JP5250914B2 - Method of supplying sensor or sensor component and artificial sweat base material - Google Patents
Method of supplying sensor or sensor component and artificial sweat base material Download PDFInfo
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- JP5250914B2 JP5250914B2 JP2010211352A JP2010211352A JP5250914B2 JP 5250914 B2 JP5250914 B2 JP 5250914B2 JP 2010211352 A JP2010211352 A JP 2010211352A JP 2010211352 A JP2010211352 A JP 2010211352A JP 5250914 B2 JP5250914 B2 JP 5250914B2
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- Measuring And Recording Apparatus For Diagnosis (AREA)
Description
本発明は、人工汗の組成、並びに、人工汗を供給する方法、人工汗機能を有するセンサ及びセンサ部品に関する。 The present invention relates to a composition of artificial sweat, a method for supplying artificial sweat, a sensor having an artificial sweat function, and a sensor component.
センサが使用される様々な部品において、センシングを行う際、センサまたはセンサが組み込まれた部品が、センシング(検出)する対象物に直接または間接的に接触し発生する高い摩擦(摩擦係数)による摩擦熱や激しい振動がセンサ受容信号をかく乱し、センサまたはセンサ部品を摩耗・損傷させる。これらの課題を解決するため、その可能性のあるセンサまたはセンサ部品(周辺材料を含む)または検出対象物の表面を保護する、あるいはセンサ受容信号を安定化するため、ヒトの感覚器を有する皮膚機能特有の瞬間的かつ流動的な保護膜である汗、これに代わる人工の汗の機能を提案し、提供する必要がある。 Friction caused by high friction (coefficient of friction) generated by direct or indirect contact with the object to be sensed (detected) when sensing in various parts where the sensor is used Heat and intense vibrations disturb the sensor acceptance signal, causing wear or damage to the sensor or sensor component. To solve these problems, the skin with a human sensory organ to protect the surface of the potential sensor or sensor component (including surrounding materials) or the object to be detected or to stabilize the sensor acceptance signal It is necessary to propose and provide the function of sweat, which is an instantaneous and fluid protective film peculiar to function, and the function of artificial sweat instead.
例えば、先行技術にあるセンサを保護する固定された材料については、特許文献1に開示されるように、圧力センサ表面に保護膜(シリコン窒化膜を固定)を使用する方法、特許文献2に開示されるように、流量センサ表面に保護膜(DLCやアルミナ、SiNを固定)を使用する方法、特許文献3〜4に開示されるように、バイオセンサ表面またはケミカルセンサ表面に保護膜(絶縁性有機物を固定)を使用する方法、特許文献5に開示されるように、超音波センサ表面に保護膜(各種金属、各種合成樹脂、ガラス、ゴムなどを固定)を使用する方法、特許文献6に開示されるように、電気化学センサ表面に保護膜(シリカ含有のエラストマーを固定)を使用する方法、また、先行技術にある潤滑剤を供給するための方法または利用可能な方法として、特許文献7〜9に開示されるように、インクジェット装置により供給する方法、特許文献10に開示されるように、エアロゾルを生成しオイルミストを噴霧供給する方法、特許文献11に開示されるように、センサから得た信号をもとに軸受に潤滑油を自動的に給油する方法、特許文献12に開示されるように、ロボット走行のために潤滑油を自動給油する方法、などが知られている。
しかしながら、従来の方法では、センサまたはセンサ表面に固定された保護膜またはセンサを内部に設けるセンサ周辺材料(以下、センサ部品という)が一旦傷つくとなかなか修復が難しく、センサ部品が有機材料の場合、特に、エラストマーのような柔軟性の高い材料の場合、無機材料のように硬い材料に比べ微小荷重の接触状態(例えば、触覚信号など)をセンサで敏感に検知できるが、弾性ヒステリシス損失の発生や、その平滑面においては吸着現象(スティクションやスティック・スリップ)に伴う高い摩擦係数(摩擦熱)の発生と、同時に発生するはげしい振動により、センサ受容信号がかく乱される、またはセンサ部品が損傷する、または摩耗するなどの課題がある。 However, in the conventional method, once the sensor peripheral material (hereinafter referred to as sensor component) in which the sensor or the protective film fixed to the sensor surface is internally damaged is damaged, it is difficult to repair. When the sensor component is an organic material, In particular, in the case of a highly flexible material such as an elastomer, a contact state (for example, a tactile signal) with a minute load can be detected more sensitively than a hard material such as an inorganic material. On the smooth surface, the sensor acceptance signal is disturbed or the sensor parts are damaged by the generation of a high coefficient of friction (friction heat) due to the adsorption phenomenon (stiction and stick-slip) and the simultaneous strong vibration. There is a problem such as wear.
前記センサ部品が無機材料の場合、特に高硬度の材料は耐摩耗性や耐久性という点で優れているが、センサ部品の接触相手材料が硬い場合には、接触面圧が高くなりやすく、傷(スクラッチ)や凝着摩耗を起こすなどの課題がある。 When the sensor component is an inorganic material, a particularly hard material is superior in terms of wear resistance and durability, but when the contact partner material of the sensor component is hard, the contact surface pressure tends to increase, There are problems such as (scratch) and adhesive wear.
さらに、前記センサ部品が接触する相手材がセンサ部品よりも柔らかい場合、特に、柔軟性の高いエラストマー系の有機材料では、上述の有機材料のセンサ部品同様の課題がある。 Further, when the mating material that the sensor component contacts is softer than the sensor component, particularly in the case of an elastomeric organic material having high flexibility, there is the same problem as the sensor component of the organic material described above.
センサ部品が接触した際に発生する高い摩擦係数とそれに伴うはげしい振動は、その摩擦熱により接触部の表面温度が高温となり、センサ部品にダメージを与える、センサ受容信号をかく乱するなどの課題もある。 The high coefficient of friction that occurs when the sensor component comes into contact with the vibrations that accompany it causes problems such as the surface temperature of the contact portion becoming high due to the frictional heat, damaging the sensor component, and disturbing the sensor acceptance signal. .
