JP5324796B2 - Rotating electric machine using insulating sheet and method of manufacturing rotating electric machine - Google Patents

Description

The present invention particularly relates to a process for the preparation of a rotary electric machine and the electric rotating machine using a useful insulation sheet insulation slot.

  As a method for insulating a slot of a rotating electrical machine, there are a method by resin impregnation and a method of providing an insulating layer in the slot. As a method by resin impregnation, there are an immersion treatment method in which resin is impregnated at room temperature and an all impregnation method in which vacuum impregnation is performed. The immersion treatment method is an insulation treatment by dipping in an impregnation resin made of a solvent-type varnish filled with an impregnation tank or a solvent-free varnish thermosetting resin. In the entire impregnation method, the impregnation tank is evacuated. After injecting the impregnating resin, the resin is pressurized and impregnated for insulation treatment.

  On the other hand, as a method of providing an insulating layer in a slot, a method of using a heat-resistant insulating material alone, a method of melting a resin of a welding layer, and filling between enameled wires and between a coil and an iron core (Reference 1) , A method using an insulating sheet in which polyethylene naphthalate films are bonded to both sides of a polyethylene terephthalate film (Document 2), a fiber reinforced plastic film base obtained by impregnating a nonwoven fabric or a woven fabric of inorganic fibers and / or organic fibers with a resin. There is a method of using insulating paper having a multilayer structure in which an exterior material is laminated on one side or both sides of an interior material made of a material (Reference 3).

  However, in these conventional methods, the insulating layer becomes thick, and the space through which the enamel wire is inserted is limited. Further, when the enameled wire is inserted into the slot, the insulating layer is broken due to the contact between the enameled wire and the insulating layer.

JP-A-9-308158 JP-A-10-304614 JP 2004-146093 A

Accordingly, the present invention is thin, and to provide a method for producing a flexible and form with excellent insulating sheet stability rotary electric machine and the rotary electric machine.

  As a result of intensive studies, the present inventor has found that the above problem can be solved by an insulating sheet composed of three layers of an insulating material, a resin sheet, and one of an insulating material and a functional agent.

  That is, the following problems can be solved by the following invention.

(1) A rotating electrical machine in which an insulating sheet is disposed in a slot so as to cover an inner peripheral surface of the slot, and the insulating sheet includes an insulating material, a resin sheet made of an epoxy resin composition, and an insulating material. And the epoxy resin composition contains (a) an epoxy resin, (b) a curing agent, and (c) a phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer. The component (a) is a trishydroxyphenylmethane type epoxy resin, and the component (b) contains 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide. Rotating electric machine characterized by that.

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( 2 ) The said (b) component in the said insulating sheet is 10 (2,5-dihydroxyphenyl) -10H-9 oxa-10-phosphaphenanthrene-10-oxide and the other hardening | curing agent in the compounding ratio. The rotating electrical machine according to ( 1 ), characterized in that it is blended in a mass ratio of 50:50 to 95: 5.

( 3 ) The rotating electrical machine according to ( 2 ) , wherein the other curing agent of the component (b) in the insulating sheet is a biphenyl novolac type phenol resin.

( 4 ) In the insulating sheet, the blending ratio of the component (a), the component (b), and the component (c) is such that the component (b) is 40 to 140 parts by mass with respect to 100 parts by mass of the component (a). (C) Component is 5-300 mass part, The rotary electric machine in any one of ( 1 ) thru | or ( 3 ) characterized by the above-mentioned.

( 5 ) The rotating electrical machine according to any one of (1) to ( 4 ), wherein at least one of the insulating materials adjacent to the resin sheet in the insulating sheet is an aramid paper.

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( 6 ) An insulating process in which the insulating sheet according to any one of (1) to ( 5 ) is disposed in the slot of the rotating electrical machine so as to cover the inner peripheral surface of the slot, and a winding is disposed in the slot. And a sealing step of sealing the winding by inserting a sealing agent containing an epoxy resin into the slot after being inserted into the insulating sheet.

Rotating electrical machine of the present invention, the insulating sheet that can realize uniform insulating layer a thin film, it can be improved while the linear factor holding the insulation reliability. Further, since the cut with reliably secure the insulating sheet to the rotating electric machine of a slot, thereby improving the workability. Furthermore, the workability | operativity of rotary electric machine manufacture can be improved with the insulating sheet which has flexibility and form stability .

