JP5632638B2 - Method and apparatus for recovering waste plastic cracked oil - Google Patents

Description

  The present invention relates to a method and an apparatus for recovering cracked oil from waste plastic, and more particularly to a method and an apparatus for recovering cracked oil by melting or melting crushed waste plastic and then thermally decomposing it.

  Plastic products are widely used for various applications. In particular, polyethylene (PE), polypropylene (PP), and polystyrene (PS) are produced in large quantities. In addition, polyvinyl chloride (PVC), polyethylene terephthalate (PET), and the like are also widely used.

  Such processing after the plastic product has been used includes processing for remanufacturing. This is to remelt and mold waste plastic and is called material recycling. Next, waste plastic will be used effectively as fuel. This process is called thermal recycling.

  On the other hand, there is a reuse of waste plastic that is converted into oil and used as an alternative fuel for heavy oil or light oil. In addition, there is a method of decomposing a molded article of polyethylene terephthalate represented by a pet bottle and decomposing it into terephthalic acid and ethylene glycol. The above-mentioned method of reusing oil and the method of reusing it as a chemical raw material are called chemical recycling.

  The present invention relates to a method for thermally decomposing waste plastic to recover decomposed oil. The present invention relates to a method and apparatus suitable for use in the treatment of halogen-based waste plastics such as PVC containing chlorine, and waste plastics containing a halogen-based flame retardant and exhibiting strong acidity when decomposed.

  When processing waste plastic, particularly when recovering cracked oil by thermal decomposition, the waste plastic dissolved and liquefied exhibits acidity. Therefore, when such an acidic cracked oil is further thermally decomposed to recover the oil component, the apparatus is corroded or damaged due to the acidic nature of the dissolved oil. Therefore, there is a problem that the life of the apparatus is shortened or the material used for the apparatus is limited.

  Recycle waste plastics containing halogen-containing waste plastics such as polyvinyl chloride (PVC) containing chlorine, and brominated flame retardants such as tetrabromobisphenol A (TBBA) and hexabromocyclododecane (HBCD). In the case of chemical recycling or material recycling, a heating process is essential. However, corrosiveness and chemical reaction of hydrogen chloride (HCl), hydrogen bromide (HBr), etc. due to halogen elements such as chlorine contained in the plastic itself and bromine contained in the added flame retardant by heating in this heating process. Material recycling is difficult due to the generation of highly reactive gases. For this reason, most of the waste plastics that generate such halogen-based gases are used for incineration and landfill disposal, except for those that recover liquid fuel by liquefaction or use it for solid fuel. It is attached.

  As a method for treating halogens related to the oily conversion of waste plastics, a method of removing halogens using a solvent (Japanese Patent Laid-Open No. 2006-225409), a method of removing halogens by utilizing the difference in decomposition temperature between plastic and flame retardant (Japanese Patent Laid-Open No. 2002-226625), a method of removing halogen from an organic substance halogenated after oil formation using a catalyst (Japanese Patent Laid-Open No. 2000-117737), and the like have been proposed. However, a treatment method effective for suppressing acidic halogen compounds has not been proposed for detoxifying halogen during the thermal decomposition process, and in particular for preventing corrosion of a recovery device that collects it as oil.

JP 2006-225409 A JP 2002-226625 A JP 2000-117737 A

  SUMMARY OF THE INVENTION An object of the present invention is to provide a method for recovering cracked oil and a recovery device for avoiding adverse effects such as corrosion of the device due to acidic cracked oil when the waste plastic is dissolved or melted and then thermally decomposed to recover the cracked oil. Is to provide.

  Another object of the present invention is to effectively harm non-corrosive and chemically reactive gases such as hydrogen chloride, hydrogen bromide, etc., generated when liquefying waste plastics containing halogenated plastics or halogenated flame retardants. It is an object of the present invention to provide a cracked oil recovery device and recovery method that eliminates adverse effects on the device.

  Still another object of the present invention is to provide a method for detoxifying halogen in any of a gas phase part and a liquefaction part in a decomposition tank of a waste plastic cracking and oil converting apparatus.

  The above-described problems and other problems of the present invention will be made clear by the technical idea of the present invention described below and the embodiments thereof.