さらに、センサ部品が接触する対象物によっては、接触した際に有害物質(毒物、微生物、細菌、ウイルスなど)がセンサ部品表面を汚染されるなどの課題もある。
そこで、本発明は、センサ部品と接触相手面との間の摩擦係数を調整し、センサ受容信号の安定化、センサ保護、センサ部品材料および接触相手材料の摩耗と摩擦熱の低減、接触する相手材料の摩擦係数の差を明瞭化し材料の判別を容易にする、センサ部品と接触相手面の相互の接触表面の消毒・殺菌・清浄化することを課題とする。Furthermore, depending on the object to which the sensor component comes into contact, there is a problem that harmful substances (poisonous substances, microorganisms, bacteria, viruses, etc.) contaminate the surface of the sensor component when contacted.
Therefore, the present invention adjusts the coefficient of friction between the sensor component and the contact counterpart surface, stabilizes the sensor reception signal, protects the sensor, reduces wear and frictional heat of the sensor component material and the contact counterpart material, and contacts the contact partner. It is an object to disinfect, sterilize, and clean the mutual contact surfaces of the sensor component and the contact partner surface, which makes it possible to clarify the difference in the friction coefficient of the material and facilitate the discrimination of the material.
以上の課題を解決するために、本発明は、センサ部品またはセンサ機能を有する材料の表面に、水と、炭素原子に結合した少なくとも1個のOH基を有する1種の水溶性化合物(以下、水溶性化合物という)からなる人工の汗(以下、人工汗という)を供給し、かつ人工汗の各基材成分の混合比および/または人工汗の供給量を変化させることで、接触対象物との摩擦係数を流動的にコントロールすることを最も主要な特徴とする。 In order to solve the above-described problems, the present invention provides a water-soluble compound (hereinafter referred to as “water-soluble compound”) having at least one OH group bonded to a carbon atom on the surface of a sensor component or a material having a sensor function. By supplying artificial sweat composed of water-soluble compounds) (hereinafter referred to as artificial sweat) and changing the mixing ratio of each base material component of artificial sweat and / or the supply amount of artificial sweat. The main feature is to fluidly control the friction coefficient.
本発明によれば、センサ部品の表面に人工汗を供給することで、センサ部品が接触する相手面に対し、センサ部品と接触相手面間の吸着や凝着と、それにともなう高い摩擦係数の発生と摩耗を抑制することができ、同時に、センサ受容信号の安定化とセンサまたはセンサ部品を保護することができる。 According to the present invention, by supplying artificial sweat to the surface of the sensor component, adsorption or adhesion between the sensor component and the contact partner surface and generation of a high friction coefficient with respect to the counterpart surface with which the sensor component contacts Wear can be suppressed, and at the same time, the sensor acceptance signal can be stabilized and the sensor or sensor component can be protected.
センサ部品と平滑な接触相手面との間にあるわずかな水分が、吸着現象(ラプラス圧力)を発生させ、高い摩擦係数の発生と同時に、センサ受容信号をかく乱するはげしい振動を発生するが、このとき人工汗を供給することで、人工汗の十分な流動膜と水溶性化合物の官能基のヒドロキシル基(OH基)が、水の表面張力(またはラプラス圧力)を低下させ、吸着現象と高い摩擦係数の発生を抑え、安定したセンサ受容信号を提供することができる。 A small amount of moisture between the sensor component and the smooth mating contact surface causes an adsorption phenomenon (Laplace pressure), and at the same time as a high friction coefficient, it generates a tremendous vibration that disturbs the sensor acceptance signal. When artificial sweat is supplied, a sufficient fluid film of artificial sweat and the hydroxyl group (OH group) of the functional group of the water-soluble compound lowers the surface tension (or Laplace pressure) of water, causing the adsorption phenomenon and high friction. Generation of a coefficient can be suppressed and a stable sensor acceptance signal can be provided.
センサ部品と粗い接触相手面との接触においては、前記平滑な接触相手面よりも同一条件化で真実接触面積は減少し、その粗さの効果が前記吸着現象を抑える効果を改善する一方で、例えば、触覚センサでは、接触面積(触覚面積)の減少とともに触覚情報が減少し、結果として不明瞭な(微弱な)触覚センサ受容信号となるが、ここに人工汗を供給することで、本来ならば接触できない、例えば、窪みや溝のような部分に、人工汗が浸透し、人工汗が触覚情報を間接的にセンサ部品へと伝達し、センサ受容信号を明瞭化することができる。 In the contact between the sensor component and the rough contact surface, the true contact area is reduced under the same conditions as the smooth contact surface, and the effect of the roughness improves the effect of suppressing the adsorption phenomenon, For example, in a tactile sensor, the tactile information decreases with a decrease in the contact area (tactile area), resulting in an unclear (weak) tactile sensor acceptance signal. For example, artificial sweat penetrates into parts such as depressions and grooves that cannot be contacted, and the artificial sweat indirectly transmits tactile information to the sensor component, thereby clarifying the sensor acceptance signal.
例えば、紙(セルロース繊維)のような粗い表面で、高い吸湿性(または親水性)の接触相手面では、人工汗中の水分が繊維に浸透すると同時に、その接触面間のラプラス圧力を高くし摩擦係数を増加させ、人工汗中の水溶性化合物がその接触相手面の表面に吸着・保護し、摩耗を抑制することができる。 For example, on a rough surface such as paper (cellulose fiber) and a highly hygroscopic (or hydrophilic) contact surface, moisture in the artificial sweat penetrates the fiber and at the same time increases the Laplace pressure between the contact surfaces. The friction coefficient can be increased, and the water-soluble compound in the artificial sweat can be adsorbed and protected on the surface of the contact partner surface to suppress wear.
