JP5330682B2 - Slimming peeling remover and slime peeling removing method - Google Patents
Slimming peeling remover and slime peeling removing method Download PDFInfo
- Publication number
- JP5330682B2 JP5330682B2 JP2007326273A JP2007326273A JP5330682B2 JP 5330682 B2 JP5330682 B2 JP 5330682B2 JP 2007326273 A JP2007326273 A JP 2007326273A JP 2007326273 A JP2007326273 A JP 2007326273A JP 5330682 B2 JP5330682 B2 JP 5330682B2
- Authority
- JP
- Japan
- Prior art keywords
- slime
- peeling
- magnesium oxide
- magnesium
- granular material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 18
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 42
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 42
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000008187 granular material Substances 0.000 claims abstract description 40
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 29
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 29
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 29
- 241000894006 Bacteria Species 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 230000001580 bacterial effect Effects 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 239000010813 municipal solid waste Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000007789 sealing Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 21
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 17
- 239000011777 magnesium Substances 0.000 description 17
- 229910052749 magnesium Inorganic materials 0.000 description 17
- -1 alkali metal hypochlorite Chemical class 0.000 description 6
- 150000002681 magnesium compounds Chemical class 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 241001148470 aerobic bacillus Species 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 150000004804 polysaccharides Chemical class 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 229910052599 brucite Inorganic materials 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000010794 food waste Substances 0.000 description 2
- 239000010800 human waste Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000011437 Amygdalus communis Nutrition 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Sink And Installation For Waste Water (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
本発明は、排水管などの固体表面に発生しているぬめりを剥離除去するのに有利に用いることができるぬめりの剥離除去剤、及び該ぬめり剥離除去剤を利用したぬめりの剥離除去方法に関するものである。 BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a slime peeling remover that can be advantageously used for peeling and removing slime generated on a solid surface such as a drain pipe, and a slime peel removing method using the slime peel remover. It is.
台所、浴室、洗面所などの水回りの排水管の内部表面には、ぬめりが発生し易い。ぬめりは美感を損ねるだけでなく、異臭の原因となる。このため、排水管に発生したぬめりを剥離除去することが必要となる。 It is easy for slime to occur on the inner surfaces of drainage pipes around water such as kitchens, bathrooms, and washrooms. Slimming not only impairs aesthetics but also causes off-flavors. For this reason, it is necessary to peel and remove the slime generated in the drain pipe.
ぬめりは、食物残渣や人体の老廃物を栄養源として増殖した細菌と、細菌の排出物とを含有する粘性物である。細菌(特に、緑膿菌)の排出物としては、アルギン酸カルシウム塩などの多糖類、タンパク質などが含まれる。このようなぬめりを排水管から剥離除去するためには、ぬめりに含まれるタンパク質あるいは多糖類を分解することが必要となる。 The slime is a viscous substance containing bacteria that have grown from food residues and human waste as nutrients, and bacterial discharge. Bacteria (particularly Pseudomonas aeruginosa) effluents include polysaccharides such as calcium alginate, proteins and the like. In order to peel and remove such slime from the drain pipe, it is necessary to decompose proteins or polysaccharides contained in the slime.
特許文献1には、タンパク質分解能力に優れたぬめり除去剤として、次亜塩素酸アルカリ金属塩を主基材として、N−アシルサルコシン塩、トリアルキルアミンオキシド、又はアルキルスルホン酸塩から選ばれる少なくとも一種の界面活性剤、水酸化アルカリ金属塩、及び水を含有するぬめり除去剤が開示されている。
上記の特許文献1に開示されている次亜塩素酸アルカリ金属塩を有効成分とするぬめり除去剤は、ぬめりの剥離除去に対して即効性はあるが、その除去効果が短いという問題がある。
本発明の目的は、ぬめりの除去効果を長期間にわたって持続させることができるぬめり剥離除去剤を提供することにある。
The slime removing agent containing an alkali metal hypochlorite disclosed in Patent Document 1 as an active ingredient has an immediate effect on peeling peeling of the slime, but has a problem that its removal effect is short.
