JP5550103B2 - Germinated brown rice and its production method - Google Patents
Germinated brown rice and its production method Download PDFInfo
- Publication number
- JP5550103B2 JP5550103B2 JP2010001652A JP2010001652A JP5550103B2 JP 5550103 B2 JP5550103 B2 JP 5550103B2 JP 2010001652 A JP2010001652 A JP 2010001652A JP 2010001652 A JP2010001652 A JP 2010001652A JP 5550103 B2 JP5550103 B2 JP 5550103B2
- Authority
- JP
- Japan
- Prior art keywords
- brown rice
- rice
- germinated brown
- germination
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000021329 brown rice Nutrition 0.000 title claims description 144
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 241000209094 Oryza Species 0.000 claims description 114
- 235000007164 Oryza sativa Nutrition 0.000 claims description 114
- 235000009566 rice Nutrition 0.000 claims description 114
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 66
- 230000035784 germination Effects 0.000 claims description 55
- 238000011282 treatment Methods 0.000 claims description 38
- 238000010411 cooking Methods 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 17
- 241001499808 Allium atrorubens Species 0.000 claims description 12
- 241000234282 Allium Species 0.000 claims description 7
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 5
- 229920000945 Amylopectin Polymers 0.000 claims description 3
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 39
- 230000000704 physical effect Effects 0.000 description 26
- 238000007710 freezing Methods 0.000 description 24
- 230000008014 freezing Effects 0.000 description 24
- 238000000034 method Methods 0.000 description 21
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 19
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 19
- 238000007654 immersion Methods 0.000 description 16
- 235000008429 bread Nutrition 0.000 description 15
- 235000013339 cereals Nutrition 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 238000010521 absorption reaction Methods 0.000 description 13
- 239000013078 crystal Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 235000013312 flour Nutrition 0.000 description 10
- 235000019640 taste Nutrition 0.000 description 10
- 235000013305 food Nutrition 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000002791 soaking Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000012149 noodles Nutrition 0.000 description 4
- 238000000638 solvent extraction Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 102000008214 Glutamate decarboxylase Human genes 0.000 description 3
- 108091022930 Glutamate decarboxylase Proteins 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZVOLCUVKHLEPEV-UHFFFAOYSA-N Quercetagetin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=C(O)C(O)=C(O)C=C2O1 ZVOLCUVKHLEPEV-UHFFFAOYSA-N 0.000 description 3
- HWTZYBCRDDUBJY-UHFFFAOYSA-N Rhynchosin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=CC(O)=C(O)C=C2O1 HWTZYBCRDDUBJY-UHFFFAOYSA-N 0.000 description 3
- 229930003270 Vitamin B Natural products 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 229960001285 quercetin Drugs 0.000 description 3
- 235000005875 quercetin Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000019156 vitamin B Nutrition 0.000 description 3
- 239000011720 vitamin B Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 235000005911 diet Nutrition 0.000 description 2
- 230000037213 diet Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 238000004108 freeze drying Methods 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 235000019583 umami taste Nutrition 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 240000002582 Oryza sativa Indica Group Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229940124277 aminobutyric acid Drugs 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 230000003727 cerebral blood flow Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002124 endocrine Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000019607 umami taste sensations Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Landscapes
- Confectionery (AREA)
- Cereal-Derived Products (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Noodles (AREA)
Description
本発明は、洗米もしくは水に浸漬して吸水した玄米を、低温処理した後、温湯中に浸漬して発芽を促してから炊飯することを特徴とする、発芽玄米米飯の製造方法に関する。 The present invention relates to a method for producing germinated brown rice, which comprises subjecting brown rice that has been washed or soaked in water to absorb water after low-temperature treatment and then immersing it in warm water to promote germination before cooking.
わが国において、健康を維持増進するために、運動とともに食生活が重視されている。食事から、生命の維持に必要なカロリーを得るのみでなく、ビタミン、食物繊維、ミネラルその他の健康維持に有益な成分を得ることが重要である。発芽玄米は、古来、農家の食用の一部とされてきたが、工業的に製造されるようになったのは、ごく最近のことであり、発明者らも1999年に特許を出願している(特許文献1参照)。
発芽玄米はその簡便性と食味の改善、さらには健康機能性が評価されて普及が進んでいるが、工業的生産においても、まだ硬くて粘りが少なく、白米との混合炊飯が推奨されていること、少なくとも一晩の温湯浸漬と加熱殺菌工程を必要とするために市販品は高価であり、家庭で製造するには同様の長時間を要するとともに、発芽玄米製品の食味、安定性、衛生性、手間などの点で問題が残されていた。
In Japan, in order to maintain and improve health, emphasis is placed on diet as well as exercise. It is important not only to obtain the calories necessary to maintain life from the diet, but also to obtain vitamins, dietary fiber, minerals and other beneficial components for maintaining health. Germinated brown rice has long been regarded as a part of farmer's food, but it has only recently been industrially manufactured. The inventors filed a patent in 1999. (See Patent Document 1).
Germinated brown rice is gaining popularity due to its convenience, improved taste, and health functionality, but it is still hard and less sticky in industrial production, and mixed rice with white rice is recommended. In addition, commercial products are expensive because they require at least one night of hot water soaking and a heat sterilization process, and it takes a similar amount of time to produce at home, and the taste, stability, and hygiene of germinated brown rice products The problem was left in terms of time and effort.
発芽玄米は、従来は30〜40℃の温湯に一晩〜数日間浸漬し、発芽させていた(特許文献1参照)。白米より硬くて粘りが弱い上に、長時間の浸漬過程で微生物が繁殖したり、玄米自身の自己消化が進んだりするために、浸漬液が濁ったり、発芽玄米に異臭が発生したり、生菌数が増加したりする問題があった。また、微生物の繁殖や異臭の発生を抑制するために、浸漬水を数回交換する必要があり、水溶性の機能性成分であるビタミンB群やミネラル類、発芽過程で生産された機能性成分であるγ−アミノ酪酸(GABA)等が溶出して失われるという問題があった。 Germinated brown rice has been soaked in hot water at 30 to 40 ° C. overnight to several days for germination (see Patent Document 1). In addition to being harder and less sticky than white rice, microorganisms propagate in the soaking process for a long time, and self-digestion of brown rice progresses. There was a problem that the number of bacteria increased. In addition, in order to suppress the growth of microorganisms and the generation of off-flavors, it is necessary to change the immersion water several times. Vitamin B groups and minerals that are water-soluble functional ingredients, functional ingredients produced in the germination process There is a problem that γ-aminobutyric acid (GABA) and the like are lost by elution.
本発明は、上記課題を解決し、玄米の迅速な発芽と炊飯が可能であって、且つ、風味、米飯物性、衛生面、機能性成分の含有率が優れた発芽玄米米飯の製造方法、を提供すること課題とする。 The present invention solves the above-mentioned problems, a method for producing germinated brown rice that enables quick germination and cooking of brown rice, and has excellent flavor, rice physical properties, hygiene, and functional component content. The issue is to provide.
本発明者らは、鋭意研究を重ねた結果、前処理条件および発芽条件を検討し、1)凍結前処理が発芽の促進および米飯物性の改良に有効であること、2)30℃〜55℃の温度帯が発芽を促進され、この温度帯で数時間処理することで発芽が起こることを見いだした。そして、これによって、浸漬液を替えることなく、そのまま加熱炊飯することで、短時間かつ容易に高品質で衛生面でも優れた発芽玄米米飯を製造できることを発見した。 As a result of extensive research, the present inventors have studied pretreatment conditions and germination conditions. 1) Pretreatment with freezing is effective for promoting germination and improving physical properties of cooked rice. 2) 30 ° C to 55 ° C. It was found that germination occurs in the temperature range of, and germination occurs when treated in this temperature range for several hours. And by this, it discovered that the germinated brown rice rice which was excellent in the quality and the hygiene side can be manufactured for a short time easily by heating-cooking rice as it is, without changing immersion liquid.