前記特性から、センサ部品が接触する対象物の高吸湿性(または親水性)と低吸湿性(または疎水性)の材料の差を、人工汗を用いることで、対象物表面での人工汗の吸着性または人工汗のぬれ性または人工汗膜の形成能力の差が、接触面間の摩擦の差となって、材料判別を容易にすることができる。 From the above characteristics, by using artificial sweat, the difference between the high hygroscopic (or hydrophilic) and low hygroscopic (or hydrophobic) materials of the target object in contact with the sensor component is used. The difference in adsorptivity, wettability of artificial sweat or ability to form an artificial sweat film becomes a difference in friction between contact surfaces, and material discrimination can be facilitated.
さらに、センサ部品と検出対象物間の人工汗の供給とその蒸発にともなう気化熱により、接触面間の摩擦熱を冷却することができる。 Furthermore, the frictional heat between the contact surfaces can be cooled by the supply of artificial sweat between the sensor component and the detection object and the heat of vaporization accompanying the evaporation.
さらに、人工汗の基材成分の水溶性化合物に、消毒・殺菌性のある、例えば、エチルアルコール(エタノール)や酢酸など、を用いることで、センサ部品または接触する相手材表面を消毒・殺菌・清浄化することができる。 In addition, disinfecting / sterilizing the surface of the sensor component or the contacted material by using, for example, ethyl alcohol (ethanol) or acetic acid as the water-soluble compound of the base material of artificial sweat. Can be cleaned.
以下、本発明の好適な実施形態について図面を参照しながら説明する。なお、図面の説明においては、同一の要素には同一の符号を付し、重複する説明については省略する。また、図面においては、寸法比率は説明のものとは必ずしも一致していない。 Preferred embodiments of the present invention will be described below with reference to the drawings. In the description of the drawings, the same elements are denoted by the same reference numerals, and redundant descriptions are omitted. In the drawings, the dimensional ratio does not necessarily match that described.
まず、簡単のため単純なセンサ部品の配置と人工汗を供給する回路と方法、人工汗の組成について説明する。 First, for the sake of simplicity, a simple sensor component arrangement, a circuit and method for supplying artificial sweat, and the composition of artificial sweat will be described.
(人工汗供給方法)
図1に基づき、センサ部品の配置と人工汗の供給方法について説明する。人工汗の基材成分である水2、そしてもうひとつの人工汗の基材成分である少なくとも1種類の水溶性化合物3を入れ、人工汗容器の上流に設置されたポンプ(インクジェット式の場合は人工汗容器の下流に設置するのが好ましい)などの加圧装置1あるいは気化装置あるいは毛細管力による負圧による液送などによって、接触をともなうセンサ8表面またはセンサ部品材料9表面に、人工汗の基材成分2、3が人工汗7となって供給される。なお、人工汗容器は、各種水溶性化合物保存のため、複数あってもよい。(Artificial sweat supply method)
Based on FIG. 1, the arrangement of sensor components and the method for supplying artificial sweat will be described. A pump installed in the upstream of the artificial sweat container (in the case of the ink jet type), containing water 2 which is a base material component of artificial sweat and at least one water-soluble compound 3 which is another base material component of artificial sweat It is preferable to install the artificial sweat on the surface of the sensor 8 or the sensor component material 9 with contact by the pressurizing device 1 such as a pressure sensor 1 such as a vaporizer or liquid feeding by a negative pressure by capillary force. Substrate components 2 and 3 are supplied as artificial sweat 7. Note that there may be a plurality of artificial sweat containers for storing various water-soluble compounds.
(人工汗容器)
人工汗容器は、水2に少なくとも1種の水溶性化合物3を予め0〜100質量%の範囲内で設定した濃度の混合液を入れてもよく、この場合、人工汗容器は合計で少なくとも1個でよい。(Artificial sweat container)
The artificial sweat container may be a mixture of water having a concentration of at least one water-soluble compound 3 set in the range of 0 to 100% by mass in advance. In this case, the artificial sweat container has a total of at least 1 Individual is enough.
(人工汗の供給量とタイミング)
人工汗の供給のタイミング(または供給量)については、センサ接触部表面に設置されたセンサ8またはセンサ部品内部に設置されたセンサ10から検知される受容信号が、アンプ11により増幅され、A/Dコンバータ12、マイコンまたはパーソナルコンピュータ13に送信される。(Supply and timing of artificial sweat)
Regarding the supply timing (or supply amount) of artificial sweat, a reception signal detected from the sensor 8 installed on the surface of the sensor contact portion or the sensor 10 installed inside the sensor component is amplified by the amplifier 11, and the A / It is transmitted to the D converter 12, the microcomputer or the personal computer 13.
(センサ部品保護のための人工汗供給のためのループ信号制御・フィードバック信号制御)
コンピュータ13によって、センサ8またはセンサ部品9が検出対象物との接触にともない発生するセンサ受容信号、例えば、圧力信号など、がセンサ8、10またはセンサ部品9で高い摩擦を発生する、または損傷または摩耗するレベルの値、例えば、検知された受容信号の大きさ、周波数、信号波形など、に到達したとき、加圧装置1へインバータ制御またはON−OFF制御、または制御バルブ4へバルブ開閉制御など、制御信号が送信され、センサ受容信号が安全な値に復帰するまで、ループまたはフィードバック制御される。(Loop signal control and feedback signal control for artificial sweat supply to protect sensor parts)
A sensor acceptance signal generated by the computer 13 when the sensor 8 or the sensor component 9 comes into contact with the object to be detected, such as a pressure signal, causes high friction in the sensor 8, 10 or the sensor component 9, or damage or When the wear level value, for example, the magnitude, frequency, signal waveform, etc. of the detected reception signal is reached, inverter control or ON-OFF control to the pressurizing device 1 or valve opening / closing control to the control valve 4 etc. The control signal is transmitted and looped or feedback controlled until the sensor acceptance signal returns to a safe value.