An object of the present invention is to provide a slime peeling remover capable of maintaining the slime removing effect over a long period of time.
本発明者は、排水管などの固体表面に発生したぬめりに、弱アルカリ性のマグネシウム水溶液を接触させると、ぬめりが固体表面から剥離し易くなることを見出した。そして、ぬめりが発生している排水管の開口部又はその周囲、もしくは排水管内のぬめりの発生位置よりも上流側の位置に、水酸化マグネシウムや酸化マグネシウムを含有する粒状物を設置すると、排水管内を流れる水に、少量ずつ水酸化マグネシウム及び/又は酸化マグネシウムが溶解して、長期間にわたって弱アルカリ性のマグネシウム水溶液をぬめりに接触させることができ、排水管の内部表面を、ぬめりを剥離除去した状態に長期間にわたって維持することが可能となることを確認して、本発明を完成した。なお、ぬめりに弱アルカリ性のマグネシウム水溶液を接触させることによって、ぬめりが固体表面から剥離し易くなるのは、ぬめりの粘性成分の一つであるアルギン酸カルシウム塩のカルシウムイオンがマグネシウムイオンに置換して、アルギン酸が水に溶解するためであると考えられる。 The present inventor has found that when a weakly alkaline magnesium aqueous solution is brought into contact with a slime generated on a solid surface such as a drain pipe, the slime is easily peeled off from the solid surface. And if the granular material containing magnesium hydroxide or magnesium oxide is installed at the upstream side of the opening of the drainage pipe where the slime has occurred or the surrounding area, or the location of the slime in the drainage pipe, In a state where magnesium hydroxide and / or magnesium oxide is dissolved little by little in the water flowing through the water, the weakly alkaline magnesium aqueous solution can be brought into contact with the slime over a long period of time, and the internal surface of the drainage pipe is peeled off and removed. The present invention was completed by confirming that it can be maintained over a long period of time. It should be noted that when the weakly alkaline magnesium aqueous solution is brought into contact with the slime, the slime is easily peeled off from the solid surface because the calcium ions of calcium alginate, one of the viscous components of the slime, are replaced with magnesium ions. This is probably because alginic acid is dissolved in water.
従って、本発明は、水酸化マグネシウム及び/又は酸化マグネシウムを50質量%以上含有する、平均粒子径が0.1〜50mmの範囲にある粒状物を含む、固体表面に形成された細菌と細菌の排出物とを含有するぬめりの剥離除去剤にある。 Therefore, the present invention includes bacteria and bacteria formed on a solid surface, including particulate matter containing 50% by mass or more of magnesium hydroxide and / or magnesium oxide and having an average particle diameter in the range of 0.1 to 50 mm. In slime stripping remover containing effluent.
本発明のぬめり剥離除去剤の好ましい態様は、次の通りである。
(1)粒状物が酸化マグネシウム及び/又は水酸化マグネシウムを90質量%以上含有する。
(2)粒状物が水酸化マグネシウムを50質量%以上含有し、嵩密度が1.0〜2.4g/cm3の範囲にある。
(3)粒状物が酸化マグネシウムを50質量%以上含有し、嵩密度が1.5〜3.5g/cm3の範囲にある。
Preferred embodiments of the slime peel remover of the present invention are as follows.
(1) The granular material contains 90% by mass or more of magnesium oxide and / or magnesium hydroxide.
(2) The granular material contains 50% by mass or more of magnesium hydroxide, and the bulk density is in the range of 1.0 to 2.4 g / cm 3 .
(3) The granular material contains 50% by mass or more of magnesium oxide, and the bulk density is in the range of 1.5 to 3.5 g / cm 3 .