The main invention of the present application is a method of recovering cracked oil by dissolving or melting a waste plastic in which hydrogen halide is generated by pyrolysis, and then pyrolyzing and cooling the pyrolyzed gas .
Add sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate alkali and urea , ammonium carbonate or ammonium hydrogen carbonate and water to the waste plastic ,
Neutralizing hydrogen halide generated by pyrolyzing the waste plastic with the alkali, and generating ammonia from the urea, ammonium carbonate, or ammonium bicarbonate by thermal decomposition after dissolving or melting the waste plastic. Further, the present invention relates to a method for recovering cracked oil from waste plastics, characterized by neutralizing the generated ammonia and the hydrogen halide gas generated by the thermal decomposition .

Here, the waste plastic may be halogen-based or may contain a halogen-based flame retardant. Further, the alkali to be added and urea , ammonium carbonate or ammonium hydrogen carbonate are added as an aqueous solution, and the concentration of the aqueous solution is 1.0 to 10 times the chemical amount that neutralizes the waste plastic. Good. The amount of water added may be in the range of 1 to 50% by weight with respect to the waste plastic to be added.

The main invention related to the cracked oil recovery device is a recovery device that recovers cracked oil by melting or melting the waste plastic that generates hydrogen halide by pyrolysis and then thermally decomposing it , and cooling the pyrolyzed gas . ,
Supply means for crushing the waste plastic with a crusher and supplying it with a hopper;
A liquefying device for dissolving or melting the waste plastic supplied by the supply means in a dissolution tank;
A thermal decomposition apparatus for further thermally decomposing the waste plastic liquefied by the liquefaction apparatus with a decomposition pot;
An oil generator for cooling the gas pyrolyzed by the pyrolyzer to produce an oil; and
The waste plastic supplied by the supply means includes any one of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate and urea , ammonium carbonate, or ammonium bicarbonate. An addition device for adding water ,
Neutralizing hydrogen halide generated by pyrolyzing the waste plastic with the alkali, and generating ammonia from the urea, ammonium carbonate, or ammonium bicarbonate by thermal decomposition after dissolving or melting the waste plastic. The present invention relates to an apparatus for recovering cracked oil from waste plastics, which neutralizes the generated ammonia and hydrogen halide gas generated by the thermal decomposition .

Here, the said addition apparatus may be attached to the said crusher, the said hopper, the said dissolution tank, or the said decomposition pot which comprises the said collection | recovery apparatus.

The main invention of the present application is a method of recovering cracked oil by dissolving and melting a waste plastic in which hydrogen halide is generated by pyrolysis and then thermally decomposing and cooling the pyrolyzed gas. Sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate alkali and urea , ammonium carbonate or ammonium hydrogen carbonate and water are added, and the waste plastic is heated by the alkali. In addition to neutralizing the hydrogen halide generated by the decomposition, thermal decomposition after dissolving or melting the waste plastic generates ammonia from the urea, ammonium carbonate or ammonium hydrogen carbonate, and the generated ammonia and the heat to neutralize the hydrogen halide gas generated by the decomposition One in which the.

Therefore, according to such a method for recovering cracked oil from waste plastic, the acidity of the cracked oil is reduced by the alkali , urea or ammonia carbonate and water added to the waste plastic during cracking and liquefaction. It becomes a summed state. Therefore, the generation of hydrogen chloride and hydrogen bromide can be prevented and detoxification can be achieved. Moreover, since excess water is separated from oil by oil-water separation, the quality of recovered oil is not deteriorated.

The main invention related to the cracked oil recovery device is a recovery device that recovers cracked oil by melting or melting the waste plastic that generates hydrogen halide by pyrolysis and then thermally decomposing it , and cooling the pyrolyzed gas . A supply means for crushing the waste plastic by a crusher and supplying the waste plastic by a hopper, a liquefying device for dissolving or melting the waste plastic supplied by the supply means in a dissolution tank, and waste plastic liquefied by the liquefaction device. further comprising a thermally decomposed pyrolytic apparatus by decomposition kettle, and a oil generating device for generating an oil pyrolysis gas is cooled in the pyrolysis apparatus, water in the waste plastics supplied by said supply means Sodium oxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate Any alkali and urea, comprising a dosing device for adding an ammonium carbonate or ammonium hydrogen carbonate and water, as well as neutralize the hydrogen halide of the waste plastics caused by thermal decomposition by the alkali, the waste plastic In the thermal decomposition after melting or melting, ammonia is generated from the urea, ammonium carbonate or ammonium hydrogen carbonate, and the generated ammonia and the hydrogen halide gas generated in the thermal decomposition are neutralized. is there.