前記制御方法により、人工汗容器より、人工汗7中の水2と少なくとも1種の水溶性化合物3が、個別に複数の配管、または同一配管内へ送られ、人工汗中の固形異物除去のためのろ過フィルタ5を通過し、人工汗を供給する汗孔6へと導かれる。ただし、予め人工汗が十分ろ過されたものが人工汗容器にある場合は、ろ過フィルタ5はなくてもよい。 By the control method, the water 2 and at least one water-soluble compound 3 in the artificial sweat 7 are individually sent from the artificial sweat container to the plurality of pipes or the same pipe to remove the solid foreign matter in the artificial sweat. For this reason, it is guided to the perspiration hole 6 for supplying artificial sweat. However, if the artificial sweat container contains a piece of artificial sweat that has been sufficiently filtered in advance, the filtration filter 5 may be omitted.
人工汗7が個別の配管で送られてくる場合、水2と少なくとも1種の水溶性化合物3が、汗孔6の空間で瞬間的に混ざり、センサ部品9またはセンサ8の隙間(またはセンサ内部を貫通する孔)を通過して、センサ部品9またはセンサ8表面へ人工汗7が供給される。 When the artificial sweat 7 is sent through a separate pipe, the water 2 and at least one water-soluble compound 3 are instantaneously mixed in the space of the sweat hole 6, and the gap between the sensor component 9 or the sensor 8 (or the inside of the sensor) The artificial sweat 7 is supplied to the surface of the sensor component 9 or the sensor 8 through the hole).
(センサ部品外部より人工汗が供給される場合)
センサ部品9の外部より人工汗7が供給される場合、人工汗基材成分である水2と少なくとも1種の水溶性化合物3は、バルブ4を通過した後、同一配管または個別の配管と前記汗孔6に相当する空間を通過し、センサ8またはセンサ部品9表面に供給される。このとき、孔工6部に噴霧ノズル等を付加するなど、人工汗7の供給状態を調整することが望ましい。(When artificial sweat is supplied from outside the sensor component)
When the artificial sweat 7 is supplied from the outside of the sensor component 9, the artificial sweat base material component water 2 and at least one water-soluble compound 3 pass through the valve 4 and then the same pipe or individual pipes It passes through a space corresponding to the sweat hole 6 and is supplied to the surface of the sensor 8 or the sensor component 9. At this time, it is desirable to adjust the supply state of the artificial sweat 7 by adding a spray nozzle or the like to the hole 6 part.
(汗孔の説明)
図2に示すように、汗孔6(aとb)は、センサ部品9の内部または表面に配置し、個別に送られてくる人工汗基材成分の水2と少なくとも1種の水溶性化合物3が、汗孔6の空間汗孔(b)の最大容積10mlの空間内で混合し、人工汗7としてセンサ部品9表面に汗孔6(a)より排出・供給される。このとき人工汗7は、気体、ミスト(噴霧)、液体のいずれかの状態でよく、また、汗孔6内に、親水性材料、例えば、親水性高分子ゲル/ゾル、親水性ファイバなど、を封入または導入してもよい。(Description of sweat pores)
As shown in FIG. 2, the sweat holes 6 (a and b) are disposed in or on the sensor component 9, and the artificial sweat base material water 2 and at least one water-soluble compound are individually fed. 3 are mixed in a space having a maximum volume of 10 ml of the space sweat hole (b) of the sweat hole 6 and discharged and supplied as artificial sweat 7 to the surface of the sensor component 9 from the sweat hole 6 (a). At this time, the artificial sweat 7 may be in a gas, mist (spray), or liquid state, and a hydrophilic material such as a hydrophilic polymer gel / sol, a hydrophilic fiber, etc. May be encapsulated or introduced.
図2のセンサ部品9材料が弾性体(エラストマー)の場合、検出対象物との接触の際に発生する圧力による圧迫により、人工汗7がセンサ部品9表面に排出・供給される。 When the material of the sensor component 9 in FIG. 2 is an elastic body (elastomer), the artificial sweat 7 is discharged / supplied to the surface of the sensor component 9 due to the pressure caused by the pressure generated upon contact with the detection target.
(人工汗機能を有するセンサ部品の応用例)
人工汗機能を有するセンサ部品の応用例として、多指型ロボットハンドに装備されたセンサ部品9と、センサ(8、10)の配置および人工汗供給孔の部分断面図を、図3に示す。後述の各種センサを装備可能であるロボットハンドの接触部分には、後述の各種センサ部品9材料が使用され、摩擦を調整するための人工汗の供給孔(汗孔6)が装備される。(Application examples of sensor parts with artificial sweat function)
As an application example of a sensor component having an artificial sweat function, FIG. 3 shows a sensor component 9 equipped in a multi-fingered robot hand, the arrangement of sensors (8, 10), and a partial cross-sectional view of an artificial sweat supply hole. In the contact part of the robot hand that can be equipped with various sensors described later, various sensor component 9 materials described later are used, and artificial sweat supply holes (sweat holes 6) for adjusting friction are equipped.
(センサ部品表面の凹凸またはテクスチャ)
センサ部品9またはセンサ8の表面に人工汗溜まり(汗溝)や、人工汗による不要なすべりを防止するために、センサ部品9の表面に、ドット径またはライン幅が50nm〜10mmで高さ1nm〜10mmの少なくとも1個のドットパターンおよび/またはラインパターンの凹凸を形成し、凹部または/および凸部の表面にある少なくとも1個の汗孔6から、人工汗7が分泌・供給される。このとき、汗孔6の孔径は1nm〜10mmであり、人工汗の各基材成分(2、3)が孔より別々または一緒に分泌・供給される。(Roughness or texture on the surface of sensor parts)
In order to prevent artificial sweat pools (sweat grooves) and unnecessary slip due to artificial sweat on the surface of the sensor component 9 or sensor 8, the surface of the sensor component 9 has a dot diameter or line width of 50 nm to 10 mm and a height of 1 nm. Artificial sweat 7 is secreted and supplied from at least one sweat hole 6 on the surface of the concave portion or / and the convex portion, which forms irregularities of at least one dot pattern and / or line pattern of -10 mm. At this time, the hole diameter of the sweat hole 6 is 1 nm to 10 mm, and each base material component (2, 3) of artificial sweat is secreted and supplied separately or together from the hole.