The best embodiment of the rotating electrical machine according to the present invention is a rotating electrical machine in which an insulating sheet is disposed in a slot so as to cover the inner peripheral surface of the slot, and the insulating sheet is made of an aramid paper. And a resin sheet made of an epoxy resin composition and an insulating material made of aramid paper. The epoxy resin composition comprises (a) an epoxy resin, (b) a curing agent, and (c) a phenolic hydroxyl group. Containing aromatic polyamide-polybutadiene-acrylonitrile copolymer, (a) component is a trishydroxyphenylmethane type epoxy resin, (b) component is 10 (2,5-dihydroxyphenyl) -10H-9 oxa- 10-phosphaphenanthrene-10-oxide, and the component (b) is 10 (2,5-dihydroxyphenyl) -10H- Oxa-10-phosphaphenanthrene-10-oxide and other curing agents are blended in a mass ratio of 50:50 to 95: 5, and other components of component (b) The curing agent is a biphenyl novolac type phenol resin, and the blending ratio of the component (a), the component (b), and the component (c) is 40 to 140 masses of the component (b) with respect to 100 parts by mass of the component (a). Part and (c) component are made to be the range of 5-300 mass parts.

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  The best embodiment of the method for manufacturing a rotating electrical machine according to the present invention includes an insulating step in which the insulating sheet is disposed in a slot of the rotating electrical machine so as to cover an inner peripheral surface of the slot, and a winding is disposed in the slot. After passing through the insulating sheet, a sealing step is performed in which a sealing agent containing an epoxy resin is put into the slot and the winding is sealed.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

[Test Example 1]
Next, a method for manufacturing the rotating electrical machine according to the embodiment will be described.
FIG. 1 is a cross-sectional view schematically showing a cross section of the slot 20 of the rotating electrical machine. The insulating sheet 10 is disposed in the slot 20 so as to cover the inner peripheral surface of the slot. At this time, the end of the insulating sheet 10 is overlapped so that there is no gap. Then, after the bundle of windings 22 is inserted into the insulating sheet 10, a sealing agent containing an epoxy resin is put into the slot 20 to seal the windings 22. Similarly, the insulating sheet 10 is disposed in the other slot of the rotating electrical machine, and after inserting the winding wire 22, a sealing agent is inserted to seal the winding wire 22. Since the epoxy resin composition of the resin sheet 14 constituting the insulating sheet 10 is compatible with the epoxy resin in the sealant, the winding 22 can be more effectively fixed in the slot 20.
A sectional view of the rotating electrical machine 30 obtained in this way is shown in FIG. In FIG. 2, a large number of slots including the slot 20 are arranged in an annular shape. The rotary electric machine 30 has a hollow space indicated by A in FIG. 2, and the insulating sheet 10 is disposed in this space in the same manner as the slot 20, and the winding wire 22 may be inserted into the insulating sheet 10. it can.
As shown in FIG. 3 , the insulating sheet 10 is configured by laminating an insulating material 12, a resin sheet 14, and an insulating material 16 in this order.

  As the insulating material 12, a woven fabric, a nonwoven fabric or a film made of an electrically insulating resin can be used.

  Examples of the electrically insulating resin that can be used in this example include polyimide film, PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PBT (polybutylene terephthalate), polyester, polyparabanic acid, polyetheretherketone, polyphenylene sulfide, Aramids, liquid crystal polymers and the like are exemplified, and among them, polyimide, aramid and liquid crystal polymers are preferable in view of heat resistance, dimensional stability, mechanical properties and the like. The thickness of the insulating material 12 is usually in the range of 4.2 to 75 μm, but an appropriate thickness may be used as necessary. Further, one or both surfaces of these insulating materials 12 may be subjected to a surface treatment such as a low temperature plasma treatment, a corona discharge treatment, or a sand blast treatment.

  Hereinafter, a method for manufacturing the insulating sheet 10 according to this example will be described. A coating liquid composed of the epoxy resin composition of this example, which will be described later, was prepared by the following procedure, and this coating liquid was woven, nonwoven fabric or non-woven fabric composed of an electrically insulating resin using a roll coater, a comma coater or the like. Apply to film.

[Preparation of coating solution]
(1) A phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer, an inorganic filler used as required, and a coupling agent are placed in a solvent and stirred.

  (2) A curing agent is added to (1) and further mixed.