本発明はまた、水酸化マグネシウム及び/又は酸化マグネシウムを50質量%以上含有する、平均粒子径が0.1〜50mmの範囲にある粒状物を、内部表面に細菌と細菌の排出物とを含有するぬめりが発生している排水管の開口部又はその周囲、もしくは排水管内のぬめりの発生位置よりも上流側の位置に設置し、排水管の開口部もしくはその周囲から排水管内に水を流すことによって、水酸化マグネシウム及び/又は酸化マグネシウムを溶解した水をぬめりに接触させることからなる排水管の内部表面に発生したぬめりの剥離除去方法にもある。排水管は、例えば、台所、浴室又は洗面所の排水管である。 The present invention also includes a granular material containing magnesium hydroxide and / or magnesium oxide in an amount of 50% by mass or more and having an average particle size in the range of 0.1 to 50 mm, and bacteria and bacterial effluent on the inner surface. Install the drainage pipe at or around the drainage pipe where the slime occurs, or at the upstream side of the drainage pipe in the drainage pipe, and allow water to flow from the drainage pipe opening or its surroundings into the drainage pipe. There is also a method for peeling and removing the slime generated on the inner surface of the drain pipe, which comprises bringing water in which magnesium hydroxide and / or magnesium oxide is dissolved into contact with the slime. The drain pipe is, for example, a drain pipe of a kitchen, a bathroom, or a toilet.
本発明のぬめり剥離除去剤を、ぬめりが発生している排水管に適用することによって、長期間にわたってぬめりを除去した状態に維持することができる。また、本発明のぬめり剥離除去方法を利用することによって、ぬめりが発生している排水管の内部表面を、ぬめりを剥離除去した状態に長期間にわたって維持することができる。 By applying the slime peeling remover of the present invention to the drainage pipe where the slime is generated, it is possible to maintain the slime removed state for a long period of time. Further, by utilizing the slime peeling and removing method of the present invention, the inner surface of the drainage pipe where the slime is generated can be maintained in a state where the slime is peeled and removed for a long period of time.
本発明のぬめり剥離除去剤は、有効成分として水酸化マグネシウム及び/又は酸化マグネシウムを50質量%以上含有する、平均粒子径(粒子最長部の平均長さ)が0.1〜50mmの範囲にあるマグネシウム含有粒状物からなる。マグネシウム含有粒状物の水酸化マグネシウム及び/又は酸化マグネシウム含有率は、70質量%以上であることが好ましく、80質量%以上であることがより好ましく、90質量%以上であることがさらに好ましく、90〜98質量%の範囲にあることが特に好ましい。粒状物の平均粒子径は、0.5〜20mmの範囲にあることが好ましい。 The slime peeling remover of the present invention contains 50% by mass or more of magnesium hydroxide and / or magnesium oxide as an active ingredient, and has an average particle diameter (average length of the longest part of particles) in the range of 0.1 to 50 mm. It consists of a magnesium containing granular material. The magnesium hydroxide and / or magnesium oxide content of the magnesium-containing granular material is preferably 70% by mass or more, more preferably 80% by mass or more, further preferably 90% by mass or more, It is particularly preferable to be in the range of -98% by mass. It is preferable that the average particle diameter of a granular material exists in the range of 0.5-20 mm.
マグネシウム含有粒状物の形状には特に制限はなく、球状、円柱状、アーモンド状など任意の形状とすることができる。 There is no restriction | limiting in particular in the shape of a magnesium containing granular material, It can be set as arbitrary shapes, such as spherical shape, a column shape, and an almond shape.
マグネシウム含有粒状物は、空隙が多くなり過ぎると強度が低下し、水との接触によって崩壊し易くなる。また、空隙が少なくなり過ぎると水への溶解性が低下する。従って、マグネシウム含有粒状物の嵩密度は重要である。有効成分を水酸化マグネシウムとする水酸化マグネシウム含有粒状物の場合は、嵩密度が1.0〜2.4g/cm3の範囲にあることが好ましい。また、有効成分を酸化マグネシウムとする酸化マグネシウム含有粒状物の場合は、嵩密度が1.5〜3.5g/cm3の範囲にあることが好ましい。 Magnesium-containing granular materials are reduced in strength when there are too many voids, and are easily disintegrated by contact with water. In addition, if the voids are too small, the solubility in water decreases. Therefore, the bulk density of the magnesium-containing granular material is important. In the case of a magnesium hydroxide-containing granular material in which the active ingredient is magnesium hydroxide, the bulk density is preferably in the range of 1.0 to 2.4 g / cm 3 . Moreover, in the case of the magnesium oxide containing granular material which uses magnesium oxide as an active ingredient, it is preferable that a bulk density exists in the range of 1.5-3.5 g / cm < 3 >.