図4平面図に示すように、ドットパターンは、例えば、四角形(ドットパターン1)、円形(ドットパターン2)、三角形、多角形、または不定形の突起または窪みである。 As shown in the plan view of FIG. 4, the dot pattern is, for example, a quadrangle (dot pattern 1), a circle (dot pattern 2), a triangle, a polygon, or an irregular protrusion or depression.
図4平面図に示すように、ラインパターンは、例えば、ストライプパターン1のように縞状、もしくは同心円状のストライプパターン2などの縞状の凹凸形状を形成する。 As shown in the plan view of FIG. 4, the line pattern forms a striped uneven shape such as a striped pattern 2 such as a striped pattern 1 or a concentric striped pattern 2.
(人工汗の組成)
人工汗は、水2と、炭素原子に結合した少なくとも1個のヒドロキシル基を有する少なくとも1種の水溶性化合物3を、基材成分とし、水または水溶性化合物を0〜100質量%の範囲内で濃度を変化させることで、摩擦係数を調整するためのものである。(Composition of artificial sweat)
Artificial sweat uses water 2 and at least one water-soluble compound 3 having at least one hydroxyl group bonded to a carbon atom as a base component, and water or a water-soluble compound is in the range of 0 to 100% by mass. This is for adjusting the friction coefficient by changing the concentration.
(水溶性化合物の説明)
水溶性化合物3としては、水溶性かつ炭素原子に結合したOH基を有する化合物であればよい。ここで言う炭素原子に結合したOH基とは、カルボキシル基(−COOH)やフェノール基等の複雑な官能基に含まれるものも含む概念である。(Description of water-soluble compounds)
The water-soluble compound 3 may be any compound that is water-soluble and has an OH group bonded to a carbon atom. Here, the OH group bonded to the carbon atom is a concept including those contained in a complicated functional group such as a carboxyl group (—COOH) or a phenol group.
このような水溶性化合物3としては、炭素原子に結合したOH基を有する水溶性の炭化水素類の他、水溶性アルコール類(例えば、メタノール、エタノール、プロパノール、イソプロピルアルコール、ブチルアルコール、アルカンジオール、エリスリトール、グリセリン、ポリグリセリン、キシリトール、ジグリセリン、ヘキサジオール、ヘキシトール、エチレングリコール、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール、ポリプロピレングリコール、アルキレンオキサイド(エチレンオキサイド、プロピレンオキサイド、ブチレンオキサイド等)、ヒアルロン酸等)、カルボン酸類(例えば、酢酸等)、炭素原子に結合したOH基を有する水溶性エステル類、炭素原子に結合したOH基を有する水溶性エーテル類、炭素原子に結合したOH基を有する水溶性ハロゲン化有機化合物等が挙げられる。これらの中でも、特に、水溶性アルコール類が好ましい。 As such a water-soluble compound 3, in addition to water-soluble hydrocarbons having an OH group bonded to a carbon atom, water-soluble alcohols (for example, methanol, ethanol, propanol, isopropyl alcohol, butyl alcohol, alkanediol, Erythritol, glycerin, polyglycerin, xylitol, diglycerin, hexadiol, hexitol, ethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, polyethylene glycol, polypropylene glycol, alkylene oxide (ethylene oxide, propylene oxide, butylene) Oxide, etc.), hyaluronic acid, etc.), carboxylic acids (eg, acetic acid, etc.), water-soluble esters having an OH group attached to a carbon atom, Water-soluble ethers having an OH group, include water-soluble halogenated organic compounds having an OH group attached to a carbon atom. Among these, water-soluble alcohols are particularly preferable.
(人工汗基材成分以外の添加剤)
人工汗機能をさらに改善する目的で、人工汗基材成分2,3中に基材成分以外の添加剤を加えてもよく、このとき添加剤濃度は1質量ppm〜10質量%の範囲内が望ましく、例えば、粒径1nm〜100μmの固体潤滑剤(フッ素系粒子、フッ素添加カーボンやアモルファスカーボンやグラファイトやC60などの炭素粒子、二硫化モリブデン粒子等)を添加するなど好例である。この場合、図1のろ過フィルタ5のろ過精度は、粒径サイズよりも大きくしなくてはならない。(Additives other than artificial sweat base materials)
For the purpose of further improving the artificial sweat function, additives other than the base component may be added to the artificial sweat base component 2 and 3, and the additive concentration is within the range of 1 mass ppm to 10 mass%. Desirably, for example, a solid lubricant (fluorine-based particles, fluorine-added carbon, amorphous carbon, carbon particles such as graphite and C60, molybdenum disulfide particles, etc.) having a particle diameter of 1 nm to 100 μm is a good example. In this case, the filtration accuracy of the filtration filter 5 of FIG. 1 must be larger than the particle size.
人工汗7は、検出対象物表面に残渣あるいは汚染しないものが望ましく、この場合、例えば、エタノールやメタノールなどが好例である。 The artificial sweat 7 is preferably one that does not cause residue or contamination on the surface of the detection target. In this case, for example, ethanol or methanol is a good example.
高温環境または引火または発火してはならない使用環境では、人工汗の水溶性化合物は、例えば、エチレングリコールなどの難燃性の材料が好ましい。 In high temperature environments or environments where it should not ignite or ignite, the water soluble compound of artificial sweat is preferably a flame retardant material such as ethylene glycol.
