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JP5909079B2 - Vegetable particle and / or fruit juice-containing liquid seasoning and method for producing the same - Google Patents
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JP5909079B2 - Vegetable particle and / or fruit juice-containing liquid seasoning and method for producing the same - Google Patents

Vegetable particle and / or fruit juice-containing liquid seasoning and method for producing the same Download PDF

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JP5909079B2
JP5909079B2 JP2011246036A JP2011246036A JP5909079B2 JP 5909079 B2 JP5909079 B2 JP 5909079B2 JP 2011246036 A JP2011246036 A JP 2011246036A JP 2011246036 A JP2011246036 A JP 2011246036A JP 5909079 B2 JP5909079 B2 JP 5909079B2
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fruit juice
seasoning
vegetable
soy sauce
containing liquid
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JP2013099306A (en
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史人 小島
史人 小島
武石 節子
節子 武石
唯花 五十嵐
唯花 五十嵐
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Kikkoman Corp
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本発明は、醤油と、5’−ヌクレオチドと、野菜粒子及び/又は果汁とを添加含有する野菜粒子及び/又は果汁含有液状調味料の製造法の改良に関し、該調味料の原料配合を全く変えることなく、野菜粒子(例えばおろしにんにくやおろし大根)及び/又は果汁の風味を確実に改善できる方法に関する。すなわち、原料配合が全く同一であるであるにも拘らず、ぽん酢では、柑橘果汁の生風味感が強く感じ、おろしだれでは、大根おろしの味とサッパリした味が強く感じ、また焼肉のたれでは、たまねぎなどの香味野菜の生風味感が強く感じる、野菜粒子及び/又は果汁含有液状調味料に関する。

The present invention relates to an improvement in the method for producing vegetable particles and / or fruit juice-containing liquid seasonings containing soy sauce, 5'-nucleotide, vegetable particles and / or fruit juice, and completely changing the raw material composition of the seasonings. It is related with the method which can improve the flavor of vegetable particles (for example, grated garlic or grated radish) and / or fruit juice without fail. In other words, despite the fact that the ingredients are exactly the same, Ponzu feels the raw flavor of citrus juice strongly, and the grated dripping feels the taste of daikon radish and the refreshing taste, and the grilled meat sauce The present invention relates to a vegetable seasoning and / or fruit juice-containing liquid seasoning that gives a strong sense of the raw flavor of flavored vegetables such as onions.

醤油及び5’−ヌクレオチドを添加した野菜及び/又は果汁含有液状調味料の製造法が知られている(非特許文献1参照)。そして、該5’−ヌクレオチドは、該液状調味料に旨味を与えるものとして添加されるが、熱には安定であるものの、酵素ホスファターゼによって分解され、旨味がなくなる欠点を有する。
一方、常法通り圧搾した生醤油には、微生物に由来し醤油醸造に関与した各種酵素が残存し、酵素ホスファターゼも残存している。そのため、上記5’−ヌクレオチドを添加した調味料の製造法において使用する醤油は、酵素ホスファターゼの活性を有しない熱処理(たとえば、プレートヒーターで105℃、60秒処理)された火入れ醤油が専ら用いられている。
したがって、従来醤油及び5’−ヌクレオチドを添加した野菜粒子及び/又は果汁含有液状調味料の製造業界において、生醤油を用いることは常識外のことであり、現実には実施されていない。
A method for producing a vegetable and / or fruit juice-containing liquid seasoning to which soy sauce and 5′-nucleotide are added is known (see Non-Patent Document 1). The 5′-nucleotide is added as a flavor imparting to the liquid seasoning. However, the 5′-nucleotide is stable to heat, but has the disadvantage that it is decomposed by the enzyme phosphatase and loses the flavor.
On the other hand, in the raw soy sauce compressed as usual, various enzymes derived from microorganisms and involved in soy sauce brewing remain, and the enzyme phosphatase also remains. Therefore, the soy sauce used in the method for producing a seasoning to which the 5′-nucleotide is added is exclusively a soy sauce that has been heat-treated (for example, treated at 105 ° C. for 60 seconds with a plate heater) without the activity of the enzyme phosphatase. ing.
Therefore, in the manufacturing industry of vegetable particles and / or fruit juice-containing liquid seasonings to which soy sauce and 5′-nucleotide have been added, the use of raw soy sauce is uncommon and has not been implemented in practice.

たれ類−その製造と利用−、太田静行、他著、株式会社光琳、平成4年4月10日発行、第167〜213頁参照Sauces-Manufacture and use-, Ota Shizuyuki, et al., Kogyo Co., Ltd., issued April 10, 1992, pages 167-213

本発明は、醤油及び5’−ヌクレオチドを使用する野菜粒子及び/又は果汁含有液状調味料の製造法において、喫食時における5‘−ヌクレオチドの旨味とともに該野菜粒子(例えばおろしにんにくやおろし大根)及び/又は果汁の風味を確実に改善することを課題とする。   The present invention relates to a method for producing vegetable particles and / or fruit juice-containing liquid seasonings using soy sauce and 5′-nucleotide, together with the 5′-nucleotide umami at the time of eating and the vegetable particles (for example, grated garlic and grated radish) and / or Or it makes it a subject to improve the flavor of fruit juice reliably.

本発明者らは、このような課題を解決するため鋭意検討を重ねた結果、生醤油を、従来公知の野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し5‘−ヌクレオチドは除く)と混和し、品温80〜90℃で加熱した後、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと該調味料に使用される原料の残部とを混和し、ついで品温60〜75℃で加熱するときは、従来公知の調味料に使用される原料配合が全く同一であるであるにも拘らず、5‘−ヌクレオチドの旨味及び野菜粒子(例えばおろし大根)及び/又は果汁の風味を確実に改善できることを知り、この知見に基づいて本発明を完成した。   As a result of intensive studies in order to solve such problems, the present inventors have used raw soy sauce as a part of raw materials used for conventionally known vegetable particles and / or fruit juice-containing liquid seasonings (however, 5 ' -Excluding nucleotides) and heating at a product temperature of 80 to 90 ° C., and then mixing raw vegetable particles and / or fruit juice, 5′-nucleotide and the remainder of the raw material used in the seasoning. Then, when heating at a product temperature of 60 to 75 ° C., the umami of 5′-nucleotide and vegetable particles (for example, grated daikon radish), despite the fact that the raw material composition used in the conventionally known seasoning is exactly the same. ) And / or the flavor of the fruit juice can be reliably improved, and the present invention has been completed based on this finding.

