JP5388426B2 - Aerosol contents for warm water flush toilet nozzle cleaner - Google Patents
Aerosol contents for warm water flush toilet nozzle cleaner Download PDFInfo
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- JP5388426B2 JP5388426B2 JP2007152530A JP2007152530A JP5388426B2 JP 5388426 B2 JP5388426 B2 JP 5388426B2 JP 2007152530 A JP2007152530 A JP 2007152530A JP 2007152530 A JP2007152530 A JP 2007152530A JP 5388426 B2 JP5388426 B2 JP 5388426B2
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- warm water
- toilet seat
- aerosol
- propellant
- nozzle
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 47
- 239000000443 aerosol Substances 0.000 title claims description 38
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 39
- 239000003380 propellant Substances 0.000 claims description 21
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 14
- 239000000344 soap Substances 0.000 claims description 13
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 239000003915 liquefied petroleum gas Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 7
- 239000004599 antimicrobial Substances 0.000 claims 1
- 239000000417 fungicide Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 24
- -1 terpene hydrocarbons Chemical class 0.000 description 22
- 238000009472 formulation Methods 0.000 description 19
- 239000000203 mixture Substances 0.000 description 19
- 239000007921 spray Substances 0.000 description 15
- 239000003205 fragrance Substances 0.000 description 12
- 238000005342 ion exchange Methods 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 239000003899 bactericide agent Substances 0.000 description 8
- 235000007586 terpenes Nutrition 0.000 description 8
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 7
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 6
- 235000019634 flavors Nutrition 0.000 description 6
- 239000003242 anti bacterial agent Substances 0.000 description 5
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 description 2
- 150000008365 aromatic ketones Chemical class 0.000 description 2
- 229960000686 benzalkonium chloride Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
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- 229950001046 piroctone Drugs 0.000 description 2
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 229940043810 zinc pyrithione Drugs 0.000 description 2
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 2
- 229930007845 β-thujaplicin Natural products 0.000 description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- SMNDYUVBFMFKNZ-UHFFFAOYSA-N 2-furoic acid Chemical class OC(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000010887 Aglaia odorata Nutrition 0.000 description 1
- 240000000595 Aglaia odorata Species 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 210000000436 anus Anatomy 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical class OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 239000004306 orthophenyl phenol Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 150000008379 phenol ethers Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Detergent Compositions (AREA)
Description
本発明は、エアゾール容器内に収納し、温水洗浄便座のノズルの洗浄・殺菌を行うためのクリーナーとして使用する温水洗浄便座ノズルクリーナー用のエアゾール内容物に関するものである。 The present invention relates to an aerosol content for a warm water cleaning toilet nozzle cleaner that is housed in an aerosol container and used as a cleaner for cleaning and sterilizing a nozzle of a warm water cleaning toilet seat.
従来、便座に取り付けた噴射ノズルから温水を噴射し、この温水によって肛門部等の被洗浄部を洗浄する温水洗浄方式の便座が広く一般に用いられている。このような温水洗浄方式の便座に於ては、噴射ノズルを被洗浄部の下方に配置した状態で温水を噴射して被洗浄部の洗浄を行うため、洗浄後の汚水によって噴射ノズルが必然的に汚れてしまうものとなり、噴射ノズルに温水等をかけて洗浄するのみでは衛生面に於て問題がある。そこで、特許文献１に示す如く、脂肪酸セッケンを洗浄成分として含有するエアゾール内容物をエアゾール容器内に収納し、このエアゾール内容物を温水洗浄便座の噴射ノズルに噴射することにより、汚水によって汚れた噴射ノズルを洗浄するものが公知となっている。 2. Description of the Related Art Conventionally, a warm water cleaning toilet seat is widely used in which warm water is sprayed from an injection nozzle attached to a toilet seat, and a portion to be cleaned such as an anus is washed with the warm water. In such a warm water cleaning toilet seat, in order to clean the portion to be cleaned by injecting hot water in a state where the injection nozzle is disposed below the portion to be cleaned, the injection nozzle is inevitably caused by dirty water after cleaning. If the spray nozzle is washed with warm water or the like, there is a problem in terms of hygiene. Therefore, as shown in Patent Document 1, an aerosol content containing a fatty acid soap as a cleaning component is stored in an aerosol container, and the aerosol content is injected into an injection nozzle of a warm water cleaning toilet seat, thereby causing an injection contaminated with dirty water. What cleans the nozzle is known.
しかしながら、特許文献１の如く、脂肪酸セッケンを噴射ノズルの洗浄成分として用いた場合には、噴射ノズルに塗布したエアゾール内容物の泡が消えるまでに時間がかかる。そのため、例えば便器の使用前に噴射ノズルを洗浄する場合に、短時間に洗浄を終えてすぐに便座を使用することができない不都合が生じていた。 However, when the fatty acid soap is used as a cleaning component of the injection nozzle as in Patent Document 1, it takes time until the foam of the aerosol content applied to the injection nozzle disappears. Therefore, for example, when the spray nozzle is washed before using the toilet bowl, there is a disadvantage that the toilet seat cannot be used immediately after the washing is completed in a short time.
そこで、本発明は上述の如き課題を解決しようとするものであって、十分な洗浄効果を有するとともに、噴射ノズルに塗布した後の消泡時間が短く、短時間に噴射ノズルの洗浄を終えて便座を使用することを可能とする温水洗浄便座ノズルクリーナー用のエアゾール内容物を得ようとするものである。 Therefore, the present invention is intended to solve the above-described problems, has a sufficient cleaning effect, has a short defoaming time after being applied to the injection nozzle, and has finished cleaning the injection nozzle in a short time. The present invention seeks to obtain an aerosol content for a hot water flush toilet seat nozzle cleaner that allows the use of a toilet seat.
上述の如き課題を解決するため、本願の第１発明は、ＰＯＥ(9)ラウリルエーテルと、イソプロピルアルコール又はエチルアルコールと、水と、噴射剤とを含有したものである。このように、洗浄成分として脂肪酸セッケンを除く界面活性剤を使用することにより、脂肪酸セッケンを使用した上述の従来例と比較して、温水洗浄便座の噴射ノズルに塗布したエアゾール内容物の消泡時間を短縮することが可能となり、噴射ノズルの洗浄を短時間に終えて、すぐに便座を使用することが可能となる。 In order to solve the problems as described above, the first invention of the present application contains POE (9) lauryl ether , isopropyl alcohol or ethyl alcohol, water, and a propellant. In this way, by using the surfactant excluding the fatty acid soap as a cleaning component, the defoaming time of the aerosol contents applied to the spray nozzle of the warm water cleaning toilet seat compared to the above-described conventional example using the fatty acid soap This makes it possible to shorten the cleaning time of the spray nozzle in a short time and to use the toilet seat immediately.
また、本願の第２発明は、上記本願の第１発明と同様に、ＰＯＥ(9)ラウリルエーテルと、イソプロピルアルコール又はエチルアルコールと、水と、噴射剤とを含有したものである。そのため、脂肪酸セッケンを使用した上述の従来例と比較して、温水洗浄便座の噴射ノズルに塗布したエアゾール内容物の消泡時間を短縮することが可能となり、噴射ノズルの洗浄を短時間に終えて、すぐに便座を使用することが可能となる。 In addition, the second invention of the present application contains POE (9) lauryl ether , isopropyl alcohol or ethyl alcohol, water, and a propellant, as in the first invention of the present application. Therefore, compared with the above-mentioned conventional example using fatty acid soap, it becomes possible to shorten the defoaming time of the aerosol contents applied to the spray nozzle of the warm water cleaning toilet seat, and the cleaning of the spray nozzle is completed in a short time It becomes possible to use the toilet seat immediately.
また、本願の第２発明は、上記含有成分に加えて、増粘剤、殺菌剤又は抗菌剤、香料のうちのいずれか１つ又は複数を添加したものである。そして、増粘剤を添加した場合には、噴射ノズルに塗布したエアゾール内容物の展着性を高めて、噴射ノズルの汚れを確実に落とすことが可能となる。また、殺菌剤又は抗菌剤を添加した場合には、それぞれ殺菌、抗菌効果を高めることができ、香料を添加した場合には、悪臭を緩和し、使用感を良好とすることができる。 Moreover, 2nd invention of this application adds any one or more of a thickener, a disinfectant, an antibacterial agent, and a fragrance | flavor in addition to the said content component. When the thickener is added, the spreadability of the aerosol content applied to the spray nozzle can be improved, and the spray nozzle can be reliably cleaned. Moreover, when a bactericidal agent or an antibacterial agent is added, a bactericidal and antibacterial effect can be improved, respectively, and when a fragrance | flavor is added, malodor can be relieved and a usability | use_condition can be made favorable.
また、噴射剤は、液化石油ガス、ジメチルエーテル、圧縮ガスを一種としても良いし、複数種組み合わせたものであっても良い。噴射剤を一種とした場合には、複数種を組み合わせた場合と比較して、廉価な製品を得ることができるし、複数種を組み合わせた場合には、噴射されるエアゾール内容物の噴射圧を高めて、噴射ノズルの汚れを確実に落とすことが可能となる。 In addition, the propellant may be one type of liquefied petroleum gas, dimethyl ether, or compressed gas, or a combination of a plurality of types. When one type of propellant is used, an inexpensive product can be obtained compared to the case where a plurality of types are combined, and when a plurality of types are combined, the injection pressure of the aerosol content to be injected is reduced. This makes it possible to reliably remove dirt from the injection nozzle.
本願の第１発明は上述の如く、温水洗浄便座ノズルクリーナー用のエアゾール内容物に、洗浄成分としてＰＯＥ(9)ラウリルエーテルを含有しているため、脂肪酸セッケンを使用した従来例の温水洗浄便座ノズルクリーナー用のエアゾール内容物と比較して、温水洗浄便座の噴射ノズルに塗布したエアゾール内容物の消泡時間を短縮することが可能となり、噴射ノズルの洗浄を短時間に終えて、すぐに便座を使用することが可能となる。 The first invention of the present application is as described above, the aerosol content for bidet nozzle cleaner, which contains the POE (9) lauryl ether as a cleaning component, bidet conventional example using fatty acid soap Compared with the aerosol contents for the nozzle cleaner, the defoaming time of the aerosol contents applied to the spray nozzle of the hot water cleaning toilet seat can be shortened. Can be used.
また、本願の第２発明は、上記第１発明と同様に温水洗浄便座ノズルクリーナー用のエアゾール内容物に、洗浄成分としてＰＯＥ(9)ラウリルエーテルを含有しているため、脂肪酸セッケンを使用した従来例の温水洗浄便座ノズルクリーナー用のエアゾール内容物と比較して、温水洗浄便座の噴射ノズルに塗布したエアゾール内容物の消泡時間を短縮することが可能となり、噴射ノズルの洗浄を短時間に終えて、すぐに便座を使用することが可能となる。 The second invention of the present application, in the first invention and the aerosol content for bidet nozzle cleaner Similarly, since as a cleaning component contains a POE (9) lauryl ether was used fatty acid soap Compared with the aerosol contents for the conventional warm water cleaning toilet seat nozzle cleaner, the defoaming time of the aerosol contents applied to the spray nozzle of the warm water cleaning toilet seat can be shortened, and the spray nozzle can be cleaned in a short time. Once finished, the toilet seat can be used immediately.
また、本願の第２発明は、上記含有成分に加えて、増粘剤、殺菌剤又は抗菌剤、香料のうちのいずれか１つ又は複数を添加したものであり、増粘剤を添加した場合には、噴射ノズルに塗布したエアゾール内容物の展着性を高めて、噴射ノズルの汚れを確実に落とすことが可能となる。また、殺菌剤又は抗菌剤を添加した場合には、それぞれ殺菌、抗菌効果を高めることができ、香料を添加した場合には、悪臭を緩和し、使用感を良好とすることができる。 Moreover, 2nd invention of this application adds any one or more of a thickener, a disinfectant, an antibacterial agent, and a fragrance | flavor in addition to the said content component, and the case where a thickener is added In this case, the spreadability of the aerosol content applied to the spray nozzle can be enhanced, and the spray nozzle can be reliably cleaned. Moreover, when a bactericidal agent or an antibacterial agent is added, a bactericidal and antibacterial effect can be improved, respectively, and when a fragrance | flavor is added, malodor can be relieved and a usability | use_condition can be made favorable.
本願の第１、第２発明で使用する水は、特に限定されるものではなく、例えば精製水、イオン交換水などが用いられる。 The water used in the first and second inventions of the present application is not particularly limited, and, for example, purified water, ion exchange water or the like is used.
また、本願の第２発明で使用する殺菌剤としては、例えばトリクロサン、パラクロルメタキシレノール、オルソフェニルフェノール、トリクロロカルバニリド等が挙げられる。 Examples of the bactericidal agent used in the second invention of the present application include triclosan, parachlorometaxylenol, orthophenylphenol, trichlorocarbanilide and the like.
本願の第２発明で使用する増粘剤としては、例えば水溶性高分子とガム質等が挙げられる。そして、水溶性高分子としては、セルロース系高分子及び／又はガム質であることが好ましい。上記セルロース系高分子としては、例えばヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロースナトリウム、ニトロセルロース、結晶セルロース等が挙げられる。また、ガム質としては、例えばキサンタンガム、カラギーナン、アラビアゴム、トラガントゴム、カチオン化グアガム、グアガム、ジュランガム、ローカストビーンガム等が挙げられる。 Examples of the thickener used in the second invention of the present application include water-soluble polymers and gums. The water-soluble polymer is preferably a cellulosic polymer and / or a gum. Examples of the cellulose polymer include hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropylmethyl cellulose, sodium carboxymethyl cellulose, nitrocellulose, and crystalline cellulose. Examples of gums include xanthan gum, carrageenan, gum arabic, tragacanth gum, cationized guar gum, guar gum, juran gum, locust bean gum and the like.
本願の第２発明で使用する抗菌剤としては、例えばイソプロピルメチルフェノール、塩化ベンザルコニウム、オクトピロックス、感光色素101、感光色素201、クロルヘキシジン、サリチル酸、ジンクピリチオン、ソルビン酸カリウム、ヒノキチオール、フェノール等が挙げられ、このうち、イソプロピルメチルフェノール、塩化ベンザルコニウム、オクトピロックス、ジンクピリチオン、ヒノキチオールが好ましい。 Examples of the antibacterial agent used in the second invention of the present application include isopropylmethylphenol, benzalkonium chloride, octopirox, photosensitive dye 101, photosensitive dye 201, chlorhexidine, salicylic acid, zinc pyrithione, potassium sorbate, hinokitiol, phenol and the like. Of these, isopropylmethylphenol, benzalkonium chloride, octopirox, zinc pyrithione, and hinokitiol are preferable.
本願の第２発明で使用する香料としては、特に限定するものではないが、例えば脂肪族炭化水素、テルペン炭化水素、芳香族炭化水素等の炭化水素類、脂肪族アルコール、テルペンアルコール、芳香族アルコール等のアルコール類、脂肪族エーテル、芳香族エーテル等のエーテル類、脂肪族オキサイド、テルペン類のオキサイド等のオキサイド類、脂肪族アルデヒド、テルペン系アルデヒド、水素化芳香族アルデヒド、チオアルデヒド、芳香族アルデヒド等のアルデヒド類、脂肪族ケトン、テルペンケトン、水素化芳香族ケトン、脂肪族環状ケトン、非ベンゼン系芳香族ケトン、芳香族ケトン等のケトン類、アセタール類、ケタール類、フェノール類、フェノールエーテル類、脂肪酸、テルペン系カルボン酸、水素化芳香族カルボン酸、芳香族カルボン酸等の酸類、酸アマイド類、脂肪族ラクトン、大環状ラクトン、テルペン系ラクトン、水素化芳香族ラクトン、芳香族ラクトン等のラクトン類、脂肪族エステル、フラン系カルボン酸エステル、脂肪族環状カルボン酸エステル、シクロヘキシルカルボン酸族エステル、テルペン系カルボン酸エステル、芳香族カルボン酸エステル等のエステル類、ニトロムスク類、ニトリル、アミン、ピリジン類、キノリン類、ピロール、インドール等の含窒素化合物、等の合成香料及び天然香料を挙げることができ、これらは単独で、又は２種以上を組み合わせて用いることができる。 The fragrance used in the second invention of the present application is not particularly limited, but for example, hydrocarbons such as aliphatic hydrocarbons, terpene hydrocarbons, aromatic hydrocarbons, aliphatic alcohols, terpene alcohols, aromatic alcohols. Alcohols such as, aliphatic ethers, ethers such as aromatic ethers, oxides such as aliphatic oxides and terpene oxides, aliphatic aldehydes, terpene aldehydes, hydrogenated aromatic aldehydes, thioaldehydes, aromatic aldehydes Aldehydes, aliphatic ketones, terpene ketones, hydrogenated aromatic ketones, aliphatic cyclic ketones, ketones such as non-benzene aromatic ketones, aromatic ketones, acetals, ketals, phenols, phenol ethers , Fatty acid, terpene carboxylic acid, hydrogenated aromatic carboxylic acid, aroma Acids such as carboxylic acids, acid amides, aliphatic lactones, macrocyclic lactones, terpene lactones, hydrogenated aromatic lactones, lactones such as aromatic lactones, aliphatic esters, furan carboxylic acid esters, aliphatic cyclic carboxylic acids Synthesis of acid esters, cyclohexyl carboxylic acid esters, terpene carboxylic acid esters, aromatic carboxylic acid esters, etc., nitromusks, nitriles, amines, pyridines, quinolines, pyrrole, indole and other nitrogen-containing compounds A fragrance | flavor and a natural fragrance | flavor can be mentioned, These can be used individually or in combination of 2 or more types.
本願第１発明に係る温水洗浄便座ノズルクリーナー用のエアゾール内容物の処方例（以下、処方例１〜３とする）を以下に示す。 Formulation examples (hereinafter referred to as Formulation Examples 1 to 3) of aerosol contents for the hot water washing toilet seat nozzle cleaner according to the first invention of the present application are shown below.
処方例１
POE(9)ラウリルエーテル ０．５０ｗｔ％
イソプロピルアルコール １２．５０ｗｔ％
イオン交換水 ３７．００ｗｔ％
液化石油ガス（噴射剤） ５０．００ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 1
POE (9) lauryl ether 0.50wt%
Isopropyl alcohol 12.50wt%
Ion exchange water 37.00wt%
Liquefied petroleum gas (propellant) 50.00wt%
Total 100.00wt%
処方例２
POE(9)ラウリルエーテル １．００ｗｔ％
イソプロピルアルコール ７．００ｗｔ％
イオン交換水 ９０．００ｗｔ％
圧縮ガス（噴射剤） ２．００ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 2
POE (9) lauryl ether 1.00wt%
Isopropyl alcohol 7.00 wt%
Ion exchange water 90.00wt%
Compressed gas (propellant) 2.00wt%
Total 100.00wt%
処方例３
POE(9)ラウリルエーテル １．００ｗｔ％
イソプロピルアルコール ５．００ｗｔ％
イオン交換水 ８７．００ｗｔ％
ジメチルエーテル（噴射剤） ５．００ｗｔ％
圧縮ガス（噴射剤） ２．００ｗｔ％
合計 １００．００ｗｔ％
また、本願第２発明に係る温水洗浄便座ノズルクリーナー用のエアゾール内容物の処方例（以下、処方例４〜８とする）を以下に示す。
Formulation Example 3
POE (9) lauryl ether 1.00wt%
Isopropyl alcohol 5.00wt%
Ion exchange water 87.00wt%
Dimethyl ether (propellant) 5.00wt%
Compressed gas (propellant) 2.00wt%
Total 100.00wt%
Moreover, the prescription example (henceforth prescription examples 4-8) of the aerosol content for the warm water washing toilet seat nozzle cleaner which concerns on this invention 2nd invention is shown below.
処方例４
POE(9)ラウリルエーテル ０．５０ｗｔ％
イソプロピルアルコール １２．５０ｗｔ％
イオン交換水 ３６．６５ｗｔ％
液化石油ガス（噴射剤） ５０．００ｗｔ％
イソプロピルメチルフェノール（殺菌剤） ０．１５ｗｔ％
芳香族炭化水素（香料） ０．１０ｗｔ％
キサンタンガム（増粘剤） ０．１０ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 4
POE (9) lauryl ether 0.50wt%
Isopropyl alcohol 12.50wt%
Ion exchange water 36.65wt%
Liquefied petroleum gas (propellant) 50.00wt%
Isopropylmethylphenol (bactericide) 0.15wt%
Aromatic hydrocarbon (fragrance) 0.10wt%
Xanthan gum (thickener) 0.10wt%
Total 100.00wt%
処方例５
POE(9)ラウリルエーテル ０．２５ｗｔ％
イソプロピルアルコール １０．００ｗｔ％
イオン交換水 ４９．５０ｗｔ％
液化石油ガス（噴射剤） ３２．００ｗｔ％
ジメチルエーテル（噴射剤） ８．００ｗｔ％
イソプロピルメチルフェノール（殺菌剤） ０．１５ｗｔ％
芳香族炭化水素（香料） ０．１０ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 5
POE (9) lauryl ether 0.25wt%
Isopropyl alcohol 10.00 wt%
Ion exchange water 49.50wt%
Liquefied petroleum gas (propellant) 32.00wt%
Dimethyl ether (propellant) 8.00 wt%
Isopropylmethylphenol (bactericide) 0.15wt%
Aromatic hydrocarbon (fragrance) 0.10wt%
Total 100.00wt%
処方例６
POE(9)ラウリルエーテル ０．７５ｗｔ％
イソプロピルアルコール ５．００ｗｔ％
イオン交換水 ９２．００ｗｔ％
圧縮ガス（噴射剤） ２．００ｗｔ％
イソプロピルメチルフェノール（殺菌剤） ０．１５ｗｔ％
芳香族炭化水素（香料） ０．１０ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 6
POE (9) lauryl ether 0.75wt%
Isopropyl alcohol 5.00wt%
Ion exchange water 92.00wt%
Compressed gas (propellant) 2.00wt%
Isopropylmethylphenol (bactericide) 0.15wt%
Aromatic hydrocarbon (fragrance) 0.10wt%
Total 100.00wt%
処方例７
POE(9)ラウリルエーテル ０．７５ｗｔ％
イソプロピルアルコール ７．００ｗｔ％
イオン交換水 ８５．００ｗｔ％
液化石油ガス（噴射剤） ５．００ｗｔ％
圧縮ガス（噴射剤） ２．００ｗｔ％
イソプロピルメチルフェノール（殺菌剤） ０．１５ｗｔ％
芳香族炭化水素（香料） ０．１０ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 7
POE (9) lauryl ether 0.75wt%
Isopropyl alcohol 7.00 wt%
Ion exchange water 85.00wt%
Liquefied petroleum gas (propellant) 5.00wt%
Compressed gas (propellant) 2.00wt%
Isopropylmethylphenol (bactericide) 0.15wt%
Aromatic hydrocarbon (fragrance) 0.10wt%
Total 100.00wt%
処方例８
POE(9)ラウリルエーテル １．００ｗｔ％
イソプロピルアルコール ５．００ｗｔ％
イオン交換水 ８６．７５ｗｔ％
液化石油ガス（噴射剤） ２．５０ｗｔ％
ジメチルエーテル（噴射剤） ２．５０ｗｔ％
圧縮ガス（噴射剤） ２．００ｗｔ％
イソプロピルメチルフェノール（殺菌剤） ０．１５ｗｔ％
芳香族炭化水素（香料） ０．１０ｗｔ％
合計 １００．００ｗｔ％
Formulation Example 8
POE (9) lauryl ether 1.00wt%
Isopropyl alcohol 5.00wt%
Ion exchange water 86.75wt%
Liquefied petroleum gas (propellant) 2.50wt%
Dimethyl ether (propellant) 2.50wt%
Compressed gas (propellant) 2.00wt%
Isopropylmethylphenol (bactericide) 0.15wt%
Aromatic hydrocarbon (fragrance) 0.10wt%
Total 100.00wt%
また、POE(9)ラウリルエーテルを用いた本願第１、第２発明の温水洗浄便座ノズルクリーナー用のエアゾール内容物と、界面活性剤として脂肪酸セッケンを用いた比較例の温水洗浄便座ノズルクリーナー用のエアゾール内容物とを用いて、本願第１、第２発明の消泡効果を実証するための比較実験を行った。本願第１、第２発明に係る温水洗浄便座ノズルクリーナー用のエアゾール内容物としては、上記処方例１〜８のエアゾール内容物を用いた。なお、上記処方例２、３、６の圧縮ガスは、二酸化炭素ガスで製品圧力を０．８Ｍｐａに調整し、処方例７、８のものは、製品圧力を０．６Ｍｐａに調整したものを用いた。また、脂肪酸セッケンを用いた比較例の温水洗浄便座ノズルクリーナー用のエアゾール内容物の処方を以下に示す。 In addition , the aerosol contents for the hot water cleaning toilet seat nozzle cleaner of the first and second inventions of the present application using POE (9) lauryl ether and the comparative example of the hot water cleaning toilet seat nozzle cleaner using fatty acid soap as a surfactant are used. A comparative experiment for demonstrating the defoaming effect of the first and second inventions of the present application was performed using the aerosol contents. As the aerosol contents for the hot water washing toilet seat nozzle cleaner according to the first and second inventions of the present application, the aerosol contents of the above-mentioned prescription examples 1 to 8 were used. In addition, the compressed gas of the above-mentioned prescription examples 2, 3, and 6 is carbon dioxide gas and the product pressure is adjusted to 0.8 Mpa, and the prescription examples 7 and 8 are those in which the product pressure is adjusted to 0.6 Mpa. It was. Moreover, the prescription of the aerosol content for the warm water washing toilet seat nozzle cleaner of the comparative example using fatty acid soap is shown below.
比較例
脂肪酸セッケン ２．００ｗｔ％
イソプロピルアルコール １３．６９ｗｔ％
ユーカリ精油 ０．５０ｗｔ％
イオン交換水 ７５．０４ｗｔ％
液化石油ガス（噴射剤） ８．７７ｗｔ％
合計 １００．００ｗｔ％
Comparative example Fatty acid soap 2.00wt%
Isopropyl alcohol 13.69 wt%
Eucalyptus essential oil 0.50wt%
Ion exchange water 75.04 wt%
Liquefied petroleum gas (propellant) 8.77 wt%
Total 100.00wt%
また、この比較実験は、同一形状のエアゾール容器に、前記本願第１、第２発明に係る処方例１〜８のエアゾール内容物と、上記従来例の温水洗浄便座ノズルクリーナー用のエアゾール内容物をそれぞれ充填し、これらのエアゾール内容物を、温水洗浄便座用の噴射ノズルに噴射距離１５ｃｍから２秒間噴射して、泡が完全に消えるまでの時間を計測することにより行った。また、実験時の外気温は２５℃であった。この消泡実験の結果を以下に示す。 Further, in this comparative experiment, the aerosol contents of the prescription examples 1 to 8 according to the first and second inventions of the present application and the aerosol contents for the warm water washing toilet seat nozzle cleaner of the above-described conventional example are placed in an aerosol container of the same shape. Each aerosol was filled, and these aerosol contents were sprayed from a spray distance of 15 cm to a spray nozzle for a warm water washing toilet seat for 2 seconds, and the time until the bubbles completely disappeared was measured. Moreover, the external temperature at the time of experiment was 25 degreeC. The results of this defoaming experiment are shown below.
消泡時間
比較例 ５１秒
処方例１ ２３秒
処方例２ ２０秒
処方例３ ２０秒
処方例４ ２７秒
処方例５ ３０秒
処方例６ ２５秒
処方例７ ２３秒
処方例８ ２２秒
Antifoaming time Comparative example 51 seconds Formulation example 1 23 seconds Formulation example 2 20 seconds Formulation example 3 20 seconds Formulation example 4 27 seconds Formulation example 5 30 seconds Formulation example 6 25 seconds Formulation example 7 23 seconds Formulation example 8 22 seconds
上記実験結果が示すとおり、本願第１、第２発明に係る処方例１〜８のエアゾール内容物は、比較例のエアゾール内容物と比べて消泡時間が大幅に短縮されている。即ち、本願第１、第２発明に係る温水洗浄便座ノズルクリーナー用のエアゾール内容物が、脂肪酸セッケンを洗浄成分として含有した従来例の温水洗浄便座ノズルクリーナー用のエアゾール内容物と比較して、優れた消泡効果を有することが立証された。
As the above experimental results show, the aerosol contents of Formulation Examples 1 to 8 according to the first and second inventions of the present application have a significantly shorter defoaming time than the aerosol contents of the comparative example. That is, the aerosol content for the hot water toilet seat nozzle cleaner according to the first and second inventions of the present application is superior to the aerosol content for the conventional hot water toilet seat nozzle cleaner containing a fatty acid soap as a cleaning component. It was proved to have a defoaming effect.
Claims (3)
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| JP2007152530A JP5388426B2 (en) | 2007-06-08 | 2007-06-08 | Aerosol contents for warm water flush toilet nozzle cleaner |
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| JP2007152530A JP5388426B2 (en) | 2007-06-08 | 2007-06-08 | Aerosol contents for warm water flush toilet nozzle cleaner |
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| Publication Number | Publication Date |
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| JP2008303311A JP2008303311A (en) | 2008-12-18 |
| JP5388426B2 true JP5388426B2 (en) | 2014-01-15 |
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| JP2007152530A Expired - Fee Related JP5388426B2 (en) | 2007-06-08 | 2007-06-08 | Aerosol contents for warm water flush toilet nozzle cleaner |
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Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0213827A3 (en) * | 1985-08-14 | 1988-04-06 | The Procter & Gamble Company | Nonfoaming cleansing mousse with skin conditioning benefits |
| JP2001089800A (en) * | 1999-09-24 | 2001-04-03 | Takehara:Kk | Debris remover |
| JP2003183697A (en) * | 2001-12-20 | 2003-07-03 | Lion Corp | Toilet cleaning composition |
| JP4144700B2 (en) * | 2003-02-19 | 2008-09-03 | 大日本除蟲菊株式会社 | Cleaning aerosol composition for toilet and cleaning method using the same |
| JP2005187511A (en) * | 2003-12-24 | 2005-07-14 | Lion Corp | Liquid composition and cleaning method |
| JP3828921B2 (en) * | 2005-09-28 | 2006-10-04 | 木村石鹸工業株式会社 | Cleaning composition and cleaning agent for cleaning nozzle cleaner of warm water cleaning toilet seat |
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2007
- 2007-06-08 JP JP2007152530A patent/JP5388426B2/en not_active Expired - Fee Related
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| JP2008303311A (en) | 2008-12-18 |
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