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JP5484253B2 - Aluminum welded structure - Google Patents
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JP5484253B2 - Aluminum welded structure - Google Patents

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JP5484253B2
JP5484253B2 JP2010180780A JP2010180780A JP5484253B2 JP 5484253 B2 JP5484253 B2 JP 5484253B2 JP 2010180780 A JP2010180780 A JP 2010180780A JP 2010180780 A JP2010180780 A JP 2010180780A JP 5484253 B2 JP5484253 B2 JP 5484253B2
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誠二 笹部
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Kobe Steel Ltd
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Description

本発明は、溶接後の強度及び曲げ性能等の継手特性が優れ、溶接特性が優れたアルミニウム溶接構造体に関する。   The present invention relates to an aluminum welded structure having excellent joint characteristics such as strength and bending performance after welding and excellent welding characteristics.

自動車等の分野においては、軽量化のためにアルミニウム材料を構造体に適用することが進められている。特に、電気自動車(EV)及びハイブリッド自動車(HEV)の電池ケースの筐体と、自動車フレーム等の自動車構造材に、アルミニウム材料の適用が注目されている。   In the field of automobiles and the like, aluminum materials are being applied to structures for weight reduction. In particular, the application of aluminum materials has attracted attention for the housings of battery cases of electric vehicles (EV) and hybrid vehicles (HEV) and automobile structural materials such as automobile frames.

このようなアルミニウム材(アルミニウム又はアルミニウム合金)は、一般的に、材料単体で使用されることは少なく、プレス等の所定の加工を経て溶接接合される場合は多い。このような高強度のアルミニウム溶接構造体として、特許文献1には、Si、Cu、Mg、及びMn等の元素を含有するアルミニウム合金が開示されている。   Such an aluminum material (aluminum or aluminum alloy) is generally rarely used as a single material, and is often welded and joined through a predetermined process such as pressing. As such a high-strength aluminum welded structure, Patent Document 1 discloses an aluminum alloy containing elements such as Si, Cu, Mg, and Mn.

特開2000−313933JP 2000-313933 A

しかしながら、特許文献1に開示されたアルミニウム合金材は、必ずしも、近時のアルミニウム溶接構造体に要求される強度及び曲げ特性を満足できるものではなく、また、溶接により割れが発生する等の問題点がある。   However, the aluminum alloy material disclosed in Patent Document 1 does not necessarily satisfy the strength and bending characteristics required for a recent aluminum welded structure, and has problems such as cracking caused by welding. There is.

本発明はかかる問題点に鑑みてなされたものであって、溶接割れを防止できると共に、強度及び曲げ等の高い継手性能を有するアルミニウム溶接構造体及びその製造方法を提供することを目的とする。   This invention is made | formed in view of this problem, Comprising: While preventing a weld crack, it aims at providing the aluminum welded structure which has high joint performance, such as an intensity | strength and a bending, and its manufacturing method.

本発明に係るアルミニウム溶接構造体は、JIS2219合金材又はJIS2024合金材同士を溶加材を使用して溶融溶接することにより得られたアルミニウム溶接構造体において、溶接ビードの組成が、Si:4.0乃至5.0質量%、Cu:0.6乃至1.10質量%、Mg:0.5乃至1.5質量%、Mn:0.3乃至0.5質量%を含有し、残部がAl及び不可避的不純物からなることを特徴とする。 Engaging luer aluminum welded structure of the present invention is the aluminum welding structure obtained by melting welding using filler material with each other JIS2219 alloy material or JIS2024 alloy, the composition of the weld bead, Si: 4.0 to 5.0% by mass, Cu: 0.6 to 1.10% by mass, Mg: 0.5 to 1.5% by mass, Mn: 0.3 to 0.5% by mass, the balance Consists of Al and inevitable impurities.

このアルミニウム溶接構造体において、前記溶融溶接は、例えば、MIG溶接である。   In this aluminum welded structure, the fusion welding is, for example, MIG welding.

本発明によれば、強度及び曲げ性能が優れた継手が得られ、溶接後の割れの発生も抑制される。   According to the present invention, a joint excellent in strength and bending performance is obtained, and the occurrence of cracks after welding is also suppressed.