(センサ部品の説明)
図1に示すセンサ部品9は、センサ検出対象物と直接接触をともなうセンサの保護膜またはセンサまたはセンサを内部に設けるセンサ周辺材料であり、無機材料(セメント、耐火物、磁性材料、金属の製錬加工物、ガラスなど)および/または有機材料(化学合成樹脂、高分子ゲルまたはゾル、ゴム、合成繊維、セルロースなど)である。(Explanation of sensor parts)
A sensor component 9 shown in FIG. 1 is a sensor peripheral material in which a protective film of a sensor or a sensor or a sensor having a direct contact with an object to be detected is provided, and is made of an inorganic material (cement, refractory, magnetic material, metal). Wrought products, glass, etc.) and / or organic materials (chemical synthetic resins, polymer gels or sols, rubber, synthetic fibers, cellulose, etc.).
(センサの種類)
図1に示すセンサ8またはセンサ10の種類は、人工汗を用いることが可能な物理センサまたは化学センサ(バイオセンサを含む)の全般で、例えば、力センサでは、圧力センサ、光学的圧力センサ、半導体圧力センサ、SAWフォースセンサ、ひずみセンサ、超音波センサ、感圧導電性センサなど、また、光センサでは、例えば、光量センサ、超高速光センサ、フォトトランジスタ、フォトンセンサ、画像センサ、半導体イメージセンサ、色センサ、光の位相センサ、偏光応用のセンサなど、また、温度センサでは、接触式温度センサ、非接触式温度センサ、集電型温度センサ、SAW型放射温度センサ、光ファイバ温度センサなど、また、速度センサでは、例えば、光ドップラー速度センサ、光集積化速度センサ、光ファイバジャイロスコープ、集積化加速度センサ、磁気型加速度センサなど、化学センサでは、イオンセンサ、分子認識センサなどである。(Sensor type)
The types of sensor 8 or sensor 10 shown in FIG. 1 are all physical sensors or chemical sensors (including biosensors) that can use artificial sweat. For example, in a force sensor, a pressure sensor, an optical pressure sensor, Semiconductor pressure sensors, SAW force sensors, strain sensors, ultrasonic sensors, pressure-sensitive conductive sensors, etc., and optical sensors include, for example, light quantity sensors, ultra-high speed optical sensors, phototransistors, photon sensors, image sensors, semiconductor image sensors , Color sensor, optical phase sensor, polarization application sensor, etc., and for temperature sensor, contact temperature sensor, non-contact temperature sensor, current collector temperature sensor, SAW radiation temperature sensor, optical fiber temperature sensor, etc. In the speed sensor, for example, an optical Doppler speed sensor, an optical integrated speed sensor, an optical fiber gyroscope, -Loop, integrated acceleration sensors, magnetic-type acceleration sensor, the chemical sensor, ion sensor, and the like molecular recognition sensor.
(人工汗によるセンサ部品および検出対象物の表面の消毒・殺菌)
図1に示すセンサ部品9またはセンサ8と検出対象物との接触面または表面を消毒・殺菌するには、人工汗7の水溶性化合物3に、例えば、エタノールや酢酸などを使用し、特に、エタノール水溶液の場合、エタノール体積濃度を70〜90%(15℃環境)の範囲内の人工汗7を供給するのが好ましい。(Disinfection and sterilization of sensor parts and the surface of detection objects using artificial sweat)
In order to disinfect and sterilize the contact surface or surface between the sensor component 9 or the sensor 8 and the detection target shown in FIG. 1, for example, ethanol or acetic acid is used as the water-soluble compound 3 of the artificial sweat 7. In the case of an ethanol aqueous solution, it is preferable to supply artificial sweat 7 having an ethanol volume concentration in the range of 70 to 90% (15 ° C. environment).
(人工汗によるセンサ部品および検出対象物の表面の清浄化)
図1に示すセンサ部品9またはセンサ8と検出対象物との接触面または表面を清浄化するには、水および/または炭素数1〜3個の水溶性化合物の人工汗が望ましく、このときの人工汗の供給量は1cm2当り10ml/秒以下の流量で、かつ可能な限り高流量で供給(フラッシング)することが好ましい。(Cleaning the surface of sensor parts and detection objects with artificial sweat)
In order to clean the contact surface or surface between the sensor component 9 or the sensor 8 shown in FIG. 1 and the detection target, artificial sweat of water and / or a water-soluble compound having 1 to 3 carbon atoms is desirable. The artificial sweat is preferably supplied (flushing) at a flow rate of 10 ml / second or less per cm 2 and at a flow rate as high as possible.
まず、水溶性化合物(ここではエタノール)の水中質量濃度を0〜100質量%の範囲内で変化させた人工汗を、平滑な(表面粗さRa0.01μm)かつ清浄なアクリル樹脂表面に滴下し、各濃度の人工汗の滴形をデジタル・マイクロスコープにより撮影し、その滴形から接触角(人工汗膜の形成能)を確認した。 First, artificial sweat obtained by changing the mass concentration of water-soluble compound (ethanol in this case) in water within a range of 0 to 100% by mass is dropped onto a smooth (surface roughness Ra 0.01 μm) and clean acrylic resin surface. The drop shape of artificial sweat of each concentration was photographed with a digital microscope, and the contact angle (ability to form an artificial sweat film) was confirmed from the drop shape.
さらに、図5のシリコーンゴム製ヒト指型触覚センサ(ひずみゲージ)と前記アクリル樹脂との接触表面に、前記水溶性化合物の人工汗を濃度別に定量(0.06ml)供給し、定荷重下(0.25N)かつ往復動(0〜0.02m/s)の範囲内で摩擦係数を測定し、人工汗の有効性を確認した。 Furthermore, the artificial sweat of the water-soluble compound was supplied in a fixed amount (0.06 ml) according to the concentration to the contact surface between the silicone rubber human finger type tactile sensor (strain gauge) and the acrylic resin in FIG. The coefficient of friction was measured within the range of 0.25 N) and reciprocation (0 to 0.02 m / s), and the effectiveness of the artificial sweat was confirmed.