水酸化マグネシウム含有粒状物は、例えば、天然鉱石のブルーサイト(水滑石)を粉砕し分級する方法、あるいは水酸化マグネシウム粉末を造粒する方法により製造することができる。 The magnesium hydroxide-containing granular material can be produced by, for example, a method of pulverizing and classifying brucite (water talc) of natural ore or a method of granulating magnesium hydroxide powder.
造粒により水酸化マグネシウム含有粒状物を製造するのに用いる水酸化マグネシウム粉末は、海水、かん水及び苦汁などのマグネシウムイオンを含有する水溶液に石灰乳などのアルカリ性剤を添加することによって得られたものであることが好ましい。 Magnesium hydroxide powder used to produce magnesium hydroxide-containing granules by granulation was obtained by adding an alkaline agent such as lime milk to an aqueous solution containing magnesium ions such as seawater, brine and bitter juice. It is preferable that
酸化マグネシウム含有粒状物は、例えば、マグネサイト(菱苦土鉱)及びブルーサイト(水滑石)などのマグネシウム含有天然鉱石を焼成して得た酸化マグネシウム塊状物を粉砕し分級する方法、加熱によって酸化マグネシウムを生成するマグネシウム化合物の粉末を加熱して焼結させる方法、あるいは酸化マグネシウム粉末を造粒する方法により製造することができる。 Magnesium oxide-containing granular material is, for example, a method of pulverizing and classifying a magnesium oxide lump obtained by firing magnesium-containing natural ores such as magnesite (rhizolite) and brucite (water talc), and oxidizing by heating. It can be produced by a method of heating and sintering a powder of a magnesium compound that produces magnesium, or a method of granulating a magnesium oxide powder.
酸化マグネシウム含有粒状物の製造に用いるマグネシウム化合物粉末の例としては、水酸化マグネシウム粉末、炭酸マグネシウム粉末、硫酸マグネシウム粉末及び塩化マグネシウム粉末を挙げることができる。マグネシウム化合物粉末を用いて酸化マグネシウム含有粒状物を製造するに際しては、マグネシウム化合物粉末を造粒した後に加熱して焼結させるか、もしくはロータリーキルンを用いて、マグネシウム化合物粉末を造粒しながら加熱して焼結させることが好ましい。マグネシウム化合物粉末の加熱温度は、1400℃以上であることが好ましく、1600〜2000℃の範囲にあることが特に好ましい。 As an example of the magnesium compound powder used for manufacture of a magnesium oxide containing granular material, magnesium hydroxide powder, magnesium carbonate powder, magnesium sulfate powder, and magnesium chloride powder can be mentioned. When producing a magnesium oxide-containing granule using a magnesium compound powder, the magnesium compound powder is granulated and then heated and sintered, or a magnesium kiln powder is heated while granulating using a rotary kiln. Sintering is preferred. The heating temperature of the magnesium compound powder is preferably 1400 ° C. or higher, and particularly preferably in the range of 1600 to 2000 ° C.
造粒により酸化マグネシウム含有粒状物を製造するのに用いる酸化マグネシウム粉末は、軽焼酸化マグネシウム粉末であることが好ましい。 The magnesium oxide powder used for producing the magnesium oxide-containing granule by granulation is preferably a lightly burned magnesium oxide powder.
水酸化マグネシウムと酸化マグネシウムとを含む粒状物は、例えば、水酸化マグネシウム含有粒状物を焼成して、水酸化マグネシウムの一部を酸化マグネシウムとする方法、酸化マグネシウム含有粒状物を水に接触させて、酸化マグネシウムの一部を水酸化マグネシウムとする方法、水酸化マグネシウム粉末と酸化マグネシウム粉末との混合物を造粒する方法により製造することができる。 The granular material containing magnesium hydroxide and magnesium oxide is, for example, a method in which a magnesium hydroxide-containing granular material is baked and a part of magnesium hydroxide is converted to magnesium oxide, and the magnesium oxide-containing granular material is brought into contact with water. Further, it can be produced by a method in which a part of magnesium oxide is magnesium hydroxide, or a method in which a mixture of magnesium hydroxide powder and magnesium oxide powder is granulated.
水酸化マグネシウム粉末、酸化マグネシウム粉末及びマグネシウム化合物粉末の造粒には、加圧形成法や押出法などの公知の造粒法を用いることができる。造粒の際には、必要に応じて水や糖蜜などのバインダーを使用してもよい。 For granulating the magnesium hydroxide powder, the magnesium oxide powder and the magnesium compound powder, a known granulation method such as a pressure forming method or an extrusion method can be used. During granulation, a binder such as water or molasses may be used as necessary.
本発明のぬめり剥離除去剤には、本発明の効果を損なわない範囲で、次亜塩素酸アルカリ金属塩、好気性細菌及び抗菌剤などの補助成分を配合することができる。 The slime peel remover of the present invention can contain auxiliary components such as alkali metal hypochlorite, aerobic bacteria and antibacterial agents, as long as the effects of the present invention are not impaired.
次亜塩素酸アルカリ金属塩は、ぬめりに含まれる多糖類やタンパク質を分解する作用がある。次亜塩素酸アルカリ金属塩の例としては、次亜塩素酸ナトリウム及び次亜塩素酸カリウムを挙げることができる。 The alkali metal hypochlorite has an action of degrading polysaccharides and proteins contained in the slime. Examples of the alkali metal hypochlorite include sodium hypochlorite and potassium hypochlorite.
好気性細菌は、ぬめりを形成する細菌の栄養源となる食物残渣や人体の老廃物を、異臭を放出せずに分解する作用がある。好気性細菌の例としては、枯草菌及びEM菌を挙げることができる。 Aerobic bacteria have the effect of breaking down food residues and human waste, which are nutrients for slime-forming bacteria, without releasing off-flavors. Examples of aerobic bacteria include Bacillus subtilis and EM bacteria.
抗菌剤は、ぬめりを形成する細菌の増殖を抑制して、ぬめりの発生を抑える作用がある。抗菌剤の例としては、酸化チタン、銅及び銀を挙げることができる。 The antibacterial agent has an action of suppressing the occurrence of slime by suppressing the growth of bacteria forming the slime. Examples of antibacterial agents include titanium oxide, copper and silver.
補助成分は、マグネシウム含有粒状物と分離していてもよい。また、補助成分をマグネシウム含有粒状物の表面の一部もしくは全体に担持させて、補助成分とマグネシウム含有粒状物とを一体化してもよい。補助成分の使用量は、マグネシウム含有粒状物と補助成分との質量比で、50:50〜99:1(マグネシウム含有粒状物:補助成分)の範囲となる量であることが好ましい。 The auxiliary component may be separated from the magnesium-containing granular material. Alternatively, the auxiliary component and the magnesium-containing granular material may be integrated by supporting the auxiliary component on a part or the whole of the surface of the magnesium-containing granular material. It is preferable that the usage-amount of an auxiliary | assistant component is an amount used as the mass ratio of a magnesium containing granular material and an auxiliary component, and becomes the range of 50: 50-99: 1 (magnesium containing granular material: auxiliary component).
本発明のぬめり剥離除去剤は、台所、洗面所、浴室及び洗濯機の排水管に発生しているぬめりの剥離除去剤として有利に使用することができる。 The slime peeling remover of the present invention can be advantageously used as a peel remover for slime generated in the drain pipes of kitchens, toilets, bathrooms and washing machines.
