- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
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- 238000002156 mixing Methods 0.000 description 21
- 238000012360 testing method Methods 0.000 description 21
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- 239000000523 sample Substances 0.000 description 18
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 13
- -1 methyl hydrogen Chemical class 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
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- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
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- 239000013068 control sample Substances 0.000 description 5
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- 238000012986 modification Methods 0.000 description 5
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
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- 231100000475 skin irritation Toxicity 0.000 description 5
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 3
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 241000220317 Rosa Species 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- 239000003755 preservative agent Substances 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
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- 239000000600 sorbitol Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- CLAHOZSYMRNIPY-UHFFFAOYSA-N 2-hydroxyethylurea Chemical compound NC(=O)NCCO CLAHOZSYMRNIPY-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 2
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
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- 229920002907 Guar gum Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
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- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- SCRSFLUHMDMRFP-UHFFFAOYSA-N trimethyl-(methyl-octyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C SCRSFLUHMDMRFP-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 229940078465 vanillyl butyl ether Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003712 vitamin E derivatives Chemical class 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は毛髪化粧料に関し、特に、使用感触、安全性（低刺激性）に優れ、透明感の高い毛髪化粧料に関する。本発明は、洗い流しのヘアコンディショナー、ヘアトリートメント、洗い流さないヘアトリートメント等として好適に用いられる。 The present invention relates to a hair cosmetic, and more particularly to a hair cosmetic that is excellent in feel and safety (low irritation) and has a high transparency. The present invention is suitably used as a hair conditioner for washing away, a hair treatment, a hair treatment without washing away, and the like.
毛髪をシャンプー等で洗髪した後は、一般に艶や指通りが悪くなるため、通常、シャンプー後にヘアコンディショナー、ヘアトリートメント等の毛髪処理剤（毛髪化粧料）が用いられている。近年、消費者の嗜好の多様化に伴い、毛髪化粧料では透明感のある製品に対する需要が高まりつつある。 After washing hair with shampoo or the like, gloss and fingering generally deteriorate. Therefore, hair treatment agents (hair cosmetics) such as hair conditioners and hair treatments are usually used after shampooing. In recent years, with the diversification of consumer preferences, there is an increasing demand for transparent products in hair cosmetics.
従来、このような毛髪化粧料は、カチオン界面活性剤、高級アルコール、水で形成されるラメラ型のゲル（α−ゲル）の系に、油分を添加した乳化系（白濁系）の乳液状〜クリーム状の製剤が用いられていた（例えば、非特許文献１参照）。 Conventionally, such a hair cosmetic is an emulsion (white turbid) emulsion in which an oil is added to a lamellar gel (α-gel) formed of a cationic surfactant, a higher alcohol, and water. A cream-like preparation has been used (for example, see Non-Patent Document 1).
カチオン界面活性剤として、例えば、長鎖モノアルキルの第４級アンモニウム塩、長鎖モノアルキルジメチルアミン塩等が使用されており、毛髪に対して柔軟性や帯電防止性を付与する効果があった。また、高級アルコールの配合は、製剤に粘性を付与して使用しやすくするとともに、カチオン界面活性剤による皮膚への刺激を緩和してきた。 As the cationic surfactant, for example, a long-chain monoalkyl quaternary ammonium salt, a long-chain monoalkyldimethylamine salt, or the like is used, which has an effect of imparting flexibility and antistatic properties to the hair. . In addition, the addition of higher alcohol has given viscosity to the preparation to make it easy to use, and has eased the irritation to the skin by the cationic surfactant.
しかしながら、高級アルコールの配合によるα−ゲルを活用した製剤では、上述したように外観が白濁となってしまい、透明感の高い基剤は得られていなかった。 However, in the preparation using α-gel by blending of higher alcohol, the appearance becomes cloudy as described above, and a base with high transparency is not obtained.
一方、カチオン界面活性剤に、高分子増粘剤、会合性増粘剤を配合して増粘性を高め、かつ透明感を有する毛髪化粧料も知られているが（例えば、特許文献1〜６参照）、該毛髪化粧料では、増粘剤配合により、使用感触の悪さ（ベタツキ、しっとり感）を生じたり、またカチオン界面活性剤による皮膚への刺激を緩和できなかったりする欠点があった。 On the other hand, hair cosmetics are known in which a cationic surfactant is mixed with a polymer thickener and an associative thickener to increase the viscosity and have a transparent feeling (for example, Patent Documents 1 to 6). The hair cosmetics have the disadvantages of poor use feeling (stickiness, moist feeling) due to the addition of the thickener, and that the irritation to the skin by the cationic surfactant cannot be alleviated.
他の従来技術として、例えば、特開２００５−２７２７８８号公報（特許文献７）に、特定のカチオン界面活性剤と１，２−アルカンジオールを含む組成（ヘアリンス）が実施例７〜１０として具体的に示されているが、これらヘアリンスは、本発明者が追試をしたところ、外観が分離若しくは白濁して、透明感のあるものが得られず、また粘度も低いものであった。また、［００５７］に１，２−ドデカンジオール、第４級アンモニウム塩、油分（シリコーン等）を含むヘアリンスの処方例が記載されているが、１，２−ドデカンジオールと第４級アンモニウム塩との配合比についての記載・示唆はない。また外観（透明系、白濁系）についての記載はなく、特許文献７に記載の毛髪化粧料（毛髪処理剤）は従来より汎用されている一般的な白濁系のヘアリンスを想定しているものと考えるのが妥当である。 As another conventional technique, for example, Japanese Patent Application Laid-Open No. 2005-272788 (Patent Document 7) discloses a composition (hair rinse) containing a specific cationic surfactant and 1,2-alkanediol as Examples 7 to 10. However, these hair rinses were further tested by the present inventor. As a result, the appearance was separated or clouded, and a transparent product was not obtained, and the viscosity was low. [0057] describes an example of hair rinse containing 1,2-dodecanediol, quaternary ammonium salt, oil (silicone, etc.), but 1,2-dodecanediol and quaternary ammonium salt There is no description or suggestion about the compounding ratio. Moreover, there is no description about an external appearance (transparent type, white turbidity type), and the hair cosmetics (hair treatment agent) described in Patent Document 7 assume a general white turbid hair rinse that has been widely used conventionally. It is reasonable to think.
特開２００３−８９６２３号公報（特許文献８）には、第四アンモニウム化合物（例えば、ベヘニルトリメチルアンモニウムクロリド等）と多価アルコール（例えば、１，６−ヘキサンジオール）を併用した毛髪化粧料が示されている（［００５６］の例３）。しかしながら、この例３の組成物の外観は白濁しており、透明感に欠けるものであった。 Japanese Unexamined Patent Publication No. 2003-89623 (Patent Document 8) discloses a hair cosmetic using a quaternary ammonium compound (for example, behenyltrimethylammonium chloride) and a polyhydric alcohol (for example, 1,6-hexanediol). (Example 3 of [0056]). However, the appearance of the composition of Example 3 was cloudy and lacked transparency.
特表平７−５０２５４０号公報（特許文献９）には、１，２−ラウリルジオールと塩化セチルトリメチルアンモニウムを併用した処方例（実施例８）記載されている。しかし、記載された処方量では、透明で粘性ある製剤は得られない。 JP 7-502540 A (Patent Document 9) describes a formulation example (Example 8) in which 1,2-lauryldiol and cetyltrimethylammonium chloride are used in combination. However, the described formulation amount does not provide a clear and viscous formulation.
特開２０００−１７２８３号公報（特許文献１０）には、１，２−ドデカンジオールを含む潤滑油添加剤、潤滑油組成物が示されている。しかし毛髪化粧料の記載はない。 JP 2000-17283 A (Patent Document 10) discloses a lubricating oil additive and a lubricating oil composition containing 1,2-dodecanediol. However, there is no description of hair cosmetics.
国際公開第２００４／１１０３６６号パンフレット（特許文献１１）には、サンスクリーンへの１，２−ラウリルグリコール配合の記載がある。しかし、カチオン活性剤と併用されておらず、使用感触および外観の透明性に劣る。 International Publication No. 2004/110366 pamphlet (Patent Document 11) describes the incorporation of 1,2-lauryl glycol into a sunscreen. However, it is not used in combination with a cationic activator and is inferior in use feeling and appearance transparency.
本発明は、上記事情に鑑みてなされたもので、使用感触、安全性（低刺激性）に優れ、透明感の高い毛髪化粧料を提供することを目的とするものである。 The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a hair cosmetic that is excellent in use feeling and safety (low irritation) and has a high transparency.
上記課題を解決するために本発明は、（Ａ）下記式（I）または（II）で示される長鎖モノアルキル型カチオン界面活性剤の中から選ばれる１種または２種以上を０．１〜１０質量％と、（Ｂ）１，２−ドデカンジオールおよび／または１，２−デカンジオールを２．５〜３０質量％と、（Ｃ）水を残部含み、（Ｂ）成分／（Ａ）成分（質量比）が１．５以上であり、粘度が５００（ｍＰａ・ｓ／３０℃）以上であり、Ｌ値が２０以上である毛髪化粧料を提供する。 In order to solve the above problems, the present invention provides (A) one or more selected from long chain monoalkyl type cationic surfactants represented by the following formula (I) or (II): 10% by mass, (B) 1,2-dodecanediol and / or 1,2-decanediol 2.5-30% by mass, (C) the balance of water, (B) component / (A) Provided is a hair cosmetic composition having a component (mass ratio) of 1.5 or more, a viscosity of 500 (mPa · s / 30 ° C.) or more, and an L value of 20 or more.
〔式（I）、（II）中、Ｒ1は、下記式（III）： [In the formulas (I) and (II), R 1 represents the following formula (III):
{式（III）中、Ｒ5は炭素原子数１４〜２２の直鎖または分岐のアルキル基またはアルキレン基であり、Ａは−ＣＯＮＨ−または−Ｏ−であり、ａは０または１の数であり、Ｂは−ＣＨ2ＣＨ（ＯＨ）ＣＨ2−または−ＣＨ2ＣＨ2ＣＨ2−であり、ｂは０または１の数であり、Ｃは炭素原子数２〜４のアルキレンオキシドであり、ｃは０〜２の数である。}
で示される基を表し；Ｒ2、Ｒ3、Ｒ4はそれぞれ独立に、炭素原子数１〜３のアルキル基またはヒドロキシアルキル基を表し；Ｘ-は無機酸、有機酸、ハロゲン原子の中から選ばれる１種または２種以上のアニオンを表す。〕
{In Formula (III), R 5 is a linear or branched alkyl group or alkylene group having 14 to 22 carbon atoms, A is -CONH- or -O-, and a is a number of 0 or 1. And B is —CH 2 CH (OH) CH 2 — or —CH 2 CH 2 CH 2 —, b is a number of 0 or 1, C is an alkylene oxide having 2 to 4 carbon atoms, c is a number from 0 to 2; }
R 2 , R 3 and R 4 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group; X − represents an inorganic acid, an organic acid or a halogen atom. It represents one or more selected anions. ]
また本発明は、さらに、（Ｄ）シリコーンまたはその誘導体を、シリコーン純分として０．０１〜５質量％、粒子径１００ｎｍ以下のＯ／Ｗエマルションとして含む、上記毛髪化粧料を提供する。 The present invention further provides the above-described hair cosmetic composition comprising (D) silicone or a derivative thereof as an O / W emulsion having a pure silicone content of 0.01 to 5% by mass and a particle size of 100 nm or less.
本発明の毛髪化粧料は、特定のカチオン活性剤と特定の１，２−アルカンジオールおよび水を特定の配合量・配合比で配合することにより、液晶複合体を形成して、透明性と粘性を付与し、カチオン界面活性剤による皮膚への刺激も和らげることができ、使用感触も良好であり、優れたヘアコンディシショニング効果を発揮する。さらに、特定粒子径以下のシリコーン類をＯ／Ｗマイクロエマルションにて配合することで使用感触をより一層向上することができた。 The hair cosmetic composition of the present invention forms a liquid crystal composite by blending a specific cationic activator, a specific 1,2-alkanediol and water in a specific blending amount and blending ratio, and has transparency and viscosity. And can also reduce irritation to the skin by the cationic surfactant, has a good feeling in use, and exhibits an excellent hair conditioning effect. Furthermore, the feeling of use could be further improved by blending silicones having a specific particle size or less in an O / W microemulsion.
以下、本発明について詳述する。 Hereinafter, the present invention will be described in detail.
本発明における（Ａ）成分としてのカチオン活性剤は、下記式（I）または（II）で示される長鎖モノアルキル型カチオン界面活性剤である。 The cationic surfactant as the component (A) in the present invention is a long-chain monoalkyl type cationic surfactant represented by the following formula (I) or (II).
上記式（I）、（II）中、各置換基は以下の意味を示す。
Ｒ1は、下記式（III）で示される基を表す。
In the above formulas (I) and (II), each substituent has the following meaning.
R 1 represents a group represented by the following formula (III).
〔上記式（III）中、Ｒ5は炭素原子数１４〜２２の直鎖または分岐のアルキル基またはアルキレン基であり、Ａは−ＣＯＮＨ−または−Ｏ−であり、ａは０または１の数であり、Ｂは−ＣＨ2ＣＨ（ＯＨ）ＣＨ2−または−ＣＨ2ＣＨ2ＣＨ2−であり、ｂは０または１の数であり、Ｃは炭素原子数２〜４のアルキレンオキシドであり、ｃは０〜２の数である。〕 [In the above formula (III), R 5 is a linear or branched alkyl group or alkylene group having 14 to 22 carbon atoms, A is —CONH— or —O—, and a is a number of 0 or 1. B is —CH 2 CH (OH) CH 2 — or —CH 2 CH 2 CH 2 —, b is a number of 0 or 1, and C is an alkylene oxide having 2 to 4 carbon atoms. , C is a number from 0 to 2. ]
Ｒ2、Ｒ3、Ｒ4はそれぞれ独立に、炭素原子数１〜３のアルキル基またはヒドロキシアルキル基を表す。 R 2 , R 3 and R 4 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group.
Ｘ-は無機酸、有機酸、ハロゲン原子の中から選ばれる１種または２種以上のアニオンを表す。無機酸としては、例えば塩酸、硫酸、硝酸、炭酸、メトサルフェート等が挙げられる。有機酸としては、例えばグルタミン酸、ピロリドンカルボン酸、コハク酸、リンゴ酸、酒石酸、ヒドロキシエタンジホスホン酸、エデト酸、安息香酸等が挙げられる。ハロゲン原子としては塩素、臭素、ヨウ素、フッ素が挙げられる。 X − represents one or more anions selected from inorganic acids, organic acids, and halogen atoms. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, nitric acid, carbonic acid, methosulphate and the like. Examples of the organic acid include glutamic acid, pyrrolidone carboxylic acid, succinic acid, malic acid, tartaric acid, hydroxyethanediphosphonic acid, edetic acid, benzoic acid and the like. Examples of the halogen atom include chlorine, bromine, iodine, and fluorine.
（Ａ）成分としては具体的には以下の化合物が例示される。ただしこれら例示に限定されるものでない。 Specific examples of the component (A) include the following compounds. However, it is not limited to these examples.
（１）塩化ベヘニルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化セトステアリルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、ステアリルトリメチルアンモニウムメトサルフェート、ステアリルトリメチルアンモニウム−グルタミン酸塩、ベヘニルトリメチルアンモニウム−乳酸塩、塩化ステアロキシプロピレングリコール（以下、「プロピレングリコール」を「ＰＧ」とも記す）トリメチルアンモニウム、塩化ステアロキシプロピルトリメチルアンモニウム、塩化ベヘロキシプロピルトリメチルアンモニウム、 (1) behenyltrimethylammonium chloride, stearyltrimethylammonium chloride, cetyltrimethylammonium chloride, cetostearyltrimethylammonium chloride, stearyltrimethylammonium bromide, stearyltrimethylammonium methosulfate, stearyltrimethylammonium glutamate, behenyltrimethylammonium lactate, Stearoxypropylene glycol chloride (hereinafter “propylene glycol” is also referred to as “PG”) trimethylammonium, stearoxypropyltrimethylammonium chloride, beheroxypropyltrimethylammonium chloride,
（２）ステアラミドプロピルジメチルアミン−グルタミン酸塩〔＝ステアリン酸ジメチルアミドプロピルアミン−グルタミン酸塩〕、ステアラミドプロピルジメチルアミン−塩酸塩、ステアラミドプロピルジメチルアミン−コハク酸塩、ベヘナミドプロピルジメチルアミン−乳酸塩、ステアロキシプロピルジメチルアミン−リンゴ酸塩、セトステアロキシＰＧジメチルアミン−コハク酸塩、ステアロキシＰＧジメチルアミン−グルタミン酸塩、ベヘロキシＰＧジメチルアミン−塩酸塩。 (2) stearamidepropyldimethylamine-glutamate [= stearic acid dimethylamidopropylamine-glutamate], stearamidepropyldimethylamine-hydrochloride, stearamidepropyldimethylamine-succinate, behenamidopropyldimethylamine- Lactate, stearoxypropyldimethylamine-malate, cetosteoxyxydimethylamine-succinate, stearoxyPGdimethylamine-glutamate, beheroxyPGdimethylamine-hydrochloride.
上記式（III）中、Ｒ5のアルキル鎖、アルキレン鎖の鎖長が短ければ、皮膚への刺激などの安全性が悪化し、一方、鎖長が長ければ毛髪化粧料の透明性および粘性が失われる。本発明ではＲ5のアルキル鎖、アルキレン鎖は、炭素原子数１４〜２２であり、好ましくは１８〜２２であり、中でも直鎖状の炭素原子数１８（Ｃ18）である場合が最も好ましい。Ｒ5がＣ18のアルキル鎖、アルキレン鎖を示す（Ａ）成分としては、例えば、塩化ステアリルトリメチルアンモニウム、ステアラミドプロピルジメチルアミン−グルタミン酸塩、ステアロキシプロピルジメチルアミン−コハク酸塩、ステアリルＰＧジメチルアミン−乳酸塩等が好適例として挙げられる。ただしこれら例示に限定されるものでない。 In the above formula (III), if the chain length of the alkyl chain or alkylene chain of R 5 is short, the safety such as irritation to the skin is deteriorated. On the other hand, if the chain length is long, the transparency and viscosity of the hair cosmetics are reduced. Lost. In the present invention, the alkyl chain and alkylene chain of R 5 have 14 to 22 carbon atoms, preferably 18 to 22 carbon atoms, and most preferably a linear carbon atom number 18 (C 18 ). Examples of the component (A) in which R 5 represents a C 18 alkyl chain or alkylene chain include, for example, stearyltrimethylammonium chloride, stearamidepropyldimethylamine-glutamate, stearoxypropyldimethylamine-succinate, stearyl PGdimethylamine -Lactate is a suitable example. However, it is not limited to these examples.
本発明の毛髪化粧料中の（Ａ）成分の配合量は０．１〜１０％質量％であり、好ましくは、０．２〜５質量％である。０．１質量％未満では、使用感触が悪化するとともに、液の粘性も下がるため、好ましくない。１０質量％を超えると、皮膚への刺激が強くなり好ましくない。 The blending amount of the component (A) in the hair cosmetic composition of the present invention is 0.1 to 10% by mass, preferably 0.2 to 5% by mass. If it is less than 0.1% by mass, the feeling in use is deteriorated and the viscosity of the liquid is also lowered. If it exceeds 10% by mass, the skin irritation becomes strong, which is not preferable.
本発明の（Ｂ）成分としては、１，２−アルカンジオール中、１，２−ドデカンジオールおよび／または１，２−デカンジオールが用いられる。 As the component (B) of the present invention, 1,2-dodecanediol and / or 1,2-decanediol is used in 1,2-alkanediol.
１，２−アルカンジオールは、１，２−アルキレングリコールとも呼ばれ、一般に化粧料に用いられるものでは、アルキル鎖として、炭素原子数３〜２２のアルカン（アルキレン）が直鎖、環状、または分岐鎖となっている。これらのうち、炭素原子数８以下のものは浴剤若しくは防腐剤・防腐助剤として、炭素原子数１０以上のものは乳化助剤若しくは洗浄剤の増粘剤として配合することが知られている。しかし、炭素原子数８以下のものでは皮膚刺激性が強く、粘性も低くなり、好ましくない。また炭素原子数１４以上のものでは、外観が白濁になり好ましくない。本発明では、皮膚低刺激性、外観の透明性等の点から、炭素原子数１０（Ｃ10）である１，２−デカンジオール、若しくは炭素原子数１２（Ｃ12）である１，２−ドデカンジオール（ラウリルグリコール）を用いる。 1,2-Alkanediol is also referred to as 1,2-alkylene glycol, and generally used in cosmetics, an alkane (alkylene) having 3 to 22 carbon atoms is linear, cyclic or branched as an alkyl chain. It is a chain. Among these, those having 8 or less carbon atoms are known to be blended as bathing agents or preservatives / preservatives, and those having 10 or more carbon atoms are blended as emulsifying aids or thickeners for cleaning agents. . However, carbon atoms having 8 or less carbon atoms are not preferable because they have strong skin irritation and low viscosity. A carbon atom having 14 or more carbon atoms is not preferable because the appearance becomes cloudy. In the present invention, 1,2-decanediol having 10 carbon atoms (C 10 ), or 1,2- carbon atoms having 12 carbon atoms (C 12 ) from the viewpoints of low skin irritation, appearance transparency and the like. Dodecanediol (lauryl glycol) is used.
本発明の毛髪化粧料中の（Ｂ）成分の配合量は２．５〜３０質量％であり、好ましくは、３〜２０質量％である。２．５質量％未満では、皮膚への刺激性が増すとともに粘性や透明性を付与することができず、一方、３０質量％を超す場合には透明性が低下するため、好ましくない。 The compounding quantity of (B) component in the hair cosmetics of this invention is 2.5-30 mass%, Preferably, it is 3-20 mass%. If the amount is less than 2.5% by mass, the irritation to the skin increases and viscosity and transparency cannot be imparted. On the other hand, if it exceeds 30% by mass, the transparency decreases, which is not preferable.
本発明では、（Ｂ）成分／（Ａ）成分（質量比）が１．５以上である。上記配合比（質量比）が１．５未満では、粘性を付与することができず、また外観の透明性・均質性にも劣るため、好ましくない。なお上記配合比（質量比）の上限値は特に限定されるものでないが、液晶の分散安定性の点から４０以下程度とするのが望ましい。 In this invention, (B) component / (A) component (mass ratio) is 1.5 or more. A blending ratio (mass ratio) of less than 1.5 is not preferable because viscosity cannot be imparted and the transparency and homogeneity of the appearance are poor. The upper limit of the blending ratio (mass ratio) is not particularly limited, but is preferably about 40 or less from the viewpoint of liquid crystal dispersion stability.
（Ｃ）成分としての水は、本発明化粧料中に残部配合される。 The remaining amount of water as component (C) is blended in the cosmetic of the present invention.
本発明毛髪化粧料は、粘度が５００（ｍＰａ・ｓ／３０℃。Ｂ型粘度計）以上のゲル状をなす。粘度の上限値は特に限定されるものでないが、手にとったときの使いやすさ等の点から５００，０００（ｍＰａ・ｓ／３０℃）以下程度とするのが好ましい。 The hair cosmetic composition of the present invention forms a gel having a viscosity of 500 (mPa · s / 30 ° C., B-type viscometer) or more. The upper limit of the viscosity is not particularly limited, but is preferably about 500,000 (mPa · s / 30 ° C.) or less from the viewpoint of ease of use when taken in hand.
本発明毛髪化粧料は、透明性の指標であるＬ値が２０以上であり、好ましくは４０以上、特に好ましくは６０以上である。なお本発明で「Ｌ値」とは、毛髪化粧料を光路長１０ｍｍの石英セルに所定量入れて、透過型色差測定計を用いて波長３８０〜７７０ｎｍの白色光を透過させて測定した値をいう。 The hair cosmetic composition of the present invention has an L value as an index of transparency of 20 or more, preferably 40 or more, particularly preferably 60 or more. In the present invention, the “L value” means a value measured by putting a predetermined amount of hair cosmetic into a quartz cell having an optical path length of 10 mm and transmitting white light having a wavelength of 380 to 770 nm using a transmission color difference meter. Say.
本発明化粧料は上記（Ａ）〜（Ｃ）成分の他に、使用感向上の点から、所望によりさらに（Ｄ）成分としてシリコーンまたはシリコーン誘導体を配合してもよい。 In addition to the components (A) to (C), the cosmetic of the present invention may further contain silicone or a silicone derivative as the component (D) as desired from the viewpoint of improving the feeling of use.
（Ｄ）成分としてのシリコーンまたはシリコーン誘導体は、具体的には、トリシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロペンタシロキサン等のシクロメチコン、カプリリルメチコンなどの揮発性シリコーンオイル、ジメチコン、ジメチコノール、側鎖変性タイプ・直鎖ＡＢＮタイプ等のポリエーテル変性シリコーン、アモジメチコン、アミノプロピルメチコン、フェニル変性シリコーン、プロピルシルセスキオキサン、アルキル変性シリコーン、シリコーンレジン、メチルハイドロジェンシリコーンなどの変性シリコーン、アルキル変性、アルコキシ変性、ポリアミド変性、ポリエーテル変性などによるシリコーンレジン、ジメチコンクロスポリマー、（ジメチコン／ビニルジメチコン）クロスポリマー等のシリコーンエラストマー等が挙げられるが、特にジメチコン、アミノプロピルメチコンが好ましく用いられる。 Specific examples of the silicone or silicone derivative as component (D) include cyclosiloxanes such as trisiloxane, decamethylcyclopentasiloxane and dodecamethylcyclopentasiloxane, volatile silicone oils such as caprylylmethicone, dimethicone, dimethiconol, Side chain modified type, straight chain ABN type, etc., polyether modified silicone, amodimethicone, aminopropylmethicone, phenyl modified silicone, propylsilsesquioxane, alkyl modified silicone, silicone resin, modified silicone such as methyl hydrogen silicone, alkyl Silica such as silicone resin, dimethicone crosspolymer, (dimethicone / vinyl dimethicone) crosspolymer by modification, alkoxy modification, polyamide modification, polyether modification, etc. Over emissions elastomers and the like, but in particular dimethicone, aminopropyl methicone are preferably used.
上記に挙げたシリコーンまたはシリコーン誘導体のうち、揮発性シリコーンを除いて、重合度や変性率に特に制限はない。 Among the silicones or silicone derivatives listed above, the degree of polymerization and the modification rate are not particularly limited except for volatile silicones.
（Ｄ）成分は、粒子径１００ｎｍ以下のＯ／Ｗエマルションとして配合することが好ましい。粒子径１００ｎｍ以下でないと、特に（Ｄ）成分の配合量が０．５質量％を超える場合、外観の透明性が著しく損なわれる。またＯ／Ｗエマルションとして配合することで透明性をより効果的に高めることができる。粒子径１００ｎｍ以下の（Ｄ）成分を含むＯ／Ｗエマルションは商業的に入手することができ、例えば、「ＢＹ２２−０８０」〔東レ・ダウコーニング（株）製。２００ｃｓのジメチコンを２０質量％含有する透明タイプ（粒子径約６０ｎｍ）のＯ／Ｗエマルション〕、「ＢＹ２２−０７９」〔東レ・ダウコーニング（株）製。アモジメチコンを１４質量％含有する透明タイプ（粒子径約５０ｎｍ）のＯ／Ｗエマルション〕、「ＦＺ−４６７１」〔東レ・ダウコーニング（株）製。（アミノエチルアミノプロピルメチコン／ジメチコン）コポリマーを３２質量％含有する透明タイプ（粒子径約５０ｎｍ）のＯ／Ｗエマルション〕、「ＸＳ６５−Ｂ８１２４」〔モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製、（アミノエチルアミノプロピルメチコン／ジメチコン）コポリマーを２０質量％含有する透明タイプ（粒子径約５０ｎｍ）のＯ／Ｗエマルション〕、「ＳＭＥ２５３」〔モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社製、アモジメチコンを２０質量％含有する透明タイプ（粒子径約６０ｎｍ）のＯ／Ｗエマルション〕等として市販され、これらを好適に用いることができる。 The component (D) is preferably blended as an O / W emulsion having a particle size of 100 nm or less. If the particle diameter is not 100 nm or less, particularly when the blending amount of the component (D) exceeds 0.5% by mass, the transparency of the appearance is significantly impaired. Moreover, transparency can be more effectively improved by mix | blending as O / W emulsion. An O / W emulsion containing a component (D) having a particle size of 100 nm or less can be obtained commercially, for example, “BY22-080” [manufactured by Toray Dow Corning Co., Ltd. Transparent type O / W emulsion containing 20% by mass of 200 cs dimethicone (particle diameter of about 60 nm)], “BY22-079” [manufactured by Toray Dow Corning Co., Ltd. Transparent type O / W emulsion containing 14% by mass of amodimethicone (particle size of about 50 nm)], “FZ-4671” [manufactured by Toray Dow Corning Co., Ltd. (O / W emulsion of transparent type (particle diameter of about 50 nm) containing 32% by mass of aminoethylaminopropylmethicone / dimethicone) copolymer], “XS65-B8124” [Momentive Performance Materials Japan GK, Transparent type O / W emulsion containing 20% by mass of aminoethylaminopropylmethicone / dimethicone) copolymer (particle diameter of about 50 nm)], “SME253” [Momotivational Performance Materials Japan G.K., 20 amodimethicone A transparent type (O / W emulsion having a particle size of about 60 nm) containing mass%] is commercially available, and these can be used preferably.
（Ｄ）成分を配合する場合、配合量は化粧料全量中にシリコーン純分として０．０１〜５質量％とするのが好ましく、より好ましくは０．０５〜３質量％である。配合量が少なすぎると、すすぎ時のなめらかさ、乾燥後のなめらかさに欠ける傾向があり、配合量が多すぎると、透明性および粘性を低下させ、すすぎ時のなめらかさに欠ける傾向がある。 (D) When mix | blending a component, it is preferable that a compounding quantity shall be 0.01-5 mass% as a silicone pure part in cosmetics whole quantity, More preferably, it is 0.05-3 mass%. When the blending amount is too small, the smoothness at the time of rinsing and the smoothness after drying tend to be lacking. When the blending amount is too large, the transparency and the viscosity tend to be lowered, and the smoothness at the rinsing tends to be lacking.
本発明の毛髪化粧料には上記の成分の他にさらに、目的に応じて本発明の効果を損なわない量的、質的範囲内で、その他の成分を任意に配合することができる。このような成分として、例えば以下の成分が例示される。ただしこれら例示に限定されるものでない。 In addition to the above-described components, the hair cosmetic of the present invention may further optionally contain other components within a quantitative and qualitative range that does not impair the effects of the present invention. Examples of such components include the following components. However, it is not limited to these examples.
芳香族アルコールとして、例えば、フェノキシエタノール、ベンジルアルコール、ベンジルオキシエタノール、クレゾール、ｐ−クロロフェノール、ｐ−クロロ−ｍ−キシレノール、フェネチルアルコール、フェニルプロピルアルコール、ｐ−ｔｅｒｔ−ブチルフェノール、カテコール、ヒドロキノン、フェニルエチルアルコール、レゾルシノール、フェノール等が挙げられる。 Examples of aromatic alcohols include phenoxyethanol, benzyl alcohol, benzyloxyethanol, cresol, p-chlorophenol, p-chloro-m-xylenol, phenethyl alcohol, phenylpropyl alcohol, p-tert-butylphenol, catechol, hydroquinone, and phenylethyl. Examples include alcohol, resorcinol, and phenol.
保湿剤として、例えば、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、トリグリセリン、テトラグリセリン、１，３−ブチレングリコール、１，４−ブチレングリコール、キシリトール、ソルビトール、マルチトール、グルコース、マルトース、ショ糖、フラクトース、マルトトリオース、スレイトール、エリスリトール、デンプン、分解糖還元アルコール等の単糖、２糖若しくはオリゴ糖およびそれらの誘導体、コンドロイチン硫酸、ヒアルロン酸、ムコイチン硫酸、カロニン酸、アテロコラーゲン、コレステリル−１２−ヒドロキシステアレート、乳酸ナトリウム、ｄｌ−ピロリドンカルボン酸塩、可溶性コラーゲン、ジグリセリン（ＥＯ）ＰＯ付加物、イサヨイバラ抽出物、セイヨウノコギリソウ抽出物、メリロート抽出物、イソプレングリコール、ポリグルタミン酸ナトリウム、アルキレンオキシド誘導体〔例えばＰＯＥ（１４）ＰＯＰ（７）ジメチルエーテル、ＰＯＥ（１０）ＰＯＰ（１０）ジメチルエーテル、ＰＯＥ（６）ＰＯＰ（１４）ジメチルエーテル、ＰＯＥ（２５）ＰＯＰ（４０）ジメチルエーテル、ＰＯＥ（２５）ＰＯＰ（２５）ジメチルエーテル、ＰＯＥ（７）ＰＯＰ（１２）ジメチルエーテル、ＰＯＥ（２２）ＰＯＰ（４０）ジメチルエーテル、ＰＯＥ（３５）ＰＯＰ（４０）ジメチルエーテル、ＰＯＥ（４５）ＰＯＰ（３４）ジメチルエーテル、ＰＯＥ（５０）ＰＯＰ（４０）ジメチルエーテル、ＰＯＥ（５５）ＰＯＰ（３０）ジメチルエーテル、ＰＯＥ（３０）ＰＯＰ（３４）ジメチルエーテル、ＰＯＥ（２５）ＰＯＰ（３０）ジメチルエーテル、ＰＯＥ（２７）ＰＯＰ（１４）ジメチルエーテル、ＰＯＥ（５５）ＰＯＰ（２８）ジメチルエーテル、ＰＯＥ（３６）ＰＯＰ（４１）ジメチルエーテル、ＰＯＥ（７）ＰＯＰ（１２）ジメチルエーテル、ＰＯＥ（１７）ＰＯＰ（４）ジメチルエーテル、ＰＯＥ（１４）ＰＯＢ（７）ジメチルエーテル、ＰＯＥ（１０）ＰＯＰ（１０）ジエチルエーテル、ＰＯＥ（１０）ＰＯＰ（１０）ジプロピルエーテル、ＰＯＥ（１０）ＰＯＰ（１０）ジブチルエーテル等〕などが挙げられる。なお、ＰＯＥ、ＰＯＰ、ＰＯＢは、それぞれポリオキシエチレン、ポリオキシプロピレン、ポリオキシブチレンの略である。 Examples of humectants include ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, triglycerin, tetraglycerin, 1,3-butylene glycol, 1,4-butylene glycol, xylitol, sorbitol, and maltitol. , Glucose, maltose, sucrose, fructose, maltotriose, threitol, erythritol, starch, decomposed sugar, reduced sugar, etc. monosaccharide, disaccharide or oligosaccharide and their derivatives, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, carolinic acid , Atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, dl-pyrrolidone carboxylate, soluble collagen, diglycerin (EO) PO adduct, Saoyara rose extract, Achillea millefolium extract, Merirot extract, isoprene glycol, sodium polyglutamate, alkylene oxide derivatives [eg POE (14) POP (7) dimethyl ether, POE (10) POP (10) dimethyl ether, POE (6) POP (14) Dimethyl ether, POE (25) POP (40) Dimethyl ether, POE (25) POP (25) Dimethyl ether, POE (7) POP (12) Dimethyl ether, POE (22) POP (40) Dimethyl ether, POE (35) POP (40) Dimethyl ether, POE (45) POP (34) Dimethyl ether, POE (50) POP (40) Dimethyl ether, POE (55) POP (30) Dimethyl ether, POE (30) PO (34) Dimethyl ether, POE (25) POP (30) Dimethyl ether, POE (27) POP (14) Dimethyl ether, POE (55) POP (28) Dimethyl ether, POE (36) POP (41) Dimethyl ether, POE (7) POP (12) Dimethyl ether, POE (17) POP (4) Dimethyl ether, POE (14) POB (7) Dimethyl ether, POE (10) POP (10) Diethyl ether, POE (10) POP (10) Dipropyl ether, POE ( 10) POP (10) dibutyl ether, etc.]. POE, POP, and POB are abbreviations for polyoxyethylene, polyoxypropylene, and polyoxybutylene, respectively.
また、レシチン、加水分解タンパク質とその誘導体、アルギニン、グリシン、アラニン、セリン、プロリン、ロイシン、イソロイシン、トリメチルグリシン等のアミノ酸、ビタミン類、セレシン、フィトステロール誘導体、ヒドロキシエチル尿素等の毛髪補修成分を配合することにより、さらに毛髪の修復・保護効果に優れ、且つその効果が長時間持続する毛髪化粧料が得られる。 In addition, lecithin, hydrolyzed protein and its derivatives, amino acids such as arginine, glycine, alanine, serine, proline, leucine, isoleucine, and trimethylglycine, vitamins, ceresin, phytosterol derivatives, hair repair ingredients such as hydroxyethylurea As a result, it is possible to obtain a hair cosmetic that is further excellent in the effect of repairing and protecting hair, and that the effect lasts for a long time.
また、流動パラフィン、スクワラン、ラノリン誘導体、各種エステル油、各種エーテル油、アボガド油、ツバキ油、パーム油、牛脂、ホホバ油、ポリアルキレングリコールポリエーテルおよびそのカルボン酸オリゴエステル化合物、テルペン系炭化水素油等の油分、水溶性または油溶性の紫外線吸収剤、酸化チタン、酸化亜鉛等の紫外線散乱剤、カオリン、タルク、シリカ、ＰＭＭＡ、ジンクピリチオン等の水不溶性粉末、アクリル系樹脂、シリコーン樹脂、ポリビニルピロリドン等の樹脂類、大豆タンパク質、ゼラチン、コラーゲン、絹フィブロイン、エラスチン等のタンパク質またはタンパク質分解物、動植物からの抽出液、エチルパラベン、ブチルパラベン、メチルクロロイソチアゾリノン等の防腐剤、ビオチン、パントテン酸誘導体等の賦活剤、γ−オリザノール、デキストラン硫酸ナトリウム、ビタミンＥ誘導体、ニコチン酸誘導体、メントール等の血行促進剤、硫黄、チアントール等の抗脂漏剤、エタノール、イソプロパノール、テトラクロロジフルオロエタン等の希釈剤、ヒドロキシエチルセルロース、ヒドロキシプロピルメチルセルロース、グアガム、ローカストビーンガム、ＰＥＧ−９０Ｍ等のノニオン性高分子、カルボキシビニルポリマー等のアニオン性高分子、カチオン化セルロース、カチオン化グアガム、ポリクオタニウム−７等のカチオン性高分子、ポリクオタニウム−３９等の両性高分子、（ＰＥＧ−２４０／デシルテトラデセス−２０／ＨＤＩ）コポリマー、ステアロキシヒドロキシプロピルメチルセルロース等の会合性増粘剤、薬剤、香料、色剤、界面活性剤等を必要に応じて敵宜配合してもよい。 Liquid paraffin, squalane, lanolin derivatives, various ester oils, various ether oils, avocado oil, camellia oil, palm oil, beef tallow, jojoba oil, polyalkylene glycol polyether and its carboxylic acid oligoester compound, terpene hydrocarbon oil Etc., water-soluble or oil-soluble UV absorbers, UV scattering agents such as titanium oxide and zinc oxide, water-insoluble powders such as kaolin, talc, silica, PMMA, zinc pyrithione, acrylic resins, silicone resins, polyvinylpyrrolidone, etc. Resins, soy protein, gelatin, collagen, silk fibroin, elastin and other proteins or protein degradation products, extracts from animals and plants, preservatives such as ethylparaben, butylparaben, methylchloroisothiazolinone, biotin, pantothenic acid derivatives Activators, γ-oryzanol, sodium dextran sulfate, vitamin E derivatives, nicotinic acid derivatives, blood flow promoters such as menthol, antiseborrheic agents such as sulfur and thianthol, diluents such as ethanol, isopropanol and tetrachlorodifluoroethane, hydroxy Nonionic polymers such as ethyl cellulose, hydroxypropyl methylcellulose, guar gum, locust bean gum, PEG-90M, anionic polymers such as carboxyvinyl polymer, cationic polymers such as cationized cellulose, cationized guar gum, polyquaternium-7, Amphoteric polymers such as polyquaternium-39, associative thickeners such as (PEG-240 / decyltetradeceth-20 / HDI) copolymer, stearoxyhydroxypropylmethylcellulose, drugs, fragrances, colorants, A surfactant or the like may be blended ad hoc as necessary.
本発明毛髪化粧料の剤型及び使用方法は本発明の効果が損なわれない限り特に制限されない。また、製造方法は、特に限定されるものでなく、例えば、６０〜８０℃程度に加温した水に、他配合成分を順次添加しながら撹拌混合し、常温まで冷却する等、常法により得ることができるが、これら例示の製法に限定されるものでない。 The dosage form and use method of the hair cosmetic composition of the present invention are not particularly limited as long as the effects of the present invention are not impaired. Moreover, a manufacturing method is not specifically limited, For example, it stirs and mixes in water heated at about 60-80 degreeC, adding another compounding ingredient one by one, and cools to normal temperature etc., and obtains it by a conventional method. However, it is not limited to these exemplary manufacturing methods.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック等と呼ばれている毛髪処理剤、毛髪化粧料に適用可能である。また、その使用形態は、毛髪に塗布し全体によくなじませた後にすすぎ流すものや、洗い流さないもの等、いずれも含み得る。 The hair cosmetic composition of the present invention can be applied to hair treatment agents and hair cosmetic compositions called hair rinses, hair conditioners, hair treatments, hair packs and the like. Moreover, the usage form may include any of those that are rinsed after being applied to the hair and thoroughly applied to the whole, and those that are not washed away.
以下に実施例を挙げて本発明をさらに具体的に説明するが、本発明はこれによってなんら限定されるものではない。配合量は特記しない限りすべて質量％（実分）である。 Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited thereto. Unless otherwise specified, the blending amount is mass% (actual amount).
下記表１〜４に示す組成のヘアトリートメント（試料）を常法により調製し、これら試料を用いて、下記に示す方法により、粘度、外観（透明性および分離の有無）、使用感触（すすぎ時のなめらかさ、乾燥後のなめらかさ）を評価した。なお、使用感触（すすぎ時のなめらかさ、乾燥後のなめらかさ）、皮膚刺激性の評価に際しては、下記コントロール（対照試料）を比較基準とした。 Hair treatments (samples) having the compositions shown in Tables 1 to 4 below are prepared by a conventional method, and using these samples, the viscosity, appearance (transparency and presence / absence of separation), and feeling of use (when rinsing are performed) Smoothness after drying, and smoothness after drying). In addition, the following control (control sample) was used as a reference for evaluation of the feeling of use (smoothness during rinsing, smoothness after drying) and skin irritation.
〈コントロール（対照試料）〉
塩化ステアリルトリメチルアンモニウム １．０質量％
ステアリルアルコール ３．５質量％
グルタミン酸 ０．０１質量％
イオン交換水 残 余
（調製方法）
７５℃に温めた水を撹拌しながら、水以外の組成物を添加・混合した後、常温まで冷却した。
<Control (control sample)>
Stearyltrimethylammonium chloride 1.0 mass%
Stearyl alcohol 3.5% by mass
Glutamic acid 0.01% by mass
Ion-exchanged water residue (preparation method)
While stirring water heated to 75 ° C., a composition other than water was added and mixed, and then cooled to room temperature.
［粘度］
試料を調製して翌日、３０℃に保温した後に、Ｂ型若しくはＢＬ型回転粘度計（芝浦システム（株）製）にて、１分間回転した後の粘度値（ｍＰａ・ｓ）を記録した。回転数は、Ｂ型の場合１２ｒｐｍ、ＢＬ型の場合６ｒｐｍとした。
[viscosity]
The sample was prepared and kept at 30 ° C. the next day, and then the viscosity value (mPa · s) after rotating for 1 minute with a B-type or BL-type rotational viscometer (manufactured by Shibaura System Co., Ltd.) was recorded. The number of rotations was 12 rpm for the B type and 6 rpm for the BL type.
［外観］
被験試料を透明ガラス容器にて３５℃で１ヶ月保存した後、視感判定にて層分離の有無を判別するとともに、透明性をＬ値により判断した。
層分離の有無は、外観の透明性の均一さおよび全体の粘性の均一さにより判断した。
Ｌ値は、上記１ヶ月保存後の試料を、光路長１０ｍｍの石英セルに所定量入れて、透過型色差測定計（「分光式色差計ＳＥ−２０００」；日本電色工業（株）製。波長３８０〜７７０ｎｍの光を透過）で測色することにより求めた。判定基準は以下の通りである。
（評価）
◎： 外観が１層であり、Ｌ値が６０以上である
○： 外観が１層であり、Ｌ値が４０以上６０未満である
○△： 外観が１層であり、Ｌ値が２０以上４０未満である
×： 外観が２層以上に分離している、若しくはＬ値が２０未満である
[appearance]
After storing the test sample in a transparent glass container at 35 ° C. for 1 month, the presence or absence of layer separation was determined by visual judgment, and the transparency was determined by the L value.
The presence or absence of layer separation was judged by the uniformity of the transparency of the appearance and the uniformity of the overall viscosity.
For the L value, a predetermined amount of the sample stored for 1 month is put in a quartz cell having an optical path length of 10 mm, and a transmission color difference meter (“spectral color difference meter SE-2000”; manufactured by Nippon Denshoku Industries Co., Ltd.). It was determined by measuring the color by transmitting light having a wavelength of 380 to 770 nm. Judgment criteria are as follows.
(Evaluation)
◎: Appearance is one layer, L value is 60 or more ○: Appearance is one layer, L value is 40 or more and less than 60 ○ △: Appearance is one layer, L value is 20 or more and 40 Less than x: Appearance is separated into two or more layers, or L value is less than 20
［使用感触（すすぎ時のなめらかさ）］
シャンプー（洗浄剤）で洗髪後、被験試料の実使用（＝アフターシャンプー）テストにて、専門パネル（１０名）がすすぎ時の髪のなめらかさを、コントロール（対照試料）との比較により評価した。判定基準は以下の通りである。
（判定）
◎： １０名中８名以上が、被検試料の方がなめらかと回答した。
○： １０名中５〜７名が、被検試料の方がなめらかと回答した。
△： １０名中３〜６名が、被検試料の方がなめらかと回答した。
×： １０名中２名以下が、被検試料の方がなめらかと回答した。
[Usage feel (smoothness when rinsing)]
After washing the hair with shampoo (cleaning agent), the smoothness of the hair when rinsing was performed by a specialized panel (10 persons) was evaluated by comparison with the control (control sample) in the actual use (= after shampoo) test of the test sample. . Judgment criteria are as follows.
(Judgment)
A: More than 8 out of 10 responded that the test sample was smoother.
○: 5 to 7 out of 10 responded that the test sample was smoother.
Δ: 3 to 6 out of 10 responded that the test sample was smoother.
X: 2 or less of 10 responded that the test sample was smoother.
［使用感触（乾燥後のなめらか）］
シャンプー（洗浄剤）で洗髪後、被験試料の実使用（＝アフターシャンプー）テストにて、専門パネル（１０名）が乾燥後の髪のなめらかさを、コントロール（対照試料）との比較により評価した。判定基準は以下の通りである。
（判定）
◎： １０名中８名以上が、被検試料の方がなめらかと回答した。
○： １０名中５〜７名が、被検試料の方がなめらかと回答した。
△： １０名中３〜６名が、被検試料の方がなめらかと回答した。
×： １０名中２名以下が、被検試料の方がなめらかと回答した。
[Usage feel (smooth after drying)]
After washing the hair with shampoo (cleaning agent), in the actual use (= after shampoo) test of the test sample, the expert panel (10 persons) evaluated the smoothness of the hair after drying by comparing with the control (control sample). . Judgment criteria are as follows.
(Judgment)
A: More than 8 out of 10 responded that the test sample was smoother.
○: 5 to 7 out of 10 responded that the test sample was smoother.
Δ: 3 to 6 out of 10 responded that the test sample was smoother.
X: 2 or less of 10 responded that the test sample was smoother.
［皮膚への刺激］
被験試料を前腕部に塗布した後、塗布部位を閉塞した。２４時間後に閉塞を解除して、２時間後に皮膚の状態に問題（赤み、ひりつき、肌荒れ）が生じていなかったかどうかを、専門パネル（１０名）がコントロール（対照試料）との比較により評価した。判定基準は以下の通りである。
（判定）
◎： １０名中９名以上が、被検試料の方が皮膚の状態が良好であったと回答した。
○： １０名中７〜８名が、被検試料の方が皮膚の状態が良好であったと回答した。
△： １０名中５〜６名が、被検試料の方が皮膚の状態が良好であったと回答した。
×： １０名中２名以下が、被検試料の方が皮膚の状態が良好であったと回答した。
[Skin irritation]
After applying the test sample to the forearm, the application site was occluded. After 24 hours, the occlusion was released, and after 2 hours, the specialist panel (10 persons) evaluated the skin condition (redness, tingling, rough skin) by comparison with the control (control sample). did. Judgment criteria are as follows.
(Judgment)
A: Nine or more of 10 responded that the test sample had a better skin condition.
○: 7 to 8 out of 10 responded that the test sample had better skin condition.
Δ: 5 to 6 out of 10 responded that the test sample had better skin condition.
X: 2 or less out of 10 responded that the test sample had better skin condition.
（実施例１〜４、比較例１〜３） (Examples 1-4, Comparative Examples 1-3)
表１に示す結果から明らかなように、１，２−ドデカンジオールに、長鎖モノアルキル型カチオン界面活性剤を組み合せた実施例１〜４は、本願発明効果が得られたのに対し、１，２−ドデカンジオールに他の界面活性剤等を組み合せた比較例１〜３では、本願発明効果が得られなかった。 As is clear from the results shown in Table 1, Examples 1 to 4 in which a long-chain monoalkyl type cationic surfactant was combined with 1,2-dodecanediol had the effects of the present invention, whereas 1 In Comparative Examples 1 to 3, in which other surfactants were combined with 2-dodecanediol, the effect of the present invention was not obtained.
（実施例５、１、比較例４〜１４） (Examples 5 and 1 and Comparative Examples 4 to 14)
表２に示す結果から明らかなように、長鎖モノアルキル型カチオン界面活性剤に、１，２−アルカン（Ｃ10、Ｃ12）ジオールを組み合せた実施例５、１は、本願発明効果が得られたのに対し、上記以外の他の１，２−アルカンジオールや従来の高級アルコール、その類似化合物等を組み合わせた比較例４〜１４では、本願発明効果が得られなかった。 As is apparent from the results shown in Table 2, Examples 5 and 1 in which 1,2-alkane (C 10 , C 12 ) diol is combined with a long-chain monoalkyl type cationic surfactant have the effects of the present invention. On the other hand, the effects of the present invention were not obtained in Comparative Examples 4 to 14 in which other 1,2-alkanediols other than the above, conventional higher alcohols, and similar compounds thereof were combined.
（実施例６〜８、比較例１５〜２０） (Examples 6-8, Comparative Examples 15-20)
表３に示す結果から明らかなように、本願発明の（Ａ）成分、（Ｂ）成分を本願発明範囲内の特定の配合量、配合比で配合した実施例６〜８では、本願発明効果が得られたのに対し、上記範囲を外れた配合量、配合比で配合した比較例１５〜２０では、本願発明効果が得られなかった。 As is clear from the results shown in Table 3, in Examples 6 to 8 in which the components (A) and (B) of the present invention were blended at specific blending amounts and blending ratios within the scope of the present invention, the effects of the present invention were obtained. In contrast, the effects of the present invention were not obtained in Comparative Examples 15 to 20 which were blended at a blending amount and blending ratio outside the above range.
（試験例１〜６） (Test Examples 1-6)
表４に示す結果から明らかなように、（Ａ）〜（Ｃ）成分の系にシリコーン（誘導体）を配合する場合、粒子径１００ｎｍ以下のＯ／Ｗエマルションとして０．０１〜５．０質量％の範囲で含む試験例１〜３では極めて優れた本願発明効果が得られたのに対し、粒子径が１００ｎｍ超のシリコーン（誘導体）を０．５質量％を超えて配合した試験例６は外観（透明性）に劣るものであった。 As is clear from the results shown in Table 4, when silicone (derivative) is added to the system of components (A) to (C), 0.01 to 5.0% by mass as an O / W emulsion having a particle size of 100 nm or less. In Test Examples 1 to 3 including the above range, the present invention effect was extremely excellent, whereas Test Example 6 in which silicone (derivative) having a particle size of more than 100 nm was blended in an amount exceeding 0.5% by mass was an appearance. (Transparency) was inferior.
以下に本発明の毛髪化粧料の他の処方例を示す。いずれの毛髪化粧料も透明性が高く、５００（ｍＰａ・ｓ）以上の粘性があり、皮膚への刺激も弱く、塗布した時は毛髪へのなじみがよく、すすぎ時のなめらかさ（洗い流すタイプの毛髪化粧料について評価）、乾燥後のなめらかさに優れるものであった。 Other prescription examples of the hair cosmetic composition of the present invention are shown below. All hair cosmetics are highly transparent, have a viscosity of 500 (mPa · s) or more, weak irritation to the skin, are well-familiar with the hair when applied, and are smooth when rinsed Evaluation of hair cosmetics) and excellent smoothness after drying.
（実施例９：洗い流さないヘアトリートメント）
（配 合 成 分） （質量％）
塩化ステアリルトリメチルアンモニウム ０．４
１，２−ドデカンジオール ５．０
エタノール ２．０
グリセリン ３．０
ジプロピレングリコール ２．０
ステアロキシヒドロキシプロピルメチルセルロース ０．２
ステアリルジヒドロキシプロピルジモニウムオリゴ糖 ０．０５
ＰＯＥ（２０）グリセリルエーテル ０．１５
（PEG-240／デシルテトラデセス-20／IIDI）コポリマー ０．２
ジメチコン（「BY22-080」；東レ・ダウシリコーン（株）製） ０．２（シリコーン純分）
クエン酸 ０．０１
カラス麦抽出液 ０．１
大豆レシチン ０．１
タウリン ０．２
フェノキシエタノール ０．５
香料 ０．１
水 残 余
（製造方法）
７５℃の水を撹拌混合しながら、順次添加する。さらに、常温まで冷却する。
(Example 9: Hair treatment without washing off)
(Mixed component) (mass%)
Stearyltrimethylammonium chloride 0.4
1,2-dodecanediol 5.0
Ethanol 2.0
Glycerin 3.0
Dipropylene glycol 2.0
Stearoxyhydroxypropylmethylcellulose 0.2
Stearyl dihydroxypropyl dimonium oligosaccharide 0.05
POE (20) glyceryl ether 0.15
(PEG-240 / decyltetradeceth-20 / IIDI) copolymer 0.2
Dimethicone (“BY22-080”; manufactured by Toray Dow Silicone Co., Ltd.) 0.2 (pure silicone)
Citric acid 0.01
Oat extract 0.1
Soy lecithin 0.1
Taurine 0.2
Phenoxyethanol 0.5
Fragrance 0.1
Water residue (manufacturing method)
75 ° C. water is added sequentially with stirring and mixing. Furthermore, cool to room temperature.
（実施例１０：ヘアコンディショナー）
（配 合 成 分） （質量％）
塩化ステアリルトリメチルアンモニウム ２．０
１，２−ドデカンジオール １０．０
ジグリセリン ５．０
１，３−ブチレングリコール ３．０
ＰＥＧ／ＰＰＧ−１４／７ジメチルエーテル １．０
ステアロキシヒドロキシプロピルメチルセルロース ０．２
ヒドロキシエチルセルロース ０．２
ＰＯＥ（６０）硬化ヒマシ油 ０．３
グルタミン酸 ０．０５
グリシン ０．１
アモジメチコン（「BY22-079」；東レ・ダウシリコーン（株）製） ０．２１（シリコーン純分）
（アミノエチルアミノプロピルメチコン／ジメチコン）コポリマー １．０
（「FZ-4671」；（東レ・ダウシリコーン（株）製）
ベンジルアルコール ０．２
バラ抽出液 ０．２
トウツバキ種子油 ０．１
ポリクオタニウム−６１ ０．０５
香料 ０．４
水 残 余
（製造方法）
７５℃の水を撹拌混合しながら、順次添加する。さらに、常温まで冷却する。
(Example 10: Hair conditioner)
(Mixed component) (mass%)
Stearyltrimethylammonium chloride 2.0
1,2-dodecanediol 10.0
Diglycerin 5.0
1,3-butylene glycol 3.0
PEG / PPG-14 / 7 dimethyl ether 1.0
Stearoxyhydroxypropylmethylcellulose 0.2
Hydroxyethyl cellulose 0.2
POE (60) hydrogenated castor oil 0.3
Glutamic acid 0.05
Glycine 0.1
Amodimethicone ("BY22-079"; manufactured by Toray Dow Silicone Co., Ltd.) 0.21 (silicone pure)
(Aminoethylaminopropyl methicone / dimethicone) copolymer 1.0
("FZ-4671"; (Toray Dow Silicone Co., Ltd.)
Benzyl alcohol 0.2
Rose extract 0.2
Apis seed oil 0.1
Polyquaternium-61 0.05
Fragrance 0.4
Water residue (manufacturing method)
75 ° C. water is added sequentially with stirring and mixing. Furthermore, cool to room temperature.
（実施例１１：洗い流すヘアトリートメント）
（配 合 成 分） （質量％）
塩化ステアリルトリメチルアンモニウム ２．０
１，２−ドデカンジオール １０．０
ソルビトール ５．０
イソペンチルジオール ３．０
ステアレス−４ ０．２
イソステアリン酸イソセチル ０．０３
ステアロキシヒドロキシプロピルメチルセルロース ０．２
モノオレイン酸グリセリン ０．１
メントール ０．３
トウガラシチンキ ０．０５
バニリルブチルエーテル ０．０２
乳酸ナトリウム ０．０５
ヒドロキシエチル尿素 ０．１
コハク酸 ０．０２
Ｌ−アルギニン塩酸塩 ０．０１
アモジメチコン（「BY22-079」；東レ・ダウシリコーン（株）製） ０．２１（シリコーン純分）
（アミノエチルアミノプロピルメチコン／ジメチコン）コポリマー １．０
（「FZ-4671」；（東レ・ダウシリコーン（株）製）
メチルパラベン ０．３
安息香酸ナトリウム ０．２
バラ抽出液 ０．２
香料 ０．４
水 残 余
（製造方法）
７５℃の水を撹拌混合しながら、順次添加する。さらに、常温まで冷却する。
(Example 11: Washing off hair treatment)
(Mixed component) (mass%)
Stearyltrimethylammonium chloride 2.0
1,2-dodecanediol 10.0
Sorbitol 5.0
Isopentyldiol 3.0
Steerless-4 0.2
Isocetyl isostearate 0.03
Stearoxyhydroxypropylmethylcellulose 0.2
Glycerol monooleate 0.1
Menthol 0.3
Pepper tincture 0.05
Vanillyl butyl ether 0.02
Sodium lactate 0.05
Hydroxyethylurea 0.1
Succinic acid 0.02
L-arginine hydrochloride 0.01
Amodimethicone ("BY22-079"; manufactured by Toray Dow Silicone Co., Ltd.) 0.21 (silicone pure)
(Aminoethylaminopropyl methicone / dimethicone) copolymer 1.0
("FZ-4671"; (Toray Dow Silicone Co., Ltd.)
Methylparaben 0.3
Sodium benzoate 0.2
Rose extract 0.2
Fragrance 0.4
Water residue (manufacturing method)
75 ° C. water is added sequentially with stirring and mixing. Furthermore, cool to room temperature.
（実施例１２：ヘアコンディショナー）
（配 合 成 分） （質量％）
ステアラミドプロピルジメチルアミン−コハク酸塩 ２．０
１，２−ドデカンジオール １０．０
ソルビトール １０．０
イソプレングリコール ４．０
POE（35）POP（40）ジメチルエーテル（ブロック共重合体） １．５
高重合ポリエチレングリコール（Ｍｗ２００万） ０．１
（PEG−240／デシルテトラデセス−20／HDI）コポリマー ０．２
エリスリトール ２．５
ジメチコン（「BY22-080」；東レ・ダウシリコーン（株）製） ０．２（シリコーン純分）
ジメチコン（２０ｃｓ） ０．０２
ピロリドンカルボン酸 ０．４
酒石酸 ０．０２
トリメチルグリシン ０．１
ＰＯＥ（５）イソステアリルグリセリルエーテル ０．２
カチオン化デンプン ０．０２
カチオン化セルロース ０．０２
N-ラウロイルグルタミン酸ジ（フィトステリル／2-オクチルドデシル） ０．１
ビワ抽出液 ０．２
加水分解小麦タンパク質 ０．１
加水分解小麦タンパク質・加水分解小麦デンプン ０．０２
エデト酸２ナトリウム ０．０５
香料 ０．４
水 残 余
(Example 12: Hair conditioner)
(Mixed component) (mass%)
Stearamidopropyldimethylamine-succinate 2.0
1,2-dodecanediol 10.0
Sorbitol 10.0
Isoprene glycol 4.0
POE (35) POP (40) Dimethyl ether (block copolymer) 1.5
Highly polymerized polyethylene glycol (Mw 2 million) 0.1
(PEG-240 / decyltetradeceth-20 / HDI) copolymer 0.2
Erythritol 2.5
Dimethicone ("BY22-080"; manufactured by Toray Dow Silicone Co., Ltd.) 0.2 (pure silicone)
Dimethicone (20cs) 0.02
Pyrrolidone carboxylic acid 0.4
Tartaric acid 0.02
Trimethylglycine 0.1
POE (5) isostearyl glyceryl ether 0.2
Cationized starch 0.02
Cationized cellulose 0.02
N-lauroyl glutamate di (phytosteryl / 2-octyldodecyl) 0.1
Loquat extract 0.2
Hydrolyzed wheat protein 0.1
Hydrolyzed wheat protein, hydrolyzed wheat starch 0.02
Edetic acid disodium 0.05
Fragrance 0.4
Water residue
Claims (2)
で示される基を表し；Ｒ２、Ｒ３、Ｒ４はそれぞれ独立に、炭素原子数１〜３のアルキル基またはヒドロキシアルキル基を表し；Ｘ−は無機酸、有機酸、ハロゲン原子の中から選ばれる１種または２種以上のアニオンを表す。〕 (A) 0.1 to 10% by mass of one or more selected from long-chain monoalkyl type cationic surfactants represented by the following formula (I) or (II); 2-dodecanediol and / or 1,2-decanediol is contained in an amount of 2.5 to 30% by mass, (C) the remainder of water is included, and (B) component / (A) component (mass ratio) is 1.5 or more. Hair cosmetics having a viscosity of 500 (mPa · s / 30 ° C.) or higher and an L value of 20 or higher.
R 2 , R 3 and R 4 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group; X − represents an inorganic acid, an organic acid or a halogen atom. It represents one or more selected anions. ]
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| JP5454908B2 (en) * | 2010-02-26 | 2014-03-26 | 株式会社ミルボン | Non-gas former hair cosmetics |
| JP5998445B2 (en) * | 2010-10-22 | 2016-09-28 | 三菱化学株式会社 | Hair cosmetics |
| WO2014199936A1 (en) * | 2013-06-13 | 2014-12-18 | 株式会社 資生堂 | Hair treatment composition |
| JP6169421B2 (en) * | 2013-06-27 | 2017-07-26 | ポーラ化成工業株式会社 | Cosmetics |
| CN108495686A (en) | 2015-11-24 | 2018-09-04 | 欧莱雅 | Composition for handling hair |
| WO2018183858A1 (en) * | 2017-03-31 | 2018-10-04 | L'oreal | Hair-treatment compositions |
| JP7336989B2 (en) * | 2017-09-27 | 2023-09-01 | 株式会社 資生堂 | hair cosmetics |
| JP7217925B2 (en) * | 2018-09-05 | 2023-02-06 | クラシエホームプロダクツ株式会社 | skin cleanser composition |
| US11090249B2 (en) | 2018-10-31 | 2021-08-17 | L'oreal | Hair treatment compositions, methods, and kits for treating hair |
| US20200170906A1 (en) * | 2018-12-04 | 2020-06-04 | The Procter & Gamble Company | Hair care composition for cleansing and refreshing the hair and the scalp |
| JP7358114B2 (en) * | 2019-08-20 | 2023-10-10 | 株式会社ノエビア | hair cosmetics |
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| US4294728A (en) * | 1971-02-17 | 1981-10-13 | Societe Anonyme Dite: L'oreal | Shampoo and/or bubble bath composition containing surfactant and 1,2 alkane diol |
| JPH01153610A (en) * | 1987-12-10 | 1989-06-15 | Lion Corp | Hair cosmetic |
| JP2571117B2 (en) * | 1989-02-03 | 1997-01-16 | 花王株式会社 | Detergent composition |
| DE4234743A1 (en) * | 1992-10-15 | 1994-04-21 | Wella Ag | Means for setting the hair |
| JP4629354B2 (en) * | 2004-02-25 | 2011-02-09 | 三洋化成工業株式会社 | Surfactant composition |
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