JP5565616B2 - Cooked rice suitable for preservation, cooked rice production method, and cooked rice processing improver used therefor - Google Patents
Cooked rice suitable for preservation, cooked rice production method, and cooked rice processing improver used therefor Download PDFInfo
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- 235000007164 Oryza sativa Nutrition 0.000 title claims description 204
- 235000009566 rice Nutrition 0.000 title claims description 204
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- Cereal-Derived Products (AREA)
Description
本発明は、保存時(特にチルド保存時)に食感の変化が起りやすい米飯に対して、その変化を抑制する技術に関する。さらに詳細には、保存時の食感の変化を抑制するために、レシチンとナトリウム塩を含有させた米飯と、保存時の食感の変化を抑制した米飯の製造方法と、保存時に米飯の澱粉の老化を抑制することのできる米飯加工改良剤と、に関する。
なお、ここで「保存時」とは、厳密な意味での保存時だけでなく、製造してから消費者の手に渡るまでの時間であり、流通段階や店頭に置かれている時間を含めた概念である。
The present invention relates to a technique for suppressing the change of cooked rice that tends to change in texture during storage (particularly during chilled storage). More specifically, cooked rice containing lecithin and sodium salt to suppress changes in texture during storage, a method for producing cooked rice that suppresses changes in texture during storage, and starch of cooked rice during storage The present invention relates to a rice processing improver capable of suppressing aging of rice.
Here, “at the time of storage” means not only the time of storage in a strict sense but also the time from manufacturing to the hands of consumers, including the time in the distribution stage and storefront. Concept.
近年、夫婦共働き等、家事に時間をかけない傾向にある社会的背景の下、スーパーマーケットやコンビニエンスストア等で販売される弁当や惣菜、寿司等を購入して持ち帰って食する、いわゆる「中食」と呼ばれる食習慣が普及してきている。
このコンビニエンスストア等で販売される中食において、消費期限の切れた中食(例えば、弁当)を大量に廃棄することが問題となっており、大手コンビニチェーンの取組みを皮切りに、従来のものより消費期限の長い、低温弁当の販売に着手する流れが出来つつある。
即ち、従来のように20℃前後で弁当を保存することに代えて、弁当をより低温で保存する、特に10℃以下のチルド領域で保存(チルド保存)することにより、消費期限をおよそ3〜4日延長することが可能になり、消費期限が延長された分、弁当の廃棄率の低下が期待されている。
ここで、米飯を一定期間保存すると、米飯の澱粉が老化してしまい、硬く、ぼそぼそとした食感になることが知られているが、上記低温弁当化により、この「老化」の問題は、ますます加速されるものと思われる。米飯の澱粉の老化の程度は、より低温の方が大きいからである。
In recent years, so-called “meal” where you can buy lunch boxes, prepared dishes, sushi, etc. that are sold at supermarkets and convenience stores, etc. Eating habits called are becoming popular.
In the prepared meals sold at convenience stores, etc., it has become a problem to dispose of a large amount of expired meals (for example, lunch boxes), starting with the efforts of major convenience store chains. There is a trend to start selling low-priced lunch boxes with long expiration dates.
That is, instead of storing the bento at around 20 ° C. as in the past, the bento is stored at a lower temperature, particularly in a chilled region at 10 ° C. or less (chilled storage), so that the expiration date is approximately 3 to 3. It is possible to extend it for 4 days, and as the expiration date is extended, it is expected that the rate of box lunch disposal will decrease.
Here, it is known that when cooked rice is stored for a certain period of time, the starch of the cooked rice will age, resulting in a hard and loose texture, but due to the low temperature lunch, the problem of this aging is It seems to be increasingly accelerated. This is because the degree of aging of rice starch is greater at lower temperatures.
尚、米飯の澱粉の老化は、米飯を長期間保存することにより、炊飯工程でα化した澱粉から水が遊離又は局在化し、もとの生澱粉に近い規則的な結晶配列(β澱粉)に戻ろうとする状態である。 In addition, the aging of the starch of cooked rice is that the cooked rice is stored for a long period of time, so that water is released or localized from the starch that has been gelatinized in the cooking process, and a regular crystal arrangement close to the original raw starch (β starch) It is in a state of trying to return to.
老化した米飯は、電子レンジ等で再加熱することによって、元のふっくらとした米飯に近い食感に戻ることが知られているが、寿司のような生鮮食材を使用したものは、再加熱することは困難である。従って、長時間低温温度帯に置かれた寿司飯は、老化に伴う食感の低下が避けられない状況にある。 Aged rice is known to return to a texture close to the original plump rice by reheating it with a microwave oven, etc., but those using fresh ingredients such as sushi are reheated. It is difficult. Therefore, sushi rice placed in a low-temperature temperature zone for a long time is in a situation in which a decrease in texture associated with aging cannot be avoided.
米飯の老化を抑制する方法が従来からいくつか提案されている。
例えば、トレハロースのような保水性の高い糖類を使用して炊飯することにより、経時的な米飯の老化を抑制する方法や(特許文献1参照)、酵素(アミラーゼとパパイン)や乳化剤(ジグリセリン脂肪酸エステル)を使用して、同様に米飯の老化を抑制する方法が提示されている(特許文献2、特許文献3参照)。
しかしながら、いずれの方法も一定の老化抑制効果は認められるものの、十分な老化抑制は達成できないというのが現状である。
このような背景の下、一定時間保存された米飯、特に低温下で保存された米飯の澱粉の老化を抑制する方法が強く望まれていた。
Several methods for suppressing the aging of cooked rice have been proposed.
For example, a method of suppressing aging of cooked rice over time by cooking using a sugar having high water retention such as trehalose (see Patent Document 1), an enzyme (amylase and papain), an emulsifier (diglycerin fatty acid) A method for suppressing the aging of cooked rice using an ester is also proposed (see Patent Document 2 and Patent Document 3).
However, although both methods have a certain aging inhibitory effect, the present situation is that sufficient aging inhibition cannot be achieved.
Under such circumstances, there has been a strong demand for a method for suppressing the aging of cooked rice that has been stored for a certain period of time, particularly starch of cooked rice that has been stored at a low temperature.
本発明は上記の問題に鑑みてなされたものであり、その第一の目的は、常温以下の温度帯、特に低温下にて一定時間保存された米飯の澱粉の老化を抑制する米飯を提供することにある。
本発明の第二の目的は、常温以下の温度帯、特に低温下にて一定時間保存された米飯の澱粉の老化を抑制する米飯の製造方法を提供することにある。
本発明の第三の目的は、常温以下の温度帯、特に低温下にて一定時間保存するときに、米飯の澱粉の老化を抑制することのできる米飯加工改良剤を提供することである。
The present invention has been made in view of the above problems, and a first object of the invention is to provide cooked rice that suppresses aging of starch of cooked rice that has been stored for a certain period of time under a temperature range of room temperature or lower, particularly at a low temperature. There is.
The second object of the present invention is to provide a method for producing cooked rice that suppresses the aging of the starch of cooked rice that has been stored for a certain period of time at a temperature range below room temperature, particularly at a low temperature.
The third object of the present invention is to provide a cooked rice processing improver that can suppress the aging of the starch of cooked rice when stored for a certain period of time in a temperature range of room temperature or lower, particularly at a low temperature.
前述したように、乳化剤には、澱粉の老化抑制に効果があるものもあることは知られており、この効果は、澱粉鎖と乳化剤の炭化水素鎖の疎水結合、あるいは澱粉鎖を取り込んだ乳化剤のミセル形成に起因すると思われる。このような乳化剤−澱粉複合体が形成されれば、老化に伴う澱粉鎖の集合が妨げられ、米飯の澱粉の老化が抑制されるものと思われる。 As described above, it is known that some emulsifiers are effective in inhibiting starch aging, and this effect is due to the hydrophobic bond between the starch chain and the hydrocarbon chain of the emulsifier, or the emulsifier incorporating the starch chain. This is probably due to micelle formation. If such an emulsifier-starch complex is formed, aggregation of starch chains accompanying aging is hindered, and it is considered that aging of the starch of cooked rice is suppressed.
しかしながら、乳化剤は、特有のエグ味、異味、香り、色調変化等の影響をもたらすため、特に米飯のような風味の淡白な食品に関しては、その使用量に限界があり、それに伴い、老化抑制効果にも限界があった。 However, since emulsifiers have effects such as peculiar taste, nasty taste, aroma, and color change, there is a limit to the amount of use, especially for light-flavored foods such as cooked rice. There was also a limit.
そこで、本発明者らは、十分な老化抑制効果があり、尚且つ、米飯のような淡白な風味の食品にも使用しても悪影響を及ぼさない素材を鋭意検討した。
その結果、本発明者らは、乳化剤の一種であるレシチンと、ナトリウム塩とを組み合わせて用いて炊飯することにより、老化抑制効果が極めて高い米飯が得られ、しかも米飯の風味にも悪影響を及ぼさないことを見出し、この知見に基づいて本発明を完成するに至った。
Therefore, the present inventors have intensively studied a material that has a sufficient anti-aging effect and that does not have an adverse effect even when used for a light-flavored food such as cooked rice.
As a result, the present inventors can cook rice using a combination of lecithin, which is a kind of emulsifier, and a sodium salt, to obtain cooked rice with an extremely high antiaging effect, and also adversely affect the flavor of cooked rice. Based on this finding, the present inventors have completed the present invention.
尚、炊飯時にナトリウム塩を添加すると、ナトリウムが米の表面の糊化を促進し、この糊化層が米内部への水の供給を阻害し、炊飯時における米中心部の澱粉の膨潤を阻害することが知られている(「炊飯溶液中のカルシウムとナトリウムが飯の性状に及ぼす影響(第1報)飯の物性と食味に及ぼす影響:出典 日本家政学会誌,Vol.57, No.10, 669〜675(2006)」など参照)。また、炊飯時にナトリウム塩を添加すると、炊飯時に米飯中の自由水がナトリウムイオンと結合するために使われ、澱粉を糊化させるための自由水が減少した結果、澱粉が十分に糊化しないことが知られている(「米飯の物性解析と官能検査−老化を中心として−(第2報):出典 飯島記念食品科学振興財団年報(1998)」など参照)。
つまり、ナトリウム塩は、炊飯米中心部のα化を阻害するため、老化を促進する方向に働くものと考えられていた。
In addition, when sodium salt is added during cooking, sodium promotes gelatinization on the surface of the rice, and this gelatinization layer inhibits the supply of water to the inside of the rice and inhibits the swelling of starch in the center of rice during cooking. ("Effects of calcium and sodium in rice cooking solution on properties of rice (Part 1) Effects on physical properties and taste of rice: Source: Journal of Japanese Society of Home Economics, Vol.57, No.10, 669-675 (2006) "). In addition, when sodium salt is added during cooking, the free water in the cooked rice is used to bind sodium ions during cooking, and as a result of the reduction of free water to gelatinize the starch, the starch does not sufficiently gelatinize. (Refer to "Iijima Memorial Food Science Foundation Annual Report (1998)").
In other words, the sodium salt was thought to work in the direction of promoting aging because it inhibits the alpha conversion of the center of cooked rice.
ところが、驚くべきことに、ナトリウム塩単独では老化抑制効果はない(むしろ老化を促進すると考えられていた)ものの、レシチンと組み合わせることによって高い老化抑制効果を発揮することを見出したものである。このメカニズムは定かではないが、レシチンが澱粉と複合体を形成する際にナトリウム塩が相乗的に働いて、澱粉の老化をより高度に抑制するものと考えられる。 Surprisingly, however, the sodium salt alone has no anti-aging effect (although it was thought to promote aging), but it has been found to exhibit a high anti-aging effect when combined with lecithin. Although this mechanism is not clear, it is considered that the sodium salt works synergistically when lecithin forms a complex with starch and suppresses aging of starch to a higher degree.
すなわち、本発明は以下のものである。
(1):生米重量に対し、レシチンを0.04〜0.4質量%含有し、且つ、ナトリウム塩を0.3〜5.0質量%含有することを特徴とする白飯又は寿司飯。
(2):前記レシチンが、HLB9〜14の範囲のものである、前記(1)に記載の白飯又は寿司飯。
(3):前記白飯又は寿司飯が、製造後に、20℃以下の温度帯で6時間以上保存されたものである、前記(1)〜(2)のいずれかに記載の白飯又は寿司飯。
(4):生米に、レシチン又はレシチン含有食品と、ナトリウム塩又はナトリウム塩含有食品とを添加した後に炊飯すること、並びに、上記ナトリウム塩が塩化ナトリウム、クエン酸ナトリウム、リンゴ酸ナトリウム、及び酢酸ナトリウムからなる群より選ばれた1種以上であることを特徴とする、レシチンとナトリウム塩とを含有してなる白飯又は寿司飯の製造方法。
(5):生米重量に対し、レシチンの割合が0.04〜0.4質量%、ナトリウム塩の割合が0.3〜5.0質量%となるように、生米に、レシチン又はレシチン含有食品と、ナトリウム塩又はナトリウム塩含有食品とを添加した後に炊飯することを特徴とする、レシチンとナトリウム塩とを含有してなる白飯又は寿司飯の製造方法。
(6):レシチンとナトリウム塩とを含有してなり、上記ナトリウム塩が塩化ナトリウム、クエン酸ナトリウム、リンゴ酸ナトリウム、及び酢酸ナトリウムからなる群より選ばれた1種以上であることを特徴とする、低温での流通・保存時に白飯又は寿司飯の澱粉の老化を抑制することのできる白飯又は寿司飯用米飯加工改良剤。
(7):前記(6)記載の米飯加工改良剤を、生米重量に対し、レシチンの割合が0.04〜0.4質量%、ナトリウム塩の割合が0.3〜5.0質量%となるように添加した後に炊飯することを特徴とする、前記(4)〜(5)のいずれかに記載の白飯又は寿司飯の製造方法。
That is, the present invention is as follows.
(1): White rice or sushi rice containing 0.04 to 0.4 mass% of lecithin and 0.3 to 5.0 mass% of sodium salt based on the weight of raw rice.
(2): White rice or sushi rice according to (1), wherein the lecithin is in the range of HLB 9-14.
(3): The white rice or sushi rice according to any one of (1) to (2), wherein the white rice or sushi rice is stored for 6 hours or more in a temperature zone of 20 ° C. or less after production.
(4): Cooking rice after adding lecithin or lecithin-containing food and sodium salt or sodium salt-containing food to raw rice, and the sodium salt is sodium chloride, sodium citrate, sodium malate, and acetic acid A method for producing white rice or sushi rice comprising lecithin and a sodium salt, wherein the method comprises at least one selected from the group consisting of sodium .
(5): Lecithin or lecithin is added to raw rice so that the proportion of lecithin is 0.04 to 0.4 mass% and the proportion of sodium salt is 0.3 to 5.0 mass% with respect to the weight of raw rice. A method for producing white rice or sushi rice comprising lecithin and a sodium salt , wherein the rice is cooked after adding the containing food and the sodium salt or the sodium salt-containing food.
(6): Ri greens contain lecithin and sodium salt, and wherein the sodium salt is sodium chloride, sodium citrate, is sodium malate, and at least one member selected from the group consisting of sodium acetate A rice processing improver for white rice or sushi rice that can suppress aging of starch of white rice or sushi rice during distribution and storage at low temperatures.
(7): The cooked rice processing improver described in (6) above is 0.04 to 0.4% by mass of lecithin and 0.3 to 5.0% by mass of sodium salt based on the weight of raw rice. The method for producing white rice or sushi rice according to any one of the above (4) to (5) , wherein the rice is cooked after being added so as to become.
本発明によると、常温下、特に低温下に一定時間保存された澱粉の老化に伴う食感の変化が起り易い米飯に関して、澱粉の老化に伴う食感の変化を抑制した米飯を提供することが出来る。即ち、常温下、特に低温下に一定時間保存された澱粉の老化に伴う食感の変化が起り易い米飯に関して、エグ味、異味、香り、色調変化を与えずに、その食感の変化を抑制した米飯を提供することが出来る。
また、そのような澱粉の老化に伴う食感の変化を抑制した米飯の製造方法を提供することが出来る。
さらには、そのような澱粉の老化に伴う食感の変化を抑制することのできる米飯加工改良剤を提供することが出来る。
これらにより、寿司飯等の米飯の長期保管が可能となり、ひいては賞味期限の延長による弁当の廃棄率の低下をもたらすことが出来る。
According to the present invention, with respect to cooked rice that is susceptible to changes in texture associated with aging of starch stored at room temperature, particularly at low temperatures for a certain period of time, it is possible to provide cooked rice that suppresses changes in texture associated with aging of starch. I can do it. In other words, for rice that is susceptible to changes in texture due to aging of starch stored at room temperature, especially at low temperatures for a certain period of time, it suppresses changes in texture without causing any changes in taste, taste, aroma, or color. Cooked rice can be provided.
Moreover, the manufacturing method of the cooked rice which suppressed the change of the food texture accompanying aging of such starch can be provided.
Furthermore, the cooked rice processing improvement agent which can suppress the change of the food texture accompanying aging of such starch can be provided.
As a result, cooked rice such as sushi rice can be stored for a long period of time, and as a result, the box lunch disposal rate can be reduced by extending the shelf life.
本発明における米飯とは、炊飯米又はその加工品のことを指し、炊飯米の加工品としては、例えば、寿司飯やおむすび用の塩味調味炊飯米、味付きご飯などが該当する。本発明は、風味の淡白な炊飯米、寿司飯のような米飯に好適である。ここで言う炊飯米とは、米に水を加え、炊飯加工を施したものを言い、寿司飯とは、上記炊飯米に、食酢、塩、糖類等を加えて調味されたもの、例えば調味酢を加えて調味されたものを言う。 The cooked rice in the present invention refers to cooked rice or processed products thereof, and examples of the cooked rice products include sushi rice, salted seasoned cooked rice for rice balls, and seasoned rice. The present invention is suitable for cooked rice with light flavor and sushi rice. Cooked rice as used herein refers to rice that has been added water and cooked, and sushi rice is prepared by adding vinegar, salt, sugar, etc. to the above cooked rice, such as seasoned vinegar. Add the seasoning.
本発明における米飯の商品形態としては特に限定はされないが、製造後に25℃以下、特に20℃以下の温度帯で、6時間以上経過して流通・販売されるコンビニエンスストア、スーパーマーケット、およびテイクアウト惣菜店等で販売される弁当、寿司等が主に該当する。即ち、米飯としては、製造後に、20℃以下の温度帯で6時間以上保存された、とりわけ10℃以下のチルド領域で6時間以上保存(チルド保存)されたものに好適である。
特に、しょうゆや味噌等を使用していない風味の淡白な白飯や寿司飯に好適である。何故ならば、しょうゆや味噌等を使用している米飯(炊き込み御飯等)は、濃い味付けの場合が多く、そのような米飯には従来からある異味のある老化抑制素材をある程度大量に使用しても味に影響が出にくい。一方、風味の淡白な白飯や寿司飯は従来の老化抑制素材を用い難いため、本発明の素材を使用する必要性が高いのである。また、寿司飯のような再加熱の出来ない米飯は、老化抑制の必要性が大きいため本発明が特に好適である。
The product form of cooked rice in the present invention is not particularly limited, but it is a convenience store, supermarket, and take-out side dish store that is distributed and sold in a temperature range of 25 ° C. or less, particularly 20 ° C. or less after production, after 6 hours or more. Lunch boxes, sushi, etc. sold in That is, as cooked rice, it is suitable for rice that has been stored for 6 hours or more in a temperature zone of 20 ° C. or less after production, and in particular, has been stored (chilled storage) for 6 hours or more in a chilled region of 10 ° C. or less.
In particular, it is suitable for pale white rice or sushi rice that does not use soy sauce or miso. This is because rice cooked with soy sauce or miso (cooked rice, etc.) is often heavily seasoned, and such cooked rice uses a certain amount of traditional anti-aging ingredients to some extent. It is hard to affect the taste. On the other hand, since it is difficult to use conventional aging-inhibiting materials for flavored white rice and sushi rice, it is highly necessary to use the materials of the present invention. In addition, the present invention is particularly suitable for cooked rice that cannot be reheated, such as sushi rice, because there is a great need to suppress aging.
なお、本発明におけるレシチンとナトリウム塩は、炊飯工程の前に、生米に対して、水とともに添加する必要がある。澱粉のα化時に両者が相乗的に作用するためである。 In addition, it is necessary to add the lecithin and sodium salt in this invention with water with respect to raw rice before a rice cooking process. This is because both act synergistically when the starch is gelatinized.
本発明におけるレシチンとは、化学的にはホスファチジルコリンであり、構造的には親水性基と疎水性基を持つ両親媒性の物質である。主に大豆又は卵黄から製造されるが、米飯への利用においては、その淡白な味への影響の少ない大豆由来のものが好ましい。また、HLBが9〜14であるものが望ましい。HLBが9より低いものは、老化抑制効果が比較的弱くなるためである。
レシチンは、大豆レシチン、卵黄レシチンのような形態で含有してもよいが、レシチン含有食品、例えば卵黄を添加することにより含有することもできる。
The lecithin in the present invention is phosphatidylcholine chemically and is structurally an amphiphilic substance having a hydrophilic group and a hydrophobic group. Although it is mainly produced from soybeans or egg yolks, those derived from soybeans that have little influence on the pale taste are preferred for use in cooked rice. Moreover, the thing whose HLB is 9-14 is desirable. The reason why the HLB is lower than 9 is because the aging inhibitory effect is relatively weak.
Lecithin may be contained in a form such as soybean lecithin and egg yolk lecithin, but can also be contained by adding lecithin-containing food such as egg yolk.
米飯のレシチンの含有量としては、生米当たり0.04〜0.4質量%(生米100g当たり0.04〜0.4g)であることが必要であるが、好ましくは0.1〜0.4質量%であり、特に好ましくは0.2〜0.3質量%である。0.4質量%よりも多いと、レシチン特有のエグ味、異味、香り、及び色調変化が強く出てしまい、味や香りの淡白な米飯の本来の香味を損なってしまう。また、0.04質量%より少ないと、澱粉の老化抑制効果を十分に得られない。 The content of lecithin in cooked rice is required to be 0.04 to 0.4% by mass per raw rice (0.04 to 0.4 g per 100 g of raw rice), preferably 0.1 to 0 .4 mass%, particularly preferably 0.2 to 0.3 mass%. When the amount is more than 0.4% by mass, the egg flavor, nasty taste, fragrance, and color change specific to lecithin appear strongly, and the original flavor of the light white rice with the taste and fragrance is impaired. Moreover, when less than 0.04 mass%, the aging inhibitory effect of starch cannot fully be acquired.
本発明において、ナトリウム塩としては、例えば、塩化ナトリウム、クエン酸ナトリウム、リンゴ酸ナトリウム、酢酸ナトリウム等を使用することが出来、これらの中でも、米飯の良好な食味を損なわず、価格が安く、食品素材である塩化ナトリウムが最も好適に用いられる。
また、ナトリウム塩は、単体の物質として添加してもよいし、ナトリウム塩を含有する食品や添加物を添加することによって、結果としてナトリウム塩を含有させてもよい。また、上記添加方法にて、ナトリウム塩を1種、又は2種以上を組み合わせて添加してもよい。
In the present invention, as the sodium salt, for example, sodium chloride, sodium citrate, sodium malate, sodium acetate and the like can be used, and among these, the good taste of cooked rice is not impaired, the price is low, and the food The material sodium chloride is most preferably used.
Further, the sodium salt may be added as a single substance, or as a result, a sodium salt may be contained by adding a food or additive containing the sodium salt. Moreover, you may add a sodium salt in the said addition method 1 type, or in combination of 2 or more types.
米飯のナトリウム塩の含有量としては、生米当り0.3〜5.0質量%であることが必要であるが、さらに好ましくは1.0〜3.0質量%である方が良い。上限値としては、5.0質量%より多いと塩味を強く感じすぎるため、米飯としては好ましくない。中でも、塩味を有さない白飯などの場合は、2.5質量%以下、特に1.5質量%、さらには1.0質量%以下が望ましい。また、寿司飯であれば、5.0質量%以下が必要であるが、さらには3.0質量%以下が望ましい。
また、ナトリウム塩の含有量の下限値としては0.3質量%であり、0.3質量%より少ないとナトリウム塩のレシチンと相乗的に澱粉の老化を抑制する効果が得られにくくなる。
The content of sodium salt of cooked rice is required to be 0.3 to 5.0% by mass per raw rice, and more preferably 1.0 to 3.0% by mass. As the upper limit, if it is more than 5.0% by mass, the salty taste is too strong, so it is not preferable as cooked rice. In particular, in the case of white rice having no salty taste, it is preferably 2.5% by mass or less, particularly 1.5% by mass, and more preferably 1.0% by mass or less. Moreover, if it is sushi rice, 5.0 mass% or less is required, Furthermore, 3.0 mass% or less is desirable.
The lower limit of the sodium salt content is 0.3% by mass, and if it is less than 0.3% by mass, the effect of suppressing starch aging synergistically with the sodium salt lecithin becomes difficult to obtain.
また、レシチンとナトリウム塩は、両者を予め水と混合した組成物(米飯加工改良剤)として、炊飯時に添加して用いることも出来る。尚、ここで言う米飯加工改良剤は、生米に対して所定量のレシチンとナトリウム塩が添加されるように予め調整された調味料である。 Moreover, a lecithin and a sodium salt can also be added and used at the time of rice cooking as a composition (boiled rice processing improvement agent) which mixed both with water previously. In addition, the cooked rice processing improver said here is a seasoning adjusted beforehand so that a predetermined amount of lecithin and sodium salt may be added with respect to raw rice.
また、米飯加工改良剤には、必要に応じて、還元水あめ等の糖類、各種有機酸及び有機酸塩等、風味付けやその他の機能を付与するための食品又は食品添加物を加えても良い。 In addition, food or food additives for imparting flavor or other functions, such as sugars such as reduced candy, various organic acids and organic acid salts, may be added to the cooked rice processing improver, if necessary. .
本発明において前記米飯加工改良剤を使用する場合は、炊飯前に、生米に対して添加する必要がある。澱粉のα化時に、米飯加工改良剤中のレシチンとナトリウム塩が作用するためである。
前記米飯加工改良剤を、生米重量に対し、レシチンの割合が0.04〜0.4質量%、ナトリウム塩の割合が0.3〜5.0質量%となるように添加した後に炊飯することにより、目的とする米飯、つまり低温での流通・保存時に米飯の澱粉の老化を抑制した米飯が得られる。
When using the said cooked rice processing improver in this invention, it is necessary to add with respect to raw rice before cooking rice. This is because lecithin and sodium salt in the cooked rice processing improver act during the gelatinization of starch.
After the rice cooker is added so that the ratio of lecithin is 0.04 to 0.4 mass% and the ratio of sodium salt is 0.3 to 5.0 mass% with respect to the weight of raw rice, rice is cooked. As a result, the desired cooked rice, that is, cooked rice that suppresses the aging of the starch of the cooked rice during distribution and storage at low temperatures can be obtained.
次に、上記米飯加工改良剤、又は規定量のレシチンと食塩を添加して米飯を製造する方法の一例を説明する。
まず、生米を定法にて水で洗米、浸漬し、十分に吸水させる。吸水させた米に、所定量の水と、さらに上記米飯加工改良剤、または規定量のレシチンと食塩を添加して炊飯する。以上の方法にて、低温保存に適した米飯を製造することが出来る。
Next, an example of the method for producing cooked rice by adding the above-described cooked rice processing improver or the prescribed amounts of lecithin and salt will be described.
First, uncooked rice is washed and soaked with water by a conventional method to sufficiently absorb water. A predetermined amount of water and the above-mentioned cooked rice processing improver, or specified amounts of lecithin and sodium chloride are added to the absorbed rice and cooked. By the above method, cooked rice suitable for low temperature storage can be produced.
また、寿司飯を製造する際は、上記米飯が炊き上がった際に、つまり炊飯後に、一定量の調味酢を混合すると良い。炊飯前に加えるナトリウム塩として食塩を使用した場合は、寿司酢に用いる食塩から先に加えた食塩を差し引いたものを前記炊き上がり米飯に混合して寿司飯を製造するとよい。 Moreover, when manufacturing sushi rice, it is good to mix a certain amount of seasoning vinegar when the above rice is cooked, that is, after cooking. When salt is used as a sodium salt to be added before cooking rice, it is preferable to produce sushi rice by mixing the salt used in sushi vinegar minus the salt added earlier with the cooked rice.
以下、本発明を実施例により具体的に説明するが、本発明はこれにより何ら制限されるものではない。 EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.
〔実施例1〕
(1)レシチン及びナトリウム塩を含有する白飯の炊飯
生米(福島県産こしひかり)300gを洗米し、約1時間水に浸漬した。次いで水切りしたのち、5合釜の家庭用炊飯機に投入し、表1〜4に示す量のレシチン(0〜0.9g)及び塩化ナトリウム(0〜6g)を溶解した液をそれぞれ投入した後、釜内の総重量が735gになるように水を加えた。釜内を攪拌した後、定法により加熱して炊飯した。その後、加熱を止め、30分間の蒸らし工程を経て、炊飯を完了した。
このようにして調整した炊飯米は、冷却後重量がおよそ660gとなり、60gずつ円盤上に成型したものを白飯サンプルとした。
なお、レシチンとしては、HLBが14の大豆レシチン(ベイシスLP−20E:日清オイリオグループ社製)を用いた。
[Example 1]
(1) Cooked white rice containing lecithin and sodium salt 300 g of raw rice (Koshihikari from Fukushima Prefecture) was washed and immersed in water for about 1 hour. Next, after draining, after putting into a 5 rice kettle household rice cooker, each of the solutions of lecithin (0-0.9 g) and sodium chloride (0-6 g) shown in Tables 1-4 was added. Water was added so that the total weight in the kettle was 735 g. After stirring the inside of the kettle, it was cooked by heating by a conventional method. Then, heating was stopped and the cooking of rice was completed through a steaming process for 30 minutes.
The cooked rice prepared in this manner had a weight of about 660 g after cooling, and was formed on a disc by 60 g as a white rice sample.
In addition, as lecithin, soybean lecithin (Basis LP-20E: Nisshin Oillio Group Co., Ltd.) having an HLB of 14 was used.
(2)熟練官能検査員による白飯の老化評価
以上の工程にて作成した白飯サンプルを5℃で24時間静置したのち、常温に品温を戻した状態で、弊社熟練官能検査員により各々の老化の程度を下記の基準にて評価した。結果を表1〜4中に示した。
なお、表中において、白飯サンプルに含有されるレシチン及び塩化ナトリウムの濃度(質量%)は、生米100gに対する、レシチン及び塩化ナトリウムの添加量(g)である。
(2) Evaluation of white rice aging by skilled sensory inspectors After the white rice sample prepared in the above process was allowed to stand at 5 ° C. for 24 hours, the product temperature was returned to room temperature. The degree of aging was evaluated according to the following criteria. The results are shown in Tables 1-4.
In the table, the concentration (mass%) of lecithin and sodium chloride contained in the white rice sample is the addition amount (g) of lecithin and sodium chloride to 100 g of raw rice.
〔老化の評価基準〕
◎:澱粉の老化はなく、食感も非常に良好である。
○:澱粉の老化はほとんどなく、食感も良好である。
△:澱粉がやや老化しており、食感に固さ、粉っぽさをわずかに感じる。
×:澱粉が老化しており、食感は固く感じ、粉っぽい。
[Evaluation criteria for aging]
(Double-circle): There is no aging of starch and food texture is also very favorable.
○: Starch is hardly aged and texture is good.
(Triangle | delta): Starch is aged a little and it is hard to texture, and feels slightly powdery.
X: Starch is aged, texture is hard and powdery.
上表から、レシチンを0.04質量%以上、ナトリウム塩を0.3質量%以上添加した白飯は、両素材無添加のものに比べて、明らかに老化を抑制していることが確認された。
また、レシチンを単体を添加したものでは老化を抑制する効果は乏しく、ナトリウム塩を併用することにより、その効果が格段に高まることが確認できた。一方で、ナトリウム塩を単体で添加したものでは全く老化を抑制する効果がないことも確認できた。
このような老化を抑制する効果は、レシチンが0.2質量%以上のときに特に顕著であることが明らかとなり、また、ナトリウム塩が1.0質量%以上のときに顕著であることが明らかになった。
ただし、白飯の場合、ナトリウム塩を3.0質量%添加した場合、味への影響が大きいため、実質的には2.5質量%以下、好ましくは1.5%以下、最も好ましくは1.0質量%以下がよいと考えられる。
なお、詳細は省略するが、レシチンを0.5質量%及び塩化ナトリウムを適量(0.3質量%、1.0質量%、3.0質量%、5.0質量%)添加した米飯を作成したが、老化抑制効果はあるものの、レシチン特有のエグ味、異味、香り、及び色調変化が強く出すぎてしまい好ましくないことがわかった。
From the above table, it was confirmed that white rice to which lecithin was added in an amount of 0.04% by mass or more and sodium salt in an amount of 0.3% by mass or more clearly suppressed aging as compared with the case of no addition of both materials. .
Moreover, the effect which suppresses aging is scarce in what added the lecithin simple substance, It has confirmed that the effect increased markedly by using sodium salt together. On the other hand, it was also confirmed that the sodium salt added alone had no effect of suppressing aging.
It is clear that the effect of suppressing such aging is particularly remarkable when lecithin is 0.2% by mass or more, and it is obvious that the sodium salt is 1.0% by mass or more. Became.
However, in the case of white rice, when 3.0% by mass of sodium salt is added, the effect on the taste is large, so that it is substantially 2.5% by mass or less, preferably 1.5% or less, most preferably 1. 0% by mass or less is considered good.
Although details are omitted, cooked rice to which 0.5% by mass of lecithin and appropriate amounts of sodium chloride (0.3% by mass, 1.0% by mass, 3.0% by mass, 5.0% by mass) are added is prepared. However, it has been found that although there is an effect of inhibiting aging, the eggy taste, nasty taste, fragrance, and color tone characteristic peculiar to lecithin are excessively increased, which is not preferable.
〔実施例2〕
実施例1の結果を踏まえ、レシチンとナトリウム塩を添加した寿司飯の澱粉の老化抑制効果について、経時的に検証を行なった。
(1)寿司飯の作成
生米(福島県産こしひかり)300gを洗米し、約1時間水に浸漬した。次いで水切りしたのち、5合釜の家庭用炊飯機に投入し、一方の試験区にはレシチン0.3g及び塩化ナトリウム4.5gを溶解した液を投入した後、もう一方の試験区にはレシチンも塩化ナトリウムも加えずに、それぞれ釜内の総重量が705gになるように水を加えた。釜内を攪拌した後、定法により加熱して炊飯した。その後、加熱を止め、30分間の蒸らし工程を経て、炊飯を完了した。
上記炊飯米に、寿司酢(各々の試験区に表5記載の寿司酢を使用)66mlを添加し、十分混ぜ合わせたものを60gずつ円盤上に成型したものを寿司飯サンプルとした。
なお、試験区ごとに異なる寿司酢を用いるのは両試験区の寿司飯における食酢、食塩、砂糖の量を統一するためである。つまり、レシチン・ナトリウム塩添加区に用いる寿司酢の食塩は、同試験区にて塩化ナトリウム(食塩)を炊飯時に添加しているため、その添加量を差し引いた量になっている。
[Example 2]
Based on the results of Example 1, the aging inhibitory effect of sushi rice starch added with lecithin and sodium salt was verified over time.
(1) Preparation of sushi rice 300 g of fresh rice (Koshihikari from Fukushima Prefecture) was washed and immersed in water for about 1 hour. Next, after draining, the mixture was put into a 5 rice cooker household rice cooker, and a solution containing 0.3 g of lecithin and 4.5 g of sodium chloride was added to one test zone, and then lecithin was added to the other test zone. Water was added so that the total weight in the kettle would be 705 g without adding sodium chloride or sodium chloride. After stirring the inside of the kettle, it was cooked by heating by a conventional method. Then, heating was stopped and the cooking of rice was completed through a steaming process for 30 minutes.
A sushi rice sample was prepared by adding 66 ml of sushi vinegar (using the sushi vinegar shown in Table 5 for each test zone) to the above cooked rice and mixing them well onto a disc of 60 g.
The different sushi vinegar is used for each test zone in order to unify the amounts of vinegar, salt and sugar in the sushi rice of both test zones. That is, the salt of sushi vinegar used in the lecithin / sodium salt addition group is the amount obtained by subtracting the added amount because sodium chloride (salt) was added at the time of cooking in the test group.
(2)熟練官能検査員による寿司飯の老化評価
以上の工程にて作成した寿司飯サンプルを5℃で0〜36時間静置したのち、常温に品温を戻した状態で、弊社熟練官能検査員により各々の老化の程度を下記の基準にて評価した。結果を表6中に示した。
なお、表中において、寿司飯サンプルに含有されるレシチン及び塩化ナトリウムの濃度(質量%)は、生米100gに対する、レシチン及び塩化ナトリウムの添加量(g)である。
(2) Aging evaluation of sushi rice by a skilled sensory inspector After leaving the sushi rice sample prepared in the above process for 0 to 36 hours at 5 ° C, after returning the product temperature to room temperature, our expert sensory inspection Each member evaluated the degree of aging according to the following criteria. The results are shown in Table 6.
In the table, the concentration (mass%) of lecithin and sodium chloride contained in the sushi rice sample is the addition amount (g) of lecithin and sodium chloride relative to 100 g of raw rice.
〔老化の評価基準〕
◎:澱粉の老化はなく、食感も非常に良好である。
○:澱粉の老化はほとんどなく、食感も良好である。
△:澱粉がやや老化しており、食感に固さ、粉っぽさをわずかに感じる。
×:澱粉が老化しており、食感は固く感じ、粉っぽい。
[Evaluation criteria for aging]
(Double-circle): There is no aging of starch and food texture is also very favorable.
○: Starch is hardly aged and texture is good.
(Triangle | delta): Starch is aged a little and it is hard to texture, and feels slightly powdery.
X: Starch is aged, texture is hard and powdery.
表6から、レシチンとナトリウム塩を添加した寿司飯は、両素材無添加のものに比べて、経時的にも老化を抑制していることが確認された。 From Table 6, it was confirmed that the sushi rice to which lecithin and sodium salt were added suppressed the aging over time as compared to the sushi rice to which neither material was added.
本発明によると、常温以下、特に低温下に一定時間保存された澱粉の老化に伴う食感の変化が起り易い米飯に関して、澱粉の老化に伴う食感の変化を抑制した米飯を提供することが可能となる。
また、常温以下、特に低温下に一定時間保存された澱粉の老化に伴う食感の変化が起り易い米飯に関して、澱粉の老化に伴う食感の変化を抑制した米飯の製造方法を提供することが可能となる。
さらには、前記米飯を提供することが出来る米飯加工改良剤を提供することが可能となる。
According to the present invention, with respect to cooked rice that is susceptible to changes in texture due to aging of starch stored at a room temperature or lower, particularly at a low temperature for a certain period of time, it is possible to provide cooked rice that suppresses changes in texture associated with aging of starch. It becomes possible.
In addition, with respect to cooked rice that is susceptible to changes in texture associated with aging of starch stored at a room temperature or lower, particularly at a low temperature for a certain period of time, a method for producing cooked rice that suppresses changes in texture associated with aging of starch is provided. It becomes possible.
Furthermore, it becomes possible to provide the cooked rice processing improver which can provide the cooked rice.
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