JP5458469B2 - Letterpress for letterpress reversal offset printing, method for producing the same, and method for producing printed matter - Google Patents

Description

The present invention relates to a letterpress reverse offset printing method using a relief plate as a removal plate used in the reverse offset printing method, and more particularly to a letterpress plate and a method for producing the same, and a method for producing a printed material using the same.

In recent years, in order to cope with cost reduction and miniaturization of electronic components, it has been attempted to form a patterned film such as a wiring or an insulating layer included in the electronic component by a printing method.

Among printing methods, a reverse offset printing method can be cited as a printing method capable of forming a fine image pattern (see, for example, Patent Document 1).

A schematic diagram of an apparatus 50 used in the reverse offset printing method is shown in FIG. In addition, the white arrow in FIG.5 and FIG.6 has shown the moving direction. In FIG. 5, a cylindrical ink film forming substrate called a so-called blanket 52, an ink supply means 51 for supplying ink to the blanket to form an ink film 53, and an unnecessary portion 53b from the ink film formed on the blanket are shown. A removal plate 54 to be removed, a printing substrate 55 to be printed by transferring a main part 53a remaining on the blanket, and a conveying means 56 for conveying the printing substrate to a position suitable for printing are shown. The blanket is usually treated so that the ink film is easily peeled off. For example, silicone rubber is used. Here, the ink film forming substrate is drawn in a cylindrical shape, and the removal plate is drawn in a plate shape. However, as long as a uniform ink film can be formed, the shape of the ink film forming substrate is cylindrical. A plate shape may be used, and for example, an arc shape having a deflection can be selected. Further, any shape may be selected for the removed plate as long as unnecessary portions of the ink film can be removed appropriately.

The printing process will be described step by step with reference to FIG.
First, the ink is applied from the ink supply means 61 onto the ink film forming substrate 62 to form the ink film 63 (FIG. 6A). At this time, the ink is placed in a pre-dried state on the ink film-forming substrate and loses some solvent to form an ink film. Next, a removal plate 64 having a predetermined shape is brought into contact with the ink film to transfer the unnecessary portion 63b of the ink film and remove it from the ink film forming substrate (FIG. 6B). Here, a relief plate is used in which the part corresponding to the main part is a concave part and the part corresponding to the unnecessary part is a convex part. Next, the principal part 63a of the ink film remaining on the ink film forming substrate can be transferred to the substrate to be printed 65 to obtain a printed matter (FIG. 6C).

As an example of forming an image pattern by such a relief reversal offset printing method, it has been proposed to produce an electromagnetic wave shield by performing printing using a conductive ink on a substrate (see, for example, Patent Document 2). In addition, it is desired to produce printed materials on which various image patterns are printed. In particular, it is desired to form both a large area solid pattern, such as a capacitor electrode and a wiring pattern, and a narrow and narrowly spaced pattern on one printed surface.

JP 2000-289320 A JP 2005-175061 A

However, the relief reversal offset printing method is not good at leaving an image pattern having a large area as a main part with respect to the relief depth (plate depth) of the removed plate. This will be described with reference to FIG. In FIG. 4 (a), an ink film was formed on the entire surface using a relief plate 40 in which the relief side wall was formed substantially perpendicular to the top of the convex portion or the bottom surface of the concave portion as a removal plate of the relief reverse printing method. It is sectional drawing which shows typically the state which made the ink film 43 of an ink film formation base material and the convex-part top part of the said relief plate 40 contact. The relief plate 40 includes a pattern sparse portion 41a where the image pattern is relatively sparse and a pattern dense portion 41b where the image pattern is dense. Further, the difference in height between the top of the convex part and the bottom of the concave part is called plate depth.

Here, since the ink film forming substrate 42 normally has elasticity, it is deformed by being subjected to pressure when it comes into contact with the relief plate 40. That is, since the contact portion with the convex portion of the relief plate is dented, the concave portion provided in the relief plate when the area of the concave portion, which is a region corresponding to the main part of the printed material, is large with respect to the depth of the relief plate as in the pattern sparse portion 41a The bottom surface and the ink film on the ink film forming substrate come into contact with each other. The concave part provided on the relief plate means that the ink film must remain on the ink film forming substrate, so that if it comes into contact with the ink film, the ink film to be formed as an image pattern on the printed matter It is removed from the base material, and image pattern omission occurs.

Therefore, in the relief plate used as the removal plate in the reverse offset printing, unlike the relief plate used in the relief printing method, the contact and adsorption of the ink on the bottom surface of the recess has a great influence on the production of the printed matter. Furthermore, since the ink removability from the blanket ink film is necessary at the top of the convex portion of the relief printing plate, the entire plate cannot be provided with ink repellency.

