JP5543101B2 - Double-sided adhesive sheet - Google Patents

Description

  The present invention relates to a double-sided pressure-sensitive adhesive sheet.

Conventionally, as shown in an enlarged cross-sectional view in FIG. 7, a first pressure-sensitive adhesive layer 46 and a second pressure-sensitive adhesive layer 47 are laminated with an intermediate base material layer 41 such as a plastic film or a nonwoven fabric interposed therebetween, A double-sided pressure-sensitive adhesive sheet 44 in which release sheets 42 and 43 are further laminated on the outer surface is widely known. Furthermore, as previously proposed by the present applicant, even in a large number of laminated sheets, an intermediate substrate is always interposed between the pressure-sensitive adhesive layer and the pressure-sensitive adhesive layer (see Patent Document 1). .
Japanese Patent No. 4052900

  However, the conventional double-sided pressure-sensitive adhesive sheet 44 having the structure shown in FIG. 7 has the following problems. (I) The point that it is difficult to adhere along the shape of the unevenness of the adherend, (ii) The point that the transparency is lowered and the liquid crystal screen (optical film) is not suitable, (iii) When a general highly transparent polyester film is used as the intermediate base material layer 41, the birefringence increases and the liquid crystal screen (optical film) is not clear.

  Further, conventionally, as shown in FIG. 8, a double-sided pressure-sensitive adhesive sheet 51 comprising a single-layer pressure-sensitive adhesive layer 48 and release sheets 49, 50 laminated on both sides thereof is also known, but of course, The front and back surfaces 48a and 48b of the pressure-sensitive adhesive layer 48 exhibit the same pressure-sensitive adhesive properties and have the following problems. That is, (i) When used between two types of adherends with different properties (characteristics), if one can be stably and firmly adhered to the other, but the other is difficult to adhere or has low adhesive strength (Ii) The material that becomes the adherend is limited in connection with this, (iii) Even when trying to peel off only one release sheet from the state of FIG. However, the adhesive layer 48 is locally deformed and cannot be adhered to the adherend cleanly.

Therefore, the double-sided PSA sheet according to the present invention is to omit the intermediate base layer, the laminated first adhesive layer and second adhesive layer different adhesive properties, the outer surface of the first pressure-sensitive adhesive layer A double-sided pressure-sensitive adhesive sheet comprising a first release sheet and a second release sheet laminated on the outer surface of the second pressure-sensitive adhesive layer ; the pressure-sensitive adhesive property of the first pressure-sensitive adhesive layer is excellent in flexibility and uneven follow-up As it is high, in a holding power test according to JIS Z0237 , the displacement is 0.1 mm or more at 40 ° C atmosphere and 10,000 seconds, the storage elastic modulus at 25 ° C is 0.01 to 10 MPa, and at 25 ° C. Loss tangent tan δ value is 0.1 or more; in the holding power test according to JIS Z0237, the deviation property is less than 0.2mm in 40 ° C atmosphere and 10,000 seconds so that the adhesive property of the second adhesive layer is excellent in cohesive force In addition, a ball tack No. at an inclination angle of 30 ° with an inclination ball tack according to JIS Z0237. Is 8 or less.
Further, the displacement of the first pressure-sensitive adhesive layer is 0.2 mm or more, the value of the storage elastic modulus is 0.01 to 0.5 MPa, and the loss tangent tan δ value is 0.3 or more; The above-mentioned ball tack No. Was set to 3 or less.

According to the present invention, when used between two types of adherends having different properties (characteristics), they can be stably and firmly attached to any adherend. That is, the first pressure-sensitive adhesive layer can be beautifully affixed to an adherend having an irregularity, and on the other hand, the second pressure-sensitive adhesive layer can prevent the edge from protruding and can also prevent the phenomenon of rising due to gas.