レーザ溶接方法を示す図である。It is a figure which shows the laser welding method. MIG溶接方法を示す図である。It is a figure which shows the MIG welding method. フィッシュボーン(Fish-bone)溶接割れ試験の試験片の形状を示す図である。It is a figure which shows the shape of the test piece of a Fish-bone welding crack test.

以下、本発明の実施形態について、詳細に説明する。先ず、本願請求項1に係る発明のアルミニウム溶接構造体について説明する。このアルミニウム溶接構造体は、Al−Cu系合金材同士を、溶加材を使用して溶融溶接したものであり、この場合は、例えば、MIG溶接により溶融溶接することができる。溶加材としては、例えば、Si:4.7乃至5.55質量%、Cu:0.02乃至0.26質量%、Mg:0.59乃至1.66質量%、Mn:0.3乃至0.52質量%、残部Al及び不可避的不純物のアルミニウム合金からなるソリッドワイヤを使用することができる。
このアルミニウム溶接構造体の溶接ビードは、Si:4.0乃至5.0質量%、Cu:0.6乃至1.10質量%、Mg:0.5乃至1.5質量%、Mn:0.3乃至0.5質量%を含有し、残部がAl及び不可避的不純物からなる組成を有する。この各成分の添加理由及び組成限定理由は、以下のとおりである。従って、この溶接ビードは、高強度であり、曲げ特性が優れたものとなる。このアルミニウム合金溶接構造体は、母材としては、例えば,JIS2219合金又はJIS2024合金を使用することができる。この母材に対し、溶加材として、上記アルミニウム合金を使用してMIG溶接すると、その溶加材の供給速度等を適宜調節することにより、上記組成の溶接ビードを得ることができる。
以下、この溶接ビードの組成を上述のように規定した理由について説明する。
Hereinafter, embodiments of the present invention will be described in detail. First, an aluminum welded structure according to the first aspect of the present invention will be described. This aluminum welded structure is obtained by melting and welding Al—Cu based alloy materials using a filler metal. In this case, for example, it can be melt welded by MIG welding. Examples of the filler material include Si: 4.7 to 5.55 mass%, Cu: 0.02 to 0.26 mass%, Mg: 0.59 to 1.66 mass%, Mn: 0.3 to A solid wire made of an aluminum alloy of 0.52% by mass, the balance Al and unavoidable impurities can be used.
The weld bead of this aluminum welded structure has Si: 4.0 to 5.0% by mass, Cu: 0.6 to 1.10% by mass, Mg: 0.5 to 1.5% by mass, Mn: 0.00%. It contains 3 to 0.5% by mass, and the balance is composed of Al and inevitable impurities. The reason for adding each component and the reason for limiting the composition are as follows. Therefore, this weld bead has high strength and excellent bending characteristics. In this aluminum alloy welded structure, for example, JIS2219 alloy or JIS2024 alloy can be used as a base material. When MIG welding is performed on the base material using the aluminum alloy as a filler material, a welding bead having the above composition can be obtained by appropriately adjusting the supply rate of the filler material.
The following describes the reason for defining the composition of this weld bead, as described above.

「Si:4.0乃至5.0質量%」
Siは溶接部の融点を低下させる作用を有するが、溶接部のSi量が少ないと、溶接割れが生じ易くなる。一方、Si量が多すぎると、継手強度が低くなり、曲げ特性が劣化する。よって、溶接ビードのSiの含有量は4.0乃至5.0質量とすることが必要である。
“Si: 4.0 to 5.0 mass%”
Si has an effect of lowering the melting point of the welded portion, but if the amount of Si in the welded portion is small, weld cracks are likely to occur. On the other hand, when there is too much Si amount, joint strength will become low and a bending characteristic will deteriorate. Therefore, the Si content of the weld bead needs to be 4.0 to 5.0 mass.

「Cu:0.6乃至1.10質量%」
Cuもアルミニウム合金材の融点を低下させるが、Cu含有量が少ないと、溶接割れが発生しやすい。一方、Cu量が多すぎると、継手強度が低下する。このため、溶接ビードのCu量は、0.6乃至1.10質量%であることが必要である。
“Cu: 0.6 to 1.10 mass%”
Cu also lowers the melting point of the aluminum alloy material, but if the Cu content is low, weld cracks are likely to occur. On the other hand, when there is too much Cu content, joint strength will fall. For this reason, the Cu amount of the weld bead needs to be 0.6 to 1.10% by mass.

「Mg:0.5乃至1.5質量%」
Mgはその含有量が少なすぎると、溶接ビードの強度が不足すると共に、溶接ビードで割れが発生しやすくなり、継手強度が不足する。一方、Mg含有量が多すぎると、継手強度は高くなるが、含有量が少ない場合と同様に、割れが発生しやすくなる。このため、Mgの含有量は、0.5乃至1.5質量%である。
“Mg: 0.5 to 1.5 mass%”
If the content of Mg is too small, the strength of the weld bead is insufficient and cracks are likely to occur in the weld bead, resulting in insufficient joint strength. On the other hand, when the Mg content is too high, the joint strength is increased, but cracking is likely to occur as in the case where the content is low. For this reason, the content of Mg is 0.5 to 1.5 mass%.

「Mn:0.3乃至0.5質量%」
MnもMgと同様の作用効果を奏する。このため、Mnの含有量は、0.3乃至0.5質量%とする。
“Mn: 0.3 to 0.5 mass%”
Mn has the same effect as Mg. For this reason, content of Mn shall be 0.3 thru | or 0.5 mass%.

「溶接ビードの不可避的不純物」
溶接ビードにおける不可避的不純物として、Cr,Zr,Ti、Fe、Zn、V等があるが、これらは、Cr≦0.10質量%、Zr≦0.25質量%、Ti≦0.10質量%、Fe≦0.5質量%、Zn≦0.25質量%、V≦0.15質量%程度であれば、含まれていても許容される。
"Inevitable impurities in weld beads"
Inevitable impurities in the weld bead include Cr, Zr, Ti, Fe, Zn, V, and the like. These are Cr ≦ 0.10 mass%, Zr ≦ 0.25 mass%, Ti ≦ 0.10 mass%. , Fe ≦ 0.5 mass%, Zn ≦ 0.25 mass%, and V ≦ 0.15 mass%, even if contained.

本発明のアルミニウム溶接構造体は、アルミニウム合金材同士を溶融溶接したときの溶接ビードの組成が、上記所定の組成を満足するものであり、これにより、高強度で曲げ特性が優れた継手が得られる。前記アルミニウム合金材自体は、所謂アルミニウム合金展伸材であり、通常の圧延により製造される板材及び通常の押出によって製造される押出材である。   In the aluminum welded structure of the present invention, the composition of the weld bead when the aluminum alloy materials are melt-welded with each other satisfies the above predetermined composition, thereby obtaining a joint having high strength and excellent bending characteristics. It is done. The aluminum alloy material itself is a so-called aluminum alloy wrought material, which is a plate material manufactured by normal rolling and an extruded material manufactured by normal extrusion.

溶接構造体の母材として、溶接ビードと同様の組成を有することにより、上述の各元素の添加理由及び組成限定理由に記載したように、母材自体が、強度が高く、曲げ特性が優れたものとなる。従って、溶接構造体としても、母材及び継手の双方について、強度及び曲げ特性が優れたものとなる。   By having the same composition as the weld bead as the base material of the welded structure, the base material itself has high strength and excellent bending characteristics, as described in the reasons for adding each element and the reason for limiting the composition. It will be a thing. Accordingly, the welded structure also has excellent strength and bending characteristics for both the base material and the joint.

この本発明のアルミニウム溶接構造体は、適宜、製造工程において、溶体化焼入れ処理後、時効硬化の熱処理を施しても良い。   The aluminum welded structure of the present invention may be subjected to age hardening heat treatment after solution heat treatment in the manufacturing process as appropriate.

本発明のアルミニウム溶接構造体は、溶加材を使用しないで溶融溶接する場合は、TIG溶接又はレーザ溶接により溶融溶接することができる。   When the aluminum welded structure of the present invention is melt welded without using a filler metal, it can be melt welded by TIG welding or laser welding.

次に、本願請求項3に係る発明のアルミニウム溶接構造体について説明する。このアルミニウム溶接構造体は、Al−Cu系合金材同士を、溶加材を使用して溶融溶接したものであり、この場合は、例えば、MIG溶接により溶融溶接することができる。溶加材としては、例えば、Si:4.7乃至5.55質量%、Cu:0.02乃至0.26質量%、Mg:0.59乃至1.66質量%、Mn:0.3乃至0.52質量%、残部Al及び不可避的不純物のアルミニウム合金からなるソリッドワイヤを使用することができる。   Next, an aluminum welded structure according to the third aspect of the present invention will be described. This aluminum welded structure is obtained by melting and welding Al—Cu based alloy materials using a filler metal. In this case, for example, it can be melt welded by MIG welding. Examples of the filler material include Si: 4.7 to 5.55 mass%, Cu: 0.02 to 0.26 mass%, Mg: 0.59 to 1.66 mass%, Mn: 0.3 to A solid wire made of an aluminum alloy of 0.52% by mass, the balance Al and unavoidable impurities can be used.

このアルミニウム溶接構造体の溶接ビードは、Si:4.0乃至5.0質量%、Cu:0.6乃至1.10質量%、Mg:0.5乃至1.5質量%、Mn:0.3乃至0.5質量%を含有し、残部がAl及び不可避的不純物からなる組成を有する。この各成分の添加理由及び組成限定理由は、前述のとおりである。従って、この溶接ビードは、高強度であり、曲げ特性が優れたものとなる。このアルミニウム合金溶接構造体は、母材としては、例えば,JIS2219合金又はJIS2024合金を使用することができる。この母材に対し、溶加材として、上記アルミニウム合金を使用してMIG溶接すると、その溶加材の供給速度等を適宜調節することにより、上記組成の溶接ビードを得ることができる。   The weld bead of this aluminum welded structure has Si: 4.0 to 5.0% by mass, Cu: 0.6 to 1.10% by mass, Mg: 0.5 to 1.5% by mass, Mn: 0.00%. It contains 3 to 0.5% by mass, and the balance is composed of Al and inevitable impurities. The reason for adding each component and the reason for limiting the composition are as described above. Therefore, this weld bead has high strength and excellent bending characteristics. In this aluminum alloy welded structure, for example, JIS2219 alloy or JIS2024 alloy can be used as a base material. When MIG welding is performed on the base material using the aluminum alloy as a filler material, a welding bead having the above composition can be obtained by appropriately adjusting the supply rate of the filler material.

次に、溶接方法について説明する。図1は、参考例として、溶加材を使用しないレーザ溶接による重ね合わせ溶接方法を示す図である。アルミニウム合金材2及び3が突き合わされ、この突合せ部6にレーザ光が照射され、そのレーザ光により、母材のアルミニウム合金材2,3が加熱されてアルミニウム合金材2、3が溶融溶接される。これにより、突合せ継手が得られる。 Next, the welding method will be described. FIG. 1 is a diagram showing a lap welding method by laser welding without using a filler material as a reference example . The aluminum alloy materials 2 and 3 are butted together, and the butted portion 6 is irradiated with laser light. The aluminum alloy materials 2 and 3 are heated by the laser light, and the aluminum alloy materials 2 and 3 are melt-welded. . Thereby, a butt joint is obtained.

図2は溶加材を使用するMIG溶接による突合せ溶接方法を示す図である。アルミニウム合金材2,3が突合せられ、MIG溶接の場合は、この突合せ部6に、フラックス入りワイヤ又はソリッドワイヤ等の溶接ワイヤ1がトーチ7を介して送給される。そして、この突合せ部6とワイヤ1との間にアークが形成されて、突合せ部6が溶融溶接される。これにより、突合せ継手が得られる。このMIG溶接による溶加材は、溶接ワイヤ1である。   FIG. 2 is a view showing a butt welding method by MIG welding using a filler metal. In the case of MIG welding, the aluminum alloy materials 2 and 3 are butted together, and a welding wire 1 such as a flux-cored wire or a solid wire is fed to the butting portion 6 via a torch 7. An arc is formed between the butt 6 and the wire 1, and the butt 6 is melt welded. Thereby, a butt joint is obtained. The filler material by MIG welding is a welding wire 1.

上記図1及び図2のいずれの場合も、得られた溶接ビードは前述のごとく、強度及び曲げ特性が優れたものであり、溶接割れの発生が防止される。   1 and 2, the obtained weld bead is excellent in strength and bending characteristics as described above, and the occurrence of weld cracks is prevented.

次に、本発明の溶加材を使用した実施例の効果について、その比較例と比較して説明する。JIS2219合金(Cu:5.84%、Si:0.08%、Mg:0.01%、Mn:0.3%、残部Al及び不可避的不純物)と、JIS2024合金(Cu:4.7%、Si:0.12%、Mg:1.44%、Mn:0.6%、残部Al及び不可避的不純物)の2種類のアルミニウム合金板(板厚4mm)を突き合わせして、下記表1に記載の組成(残部はAl及び不可避的不純物)を有する溶加材(直径1.6mm)を添加しつつ、MIG溶接を行った。突き合わせ部は90°の開先角度を設けた。また、溶接条件は電流が195A、電圧が23V、溶接速度が50cm/分であり、シールドガスとしてArガスを使用し、シールドガス流量は10リットル/分であった。なお、規格上、JIS2219合金は、Cu:5.8乃至6.8質量%、Si:0.20質量%未満であり、JIS2024合金は、Cu:3.8乃至4.9質量%、Si;0.5質量%未満であり、いずれもCu含有量が高いAl−Cu系合金である。 Next, the effect of the actual施例using filler metal of the present invention will be described in comparison with the comparative example. JIS2219 alloy (Cu: 5.84%, Si: 0.08%, Mg: 0.01%, Mn: 0.3%, balance Al and unavoidable impurities) and JIS2024 alloy (Cu: 4.7%, Two types of aluminum alloy plates (sheet thickness 4 mm) of Si: 0.12%, Mg: 1.44%, Mn: 0.6%, the balance Al and unavoidable impurities) were butted together and listed in Table 1 below. MIG welding was performed while adding a filler metal (diameter: 1.6 mm) having the following composition (the balance being Al and inevitable impurities). The butt portion was provided with a groove angle of 90 °. The welding conditions were as follows: current was 195 A, voltage was 23 V, welding speed was 50 cm / min, Ar gas was used as the shielding gas, and the shielding gas flow rate was 10 liters / min. According to the standard, JIS2219 alloy is Cu: 5.8 to 6.8 mass%, Si: less than 0.20 mass%, and JIS2024 alloy is Cu: 3.8 to 4.9 mass%, Si; It is less than 0.5% by mass, and all are Al—Cu based alloys having a high Cu content.

Figure 0005484253
Figure 0005484253

なお、溶加材を添加する場合の溶融ビードの成分調整は、母材の成分を元に溶加材の成分調整と開先形状(I型、V型等)から希釈率を算出することより行うことができる。このようにして得られた継手について、引張試験及びフィッシュボーン試験を行った。その結果を、下記表2に示す。なお、FBはフィッシュボーン割れのことであり、HAZとは溶接熱影響部割れのことである。
先ず、溶接余盛を研削により除去し、JIS Z3121の1号試験片により引張試験を実施し、溶接金属部で破断させ、溶接金属部の特性を評価した。この評価結果を表2に示す。また、曲げ試験として、同じく継手から余盛を研削除去して、曲率半径が8mmのU字曲げを実施した。この曲率半径は、試験片の厚さ方向の中央の位置の曲率半径である。更に、溶接金属部についてフィッシュボーン試験を実施し、割れ率=割れ長さ/溶接長×100により割れ率(%)を算出して、溶接割れを評価した。図3はフィッシュボーン試験片を示す図である。フィッシュボーン割れ率は20%を超える場合を×、20%以下の場合を○とした。溶接熱影響部(HAZ)割れの欄は、溶接熱影響部の断面を観察した。継手特性強度の欄は、余盛高さが無い状態で、300MPa未満の場合を×、300MPa以上の場合を○とした。継手特性の曲げ欄においては、継手の曲げ試験に際して、割れが発生した場合を×、割れが発生しなかった場合を○とした。総合評価欄は、フィッシュボーン割れ率、溶接熱影響部割れ、継手強度、継手曲げ試験割れのいずれの場合も○のときに○、いずれかが×の場合に×とした。
In addition, the component adjustment of the molten bead when the filler material is added is based on the component adjustment of the filler material and the dilution rate calculated from the groove shape (I type, V type, etc.) based on the component of the base material. It can be carried out. The joint thus obtained was subjected to tensile test and fishbone test. The results are shown in Table 2 below. In addition, FB is a fishbone crack, and HAZ is a weld heat affected zone crack.
First, the weld surplus was removed by grinding, a tensile test was performed with a No. 1 test piece of JIS Z3121, the weld metal part was broken, and the characteristics of the weld metal part were evaluated. The evaluation results are shown in Table 2. Moreover, as a bending test, the surplus was similarly removed by grinding from the joint, and U-shaped bending with a radius of curvature of 8 mm was performed. This radius of curvature is the radius of curvature at the center position in the thickness direction of the test piece. Further, a fish bone test was performed on the weld metal part, and the crack ratio (%) was calculated by crack ratio = crack length / weld length × 100 to evaluate weld cracks. FIG. 3 is a view showing a fishbone test piece. The case where the fishbone cracking ratio exceeds 20% was evaluated as x, and the case where it was 20% or less was evaluated as ◯. In the column of the weld heat affected zone (HAZ) crack, the cross section of the weld heat affected zone was observed. In the column of joint characteristic strength, the case of less than 300 MPa is indicated as “x” and the case of 300 MPa or more is indicated as “◯” when there is no extra height. In the bending column of the joint characteristics, when the joint was subjected to a bending test, the case where cracking occurred was indicated as x, and the case where cracking did not occur was indicated as ◯. In the comprehensive evaluation column, “◯” was given when the fishbone cracking ratio, weld heat affected zone cracking, joint strength, and joint bending test cracking were “good”, and “x” was given when any of them was x.

Figure 0005484253
Figure 0005484253

この表2に示すように、比較例21は溶融ビードのCu成分量が高いため、継手強度が低下した。比較例22は溶融ビードのCu成分量が低いため溶接割れが発生した。比較例23は、溶融ビードのSiが高いため、継手強度及び曲げ特性が低下した。比較例24はSiが低いため、溶接割れが発生するとともに、継手強度と曲げ性が共に低下した。比較例25はMgが高いため、溶接割れが発生し熱影響部(HAZ)での割れも観察された。比較例26はMgが低いため、溶接割れが発生し、継手強度及び曲げ特性が低下した。比較例27はMnが高いため、溶接割れが発生した。比較例28はMnが低いため、継手強度が低下した。
As shown in Table 2 , since Comparative Example 21 had a high Cu component in the molten bead, the joint strength was reduced. In Comparative Example 22, weld cracking occurred because the amount of Cu component in the molten bead was low. Since the comparative example 23 had high Si of molten bead, joint strength and the bending characteristic fell. Since Comparative Example 24 had low Si, weld cracking occurred and joint strength and bendability both decreased. Since Comparative Example 25 had high Mg, a weld crack was generated and a crack in the heat affected zone (HAZ) was also observed. In Comparative Example 26, since Mg was low, weld cracks occurred, and joint strength and bending characteristics were deteriorated. Since Comparative Example 27 had a high Mn, weld cracks occurred. Since the comparative example 28 had low Mn, joint strength fell.

一方、本発明の実施例21〜33はいずれも溶接割れは発生せず、継手強度及び曲げ特性が良好であり、高い継手性能を示した。   On the other hand, all of Examples 21 to 33 of the present invention did not generate weld cracks, had good joint strength and bending characteristics, and exhibited high joint performance.

1:溶接ワイヤ
2,3:アルミニウム合金材
6:突合せ部
1: Welding wire 2, 3: Aluminum alloy material 6: Butting part

Claims (2)

JIS2219合金材又はJIS2024合金材同士を溶加材を使用して溶融溶接することにより得られたアルミニウム溶接構造体において、溶接ビードの組成が、Si:4.0乃至5.0質量%、Cu:0.6乃至1.10質量%、Mg:0.5乃至1.5質量%、Mn:0.3乃至0.5質量%を含有し、残部がAl及び不可避的不純物からなることを特徴とするアルミニウム溶接構造体。 In an aluminum welded structure obtained by melt welding JIS2219 alloy material or JIS2024 alloy material using a filler metal, the composition of the weld bead is Si: 4.0 to 5.0 mass%, Cu: 0.6 to 1.10% by mass, Mg: 0.5 to 1.5% by mass, Mn: 0.3 to 0.5% by mass, the balance being made of Al and inevitable impurities Aluminum welded structure. 前記溶融溶接は、MIG溶接であることを特徴とする請求項に記載のアルミニウム溶接構造体。 The aluminum welded structure according to claim 1 , wherein the fusion welding is MIG welding.
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