In order to avoid the above problem, when the image pattern is sparse, a method of increasing the plate depth to prevent contact between the ink film and the bottom surface of the recess can be considered. However, there is a problem that the aspect ratio (plate depth / opening width) of the convex portion of the dense pattern portion formed on the same convex plate is increased, and the strength of the convex portion is lowered.

Further, as a typical method for forming a relief plate as a removal plate, there is a relief formation by etching. FIG. 4B shows a cross-sectional view schematically showing the state of the letterpress during etching. In FIG. 4B, a mask 45 is formed on the relief plate substrate 44, and wet etching is performed in this state. In wet etching, a portion not isotropically covered with a mask is removed (black arrow in the figure), and side etching equivalent to the plate depth is generated. Therefore, when the plate depth of the pattern sparse portion 41a is increased, the accuracy of the relief pattern is relatively impaired, and in particular, the resolution of the pattern dense portion 41b is lowered.

The present invention was made in order to provide a relief plate used as a removal plate in the relief reverse printing method, which does not cause ink transfer omission in a portion having a sparse pattern without increasing the plate depth. In particular, to provide a high-definition relief printing pattern that does not cause pattern omission even when a sparse part and a dense part are mixed, a method for producing the same, and a method for producing printed matter using the same. Let it be an issue.

In order to solve the above-mentioned problems, the first invention according to claim 1 is the ink applied to the ink film forming substrate by using any of bar coating, die coating, cap coating, spin coating, and slit coating. From the ink film forming substrate, an ink film forming step of forming an ink film by coating, and contacting the intaglio of a predetermined shape with the ink film to transfer an unnecessary portion of the ink film to the convex portion of the intaglio A relief plate used in a relief reversal offset printing method comprising a removal step to remove and a transfer step of transferring a main part of the ink film remaining on the ink film forming substrate to a substrate to be printed, wherein the relief plate A printed pattern in which a pattern dense portion and a pattern sparse portion are mixed is formed, and the area of the concave portion corresponding to the main part of the printed material with respect to the plate depth of the relief plate is on the concave bottom surface and the ink film forming substrate. No · The film is a letterpress large print pattern the extent of contact is formed, the relief plate is either material combining glass, metallic materials, glass and metal materials, fluoroalkyl silanes, fluoroalkyl group-containing oligomer, Using an ink-repellent silane coupling agent containing a fluoroether group-containing polymer or a hydrolyzable group-containing siloxane, a monomolecular ink-repellent layer is spin-coated on a concave portion, which is a main area corresponding to the letterpress, and rolled. The relief printing plate for letterpress reverse offset printing is characterized in that it is formed by heat drying after it is formed using any method of coating or applicator coating.

A second aspect of the invention according to claim 2 is the relief printing plate for letterpress reverse offset printing according to claim 1 , wherein the top of the projections of the relief printing plate is subjected to ink-philic treatment .

According to a third aspect of the present invention, an ink film is formed by applying ink onto an ink film forming substrate using any of bar coating, die coating, cap coating, spin coating, and slit coating. An ink film forming step, a removing step of bringing a predetermined shape of the relief plate into contact with the ink film, transferring an unnecessary portion of the ink film to the convex portion of the relief plate, and removing the ink film from the ink film forming substrate; and forming the ink film A method for producing a relief printing plate for use in a relief printing offset printing method comprising a transfer step for transferring a main part of the ink film remaining on the backing material to a printing substrate, wherein the projections on the surface of the substrate serving as the relief printing substrate Masking positions corresponding to the pattern in a pattern, then etching an unmasked area of the substrate surface, and then etching the fluoroalkylsilane, Roarukiru group-containing oligomer, fluoroether group-containing polymer, ink repellency of the silane coupling agent spin coating comprising a hydrolyzable group-containing siloxane, roll coating, after forming using any method applicator coating, heating 2. The method for producing a relief printing plate for letterpress reverse offset printing according to claim 1, further comprising a step of performing an ink repellency treatment by drying and then a step of peeling off the mask formed in a pattern.

4th invention which concerns on Claim 4 is a manufacturing method of the relief printing used for the said relief printing reverse offset printing method, Comprising: The process of masking the position corresponding to the convex part of the substrate surface used as a relief printing base material in pattern shape, Next, a step of etching an unmasked region of the substrate surface, and then a fluoroalkylsilane, a fluoroalkyl group-containing oligomer, a fluoroether group-containing polymer, or a hydrolyzable group-containing siloxane in the etched region of the substrate surface After forming an ink-repellent silane coupling agent containing spin coating, roll coating, or applicator coating, a process of performing ink-repellent treatment by heating and drying, then into a pattern The step of peeling off the masking made, and then using an ink-philic silane coupling agent on the top of the convex part on the substrate Te is a method for producing a letterpress reverse offset relief printing plate according to claim 2, characterized in that it comprises the step, of applying a parent ink process.

A fifth invention according to claim 5, the ink film formed bar coating ink on an ink film forming substrate, die, cap coating, spin coating, the ink film using any of the methods of slit coating formation A step of contacting the ink film with a predetermined shape on the ink film, transferring an unnecessary portion of the ink film to the convex portion of the relief plate, and removing the ink film from the ink film forming substrate; the main part of the remaining said ink film to a print manufacturing method according letterpress reverse offset printing method and a transfer step of transferring the substrate to be printed, the relief reversal offset relief printing plate of claim 1 Symbol placement as Toppan to It is the manufacturing method of the printed matter characterized by using.

According to the first aspect of the present invention, the ink film formed on the ink film-forming substrate and the bottom surface of the concave portion of the relief plate are obtained by using the plate having the ink repellency treatment on the concave portion of the relief plate used for relief reverse printing. Since the ink film does not transfer from the ink film forming substrate to the recess even if it touches the image pattern, the image pattern is sparse, and the omission of the image pattern can be prevented even when forming a printed matter with a wide ink film forming area. . In addition, since the portion of the plate that has been subjected to ink repellent treatment is firmly fixed by the silane coupling agent, it becomes a durable high-definition plate, and further, because the ink repellent treated portion is a monomolecular layer, Without affecting the shape of the plate, it was possible to prevent omission of the image pattern even when a printed matter having a wide ink film formation area was formed.

According to the invention described in claim 2 , by using the relief printing plate in which the convex portion is further subjected to ink-philic treatment in the invention described in claim 1, the ink unnecessary portion can be accurately removed, and the high definition and pixel It was possible to produce a printed material without omissions.

According to the third aspect of the invention, the relief printing for letterpress reversal offset printing according to the first or second aspect of the invention can be produced, and the omission of the image pattern can be prevented even when a printed matter having a wide ink film formation region is formed. . In addition, a monomolecular ink-repellent layer could be easily formed. In addition, since the silane coupling agent is firmly fixed on the surface of the plate, a durable high-definition plate can be produced, and since it is a monomolecular film, the ink film can be formed without affecting the shape of the plate. Even when a printed matter having a wide area was formed, it was possible to prevent the image pattern from being lost. A good monomolecular ink-repellent layer could be easily formed, and omission of an image pattern could be prevented even when a printed material having a wide ink film formation region was formed.

According to the invention described in claim 4 , the relief printing for letterpress reverse offset printing described in claim 2 can be manufactured. With this relief printing, it is possible to prevent missing image patterns even when forming printed matter with a wide ink film formation area, and furthermore, by accurately removing unnecessary ink parts, printed matter with high definition and no missing pixels. Could be manufactured. Further, by using a silane coupling agent for the ink-philic treatment, a monomolecular ink-philic layer could be easily formed. Furthermore, since the silane coupling agent is firmly fixed on the surface of the plate, a durable high-definition plate can be produced, and since it is a monomolecular film, it does not affect the shape of the plate. A printed matter with no missing pixels could be produced.

According to the fifth aspect of the present invention, it is possible to prevent the image pattern from being lost even when a printed matter having a sparse image pattern and a wide ink film forming area is formed. In particular, even when a printed material in which a portion having a sparse image pattern and a portion having a dense image pattern are mixed, a printed material having no missing pixels can be manufactured.

<Letterpress>
The letterpress of the present invention will be described with reference to FIG.
The material of the relief printing plate of the present invention may be a metal such as glass or stainless steel, various materials, or a combination thereof, but is not limited thereto. Glass is preferred because it is robust and easy to process.

The relief plate 10 of the present invention shown in FIG. 1 (a) removes unnecessary portions from the ink film on the ink film forming substrate and leaves the portions corresponding to the unnecessary portions as convex portions (relief pattern). It is formed to become. To explain with reference to FIG. 1, the convex portion top 14 highest portion of the relief plate surface herein, the bottom surface of the recess 16 the lowest site, site in the side surface of the protrusion, or in the side surface of the concave convex side surface 15 is assumed. The difference between the convex top 14 and the concave bottom 16 is the plate depth d, and the allowable range is selected depending on the printed matter to be manufactured.

Further, the relief printing plate of the present invention is subjected to ink repellency treatment on the surface, or further ink-repellent treatment on the ink removal surface (FIGS. 1 and 2). Examples of the ink repellent treatment include chemical treatment using silicone or a silane coupling agent, physical treatment such as fluorine plasma, and the like, but considering long-term stability, silane coupling treatment on glass or metal surfaces is preferable.

In the letterpress of FIG. 1A of the present invention, the ink film is formed without transferring the main part of the ink film to the letterpress side because the ink film is provided with the concave portion 22 as the contact surface of the ink film. Only unnecessary portions can be removed from the ink film formed on the substrate. Accordingly, even when an image pattern having a large area corresponding to the concave portion represented as the pattern sparse portion 27 in FIG. 2 is printed, printing can be performed without lacking the ink film.

The ink-repellent treated part uses a highly ink-repellent fluoroalkyl group, fluoroether group, or siloxane, so that the ink-repellent part is firmly fixed by these silane coupling agents. It becomes a fine version. Furthermore, since the ink-repellent treated portion is a monomolecular layer, the image pattern can be prevented from being lost even when a printed matter having a wide ink film forming region is formed without affecting the shape of the plate.

In the relief printing plate of FIG. 1B of the present invention, the presence of the ink-philic treatment surface 17 on the surface of the convex portion increases the affinity between the ink and the ink contact surface, and the unnecessary portion can be removed with a lower pressure. . As a result, deformation of the ink film forming substrate can be suppressed. Accordingly, white spots due to deformation as shown in FIG. 4A are improved, and a high-definition print pattern can be formed.

<Manufacture of letterpress>
An example of the process for producing the relief printing plate of the present invention will be described with reference to FIG.
First, a pattern 32 masks the positions corresponding to the convex portions on the surface of the substrate to be the relief base 31 (FIG. 3A). The mask only needs to protect the surface of the substrate in the subsequent relief forming process. For example, a metal or a photosensitive resin can be used. In the case of metal, after vapor deposition, a resist is formed so as to cover a necessary portion, and etching can be performed under the condition that only the metal is etched.

An area not covered with the mask of the masked base material 33 thus obtained is engraved to form a relief 34 (FIG. 3B). Method of forming a relief can be appropriately selected depending on the substrate chosen, for example sand blasting, blasting, such as c E Ttoburasuto, cutting with FIB (focused ion beam), nanoimprinting method, a dry etching, wet etching, etc. Can be mentioned.

As a relief forming method, for example, chromium vapor deposition is performed on a glass substrate, a resist is formed on the chromium film by a photolithography method, unnecessary portions (that is, regions corresponding to the main portions) are opened, and etching is performed. Next, the resist on the chromium film is peeled off, and the glass substrate is wet etched using the chromium film as a mask to form a relief pattern having a predetermined depth on the glass substrate.

Here, the ink-repellent treatment 35 is performed on the side surfaces of the relief plate and the recesses (that is, the surface newly formed by etching) before peeling off the mask of the chromium film (FIG. 3C).

The surface treatment agent selected for the ink repellent treatment varies depending on the ink used, but it is preferable to use a silane coupling agent containing a fluorine element or a siloxane group having high water repellency and oil repellency. Examples of compounds that can be preferably used include long-chain fluoroalkylsilanes, hydrolyzable group-containing siloxanes, fluoroether group-containing polymers, and fluoroalkyl group-containing oligomers.

Examples of the method for applying an ink repellent treatment to the surface of the relief plate include a method in which the above-mentioned coupling agent is chemically bonded to the relief surface and fixed. For example, a known glass surface treatment method using a silane coupling agent can be used. That is, a silane coupling agent is dissolved in water, acetic acid water, a water-alcohol mixed solution, or alcohol to prepare a coupling agent solution. Next, the coupling agent solution is applied to the glass surface using a known coating method such as spin coating, roll coating, and applicator. Finally, the silane coupling agent can be fixed to a relief surface such as glass by drying by heating and removing the solvent. At this time, by heat drying, the silane coupling agent and the glass surface are strongly bonded by oligomerization, so that the surface treatment is extremely resistant.

After the ink repellent treatment, the mask 32 is removed from the relief base 31 to obtain the relief plate 30 of the present invention in which the ink repellent treatment is applied to the concave portion corresponding to the main part (pattern forming position) (FIG. 3). (D)).

Further, by applying the ink-affinity treatment 37 to the relief printing plate, the relief printing plate 39 of the present invention in which the upper surface of the projections is ink-philicity and the depressions are ink-inking properties (FIG. 3 (e)).

The surface treatment agent used for the parent ink treatment can be appropriately selected from those having high affinity with the ink used for printing. For example, when a composition in which polyethylene glycol is added to an aqueous dispersion of silver particles is used as the ink, examples of the ink treatment agent include polyethylene glycol, ethylene glycol, and a silane coupling agent containing an ethylene ether part. Is not to be done.

As a method for performing the ink-philic treatment on the surface of the relief printing plate, a known glass surface treatment method can be used as in the ink repellent treatment. The ink-repellent treatment covers the recesses with ink-repellent silane coupling agent molecules in the form of a monomolecular film, so the ink-philic surface treatment agent is inhibited in the recesses, and only the top surface of the protrusions is chemically treated. Will be adsorbed. By rinsing this with a solvent for the surface treatment agent, excess surface treatment agent that is physically adsorbed is washed away. Thereafter, this is heated and dried in the same manner as the ink repellent treatment. As a result, the silane coupling agent is firmly fixed to the surface of the relief plate, and even a monomolecular film is a highly resistant surface treatment.

<Manufacture of printed matter>
The production of a printed matter by the relief reversal offset printing method using the relief plate of the present invention thus obtained will be described with reference to FIGS. Note that description of what has already been described is omitted. The relief printing plate of the present invention is used as a removal plate for relief printing offset printing.

The ink film forming substrate 52 used in the letterpress reversal offset printing method is commonly called a blanket. This material includes ink film formation, ink film removal of non-image parts (unnecessary parts 53b and 63b) by letterpress, and a substrate to be printed. An image portion (main portions 53a and 63a) capable of transferring an ink film to 55 and 65 is used. A material with little deformation is preferable, but a certain degree of flexibility is required. As such a material, silicone elastomer, butyl rubber, ethylene propylene rubber and the like can be used. Further, in order to adjust the wettability of the blanket surface, surface treatment such as application of fluororesin and silicone, plasma treatment, UV ozone cleaning treatment may be performed on the blanket surface. Since such an ink film forming member is usually supplied as a flexible plate, it is used by winding it around a cylindrical plate cylinder (see FIG. 5) or by fixing it to a strong flat plate. be able to.

The ink used in the letterpress reverse printing method can be adjusted according to the type of printed matter to be produced, and various additions can be made to metal fine particle dispersions such as gold, silver, copper, nickel, platinum, palladium, and rhodium. Examples include, but are not limited to, conductive ink with an additive, ink in which an organic electroluminescence (EL) material is dissolved or dispersed in an organic solvent, and a pigment dispersion for a color filter. In consideration of swelling of the blanket material and the like, it is preferable to adjust using water or an alcohol solvent.

As the ink supply means 51 and 61 on the ink film forming substrate, it is only necessary to form a uniform ink film, and bar coating, die coating, cap coating, spin coating, slit coating, and the like can be used. It is not limited to.

The printed substrates 55 and 65 on which an image is formed by transferring the ink film can be appropriately selected according to the target printed matter. In the case of manufacturing electronic components, usually, polyethylene terephthalate (PET), polyimide, polyethersulfone (PES), polyethylene naphthalate (PEN), flexible plastic materials such as polycarbonate, glass substrates such as quartz, and silicon wafers are listed. be able to. It is also possible to select a flexible base material such as a film according to the environment in which the printed material is used. In this case, continuous printing is performed using a long base material to improve production efficiency. Is preferred.

Examples of the printed matter produced by the production method using the relief plates 54 and 55 of the present invention include a thin film transistor substrate, a color filter, a printed wiring board, and an organic electroluminescence element. The thin film transistor substrate includes a plurality of thin film transistors in an array corresponding to the pixels, and can be used as a display member that needs to be turned on and off for each pixel such as a liquid crystal display.

Examples of the image pattern printed using the relief printing plate of the present invention include, for example, an electrode, a capacitor electrode, a wiring, and the like provided in the thin film transistor substrate, a colored layer provided in the color filter, an electrode provided in the organic electroluminescence element, and organic electroluminescence. In the case of a layer, a wiring provided in a printed wiring board, or a printed wiring board with a built-in element, list passive elements / active elements such as capacitor electrodes, dielectric layers, resistive element electrodes, resistors, inductors, transistor components, etc. Can do.

After the unnecessary ink film is removed from the ink film forming substrate, the ink film held by the convex portions of the relief printing plate is washed by a washing process. As a method for washing the relief plate, there can be mentioned a method of washing with a chemical solution or an organic solvent, and a method of removing an ink film by pressing it onto an adhesive film carrying an adhesive. Examples of chemicals that can be used for washing include sulfuric acid and hydrochloric acid. Examples of the organic solvent include toluene. The liquid can be selected appropriately depending on the composition of the ink film, and a liquid that does not attack the material constituting the relief printing plate may be selected. Vibration can also be applied by ultrasonic waves during cleaning. As an adhesive film that can be used for washing, a commercially available adhesive film can be used. For example, an ethylene vinyl acetate copolymer is used as a base film, and adhesion is imparted by applying an acrylic adhesive. The adhesive film made can be used. It is sufficient that the pressure-sensitive adhesive does not transfer to the relief plate during washing. Washing with an adhesive film can be used for immediate printing after washing, and is particularly suitable for printing continuously using the same letterpress. Therefore, the adhesive film is also supplied in a roll state, and a necessary portion may be pressed against the relief plate according to use, and the used film may be wound up.
Hereinafter, embodiments of the present invention will be described by way of examples.

A 100 mm × 100 mm, 0.7 mm thick glass plate was used as the material for the relief plate. Chromium was deposited on one side of this glass plate to a thickness of 50 nm. A resist pattern was formed on the chromium film by a photolithography method using a positive resist, and the exposed chromium film was etched. The resist was peeled off to obtain a glass plate on which a chromium image pattern was formed.

The pattern formed here is one in which the pattern schematically shown in FIG. 2A is set as one unit, and is arranged in a unit of 100 × 10 units in a 100 mm square region at the center of the glass plate. The image pattern corresponding to the pattern sparse part 27 is a 250 μm × 250 μm square, and the image pattern corresponding to the pattern dense part 28 is a 140 μm × 210 μm rectangle. The line / space width between the pattern sparse part and the pattern dense part is 5 μm / 5 μm.

Using this chromium film as a mask, irregularities were formed by glass etching using hydrofluoric acid so that the depth of the depressions became 5 μm. Next, this relief printing plate was immersed for 10 minutes in a solution obtained by dissolving fluoroalkylsilane (manufactured by GE Toshiba Silicone Co., Ltd .: trade name TSL8233) as silane coupling agent in isopropyl alcohol so as to be 0.5% by weight. The surface of the relief printing plate exposed by partial drying was subjected to ink repellent treatment. After that, the chrome pattern is peeled off by etching, the part corresponding to the unnecessary part becomes the convex part, the part corresponding to the main part becomes the concave part, and the relief reversal offset printing in which the concave part which is the main part corresponding area is subjected to ink repellent treatment. A relief printing plate was prepared.

<Ink 1>
As an ink, polyethylene oxide (average molecular weight 10,000, manufactured by Aldrich) is added to an aqueous silver particle dispersion (average particle size 20 nm, manufactured by Sumitomo Electric), and (polyethylene oxide / silver particles / water) = (1/8/31). A conductive ink was prepared by dissolving so as to have a weight ratio.

<Manufacture of printed matter>
The printed matter according to the example was manufactured as follows.
First, a two-pack type silicone rubber manufactured by Toshiba GE (manufactured by GE Toshiba Silicone: trade name TSE3455T) was molded into a thickness of 2 mm and a size of 150 mm × 120 mm to produce a blanket as an ink film forming substrate.

The blanket was wound around a blanket roll to form a cylindrical shape, and the conductive ink adjusted as described above was applied on the blanket with a bar coater, and then dried at room temperature for 3 minutes to form a conductive ink film on the blanket.

Next, the relief printing plate of the present invention according to Example 1 in which the ink-repellent treatment was applied to the recesses was adhered to the ink film on the blanket and then peeled to remove the ink film in the non-image area. Next, the blanket with the image portion left and the soda lime glass substrate having a thickness of 0.7 mm and a size of 100 mm × 100 mm are adhered and then peeled off, and the ink film on the blanket is moved to the printed substrate side. Transcribed. Next, this was heat-treated at 200 ° C. for 30 minutes to form a printed matter having a conductive pattern. When the obtained electroconductive pattern was observed with the optical microscope, the pattern omission was not seen in the pattern sparse part.

A relief printing plate for letterpress reversal offset printing was produced in the same manner as in Example 1 except that hydrolyzable group-containing siloxane (manufactured by GE Toshiba Silicone Co., Ltd .: trade name KPN3504) was used as the coupling agent used for the ink repellent treatment. A printed material was produced using the conductive ink prepared by using Ink 1. When the electroconductive pattern was observed with the optical microscope about the obtained printed matter, the pattern omission was not seen in the pattern sparse part.

A relief printing for letterpress reverse offset printing was produced in the same manner as in Example 1 except that a fluoroether group-containing polymer (Fluor Technology FG5010) was used as the silane coupling agent used for the ink repellent treatment. A printed material was produced using the conductive ink prepared in step 1 above. When the electroconductive pattern was observed with the optical microscope about the obtained printed matter, the pattern omission was not seen in the pattern sparse part.

A relief printing for letterpress reversal offset printing was produced in the same manner as in Example 1 except that the color filter color ink adjusted as shown below was used as the ink, and a printed material was produced using this.

<Ink 2>
First, a red pigment dispersion was prepared with the following composition.
[Red pigment dispersion]
-Red pigment C.I. I. Pigment Red 254 (“Ilgar Forred B-CF” manufactured by Ciba Specialty Chemicals) 18 parts by weight C.I. I. Pigment Red 177 ("Chromophthal Red A2B" manufactured by Ciba Specialty Chemicals) ... 2 parts by weight / acrylic varnish (solid content 20%) ... 108 parts by weight

[Red coloring ink]
Thereafter, a mixture having the following composition was stirred and mixed to be uniform, and then filtered through a 5 μm filter to obtain a red colored ink.
-Red pigment dispersion liquid: 100 parts by weight-Methylated methylol melamine (manufactured by Sanyo Chemical Industries, Ltd .: trade name MW-30) ... 20 parts by weight- Leveling agent (manufactured by Dainippon Ink & Chemicals, Inc .: trade name: Megafuck) F-483SF) ... 1 part by weight, propylene glycol monomethyl ether ... 85 parts by weight, propylene glycol monomethyl ether acetate ... 45 parts by weight

The red colored ink thus adjusted was applied to a blanket, removed unnecessary portions, and transferred to a substrate to be printed in the same manner as in Example 1 to obtain an ink pattern on a glass substrate. In the printed matter thus obtained, no pattern omission was observed in the pattern sparse part.

After producing a letterpress in the same process as in Example 1, after immersing in a solution prepared by dissolving 0.5% by weight of silane coupling agent (Nihon Unicar A-1230) containing ethylene ether in isopropyl alcohol for 10 minutes. By drying at 120 ° C. for 10 minutes, the convex portion of the relief plate was subjected to ink-philic surface treatment to produce a relief printing plate for letterpress reverse offset printing. The printed material was produced using the same process and ink as in Example 1.

When the obtained conductive pattern was observed with an optical microscope, pattern omission was not observed in the pattern sparse part, and a fine pattern in the pattern dense part was also printed accurately.

(Comparative example)
A relief printing for letterpress reversal offset printing was produced in the same manner as in Example 1 except that the ink repellency treatment was not performed on the depressions, and the production of printed matter was performed. About the obtained printed matter, when the conductive pattern was observed with an optical microscope, pattern omission in the pattern sparse part was remarkable, and there were printing defects in some places.

The results of the above examples are summarized in Table 1. In the evaluation of each example, ◯ indicates a state in which no ink is transferred to the printing medium in the unnecessary portion region (portion other than the print pattern forming portion), and the print pattern in the main portion region (print pattern forming portion). Represents a state in which no white spots are observed at all (this is a state in which there is no printing defect). Δ indicates a state in which some printing defects are observed, and × indicates a state in which printing defects are frequently generated.

The relief printing for relief printing of the relief printing of the present invention can be printed even in a wide area pattern, and further, a fine pattern and a large area pattern can be formed by a single printing. It can be applied when manufacturing a device such as a color filter as a printed matter.

It is sectional drawing which shows an example of the relief printing for relief printing reverse offset printing of this invention . (A) is a top view which shows the other example of the relief printing for letterpress reverse offset printing of this invention, (b) is sectional drawing in the AB line of the figure shown by (a). It is a schematic diagram which shows an example of the manufacturing process of the relief printing plate of this invention. (A) is a schematic diagram explaining the contact state of an ink film and a letterpress. (B) is a schematic diagram for explaining an example of a method for producing a relief printing plate. It is a schematic diagram of the apparatus used for the reverse offset printing method. It is a schematic diagram of the process explaining the reverse offset printing method.