本発明のぬめり剥離除去剤は、そのままの状態で、あるいは多孔性容器に収容した状態で、ぬめりの発生している排水管に設置することができる。ぬめり剥離除去剤を収容するための多孔性容器としては、合成繊維製網状袋、不織布製袋、及び内部にぬめり剥離除去剤の収容部を有し、該収容部に水を導入するための導水口と、該収容部に導入された水を外部に導出するための導出口とを備えた合成樹脂製ケースを挙げることができる。 The slime peeling remover of the present invention can be installed in the drainage pipe where the slime is generated as it is or in a state of being accommodated in a porous container. The porous container for containing the slime release remover includes a synthetic fiber mesh bag, a non-woven fabric bag, and a container for the release release agent inside, and a guide for introducing water into the container. A synthetic resin case having a water port and a lead-out port for leading the water introduced into the housing part to the outside can be mentioned.
ぬめり剥離除去剤の設置場所は、排水管に流れる水に接する位置であれば特には制限はないが、通常は、排水管の開口部、開口部の周囲、及び排水管内のぬめりの発生位置よりも上流側の位置である。排水管にトラップが付設されている場合には、ぬめり剥離除去剤をトラップの内部、特に封水部に設置してもよい。 There are no particular restrictions on the location where the nail peeling remover is installed, as long as it is in contact with the water flowing through the drainpipe, but it is usually from the opening of the drainpipe, around the opening, and where the slime occurs in the drainpipe. Is also an upstream position. In the case where a trap is attached to the drain pipe, a slime peeling remover may be installed inside the trap, particularly in the sealed portion.
本発明のぬめり剥離除去剤を用いた、ぬめり剥離除去方法の実施態様の例を、図1を用いて説明する。 An example of the embodiment of the slime peeling removal method using the slime peeling removal agent of the present invention will be described with reference to FIG.
図1は、本発明のぬめり剥離除去剤を、台所流し台の排水口に接続するトラップ付き排水管に設置する際の設置例を示す一例の断面図である。
図1において、台所流し台の排水口1と排水管2と間に付設されているトラップ3は、排水口1の縁部にて支持されているゴミ取り用バスケット4、トラップ内壁面に形成されている椀支持部5、椀支持部5にて支持されている椀6、及び水で満たされた封水部7からなる椀トラップ(ベルトラップ)である。ゴミ取り用バスケット4の底部並びにゴミ取り用バスケット4と椀6との間には、ぬめり剥離除去剤8が袋状多孔性容器9に収容された状態で設置されている。さらに、封水部7の排水管2の周囲には、ぬめり剥離除去剤8がドーナツ状の袋状多孔性容器10に収容された状態で設置されている。
FIG. 1 is a cross-sectional view showing an example of installation when the slime peeling remover of the present invention is installed in a drain pipe with a trap connected to a drain outlet of a kitchen sink.
In FIG. 1, a
図1のトラップ付き排水管では、台所流し台の排水口1からトラップ3に流れた水は、ぬめり剥離除去剤8に含まれる水酸化マグネシウム及び/又は酸化マグネシウムを溶解し、弱アルカリ性(pH=8〜11)のマグネシウム水溶液として、トラップ3及び排水管2に流れて、トラップ3及び排水管2の内部表面に発生したぬめりと接触して、ぬめりが剥離除去される。
In the drain pipe with a trap in FIG. 1, the water flowing from the drain outlet 1 of the kitchen sink to the
[実施例1]
ぬめりが排水管に発生している台所流し台を用意した。排水管は、図1に示した椀トラップ付き排水管である。ぬめりは、ゴミ取り用バスケット、椀及び排水管内壁に発生しており、異臭が発生している。台所流し台の平均水道水使用量は120L/日である。
[Example 1]
A kitchen sink with slime in the drain pipe was prepared. The drain pipe is a drain pipe with a trap shown in FIG. The slime is generated in the garbage collection basket, the basket, and the inner wall of the drain pipe, and a strange odor is generated. The average tap water usage of the kitchen sink is 120 L / day.