すなわち、本発明は以下に示すごとき野菜粒子及び/又は果汁含有液状調味料の製造法である。
(1)生醤油を、野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し5‘−ヌクレオチドを除く)と混和したものを、品温80〜90℃で加熱した後、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと、該調味料に使用される原料の残部とを混和し、次いで品温60〜75℃で加熱することを特徴とする野菜粒子及び/又は果汁含有液状調味料。
(2)生醤油を、野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し5‘−ヌクレオチドを除く)と混和したものを、品温80〜90℃で加熱した後、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと、該調味料に使用される原料の残部とを混和し、次いで品温60〜75℃で加熱することを特徴とする野菜粒子及び/又は果汁含有液状調味料の製造法。
(3)5’−ヌクレオチドが、5’−ヌクレオチドを含有する酵母エキス、鰹節エキス、椎茸エキスから選ばれる1種又は2種を含有する前記(2)に記載の製造法。
(4)野菜粒子が、乾燥香味野菜粒子である前記(2)に記載の製造法。
(5)乾燥香味野菜粒子が粒径1〜5mmの乾燥たまねぎ粒子である前記(4)に記載の製造法。
(6)野菜粒子及び/又は果汁含有液状調味料が、ぽん酢、おろしだれ、又は焼肉のたれである前記(1)に記載の調味料。
(7)野菜粒子及び/又は果汁含有液状調味料が、ぽん酢、おろしだれ、又は焼肉のたれである前記(2)に記載の調味料の製造法。
That is, this invention is a manufacturing method of the vegetable particle and / or fruit juice containing liquid seasoning as shown below.
(1) After heating raw soy sauce mixed with a part of raw materials (except 5′-nucleotide) used for vegetable particles and / or fruit juice-containing liquid seasonings at a product temperature of 80 to 90 ° C. In addition, raw vegetable particles and / or fruit juice, 5′-nucleotide, and the remainder of the raw material used for the seasoning are mixed, and then heated at a product temperature of 60 to 75 ° C. And / or fruit juice-containing liquid seasoning.
(2) After heating raw soy sauce mixed with a part of raw materials (except 5′-nucleotide) used for vegetable particles and / or fruit juice-containing liquid seasoning at a product temperature of 80 to 90 ° C. In addition, raw vegetable particles and / or fruit juice, 5′-nucleotide, and the remainder of the raw material used for the seasoning are mixed, and then heated at a product temperature of 60 to 75 ° C. And / or a method for producing a fruit seasoning-containing liquid seasoning.
(3) The production method according to (2), wherein the 5′-nucleotide contains one or two selected from yeast extract, bonito extract, and shiitake extract containing 5′-nucleotide.
(4) The production method according to (2), wherein the vegetable particles are dried flavored vegetable particles.
(5) The production method according to (4), wherein the dried flavored vegetable particles are dried onion particles having a particle diameter of 1 to 5 mm.
(6) The seasoning according to (1) above, wherein the vegetable season and / or fruit juice-containing liquid seasoning is ponzu, grated soup, or yakiniku sauce.
(7) The manufacturing method of the seasoning as described in said (2) whose vegetable particle and / or fruit juice containing liquid seasoning is a vinegar, a grated soup, or a sauce of grilled meat.

本発明によれば、醤油及び5’−ヌクレオチドを使用する従来公知の野菜粒子及び/又は果汁含有液状調味料において、原料配合が全く同一であるにも拘らず、喫食時における5‘−ヌクレオチドの旨味及び野菜粒子(例えばおろし大根)及び/又は果汁の風味を確実に改善できる。   According to the present invention, in a conventionally known vegetable particle and / or fruit juice-containing liquid seasoning using soy sauce and 5′-nucleotide, the composition of the 5′-nucleotide at the time of eating is completely the same, even though the ingredients are completely the same. The flavor of umami and vegetable particles (for example, grated radish) and / or fruit juice can be reliably improved.

野菜粒子及び/又は果汁含有液状調味料に使用される原料としては、生醤油、5’−ヌクレオチド、及び野菜粒子及び/又は果汁の他、以下の一種又は二種以上が挙げられる。
(1)砂糖、乳糖、グラニュー糖、麦芽糖、ブドウ糖、果糖、液糖、水飴、デキストリン、異性化糖などの糖類
(2)ソルビトール、マルチトールなどの糖アルコール類
(3)清酒、ワイン、みりん、酒精含有甘味調味料(みりん風調味料)などの酒類
(4)サッカリン、グリチルリチン、ステビオサイド、アスパラテームなどの甘味料類
(5)ガーリック、オニオン、オレガノ、タイム、セージ、ジンジャー、レッドペパー、オールスパイス、クローブ、ナツメグ、カルダモンなどの香辛料類
(6)味噌、豆板醤などの味噌類
(7)魚醤、小麦グルテン分解物などのうまみ調味料
(8)酸味調味料
(9)食酢、醸造酢
(10)乳酸、クエン酸などの有機酸
(11)発酵調味料
(12)海草(コンブ)、茸(シイタケ)の抽出だし汁
(13)鰹節、鯖節などの魚節類、魚介類、野菜類のエキス、ビーフエキスなどのエキス類、蛋白加水分解物
(14)グルタミン酸ナトリウム、グリシンなどのアミノ酸
(15)香料
(16)着色料
As a raw material used for vegetable particle and / or fruit juice containing liquid seasoning, the following 1 type, or 2 or more types other than raw soy sauce, 5'-nucleotide, and vegetable particle and / or fruit juice are mentioned.
(1) Sugar, lactose, granulated sugar, maltose, glucose, fructose, liquid sugar, starch syrup, dextrin, sugars such as isomerized sugar (2) Sugar alcohols such as sorbitol, maltitol (3) Sake, wine, mirin, Alcoholic beverages such as alcoholic condiments (Mirin-style seasonings) (4) Sweeteners such as saccharin, glycyrrhizin, stevioside, aspartame (5) Garlic, onion, oregano, thyme, sage, ginger, red pepper, allspice , Cloves, nutmeg, cardamom, etc. (6) miso, miso, soy sauce, etc. (7) umami seasonings, such as fish soy, wheat gluten decomposition products (8) sour seasoning (9) vinegar, brewed vinegar ( 10) Organic acids such as lactic acid and citric acid (11) Fermented seasoning (12) Seaweed (comb), extract of shiitake mushroom 13) dried bonito, fish clause such as mackerel clause, seafood, extracts of vegetables, extracts such as beef extract, protein hydrolyzate (14) sodium glutamate, amino acids such as glycine (15) Perfume (16) coloring