Explanation of symbols

10: Letterpress 11: Ink repellent treatment surface 14: Convex portion top 15: Convex portion side surface 16: Concave bottom surface 20: Concavity 22: Concave portion 27 subjected to ink repellent treatment 27: Pattern sparse portion 28: Pattern dense portion 30: Ink repellency treatment Letterpress 31: Letterpress substrate 32: Mask 33: Masked substrate 34: Relief 35: Ink-repellent treatment 36: Ink-repellent treated surface (silane coupling agent monomolecular film)
37: Ink-philic treatment 38: Ink-treated surface (silane coupling agent monomolecular film)
39: Ink-affinity treatment letterpress 40: letterpress 41a: pattern sparse part 41b: pattern dense part 42: ink film forming substrate 43: ink film 44: letterpress substrate 45: mask 50: letterpress reverse offset printing apparatus 51, 61: Ink supply means 52: Blanket 62: Ink film forming substrate 53, 63: Ink film 53a, 63a: Main part 53b of ink film, 63b: Unnecessary part of ink film 54: Removal plate 55: Printed substrate 56: Conveying means 64: Letterpress 65: Printed substrate

Claims (5)

An ink film forming step of forming an ink film by applying ink onto the ink film forming substrate using any of bar coating, die coating, cap coating, spin coating, and slit coating; and the ink film Removing the ink film from the ink film-forming substrate by removing an unnecessary portion of the ink film from the ink film-forming substrate by bringing a predetermined shape of the relief plate into contact with the convex portion of the relief plate; A relief printing used in a relief reversal offset printing method comprising a transfer step of transferring a main part to a substrate to be printed, wherein the relief plate has a printing pattern in which a pattern dense portion and a pattern sparse portion are mixed, and the relief plate edition letterpress der the area of the recess is a region corresponding to the main part of the printed matter is large print pattern the extent of contact ink film on the the recess bottom surface ink film forming substrate is formed in the depth of The relief printing plate is one of glass, metal material, and a combination of glass and metal material, and ink repellent containing fluoroalkylsilane, fluoroalkyl group-containing oligomer, fluoroether group-containing polymer, or hydrolyzable group-containing siloxane. After forming a monomolecular ink repellent layer in a concave portion corresponding to a main part corresponding region of the relief printing plate using a spin coating, roll coating, or applicator coating method , A relief printing for letterpress reversal offset printing, characterized by being formed by heating and drying.   2. The relief printing for letterpress reversal offset printing according to claim 1, wherein the top of the projections of the relief printing is subjected to an lyophilic process. An ink film forming step of forming an ink film by applying ink onto the ink film forming substrate using any of bar coating, die coating, cap coating, spin coating, and slit coating; and the ink film A step of removing the ink film from the ink film-forming substrate by bringing an unnecessary portion of the ink film onto the convex portion of the relief plate by contacting the relief plate of a predetermined shape and removing the essential part of the ink film remaining on the ink film-forming substrate. A method for producing a relief plate for use in a relief reversal offset printing method comprising a transfer step for transferring a portion to a substrate to be printed, wherein the position corresponding to the projection on the substrate surface to be a relief substrate is masked in a pattern Next, a step of etching an unmasked region of the substrate surface, and then a fluoroalkylsilane and a fluoroalkyl group-containing oligomer in the etched region of the substrate surface Fluoroether group-containing polymer, a hydrolyzable group-containing ink-repellent silane coupling agent spin coating containing siloxane, roll coating, after forming using any method applicator coating, by performing the heating and drying 2. The method for producing a relief printing plate for letterpress reversal offset printing according to claim 1, further comprising a step of performing an ink repellent treatment and then a step of peeling off the masking formed in a pattern. A method of manufacturing a relief plate used for the relief printing offset printing method, wherein a step corresponding to a convex portion of a substrate surface serving as a relief substrate is masked in a pattern, and then an unmasked area on the substrate surface Next, an ink-repellent silane coupling agent containing fluoroalkylsilane, fluoroalkyl group-containing oligomer, fluoroether group-containing polymer, or hydrolyzable group-containing siloxane is etched in the etched region of the substrate surface. After forming using any method of spin coating, roll coating, and applicator coating, a step of performing ink repellent treatment by heat drying, then a step of peeling the masking formed in a pattern, A step of performing an ink-philic treatment using an ink-philic silane coupling agent on the top of the convex portion on the base material; Method for producing a letterpress reverse offset relief printing plate according to claim 2, characterized in that it comprises.   An ink film forming step of forming an ink film on the ink film forming substrate using any of bar coating, die coating, cap coating, spin coating, and slit coating; and a predetermined shape for the ink film. A removing step of contacting the relief plate to transfer an unnecessary portion of the ink film to the relief portion of the relief plate and removing it from the ink film forming substrate, and covering the essential portion of the ink film remaining on the ink film forming substrate. A method for producing a printed matter by a letterpress reverse offset printing method comprising a transfer step for transferring to a printing substrate, wherein the letterpress reverse printing offset letterpress according to claim 1 is used as a letterpress.

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