Hereinafter, the present invention will now be described with reference to certain exemplary embodiments illustrated.
In FIG. 1, the adhesive sheet S which concerns on this invention is illustrated, the intermediate | middle base material layer is abbreviate | omitted, and the 1st adhesive layer 1 and the 2nd adhesive layer 2 which differed in the adhesive characteristic were mutually (mutually). It is constructed by stacking. As shown in FIG. 5, the double-sided pressure-sensitive adhesive sheet S is interposed between the facing adherends 11 and 12 and adheres the adherends 11 and 12 to each other.

By the way, since only the basic structure shown in FIG. 1 is difficult to handle (work), as shown in FIG. 2, the first release sheet 3 is laminated on the outer surface 1a of the first pressure-sensitive adhesive layer 1, and The second release sheet 4 is laminated on the outer surface 2 a of the second pressure-sensitive adhesive layer 2. As described above, in another embodiment shown in FIG. 2, the first release sheet 3, the first pressure-sensitive adhesive layer 1, the second pressure-sensitive adhesive layer 2, and the second release sheet 4 are sequentially laminated and integrated. is there.
In the present invention, the term “release sheet” is defined to include both various plastic sheets (films) and so-called release papers such as natural paper and synthetic paper. .

The first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 are made of a highly transparent material. That is, the total light transmittance of the first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 combined (totaled) is set to 85% or more and Haze is set to 1.0 or less.
And the difference of the adhesive force of the 1st adhesive layer 1 and the 2nd adhesive layer 2 is set to 1 N / 25mm or more. Desirably, it shall be 2N / 25mm or more. More desirably, it is 3N / 25 mm or more.
Specifically, the adhesive property of the second adhesive layer 2 is set to a weak adhesive strength of 0.1 to 8 N / 25 mm, and the adhesive property of the first adhesive layer 1 is a strong strength of 10 N / 25 mm or more. Set to adhesive strength.
In addition, the measurement of the above-mentioned adhesive strength is in accordance with JIS Z0237. Adhesion and measurement atmosphere: 23 ° C 50%, 2 reciprocating pressure bonding with 2kg rubber roll, peeling speed 300mm / min, peeling angle 180 °, adherend: stainless steel Paste under conditions, and measure the adhesive strength after 24 hours.

  Since the adhesive strength of the second pressure-sensitive adhesive layer 2 is set sufficiently smaller than the adhesive strength of the first pressure-sensitive adhesive layer 1, the second adhesive layer 2 is used as shown in FIG. It is reliable and easy to peel only the pressure-sensitive adhesive layer 2. That is, in the single pressure-sensitive adhesive layer 48 as in the conventional example (see FIG. 8), if one of the release sheets 49 and 50 is peeled off, the other part is also peeled off, and the pressure-sensitive adhesive layer is beautiful. 48 was difficult to affix to the adherend, but in the present invention, it can be easily peeled only from the weak adhesive side (that is, the second adhesive layer 2 side), and the arrow as shown in FIG. As shown in A, the adherend 12 can be neatly attached without causing wrinkles or local deformation, and then the first release sheet 3 is peeled off as shown by an arrow B as shown in FIG. Then, as shown in FIG. 5, if another adherend 11 is pressed as shown by an arrow C, it can be beautifully attached without any wrinkles, lifting, or local deformation.

  In the present invention, for the convenience of explanation in FIGS. 2 to 5, the adhesive force of the second adhesive layer 2 is weak and the adhesive force of the first adhesive layer 1 is strong. Even if it is a case, it is free.

  Next, another embodiment will be described. In FIG. 1, FIG. 3, and FIG. 6, the adhesive property of the first pressure-sensitive adhesive layer 1 is excellent in flexibility and has high unevenness followability. On the other hand, the adhesive property of the second adhesive layer 2 is excellent in cohesive force. Thus, the first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 are greatly different in pressure-sensitive adhesive properties. Since the second pressure-sensitive adhesive layer 2 is excellent in cohesive force as described above, it protrudes from the end 6 of the second pressure-sensitive adhesive layer 2 (as shown in FIG. 6). (Refer to section 7). Moreover, as shown in FIG. 6, even if it is the shape where the unevenness | corrugation 8 exists in one to-be-adhered body 11, the 1st adhesive layer 1 with sufficient flexibility follows the unevenness | corrugation 8 deform | transforming easily. There are advantages.