(比較例1)
人工汗を供給しない以外は、実施例1〜7同様にして摩擦係数を測定した。(Comparative Example 1)
The coefficient of friction was measured in the same manner as in Examples 1 to 7, except that no artificial sweat was supplied.
すべり接触面が紙(PPC用紙、粗さRa2.38μm)以外は、実施例1〜7同様にして摩擦実験を実施した。 Friction experiments were carried out in the same manner as in Examples 1-7 except that the sliding contact surface was paper (PPC paper, roughness Ra 2.38 μm).
図5のシリコーンゴム製ヒト指型触覚センサに、人工汗を定量(0.06ml)供給した場合とそうでない場合の、アクリル表面と紙(PPC用紙)の差を、内部にある垂直に配置した2つのひずみゲージの信号で比較した。 The difference between the acrylic surface and paper (PPC paper) when the artificial sweat is supplied (0.06 ml) and when it is not supplied to the silicone rubber human finger type tactile sensor is vertically arranged inside. Comparison was made with signals from two strain gauges.
(評価)
まず、アクリル表面において、エタノール濃度0〜100質量%範囲内の人工汗の接触角測定結果を図6に示す。(Evaluation)
First, on the acrylic surface, the measurement results of the contact angle of artificial sweat in the ethanol concentration range of 0 to 100% by mass are shown in FIG.
図6に示されるように、人工汗中のエタノール濃度の上昇とともに水の接触角(表面張力)が、瞬時に低下することから、エタノール濃度を意図的に変化させることで、水の接触角を瞬時に調整できることが容易に理解できる。 As shown in FIG. 6, the water contact angle (surface tension) decreases instantaneously as the ethanol concentration in artificial sweat increases, so the water contact angle can be reduced by intentionally changing the ethanol concentration. It can be easily understood that it can be adjusted instantaneously.
これは、本発明の最も主要な特徴である人工汗の基材成分である水溶性化合物(ここではエタノール)中の官能基であるヒドロキシル基(OH基)が、もうひとつの基材成分の水分子と検出対象物(ここではアクリル表面)に吸着し、水の表面張力を弱め、結果として、水溶性化合物またはヒドロキシル基の濃度、すなわち、エタノール濃度の変化とともに、人工汗の膜形成能力を瞬時に変化・調整できることが理解できる。 This is because the hydroxyl group (OH group), which is a functional group in the water-soluble compound (in this case, ethanol), which is the base component of artificial sweat, which is the main feature of the present invention, is another base component water. Adsorbs to molecules and detection objects (here acrylic surface), weakens the surface tension of water, and as a result, the ability of artificial sweat to form a film instantly changes with the concentration of water-soluble compounds or hydroxyl groups, ie, ethanol concentration You can understand that you can change and adjust
表1に、実施例1〜7の接触角測定結果と摩擦実験結果を示す。
図6に示された人工汗の接触角(膜形成能力あるいは吸着能力)の変化にともない、表1の結果に示すように、摩擦係数も変化させることが可能であることが理解できる。 It can be understood that the coefficient of friction can be changed as shown in the results of Table 1 as the contact angle (film forming ability or adsorption ability) of the artificial sweat shown in FIG. 6 changes.
図5に示されたシリコーンゴム製ヒト指型触覚センサは、アクリル表面に対し摩擦係数でおおよそ1を越えると、時間の経過とともに、シリコーンゴムは破断し、内部のひずみセンサに大きな損傷を与えることがわかっている。 When the silicone rubber human finger type tactile sensor shown in FIG. 5 has a coefficient of friction exceeding about 1 with respect to the acrylic surface, the silicone rubber breaks with time and causes great damage to the internal strain sensor. I know.
このようなセンサまたはセンサ部品または検出対象物にダメージを与えるようなセンサ受容信号を検知した際、適切な供給量または水溶性化合物濃度の人工汗が供給されれば、適切な摩擦係数に調整でき、センサまたはセンサ部品または検出対象物を保護できることが容易に理解できる。 When a sensor acceptance signal that damages such a sensor, sensor component, or detection target is detected, an appropriate friction coefficient can be adjusted if artificial sweat with an appropriate supply amount or water-soluble compound concentration is supplied. It can be easily understood that the sensor or the sensor component or the detection object can be protected.
図7に、実施例1〜7(人工汗あり)および比較例1(人工汗なし)に係わる摩擦係数と水中エタノール濃度の関係を示す。 FIG. 7 shows the relationship between the friction coefficient and the ethanol concentration in water in Examples 1 to 7 (with artificial sweat) and Comparative Example 1 (without artificial sweat).
図5のシリコーンゴム製ヒト指型触覚センサのアクリル表面との接触において、センサを保護するためには、図7の近似曲線より、おおよそ水溶性化合物(エタノール)濃度を20質量%以上にしてやればよい。ただし、図5のようにロボットハンドの“握る”という機能においては、摩擦係数は低すぎても問題であり、できるだけ水溶性化合物(実施例ではエタノール)濃度は低い値に設定することが好ましい。 In order to protect the sensor in contact with the acrylic surface of the silicone rubber human finger type tactile sensor, the concentration of the water-soluble compound (ethanol) should be approximately 20% by mass or more from the approximate curve of FIG. Good. However, in the function of “grabbing” the robot hand as shown in FIG. 5, the friction coefficient is too low, and it is preferable to set the concentration of the water-soluble compound (ethanol in the embodiment) as low as possible.
また、図7に示すように、水溶性化合物(エタノール)濃度の上昇とともに、摩擦係数の変動が小さくなる傾向も理解できる。 Further, as shown in FIG. 7, it can be understood that the variation of the friction coefficient tends to decrease as the concentration of the water-soluble compound (ethanol) increases.