なお、発芽玄米は硬くて粘りが少なく、食味が白米より劣るため、発芽玄米単独ではなく白米との混合炊飯が推奨されるなど、米飯物性や食味の点で問題が残されていた。本発明では、発芽前に低温処理を施すことにより、吸水を促進する効果があることを見いだし、低温処理の中でも凍結処理、特に緩慢凍結による場合にもっとも効果が顕著であることを見いだした。
また、従来、食品の凍結においては、その物性を良好に保つために、急速凍結が適しているとされてきた(「食品加工学」、朝倉書店、p.162)。本発明者らは、緩慢凍結によって氷晶の生成を促進し、ことさら細胞構造を破壊することによって吸水と発芽を促進するとともに、発芽玄米の物性を改善できることを見いだした。
さらに、玉葱や赤玉葱の成分によって発芽がさらに促進されること、発芽玄米米飯の食味がさらに向上することも見いだした。
本発明は、これらの知見に基づいて完成したものである。
In addition, since germinated brown rice is hard and less sticky, and its taste is inferior to that of white rice, it is recommended to use mixed rice with white rice instead of germinated brown rice alone. In the present invention, it has been found that a low-temperature treatment before germination has an effect of promoting water absorption, and among the low-temperature treatments, it has been found that the effect is most remarkable in the case of freezing treatment, particularly slow freezing.
Conventionally, quick freezing has been considered suitable for freezing foods in order to maintain good physical properties ("Food Processing", Asakura Shoten, p.162). The present inventors have found that slow freezing promotes the formation of ice crystals and, in particular, promotes water absorption and germination by destroying the cell structure, and improves the physical properties of germinated brown rice.
Furthermore, it was found that germination is further promoted by components of onion and red onion and that the taste of germinated brown rice is further improved.
The present invention has been completed based on these findings.
本発明の特徴は、洗米もしくは水に浸漬して吸水した玄米を、0℃未満〜−80℃で低温処理した後、30〜55℃の温湯中に浸漬して発芽を促してから炊飯すること、並びに、前記低温処理が、前記玄米の吸水した水分を緩慢凍結させる条件で行うものであること、を特徴とする、発芽玄米米飯の製造方法である。
本発明の第2の特徴は、前記炊飯が、10℃から加熱開始した場合に60℃までの昇温に20分以上かける昇温速度で行うものである、請求項1に記載の発芽玄米米飯製造方法である。
本発明の第3の特徴は、前記炊飯が、前記温湯中に浸漬して発芽を促した後、液交換することなく直接炊飯を行うものである、請求項1又は2に記載の発芽玄米米飯の製造方法である。
本発明の第4の特徴は、前記温湯に浸漬して発芽を促す処理時間を6時間以内とし且つ炊飯時間を4時間以内とすることによって、迅速に玄米の発芽と炊飯を行う、請求項1〜3のいずれかに記載の発芽玄米米飯の製造方法である。
本発明の第5の特徴は、前記温湯が、赤玉葱および/または玉葱、もしくは、その抽出成分、を含むものである、請求項1〜4のいずれかに記載の発芽玄米米飯の製造方法である。
本発明の第6の特徴は、前記玄米が、アミロペクチン短鎖の少ない超硬質米である、請求項1〜5のいずれかに記載の発芽玄米米飯の製造方法である。
本発明の第7の特徴は、前記0℃未満〜−80℃での低温処理の前に、0〜10℃で低温処理を行う、請求項1〜6のいずれかに記載の発芽玄米米飯の製造方法である。
A feature of the present invention is that brown rice that has been washed or immersed in water to absorb water is subjected to low temperature treatment at less than 0 ° C. to −80 ° C. and then immersed in hot water at 30 to 55 ° C. to promote germination before cooking rice. And the low-temperature treatment is a method for producing germinated brown rice, characterized in that the water absorbed by the brown rice is slowly frozen .
The germinated brown rice according to claim 1, wherein the second feature of the present invention is that the cooked rice is heated at a heating rate of 20 minutes or more for heating to 60 ° C when heating is started from 10 ° C. It is a manufacturing method.
The third feature of the present invention is the germinated brown rice according to claim 1 or 2, wherein the cooked rice is directly cooked without changing the liquid after the rice is immersed in the hot water to promote germination. It is a manufacturing method.
The fourth feature of the present invention is that brown rice is germinated and cooked quickly by setting the treatment time to sprouting by immersing in the hot water within 6 hours and the rice cooking time within 4 hours. It is a manufacturing method of germinated brown rice rice in any one of -3.
The fifth feature of the present invention is the method for producing germinated brown rice according to any one of claims 1 to 4, wherein the hot water contains red onion and / or onion or an extracted component thereof.
The sixth feature of the present invention is the method for producing germinated brown rice according to any one of claims 1 to 5, wherein the brown rice is ultra-hard rice having a short amylopectin short chain.
The seventh feature of the present invention is that the germinated brown rice according to any one of claims 1 to 6, wherein the low temperature treatment at 0 to 10 ° C is performed before the low temperature treatment at less than 0 ° C to -80 ° C. It is a manufacturing method.
本発明により、従来は一晩以上かけて発芽玄米を調製し、次いで、別の炊飯器で炊飯して得られてきた発芽玄米米飯が、1種類の発芽玄米製造炊飯装置を用いることにより、浸漬開始後4時間から10時間の間に発芽玄米米飯として食することが可能(玄米の迅速な発芽と炊飯が可能)となる。
これにより、従来の発芽玄米で問題となっていた、微生物の繁殖と自己消化の問題が著しく軽減され、衛生性が良好で異臭のない風味良好な発芽玄米米飯を得ることができる。また、吸水後、発芽処理前の緩慢凍結処理を加えることで氷晶を意図的に形成させることにより、さらに発芽を促進するとともに、玄米米飯の物性、機能性および食味をさらに向上させることが可能となる。
さらに、赤玉葱等を用いることで発芽をさらに促進し、衛生性を向上させ、GABAやケルセチン等の機能性成分の多い発芽玄米製品を得ることができる。
According to the present invention, the germinated brown rice that has been conventionally prepared over one night or longer and then cooked in another rice cooker is immersed by using one kind of germinated brown rice production rice cooker. It becomes possible to eat as germinated brown rice for 4 hours to 10 hours after the start (quick germination and cooking of brown rice are possible).
Thereby, the problem of microbial reproduction and self-digestion, which has been a problem with conventional germinated brown rice, is remarkably reduced, and germinated brown rice with good sanitation and good odor is obtained. In addition, it is possible to further promote the germination and further improve the physical properties, functionality and taste of brown rice rice by intentionally forming ice crystals by adding a slow freezing treatment prior to germination after water absorption. It becomes.
Furthermore, germination can be further promoted by using red onion, etc., hygiene can be improved, and a germinated brown rice product rich in functional components such as GABA and quercetin can be obtained.
本発明は、洗米もしくは水に浸漬して吸水した玄米を、低温処理した後、温湯中に浸漬して発芽を促してから炊飯することを特徴とする、発芽玄米米飯の製造方法に関する。 The present invention relates to a method for producing germinated brown rice, which comprises subjecting brown rice that has been washed or soaked in water to absorb water after low-temperature treatment and then immersing it in warm water to promote germination before cooking.
<原料玄米>
本発明における玄米とは、イネ種子から籾すりによって籾殻を除いたものである。また、玄米の種類としては、如何なる品種や系統のもの、例えば、コシヒカリ等の一般飯用米、ジャスミンライスなどの外国産インディカ米、はいいぶきやミルキークイーンなどの新形質米、こがねもちなどのもち米、EM10など超硬質米を用いることができる。
これらの中でも特に、アミロペクチン短鎖の少ない超硬質米を使用した場合は、通常の米に比べて発芽が早いこと、難消化性デンプン含量が多いことにより、発芽玄米の価値がさらに高まるので最も好適である。
<Raw raw rice>
The brown rice in the present invention is obtained by removing rice husk from rice seeds by rice bran. In addition, as the kind of brown rice, any varieties and strains, for example, general rice for rice such as Koshihikari, foreign indica rice such as jasmine rice, new trait rice such as haibuki and milky queen, rice cake, etc. Ultra hard rice such as rice and EM10 can be used.