Therefore, according to such a cracked oil recovery device, the generation of hydrogen chloride and hydrogen bromide when waste plastic is oiled is prevented by the alkali and urea or ammonia carbonate added by the addition device and water. This makes it possible to render halogenation harmless in the thermal decomposition process, effectively prevent corrosion of the apparatus and suppress halogenated organic substances. In addition, since the corrosion of the apparatus is prevented in particular, it is possible to reduce the cost of the apparatus without using a special material for the apparatus.

It is a block diagram which shows the structure of the collection | recovery apparatus of cracked oil.

  The present invention will be described below with reference to embodiments shown in the drawings. The plasticization of waste plastics consists of a supply process for supplying waste plastics as raw materials, a liquefaction process for the supplied waste plastics, a process for thermally decomposing the liquefied waste plastics, and condensing the pyrolysis product gas (Liquefaction) process. Here, in particular, the thermal decomposition is performed at a temperature of 300 ° C. or higher.

  Ordinary plastic waste often exhibits weak acidity due to its liquefaction. Further, when the waste plastic contains a halogen element such as PVC or a halogen-based flame retardant, hydrogen chloride or hydrogen bromide is generated by the waste plastic itself or the flame retardant. The present invention relates to a method and an apparatus for recovering cracked oil of waste plastics that prevent the acidity of itself or adverse effects caused by the generation of hydrogen chloride and hydrogen bromide.

  FIG. 1 shows an example of a waste plastic recovery apparatus according to the present embodiment, and this recovery apparatus includes a hopper 10 that supplies crushed waste plastic. A horizontal transfer machine 11 is attached to the lower side of the hopper 10 and is driven by a motor 12 so that the horizontal transfer machine 11 supplies waste plastic from the hopper 10 forward. And the melting machine 13 provided with the skew type screw conveyor is provided in the front end side lower part of the said horizontal transfer machine 11. As shown in FIG. The melting machine 13 has its internal screw conveyor driven by a motor 14. Then, the waste plastic sent by the melting machine 13 is supplied to the melting tank 15.

  The lower end side of the dissolver 13 is connected to a dissolver level tank 18. The dissolver level tank 18 is provided with a heater 19 so as to heat the oil recovered by thermal decomposition and supply it to the dissolver 13 through an oil supply pipe 20.

  On the other hand, the dissolution tank 15 has heaters 21, 22, and 23 attached to its side and bottom, and a screen 24 is disposed in the dissolution tank 15. Further, a fan 26 driven by a motor 25 is provided, whereby the decomposition liquid in the dissolution tank 15 is agitated.

  An addition device 27 is provided in the upper part of the dissolution tank 15. The addition device 27 is for adding alkali or / and urea and water into the dissolution tank 15, thereby increasing the pH of the decomposition solution of the thermal decomposition tank 31 and neutralizing it. And constitutes the main feature of the present invention.

  The bottom of the dissolution tank 15 is communicated with the pyrolysis tank 31 via the oil feed pipe 30 so that the solution is supplied from the dissolution tank 15 to the pyrolysis tank 31. A solution pump 32 is connected to the oil feed pipe 30 and is driven by a motor 33. Further, the oil feeding pipe 30 is further provided with a circulation circuit 34 which is further branched and connected with a valve 35 so that the liquefied and sent solution is once again returned to the dissolution tank 15 as necessary. Such circulation is performed only when the valve 35 is opened.

  The pyrolysis vessel 31 is for thermally decomposing liquefied waste plastic, and the inside is stirred by a stirrer 36. The stirrer 36 is driven by a motor 37.

  A burner 42 is provided to generate high-temperature gas to be supplied to the pyrolysis kettle 31. The burner 42 is supplied with air by a burner blower 43 connected to the rear part thereof. The burner blower 43 is driven by a motor 44 so that air is supplied to the burner 41 by a pair of air-blowing pipes 45 and 46 parallel to each other. Here, the air preheater 47 preheats the air passing through the blower pipe 46.