生醤油としては、通常の濃口醤油、淡口醤油、溜醤油、又は白醤油など各種醤油の醸造法にしたがって得られた熟成諸味を圧搾し得られた清澄な液体で、微生物に由来し醤油醸造に関与した各種酵素が残存したもの、すなわち酵素ホスファターゼも残存しているものが挙げられる。該生醤油は、必要によりフィルター等で酵母等の微生物を除いたものを使用することができる。   As raw soy sauce, it is a clear liquid obtained by squeezing ripening moromi obtained according to various soy sauce brewing methods such as normal soy sauce, light soy sauce, tame soy sauce, white soy sauce, etc. Examples include those in which various enzymes involved remain, that is, in which the enzyme phosphatase also remains. The raw soy sauce can be used after removing microorganisms such as yeast with a filter or the like if necessary.

野菜粒子は、大根、たまねぎ、長ネギ、ニンジン、生姜、ニンニク、ピーマン、トマト、コーン、竹の子、シソ、パセリ、セロリ、ニラ、ミツバなどを、フードカッターやダイサーなどで1.0〜7.0cm程度までカットしたもの、あるいはこれらを更に高速粉砕機などで、網目が0.5〜5.0mmのスクリーンを用いて粉砕した粒径0.1〜3.0mmのもの、またはすりおろし機などで得られたおろしなどが挙げられる。   Vegetable particles include radish, onion, long onion, carrot, ginger, garlic, pepper, tomato, corn, bamboo shoot, perilla, parsley, celery, leek, honey, etc., about 1.0-7.0 cm with a food cutter or dicer. Obtained with a high-speed pulverizer or the like and pulverized with a screen having a mesh size of 0.5 to 5.0 mm, or with a grate For example.

野菜粒子としては、果実を、上述の野菜と同様に粒子状にカットあるいはすりおろし機で粒子状に加工した果実粒子を用いてもよい。果実としてはリンゴ、ナシ、キウイ、パイナップル、ユズ、スダチ、カボス、レモンなどが挙げられる。本発明で野菜粒子とは、上記野菜粒子又は果実粒子を意味する。   As a vegetable particle, you may use the fruit particle which cut the fruit into the particle shape like the above-mentioned vegetable, or processed it into the particle shape with the grate machine. Examples of fruits include apples, pears, kiwis, pineapples, yuzu, sudachi, kabosu, and lemon. In the present invention, vegetable particles mean the vegetable particles or fruit particles.

本発明の生野菜、果実は、加工食品原料として市販されている冷凍の野菜、果実を含むものである。   The raw vegetables and fruits of the present invention include frozen vegetables and fruits that are commercially available as processed food ingredients.

果汁としては、上記果実の搾汁液が挙げられ、このうちレモン、柚子、酢橘、カボスなどの柑橘果汁が好ましい。   Examples of fruit juice include juices of the above-mentioned fruits, and among these, citrus fruit juices such as lemon, eggplant, vinegar, and kabosu are preferred.

5’−ヌクレオチドとしては、グアニル酸ナトリウム、イノシン酸ナトリウム、リボヌクレオタイドナトリウム、又はこれを含有する酵母エキス、鰹節エキス、椎茸エキス等が挙げられる。   Examples of the 5'-nucleotide include sodium guanylate, sodium inosinate, sodium ribonucleotide, or yeast extract, bonito extract, shiitake extract and the like containing the same.

本発明を実施するには、生醤油を、先ず、野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し、5‘−ヌクレオチドを除く)と混和したものを、品温80〜90℃で、達温〜30分加熱し、そのまま次の工程に移行する。また、この工程は、生醤油に乾燥野菜、糖類、酸味料などを混和した後、品温80〜90℃で、達温〜30分加熱処理を行い、次の工程に移行してもよい。
この加熱処理によって、生醤油に含まれる微生物に由来し醤油醸造に関与した各種酵素、及び酵素ホスファターゼを失活させることができるが、加熱処理の条件によっては、醤油特有の香気や風味成分の生成を促進することから、生野菜の新鮮な風味を弱める原因となる。しかしながら、品温を80〜90℃とすることによって、生野菜及び/又は果汁の新鮮な風味を強く維持することができる。
In order to carry out the present invention, raw soy sauce is first mixed with a part of raw materials used for vegetable seasoning and / or fruit juice-containing liquid seasoning (excluding 5′-nucleotide). Heat at 80 to 90 ° C. for 30 to 30 minutes, and proceed to the next step as it is. Moreover, after mixing dried vegetables, saccharides, a sour agent, etc. with raw soy sauce, this process may heat-process for 30 to 30 minutes at the product temperature of 80-90 degreeC, and you may transfer to the following process.
This heat treatment can inactivate enzymes and phosphatases that are derived from microorganisms contained in raw soy sauce and participate in soy sauce brewing, but depending on the conditions of heat treatment, generation of flavor and flavor components peculiar to soy sauce This will cause the fresh flavor of raw vegetables to weaken. However, the fresh flavor of raw vegetables and / or fruit juice can be strongly maintained by setting the product temperature to 80 to 90 ° C.