酸化マグネシウム含有粒状物100gを、塩化ビニル製ネット(網目のサイズ2mm)に収容し、これを上記台所流し台のゴミ取り用バスケットに紐で吊してゴミ取り用バスケットと椀との間に設置し、60日間、この状態で台所流し台を使用した。酸化マグネシウム含有粒状物は、酸化マグネシウム含有率が99質量%、平均粒子径が5mm、そして嵩密度が3.3g/cm3である。この酸化マグネシウム含有粒状物は、海水に石灰乳を投入して、生成した水酸化マグネシウムをろ過、乾燥して製造した水酸化マグネシウム粉末を、ロータリーキルンを用いて、回転造粒しながら1800℃の温度に加熱し、焼結させて製造した粒状物を、篩を用いて分級して製造したものである。
100 g of magnesium oxide-containing granular material is contained in a vinyl chloride net (
酸化マグネシウム含有粒状物の設置後の状態を目視で観察した結果、酸化マグネシウム含有粒状物を設置した翌日には、ゴミ取り用バスケット内のぬめりが消失していた。また、酸化マグネシウム含有粒状物を設置してから4日後には、椀のぬめりが消失していた。さらに、酸化マグネシウム含有粒状物を設置してから7日後には、排水管内壁のぬめりが消失していた。異臭の発生は、酸化マグネシウム含有粒状物を設置した翌日からおさまり、それ以後、異臭は発生しなかった。 As a result of visually observing the state after the magnesium oxide-containing granular material was installed, the slime in the garbage collecting basket disappeared the day after the magnesium oxide-containing granular material was installed. In addition, after 4 days from the installation of the magnesium oxide-containing granular material, the slime of the cocoon disappeared. Furthermore, the sliminess of the inner wall of the drainage pipe disappeared 7 days after the magnesium oxide-containing granular material was installed. The generation of off-flavor was subsided the day after the magnesium oxide-containing granular material was installed, and no off-flavor was generated thereafter.
1 台所流し台の排水口
2 排水管
3 トラップ
4 ゴミ取り用バスケット
5 椀支持部
6 椀
7 封水部
8 ぬめり剥離除去剤
9 袋状多孔性容器
10 ドーナツ状の袋状多孔性容器
DESCRIPTION OF SYMBOLS 1 Drain outlet of
Claims (7)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007326273A JP5330682B2 (en) | 2007-12-18 | 2007-12-18 | Slimming peeling remover and slime peeling removing method |
| TW097148517A TWI480373B (en) | 2007-12-18 | 2008-12-12 | And a method for removing the adhesive from the release agent and the adhesive |
| KR1020080127232A KR101549702B1 (en) | 2007-12-18 | 2008-12-15 | Agent for separating and removing slime and method for separating and removing slime |
| CN200810189556.4A CN101486957B (en) | 2007-12-18 | 2008-12-18 | Agent for separating and removing slime and method for separating and removing slime |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007326273A JP5330682B2 (en) | 2007-12-18 | 2007-12-18 | Slimming peeling remover and slime peeling removing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009149705A JP2009149705A (en) | 2009-07-09 |
| JP5330682B2 true JP5330682B2 (en) | 2013-10-30 |
Family
ID=40890020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007326273A Expired - Fee Related JP5330682B2 (en) | 2007-12-18 | 2007-12-18 | Slimming peeling remover and slime peeling removing method |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5330682B2 (en) |
| KR (1) | KR101549702B1 (en) |
| CN (1) | CN101486957B (en) |
| TW (1) | TWI480373B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009133926A1 (en) * | 2008-05-01 | 2009-11-05 | 宇部マテリアルズ株式会社 | Slime remover, method for removing slime, and kit for preparing aqueous slime remover |
| JP2011140210A (en) | 2009-06-24 | 2011-07-21 | Sumitomo Chemical Co Ltd | Molding and method of manufacturing the same, and catalyst and method of manufacturing the same |
| CN103781976B (en) * | 2011-07-08 | 2015-08-12 | 日本曹达株式会社 | Adapter for slime removal installed in the drain pipe of washing machine or washbasin |
| JP5887126B2 (en) * | 2011-12-15 | 2016-03-16 | 株式会社環境マグネシア | Maintenance and cleaning method for outdoor swimming pool |
| JP5887127B2 (en) * | 2011-12-15 | 2016-03-16 | 株式会社環境マグネシア | Maintenance and cleaning method for outdoor swimming pool |
| KR102120846B1 (en) | 2018-09-06 | 2020-06-09 | 김성오 | Eco-friendly slime removing agent for cooling system |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5738900A (en) * | 1980-08-18 | 1982-03-03 | Nitsupon Teiipooru Kk | Cleaner composition for drainpipe, oil sink or like |