  (3) Next, in (2), an epoxy resin dissolved in a solvent is added and mixed uniformly.

  This is passed through an in-line dryer and heat-treated at 40 to 160 ° C. for 1 to 20 minutes to remove the solvent in the coating liquid composed of the epoxy resin composition, thereby forming the resin sheet 14. On the resin sheet surface of the insulating sheet 10, a release material may be pressure-bonded and laminated with a heating roll as desired. The release materials that can be used at this time include polyethylene film, polypropylene film, polymethylpentene (TPX) film, PET film, polyethylene film with silicone release agent, polypropylene film and PET film, polyethylene resin-coated paper, polypropylene resin coat Paper and PET resin-coated paper can be used, and the release material has a film-based thickness of 13 to 75 μm and a paper-based thickness of 50 to 200 μm. used.

  Generally the application | coating thickness of the resin sheet 14 should just be 5-100 micrometers in a dry state.

  In addition, when the thickness of the woven fabric, nonwoven fabric, or film made of the electrically insulating resin to be used is less than 25 μm, the woven fabric made of the electrically insulating resin is used for the film transportability at the time of application and the suppression of smearing of the resin sheet. It is preferable to apply the coating liquid after reinforcing the surface of the nonwoven fabric or film on the side opposite to the surface on which the resin sheet is formed with a carrier sheet or the like provided with an adhesive layer on the substrate.

  In this embodiment, the insulating material 12 is an aramid paper using an aramid film as an electrically insulating film.

  The resin sheet 14 is made of an epoxy resin composition. This epoxy resin composition contains (a) an epoxy resin, (b) a curing agent, and (c) a phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer, and (a) the component is trishydroxyphenylmethane. Type epoxy resin, and the component (b) contains 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide. The trishydroxyphenylmethane type epoxy resin used in this example is represented by the following chemical formula 1.

  As this epoxy resin, those which are solid at normal temperature are preferred, and those having an epoxy equivalent of 190 g / eq or less are particularly preferred from the viewpoint of heat resistance and flame retardancy. In addition, the epoxy resin may be another epoxy resin within a range not inhibiting the present embodiment, for example, bisphenol A type epoxy resin, bisphenol F type epoxy resin, phenol novolac type or cresol novolac type epoxy resin, gypsum dry type epoxy resin, hydrogenated bisphenol. A-type or AD-type epoxy resin, propylene glycol diglycidyl ether, aliphatic epoxy resin such as pentaerythritol polyglycidyl ether, epoxy resin obtained from aliphatic or aromatic carboxylic acid and epichlorohydrin, aliphatic or aromatic amine, Used in combination with epoxy resins obtained from epichlorohydrin, heterocyclic epoxy resins, spiro ring-containing epoxy resins, epoxy-modified resins, bisphenol S-type epoxy resins, biphenol-type epoxy resins, etc. And it may be.

  Moreover, as a hardening | curing agent used for the epoxy resin composition of a present Example, at least 10 (2,5-dihydroxyphenyl) -10H-9 oxa-10-phosphaphenanthrene-10-oxide is used. The use ratio of the curing agent is preferably such that the phenolic hydroxyl group is 0.5 or more with respect to 1.0 mol of the epoxy group in the epoxy resin. A particularly preferable range is 0.6 or more.

  Furthermore, although 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide may be used alone as the curing agent, it has been conventionally used in epoxy resin compositions. You may use it in combination with a hardening | curing agent, for example, an acid anhydride, imidazoles, a phenolic compound, amides, etc.

  Curing agents used in combination with 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide include, for example, acid anhydrides, amines, imidazoles, dihydroazines, Lewis acids , Bronsted acid salts, polymercaptons, isocyanates, blocked isocyanates, phenol resins and the like. Of these, phenol resins are preferred. Examples of the phenol resin include bisphenol A, bisphenol F, bisphenol S, 4,4′-bisphenol, 2,2′-methylene-bis (4-methyl-6-tert-butylphenol), and 2,2′-methylene. -Bis (4-ethyl-6-tert-butylphenol), 4,4'-butylene-bis (3-methyl-6-tert-butylphenol), 1,1,3-tris (2-methyl-4-hydroxy-) 5-tert-butylphenol), trishydroxymethane, methane, phenyl pyrogallol, phenols having a diisopropylidene skeleton, phenols having a fluorene skeleton such as 1,1-di-4-hydroxyphenylfluorene, phenolized polybutadiene, etc. Polyphenol compounds, phenol, Novolak resin, xylylene skeleton-containing phenol novolak resin, dicyclopentadiene skeleton-containing phenol novolak Examples thereof include novolac resins such as resins and fluorene skeleton-containing phenol novolac resins, and biphenyl novolac type phenol resins are particularly preferred from the standpoint of balance between toughness and flexibility. This biphenyl novolac type phenol resin is represented by the following chemical formula 2.

（式中ｎは０．１以上である。）

(In the formula, n is 0.1 or more.)

  When 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide is used in combination with another curing agent, the blending ratio is 50:50 to 95: 5 by mass ratio. Range. When the amount of the other curing agent is larger than this range, the flame retardancy is lowered, and when it is less than this range, an effect commensurate with the blending cannot be obtained. A preferable blending ratio is in the range of 50:50 to 70:30.

  The phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer used in the epoxy resin composition of this example is a dicarboxylic acid component having a phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymeric hydroxyl group, for example, , 5-hydroxyisophthalic acid, 4-hydroxyisophthalic acid, 2-hydroxyisophthalic acid, 3-hydroxyphthalic acid, 2-hydroxyterephthalic acid, dicarboxylic acids having no phenolic hydroxyl group include phthalic acid, isophthalic acid, terephthalic acid Diamine for dicarboxyl naphthalene, succinic acid, fumaric acid, glutaric acid, adipic acid, 1,3-dichlorohexanedicarboxylic acid, 4,4'-diphenyldicarboxylic acid, 3,3'-methylenedibenzoic acid, etc. For example, , 3′-diamine-4,4′-dihydroxyphenylmethane, 2,2-bis (3-amino-4-hydroxyphenyl) hexafluoropropane, 2,2-bis (3-amino-4-hydroxyphenyl) dichloromethane 3,4-diamino-1,5-benzenediol, 3,3′-hydroxy-4,4′-diaminobisphenyl, 3,3′-diamino-4,4′-dihydroxybiphenyl, 2,2-bis (3-amino-4-hydroxyphenyl) ketone, 2,2-bis (3-amino-4-hydroxyphenyl) sulfide, 2,2-bis (3-amino-4-hydroxyphenyl) ether, 2,2- Bis (3-amino-4-hydroxyphenyl) sulfone, 2,2-bis (3-amino-4-hydroxyphenyl) propane, 2,2-bis (3 Hydroxy-4-aminophenyl) methane and other diamines that do not contain phenolic hydroxyl groups include 3,3'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 4,4'-diaminodiphenyl ether, diaminonaphthalene, piperazine, hexanet Range amine, tetramethylenediamine, m-xylenediamine, 4,4'-diaminodiphenylmethane, 4,4'-diaminobenzophenone, 2,2'-bis (4-aminophenyl) propane, 3,3'-diaminodiphenylsulfone 3,3′-diaminodiphenyl and the like, and these are added to nitrogen in an organic solvent represented by N-methyl-2-pyrrolidone, for example, using a condensing agent in the presence of a phosphite and a pyridine derivative. Stirring and shrinking under an inert atmosphere such as A combination reaction is performed to produce a polyamide-polybutadiene-acrylonitrile copolymer containing a phenolic hydroxyl group. Among them, it is preferable to use a compound represented by the following chemical formula 3.

（式中、ｘ、ｙ、ｚ、ｌ、ｍ及びｎは、それぞれ平均重合度であって、ｘ＝３〜７、ｙ＝１〜４、ｚ＝５〜１５、ｌ＋ｍ＝２〜２００の整数をそれぞれ示し、ｍ／（ｌ＋ｍ）≧０．０４である。）

(Wherein, x, y, z, l, m and n are average polymerization degrees, and x = 3 to 7, y = 1 to 4, z = 5 to 15, and l + m = 2 to 200 integers. And m / (l + m) ≧ 0.04.)

  This is necessary for imparting flexibility and adhesiveness, and by adding it, it is possible to impart flexibility to the cured product and at the same time increase the adhesive strength with the windings and slots. The blending ratio of the phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer is preferably in the range of 5 to 300 parts by mass with respect to 100 parts by mass of the total amount of the epoxy resin and the curing agent. If the amount of the phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer is less than this range, the flexibility and adhesiveness are lowered, and if it exceeds this range, the electrical properties are lowered, which is not preferable. A particularly preferred blending ratio is in the range of 10 to 150 parts by mass from the viewpoints of flexibility, adhesiveness, and electrical characteristics.

  Moreover, another additive can be added to the epoxy resin composition of a present Example as needed.

  Examples of the additive include phosphorus compounds such as triphenylphosphine, for example, triethylamine, tetraethanolamine, 1,8-diaza-bicyclo [5.4.0] -7-undecene (DBU), N, N-dimethyl. Tertiary amine compounds such as benzylamine, 1,1,3,3-tetramethylguanidine, 2-ethyl-4-methylimidazole, N-methylpiperazine, such as 1,8-diaza-bicyclo [5.4. 0] -7-undecenium tetraphenylborate and other hardening compounds such as boron compounds, plasticizers such as natural waxes, synthetic waxes and metal salts of long-chain aliphatic acids, acid amides, esters, Release agents such as paraffins, stress relaxation agents such as nitrile rubber and butadiene rubber, antimony trioxide, antimony pentoxide, tin oxide, tin hydroxide, Inorganic flame retardants such as molybdenum bromide, zinc borate, barium metaborate, red phosphorus, aluminum hydroxide, magnesium hydroxide, calcium aluminate, brominated flame retardants such as tetraprobisbisphthalic anhydride, hexapromobenzene, brominated phenol novolac Combustion agents, silane coupling agents, titanate coupling agents, coupling agents such as aluminum coupling agents, fused silica, crystalline silica, low α-ray silica, glass flakes, glass beads, glass balloons, talc, alumina, Metal powder such as calcium silicate, aluminum hydroxide, calcium carbonate, barium sulfate, magnesia, silicon nitride, boron nitride, ferrite, rare earth cobalt, gold, silver, nickel, copper, lead, iron powder, iron oxide, sand iron, Inorganic filler such as graphite, carbon, valve, chrome-lead, etc. or conductive Particles, coloring agents such as dyes and pigments, carbon fibers, glass fibers, boron fibers, silicon carbide fibers, alumina fibers, silica alumina fibers and other inorganic fibers, aramid fibers, polyester fibers, cellulose fibers, carbon fibers, etc. Organic fibers, oxidation stabilizers, light stabilizers, moisture resistance improvers, thixotropy imparting agents, diluting agents, antifoaming agents, other various resins, tackifiers, antistatic agents, lubricants, UV absorbers, etc. Can be mentioned. Among them, the silane coupling agent is preferably used in terms of adhesion between the epoxy resin and the filler. Moreover, it is preferable to use aluminum hydroxide etc. when providing a flame retardance and flow resistance.

  The epoxy resin composition of this example can be obtained by mixing an epoxy resin, a curing agent, a phenolic hydroxyl group-containing polyamide-polybutadiene-acrylonitrile copolymer, and various additives as required. It is set as a coating liquid by mixing uniformly in a solvent in a ratio. Examples of the solvent in this case include organic solvents such as toluene, ethanol, cellosolve, tetrahydrofuran, N-methyl-2-pyrrolidone, and dimethylformamide.

  The preparation of the epoxy resin composition of the present example is mainly performed by heat curing, for example, combined use of a catalyst at around room temperature, room temperature curing caused by oxygen and moisture, photocuring caused by an acid generated by ultraviolet irradiation, etc. It is also possible to do.

  The insulating material 16 has the same configuration as the insulating material 12, but an electrically insulating resin different from the insulating material 12 may be used.

Next, the insulation sheet 10 of the test examples 1-3 and the insulation sheet of the comparative examples 1-3 are created as a sample, and six items of a flame retardance, a bendability, an electrical property, heat resistance, embedding property, and a bleed-out property are shown. Was evaluated. These items were evaluated by the following methods.

(1) Flame retardancy The produced insulating sheet was pressed and cured at 180 ° C. under a load of 40 kgf / cm ² for 60 minutes, and the flame retardancy of the sample was evaluated according to the UL94 test method.
○: VTM-0
Δ: VTM-1
X: VTM-2

(2) Bending property The produced insulating sheet was pressed and cured at 180 ° C. under a load of 40 kgf / cm ² for 60 minutes, and the state where it was bent at 180 ° was visually evaluated according to the following criteria.
○: No cracks are observed in the bent part.
X: Generation | occurrence | production of a crack is seen in a bending part.

(3) Electrical characteristics The dielectric breakdown voltage of each insulation sheet was measured by the dielectric breakdown voltage measurement method based on JIS C 2317.

(4) Heat resistance (glass transition temperature)
The glass transition temperature was measured by differential scanning calorimetry (DSC).

(5) Exudation property An insulating sheet cut into 40 mm square was hot-pressed at 180 ° C. for 1 hour at 40 kgf / cm 2, and the shape after curing was observed.
○: Within 40 ± 3 mm square ×: 44 mm square or more

Specifically, the insulating sheet 10 of Test Example 1 was produced by the following method.

  300 parts by mass of phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer (solid content 40% DMF solution product), 100 parts by mass of hydroxyphenylmethane type epoxy resin (manufactured by Nippon Kayaku Co., Ltd., trade name “EPPN502H”), Curing agent [10 (2,5-dihydroxyphenyl) -10H-9 oxa-10-phosphaphenanthrene-10-oxide (manufactured by Sankosha, trade name “HCA-HQ”) 65 parts by mass and biphenyl novolac type phenolic resin ( Meiwa Kasei Co., Ltd., trade name “MEH-7785-3H”) 30 parts by mass] 95 parts by mass and 3 parts by mass of triphenylphosphine were mixed and dissolved in 400 parts by mass of DMAC (dimethylacetamide) to obtain a resin sheet-forming coating solution. Prepared.

  This coating solution is applied to one side of an aramid film (manufactured by DuPont Teijin Advanced Paper Co., Ltd., trade name “NOMEX 410”, thickness 50 μm), dried (110 ° C., 3 minutes), and then further applied to the coated surface. (DuPont Teijin Advanced Paper Co., Ltd., trade name “NOMEX 410”, thickness 50 μm) was heated and pressurized at 120 ° C. to produce an insulating sheet having a resin sheet thickness of about 30 μm and a total thickness of 130 μm.

[Test Example 2]
The insulating sheet of Test Example 2 was produced by the following method.

In Test Example 1, the curing agent was 95 parts by mass of 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide (manufactured by Sankosha, trade name “HCA-HQ”), An insulating sheet was produced in the same manner as in Test Example 1 except that the biphenyl novolac type phenol resin was not used.

[Test Example 3]
The insulating sheet of Test Example 3 was produced by the following method.

In Test Example 1, the curing agent was 47.5 parts by mass of 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide (manufactured by Sankosha, trade name “HCA-HQ”). An insulating sheet was prepared in the same manner as in Test Example 1 except that 47.5 parts by mass of biphenyl novolac type phenolic resin (Maywa Kasei Co., Ltd., trade name “MEH-7851-3H”) was used.

[Comparative Example 1]
The insulating sheet of Comparative Example 1 was produced by the following method.

In Test Example 1, the epoxy resin of bisphenol A type epoxy resin except that the (Dainippon Ink and Chemicals, Inc., trade name "EPICLON850S") was prepared insulating sheet in the same manner as all Test Example 1.

[Comparative Example 2]
The insulating sheet of Comparative Example 2 was produced by the following method.

In Test Example 1, 130 parts by mass of a biphenyl novolac type phenol resin was used as a curing agent, and 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide (trade name “HCA-”) was used. HQ ") An insulating sheet was produced in the same manner as in Test Example 1 except that 85 parts by mass was not used.

[Comparative Example 3]
The insulating sheet of Comparative Example 3 was produced by the following method.

In Test Example 1, the phenolic hydroxyl group-containing aromatic polyamide - was except for using no acrylonitrile copolymer in the same manner as all Test Example 1 to prepare a dielectric sheet - polybutadiene.

Table 1 shows the results of evaluation of the insulating sheets of Test Examples 1 to 3 and the insulating sheets of Comparative Examples 1 to 3.

[Comparative Example 4]
The following was used for the insulating sheet of Comparative Example 4.

  Aramid film (manufactured by DuPont Teijin Advanced Paper, trade name “NOMEX 410”, thickness 130 μm)

Table 1 shows the evaluation results of the insulating sheets of Test Examples 1 to 3 and the insulating sheets of Comparative Examples 1 to 4.

From the results in Table 1, it can be seen that the insulating sheets according to Test Examples 1 to 3 of the present invention have performances satisfying both flame retardancy and flexibility.

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Insulation sheet is not limited to the above embodiment, may be coated with a resin sheet to an insulating material, it may also be prepared by thermal lamination. Further, the curing process may be taken or not taken.

Since the insulating sheets of the examples are thinner and more uniform than conventional ones, improvement in insulation reliability and line area ratio can be expected. Therefore, it is possible to insert more windings into the slot than before. In addition, since it can be securely fixed to the slot, improvement in workability when manufacturing a rotating electrical machine can be expected. In addition, since the insulating sheet of the present invention is excellent in flexibility and shape stability, it does not break when the winding is passed through the slot, and improvement in workability can be expected. Since it is possible to insulate the edge portion, an improvement in edge coverage can be expected.

In addition, as shown in FIG. 4 , the insulating sheet of the example may use a functional material 18 instead of the insulating material 16. Since this insulating sheet 40 includes the functional material 18, it is excellent in slipping and scratch resistance.

  In addition, this invention is not limited to the said Example, You may use insulating materials other than an aramid paper, and may use another epoxy resin composition. Moreover, an enameled wire etc. can be used for a winding.

When the insulating sheet is disposed in the slot of the rotating electrical machine, as shown in FIG. 1 , the end-to-end overlapping position may be located in the slot opening or other than the slot opening. You may do it.

The rotary electric machine according to another embodiment of the present invention, for the insulation of the core 40 as shown in FIG. 5, Ru der those using the insulating sheet. In this case, the insulating sheet may be disposed so as to cover the core surface 41 or may be disposed so as to be bent from the core surface 41 to the core inner surface 42. Furthermore, an insulating sheet may be disposed on the core inner surface 42 as in the slot described above.

Sectional drawing which shows typically the rotary electric machine which concerns on the Example of this invention. The perspective view which shows typically the core of the rotary electric machine which concerns on the Example of this invention. Sectional drawing which shows typically the insulating sheet which concerns on the Example of this invention. Sectional drawing which shows typically the insulating sheet which concerns on the other Example of this invention. Sectional drawing which shows typically the slot in the rotary electric machine which concerns on the other Example of this invention.

DESCRIPTION OF SYMBOLS 10, 40 ... Insulating sheet 12, 16 ... Insulating material 14 ... Resin sheet 18 ... Functional material 20 ... Slot 22 ... Winding 30 ... Rotating electric machine 40 ... Core 41 ... Core surface 42 ... Core inner surface

Claims (6)

Insulation sheet is a disposed that have rotary electric machine so as to cover the inner peripheral surface of the slot in the slot,
The insulating sheet is formed by laminating an insulating material, a resin sheet made of an epoxy resin composition, and an insulating material in three layers,
The epoxy resin composition contains (a) an epoxy resin, (b) a curing agent, and (c) a phenolic hydroxyl group-containing aromatic polyamide-polybutadiene-acrylonitrile copolymer, and the component (a) is trishydroxyphenyl. A rotating electrical machine characterized by being a methane type epoxy resin, wherein the component (b) contains 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide . In claim 1 ,
In the insulating sheet, the component (b) is composed of 10 (2,5-dihydroxyphenyl) -10H-9oxa-10-phosphaphenanthrene-10-oxide and other curing agents in a mass ratio. A rotating electrical machine characterized by being blended in a range of 50:50 to 95: 5. In claim 2 ,
Rotating electric machine, wherein the in the insulating sheet, the other curing agent for the component (b) is a biphenyl novolak type phenolic resin. In any one of Claims 1 thru | or 3 ,
In the insulating sheet, the blending ratio of the component (a), the component (b), and the component (c) is 40 to 140 parts by mass of the component (b) with respect to 100 parts by mass of the component (a), (c). A rotating electrical machine characterized in that the component is in the range of 5 to 300 parts by mass. In any one of Claims 1 thru | or 4 ,
Rotating electric machine, wherein the in the insulating sheet, at least one of said insulating material adjacent to the resin sheet is an aramid paper. An insulating step of disposing the insulating sheet according to any one of claims 1 to 5 in a slot of a rotating electric machine so as to cover an inner peripheral surface of the slot; and a winding wire disposed on the insulating sheet disposed in the slot After the insertion, a sealing step including an epoxy resin in the slot and sealing the winding,
The manufacturing method of the rotary electric machine characterized by having.

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