  The hot air blowing pipe 48 connected to the outlet side of the burner 42 is bent in a U shape and connected to the pyrolysis pot 31. In addition, an oil feed pipe 49 is connected to the inlet side portion of the burner 42, and a tip side portion of the oil feed pipe 49 is an injection hole 50, and the oil recovered from the injection hole 50 is injected, I try to burn it.

  A gas supply pipe 54 is connected to the upper outlet of the pyrolysis pot 31. This gas supply pipe 54 is connected to a capacitor 55. The condenser 55 cools the pyrolyzed gas and liquefies it, thereby collecting the oil. That is, a radiator 56 is connected to the condenser 55 via a pair of upper and lower cooling water pipes 57 and 58. A fan 59 is disposed in front of the radiator 56 and is driven by a motor 60.

  Next, a generated oil tank 63 is provided below the condenser 55, and this generated oil tank 63 is partitioned by a partition wall 64, and a front portion thereof is an oil / water separation tank 65. An oil feed pipe 66 is connected to the generated oil tank 63, and a pump 67 is connected to the oil feed pipe 66. When the pump 67 is driven, the recovered oil is supplied to the dissolver level tank 18 through the oil feeding pipe 66.

  The base end portion of the oil feed pipe 49 described above is further connected to the bottom portion of the product oil tank 63, whereby a part of the recovered oil in the product oil tank 63 is supplied to the injection hole 50 portion of the burner 42. It is supposed to be burned. A filter 70 is connected to the oil feed pipe 49, and an oil feed pipe 72 is branched and connected via a switching valve 73 above the filter 70. A kerosene tank 71 is connected to the oil feeding pipe 72. When the generated oil tank 63 is empty, the kerosene in the kerosene tank 71 is supplied from the oil feed pipe 49 to the injection hole 50 of the burner 42 via the switching valve 73. A shut-off valve 74 is connected to the inlet side of the burner 42 of the oil feed pipe 49 so that the supply of oil or kerosene to the burner 42 can be stopped in an emergency.

  A discharge pipe 77 is connected to the bottom of the pyrolysis vessel 31, and a residue valve 75 is attached to the discharge pipe 77. A residue tank 76 is disposed below the residue valve 75. The residue generated in the pyrolysis vessel 31 is supplied to the residue tank 76 through the discharge pipe 77 by opening the residue valve 75.

  Next, the operation of the waste plastic decomposition and recovery apparatus according to the above configuration will be described. The waste plastic is crushed and supplied sequentially by the hopper 10. The crushed waste plastic from the hopper 10 is supplied to the melting tank 15 by the lateral transfer machine 11 and the melting machine 13. In addition, the oil supplied by the dissolver level tank 18 exists in the bottom part of the dissolver 13, and for this reason, the waste plastic is supplied to the dissolution tank 15 in a semi-molten state. Then, in the dissolution tank 15, it is heated by the heaters 21, 22, and 23 and stirred by the fan 26 to become almost liquid.

  Dissolved waste plastic in the dissolution tank 15 is pushed up by a solution pump 32 connected to the oil feeding pipe 30 and reaches a thermal decomposition pot 31. The pyrolysis pot 31 is heated by the combustion gas from the burner 42. Part of the oil stored in the product oil tank 63 is supplied to the injection hole 50 of the burner 42 by the oil feeding pipe 49, where the oil burns, the burner 42 generates a flame, and high-temperature gas is produced. It is done. At this time, air is supplied by the burner blower 43. The air is supplied to the burner 42 by the blower pipe 46 directly or by being heated by the air preheater 47. On the other hand, the high-temperature gas generated in the burner 42 is supplied to the pyrolysis vessel 31 through the hot air blowing pipe 48, and the waste plastic solution is thermally decomposed into gas.

  The pyrolyzed oil component gas is sent to the condenser 55 through the gas supply pipe 54, and is cooled into the liquefied oil component in the condenser 55 by the cooling water passing through the radiator 56. This oil component falls into the product oil tank 63 and is separated by moisture and weight in the oil / water separation tank 65 on the front side of the partition wall 64, and only the oil component is guided to the right portion of the partition wall 64. A part of the recovered oil generated here is supplied to the burner 42 through the oil feeding pipe 49 and used as fuel for the burner 42. Another part of the oil generated here is supplied to the dissolver level tank 18 through the oil feeding pipe 66 and used as the dissolved oil of the dissolver 13.

  In such a cracked oil recovery device, the present invention uses an addition device 27 provided at the upper portion of the dissolution tank 15 to cause acid waste plastic, halogen elements used in this waste plastic, or hydrogen chloride by an added flame retardant. It is a great feature to achieve neutralization and detoxification of halogen such as. The addition device 27 for adding alkali or / and urea and moisture does not necessarily have to be attached to the dissolution tank 15, and may be attached to the waste plastic crusher, the hopper 10, or the pyrolysis vessel 31. You may attach the addition apparatus 27 to a location. Here, as shown in FIG. 1, the waste plastic is decomposed not continuously but batchwise. That is, the supply of waste plastic by the hopper 10, the decomposition by the melting tank 15, and the thermal decomposition by the thermal decomposition pot 31 are continuously performed. It is also possible to carry out in batch mode.

  In particular, the feature of neutralization by the addition device 27 of the dissolution tank 15 is that water is injected into the dissolution tank 15. The amount of water injected is in the range of 1 to 50% of the input raw material. If the amount of water injected is less than 1%, the neutralization reaction will not proceed smoothly. On the other hand, if the amount of water injected exceeds 50%, it becomes excessive and neutralization is not successful, and the amount of water recovered in the oil / water separation tank 65 increases excessively. In the recovery device of the embodiment of FIG. 1, 5 to 10% by weight of water is injected into the dissolution tank 15 together with the raw material with respect to the waste plastic of the polystyrene foam as the raw material. This water is finally separated in an oil / water separation tank 65 attached to the product oil tank 63, and when 50 to 100 kg of waste plastic is processed and oil is recovered, 5 to 10 l of water is separated. Is done.

  Further, an addition device 27 in the dissolution tank 15 is used to inject the alkali, urea and water, or the aqueous alkali solution, the aqueous urea solution, or the aqueous alkaline urea mixture into the pyrolysis vessel 31 together with the waste plastic. The concentration of the aqueous alkali solution and the aqueous urea solution depends on the amount of halogen contained in the raw material. That is, in the case of waste plastic made of vinyl chloride resin, an amount necessary for neutralizing the generated hydrogen chloride HCl is added. In the case of a flame retardant contained in waste plastic, the amount is about 1 to 10 times the chemical amount required to neutralize hydrogen bromide HBr generated by the flame retardant. Since the efficiency of the neutralization reaction of hydrogen chloride HCl or hydrogen bromide HBr is not 100%, at least one times the stoichiometric amount must be added. On the other hand, if too much is added, the neutralizing agent is wasted and the residue increases, so it must not exceed 10 times.

Examples of the alkali added by the addition apparatus include sodium hydroxide (NaOH), potassium hydroxide (KOH), sodium carbonate (Na ₂ CO ₃ ), potassium carbonate (K ₂ CO ₃ ), sodium hydrogen carbonate (NaHCO ₃ ), It is preferably any one of potassium hydrogen carbonate (KHCO ₃ ), and preferably water-soluble. The alkaline aqueous solution reacts with hydrogen chloride or hydrogen bromide generated by the thermal decomposition of waste plastic, and changes to a detoxifying substance such as sodium chloride or sodium bromide. In the case where the additive is urea, urea is decomposed into ammonia in the presence of water in the pyrolysis vessel 31, and this ammonia reacts with hydrogen chloride or hydrogen bromide to detoxify ammonium chloride or odor. Becomes ammonium fluoride. The above reaction occurs in the same manner even when an alkali and urea mixed solution is added. Urea may be itself, but may further be ammonium carbonate ((NH ₄ ) ₂ CO ₃ ) or ammonium hydrogen carbonate (NH ₄ HCO ₃ ). Since these substances dissolve in water and generate ammonia by thermal decomposition, they can be used for neutralizing waste plastics.

  The neutralization reaction between ammonia and hydrogen chloride or hydrogen bromide also occurs in the pyrolysis vessel 31 described above. It also occurs in the gas phase part of the pyrolysis vessel 31 and in the solidification (liquefaction) process. In particular, the neutralization reaction in the gas phase portion effectively acts to prevent corrosion of the pyrolysis vessel 31 by hydrogen chloride or hydrogen bromide.

The oil recovery process including neutralization is a continuous process, water is added, alkali or / and urea is added, and the neutralization reaction occurs in the gas phase and the condensation process. Are interrelated. Polyvinyl chloride (PVC), which is a halogen-based plastic, begins to decompose at 200 ° C. Moreover, it is a halogen-based flame retardant added, and hexabromocyclododecane (HBCD) starts to decompose at 250 ° C. to generate hydrogen chloride and hydrogen bromide, respectively. These acidic gases are neutralized by an alkali such as slaked lime, but since the alkali is not dissolved in oil and it is not easy to make fine particles, an efficient neutralization reaction cannot be expected. On the other hand, sodium hydroxide (NaOH), potassium hydroxide (KOH), sodium carbonate (Na ₂ CO ₃ ), potassium carbonate (K ₂ CO ₃ ), sodium bicarbonate (NaHCO ₃ ), hydrogen carbonate in alkalis Since potassium (KHCO ₃ ) dissolves well in water, when it is made into an aqueous solution and injected into the pyrolysis kettle 31, the temperature of the pyrolysis kettle 31 is 300 ° C. or higher, so that water boils rapidly and the alkali becomes fine particles. Thus, it is dispersed in the oil in the dissolution tank 15 and the reaction efficiency with chlorine gas or the like is improved.

  On the other hand, when an aqueous solution of urea is injected into the thermal decomposition vessel 31, urea generates ammonia by a decomposition reaction with water. Since the evaporation temperature of water at normal pressure is 100 ° C. and the decomposition temperature of urea is 160 ° C., when the decomposition apparatus is a batch type, water is evaporated and lost during urea decomposition, so the ammonia yield by urea is Slightly lower. Moreover, since there is a difference between the urea decomposition temperature and the flame retardant decomposition temperature close to 100 ° C., the reaction between ammonia and hydrogen bromide cannot be expected so much. Therefore, in order to improve the neutralization reaction between ammonia and an acidic gas such as hydrogen bromide, it is necessary to always inject water and urea into the pyrolysis vessel 31.

  Next, a specific example will be described. When 10% (10 kg, 10,000 g) of vinyl chloride resin is mixed in 100 kg of waste plastic raw material, hydrochloric acid is generated in the pyrolysis vessel 31 as shown in the following (chemical formula 1).

  The number of moles of caustic soda (NaOH, 41 g / mole) required to neutralize 159 moles of hydrochloric acid is 159 moles (6.519 kg) as shown in the formula (2), which is a stoichiometric number. Since the total reaction efficiency is not 100%, an alkali having a stoichiometric number or more is required.

When dissolved in 10 l of water, the alkali (NaOH) concentration is 65%. Hydrochloric acid is neutralized to sodium chloride. When neutralizing with urea, urea (NH ₂ CONH ₂ ) decomposes at 160 ° C. or higher and reacts with water to produce ammonia. Neutralization is done with this ammonia to ammonium chloride.

The above reaction is a case where the reaction is neutralized with alkali (caustic soda) and urea, but the same can be considered for brominated flame retardants.
Comparative Example 1

When waste expanded polystyrene (PS) that does not contain halogen is liquefied in the continuous liquefaction apparatus of FIG. 1 with a processing capacity of 10 kg / hour, the acidity of the oil is 3.8 to 4 due to the benzoic acid in the oil. .2 shows weak acidity. In order to suppress the production of benzoic acid, 2 l of a 1% sodium carbonate aqueous solution was injected into 50 kg of waste polystyrene foam to effect oil formation. The acidity of the oil at this time was 5.5 at pH, and the acidity was significantly reduced.
Comparative Example 2

When 40 kg of the floating float mixed with the expanded polystyrene to which the flame retardant was added was liquefied by the above-mentioned oil making apparatus, the acidity of the oil was relatively high at pH 2.0. Since this acidity has a risk of corrosion of the oiling device described above, when 10 l of a 5% aqueous solution of sodium carbonate is injected by the adding device 27 of the dissolving tank 15 to make it oily, the acidity of the oil has a pH of 4. .3, and the acidity decreased.
Example 1

  When 35 kg of floating float mixed with Styrofoam (PS) and polyvinyl chloride (PVC) mixed with halogenated flame retardant was liquefied with the above-mentioned oil generator, the acidity of the oil had a strong acidity of 1.3 at pH. Indicated. When the above stray float 80 kg was made oily by the oiling device, oiling was performed while injecting 5 l of an aqueous solution of 0.6% urea and 1.0% sodium carbonate by the adding device 27 of the dissolution tank 15. As a result, the acidity of the oil was 4.5, indicating that it was almost neutralized and the acidity was greatly reduced.

  Although the present invention has been described with reference to the illustrated embodiments and examples, the present invention is not limited to the above-described embodiments and examples, and various modifications are possible within the scope of the technical idea of the present invention. is there.

  The present invention can be applied to a method for recovering oil from general waste plastics, halogen-based plastics, or waste plastics containing halogen-based flame retardants, or a decomposition that performs such a method. It can be used in an oil recovery device.

DESCRIPTION OF SYMBOLS 10 Hopper 11 Horizontal transfer machine 12 Motor 13 Dissolving machine 14 Motor 15 Dissolving tank 18 Dissolving machine level tank 19 Heater 20 Oil supply pipe 21-23 Heater 24 Screen 25 Motor 26 Fan 27 Addition device 30 Oil supply pipe 31 Pyrolysis pot 32 Solution pump 33 Motor 34 Circulating circuit 35 Valve 36 Stirrer 37 Motor 42 Burner 43 Blower blower 44 Motor 45, 46 Blow pipe 47 Air preheater 48 Hot air blow pipe 49 Oil feed pipe 50 Injection hole 54 Gas supply pipe 55 Condenser 56 Radiator 57, 58 Cooling Water piping 59 Fan 60 Motor 63 Generated oil tank 64 Partition wall 65 Oil / water separation tank 66 Oil feeding pipe 67 Pump 70 Filter 71 Kerosene tank 72 Oil feeding pipe 73 Switching valve 74 Shutoff valve 75 Residual valve 76 Residual tank 7 Discharge pipe

Claims (6)

In a method of recovering cracked oil by dissolving and melting a waste plastic that generates hydrogen halide by pyrolysis, and then pyrolyzing and cooling the pyrolyzed gas ,
Add sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate alkali and urea , ammonium carbonate or ammonium hydrogen carbonate and water to the waste plastic ,
Neutralizing hydrogen halide generated by pyrolyzing the waste plastic with the alkali, and generating ammonia from the urea, ammonium carbonate, or ammonium bicarbonate by thermal decomposition after dissolving or melting the waste plastic. A method for recovering cracked oil of waste plastics, comprising neutralizing the generated ammonia and hydrogen halide gas generated by the thermal decomposition .   The method for recovering waste plastic cracked oil according to claim 1, wherein the waste plastic is halogen-based or contains a halogen-based flame retardant. The added alkali and urea , ammonium carbonate or ammonium bicarbonate are added as an aqueous solution, and the concentration of the aqueous solution is 1.0 to 10 times the chemical amount that neutralizes the waste plastic. 2. A method for recovering cracked oil of waste plastics according to claim 1.   2. The method for recovering waste plastic cracked oil according to claim 1, wherein the amount of water added is in the range of 1 to 50% by weight with respect to the waste plastic to be added. In a recovery device that recovers cracked oil by dissolving or melting the waste plastic that generates hydrogen halide by pyrolysis and then cooling the pyrolyzed gas ,
Supply means for crushing the waste plastic with a crusher and supplying it with a hopper;
A liquefying device for dissolving or melting the waste plastic supplied by the supply means in a dissolution tank;
A thermal decomposition apparatus for further thermally decomposing the waste plastic liquefied by the liquefaction apparatus with a decomposition pot;
An oil generator for cooling the gas pyrolyzed by the pyrolyzer to produce an oil; and
The waste plastic supplied by the supply means includes any one of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate and urea , ammonium carbonate, or ammonium bicarbonate. An addition device for adding water ,
Neutralizing hydrogen halide generated by pyrolyzing the waste plastic with the alkali, and generating ammonia from the urea, ammonium carbonate, or ammonium bicarbonate by thermal decomposition after dissolving or melting the waste plastic. An apparatus for recovering cracked oil from waste plastics, which neutralizes the generated ammonia and the hydrogen halide gas generated by the thermal decomposition .   6. The apparatus for recovering cracked oil of waste plastics according to claim 5, wherein the adding device is attached to the crusher, the hopper, the melting tank, or the cracker constituting the recovering device.

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