| JPH08165497A (en) * | 1994-12-13 | 1996-06-25 | Kao Corp | Solid germicidal fining composition |
| JP3554603B2 (en) * | 1995-04-03 | 2004-08-18 | 株式会社白石中央研究所 | Slime remover composition and method for producing the same |
| CN1119295C (en) * | 1996-01-04 | 2003-08-27 | 宇部材料工业株式会社 | Magnesium oxide-based modifier for water quality and bottom sediment quality |
| JP2002241207A (en) * | 2001-02-15 | 2002-08-28 | Yahashi Kogyo Kk | Slime-preventing agent and antimicrobial agent |
-
2007
- 2007-12-18 JP JP2007326273A patent/JP5330682B2/en not_active Expired - Fee Related
-
2008
- 2008-12-12 TW TW097148517A patent/TWI480373B/en not_active IP Right Cessation
- 2008-12-15 KR KR1020080127232A patent/KR101549702B1/en not_active Expired - Fee Related
- 2008-12-18 CN CN200810189556.4A patent/CN101486957B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TWI480373B (en) | 2015-04-11 |
| KR101549702B1 (en) | 2015-09-02 |
| JP2009149705A (en) | 2009-07-09 |
| TW200942610A (en) | 2009-10-16 |
| KR20090066224A (en) | 2009-06-23 |
| CN101486957B (en) | 2015-04-29 |
| CN101486957A (en) | 2009-07-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5330682B2 (en) | Slimming peeling remover and slime peeling removing method | |
| JP5469369B2 (en) | Slimming remover and slime removing method | |
| JP5469370B2 (en) | Slimming remover and slime removing method | |
| TWI473876B (en) | Removal of slime removal agent, slime removal and preparation of water-based sludge removal agent | |
| JPH09202706A (en) | Disinfectant cleaner for drainage | |
| JP4887339B2 (en) | Anti-slip device | |
| JP5938431B2 (en) | How to suppress bad smell of grease | |
| CN109942116A (en) | A kind of purification method and domestic sewage purification device of sanitary sewage | |
| JP2009285650A (en) | Method for removing slime, and kit for preparing aqueous slime remover | |
| JP2011057781A (en) | Antibacterial composition | |
| JP2008189560A (en) | Chlorinated isocyanuric acid tablets | |
| JP2003041293A (en) | Slime remover for drainage and slime remover | |
| JP2022025276A (en) | Apparatus for processing used sanitary article | |
| JP2002255546A (en) | Method for producing massive fired calcium | |
| JP5715894B2 (en) | Decomposition and removal method of scum aggregates formed on the surface of sewage in sewage storage tanks of buildings | |
| CN104478110A (en) | Water making machine capable of rapidly changing filter plate and filter element and manufacture method of water making machine | |
| JP2006327364A (en) | Urinary calculus suppression device of toilet for aircraft | |
| JP2004180991A (en) | Washing tank cleaner | |
| JP2013123687A (en) | Method for cleaning swimming pool | |
| JPS60110800A (en) | Detergent | |
| JP2001131533A (en) | Charcoal for cleaning or grinding and cleaning or grinding by using the same | |
| JPH0931495A (en) | Cleaning agent for sink basket and its production | |
| JP2010094608A (en) | Washing-contamination prevention method and washing-contamination prevention system | |
| JPH09206757A (en) | Purifying tool for drain passage or the like | |
| JP2005139871A (en) | Drain port garbage receptacle of quick drainage in kitchen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100720 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120822 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120831 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121030 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130705 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130726 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5330682 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |