JP5360360B2 - DC Streamer Discharge Device and Toxic Substance Removal Device - Google Patents
DC Streamer Discharge Device and Toxic Substance Removal Device Download PDFInfo
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- JP5360360B2 JP5360360B2 JP2008173980A JP2008173980A JP5360360B2 JP 5360360 B2 JP5360360 B2 JP 5360360B2 JP 2008173980 A JP2008173980 A JP 2008173980A JP 2008173980 A JP2008173980 A JP 2008173980A JP 5360360 B2 JP5360360 B2 JP 5360360B2
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- 231100000167 toxic agent Toxicity 0.000 title 1
- 239000003440 toxic substance Substances 0.000 title 1
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000000383 hazardous chemical Substances 0.000 claims description 3
- 208000028659 discharge Diseases 0.000 description 61
- 239000000126 substance Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 11
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 6
- 239000011941 photocatalyst Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 230000002459 sustained effect Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005949 ozonolysis reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 208000012313 wound discharge Diseases 0.000 description 1
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- Physical Or Chemical Processes And Apparatus (AREA)
Description
本発明は直流電流ストリーマ放電での安定した持続性能を得る事が技術的に困難であった問題と電力投入量を増やす事の難易度のために、高効率な有害物質除去装置の開発が出来なかったが、これらの諸問題を解決できる方法である。The present invention is able to develop a highly efficient harmful substance removal device because of the technical difficulty in obtaining a stable sustained performance in DC current streamer discharge and the difficulty in increasing the power input. It was a method that could solve these problems.
近年環境問題が注目されている。有害物質除去装置は環境改善には必要な装置であるが装置自体が使用する電力又使われている資材も問題になってきている。現在普及している白金を主体とした消臭装置もレア.メタル問題と消費電力の問題があり早急な改善が求められている。ストリーマ放電による有害物質除去能力は同電力比でグロー放電に比べ1000倍以上の効果を持っていると言われる。又ストリーマ放電によって生成される(OH)ラジカル、又オゾン分解処理をすることによって生成される(O)ラジカル等が細菌を酸化し死滅させるという能力もあり、現在問題化してきている鳥インフルエンザの空気感染予防にも対処でき有害物質除去能力とともに注目される方式でもある。In recent years, environmental problems have attracted attention. Hazardous substance removing devices are necessary for improving the environment, but the power used by the devices themselves and the materials used are also becoming a problem. Rare deodorizers that are mainly used in platinum are rare. There is a problem of metal and power consumption, and immediate improvement is required. It is said that the ability to remove harmful substances by streamer discharge is more than 1000 times as effective as glow discharge at the same power ratio. In addition, the (OH) radicals generated by streamer discharges and (O) radicals generated by ozonolysis treatment oxidize bacteria and kill them. It is a method that can deal with infection prevention as well as the ability to remove harmful substances.
他の有害物質除去装置に比べ実用化されれば消費電力は10分の1から100分の1程度の消費電力で済むこのことは環境問題を考える上でも重要なことになってきている。これらのメリットが有るにもかかわらず実用化出来なかったのは先にも述べたとおり直流によるストリーマ放電の安定した持続性能が得られない事と電力の投入が出来ないこと、言い換えれば処理能力が低かったことにある。実用化されれば他の放電方式に比べて電源及び放電装置部の製造コストは低く抑えることが出来る。加工技術に特殊性がなく非常に簡単に出来る事もあり処理能力も小さなものから大きなものまで対応が可能であり用途は限りなく考えられる。If it is put into practical use as compared with other harmful substance removing devices, the power consumption is about 1/10 to 1 / 100th of the power. This has become important in considering environmental problems. Despite these merits, it was not possible to put it to practical use, as mentioned earlier, it was impossible to obtain a stable sustained performance of streamer discharge by direct current, and power could not be input, in other words processing power It was low. When put into practical use, the manufacturing cost of the power source and the discharge device can be kept low compared to other discharge methods. There is no special processing technology and it can be very simple, and it can be used from small to large processing capacity.
従来の直流放電素子構造は径が太く1mm程度のピン先をとがらせ隣とのピン間隔を気にせず並べたものや板を平行に並べたもの又筒の中央に線を張ったものなどがあり安定した持続的な放電性能を得ることが出来ず実用化は難しかった。従来の技術を鑑み放電素子のピン形態とピン固定方法と放電素子のピン、配置及び装置そのもの処理能力を高める全体的な構造を検討することにより、従来出来なかった直流ストリーマ放電の安定した持続性能と電流投入量の増大により細菌処理から有害物質高効率除去が出来るようになった。The conventional DC discharge element structure has a large diameter of about 1 mm with a pointed tip that is arranged without worrying about the distance between the adjacent pins, a plate that is arranged in parallel, or a line that is stretched at the center of the cylinder. It was difficult to put to practical use because stable and stable discharge performance could not be obtained. By considering the overall structure of the discharge element pin configuration, pin fixing method, discharge element pin and arrangement, and the device itself processing capacity in view of the conventional technology, the stable sustained performance of DC streamer discharge that could not be achieved before And with the increase of the current input amount, high efficiency removal of harmful substances from bacterial treatment has become possible.
径1.0mm程度のピンの先をとがらせ並べても安定したストリーマ放電を得ることは出来ない。直流電流でストリーマ放電が安定持続性を得られるためのピンの形態と固定方法を鋭意検討した結果、放電素子のピンの形状は径又は幅、厚みを0.5mm以下とし必ずピン間をあける。ピン間の距離はピンの径の数倍程度20の寸法を取り先端がピン同士接触しないよう図3のように直列に並べて固定する。直列に並べたものを放電素子5をロータリー6に複数枚取り付ける。ロータリーを中心にしたガイド筒13筒を配置する。ピンの長さは固定する板21より19の寸法を5mm以上にする。又ファン1を出口に配置し高速気流を流す。ピンの径を細くすること又ピンの間隔をとることで冷却効果を高め電極表面温度があがらないようにすると同時にイオンの電界によるドリ フトを押さえる事が出来、直流ストリーマ放電を安定持続させることが出来る。理想的なピンの形状は径、又は幅、厚みが0.15mm以下を推奨。(ピンの径、並べ方、長さ、固定方法)Even if the tips of pins having a diameter of about 1.0 mm are bent and arranged, a stable streamer discharge cannot be obtained. As a result of diligent examination of the pin configuration and fixing method for achieving stable sustainability of streamer discharge with direct current, the shape of the pin of the discharge element has a diameter or width and a thickness of 0.5 mm or less, and there is always a gap between the pins. The distance between the pins is about 20 times the diameter of the pins, and the tips are fixed in series as shown in FIG. 3 so that the tips do not contact each other. A plurality of discharge elements 5 which are arranged in series are attached to the
放電ピン18の形状は先端をとがらせるのではなく先端を90度でカットする。先端をとがらせると放電による摩耗が早くなる。又先端を磨くとき作業がしにくくなる。又ピンが太いと放電が不安定になり出来るだけ細いピンの方が放電条件が良くなるが耐久性と弾性が必要でありピン径は材質により限定される、(ピンの形状条件)。The shape of the
放電性能を維持するための放電素子の配置は対極面の13筒内面より5mm以上5の放電素子のピン先端が離れるようにする。又12より放電素子に加える電圧は5KV以上かける。この条件以外だと放電の不安定さがあり電流量が増えない。又電圧を掛けすぎても不安定になる。放電距離/電圧が=1.2以下の条件も必要になる。(放電素子の投入電圧と配置条件)The arrangement of the discharge element for maintaining the discharge performance is such that the tip of the pin of the discharge element 5 mm or more and 5 away from the inner surface of the 13 cylinders on the counter electrode surface. Further, the voltage applied to the discharge element from 12 is applied 5 KV or more. Except for this condition, the discharge is unstable and the amount of current does not increase. Moreover, it becomes unstable even if a voltage is applied too much. The condition that the discharge distance / voltage is 1.2 or less is also required. (Discharge element input voltage and placement conditions)
筒の中央に放電素子5を取り付けた6ロータリーを配置することで放電素子が劣化した場合簡単に放電素子を一括して取り外し交換出来る事により、性能の維持が可能になった。簡単に取り外しが出来る構造として電流取り入れ電極軸4をロータリーの中心に配置し電極バネ板17電流分配連結板11を通し放電素子に一括して電流を流し込む方法にした。(着脱可能にした構造)By disposing the 6 rotarys with the discharge element 5 attached to the center of the cylinder, the discharge element can be easily removed and replaced in a batch when the discharge element deteriorates, thereby maintaining the performance. As a structure that can be easily removed, the current intake electrode shaft 4 is arranged at the center of the rotary, and the current is collectively supplied to the discharge element through the
放電素子の電極の汚れは放電電流の低下する原因になり定期的に清掃しクリーンさを保たなければならない。筒型ロータリー放電装置の回転をするという特長を生かして研磨剤を塗布した布又は板の放電ピン清掃板9を薄いバネ板10でロータリの外筒113に固定する。又清掃時にピンが曲がらないため放電素子に平行にピンガイド板26を設置する。ロータリー6を回転させることにより電極ピンの先端を磨くことが出来電流の低下を防ぐことが出来るようにした。(ピン清掃構造)Dirt on the electrodes of the discharge element causes a decrease in the discharge current, which must be cleaned regularly to maintain cleanliness. The discharge pin cleaning plate 9 of cloth or plate coated with abrasive is fixed to the rotary outer cylinder 113 with a
ストリーマ放電の場合放電時に放電音が出る。音を小さくするための方法は色々発表されているが鋭意検討の結果ピンを細くすることで小音になる事を見いだせた。放電素子のピン18径1.0mmと0.15mmの径では出ていた音の比較では径0.15mmにすると3分の1程度以下になる。このことはピン1本から出る放電量の違いからくる。同放電量であれば細いピンを量多く配置し放電量を分散させピン総トータルで同放電量にする事で音を小させる事が出来る。(音を小音にするピンのの形状と配置)In the case of streamer discharge, a discharge sound is emitted during discharge. Various methods for reducing the sound have been announced, but as a result of diligent investigation, it was found that the sound is reduced by making the pin thinner. In comparison of the sound produced when the diameters of the
筒13の汚れの原因なる煙等は(+)に帯電され(−)の電極に引き寄せられる(−)電極側は筒13側になるので筒が汚れることになる。この汚れを取るために筒13の内側に光触媒を塗布する。光触媒はストリーマ放電が出す紫外線によって励起され汚れを分解することになる。(筒の汚れ防止)Smoke or the like causing dirt on the
放電素子の加工方法は線材の場合[図6]のように線材を中間板22にコイルを状態になるように24の治具を使い巻く。但しコイルの巻き方と違うのは線材の径一本分から数本分程度あけて巻かなければならない。巻き終わったら巻いた放電素子を両側固定板21で固定をし巻いた線材(ピン)がずれないようにする。巻いたコイル状の放電素子を抜き指定されたピンの長さに23の部分でカットする。(コイル形態の加工法)
板をプレスする場合指定されたピンの太さと同寸同厚の板を用意し線材と同寸法の間隔と線材と同寸の長さでプレス加工をする線材と同様にプレスしたピン板を中間板22を挟み両側面を21固定板で挟み固定する。(プレス加工によるピンの加工)In the case of a wire rod, the discharge element is processed by using 24 jigs so that the coil is placed on the
When pressing a plate Prepare a plate with the same pin thickness as the specified pin thickness, and press the pin plate pressed in the same way as a wire rod that is pressed with the same distance as the wire rod and the same length as the wire rod. The
始めに(OH)ラジカルとオゾン等が27のラジカル生成空間でストリーマ放電時に生成され有害物質、細菌等を酸化させる初段階処理をする。光触媒フィルター2を紫外線のないところで活性化させるためにオゾン分解フィルター3を光触媒フィルターの手前に配置する。筒13を通過するオゾンはオゾン分解フィルターで分解される。そのときオゾンが分解され活性種の(O)が生成さる。有害物質処理をし余った活性種(OH)と活性種(O)が光触媒フィルターを通過し光触媒を励起させる。この2種類の触媒フィルター効果で再度、有害物質除去処理し効率を高めることが出来る。又この配置を直列に図7のように処理物質の処理濃度に合わせ、ダブルに配置する又は直列に複数本くみあわせる事により有害物質を完全処理することに近づける事が出来る。(ストリーマ放電とオゾン分解フィルター、光触媒フィルターの組み合わせによる有害物質除去高効率化方法)First, (OH) radicals, ozone and the like are generated in the radical generation space of 27 at the time of streamer discharge and are subjected to an initial stage treatment for oxidizing harmful substances, bacteria and the like. In order to activate the photocatalytic filter 2 in the absence of ultraviolet rays, the ozone decomposition filter 3 is disposed in front of the photocatalytic filter. The ozone passing through the