  By the way, it is defined as follows that it is excellent in the softness | flexibility of the 1st adhesive layer 1, and uneven | corrugated followable | trackability is high. In other words, the cohesive force of the adhesive is not high in order to improve unevenness followability, and in a holding power test according to JIS Z0237, in a 40 ° C atmosphere, a deviation of 0.1 mm or more in 10,000 seconds, at 25 ° C The value of the storage elastic modulus G ′ is 0.01 to 10 MPa, and the loss tangent tan δ (tan δ = loss elastic modulus / storage elastic modulus) at 25 ° C. is 0.1 or more. Particularly preferably, the value of the storage elastic modulus G ′ at 25 ° C. is 0.01 to 0.5 MPa and the value of tan δ is 0.3 or more.

  And it is defined as being excellent in the cohesion force of the 2nd adhesive layer 2 as follows. That is, in the holding force test according to JIS Z0237, the deviation is less than 0.2 mm at 10,000C in an atmosphere of 40 ° C, and the ball tack number at an inclination angle of 30 ° is 8 with an inclined ball tack according to JIS Z0237. It is as follows. It is particularly preferable that the holding force has no deviation and the ball tack is 3 or less.

  As still another embodiment of the present invention, the first pressure-sensitive adhesive layer 1 has a high pressure-sensitive adhesive property and high unevenness followability, and the second pressure-sensitive adhesive layer 2 is to be bonded. It is also preferable to have a gas floating resistance characteristic that does not cause gas floating even when gas is generated from the surface. Thus, in this invention, it can be said that it has the characteristic in the point which makes the adhesive characteristic of the 1st adhesive layer 1 and the 2nd adhesive layer 2 different, and combines variously.

  It is also preferable to combine the embodiment described with reference to FIG. 6 and the embodiment described with reference to FIGS. By the way, as a material of the first and second pressure-sensitive adhesive layers 1 and 2, it is desirable that the difference in refractive index is small from the viewpoint of optical characteristics. For example, an acrylic pressure-sensitive adhesive / acrylic pressure-sensitive adhesive is preferable. The refractive index difference should be 0.1 or less. Of course, depending on the material, shape and use conditions of the adherends 11 and 12, a combination of acrylic / urethane or acrylic / rubber is also desirable. And this invention is a double-sided adhesive sheet suitable for uses, such as a liquid crystal touch panel.

As described above, the double-sided pressure-sensitive adhesive sheet according to the present invention is configured by laminating the first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 with different adhesive properties, omitting the intermediate base material layer. It can be attached neatly along the shape of unevenness of the adherends 11 and 12. Even if the adherend characteristics of the adherends 11 and 12 are different, it is possible to select and cope with the optimum adhesive characteristics for each. Thus, each adhesive characteristic can be selected according to a use.
Moreover, while omitting an intermediate | middle base material layer, while laminating | stacking the 1st adhesive layer 1 and the 2nd adhesive layer 2 from which an adhesive characteristic differs, it is the 1st peeling sheet 3 on the outer surface 1a of the said 1st adhesive layer 1. Since the second release sheet 4 is laminated on the outer surface 2a of the second pressure-sensitive adhesive layer 2, the handling is easy, the sticking operation is easy, and the unevenness of the adherends 11 and 12 is further improved. It can be applied neatly along the shape. Even if the adherence characteristics of the adherends 11 and 12 are different, it is possible to selectively cope with the respective optimum adhesive characteristics. In this way, the adhesive property can be selected for each according to the application. Further, the release sheets 3 and 4 can be peeled in order and can be beautifully attached to the adherends 11 and 12.

Moreover, since the first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 are made of a highly transparent material, they can be made extremely thin, have no problem of birefringence, and have excellent transparency. Suitable as an optical film.
Further, the total light transmittance of the first pressure-sensitive adhesive layer 1 and the second pressure-sensitive adhesive layer 2 is 85% or more, and the haze is set to 1.0 or less. Preferred as a film.

Further, the adhesive property of the second adhesive layer 2 is set to a weak adhesive force of 0.1 to 8 N / 25 mm, and the adhesive property of the first adhesive layer 1 is set to a strong adhesive force of 10 N / 25 mm or more. Because it is set, the peeling sheets 3 and 4 can be peeled exactly one by one according to the order at the time of sticking work, and it follows the outer surface shape of the adherends 11 and 12 cleanly without causing wrinkles or deformation. Can be attached.
In addition, since the difference in adhesive strength between the first adhesive layer 1 and the second adhesive layer 2 is set to 1 N / 25 mm or more, the release sheets 3 and 4 are peeled exactly one by one in order during the pasting operation. This is possible, and can be neatly adhered along the outer surface shape of the adherends 11 and 12 without causing wrinkles or deformation.

In addition, the adhesive properties of the first pressure-sensitive adhesive layer 1 were made different so that the adhesive properties were excellent in flexibility and uneven followability, and the adhesive properties of the second pressure-sensitive adhesive layer 2 were excellent in cohesive force. Since it was set as the structure, as illustrated in FIG. 6, the adherend 11 having the unevenness 8 is securely attached to the first pressure-sensitive adhesive layer 1, while the second pressure-sensitive adhesive layer 2 protrudes the end edge ( 6 (see reference 6 of 6).
In addition, the adhesive property of the first pressure-sensitive adhesive layer 1 is excellent in flexibility and has high unevenness followability, and the second pressure-sensitive adhesive layer 2 does not cause gas floating even when gas is generated from the adherend surface. Since it has gas floating resistance, it can be firmly attached to the first pressure-sensitive adhesive layer 1 having the irregularities 8 (as shown in FIG. 6), and the second pressure-sensitive adhesive layer 2 Even the adherend 12 made of a material that easily generates gas can be applied. In this way, the phenomenon of rising due to gas can be prevented.

It is an expanded sectional view showing one embodiment of the double-sided adhesive sheet of the present invention. It is an expanded sectional view showing other embodiments. It is an expanded sectional view for use condition explanation. It is an expanded sectional view for use condition explanation. It is an expanded sectional view for use condition explanation. It is an expanded sectional view which shows another embodiment. It is an expanded sectional view which shows a prior art example. It is an expanded sectional view showing other conventional examples.

DESCRIPTION OF SYMBOLS 1 1st adhesive layer 1a outer surface 2 2nd adhesive layer 2a outer surface 3 1st peeling sheet 4 2nd peeling sheet

Claims (2)

While omitting the intermediate base material layer, the first pressure-sensitive adhesive layer (1) and the second pressure-sensitive adhesive layer (2) having different adhesive properties are laminated , and the outer surface (1a) of the first pressure-sensitive adhesive layer (1). A first release sheet (3) and a second release sheet (4) laminated on the outer surface (2a) of the second adhesive layer (2), respectively,
In the holding force test according to JIS Z0237, the first adhesive layer (1) has an adhesive property of 40 mm atmosphere, 10,000 seconds with a displacement of 0.1 mm or more so that it has excellent flexibility and high conformity. The storage elastic modulus (G ′) at 25 ° C. is 0.01 to 10 MPa, and the loss tangent tan δ value at 25 ° C. is 0.1 or more.
In the holding power test according to JIS Z0237, the deviation of the second adhesive layer (2) is less than 0.2mm in a 40 ° C atmosphere and 10,000 seconds so that the cohesive strength is excellent. Also, JIS Z0237 No. of ball tack No. at an inclination angle of 30 ° Is 8 or less,
A double-sided pressure-sensitive adhesive sheet characterized by that. The displacement of the first pressure-sensitive adhesive layer (1) is 0.2 mm or more, the value of the storage elastic modulus (G ′) is 0.01 to 0.5 MPa, and the loss tangent tan δ value is 0.3 or more,
There is no deviation of the second pressure-sensitive adhesive layer (2), and the ball tack no. The double-sided pressure-sensitive adhesive sheet according to claim 1, wherein is 3 or less.

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