品温80〜90℃で、達温〜30分加熱することは、重要であって、品温が90℃よりも高すぎるときは(例えば、115℃、5秒間加熱するときは、表2の結果からも判るように)、醤油特有の香りなどが引き立つために、野菜粒子(例えばおろし大根)及び/又は果汁の風味を顕著に改善できない。反対に80℃より低すぎるときは酵素ホスファターゼの失活が十分に行われなくなり、5’−ヌクレオチドが分解され、風味の改善効果が低減するので好ましくない。
上記加熱は、(80℃、10〜30分)、(85℃、達温〜5分)、(90℃、達温)が好ましい。
It is important that the product temperature is 80 to 90 ° C. and the final temperature to 30 minutes is heated. When the product temperature is too higher than 90 ° C. (for example, when heating at 115 ° C. for 5 seconds, As can be seen from the results, the flavor of soy sauce is enhanced, so that the flavor of vegetable particles (eg, grated radish) and / or fruit juice cannot be significantly improved. On the contrary, when the temperature is lower than 80 ° C., the enzyme phosphatase is not sufficiently inactivated, and the 5′-nucleotide is decomposed to reduce the flavor improving effect, which is not preferable.
The heating is preferably (80 ° C., 10 to 30 minutes), (85 ° C., reaching temperature to 5 minutes), or (90 ° C., reaching temperature).

上記したように生醤油に対して野菜粒子及び/又は果汁含有液状調味料に使用原料の一部を混和し、品温80〜90℃で達温〜30分加熱する際に、5‘−ヌクレオチドは添加しないことは重要である。すなわち、5’−ヌクレオチドを添加した場合は、該5’−ヌクレオチドは、生醤油に含まれるホスファターゼによって、速やかに分解され、呈味性がなくなる欠点を招来する。   As described above, a part of the raw materials used is mixed with fresh soy sauce in a vegetable particle and / or fruit juice-containing liquid seasoning and heated at a product temperature of 80 to 90 ° C. for 30 minutes to reach 5′-nucleotide. It is important not to add. That is, when 5'-nucleotide is added, the 5'-nucleotide is rapidly degraded by phosphatase contained in the raw soy sauce, resulting in a disadvantage that the taste is lost.

生醤油に添加される原料の一部としては、加熱によって品質が損なわれない原料が好ましく、例えば乾燥した粒状野菜、又は糖類が好ましい。乾燥粒状野菜を加熱前の生醤油に添加することは重要であって、生醤油と混和後加熱されると、乾燥粒状野菜は、生醤油を吸水膨潤し、具材感が向上し、また乾燥野菜からの味が調味料全体に滲出して、該調味料の風味が向上するので好ましい。また、糖類は醤油と反応し、調味料全体のコクが深まるので好ましい。なお、生醤油を加熱した後に乾燥粒状野菜を添加した場合は、加熱不十分で十分に給水膨潤しないために食感が悪くなるので好ましくない。   As a part of the raw material added to raw soy sauce, a raw material whose quality is not impaired by heating is preferable, for example, dried granular vegetables or sugars are preferable. It is important to add dried granular vegetables to the raw soy sauce before heating. When mixed with raw soy sauce and heated, the dried granular vegetables will absorb and swell the raw soy sauce, improve the texture, and dry The taste from vegetables exudes to the whole seasoning and the flavor of the seasoning is improved, which is preferable. Saccharides are preferable because they react with soy sauce and the richness of the whole seasoning is deepened. In addition, when dry granular vegetables are added after heating raw soy sauce, since a food texture worsens because it is not heated enough and does not swell sufficiently, it is not preferable.

品温80〜90℃で、達温〜30分加熱した後は、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと野菜粒子及び/又は果汁含有液状調味料に使用予定原料の残部とを混合する。   After heating at a product temperature of 80-90 ° C. for 30-30 minutes, the remaining raw material particles and / or fruit juice, 5′-nucleotide, vegetable particles and / or fruit juice-containing liquid seasoning And mix.

生野菜粒子は、加熱によって組織が軟化し易い欠点を有する。また果汁は、風味が消失し易い欠点を有する。したがって、前述したように品温80〜90℃で、達温〜30分加熱した後で添加する。また5’−ヌクレオチドは、ホスファターゼによって分解消失する危険性があるので、品温80〜90℃で、達温〜30分加熱した後に使用する。   Raw vegetable particles have the disadvantage that the tissue tends to soften by heating. Moreover, fruit juice has the fault which a flavor lose | disappears easily. Therefore, as described above, the product is heated at a product temperature of 80 to 90 ° C. and then heated for 30 minutes, and then added. In addition, 5'-nucleotide is used after heating at a product temperature of 80 to 90 ° C for 30 minutes because of the risk of degradation by phosphatase.

本発明は、ぽん酢、おろしだれ、焼肉のたれなど従来公知の調味料のレシピー(原料配合)をそのまま変えることなく、野菜粒子(例えばおろしにんにくやおろし大根)及び/又は果汁の風味を確実に改善できる。   The present invention can reliably improve the flavor of vegetable particles (for example, grated garlic or grated radish) and / or fruit juice without changing the recipes (mixtures of ingredients) of conventional well-known seasonings such as vinegar, grated soup and grilled meat. .

本発明では、生醤油を野菜粒子及び/又は果汁含有液体調味料に使用する原料の一部(但し、5‘−ヌクレオチドは除く)と混和したものを、品温80〜90℃で加熱した後、生野菜粒子及び/又は果汁、5’−ヌクレオチド及び該野菜粒子含有液状調味料に使用する原料の残部と混和した後、加熱殺菌を行う。
加熱は、従来公知の手段が採用可能で、加熱媒体が通流するジャケット付き調合タンク、チューブヒーター、プレートヒーター等の間接加熱装置により、品温60〜75℃、5〜20分間、加熱し製品とする。
In the present invention, raw soy sauce mixed with a part of raw materials used for vegetable particles and / or fruit juice-containing liquid seasoning (except 5′-nucleotide) is heated at a product temperature of 80 to 90 ° C. After mixing with raw vegetable particles and / or fruit juice, 5′-nucleotide and the remainder of the raw material used for the vegetable particle-containing liquid seasoning, heat sterilization is performed.
Conventionally known means can be used for the heating, and the product is heated for 60 to 75 ° C. for 5 to 20 minutes by an indirect heating device such as a jacketed preparation tank through which a heating medium flows, a tube heater, a plate heater or the like. And

本発明において5’−ヌクレオチド及び野菜粒子及び/又は果汁を添加後、加熱の際に品温を60〜75℃、5〜30分加熱処理することは重要であって、表3に示すように、75℃を超える温度では野菜粒子の組織が軟化し、野菜が煮えたような風味となるため好ましくない。また果汁の風味も消失する。反対に60℃未満では原料由来の微生物を殺菌することができないため保存安定性が悪くなるので好ましくない。加熱は、(60℃で20〜30分)、(65℃で10〜20分)、(70℃で、達温〜10分)、(75℃で達温〜5分)が好ましい。   In the present invention, after adding 5′-nucleotide and vegetable particles and / or fruit juice, it is important to heat-treat the product temperature at 60 to 75 ° C. for 5 to 30 minutes, as shown in Table 3. When the temperature exceeds 75 ° C., the structure of the vegetable particles softens, and the vegetable has a boiled flavor. In addition, the flavor of the fruit juice disappears. On the other hand, when the temperature is lower than 60 ° C., the microorganisms derived from the raw materials cannot be sterilized, so that the storage stability is deteriorated. The heating is preferably (at 60 ° C. for 20 to 30 minutes), (at 65 ° C. for 10 to 20 minutes), (at 70 ° C., reaching temperature for 10 minutes), or (at 75 ° C. for reaching temperature to 5 minutes).

本発明で得られる野菜粒子及び/又は果汁含有液状調味料としては、ぽん酢、おろしだれ又は焼肉のたれ等が挙げられる。   Examples of the vegetable particles and / or fruit juice-containing liquid seasoning obtained in the present invention include ponzu, grated soup, or grilled meat.

本発明によれば、従来の火入れ醤油を利用した野菜粒子及び/又は果汁含有液状調味料と対比して、原料配合が全く同一であるにも拘らず使用した野菜(例えばおろしにんにくやおろし大根)及び/又は果汁の風味を明確に改善し、しかもそれを長期保持できる野菜粒子及び/又は果汁含有液状調味料を得ることができる。   According to the present invention, in contrast to vegetable particles and / or fruit juice-containing liquid seasonings using conventional fired soy sauce, vegetables used in spite of the same raw material composition (for example, grated garlic and grated radish) and It is possible to obtain vegetable particles and / or fruit juice-containing liquid seasonings that can clearly improve the flavor of fruit juice and can maintain it for a long time.

生醤油(醤油醪を圧搾して得た各種酵素が残存している醤油)(サンプル)の製造例
蒸煮変性した脱脂大豆と炒熬割砕した小麦とを等量混合し、これに種麹を接種し、42時間通風製麹して醤油麹を得、これを高濃度食塩水に仕込み、25〜30℃で、適宜撹拌しながら、180日間常法通りの諸味管理を行ない、発酵熟成させた後、
圧搾濾過して食塩約18%(w/v)、水溶性総窒素(T.N.)約1.7%(w/v)の生醤油(醤油醪を圧搾して得た各種酵素が残存している醤油)(実施例1〜6で使用する生醤油)を得た。
Example of production of raw soy sauce (soy sauce in which various enzymes obtained by squeezing soy sauce lees remain) (sample) Mix equal amounts of steamed denatured defatted soybeans and fried rice crackers, and seed seeds Inoculated and ventilated for 42 hours to obtain soy sauce cake, which was charged into high-concentration saline, and was properly agitated at 25-30 ° C. for 180 days, followed by aging and fermenting. rear,
Fresh soy sauce (soy sauce cake is squeezed with various enzymes remaining after pressing and filtering) about 18% (w / v) salt and about 1.7% (w / v) water-soluble total nitrogen (TN) Soy sauce) (raw soy sauce used in Examples 1 to 6).

火入醤油(サンプル)の製造例
前記生醤油を、プレートヒーターにて105℃、60秒処理した後、30℃まで冷却して、その後4日間室温で静置して、オリ引きし、その後清澄部分を分離して、対照の火入醤油(実施例3〜6で使用する火入醤油)を得た。
Production example of fired soy sauce (sample) The raw soy sauce was treated with a plate heater at 105 ° C. for 60 seconds, then cooled to 30 ° C., then allowed to stand at room temperature for 4 days, and then pulled, then clarified. A portion was separated to obtain a control fired soy sauce (fired soy sauce used in Examples 3 to 6).

(本発明の野菜おろし含有液状調味料の製造法)
下記表1の配合割合にて、生醤油と乾燥たまねぎ粒子を混合したものを品温85℃達温加熱後室温まで冷却し、これに白ねぎ、大根おろし、生姜おろし、イノシン酸ナトリウム及び水を混合溶解し、次いで70℃に達温加熱後、その温度でペットボトルに詰め本発明の野菜おろし含有液状調味料を得た。
(Production method of vegetable seasoning-containing liquid seasoning of the present invention)
The mixture of raw soy sauce and dried onion particles in the mixing ratio shown in Table 1 below is cooled to room temperature after heating to 85 ° C, and mixed with white onion, grated radish, grated ginger, sodium inosinate and water It melt | dissolved and heated up to 70 degreeC after that, and it packed in the PET bottle at the temperature, and obtained the vegetable seasoning containing liquid seasoning of this invention.

Figure 0005909079
Figure 0005909079

(比較例の野菜おろし含有液状調味料)
一方また、生醤油と乾燥たまねぎ粒子を混合したものを品温115℃、5秒加熱後室温まで冷却し、これに白ねぎ、大根おろし、生姜おろし、イノシン酸ナトリウム及び水を混合溶解し、次いで70℃に達温加熱後、その温度でペットボトルに詰め比較例の野菜おろし含有液状調味料を得た。
(The vegetable seasoning-containing liquid seasoning of the comparative example)
On the other hand, a mixture of raw soy sauce and dried onion particles is heated at a product temperature of 115 ° C. for 5 seconds and then cooled to room temperature, and then mixed with white onion, radish grated, ginger grated, sodium inosinate and water, and then 70 After heating to a temperature of 0 ° C., it was packed in a PET bottle at that temperature to obtain a vegetable seasoning-containing liquid seasoning as a comparative example.

官能試験
上記で得た2種類の野菜おろし含有液状調味料(サンプル)を試食して、サンプル間の白ねぎの味の強さについて、一対比較法(7点尺度)にて官能試験を実施した。すなわち、2つのサンプルについて、一方のサンプルを他方のサンプルと比較し、同程度を0、やや強いを1、強いを2、かなり強いを3、反対にやや弱いを−1、弱いを−2、かなり弱いを−3と評価した。また表中の評点は、それぞれ識別能力を有するパネル18名または6名の平均値を示す。そして検定の欄における記号*:危険率5%以下で有意差有り、**:危険率1%以下で有意差有りを意味する(実施例3〜5の官能試験もこの方法による)。
結果を表2に示す。
Sensory test The two types of vegetable grater-containing liquid seasonings (samples) obtained above were sampled, and the strength of the white onion taste between the samples was subjected to a sensory test by the paired comparison method (7-point scale). . That is, for two samples, one sample is compared with the other sample, the same degree is 0, slightly strong is 1, strong is 2, quite strong is 3, slightly weak is -1, weak is -2, A fairly weak value was evaluated as -3. The score in the table indicates the average value of 18 panelists or 6 panelists each having identification ability. The symbol * in the column of test means that there is a significant difference when the risk rate is 5% or less, and **: that there is a significant difference when the risk rate is 1% or less (the sensory tests of Examples 3 to 5 are also based on this method).
The results are shown in Table 2.

Figure 0005909079
Figure 0005909079

表2の結果から、生醤油と乾燥たまねぎ粒子を95℃を超える温度(115℃、5秒)で加熱した場合は、生醤油と乾燥たまねぎ粒を85℃達温加熱後、使用した場合に比べて、白ねぎの味を引き立たせる効果が、弱いことが判る。   From the results in Table 2, when raw soy sauce and dried onion particles were heated at a temperature exceeding 95 ° C. (115 ° C., 5 seconds), compared to the case where raw soy sauce and dried onion grains were heated to 85 ° C. and then used. It can be seen that the effect of enhancing the taste of white onion is weak.

5’−ヌクレオチド及び野菜粒子を添加後の加熱温度を変化させた場合の官能試験
表1の配合割合にて、生醤油と乾燥たまねぎ粒子を混合したものを品温85℃達温加熱後室温まで冷却し、これに白ねぎ、大根おろし、生姜おろし、イノシン酸ナトリウム及び水を混合溶解し、次いで60〜75℃に達温後10分間加熱処理した後、その温度でペットボトルに詰めたサンプルについて、生野菜の新鮮風味における官能試験を実施したところ、表3に示す結果を得た。
Sensory test when changing the heating temperature after adding 5'-nucleotide and vegetable particles In the blending ratio of Table 1, a mixture of raw soy sauce and dried onion particles was heated to a product temperature of 85 ° C and then heated to room temperature After cooling, white onion, radish grated, ginger grated, sodium inosinate and water mixed and dissolved, then heated to 60-75 ° C. and heated for 10 minutes, and then packed in a plastic bottle at that temperature, When the sensory test in the fresh flavor of raw vegetables was implemented, the result shown in Table 3 was obtained.

Figure 0005909079
Figure 0005909079

本発明において5’−ヌクレオチド及び野菜粒子及び/又は果汁を添加後、加熱の際に品温を60〜75℃で加熱処理することは重要であって、表3に示すように、75℃を超える温度では野菜粒子の組織が軟化し、野菜が煮えたような風味となるため好ましくないことが判る。また、50℃未満では、微生物学的安定性がなくなり、好ましくない。 In the present invention, after adding 5′-nucleotide and vegetable particles and / or fruit juice, it is important to heat-treat the product temperature at 60 to 75 ° C. at the time of heating. It can be seen that the temperature exceeding this is not preferable because the texture of the vegetable particles softens and the vegetable is boiled. Moreover, if it is less than 50 degreeC, microbiological stability will lose | disappear.

(醤油中に残存する酵素ホスファターゼの影響確認試験)
下記表4の配合割合にて、生醤油と乾燥たまねぎ粒子を混合したものを、表5記載の条件にて加熱後室温まで冷却し、これに白ねぎ、大根おろし、生姜おろし、イノシン酸ナトリウム、グアニル酸ナトリウム及び水を混合溶解し、次いで70℃達温加熱後、その温度でペットボトルに詰め野菜おろし含有液状調味料を得た。
(Effect confirmation test of enzyme phosphatase remaining in soy sauce)
A mixture of raw soy sauce and dried onion particles in the proportions shown in Table 4 below was heated to room temperature after heating under the conditions shown in Table 5, and then white onions, grated radish, grated ginger, sodium inosinate, guanyl Sodium acid and water were mixed and dissolved, and then heated to 70 ° C., and then packed in a PET bottle at that temperature to obtain a vegetable seasoning-containing liquid seasoning.

Figure 0005909079
Figure 0005909079

上記野菜おろし含有液状調味料を、調製直後及び30日経過後に、グアニル酸ナトリウムを分析した。また、白ねぎの新鮮な味の強さを評価した。結果を表5に示した。   The vegetable grated liquid seasoning was analyzed for sodium guanylate immediately after preparation and after 30 days. In addition, the strength of the fresh taste of white onion was evaluated. The results are shown in Table 5.

(グアニル酸ナトリウムの分析法)
各サンプルをNo.2のろ紙(東洋濾紙株式会社製)濾過したろ過液を0.45μmフィルター(東洋濾紙株式会社製)で不溶性固形物を除去した原液10μlをHPLC試料とした。
使用カラム:YMC Pack Polyamine II 4.6×250mm(株式会社ワイエムシイ製)
溶媒: リン酸カリウム:水:アセトトリルを2g:78ml:20mlの比で混合した溶液
流量:1.0ml/min
波長:254nm
(Analytical method of sodium guanylate)
Each sample was No. The filtrate obtained by removing the insoluble solid matter with a 0.45 μm filter (manufactured by Toyo Roshi Kaisha, Ltd.) from the filtrate obtained by filtering No. 2 filter paper (Toyo Roshi Kaisha, Ltd.) was used as an HPLC sample.
Column used: YMC Pack Polyamine II 4.6 × 250 mm (manufactured by YMC Co., Ltd.)
Solvent: potassium phosphate: water: acetotolyl mixed at a ratio of 2 g: 78 ml: 20 ml Flow rate: 1.0 ml / min
Wavelength: 254nm

Figure 0005909079
白ねぎの新鮮な味の評価:強い場合は○、弱い場合は×
Figure 0005909079
Evaluation of fresh taste of white leek: ○ for strong, x for weak

表5の結果から、生醤油と乾燥たまねぎ粒子を混合したものの加熱が、80℃未満では、野菜おろし含有液状調味料の5’−ヌクレオチド(グアニル酸ナトリウム)の一部が大きく分解消失するのを防止できないが、80℃以上では、著しく防止できることが判る。また、白ねぎの新鮮な味は、90℃以下で感じることができる。   From the results of Table 5, when heating of the mixture of raw soy sauce and dried onion particles is less than 80 ° C., a part of the 5′-nucleotide (sodium guanylate) of the vegetable grater-containing liquid seasoning is largely decomposed and lost. Although it cannot be prevented, it can be seen that it can be remarkably prevented at 80 ° C. or higher. Moreover, the fresh taste of white onion can be felt at 90 ° C. or lower.

ぽん酢の製造例   Ponzu production example

Figure 0005909079
Figure 0005909079

生醤油及びグルタミン酸ナトリウムを混和したものを、品温85℃で、1分加熱した後、室温まで冷却し、直ちに柚子果汁、5’−ヌクレオチド、砂糖、酵母エキス、醸造酢、食塩、及び水を混合溶解し、次いでこれを品温75℃で1分加熱し、そのままペットボトルに充填、密封し、40℃以下に急冷し、容器詰めぽん酢を得た。   A mixture of raw soy sauce and sodium glutamate is heated at a product temperature of 85 ° C. for 1 minute and then cooled to room temperature. Immediately after the coconut juice, 5′-nucleotide, sugar, yeast extract, brewed vinegar, salt and water are added. After mixing and dissolving, this was heated at a product temperature of 75 ° C. for 1 minute, filled in a PET bottle as it was, sealed, and rapidly cooled to 40 ° C. or lower to obtain a stuffed ponzu.

(対照のぽん酢の製造例)
比較のため、上記本発明の容器詰めぽん酢の製造法において生醤油に代えて、火入醤油を用いる以外は全く同様にして、対照の容器詰めぽん酢を得た。
(Manufacturing example of control vinegar)
For comparison, a control-filled ponzu vinegar was obtained in exactly the same manner as the above-described method for producing stuffed ponzu vinegar, except that fresh soy sauce was used instead of fresh soy sauce.

(官能試験)
このようにして得られた二種類のぽん酢について、官能試験を行った。
結果を表9に示す。
(Sensory test)
A sensory test was performed on the two types of ponzu thus obtained.
The results are shown in Table 9.

(おろしだれの製造例)   (Example of grated weeping)

Figure 0005909079
Figure 0005909079

生醤油及びグルタミン酸ナトリウムを混和したものを、品温90℃に達温加熱した後室温まで冷却し、これに、大根おろし、5’−ヌクレオチド(グアニル酸ナトリウム)、醸造酢、食塩、砂糖及び水を混合溶解し、次いでこれをチューブヒーターを用いて品温65℃で10分加熱し、その温度でペットボトルに充填、密封し、40℃以下に急冷し、本発明の容器詰めおろしだれ(野菜粒子含有液状調味料)を得た。   A mixture of fresh soy sauce and sodium glutamate is heated to a product temperature of 90 ° C. and then cooled to room temperature. Then, grated radish, 5′-nucleotide (sodium guanylate), brewed vinegar, salt, sugar and water. Mix and dissolve, then heat this using a tube heater at a product temperature of 65 ° C. for 10 minutes, fill in a PET bottle at that temperature, seal, quench rapidly to 40 ° C. Containing liquid seasoning).

(対照のおろしだれ)
比較のため、上記本発明のおろしだれの製造法において生醤油に代えて、火入醤油を用いる以外は全く同様にして、対照の容器詰めおろしだれを得た。
(Contrast grater)
For comparison, a control container-packed grated soup was obtained in exactly the same manner except that fired soy sauce was used instead of fresh soy sauce in the above-described method for producing grated soup.

(官能試験)
このようにして得られた二種類のおろしだれについて、官能試験を行った。
結果を表10に示す。
(Sensory test)
A sensory test was conducted on the two kinds of grated weeds thus obtained.
The results are shown in Table 10.

(焼肉のたれの製造例)   (Production example of grilled meat sauce)

Figure 0005909079
Figure 0005909079

生醤油、香辛料、及びぶどう糖果糖液糖を混和したものを、品温80℃で達温加熱した後室温まで冷却し、これに、香味野菜粒子(にんにくおろし、刻みネギ)、5’−ヌクレオチド(グアニル酸ナトリウム)、醸造酢、レモン果汁、砂糖、アミノ酸、及び水を混合溶解し、次いでこれを品温70℃で10分加熱し、その温度でペットボトルに充填、密封し、40℃以下に急冷し、本発明の焼肉のたれ(野菜粒子含有液状調味料)を得た。   A mixture of raw soy sauce, spices, and fructose fructose liquid sugar is heated to a product temperature of 80 ° C. and then cooled to room temperature. To this, flavored vegetable particles (garlic grated, chopped onion), 5′-nucleotide ( Sodium guanylate), brewed vinegar, lemon juice, sugar, amino acid, and water are mixed and dissolved, then heated at a product temperature of 70 ° C for 10 minutes, filled in a plastic bottle at that temperature, sealed, and kept at 40 ° C or lower The mixture was rapidly cooled to obtain a grilled meat sauce (vegetable particle-containing liquid seasoning) of the present invention.

(対照の焼肉のたれの製造例)
比較のため、上記本発明の焼肉のたれの製造法において生醤油に代えて、火入醤油を用いる以外は全く同様にして、対照の焼肉のたれを得た。
(Manufacturing example of control yakiniku sauce)
For comparison, a control yakiniku sauce was obtained in exactly the same manner as in the above-described method for producing yakiniku sauce according to the present invention except that fresh soy sauce was used instead of fresh soy sauce.

(官能試験)
このようにして得られた二種類の焼肉のたれについて、官能試験を行った。
結果を表11に示す。
(Sensory test)
A sensory test was performed on the two types of sausage of the yakiniku thus obtained.
The results are shown in Table 11.

Figure 0005909079
Figure 0005909079

Figure 0005909079
Figure 0005909079

Figure 0005909079
Figure 0005909079

表9、10及び11の結果から、火入醤油を用いた場合に比べて、生醤油を用いると、ぽん酢では、柑橘果汁の味が有意に強く感じる。おろしだれでは、大根おろしの味とサッパリした味が有意に強く感じる。焼肉のたれでは、香味野菜の味が有意に強く感じることが判る。   From the results of Tables 9, 10 and 11, when fresh soy sauce is used, the taste of citrus fruit juice is significantly stronger when using raw soy sauce than when using soy sauce. In grated dripping, the taste of radish and refreshing taste is significantly stronger. It can be seen that the taste of the flavored vegetables is significantly stronger in the yakiniku sauce.

Claims (7)

生醤油を、野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し5‘−ヌクレオチドを除く)と混和したものを、品温80〜90℃で加熱した後、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと、該調味料に使用される原料の残部とを混和し、次いで品温60〜75℃で加熱することを特徴とする野菜粒子及び/又は果汁含有液状調味料。 After mixing raw soy sauce with a part of the raw materials used for vegetable particles and / or fruit juice-containing liquid seasoning (excluding 5'-nucleotide) at a product temperature of 80-90 ° C, Vegetable particles and / or fruit juice and / or fruit juice , 5′-nucleotide and the remainder of the raw material used for the seasoning are mixed and then heated at a product temperature of 60 to 75 ° C. Fruit juice-containing liquid seasoning. 生醤油を、野菜粒子及び/又は果汁含有液状調味料に使用される原料の一部(但し5‘−ヌクレオチドを除く)と混和したものを、品温80〜90℃で加熱した後、これに生野菜粒子及び/又は果汁と、5’−ヌクレオチドと、該調味料に使用される原料の残部とを混和し、次いで品温60〜75℃で加熱することを特徴とする野菜粒子及び/又は果汁含有液状調味料の製造法。   After mixing raw soy sauce with a part of the raw materials used for vegetable particles and / or fruit juice-containing liquid seasoning (excluding 5'-nucleotide) at a product temperature of 80-90 ° C, Vegetable particles and / or fruit juice and / or fruit juice, 5′-nucleotide and the remainder of the raw material used for the seasoning are mixed and then heated at a product temperature of 60 to 75 ° C. A method for producing a fruit seasoning-containing liquid seasoning. 5’−ヌクレオチドが、5’−ヌクレオチドを含有する酵母エキス、鰹節エキス、椎茸エキスから選ばれる1種又は2種を含有する請求項2に記載の製造法。   The production method according to claim 2, wherein the 5'-nucleotide contains one or two selected from yeast extract, bonito extract and shiitake extract containing 5'-nucleotide. 野菜粒子が、乾燥香味野菜粒子である請求項2に記載の製造法。   The production method according to claim 2, wherein the vegetable particles are dried flavored vegetable particles. 乾燥香味野菜粒子が粒径1〜5mmの乾燥たまねぎ粒子である請求項4に記載の製造法。   The method according to claim 4, wherein the dried flavored vegetable particles are dried onion particles having a particle size of 1 to 5 mm. 野菜粒子及び/又は果汁含有液状調味料が、ぽん酢、おろしだれ、又は焼肉のたれである請求項1に記載の調味料。   The seasoning according to claim 1, wherein the vegetable seasoning and / or fruit juice-containing liquid seasoning is ponzu, grated soup, or yakiniku sauce. 野菜粒子及び/又は果汁含有液状調味料が、ぽん酢、おろしだれ、又は焼肉のたれである請求項2に記載の調味料の製造法。
The method for producing a seasoning according to claim 2, wherein the vegetable seasoning and / or fruit juice-containing liquid seasoning is ponzu, grated soup, or yakiniku sauce.
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