従来から直流ストリーマ放電は大量の有害物質除去に向いている方式だと言われていたが放電の安定さに欠けると同時に電流量の投入に限界があり実用化に問題があった。筒型ロータリーの特長とピンの構造、配置等の工夫により放電の安定した持続性と電流の投入量が自由に増す事が出来た。このことと同時に2種類の触媒フィルターの組み合わせにより細菌及び有害物質の除去効率が高まった。又簡単にして放電素子を交換が出来、放電素子の清掃の自動化が可能になりメンテナンスがらくになりさらに実用化に近づいた。Conventionally, DC streamer discharge was said to be a method suitable for removing a large amount of harmful substances, but the stability of the discharge was lacking, and at the same time, there was a limit to the amount of current input, and there was a problem in practical use. Stable sustainability of the discharge and the amount of input current can be increased freely by the features of the cylindrical rotary, the structure of the pin, and the arrangement. At the same time, the combination of the two types of catalytic filters increased the removal efficiency of bacteria and harmful substances. In addition, the discharge element can be easily replaced, cleaning of the discharge element can be automated, maintenance becomes difficult, and practical use is further approached.
1 処理気体用排気ファン
2 光触媒フィルター
3 オゾン分解触媒フィルター
4 電流供給電極軸
5 放電素子
6 放電素子取り付け用ロータリー
7 ロータリー駆動用モータ
8 本体ケース
9 放電素子ピン清掃板
10 清掃部取り付けバネ板
11 電流分配連結板
12 直流高圧電流取り入れ口(+)電極
13 ロータリーガイド筒
14 直流高圧電流取り入れ口(−)電極
15 ロータリー取り付け用ビス
16 気体の流れ方向
17 電極バネ板
18 放電ピン
19 ピン固定扱よりののピンの長さ
20 ピン間の距離
21 ピン固定側板
22 ピン配置用固定中間板
23 ピン用巻き線カット位置
24 ピン巻き用治具
25 ピン用巻き線
26 ピンそり防止板
27 ラジカル生成空間DESCRIPTION OF SYMBOLS 1 Exhaust fan for process gas 2 Photocatalyst filter 3 Ozone decomposition catalyst filter 4 Current supply electrode shaft 5
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| Application Number | Priority Date | Filing Date | Title |
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| JP2008173980A JP5360360B2 (en) | 2008-06-05 | 2008-06-05 | DC Streamer Discharge Device and Toxic Substance Removal Device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008173980A JP5360360B2 (en) | 2008-06-05 | 2008-06-05 | DC Streamer Discharge Device and Toxic Substance Removal Device |
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| Publication Number | Publication Date |
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| JP2009291579A JP2009291579A (en) | 2009-12-17 |
| JP5360360B2 true JP5360360B2 (en) | 2013-12-04 |
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| JPH08104502A (en) * | 1994-10-04 | 1996-04-23 | Mitsubishi Heavy Ind Ltd | Ozone generator |
| JP2002159562A (en) * | 2000-11-22 | 2002-06-04 | Nippon Paint Co Ltd | Sterilizer using high voltage |
| JP4300737B2 (en) * | 2001-05-21 | 2009-07-22 | ダイキン工業株式会社 | Plasma reactor and air purification device |
| JP4281956B2 (en) * | 2004-02-12 | 2009-06-17 | 国立大学法人室蘭工業大学 | Electrode for corona discharge, corona discharge generator, and chemical substance decomposition apparatus |
| JP4415973B2 (en) * | 2006-06-02 | 2010-02-17 | ダイキン工業株式会社 | Air purification device |
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