すなわち、接触面における吸着現象(スティクション現象)やスティック・スリップのように、センサまたはセンサ部品が検出対象物に吸着したり、離れたりする現象により、激しい振動が発生するため、このような条件下でのセンサ検出操作は、センサ受容信号をかく乱するなど、センサにとっては好ましくない。 In other words, since the sensor or sensor component is attracted to or separated from the object to be detected, such as an adsorption phenomenon (stiction phenomenon) or stick-slip on the contact surface, such a condition causes severe vibration. The sensor detection operation below is not preferable for the sensor, such as disturbing the sensor acceptance signal.
このような課題に対しても、人工汗中の水溶性化合物濃度(実施例ではエタノール濃度)を調整することで、前記のはげしい振動を抑制し、安定した接触を実現することができる。 Against such a problem, by adjusting the concentration of the water-soluble compound in the artificial sweat (ethanol concentration in the examples), it is possible to suppress the violent vibration and realize stable contact.
表1および図7に示される比較例1結果のように、人工汗がない場合は、人工汗を供給した場合(実施例1〜7)よりも高い摩擦係数を示すことがわかる。 As shown in Table 1 and Comparative Example 1 results shown in FIG. 7, it can be seen that when there is no artificial sweat, a higher coefficient of friction is exhibited than when artificial sweat is supplied (Examples 1 to 7).
図8に、実施例8の結果を示す。 FIG. 8 shows the results of Example 8.
図8に示されるように、図5のシリコーンゴム製ヒト指型触覚センサが紙(PPC用紙)表面に接触した際、人工汗が水単体では接触の際に発生する紙(PPC用紙)の摩耗を、人工汗中の水溶性化合物(ここではエタノール)が抑制することがわかる。 As shown in FIG. 8, when the silicone rubber human finger type tactile sensor shown in FIG. 5 comes into contact with the surface of the paper (PPC paper), the abrasion of the paper (PPC paper) generated when the artificial sweat is in contact with water alone. It is understood that a water-soluble compound (ethanol in this case) in artificial sweat is suppressed.
図9に、実施例9の結果を示す。 FIG. 9 shows the results of Example 9.
図9に示されるように、図5のシリコーンゴム製ヒト指型触覚センサ内に垂直に配置された2つの触覚センサ(ひずみゲージAとB)の受容信号のプロット座標位置において、従来技術のように人工汗がない場合、接触対象物のアクリル樹脂と紙(PPC用紙)との判別が困難であることがわかる。 As shown in FIG. 9, in the coordinate position of the received signals of the two tactile sensors (strain gauges A and B) arranged vertically in the silicone rubber human finger type tactile sensor of FIG. When there is no artificial sweat, it is found that it is difficult to distinguish between the acrylic resin as the contact object and paper (PPC paper).
ここに、人工汗を供給することで、かつ水溶性化合物(ここではエタノール)濃度を高くすることで、センサA信号とセンサB信号のプロット座標位置において、接触対象物のアクリル樹脂と紙(PPC用紙)を分離し、判別(識別)を容易にすることが理解できる。 Here, by supplying artificial sweat and increasing the concentration of the water-soluble compound (ethanol in this case), the acrylic resin and paper (PPC) of the contact object at the plot coordinate positions of the sensor A signal and the sensor B signal It can be understood that the sheet is separated and identification (identification) is facilitated.
これらの実施例1〜9の結果から、人工汗の基材成分の水と少なくとも1種の水溶性化合物(実施例ではエタノールを使用)の濃度を変化させる、および/または人工汗の供給の有無によって、センサまたはセンサ部品または検出対象物の摩擦をコントロールし、それらの材料を摩耗から保護、接触にともなうはげしい振動を抑制、接触対象物の判別を容易にする機能を理解できる。 From the results of these Examples 1 to 9, the concentration of water and at least one water-soluble compound (ethanol is used in the examples) of the base material component of artificial sweat is changed, and / or whether or not artificial sweat is supplied Thus, it is possible to understand the functions of controlling the friction of the sensor, the sensor component, or the detection object, protecting those materials from abrasion, suppressing the significant vibration caused by the contact, and facilitating the discrimination of the contact object.
おそらく、人工汗の基材成分の水分子によるメニスカス効果や分子吸着性と、もうひとつの基材成分である水溶性化合物の親水基(すなわちヒドロキシル基)の吸着性と水溶性化合物中の疎水基(または親油基)の吸着性と人工汗膜形成能力等が、センサまたはセンサ部品または検出対象物との摩擦係数をコントロールし、前記機能を発揮しているものと考えられる。 Perhaps the meniscus effect and molecular adsorptivity by water molecules of the base material component of artificial sweat, the adsorptivity of the hydrophilic group (ie hydroxyl group) of the water-soluble compound that is another base material component, and the hydrophobic group in the water-soluble compound It is considered that the adsorptivity of (or lipophilic group) and the ability to form an artificial sweat film control the coefficient of friction with the sensor, sensor component, or detection target, and exhibit the above functions.
1・・・ポンプまたは加圧装置、2・・・水、3・・・水溶性化合物、4・・・バルブ、5・・・ろ過フィルタ、6・・・汗孔、7・・・人工汗、8・・・外部センサ、9・・・センサ部品(センサ周辺材料またはセンサ保護材料)、10・・・内部センサ、11・・・アンプ(センサ用増幅器)、12・・・A/Dコンバータ、13・・・マイクロコンピュータまたはパーソナルコンピュータによるセンサ受容信号の情報処理、14・・・人工汗の供給量調整のためのフィードバック制御信号DESCRIPTION OF SYMBOLS 1 ... Pump or pressurization apparatus, 2 ... Water, 3 ... Water-soluble compound, 4 ... Valve, 5 ... Filtration filter, 6 ... Sweat hole, 7 ... Artificial sweat 8 ... external sensor, 9 ... sensor parts (sensor peripheral material or sensor protection material), 10 ... internal sensor, 11 ... amplifier (sensor amplifier), 12 ... A / D converter , 13 ... Information processing of sensor acceptance signal by microcomputer or personal computer, 14 ... Feedback control signal for adjusting supply amount of artificial sweat
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