Among these, the use of super-hard rice with a short amylopectin short chain is the most suitable because germination is quicker than normal rice, and the content of hard-to-digest starch increases the value of germinated brown rice. It is.
<低温処理>
本発明では、吸水させた玄米に対して低温処理を行うことによって、玄米の吸水をさらに促進し、発芽を促進することができる。
ここで‘発芽’とは、吸水現象に始まり、‘幼根や子葉が種皮を破って出現するまで’の一連の複雑な生理・生化学変化を含む過程を指す。水分は種子の発芽を規制している第一の要因で、成熟した種子は水分含量が少なく、種子内の代謝活動が著しく抑制されており、発芽に際して多量の水分を必要とする。
ここで、‘吸水’は、通常の如何なる方法で行うことができるが、例えば、玄米を水に浸漬したり、通常の方法で洗米することで行うことができる。なお、低温処理の前に吸水を行わなかった場合、低温処理の効果が十分に得られない。
<Low temperature treatment>
In the present invention, by performing low-temperature treatment on the absorbed brown rice, water absorption of the brown rice can be further promoted, and germination can be promoted.
Here, 'germination' refers to a process that includes a series of complex physiological and biochemical changes starting with water absorption and until 'roots and cotyledons break through the seed coat. Moisture is the first factor that regulates germination of seeds. Mature seeds have low water content, metabolic activity in seeds is remarkably suppressed, and a large amount of water is required for germination.
Here, 'water absorption' can be performed by any ordinary method, for example, it can be performed by immersing brown rice in water or washing the rice by a conventional method. In addition, when water absorption is not performed before a low temperature process, the effect of a low temperature process is not fully acquired.
本発明における低温処理は、10℃以下、好ましくは5℃以下、で行うことができる。例えば、低温処理は、0〜10℃(例えば5℃付近)という通常の冷蔵庫の温度帯で行うことができる。前記吸水した玄米を水に浸漬した状態や乾燥しない状態で、1時間以上(例えば一晩)、当該所定温度に静置することで行うことができる。 The low temperature treatment in the present invention can be performed at 10 ° C. or less, preferably 5 ° C. or less. For example, the low temperature treatment can be performed in a normal refrigerator temperature range of 0 to 10 ° C. (for example, around 5 ° C.). This can be performed by allowing the absorbed brown rice to stand at the predetermined temperature for 1 hour or longer (for example, overnight) in a state where it is immersed in water or not dried.
本発明における低温処理は、特に玄米が吸水した水分を‘緩慢凍結’させて、玄米の組織中に氷晶を形成させるように行うことが望ましい。
本発明においては、氷晶を形成させた後に、発芽及び炊飯を行うことにより、発芽玄米米飯の物性を改良することができる。なお、一般の冷凍食品では、品質を維持するために急速凍結を行い、氷晶形成を抑えることが行われるが、本発明では、通常は避けるべき緩慢凍結によって意図的に氷晶を形成させ、その後に温湯浸漬することによってジベレリンやアミラーゼなどのホルモンや酵素の種子内分泌を加速し、発芽および組織の軟化を促進することができる点に特徴がある。
緩慢凍結をさせる条件としては、玄米の組織中に氷晶を形成される温度で行うことができるが、具体的には、0℃未満〜−80℃程度(例えば−20℃付近)で、前記吸水した玄米を、静置することで行うことができる。
なお、氷晶を形成させるためには、例えば−20℃の場合15分間以上、好ましくは30分間以上、静置することで氷晶を形成させることができる。
The low-temperature treatment in the present invention is particularly preferably performed so that the water absorbed by the brown rice is “slow frozen” to form ice crystals in the brown rice tissue.
In the present invention, the properties of germinated brown rice can be improved by germination and cooking after ice crystals are formed. In addition, in general frozen foods, quick freezing is performed in order to maintain the quality, and ice crystal formation is suppressed.In the present invention, ice crystals are intentionally formed by slow freezing that should normally be avoided, It is characterized by the ability to accelerate seed endocrine secretion of hormones and enzymes such as gibberellin and amylase and to promote germination and tissue softening by immersing in hot water thereafter.
As a condition for slow freezing, it can be performed at a temperature at which ice crystals are formed in the brown rice tissue. Specifically, it is less than 0 ° C. to about −80 ° C. (for example, around −20 ° C.), This can be done by allowing the brown rice that has absorbed water to stand still.
In order to form ice crystals, for example, at −20 ° C., the ice crystals can be formed by standing for 15 minutes or longer, preferably 30 minutes or longer.
なお、当該低温処理は、最初に冷蔵庫の温度帯で行って玄米の吸水をさらに促した後に、緩慢凍結を行ってもよい。 Note that the low-temperature treatment may be first performed in a temperature range of the refrigerator to further promote the water absorption of the brown rice, and then slowly freeze.
<発芽促進処理>
なお、従来の発芽玄米の炊飯法では、一晩から3日間の発芽期間を要し、微生物が繁殖したり、玄米自身の自己消化が進んだりするために、浸漬液が濁ったり、発芽玄米に異臭が発生したり、生菌数が増加したりする問題があった(特開2000-217520号公報)。
また、数回浸漬水を交換しても、微生物の繁殖や発芽玄米の発酵臭の生成抑制には充分ではなく、さらに、浸漬水を交換することによって、水溶性のビタミンB群、ミネラル、γ−アミノ酪酸(GABA)等が失われてしまう問題もあった。
<Sprouting promotion treatment>
In addition, in the conventional rice cooking method of germinated brown rice, it takes a germination period of 3 days from one night, the microorganisms propagate and the self-digestion of the brown rice itself progresses, so the immersion liquid becomes cloudy, There was a problem that a strange odor was generated or the number of viable bacteria increased (Japanese Patent Laid-Open No. 2000-217520).
Moreover, even if the immersion water is changed several times, it is not sufficient to suppress the growth of microorganisms and the generation of the fermentation odor of germinated brown rice. Furthermore, by changing the immersion water, water-soluble vitamin B group, mineral, γ -There was also a problem that aminobutyric acid (GABA) was lost.
本発明では、上記低温処理を施した後、30〜55℃、好ましくは35〜55℃、の温湯中に浸漬することによって、玄米の発芽を促進することができる(発芽促進処理)。
当該温度帯で発芽促進処理を行うことによって、発芽処理時間を大幅に短縮することができる。
具体的には、当該発芽促進処理は、発芽時間を最長でも10時間以内、通常でも6時間以内、最短で4時間以内、で行うものである。
これによって、本発明では、微生物の繁殖が抑えられることによって良好な衛生性を有し、発芽玄米の発酵臭生成を抑制でき、‘浸漬液を交換することなく’そのまま直接加熱炊飯することができる。また、それによって、栄養機能性成分流出を防ぐことができるため、これらの含量を高く保つことが可能となる。
In this invention, after performing the said low temperature process, germination of brown rice can be accelerated | stimulated by immersing in 30-55 degreeC, Preferably it is 35-55 degreeC hot water (germination promotion process).
By performing the germination promotion treatment in the temperature range, the germination treatment time can be greatly shortened.
Specifically, the germination promotion treatment is performed for a germination time of 10 hours or less at the longest, usually 6 hours or less, and 4 hours or less at the shortest.
Thereby, in this invention, it has favorable hygiene by suppressing the propagation of microorganisms, can suppress the generation of fermented odor of germinated brown rice, and can be directly cooked by heating without changing the soaking liquid. . Moreover, since it can prevent a nutrient functional component outflow, it becomes possible to keep these content high.
浸漬液としては、水(温湯)を用いることができるが、種子の発芽を阻害しない程度であれば、薄い塩や緩衝剤を含有するものも用いることができる。
また、浸漬液は、赤玉葱および/または玉葱、もしくは、その抽出成分を含むものであると、発芽促進や微生物の繁殖抑制効果が得られるため、さらに好適である。特には、赤玉葱とその抽出成分が好適である。
これら赤玉葱や玉葱は、生のまま又は半乾燥状態で、丸ごと、大きくカットした状態、細片化、磨砕、もしくは擂潰して、溶液に含有させることができるが、特には、乾燥(具体的には凍結乾燥)させてから細片化(好ましくは粉末化)して、含有させることが望ましい。また、攪拌や混合処理を行い、固形分を懸濁させた状態にすることが望ましい。
赤玉葱および/または玉葱、もしくは、その抽出成分としては、乾燥物換算で0.2〜10.0重量%含有するもの(好ましくは1.0重量%以上、さらには2.0重量%以上含有するもの)であることが望ましい。なお、抽出成分としては、水抽出成分、極性有機溶媒抽出成分(アルコール抽出成分)、混合溶媒抽出成分(クロロホルム・メタノール混合溶媒抽出成分)、非極性有機溶媒抽出成分(ヘキサン抽出成分)などを挙げることができる。
As the immersion liquid, water (hot water) can be used. However, a liquid containing a thin salt or a buffering agent can be used as long as it does not inhibit seed germination.
In addition, it is more preferable that the immersion liquid contains red onion and / or onion, or an extract component thereof, because an effect of promoting germination and suppressing the growth of microorganisms can be obtained. In particular, red onion and its extract components are suitable.
These red onions and onions can be contained in the solution in raw or semi-dried state, whole, large cut, fragmented, ground, or crushed. Specifically, it is desirable to make it contain after freeze-drying) and then pulverizing (preferably pulverizing). In addition, it is desirable that the solid content is suspended by stirring or mixing.
As red onion and / or onion, or as its extract component, 0.2 to 10.0% by weight in terms of dry matter (preferably 1.0% by weight or more, and further 2.0% by weight or more) It is desirable that Examples of the extraction component include a water extraction component, a polar organic solvent extraction component (alcohol extraction component), a mixed solvent extraction component (chloroform / methanol mixed solvent extraction component), and a nonpolar organic solvent extraction component (hexane extraction component). be able to.
<炊飯>
本発明では、上記所定の条件での低温処理と温湯浸漬による発芽促進処理を行って、それを炊飯することで発芽玄米米飯を得ることができる。
炊飯方法としては、前記前処理を行った玄米であれば、通常の炊飯方法(10℃から加熱開始した場合に60℃までの昇温に5〜10分かける昇温速度)で行うことができるが、好ましくは10℃から加熱開始した場合に60℃までの昇温に20分以上かける昇温速度が好適である。
例えば、前記発芽促進処理を37℃で行い、直接炊飯する場合であっても、前記昇温速度に相当するように加熱すればよい。
このような緩やかな昇温条件で加熱を行うことによって、さらに発芽を促進し、酵素の反応時間を長くし、風味と物性の良好な発芽玄米米飯を製造することが可能となる。
なお、本発明における炊飯は、加熱開始から4時間以内、好ましくは3時間以内、で行うことが望ましい。あまりに長く加熱した場合、粒の崩れ、異臭の発生、成分の溶出、がおこるため好ましくない。
<Cooking rice>
In this invention, the germination brown rice rice can be obtained by performing the germination acceleration | stimulation process by the low-temperature process and hot water immersion in the said predetermined conditions, and cooking it.
As a rice cooking method, if it is the brown rice which performed the said pre-processing, it can carry out with the normal rice cooking method (The heating rate which takes 5 to 10 minutes for the temperature rise to 60 degreeC, when heating is started from 10 degreeC). However, when the heating is started from 10 ° C., a heating rate that takes 20 minutes or more to increase the temperature to 60 ° C. is suitable.
For example, even when the germination promotion treatment is performed at 37 ° C. and the rice is directly cooked, it may be heated so as to correspond to the heating rate.
By heating under such mild temperature rise conditions, germination can be further promoted, the reaction time of the enzyme can be increased, and germinated brown rice with good flavor and physical properties can be produced.
In addition, it is desirable that the rice cooking in the present invention is performed within 4 hours, preferably within 3 hours from the start of heating. When heated for too long, it is not preferable because the particles collapse, the generation of a strange odor, and the elution of components occur.
なお、本発明における発芽玄米米飯の製造は、上記発芽促進処理と炊飯を行うのに必要な温度制御が可能な炊飯装置や調理装置を用いて行うことができる。これによって、1種類の炊飯装置を用いて、浸漬液を交換することなく、そのまま直接炊飯して迅速に発芽玄米の米飯を得ることができる。
なお、特には、玄米浸漬槽、温度計測部、加熱冷却部および温度制御部から構成される発芽玄米製造炊飯装置を用いることによって、その効果がもっとも十分に発揮された発芽玄米米飯を製造することができる。
In addition, manufacture of the germinated brown rice rice in this invention can be performed using the rice cooking apparatus and cooking apparatus in which temperature control required in performing the said germination acceleration | stimulation process and rice cooking is possible. Thereby, using one kind of rice cooking apparatus, it is possible to directly cook rice as it is without changing the immersion liquid, and to quickly obtain germinated brown rice.
In particular, by using a germinated brown rice production rice cooker composed of a brown rice soaking tank, a temperature measuring unit, a heating / cooling unit, and a temperature control unit, producing germinated brown rice whose effects are most fully demonstrated. Can do.
<発芽玄米米飯>
上記工程を経られた発芽玄米米飯は、発芽促進処理の浸漬時間が大幅に短いため、菌数103cfs以下の良好な衛生性を有し、発芽玄米米飯特有の発酵臭がなくて良好な風味を有したものとなる。
<Sprouted brown rice>
The germinated brown rice that has undergone the above process has good hygiene with a bacteria count of 10 3 cfs or less because the soaking time for germination promotion treatment is significantly short, and it is good without the fermentation odor characteristic of germinated brown rice. It has a flavor.
また、上記工程を経られた発芽玄米米飯は、テンシプレッサー高圧縮低圧縮連続測定(H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal Chemistry, 76(6), 855-860, 1999)による米飯表層の硬さが、1.2kgw/cm2以下、好ましくは1.0kgw/cm2以下、の軟らかい米飯物性を有したものとなる。
上記所定範囲の軟らかい米飯物性を示すことで、従来の発芽玄米米飯と異なり、日本人の食味嗜好にもよく適合した発芽玄米米飯となる。
In addition, the germinated brown rice cooked through the above process is continuously measured by H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal. Chemistry, 76 (6), 855-860, 1999) has a soft cooked rice physical hardness of 1.2 kgw / cm 2 or less, preferably 1.0 kgw / cm 2 or less.
By exhibiting the soft rice physical properties within the above-mentioned predetermined range, unlike the conventional germinated brown rice, it becomes a germinated brown rice that is well adapted to Japanese taste preference.
また、上記工程を経られた発芽玄米米飯は、発芽促進処理に用いた浸漬液の交換をしない上に、低温前処理や炊飯における緩やかな昇温等によってGADの反応が促進されるため、機能性成分であるγ−アミノ酪酸(GABA)の含量が高いものとなる。具体的には、乾重あたり15mg/100g以上となる。
なお、発芽玄米中のGABAは、発芽過程でグルタミン酸脱炭酸酵素(GAD)の作用によってグルタミン酸から生成する。GABAは高血圧抑制や脳の血流の調節、肝臓における脂肪蓄積の抑制等、様々な機能性が報告されている(茅原 紘・杉浦友美、食品と開発、36(6)、4-6、2000)。通常の発芽玄米は10-15mg/100gと報告されている(喜瀬光男・水口 彩、FOOD Style 21、8(7)、54-57、2004)。
また、浸漬液の交換をしないため、ビタミンB群やミネラルなどの水溶性成分含量の高いものとなる。
In addition, the germinated brown rice that has undergone the above steps is not replaced with the immersion liquid used for the germination promotion treatment, and the GAD reaction is promoted by a low temperature pretreatment or a mild temperature rise in cooking rice. The content of gamma-aminobutyric acid (GABA), which is a sex component, is high. Specifically, it becomes 15 mg / 100g or more per dry weight.
Note that GABA in germinated brown rice is produced from glutamic acid by the action of glutamate decarboxylase (GAD) during the germination process. GABA has been reported to have various functionalities such as suppression of hypertension, regulation of cerebral blood flow, and suppression of fat accumulation in the liver (Akira Sugawara, Tomomi Sugiura, Food and Development, 36 (6), 4-6, 2000 ). Normal germinated brown rice is reported to be 10-15mg / 100g (Kise Mitsuo / Mizuguchi Aya, FOOD Style 21, 8 (7), 54-57, 2004).
Moreover, since the immersion liquid is not exchanged, the content of water-soluble components such as vitamin B group and mineral is high.
なお、上記発芽促進処理の浸漬液として、前記赤玉葱および/または玉葱、もしくは、その抽出成分を含有するものを用いた場合、得られた発芽玄米米飯の発芽率、GABA含有量はさらに向上したものとなる。さらに、これらに由来するケルセチン等の機能性成分が付与されたものとなる。 In addition, when the above-mentioned soaking liquid for the germination promotion treatment was used, the germination rate and GABA content of the germinated brown rice obtained were further improved when the red onion and / or onion or one containing the extract component was used. It will be a thing. Furthermore, functional components such as quercetin derived therefrom are added.
<飲食品>
上記のようにして得られた発芽玄米米飯は、単独使用あるいは米粉や小麦粉に添加使用することによって、パン、麺、菓子、シート状食品、スープ状食品等に加工することができる。また、得られた発芽玄米米飯は、乾燥後に粉砕した粉末として用いることもできる。なお、発芽玄米米飯と当該乾燥粉末を混合して用いることもできる。
<Food &Drink>
The germinated brown rice rice obtained as described above can be processed into bread, noodles, confectionery, sheet-like food, soup-like food, etc. by using it alone or by adding to rice flour or wheat flour. Moreover, the obtained germinated brown rice can be used as a powder pulverized after drying. In addition, germinating brown rice rice and the dry powder can be mixed and used.
発芽玄米加工食品の場合、GABAなどの機能性成分の有効性及びアミノ酸や少糖類による呈味性向上効果の有効性、米含有加工品の物性の特徴を示すという観点から、米を25重量%以上含有し、当該米の40重量%以上が、前記発芽玄米米飯であることが好適である。
In the case of germinated brown rice processed foods, 25% by weight of rice is used in view of the effectiveness of GABA and other functional ingredients, the effect of improving taste by amino acids and oligosaccharides, and the physical properties of processed rice-containing products. It is preferable that 40% by weight or more of the rice is the germinated brown rice.
以下に本発明の実施形態について説明するが、本発明はこれらの実施例のみに限定されるものではない。 Embodiments of the present invention will be described below, but the present invention is not limited to these examples.
<実施例1> (6時間20分の発芽玄米米飯の一貫迅速製造)
コシヒカリおよびホシユタカの玄米それぞれ20gを洗米し、2時間吸水させた後、−20℃のフリーザー中で緩慢凍結した後、炊飯装置に入れ、水900mlを加え、37℃の温湯中で4時間浸漬した。次いで、図1のモード2に示す加熱条件で140分かけて炊飯した。これらの写真を図2に示す。
<Example 1> (Integrated rapid production of germinated brown rice for 6 hours and 20 minutes)
Wash 20g each of Koshihikari and Hoshiyutaka brown rice, absorb water for 2 hours, slowly freeze in -20 ° C freezer, put in rice cooker, add 900ml water, and soak in warm water at 37 ° C for 4 hours . Next, rice was cooked over 140 minutes under the heating conditions shown in mode 2 of FIG. These photographs are shown in FIG.
その結果、コシヒカリ、ホシユタカともに発芽玄米の米飯が得られた。なお、比較対象として、通常の電気炊飯器(東芝RC300)で1.5倍量の水を加えて直接炊飯したコシヒカリは発芽玄米とならなかった(図3)。
この結果から、従来は、一晩温湯浸漬して発芽玄米を調製し、次いで、洗浄や加熱を施した後に市販され、購入後に改めて電気炊飯器等で炊飯されて得られてきた発芽玄米米飯が、本発明の方法によれば、浸漬開始後液交換することなくさらに短時間で、発芽玄米米飯として食すことが可能になることが示された。
As a result, germinated brown rice was obtained for both Koshihikari and Hoshiyutaka. In addition, as a comparison object, Koshihikari cooked directly by adding 1.5 times the amount of water with a normal electric rice cooker (Toshiba RC300) did not become germinated brown rice (FIG. 3).
From this result, conventionally germinated brown rice was prepared by immersing overnight in warm water, then being marketed after washing and heating, and after being purchased and cooked again in an electric rice cooker etc. According to the method of the present invention, it was shown that it was possible to eat germinated brown rice in a shorter time without changing the solution after the start of immersion.
<比較例1> (超硬質米EM10の緩慢加熱)
超硬質米であるEM10の玄米20gを洗米し、2時間吸水させた後、−20℃のフリーザー中で緩慢凍結した後、実施例1と同じ炊飯装置に入れ、水900mlを加え、30℃、40℃、50℃、60℃、70℃、80℃、90℃のそれぞれの温度で2時間ずつ合計14時間かけて、緩慢に加熱し、最後に100℃で15分間加熱した。
その結果、EM10玄米は、図4に示すように、発芽はしたが、異臭が発生し、成分が浸漬液に溶出して濁るとともに、玄米粒が崩れてしまい食用に適さないものとなってしまった。
<Comparative example 1> (Slow heating of super-hard rice EM10)
After washing 20g of brown rice of EM10, which is super hard rice, and absorbing water for 2 hours, it was slowly frozen in a freezer at -20 ° C, put into the same rice cooker as in Example 1, 900 ml of water added, 30 ° C, It was heated slowly at a temperature of 40 ° C., 50 ° C., 60 ° C., 70 ° C., 80 ° C., and 90 ° C. for 2 hours over a total of 14 hours, and finally at 100 ° C. for 15 minutes.
As a result, EM10 brown rice sprouted as shown in FIG. 4, but an unpleasant odor was generated, the components were dissolved in the immersion liquid and became cloudy, and the brown rice grains collapsed, making them unfit for consumption. It was.
<比較例2> (超硬質米EM10の急速加熱)
超硬質米であるEM10の玄米20gを洗米し、2時間吸水させた後、−20℃のフリーザー中で緩慢凍結した後、実施例1と同じ炊飯装置に入れ、水900mlを加え、炊飯装置で40℃で1時間浸漬した。次いで、40℃から100℃まで10分間で昇温させた後、100℃で15分間加熱した。
その結果、図5に示すように、浸漬液の濁りは少なかったものの、玄米粒はほとんど発芽せず、硬くて食用に不適当であった。
<Comparative example 2> (Rapid heating of super-hard rice EM10)
After washing 20g of brown rice of EM10, which is super hard rice, and absorbing water for 2 hours, slowly frozen in a freezer at -20 ° C, put it in the same rice cooker as in Example 1, add 900 ml of water, Immersion at 40 ° C. for 1 hour. Next, the temperature was raised from 40 ° C. to 100 ° C. over 10 minutes, and then heated at 100 ° C. for 15 minutes.
As a result, as shown in FIG. 5, although the turbidity of the immersion liquid was small, the brown rice grains hardly germinated and were hard and unfit for consumption.
<実施例2> (加熱温度条件を変化させたコシヒカリ発芽玄米米飯の物性)
コシヒカリの玄米200gを洗米し、−20℃のフリーザー中で緩慢凍結した後、炊飯装置に入れ、400mlの水を加え、38℃で4時間浸漬した。次いで、図1に示す3つの条件(モード1〜3)で加熱した。
得られた玄米の物性をタケトモ電機製のテンシプレッサーで測定した。測定方法は岡留らの条件によった(H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal Chemistry, 76(6), 855-860, 1999)。結果を図6に示す。なお、図6において、H1は米飯粒表層の硬さを、H2は米飯粒全体の硬さを、S1は米飯粒表層の粘りを、S2は米飯粒全体の粘りを、Balance H1は米飯粒表層の(粘り/硬さ)を、Balance H2は米飯粒全体の(粘り/硬さ)を、それぞれ表す。
<Example 2> (Physical properties of Koshihikari germinated brown rice with different heating temperature conditions)
After 200 g of Koshihikari brown rice was washed and slowly frozen in a freezer at −20 ° C., it was placed in a rice cooker, 400 ml of water was added, and it was immersed at 38 ° C. for 4 hours. Subsequently, it heated on three conditions (modes 1-3) shown in FIG.
The physical properties of the obtained brown rice were measured with a Takeshimo electric tensipressor. The measurement method was based on the conditions of Okadome et al. (H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal Chemistry, 76 (6), 855-860, 1999). The results are shown in FIG. In FIG. 6, H1 is the hardness of the cooked rice grain surface, H2 is the hardness of the cooked rice grain, S1 is the stickiness of the cooked rice grain surface, S2 is the stickiness of the cooked rice grain, and Balance H1 is the cooked rice grain surface layer. Of (stickiness / hardness) and Balance H2 represents (stickiness / hardness) of the whole cooked rice grain.
その結果、モード2の条件で加熱した発芽玄米米飯(図6のB)がもっとも軟らかく、粘りが強く、食味が優れていた。
なお、モード1(図6のA)及びモード3(図6のC)の場合は、モード2(図6のB)に比べると玄米米飯の発芽が不充分であり、硬くて粘りが弱かった。
As a result, the germinated brown rice cooked under the condition of mode 2 (B in FIG. 6) was the softest, sticky, and excellent in taste.
In addition, in the case of mode 1 (A in FIG. 6) and mode 3 (C in FIG. 6), germination of brown rice was insufficient, compared with mode 2 (B in FIG. 6), and it was hard and weak. .
<実施例3> (吸水処理および冷凍処理を施したコシヒカリ発芽玄米米飯)
コシヒカリ玄米を実施例2のモード2の条件で炊飯するに際し、前処理条件の検討を行った。
前処理条件Aでは、38℃で4.5時間浸漬した。前処理条件Bでは、玄米を洗米も水浸漬もせずに、−20℃で1時間緩慢凍結した後に38℃で4.5時間浸漬した。前処理条件Cでは、洗米して充分吸水させた後に−20℃で1時間緩慢凍結し、38℃で4.5時間浸漬した。
次いで、これらの3種類の前処理を施したコシヒカリ玄米を実施例2のモード2で炊飯した後、テンシプレッサーで米飯物性を測定した。
<Example 3> (Koshihikari germinated brown rice with water absorption and freezing treatment)
When Koshihikari brown rice was cooked under the conditions of mode 2 of Example 2, the pretreatment conditions were examined.
In pretreatment condition A, the film was immersed at 38 ° C. for 4.5 hours. Under pretreatment condition B, brown rice was slowly frozen at −20 ° C. for 1 hour without being washed or immersed in water, and then immersed at 38 ° C. for 4.5 hours. Under pretreatment conditions C, the rice was washed and sufficiently absorbed, and then slowly frozen at -20 ° C for 1 hour and immersed at 38 ° C for 4.5 hours.
Next, after Koshihikari brown rice subjected to these three types of pretreatment was cooked in mode 2 of Example 2, the physical properties of the cooked rice were measured with a tensipressor.
その結果、図7に示すとおり、吸水処理の後に緩慢凍結した場合(前処理条件C)、凍結を行わなかった場合(前処理条件A)に比べて、さらに粘りが強く、食味が良好であった。一方、吸水させずに凍結させた場合(前処理条件B)は、米飯粒が硬くなり、凍結の効果が認められなかった。
GABAの含有量は、前処理条件Aの米飯は8mg/100g(乾重)、前処理条件Bの米飯は11mg/100g(乾重)、前処理条件Cの米飯は15mg/100g(乾重)であった。
これらの結果から、洗米で吸水させたのちに緩慢凍結することによって、発芽が促進され、氷晶による組織破壊が起こることで、米飯物性が改良されるとともに、GABA生成酵素が活発にGABAを生産するということが示された。
As a result, as shown in FIG. 7, it was more sticky and tasted better when it was slowly frozen after water absorption treatment (pretreatment condition C) and when it was not frozen (pretreatment condition A). It was. On the other hand, when it was frozen without water absorption (pretreatment condition B), the rice grains became hard and the effect of freezing was not recognized.
GABA content is 8mg / 100g (dry weight) for pretreated condition A, 11mg / 100g (dry weight) for pretreated condition B, 15mg / 100g (dry weight) for pretreated condition C. Met.
From these results, germination is promoted by slow freezing after water-absorbing in washed rice, and tissue destruction caused by ice crystals improves the rice physical properties and GABA-producing enzyme actively produces GABA. It was shown to do.
<実施例4> (赤玉葱による発芽促進効果)
コシヒカリ、春陽、ホシユタカ、夢十色、ミルキークイーンの各玄米200gを洗米し、−20℃のフリーザー中で緩慢凍結した後、赤玉葱水溶液(pH5.9:赤玉葱凍結乾燥粉末を2重量%含む水溶液)に浸漬し、37℃で2時間保持した。次いで、実施例2のモード2の条件で120分間加熱した。
その結果、このようにして製造した発芽玄米米飯は、発芽率が約70%(コシヒカリ)から90%(ホシユタカ)と高く、15mg/100g(乾重)以上のγ―アミノ酪酸および12mg/100g(乾重)以上のケルセチンを含んでおり、米飯は良好な食味となった。
この結果から、赤玉葱を含む水溶液を用いることによって、玄米の発芽率、米飯の機能性成分を向上できることが示された。
また、浸漬開始後4時間で発芽玄米米飯として食すことが可能になることが示された。
<Example 4> (Sprouting promotion effect by red onion)
Wash 200g brown rice of Koshihikari, Chunyang, Hoshiyutaka, Yumeyoku and Milky Queen, slowly freeze them in a freezer at -20 ° C, and then add 2% by weight of red onion aqueous solution (pH5.9) And was kept at 37 ° C. for 2 hours. Subsequently, it heated for 120 minutes on the conditions of the mode 2 of Example 2. FIG.
As a result, the germinated brown rice cooked in this way has a high germination rate of about 70% (Koshihikari) to 90% (Hoshiyutaka), 15mg / 100g (dry weight) or more of γ-aminobutyric acid and 12mg / 100g ( Dry weight) More quercetin was included, and the cooked rice had a good taste.
From this result, it was shown that the germination rate of brown rice and the functional components of cooked rice can be improved by using an aqueous solution containing red onion.
It was also shown that it was possible to eat germinated brown rice 4 hours after the start of soaking.
<実施例5> (緩慢凍結処理による発芽促進効果)
平成20年新潟県産夢十色の玄米を洗米した。その後、前処理条件Aでは、15℃で一晩浸漬した後に、37℃の温湯に4時間浸漬した。前処理条件B〜Eでは、5℃で一晩浸漬した後に、−20℃のフリーザーに入れて、30分(条件B)、60分(条件C)、90分(条件D)、120分(条件E)それぞれ緩慢凍結する低温処理を行った後に、37℃の温湯に4時間浸漬した。
次いで、これらの発芽玄米試料を温度コントローラー付き加熱炊飯装置を用いて、前記モード2の条件で炊飯した。炊飯後の発芽率を図8に示す。
その結果、図8から明らかなように、30分間凍結処理した試料が最も発芽が促進され、以下、60分間、90分間、120分間の順であった。
なお、低温処理や緩慢凍結を行わない場合(前処理条件A)は、温湯浸漬から4時間後でも発芽は見られなかった。
<Example 5> (Sprouting promotion effect by slow freezing treatment)
In 2008, we washed dreamed brown rice from Niigata Prefecture. Thereafter, under pretreatment condition A, the film was immersed overnight at 15 ° C. and then immersed in warm water at 37 ° C. for 4 hours. In pretreatment conditions B to E, after being immersed at 5 ° C. overnight, it was placed in a freezer at −20 ° C., and 30 minutes (condition B), 60 minutes (condition C), 90 minutes (condition D), 120 minutes ( Condition E) After performing a low-temperature treatment of slowly freezing, each was immersed in hot water at 37 ° C. for 4 hours.
Next, these germinated brown rice samples were cooked under the conditions of Mode 2 using a heating rice cooker with a temperature controller. The germination rate after cooking rice is shown in FIG.
As a result, as is apparent from FIG. 8, germination was most promoted in the sample that had been subjected to the 30 minute freezing treatment, and in the order of 60 minutes, 90 minutes, and 120 minutes.
In addition, when not performing low temperature processing or slow freezing (pretreatment condition A), germination was not seen even 4 hours after the hot water immersion.
<実施例6> (緩慢凍結による発芽玄米物性の改善)
平成20年九州大学産EM10の玄米を洗米した。その後、前処理条件Aでは、5℃で一晩浸漬する低温処理を行った後に、37℃の温湯に4時間浸漬した。前処理条件B〜Dでは、5℃で一晩浸漬した後に、−20℃のフリーザーに入れて、30分(条件B)、60分(条件C)、90分(条件D)それぞれ緩慢凍結する低温処理を行った後に、37℃の温湯に4時間浸漬した。
次いで、これらの発芽玄米試料を温度コントローラー付き加熱炊飯装置を用いて前記モード2の条件で炊飯した。そして、それぞれの米飯の物性を、テンシプレッサー多重積算バイト法(H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal Chemistry, 76(6), 855-860, 1999)を用いて測定した。測定結果を図9に示す。
その結果、図9から明らかなように、緩慢凍結を施すことで、発芽玄米米飯の硬さが、1kgw/cm2以下となり、米飯物性が著しく改良されることが示された。
<Example 6> (Improvement of germinated brown rice physical properties by slow freezing)
In 2008, brown rice from Kyushu University EM10 was washed. Thereafter, under pretreatment condition A, after low-temperature treatment was performed at 5 ° C. overnight, the substrate was immersed in hot water at 37 ° C. for 4 hours. In pretreatment conditions B to D, after being immersed at 5 ° C. overnight, put in a freezer at −20 ° C. and slowly freeze for 30 minutes (condition B), 60 minutes (condition C), and 90 minutes (condition D). After performing the low temperature treatment, it was immersed in 37 ° C. hot water for 4 hours.
Subsequently, these germinated brown rice samples were cooked under the condition of Mode 2 using a heating rice cooker with a temperature controller. Then, the physical properties of each cooked rice can be expressed by the tensipressor multiple accumulation byte method (H. Okadome, H. Toyoshima, K. Ohtsubo, Multiple measurements of physical properties of individual cooked rice grains with a single apparatus, Cereal Chemistry, 76 (6) , 855-860, 1999). The measurement results are shown in FIG.
As a result, as is apparent from FIG. 9, it was shown that the hardness of the germinated brown rice became 1 kgw / cm 2 or less and the physical properties of the rice were remarkably improved by slow freezing.
<実施例7> (液体窒素による急速凍結との比較)
実施例3と同様に、コシヒカリ玄米を実施例2のモード2の条件で炊飯するに際し、前処理条件の検討を行った。前処理条件Aでは、38℃で4.5時間浸漬した。前処理条件Bでは、液体窒素によって瞬間的に凍結した後に38℃で4.5時間浸漬した。前処理条件Cでは、洗米して充分吸水させた後に−20℃で1時間緩慢凍結し、38℃で4.5時間浸漬した。
次いで、これらの3種類の前処理を施したコシヒカリ玄米を実施例2のモード2で炊飯した後、テンシプレッサーで米飯物性を測定した。
その結果、吸水処理の後に緩慢凍結した場合(前処理条件C)、凍結を行わなかった場合(前処理条件A)に比べて、粘りが強く、食味が良好であった。一方、液体窒素によって瞬間凍結した場合(前処理条件B)は、緩慢凍結した場合(前処理条件C)に比べて、凍結による米飯物性改良効果が認められなかった。
GABAの含有量は、前処理条件Aの米飯は8mg/100g(乾重)、前処理条件Bの米飯は12mg/100g(乾重)、前処理条件Cの米飯は15mg/100g(乾重)であった。
これらの結果から、洗米で吸水させたのちに緩慢凍結することによって、発芽が促進され、氷晶による組織破壊が起こることで、米飯物性が改良されるとともに、GABA生成酵素が活発にGABAを生産するということが示された。
<Example 7> (Comparison with quick freezing with liquid nitrogen)
Similarly to Example 3, when Koshihikari brown rice was cooked under the conditions of Mode 2 of Example 2, the pretreatment conditions were examined. In pretreatment condition A, the film was immersed at 38 ° C. for 4.5 hours. In the pretreatment condition B, after being frozen instantaneously with liquid nitrogen, it was immersed at 38 ° C. for 4.5 hours. Under pretreatment conditions C, the rice was washed and sufficiently absorbed, and then slowly frozen at -20 ° C for 1 hour and immersed at 38 ° C for 4.5 hours.
Next, after Koshihikari brown rice subjected to these three types of pretreatment was cooked in mode 2 of Example 2, the physical properties of the cooked rice were measured with a tensipressor.
As a result, when it was slowly frozen after the water absorption treatment (pretreatment condition C), it was more sticky and tasted better than when it was not frozen (pretreatment condition A). On the other hand, in the case of instant freezing with liquid nitrogen (pretreatment condition B), compared with the case of slow freezing (pretreatment condition C), the effect of improving rice physical properties by freezing was not recognized.
GABA content is 8mg / 100g (dry weight) for pretreatment condition A, 12mg / 100g (dry weight) for pretreatment condition B, 15mg / 100g (dry weight) for pretreatment condition C. Met.
From these results, germination is promoted by slow freezing after water-absorption in washed rice, and tissue destruction caused by ice crystals improves the rice physical properties and GABA-producing enzyme actively produces GABA. It was shown to do.
<実施例8> (発芽玄米米飯の粉末を用いた蒸しパン)
まず、実施例6のDの条件と同様にして、九州大学産EM10の発芽玄米米飯を調製した。この発芽玄米米飯を凍結乾燥したのち、UDY社製サイクロンミルで粉砕して発芽玄米米飯の乾燥粉末を得た。
次いで、卵1個(水分込みで約60g)に、当該‘発芽玄米米飯の乾燥粉末’30g、砂糖10g、ベーキングパウダー2g、スキムミルク3gを加えて生地を調製し、ティファール製電気蒸し器(ウルトラコンパクト)を用いて25分間蒸し、蒸しパンを製造した。
なお、比較例として、市販の米粉(波里製強力米粉)、もしくは、小麦粉(日清製粉製カメリヤ)により、同じ処方で蒸しパンを製造した。
これらの写真を図10に示す。
<Example 8> (Steamed bread using germinated brown rice rice powder)
First, germinated brown rice cooked with EM10 from Kyushu University was prepared in the same manner as in D of Example 6. This germinated brown rice was freeze-dried and then pulverized with a cyclone mill manufactured by UDY to obtain a dried powder of germinated brown rice.
Next, the dough is prepared by adding 30g of 'dried powder of germinated brown rice', 10g of sugar, 2g of baking powder and 3g of skim milk to one egg (about 60g with water), and Tefal's electric steamer (ultra compact) Steamed for 25 minutes to produce steamed bread.
In addition, as a comparative example, steamed bread was manufactured with the same prescription using commercially available rice flour (Hamari strong rice flour) or wheat flour (Nisshin Flour Camellia).
These photographs are shown in FIG.
また、上記得られた蒸しパンを凍結乾燥し、サイクロンミルで粉砕した粉末中のGABA含有量を高速液体クロマトグラフ法によって測定した。
その結果、小麦粉の場合は0.5mg/100gであり、市販米粉混合の場合は0.7mg/100gであり、本発明例の発芽玄米の場合は12.2mg/100gであり、比較例に比べて著しく多いGABAを含んでいた。
また、6名の専門試食者による官能検査の結果、比較例の蒸しパンに比べて、本発明例の蒸しパンは、甘味とうま味が強い結果となった。
Moreover, the GABA content in the powder obtained by freeze-drying the steamed bread obtained above and pulverizing with a cyclone mill was measured by high performance liquid chromatography.
As a result, it is 0.5 mg / 100 g in the case of wheat flour, 0.7 mg / 100 g in the case of commercially available rice flour mixture, and 12.2 mg / 100 g in the case of germinated brown rice of the present invention example, which is significantly larger than the comparative example Contains GABA.
Moreover, as a result of the sensory test by six professional tasters, the steamed bread of the example of the present invention was stronger in sweetness and umami than the steamed bread of the comparative example.
<実施例9> (発芽玄米米飯を用いた米粉含有麺)
まず、実施例6のDの条件と同様にして、発芽玄米米飯を調製した。この‘発芽玄米米飯’100gと、市販小麦粉(日清製粉製カメリヤ)100gとを混合し、食塩6g、ぬるま湯108gを加え、テスコム製スティックブレンダーを用いて生地を調製した。この生地を冷蔵庫に一晩静置して硬化させた後、インペリア製パスタマシンを用いて2mmの米粉含有麺を製造した。
製造したこの麺は、茹で上がりが早く、うま味の強い麺であった。
<Example 9> (Rice-containing noodles using germinated brown rice)
First, germinated brown rice was prepared in the same manner as in Example 6D. 100 g of this “germinated brown rice” and 100 g of commercially available wheat flour (Nisshin Flour Camellia) were mixed, 6 g of salt and 108 g of lukewarm water were added, and a dough was prepared using a Tescom stick blender. The dough was allowed to stand overnight in a refrigerator and cured, and then 2 mm rice flour-containing noodles were produced using an imperia pasta machine.
The produced noodles were boiled quickly and had a strong umami taste.
<実施例10> (発芽玄米米飯を用いたパン)
まず、実施例6のDの条件と同様にして、発芽玄米米飯を調製した。この‘発芽玄米米飯’360gに、市販の小麦粉(日清製粉製カメリヤ)300g、食塩1.5g、脱脂ミルク8.5g、無塩バター15g、砂糖17g、パン酵母3gを加え、パナソニック製家庭用製パン器(SD-BH101)を用いて食パンを製造した。
<Example 10> (Bread using germinated brown rice)
First, germinated brown rice was prepared in the same manner as in Example 6D. Add 360g of commercially available flour (Nisshin Flour Camellia), 1.5g of salt, 8.5g of nonfat milk, 15g of unsalted butter, 17g of sugar and 3g of bread yeast to 360g of this 'germinated brown rice rice'. The bread (SD-BH101) was used to produce bread.
製造した食パンについて、植物種子置換法によって比容積を測定した。その結果、パンの比容積は4.1であった。
また、6名で試食した結果、硬さや弾力性などの物理性においては市販の食パンと同等であり、外観と味については、市販の食パンを上まわる評価であった。
The specific volume of the produced bread was measured by the plant seed replacement method. As a result, the specific volume of the bread was 4.1.
In addition, as a result of tasting by six people, the physical properties such as hardness and elasticity were the same as those of commercially available breads, and the appearance and taste were evaluated to be superior to those of commercially available breads.
本発明は、発芽玄米米飯の迅速な製造を可能とし、また、発芽玄米米飯の風味、米飯物性、衛生面、機能性成分の含有率を向上させることができる。これにより、発芽玄米米飯やそれを用いた米加工食品の消費の拡大に貢献することが期待される。 The present invention enables rapid production of germinated brown rice, and can improve the flavor, physical properties, hygiene, and functional component content of germinated brown rice. This is expected to contribute to the expansion of consumption of germinated brown rice and processed rice foods using it.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010001652A JP5550103B2 (en) | 2010-01-07 | 2010-01-07 | Germinated brown rice and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010001652A JP5550103B2 (en) | 2010-01-07 | 2010-01-07 | Germinated brown rice and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011139659A JP2011139659A (en) | 2011-07-21 |
| JP5550103B2 true JP5550103B2 (en) | 2014-07-16 |
Family
ID=44455984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010001652A Expired - Fee Related JP5550103B2 (en) | 2010-01-07 | 2010-01-07 | Germinated brown rice and its production method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5550103B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118985820A (en) * | 2024-08-21 | 2024-11-22 | 江苏大学 | GABA-enriched brown rice and GABA enrichment method based on multi-cycle wet heat treatment of brown rice |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3585761B2 (en) * | 1999-02-02 | 2004-11-04 | 独立行政法人食品総合研究所 | Sprouted brown rice with excellent safety and cookability, and its production method |
| JP2005192489A (en) * | 2004-01-08 | 2005-07-21 | Satoru Imura | Method for producing sprouted brown rice and cooked sprouted brown rice |
| JP5641467B2 (en) * | 2009-07-24 | 2014-12-17 | 国立大学法人 新潟大学 | Germinated seed and method for producing the same |
-
2010
- 2010-01-07 JP JP2010001652A patent/JP5550103B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011139659A (en) | 2011-07-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102049591B1 (en) | Method for Manufacturing Corn Bread | |
| CN103445090B (en) | A kind of production method and product of rice product rich in γ-aminobutyric acid | |
| US20040105921A1 (en) | Method for preparing germinated brown rice having improved texture and cookability without microbial contamination and a germinated brown rice obtained therefrom | |
| JP2004033139A (en) | Fried powder | |
| JP2013017482A (en) | Rice and rice flour which have flavor like soybean flour | |
| JP4868336B2 (en) | Functional rice flour, method for producing the same, and food and drink using the rice flour | |
| KR20160078548A (en) | Preparing Method for Pudding of Platycondon And Pudding of Platycondon Prepared Thereby | |
| KR101626707B1 (en) | Barley syrup manufacture method | |
| CN114711358A (en) | Preparation method of black waxy corn beverage | |
| CN104719774A (en) | A kind of preparation method of germinated brown rice instant health-care rice porridge | |
| JP5439672B2 (en) | Instant dried persimmon containing ornithine | |
| JP5550103B2 (en) | Germinated brown rice and its production method | |
| WO2002071873A1 (en) | Functional cereals | |
| CN104171979A (en) | Application of method for producing gamma-aminobutyric acid rice products by utilizing germinated brown rice | |
| RU2296473C1 (en) | Method for preparing of food product from bean | |
| KR101673400B1 (en) | Preparation Method of Kimchi Containing Extract of Phragmitis Rhizoma and Kimchi Manfactued Thereby | |
| KR20160069772A (en) | Sikhye Using Purple Sweet Potato and a Production Method thereof | |
| WO2005065465A1 (en) | Functional component-enriched barley malt rootlets and process for producing the same | |
| CN104938582B (en) | A kind of agaric cookies and preparation method thereof | |
| KR20110138127A (en) | Manufacturing method of rice cake using figs and rice cake prepared thereby | |
| JP4662276B2 (en) | Shochu, fermented products, food and drink, feed and methods for producing them | |
| CN106819024A (en) | A kind of spirulina chinese cymbidium cake and preparation method thereof | |
| KR101832248B1 (en) | Yoogwa with sweet potato chrysanthemum and its production method | |
| KR102488360B1 (en) | Manufacturing method of dried sweet persimmon food | |
| JP4900705B2 (en) | Shochu, its production method and concentrate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20121218 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20131126 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20131203 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140129 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140219 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140408 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140430 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140515 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5550103 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |