JP5945201B2 - Rust prevention coating method, new installation method and renovation method of parking facilities - Google Patents
Rust prevention coating method, new installation method and renovation method of parking facilities Download PDFInfo
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この発明は、防錆塗装方法、駐車設備の新設方法及び改修方法に関し、さらに詳しくは、耐食性及び密着性に優れた塗膜を安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる駐車設備の防錆塗装方法、新設方法及び改修方法に関する。 This invention relates to a method anticorrosive painting relates to new methods and refurbishment how the parking, more particularly, corrosion resistance and safety hygiene coating film having excellent adhesion and also excellent drying properties while achieving environmental conservation and anti-rust coating method of the parking facilities that can be formed by coating with a high workability relates to new methods and refurbishment how.
従来、立体駐車場等の駐車設備の補修や改修工事では、駐車設備の躯体、特に自動車のタイヤが接する床面に腐食による発錆があり、他にも機械油やタイヤ艶だし剤のシリコーン化合物等が付着しているため、付着性や成膜性に優れた有機溶剤系塗料で仕上げられてきた。このような有機溶剤系塗料で駐車設備の補修等を行う技術として例えば特許文献1が挙げられる。具体的には、特許文献1には「有機溶剤を含有するエポキシ樹脂系防錆塗料である『サビタイト(商品名、大同塗料株式会社)』をタイヤスペース鋼鈑床面に塗布する防錆方法」が記載されている(0019欄及び0020欄等)。 Conventionally, parking facilities such as multistory parking lots have been repaired and refurbished, and there has been rusting due to corrosion on the housing of the parking facilities, especially on the floor surface where automobile tires come into contact. In addition, mechanical oils and tire polish silicone compounds Has been finished with an organic solvent-based paint having excellent adhesion and film-forming properties. As a technique for repairing a parking facility with such an organic solvent-based paint, for example, Patent Document 1 is cited. Specifically, Patent Document 1 discloses a “rust prevention method for applying“ Sabitite (trade name, Daido Paint Co., Ltd.) ”, an epoxy resin-based anticorrosion paint containing an organic solvent, to a tire space steel floor. Are described (columns 0019 and 0020, etc.).
このような有機溶剤系塗料中には、トルエン等の芳香族系溶剤、酢酸ブチル等のエステル系溶剤、ブタノール等のアルコール系溶剤、メチルエチルケトン等のケトン系溶剤、エチレングリコールモノブチルエーテル等のグリコールエーテル系溶剤、シクロヘキサノン等の脂環式炭化水素系溶剤、他に脂肪族及び芳香族炭化水素の混合物等が含有されている。これらの有機溶剤の多くは、労働安全衛生法の有機溶剤中毒予防規則に該当するものであり、施工中の作業者への曝露による健康被害が懸念される。また、有機溶剤の多くは、揮発性有機化合物であり、大気中に放出された後、窒素酸化物とともに太陽光からの紫外線の作用を受けて、有害な光化学オキシダントを生成するほか、粒子化して浮遊粒子状物質にも変化するため、大気汚染の悪化が懸念される。そして、駐車設備の多くは、市街地に設置されており、補修及び改修工事で有機溶剤系塗料が施工された場合には、有機溶剤の刺激臭や悪臭が周辺に放出され、通行人や近隣住民の体調を悪化させる危険性があり、また、飲食店等では食欲の低下等を起こす懸念もある。このように従来の有機溶剤系塗料を駐車設備に利用するに当たっては、施工中や施工後に発生する臭気等による安全衛生面及び施工中や施工後に揮発する有機溶剤による環境保全に解決すべき課題があった。 In such organic solvent paints, aromatic solvents such as toluene, ester solvents such as butyl acetate, alcohol solvents such as butanol, ketone solvents such as methyl ethyl ketone, glycol ethers such as ethylene glycol monobutyl ether It contains a solvent, a cycloaliphatic hydrocarbon solvent such as cyclohexanone, and a mixture of aliphatic and aromatic hydrocarbons. Many of these organic solvents fall under the Occupational Safety and Health Act's organic solvent poisoning prevention regulations, and there are concerns about health hazards due to exposure to workers during construction. In addition, most organic solvents are volatile organic compounds that, after being released into the atmosphere, are subjected to the action of ultraviolet rays from sunlight together with nitrogen oxides to produce harmful photochemical oxidants, which are then granulated. Since it changes to suspended particulate matter, air pollution is a concern. Many parking facilities are installed in urban areas, and when organic solvent-based paints are applied for repairs and repairs, the irritating odors and odors of organic solvents are released to the surrounding area, and passersby and neighbors In addition, there is a concern that the appetite may be deteriorated in restaurants and the like. As described above, when using conventional organic solvent-based paints for parking facilities, there are issues to be solved in terms of safety and hygiene due to odors etc. generated during and after construction and environmental conservation due to organic solvents that volatilize during and after construction. there were.
また、別の視点からみると、駐車設備は場合によっては街中では風通しの悪い状態に設置されるため塗布する(常乾)塗料の乾燥性及び作業性も要求されることがある。 From another point of view, in some cases, parking facilities are installed in poorly ventilated areas in the city, so that drying (operating dry) paint and workability may be required.
この発明は、耐食性及び密着性に優れた塗膜を、安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる駐車設備の防錆塗装方法、新設方法及び改修方法を提供すること、を目的とする。 The present invention provides a rust-proof coating method, a new installation method, and a renovation of a parking facility capable of coating and forming a coating film excellent in corrosion resistance and adhesion with excellent drying and high workability while achieving safety and hygiene and environmental conservation. It aims to provide a method.
この発明の発明者らは、前記課題を解決するために種々検討を行った結果、有機溶剤系塗料の組成等を改良しても、また有機溶剤系塗料を無溶剤系塗料に代替しても前記課題を一挙に解決するには至らなかったものの、有機溶剤系塗料を水系防錆塗料に代替すると、作業者や近隣住民への悪影響を大幅に低減できるうえ大気汚染防止にも極めて有用で安全衛生面及び環境保全の問題を解決できると共に優れた乾燥性及び高い作業性で耐食性に優れた塗膜を躯体に塗布形成でき、前記課題を解決できることを見出した。 As a result of various studies to solve the above problems, the inventors of the present invention have improved the composition of the organic solvent-based paint, or replaced the organic solvent-based paint with a solvent-free paint. Although the above problems could not be solved at once, replacing organic solvent-based paints with water-based anti-corrosion paints can greatly reduce the adverse effects on workers and neighboring residents, and is extremely useful and safe for preventing air pollution. It was found that a coating film excellent in corrosion resistance with excellent drying properties and high workability can be applied and formed on the housing, as well as solving the problems of hygiene and environmental conservation, and the above problems can be solved.
すなわち、前記課題を解決するための第1の手段として、
請求項1は、駐車設備の躯体に、耐食性に優れる水系防錆塗料を塗布し乾燥する前に、メラミン系樹脂の多孔質体を用いる脱脂処理又はメラミン系樹脂の多孔質体で研摩する研磨処理を行うことを特徴とする駐車設備の防錆塗装方法であり、
請求項2は、前記水系防錆塗料は、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂及びシリコーン系樹脂からなる群より選択される少なくとも1種の樹脂と防錆剤とを含有することを特徴とする請求項1に記載の駐車設備の防錆塗装方法であり、
請求項3は、前記水系防錆塗料は、1液型塗料又は2液型塗料であることを特徴とする請求項1又は2に記載の駐車設備の防錆塗装方法であり、
請求項4は、前記躯体に塗布された前記水系防錆塗料の上に上塗水系塗料を塗布し乾燥することを特徴とする請求項1〜3のいずれか1項に記載の駐車設備の防錆塗装方法であり、
請求項5は、前記上塗水系塗料は、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂、シリコーン系樹脂及びフッ素系樹脂からなる群より選択される少なくとも1種の樹脂と顔料とを含有することを特徴とする請求項4に記載の駐車設備の防錆塗装方法である。
請求項6は、前記躯体に前記水系防錆塗料を塗布する前に水系ジンクリッチ塗料を塗布して乾燥し、前記躯体に塗布された前記水系防錆塗料の上に前記フッ素系樹脂及び前記顔料を含有する前記上塗水系塗料を塗布し乾燥することを特徴とする請求項5に記載の駐車設備の防錆塗装方法であり、
請求項7は、前記上塗水系塗料は、1液型塗料又は2液型塗料であることを特徴とする請求項4〜6のいずれか1項に記載の駐車設備の防錆塗装方法である。
That is, as a first means for solving the above problems,
Claim 1 is a degreasing treatment using a porous body of melamine resin or a polishing process for polishing with a porous body of melamine resin before applying a water-based anticorrosive paint having excellent corrosion resistance to a housing of a parking facility and drying it. It is a rust-proof coating method for parking equipment, characterized by
According to a second aspect of the present invention, the water-based anticorrosive paint contains at least one resin selected from the group consisting of acrylic resins, urethane resins, epoxy resins, vinyl resins, and silicone resins and an antirust agent. It is a rust preventive coating method for parking equipment according to claim 1,
Claim 3 is the rust-proof coating method for parking equipment according to claim 1 or 2, wherein the water-based rust-proof paint is a one-component paint or a two-component paint.
4. A rust preventive for a parking facility according to any one of claims 1 to 3, wherein an overcoat water-based paint is applied on the water-based anticorrosive paint applied to the housing and dried. Painting method,
According to a fifth aspect of the present invention, the overcoating water-based paint comprises at least one resin selected from the group consisting of an acrylic resin, a urethane resin, an epoxy resin, a vinyl resin, a silicone resin, and a fluorine resin, and a pigment. It contains, It is a rust prevention coating method of the parking equipment of Claim 4 characterized by the above-mentioned.
6. The method according to claim 6, wherein before applying the water-based anticorrosive paint to the casing, the water-based zinc rich paint is applied and dried, and the fluororesin and the pigment are formed on the water-based anticorrosive paint applied to the casing. It is a rust preventive coating method for a parking facility according to claim 5, characterized in that the topcoat water-based paint containing
A seventh aspect of the present invention is the rust-proof coating method for a parking facility according to any one of claims 4 to 6, wherein the topcoat water-based paint is a one-component paint or a two-component paint.
また、前記課題を解決するための第2の手段として、
請求項8は、前記躯体を組み立てた後に、請求項1〜7のいずれか1項に記載の駐車設備の防錆塗装方法によって前記躯体に前記水系防錆塗料を塗布し乾燥することを特徴とする駐車設備の新設方法であり、
請求項9は、既存の駐車設備の躯体に請求項1〜7のいずれか1項に記載の駐車設備の防錆塗装方法によって前記水系防錆塗料を塗布し乾燥することを特徴とする駐車設備の改修方法であり、
請求項10は、前記水系防錆塗料の塗布前に前記躯体を前処理(前記脱脂処理及び前記研磨処理を除く。)することを特徴とする請求項9に記載の駐車設備の改修方法である。
In addition, as a second means for solving the above problem,
Claim 8 is characterized in that after assembling the casing, the water-based anticorrosive paint is applied to the casing and dried by the antirust coating method for a parking facility according to any one of claims 1 to 7. is a new way of parking facilities to be,
Claim 9 applies the water-based anti-corrosion paint to the frame of an existing parking facility according to any one of claims 1 to 7 and dries it, and then dries the parking facility. Renovation method,
10. The method for repairing a parking facility according to claim 9 , wherein the casing is pretreated (except for the degreasing treatment and the polishing treatment) before the application of the water-based anticorrosive paint . .
この発明に係る駐車設備の防錆塗装方法は駐車設備の躯体に耐食性を発揮する水系防錆塗料を塗布し乾燥することを特徴とするから、施工中又は施行後の作業者への有機溶剤の曝露を極めて低減することができ、また周辺環境に有機溶剤の刺激臭や悪臭を放散することも無く、さらに揮発性有機化合物の大気環境への放出を大幅に低減できることにより、安全衛生面及び環境保全を実現できる。また、この発明に係る駐車設備の防錆塗装方法は同様に前記水系防錆塗料を塗布し乾燥することを特徴とするから、優れた乾燥性及び高い作業性で耐食性に優れた塗膜を躯体に塗布形成できる。また、この発明に係る駐車設備の防錆塗装方法は、前記水系防錆塗料を塗布し乾燥する前に、メラミン系樹脂の多孔質体を用いる脱脂処理又はメラミン系樹脂の多孔質体で研摩する研磨処理を行うから、躯体表面に塗布された水系防錆塗料のはじき現象を防止して躯体表面に密着性の高い塗膜を形成することができる。したがって、この発明によれば、耐食性及び密着性に優れた塗膜を、安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる駐車設備の防錆塗装方法、新設方法及び改修方法を提供できる。 Since the rust-proof coating method for parking equipment according to this invention is characterized by applying and drying a water-based rust-proof paint that exhibits corrosion resistance on the housing of the parking equipment, the organic solvent to the worker during or after construction Safety and hygiene aspects and the environment can be reduced by significantly reducing exposure, without releasing irritating odors and odors of organic solvents in the surrounding environment, and by significantly reducing the release of volatile organic compounds to the atmosphere. Conservation can be realized. Moreover, since the antirust coating method for parking equipment according to the present invention is characterized in that the water-based anticorrosion paint is similarly applied and dried, a coating film excellent in corrosion resistance with excellent drying properties and high workability is provided as a casing. It can be applied and formed. Further, in the antirust coating method for parking equipment according to the present invention, before applying the water-based anticorrosive paint and drying, the degreasing treatment using the porous body of the melamine resin or the porous body of the melamine resin is polished. Since the polishing treatment is performed, it is possible to prevent the repelling phenomenon of the water-based anticorrosive paint applied to the surface of the housing and to form a highly adhesive coating on the surface of the housing. Therefore, according to the present invention, the anticorrosion coating method for a parking facility capable of coating and forming a coating film excellent in corrosion resistance and adhesion with excellent drying properties and high workability while achieving safety and hygiene and environmental conservation, New installation and renovation methods can be provided.
この発明は、駐車設備の躯体に耐食性を発揮する水系防錆塗料を塗布し乾燥することを特徴とする。ここで、駐車設備は、自動車を駐車させる設備であればよく、例えば、立体駐車場、平置き駐車場、地下駐車場、機械式駐車場等が挙げられる。この発明において水系防錆塗料が塗布される箇所(塗場とも称される。)は駐車設備の躯体のうち少なくとも自動車のタイヤが接する床面であればよく、それ以外の躯体の表面も含まれる。なお、この発明において、駐車設備の躯体は特に防錆が要求される鋼鈑で組み立てられているのがよい。 The present invention is characterized in that a water-based anticorrosive paint exhibiting corrosion resistance is applied to a housing of a parking facility and dried. Here, the parking facility may be a facility for parking a car, and examples thereof include a multilevel parking lot, a flat parking lot, an underground parking lot, and a mechanical parking lot. In the present invention, the location where the water-based anticorrosive paint is applied (also referred to as a coating site) may be at least the floor surface in contact with the vehicle tire among the parking equipment housings, and the surface of other housings is also included. . In addition, in this invention, it is good to assemble the frame of a parking facility with the steel plate in which especially rust prevention is requested | required.
駐車設備の躯体、特に使用されている駐車設備の躯体は、後述する水系防錆塗料を塗布する前に前処理されるのが、水系防錆塗料が硬化してなる塗膜が躯体表面に強固に付着する点で好ましい。前処理としては、躯体表面に付着している油分若しくはタイヤ艶出し剤のシリコーン成分等を水系洗浄剤で除去する脱脂処理、タイヤ艶出し剤のシリコーン等を旧塗膜の表面層と共に研磨除去する研摩処理、錆び及び剥離が発生している脆弱な旧塗膜や腐食生成物を動力工具等で除去する除去処理、錆び及び剥離の発生のない健全な旧塗膜表面を手工具や動力工具でサンディングするサンディング処理等が挙げられる。なお、旧塗装面が健全な状態にある場合には旧塗装面に後述する水系防錆塗料を塗布することができる。 Parking equipment housings, especially used parking equipment housings, are pre-treated before applying the water-based anti-corrosion paint described later, and the coating film formed by curing the water-based anti-corrosion paint is strong on the surface of the housing. It is preferable at the point which adheres to. As pre-treatment, degreasing treatment that removes the oil component adhering to the chassis surface or the silicone component of the tire polish with an aqueous cleaning agent, and the silicone of the tire polish with the surface layer of the old paint film are removed by polishing. Polishing treatment, removal treatment to remove fragile old paint film and corrosion products with rust and peeling with a power tool, etc., hand tool and power tool to remove a sound old paint film surface without rust and peeling. For example, sanding processing for sanding. In addition, when the old paint surface is in a healthy state, a water-based anticorrosive paint described later can be applied to the old paint surface.
ここで、研摩処理、除去処理及びサンディング処理は、下地の表面に数μmの傷を付けることを目的とするので、下地の目粗し処理と称されることがある。これらの処理は、それぞれ、定法に従って実施することができ、通常、駐車設備を改修する場合には実施され、新設する場合には実施されないこともある。これらの処理は、錆び及び剥離が発生している場合には塗装膜全体を除去するのがよい。 Here, the polishing process, the removal process, and the sanding process are sometimes referred to as a roughening process of the base because the purpose is to scratch the surface of the base by several μm. Each of these processes can be performed according to a regular method, and is usually performed when the parking facility is renovated, and may not be performed when a new facility is installed. In these treatments, the entire coating film is preferably removed when rusting and peeling occur.
このような前処理のうち、少なくともメラミン系樹脂の多孔質体を用いる脱脂処理及びメラミン系樹脂の多孔質体で研摩する研磨処理を行う。前処理としてこれらの脱脂処理又は研磨処理を選択すると、溶剤等が必要であっても水を前提とし、有機溶剤等は不要であるから高い安全衛生面及び環境保全を図ることができ、後述する水系防錆塗料による効果をより効果的なものとすることができる。また、これらの脱脂処理又は研磨処理を選択すると、エンジンオイル等の鉱物油に加えて通常除去しにくい躯体表面に付着したシリコーンオイル等も効果的に除去でき、躯体表面に塗布された水系防錆塗料のはじき現象を防止して躯体表面に付着性の高い塗膜を形成できる。 Among such pre-treatments , at least a degreasing treatment using a melamine-based resin porous body and a polishing process for polishing with the melamine-based resin porous body are performed . When these degreasing treatments or polishing treatments are selected as pretreatment, even if a solvent is required, water is premised and no organic solvent is required, so high safety and hygiene and environmental conservation can be achieved. The effect of the water-based rust preventive paint can be made more effective. Moreover, when these degreasing treatments or polishing treatments are selected, in addition to mineral oils such as engine oils, it is possible to effectively remove silicone oil and the like that are usually difficult to remove, and water-based anticorrosion applied to the surface of the housing. A paint film having high adhesion can be formed on the surface of the housing by preventing the repelling phenomenon of the paint.
これら脱脂処理又は研磨処理で用いるメラミン系樹脂の多孔質体は、メラミン系樹脂で多孔質構造に形成されている。メラミン系樹脂は、メラミン系化合物とホルムアルデヒドとを縮合重合して得られる樹脂であって、例えば、メラミンとホルムアルデヒドとを縮合重合して得られるメラミン樹脂、グアナミンとホルムアルデヒドとを縮合重合して得られるメラミン樹脂等が挙げられる。グアナミンは炭素数1〜6のアルキル基、置換基を有していてもよい芳香族基等を有していてもよい。 The porous body of the melamine resin used in the degreasing process or the polishing process is formed in a porous structure with the melamine resin. The melamine resin is a resin obtained by condensation polymerization of a melamine compound and formaldehyde. For example, it is obtained by condensation polymerization of melamine resin, guanamine and formaldehyde obtained by condensation polymerization of melamine and formaldehyde. A melamine resin etc. are mentioned. Guanamine may have an alkyl group having 1 to 6 carbon atoms, an aromatic group which may have a substituent, or the like.
多孔質体は、3次元網目状の多孔質構造を有しており、具体的には、メラミン系樹脂の繊維からなる網目骨格の多孔質構造、好ましくは前記繊維が鋭利な状態の多孔質構造を有している。このような多孔質構造を有していると、躯体表面に付着したシリコーンオイル等を効果的に除去できる。このような多孔質構造を有する多孔質体は、例えば、以下の特性等を有しているのが好ましい。 The porous body has a three-dimensional network-like porous structure. Specifically, the porous structure has a network skeleton composed of fibers of a melamine resin, preferably a porous structure in which the fibers are sharp. have. With such a porous structure, silicone oil and the like attached to the surface of the housing can be effectively removed. The porous body having such a porous structure preferably has, for example, the following characteristics.
3次元網目状の多孔質構造における骨格の断面形状が円形、楕円形又は多角形であるのが好ましく、楕円形又は多角形であるのが特に好ましい。3次元網目状の多孔質構造における骨格の太さは5〜10μmであるのが好ましく、多孔質体の孔径は30〜150μmであるのが好ましい。骨格の太さは多孔質体を電子顕微鏡で観察した写真から測定でき、孔径は多孔質体を電子顕微鏡で観察した写真から円相当径として測定できる。 The cross-sectional shape of the skeleton in the three-dimensional network-like porous structure is preferably a circle, an ellipse or a polygon, and particularly preferably an ellipse or a polygon. The thickness of the skeleton in the three-dimensional network porous structure is preferably 5 to 10 μm, and the pore diameter of the porous body is preferably 30 to 150 μm. The thickness of the skeleton can be measured from a photograph of the porous body observed with an electron microscope, and the pore diameter can be measured as a circle-equivalent diameter from a photograph of the porous body observed with an electron microscope.
多孔質体の気孔率は0.1%以上であるのが好ましく、多孔質体の密度は6〜50kg/m3であるのが好ましく、多孔質体の引張強度は50〜700kPaであるのが好ましく、多孔質体の破断伸びは0.1〜20N/cmであるのが好ましい。 The porosity of the porous body is preferably 0.1% or more, the density of the porous body is preferably 6 to 50 kg / m 3 , and the tensile strength of the porous body is 50 to 700 kPa. Preferably, the breaking elongation of the porous body is preferably 0.1 to 20 N / cm.
このように、多孔質体が前記断面形状及び/又は前記範囲の少なくとも1つの特性又は物性を有していると、躯体の表面に付着しているシリコーンオイル等を効果的に除去できるうえ、躯体の表面形状によく追従して平坦な表面だけでなく複雑な形状であってもシリコーンオイル等を除去できる。また、躯体の表面を下地目粗しもでき、水系防錆塗料の塗膜を躯体の表面に高い密着力で密着させることもできる。 As described above, when the porous body has at least one characteristic or physical property within the cross-sectional shape and / or the range, it is possible to effectively remove the silicone oil or the like adhering to the surface of the casing. Silicone oil and the like can be removed not only with a flat surface but also with a complicated shape by following the surface shape well. In addition, the surface of the housing can be roughened, and the coating film of the water-based anticorrosive paint can be adhered to the surface of the housing with high adhesion.
このようなメラミン系樹脂の多孔質体は、下記条件で製造することもでき、市販品、例えば、商品名「激落ち君」(レック株式会社製)、商品名「お掃除消しゴム」(アズマ工業株式会社製)等を使用することもできる。
<製造方法>
メラミン系化合物とホルムアルデヒドとをアルカリ条件下で縮合させたメチロールメラミンを加熱することにより、多孔質構造を有するメラミン系樹脂の多孔質体を製造できる。
Such a porous body of melamine-based resin can also be manufactured under the following conditions, and is a commercially available product, for example, the trade name “Kakiki-kun” (manufactured by Lec Co., Ltd.), the trade name “Cleaning Eraser” (Azuma Industry Etc.) can also be used.
<Manufacturing method>
By heating methylolmelamine obtained by condensing a melamine compound and formaldehyde under alkaline conditions, a porous body of a melamine resin having a porous structure can be produced.
前記水系防錆塗料は、耐食性に優れる塗料であって、少なくとも樹脂と防錆剤と水と所望により各種添加剤とを含有し、硬化すると耐食性等を発揮する塗膜を形成する。 The water-based anticorrosive paint is a paint excellent in corrosion resistance, and contains at least a resin, an antirust agent, water, and various additives as required, and forms a coating film that exhibits corrosion resistance and the like when cured.
ところで、立体駐車場等の駐車設備、特に自動車のタイヤが圧接する床面に形成される塗装には耐食性はもちろん自動車を駐車するうえでの特有の課題がある。例えば、塗膜が駐車設備の躯体表面に高い密着性で密着形成されタイヤに転着しない特性、すなわち塗膜の躯体への高い密着性が挙げられる。また立体駐車場等の駐車設備は通常屋外に露出した状態に設置されるため、塗膜の耐湿性及び耐候性も要求される。 By the way, parking facilities such as a multi-story parking lot, especially the coating formed on the floor surface where the tires of an automobile come into pressure contact have not only corrosion resistance but also a particular problem in parking the automobile. For example, the coating film is formed on the surface of the casing of the parking facility with high adhesion and does not transfer to the tire, that is, the coating film has high adhesion to the casing. In addition, since parking facilities such as a multi-story parking lot are usually installed in an exposed state outdoors, the coating film is also required to have moisture resistance and weather resistance.
この発明に係る水系防錆塗料において、水系防錆塗料に含有される樹脂としては、特に限定されないが、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂及びシリコーン系樹脂からなる群より選択される少なくとも1種の樹脂を含有しているのが好ましい。水系防錆塗料がこのような樹脂の少なくとも1種を含有していると、耐食性に加えて駐車設備に特有の課題を解決できる塗膜を形成でき、これらの樹脂は所望の特性、すなわち解決しようとする駐車設備に特有の課題に応じて適宜の樹脂が選択される。例えば、水系防錆塗料の塗膜に、耐食性に加えて躯体との高い密着性が特に要求される場合には少なくとも1種の前記樹脂が選択され、耐食性に加えて躯体とのより一層高い密着性が特に要求される場合にはエポキシ系樹脂が選択され、耐食性に加えて耐候性及び/又は耐湿性が特に要求される場合には前記群よりウレタン系やシリコーン系樹脂が選択される。 In the water-based anticorrosive paint according to the present invention, the resin contained in the water-based anticorrosive paint is not particularly limited, but from the group consisting of acrylic resin, urethane resin, epoxy resin, vinyl resin and silicone resin. It preferably contains at least one selected resin. If the water-based anti-corrosion paint contains at least one of these resins, it can form a coating film that can solve the problems specific to parking facilities in addition to corrosion resistance. Appropriate resin is selected according to the problem specific to the parking facility. For example, when the coating film of the water-based anti-corrosion paint requires particularly high adhesion to the housing in addition to corrosion resistance, at least one kind of the resin is selected, and even higher adhesion to the housing in addition to corrosion resistance Epoxy resins are selected when the properties are particularly required, and urethane and silicone resins are selected from the above group when weather resistance and / or moisture resistance is particularly required in addition to the corrosion resistance.
この発明に係る水系防錆塗料において、これらの樹脂は複数種含有されていてもよく、通常高分子量でエマルジョンタイプであるのが水によく分散するうえ強靭な塗膜が形成できる点で好ましい。 In the water-based anticorrosive paint according to the present invention, a plurality of these resins may be contained, and usually a high molecular weight emulsion type is preferable because it can be well dispersed in water and can form a tough coating film.
アクリル系樹脂は、(メタ)アクリルモノマーを構成単位とする樹脂であればよく、例えば、構成モノマーとして、(メタ)アクリル酸のアルキルエステルであるのが好ましく、このエステルにおけるアルキル基は炭素数1〜10が好ましく、1〜8が特に好ましい。このような構成モノマーとしては、例えば、(メタ)アクリル酸メチル、(メタ)アクリル酸エチル、(メタ)アクリル酸n−プロピル、(メタ)アクリル酸i−プロピル、(メタ)アクリル酸n−ブチル、(メタ)アクリル酸i−ブチル、(メタ)アクリル酸t−ブチル、(メタ)アクリル酸ヘキシル、(メタ)アクリル酸2−エチルヘキシル等の少なくとも1種を含有している。また、アクリル系樹脂は各種変性樹脂を用いることができる。このアクリル樹脂は水への分散性に優れる点でアクリルエマルジョンを使用することが好ましい。 The acrylic resin may be a resin having a (meth) acrylic monomer as a structural unit. For example, the structural monomer is preferably an alkyl ester of (meth) acrylic acid, and the alkyl group in this ester has 1 carbon atom. To 10 is preferable, and 1 to 8 is particularly preferable. Examples of such constituent monomers include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, i-propyl (meth) acrylate, and n-butyl (meth) acrylate. , (Meth) acrylic acid i-butyl, (meth) acrylic acid t-butyl, (meth) acrylic acid hexyl, (meth) acrylic acid 2-ethylhexyl, and the like. Various modified resins can be used as the acrylic resin. The acrylic resin is preferably an acrylic emulsion because of its excellent dispersibility in water.
ウレタン系樹脂は、ポリオール及びポリイソシアネートを構成単位とする樹脂であればよい。例えば、ポリオールは、ポリエステルポリオール、ポリエーテルポリオール、ポリカーボネートポリオール等の少なくとも1種を含有していればよく、ポリイソシアネートは脂肪族ポリイソシアネートが好ましく、例えば、ヘキサメチレンジイソシアネート、イソホロンジイソシアネート、ジシクロヘキシルメタンジイソシアネート、水添トリレンジイソシアネート、水添キシリレンジイソシアネート、水添メチレンジフェニルジイソシアネート等の少なくとも1種を含有している。また、ウレタン系樹脂は各種変性樹脂を用いることができる。このウレタン樹脂は水への分散性に優れる点でウレタンエマルジョンを使用することが好ましい。 The urethane-based resin may be a resin having polyol and polyisocyanate as structural units. For example, the polyol only needs to contain at least one of polyester polyol, polyether polyol, polycarbonate polyol, etc., and the polyisocyanate is preferably an aliphatic polyisocyanate, such as hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane diisocyanate, It contains at least one of hydrogenated tolylene diisocyanate, hydrogenated xylylene diisocyanate, hydrogenated methylene diphenyl diisocyanate and the like. Various modified resins can be used as the urethane resin. This urethane resin is preferably a urethane emulsion because of its excellent dispersibility in water.
エポキシ系樹脂は、エポキシ化合物を構成単位とする樹脂であればよく、例えば、構成モノマーとして、ビスフェノールAやビスフェノールF、ビスフェノールAD、ビスフェノールZ等の少なくとも1種とグリシジルエーテル類を反応させたものが好ましい。また、エポキシ系樹脂は各種変性樹脂を用いることができる。このエポキシ系樹脂は水への分散性に優れる点でエポキシエマルジョンを使用することが好ましい。 The epoxy resin may be a resin having an epoxy compound as a structural unit. For example, a resin obtained by reacting glycidyl ethers with at least one of bisphenol A, bisphenol F, bisphenol AD, bisphenol Z and the like as a constituent monomer. preferable. Various modified resins can be used as the epoxy resin. It is preferable to use an epoxy emulsion because this epoxy resin is excellent in water dispersibility.
ビニル系樹脂は、炭素−炭素不飽和結合を有する化合物((メタ)アクリルモノマー等の(メタ)アクリル系化合物を除く。)を構成単位とする樹脂であればよく、例えば、構成モノマーとして、塩化ビニル、酢酸ビニル、スチレン、アクリロニトリル等の少なくとも1種を含有している。また、ビニル系樹脂は各種変性樹脂を用いることができる。このビニル系樹脂は水への分散性に優れる点でビニル系エマルジョンを使用することが好ましい。 The vinyl resin only needs to be a resin having a structural unit of a compound having a carbon-carbon unsaturated bond (excluding (meth) acrylic compounds such as (meth) acrylic monomers). It contains at least one of vinyl, vinyl acetate, styrene, acrylonitrile and the like. Various modified resins can be used as the vinyl resin. The vinyl resin is preferably a vinyl emulsion because of its excellent dispersibility in water.
シリコーン系樹脂は、アルキルシリケートの部分加水分解縮合物あるいはその変性物が挙げられる。 Examples of the silicone resin include a partially hydrolyzed condensate of alkyl silicate or a modified product thereof.
このような部分加水分解縮合物として、例えば、一般式R1nSi(OR2)4−n
〔式中、R1は炭素数1〜8の有機基であり、R2は炭素数1〜5のアルキル基であり、nは0又は1である。〕で示されるアルキルシリケートの加水分解縮合物が好適に挙げられる。上記式において、R1としての有機基としては、例えば、アルキル基、シクロアルキル基、アリール基、ビニル基等が挙げられる。ここで、アルキル基としては、直鎖でも分岐したものでもよい。アルキル基としては、例えば、メチル基、エチル基、n−プロピル基、i−プロピル基、n−ブチル基、i−ブチル基、s−ブチル基、t−ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基等のアルキル基が挙げられる。好ましいアルキル基は炭素数が1〜4個のものである。シクロアルキル基としては、例えば、シクロヘキシル基、シクロヘプチル基、シクロオクチル基等が好適に挙げられる。アリール基としては、例えば、フェニル基、ナフチル基等が挙げられる。上記各官能基は任意に置換基を有してもよい。このような置換基としては、例えば、ハロゲン原子(例えば、塩素原子、臭素原子、フッ素原子等)、(メタ)アクリロイル基、アミノ基、メルカプト基、グリシドキシ基、エポキシ基、脂環式基等が挙げられる。R2としてのアルキル基としては直鎖でも分岐したものでもよい。このようなアルキル基としては、例えば、メチル基、エチル基、n−プロピル基、i−プロピル基、n−ブチル基、i−ブチル基、s−ブチル基、t−ブチル基、ペンチル基等が挙げられ、好ましいアルキル基は炭素数が1〜2個のものである。
As such a partial hydrolysis-condensation product, for example, the general formula R 1 nSi (OR 2 ) 4-n
[Wherein, R 1 is an organic group having 1 to 8 carbon atoms, R 2 is an alkyl group having 1 to 5 carbon atoms, and n is 0 or 1. Preferred examples thereof include hydrolysis condensates of alkyl silicates represented by the following formula: In the above formula, examples of the organic group as R 1 include an alkyl group, a cycloalkyl group, an aryl group, and a vinyl group. Here, the alkyl group may be linear or branched. Examples of the alkyl group include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, i-butyl group, s-butyl group, t-butyl group, pentyl group, hexyl group, heptyl. And alkyl groups such as an octyl group. Preferred alkyl groups are those having 1 to 4 carbon atoms. Preferred examples of the cycloalkyl group include a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, and the like. Examples of the aryl group include a phenyl group and a naphthyl group. Each of the above functional groups may optionally have a substituent. Examples of such substituents include halogen atoms (eg, chlorine atoms, bromine atoms, fluorine atoms, etc.), (meth) acryloyl groups, amino groups, mercapto groups, glycidoxy groups, epoxy groups, alicyclic groups, and the like. Can be mentioned. The alkyl group as R 2 may be linear or branched. Examples of such an alkyl group include a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, an i-butyl group, an s-butyl group, a t-butyl group, and a pentyl group. Preferred alkyl groups are those having 1 to 2 carbon atoms.
このようなアルキルシリケートの具体例としては、テトラメチルシリケート、テトラエチルシリケート、テトラ−n−プロピルシリケート、テトラ−i−プロピルシリケート、テトラ−n−ブチルシリケートなどのnが0の場合のアルキルシリケート;メチルトリメトキシシラン、メチルトリエトキシシラン、エチルトリメトキシシラン、エチルトリエトキシシラン、n−プロピルトリメトキシシラン、n−プロピルトリエトキシシラン、i−プロピルトリメトキシシラン、i−プロピルトリエトキシシラン、γ−グリシドキシプロピルトリメトキシシラン、γ−グリシドキシプロピルトリエトキシシラン、γ−メタクリルオキシプロピルトリメトキシシラン、γ−メタクリルオキシプロピルトリエトキシシラン、γ−メルカプトプロピルトリメトキシシラン、γ−メルカプトプロピルトリエトキシシラン、フェニルトリメトキシシラン、フェニルトリエトキシシラン、γ−アミノプロピルトリメトキシシラン、3,4−エポキシシクロヘキシルエチルトリメトキシシラン、3,4−エポキシシクロヘキシルエチルトリエトキシシランなどの、nが1の場合のアルキルシリケート等が挙げられる。これらは単独又は2種以上組み合わせて用いてもよい。またシリコーン系樹脂は各種変性樹脂を用いることができる。このシリコーン系樹脂は水への分散性に優れる点でシリコーン系エマルジョンを使用することが好ましい。 Specific examples of such alkyl silicates include alkyl silicates where n is 0, such as tetramethyl silicate, tetraethyl silicate, tetra-n-propyl silicate, tetra-i-propyl silicate, tetra-n-butyl silicate; Trimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, n-propyltrimethoxysilane, n-propyltriethoxysilane, i-propyltrimethoxysilane, i-propyltriethoxysilane, γ-glycine Sidoxypropyltrimethoxysilane, γ-glycidoxypropyltriethoxysilane, γ-methacryloxypropyltrimethoxysilane, γ-methacryloxypropyltriethoxysilane, γ-mercaptopropyltrime Toxisilane, γ-mercaptopropyltriethoxysilane, phenyltrimethoxysilane, phenyltriethoxysilane, γ-aminopropyltrimethoxysilane, 3,4-epoxycyclohexylethyltrimethoxysilane, 3,4-epoxycyclohexylethyltriethoxysilane, etc. And alkyl silicate when n is 1. You may use these individually or in combination of 2 or more types. Various modified resins can be used as the silicone resin. The silicone resin is preferably a silicone emulsion because of its excellent dispersibility in water.
これらの樹脂は、水系防錆塗料の全質量に対して1〜80質量%含有されているのが好ましく、5〜60質量%含有されているのが特に好ましい。 These resins are preferably contained in an amount of 1 to 80% by mass, particularly preferably 5 to 60% by mass, based on the total mass of the water-based anticorrosive paint.
水系防錆塗料は、樹脂に加えて防錆剤を含有している。防錆剤としては、酸化亜鉛、リン酸亜鉛、リン酸カルシウム、リン酸アルミニウム(縮合リン酸アルミニウムを含む。)、久郷、モリブデン酸アルミニウム等が挙げられる。これらの防錆剤は水系防錆塗料の全質量に対して1〜60質量%含有されているのが好ましく、5〜40質量%含有されているのが特に好ましい。 The water-based rust preventive paint contains a rust preventive agent in addition to the resin. Examples of the rust preventive include zinc oxide, zinc phosphate, calcium phosphate, aluminum phosphate (including condensed aluminum phosphate), Hisago, and aluminum molybdate. These rust preventives are preferably contained in an amount of 1 to 60% by mass, particularly preferably 5 to 40% by mass, based on the total mass of the water-based anticorrosive paint.
水系防錆塗料は、前記成分の他に、硬化剤、顔料、溶媒、分散剤、沈降防止剤、たれ防止剤、消泡剤、レベリング剤、防カビ剤、抗菌剤等の添加剤を含有することができる。前記顔料としては、着色顔料、体質顔料等がある。前記溶媒は臭気等の問題が生じない程度の含有量であれば有機溶剤であってもよいが、この発明の目的をよく達成できる点で有機溶媒を含有しないことが好ましい。硬化剤は水系防錆塗料に含有される樹脂の種類に応じて適宜の化合物が選択される。分散剤、沈降防止剤、たれ防止剤、消泡剤、レベリング剤、防カビ剤及び抗菌剤等は水系塗料に通常用いられる各種化合物が挙げられ、その含有量はこの発明の目的を損なわない範囲で適宜に設定される。 In addition to the above components, the water-based anticorrosive paint contains additives such as a curing agent, a pigment, a solvent, a dispersant, an anti-settling agent, an anti-sagging agent, an antifoaming agent, a leveling agent, an antifungal agent, and an antibacterial agent. be able to. Examples of the pigment include coloring pigments and extender pigments. The solvent may be an organic solvent as long as it does not cause a problem such as odor. However, it is preferable that the solvent does not contain an organic solvent because the object of the present invention can be achieved well. As the curing agent, an appropriate compound is selected according to the type of resin contained in the water-based anticorrosive paint. Dispersing agents, anti-settling agents, anti-sagging agents, antifoaming agents, leveling agents, anti-fungal agents, antibacterial agents, and the like include various compounds that are usually used in water-based paints, and the content thereof does not impair the purpose of the present invention. Is set appropriately.
前記樹脂と防錆剤と水と所望により各種添加剤とを含有する水系防錆塗料は固形分濃度が5〜90質量%であるのが好ましく、10〜70質量%であるのが特に好ましい。固形分濃度が前記範囲内にあると塗膜になった場合、十分な物理的強度が得られる。 The aqueous rust preventive paint containing the resin, the rust preventive agent, water and optionally various additives preferably has a solid content concentration of 5 to 90% by mass, particularly preferably 10 to 70% by mass. When the solid content concentration is within the above range, a sufficient physical strength can be obtained when a coating film is formed.
水系防錆塗料は、前記成分をすべて含む1液型塗料であってもよく、2液型塗料であってもよい。2液型塗料とする場合には、前記樹脂を含む主剤成分としての第1液と硬化剤成分を含む第2液との2液で、これら2液全体で前記成分をすべて含むように構成される。2液型塗料はこれら2液を使用する前に混合する。 The water-based anticorrosive paint may be a one-component paint containing all of the above components or a two-component paint. In the case of a two-pack type paint, the first liquid as the main ingredient component containing the resin and the second liquid containing the curing agent component are configured to include all of the components in the two liquids as a whole. The Two-component paints are mixed before using these two components.
この発明は駐車設備の躯体に前記水系防錆塗料を塗布し乾燥する。この発明においては、まず水系防錆塗料を準備する。特に水系防錆塗料が2液型塗料である場合には2液を混合して塗料とする。この発明においては、次いで、所望により、水系防錆塗料を塗布する前に前記した躯体の前処理を行う。このようにして水系防錆塗料の準備及び躯体の前処理が完了したら躯体に水系防錆塗料を塗布する。水系防錆塗料の躯体への塗布は、通常の塗布手段を採用することができ、具体的には、刷毛、エアースプレー、エアレススプレー、ローラー等の手段が挙げられるが、各種スプレーで塗布することが一般的である。水系防錆塗料は例えば乾燥膜厚が10〜500μmになるように塗装され、1回で塗布されてもよく、複数回例えば2〜4回で塗布されてもよい。複数回で水系防錆塗料が塗布されると塗膜が良好な耐久性を発揮する。このとき、既に塗布された水系防錆塗料に重ね塗りされる水系防錆塗料は既に塗布された水系防錆塗料が硬化した状態で塗布されても、未硬化でウェット状態で塗布されてもよい。 In the present invention, the water-based anticorrosive paint is applied to a housing of a parking facility and dried. In this invention, first, a water-based rust preventive paint is prepared. In particular, when the water-based anticorrosive paint is a two-pack type paint, the two liquids are mixed to obtain a paint. In this invention, next, the above-described pre-treatment of the casing is performed before applying the water-based anti-corrosion paint, if desired. When the preparation of the water-based anticorrosive paint and the pretreatment of the housing are completed in this way, the water-based anticorrosive paint is applied to the housing. The application of the water-based anticorrosive paint to the housing can adopt normal application means, and specifically, means such as brushes, air sprays, airless sprays, rollers, etc. can be applied. Is common. The water-based anticorrosive paint may be applied, for example, so that the dry film thickness is 10 to 500 μm, and may be applied once, or may be applied multiple times, for example, 2 to 4 times. When water-based anticorrosive paint is applied multiple times, the coating film exhibits good durability. At this time, the water-based anticorrosive paint to be applied over the already applied water-based anticorrosive paint may be applied in a state where the water-based anticorrosive paint already applied is cured, or may be applied in an uncured wet state. .
この発明において、水系防錆塗料を塗布した後に水系防錆塗料を乾燥する。水系防錆塗料の乾燥は、水系防錆塗料に含まれる水又は水及び溶媒が揮発する条件で実施されればよく、例えば20〜25℃程度の常温で1〜48時間放置する。 In this invention, after applying the water-based anticorrosive paint, the water-based anticorrosive paint is dried. The water-based anticorrosive paint may be dried under conditions where water or water and the solvent contained in the water-based anticorrosive paint volatilize. For example, the water-based anticorrosive paint is left at room temperature of about 20 to 25 ° C. for 1 to 48 hours.
このようにして水系防錆塗料の水又は水及び溶媒が揮発して躯体の表面に塗膜が形成される。形成された塗膜は優れた耐食性を有しており、水系防錆塗料に含有される樹脂に応じて耐食性に加えて躯体への高い密着性、耐湿性及び耐候性の少なくとも1つの特性を有している。したがって、この発明によれば、駐車設備に、耐食性に加えて躯体への密着性、耐湿性及び/又は耐候性に優れた塗膜を安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる。この発明によれば、駐車設備の躯体に水系防錆塗料を塗布し乾燥することによって、駐車設備の躯体が未使用すなわち新たに組み立てられた場合には駐車設備を新設でき、駐車設備の躯体がすでに使用されている場合には駐車設備を改修できる。 In this way, water or water and the solvent of the water-based anticorrosive paint are volatilized and a coating film is formed on the surface of the casing. The formed coating film has excellent corrosion resistance, and has at least one characteristic of high adhesion to the housing, moisture resistance and weather resistance in addition to corrosion resistance depending on the resin contained in the water-based anticorrosive paint. doing. Therefore, according to the present invention, a coating film excellent in adhesion to the housing, moisture resistance and / or weather resistance in addition to corrosion resistance, in addition to corrosion resistance, has excellent drying properties while achieving safety and hygiene and environmental protection. And it can be applied and formed with high workability. According to this invention, by applying a water-based anticorrosive paint to the housing of the parking facility and drying it, the parking facility can be newly installed when the housing of the parking facility is unused, that is, newly assembled. Parking facilities can be refurbished if already in use.
この発明においては、所望により水系防錆塗料の塗膜に上塗水系塗料が塗布され、乾燥される。この上塗水系塗料は、水系防錆塗料の特性を補強する上塗水系塗料、又は、水系防錆塗料が発揮しえない特性を発揮する上塗水系塗料であり、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂、シリコーン系樹脂及びフッ素系樹脂からなる群より選択される少なくとも1種の樹脂と顔料を含有している。この上塗水系塗料は、必要により、前記顔料とは別に前記特性を発揮する公知の添加剤、例えば耐食性を発揮するための防錆剤、耐候性を発揮するための樹脂(この発明に係る水系防錆塗料に含有される前記樹脂を除く。)等を含有していてもよい。この上塗水系塗料は顔料を含有している点で水系防錆塗料と区別され、場合によっては防錆剤を含有していない点で水系防錆塗料と区別される。 In the present invention, if desired, the overcoat water-based paint is applied to the coating film of the water-based anticorrosive paint and dried. This top-coat water-based paint is a top-coat water-based paint that reinforces the characteristics of water-based anti-corrosion paints, or a top-coat water-based paint that exhibits characteristics that water-based anti-corrosion paints cannot exhibit. Acrylic resins, urethane resins, epoxy-based paints It contains at least one resin selected from the group consisting of a resin, a vinyl resin, a silicone resin, and a fluorine resin and a pigment. If necessary, this overcoating water-based paint may be a known additive that exhibits the above-mentioned properties separately from the pigment, for example, a rust inhibitor for exhibiting corrosion resistance, a resin for exhibiting weather resistance (the water-based anti-corrosion agent according to the present invention). The resin contained in the rust paint may be excluded. This topcoat water-based paint is distinguished from a water-based anticorrosive paint in that it contains a pigment, and in some cases, it is distinguished from a water-based anticorrosive paint in that it does not contain a rust inhibitor.
上塗水系塗料に含有される樹脂は、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂、シリコーン系樹脂及びフッ素系樹脂からなる群より選択される少なくとも1種の樹脂であればよく、アクリル系樹脂、ウレタン系樹脂、エポキシ系樹脂、ビニル系樹脂及びシリコーン系樹脂それぞれは水系防錆塗料に含有される各樹脂と基本的に同様である。 The resin contained in the overcoat paint may be at least one resin selected from the group consisting of an acrylic resin, a urethane resin, an epoxy resin, a vinyl resin, a silicone resin, and a fluorine resin, Each of the acrylic resin, urethane resin, epoxy resin, vinyl resin and silicone resin is basically the same as each resin contained in the water-based anticorrosive paint.
フッ素系樹脂は、フッ素原子を含むオレフィンを重合して得られる樹脂であって、例えば、ポリテトラフルオロエチレン(PTFE)、ポリフッ化ビニリデン(PVDF)、ポリフッ化ビニル(PVF)、ペルフルオロアルコキシフッ素樹脂(PFA)、四フッ化エチレン・六フッ化プロピレン共重合体(FEP)、エチレン・四フッ化エチレン共重合体(ETFE)等が挙げられる。 The fluororesin is a resin obtained by polymerizing an olefin containing a fluorine atom. For example, polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), perfluoroalkoxy fluororesin ( PFA), tetrafluoroethylene / hexafluoropropylene copolymer (FEP), ethylene / tetrafluoroethylene copolymer (ETFE), and the like.
上塗水系塗料に含有される樹脂は、前記したように所望の特性によって適宜の樹脂が選択される。例えば、上塗水系塗料の塗膜により一層高い密着性が特に要求される場合にはエポキシ系樹脂が選択され、同様に耐候性及び/又は耐湿性が特に要求される場合には前記群よりウレタン系又はシリコーン系樹脂が選択され、同様に耐候性及び/又は耐汚染性が特に要求される場合には前記群よりフッ素系樹脂が選択される。特に水系防錆塗料の樹脂としてエポキシ系樹脂を選択する場合には上塗水系塗料の樹脂としてはウレタン系樹脂、アクリル系樹脂又はフッ素系樹脂が好適に選択され、水系防錆塗料の樹脂としてアクリル系やビニル系樹脂を選択する場合には上塗水系塗料の樹脂としてはウレタン系やシリコーン系樹脂が好適に選択される。 As described above, an appropriate resin is selected as the resin contained in the overcoat water-based paint depending on the desired characteristics. For example, an epoxy resin is selected when higher adhesion is particularly required by the coating film of the overcoat water-based paint, and similarly, urethane-based resin is selected from the above group when weather resistance and / or moisture resistance is particularly required. Alternatively, a silicone-based resin is selected, and similarly, a fluorine-based resin is selected from the above group when weather resistance and / or contamination resistance is particularly required. In particular, when an epoxy resin is selected as the resin for the water-based anticorrosive paint, urethane resin, acrylic resin or fluorine resin is preferably selected as the resin for the topcoat water-based paint, and acrylic resin is used as the resin for the water-based anticorrosive paint. When a vinyl resin is selected, a urethane or silicone resin is preferably selected as the resin for the top coat.
これらの樹脂は、上塗水系塗料の全質量に対して1〜80質量%含有されているのが好ましく、5〜60質量%含有されているのが特に好ましい。 These resins are preferably contained in an amount of 1 to 80% by mass, particularly preferably 5 to 60% by mass, based on the total mass of the overcoating water-based paint.
上塗水系塗料に含有される顔料は、各種塗料に用いられる公知の顔料を特に制限されることなく用いることができ、例えば、酸化チタン、黄色酸化鉄、カーボンブラック等が挙げられる。顔料は、各種塗料に一般的に適用される含有量で含有されていればよく、例えば、上塗水系塗料の全質量に対して0質量部を超え50質量%以下含有されているのが好ましく、10〜30質量%含有されているのが特に好ましい。 As the pigment contained in the overcoat paint, known pigments used in various paints can be used without particular limitation, and examples thereof include titanium oxide, yellow iron oxide, and carbon black. The pigment only needs to be contained in a content generally applied to various paints. For example, the pigment is preferably contained in an amount of more than 0 parts by mass and 50% by mass or less based on the total mass of the overcoat water-based paint. The content of 10 to 30% by mass is particularly preferable.
この上塗水系塗料は仕上水系塗料と称することもでき、好ましくは水系防錆塗料が乾燥してなる塗膜の上に、水系防錆塗料と基本的に同様にして塗布、乾燥される。この上塗水系塗料は、前記成分をすべて含む1液型塗料であってもよく、2液型塗料であってもよい。2液型塗料とする場合には、前記樹脂を含む主剤成分としての第1液と硬化剤成分を含む第2液との2液で、これら2液全体で前記成分をすべて含むように構成される。2液型塗料はこれら2液を使用する前に混合する。 This top-coat water-based paint can also be referred to as a finish water-based paint, and is preferably applied and dried on a coating film formed by drying the water-based rust-proof paint basically in the same manner as the water-based rust-proof paint. This topcoat water-based paint may be a one-component paint containing all of the above components or a two-component paint. In the case of a two-pack type paint, the first liquid as the main ingredient component containing the resin and the second liquid containing the curing agent component are configured to include all of the components in the two liquids as a whole. The Two-component paints are mixed before using these two components.
このようにして上塗水系塗料の水又は水及び溶媒が揮発して水系防錆塗料が乾燥してなる塗膜の表面に仕上げ塗膜が形成される。形成された仕上げ塗膜は水系防錆塗料の塗膜への密着性、耐湿性、耐候性及び耐食性等の少なくとも1つの特性を有している。したがって、この発明によれば、駐車設備に、耐食性に加えて密着性、耐湿性及び/又は耐候性に優れた塗膜を安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる。この発明によれば、駐車設備の躯体に水系防錆塗料及び上塗水系塗料を順次塗布し乾燥することによって、駐車設備の躯体が未使用すなわち新たに組み立てられた場合には駐車設備を新設でき、駐車設備の躯体がすでに使用されている場合には駐車設備を改修できる。 In this way, the finished coating film is formed on the surface of the coating film formed by evaporating water or water and the solvent of the top coating water-based paint and drying the water-based anticorrosive paint. The formed finished coating film has at least one characteristic such as adhesion to the coating film of the water-based anticorrosive paint, moisture resistance, weather resistance, and corrosion resistance. Therefore, according to the present invention, a coating film excellent in adhesion, moisture resistance and / or weather resistance in addition to corrosion resistance in a parking facility has excellent drying properties and high work while achieving safety and hygiene and environmental protection. It can be formed by coating. According to the present invention, by sequentially applying the water-based anti-corrosion paint and the overcoat water-based paint to the housing of the parking facility and drying, the parking facility can be newly installed when the housing of the parking facility is unused, that is, newly assembled, Parking facilities can be refurbished if the parking facilities are already in use.
この発明においては、所望により、水系防錆塗料の塗膜の下に、換言すると、水系防錆塗料を塗布する前に、水系ジンクリッチ塗料が塗布され、乾燥される。この水系ジンクリッチ塗料は、金属亜鉛末又は亜鉛合金末を通常60〜95質量%含有する塗料であればよく、水溶性又は水分散性の結合剤、その他の添加剤、及び水を含有している。結合剤は、水溶性又は水分散性を有していればよく、例えば、エポキシ系樹脂、アミド系樹脂、アミン系樹脂、ウレタン系樹脂、アルキド系樹脂、フッ素系樹脂の有機系結合剤、アルキルシリケート、エチルシリケート、ブチルシリケート等の無機系結合剤が挙げられる。結合剤の含有量は少ないのがよく、例えば、1〜30質量%であるのがよい。その他の添加剤としては、通常のジンクリッチ塗料に用いられる体質顔料、着色顔料、タレ止め剤、色別れ防止剤、分散剤、沈殿防止剤、消泡剤等が挙げられる。これらの含有量は少ないのがよく、例えば、0〜10質量%であるのがよい。このような水系ジンクリッチ塗料の一例として、例えば、特開平07−133442号公報似記載された「カルボキシ基を含有する水性ウレタン樹脂を結合剤とするジンクリッチ塗料」が挙げられる。 In the present invention, the aqueous zinc rich paint is applied and dried under the coating film of the aqueous anticorrosive paint, in other words, before applying the aqueous anticorrosive paint, if desired. This water-based zinc-rich paint may be any paint that normally contains metal zinc powder or zinc alloy powder in an amount of 60 to 95% by mass, and contains a water-soluble or water-dispersible binder, other additives, and water. Yes. The binder may be water-soluble or water-dispersible. For example, an epoxy resin, an amide resin, an amine resin, a urethane resin, an alkyd resin, a fluorine resin organic binder, an alkyl resin, Inorganic binders such as silicate, ethyl silicate, butyl silicate and the like can be mentioned. The content of the binder is preferably small, for example, 1 to 30% by mass. Examples of other additives include extender pigments, color pigments, anti-sagging agents, anti-coloring agents, dispersants, suspending agents, and antifoaming agents used in ordinary zinc-rich paints. These contents should be small, for example, 0 to 10% by mass. An example of such a water-based zinc rich paint is, for example, “zinc rich paint using a water-based urethane resin containing a carboxy group as a binder” described in Japanese Patent Application Laid-Open No. 07-133442.
この水系ジンクリッチ塗料は、駐車設備の躯体に、所望により前処理した後であって水系防錆塗料を塗布する前に、水系防錆塗料と基本的に同様にして塗布、乾燥される。 This water-based zinc-rich paint is applied and dried in the same manner as the water-based anticorrosive paint, after being pretreated if necessary, and before the water-based anticorrosive paint is applied to the housing of the parking facility.
このようにして水系ジンクリッチ塗料の水又は水及び溶媒が揮発して水系ジンクリッチ塗料が乾燥してなる塗膜が形成される。水系ジンクリッチ塗料の塗膜は金属亜鉛末又は亜鉛合金末を含有しているから、駐車設備の躯体に対する水系防錆塗料による防食効果を補強できる。特に、駐車設備の躯体に水系ジンクリッチ塗料、水系防錆塗料及びフッ素系樹脂を含有する上塗水系塗料をこの順で塗布して硬化すると、駐車設備の躯体に対する防食効果をより一層長期間にわたって発揮させることができる。また、この水系ジンクリッチ塗料は水を含有し、有機溶媒を実質的に含有していないから、水系防錆塗料による安全衛生面及び環境保全を損なうことがない。したがって、この発明によれば、駐車設備に、躯体への密着性、耐湿性及び/又は耐候性に加えてより一層長期間にわたって発揮される耐食性に優れた塗膜を安全衛生面及び環境保全を達成しつつも優れた乾燥性及び高い作業性で塗布形成できる。この発明によれば、駐車設備の躯体に水系ジンクリッチ塗料、水系防錆塗料及び上塗水系塗料を順次塗布し乾燥することによって、駐車設備の躯体が未使用すなわち新たに組み立てられた場合には駐車設備を新設でき、駐車設備の躯体がすでに使用されている場合には駐車設備を改修できる。 Thus, the water-based zinc rich paint water or water and the solvent are volatilized to form a coating film formed by drying the water-based zinc rich paint. Since the coating film of the water-based zinc rich paint contains metallic zinc powder or zinc alloy powder, the anticorrosive effect of the water-based anticorrosive paint on the housing of the parking facility can be reinforced. In particular, applying a water-based zinc-rich paint, a water-based anti-corrosion paint, and a top-coat water-based paint containing a fluororesin in this order to the parking equipment housing will exhibit the anticorrosion effect on the parking equipment housing for a longer period of time. Can be made. Further, since this water-based zinc rich paint contains water and does not substantially contain an organic solvent, it does not impair the safety and hygiene and environmental conservation due to the water-based anticorrosive paint. Therefore, according to this invention, in addition to adhesion to the housing, moisture resistance and / or weather resistance, a coating film excellent in corrosion resistance that is exhibited for a longer period of time is provided on the parking facility for safety and hygiene and environmental conservation. While achieving, it can be applied and formed with excellent drying properties and high workability. According to the present invention, the water-based zinc rich paint, the water-based anticorrosive paint, and the top-coat water-based paint are sequentially applied to the housing of the parking facility and dried, so that the parking facility housing is parked when it is unused, that is, newly assembled. New facilities can be installed, and parking facilities can be refurbished if parking facilities are already in use.
以下、この発明を実施例及び比較例により具体的に説明する。以下に示す実施例は、この発明の一例を示すものであり、この発明は以下の実施例によって限定されるものではない。なお、実施例中の「部」や「%」は、特に断らない限り、質量基準で示す。 Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The following examples show examples of the present invention, and the present invention is not limited to the following examples. In the examples, “parts” and “%” are based on mass unless otherwise specified.
(参考例1)
<試験板作製方法>
サンドブラスト板(150mm×70mm×t3.2mm、軟鋼板)に水系防錆塗料として下記組成の2液型水系エポキシ樹脂塗料を乾燥膜厚が約50μmになるように1回で塗装し、塗装後、温度23℃に保たれた恒温室内で24時間乾燥させた。
<2液型水系エポキシ樹脂塗料>
第一液:商品名「エピコート828」(ジャパン・エポキシレジン社製)、防錆成分「リン酸カルシウム」、溶剤「水」、樹脂濃度30質量%、固形分濃度60質量%
第二液:商品名「変性ポリアミン樹脂FXI−919」(富士化成工業社製)、溶剤「水」、固形分濃度50質量%、第一液との混合割合(質量比) 第一液:第二液=3:1
( Reference Example 1)
<Test plate production method>
A two-component water-based epoxy resin paint having the following composition as a water-based anti-corrosion paint is applied to a sandblast plate (150 mm × 70 mm × t 3.2 mm, mild steel plate) once so that the dry film thickness is about 50 μm. It was dried for 24 hours in a constant temperature room maintained at a temperature of 23 ° C.
<Two-component water-based epoxy resin paint>
First liquid: Trade name “Epicoat 828” (manufactured by Japan Epoxy Resin Co., Ltd.), rust preventive component “calcium phosphate”, solvent “water”, resin concentration 30 mass%, solid content concentration 60 mass%
Second liquid: Trade name “modified polyamine resin FXI-919” (manufactured by Fuji Kasei Kogyo Co., Ltd.), solvent “water”, solid content concentration 50 mass%, mixing ratio with first liquid (mass ratio) first liquid: first Two liquids = 3: 1
このようにして形成した水系防錆塗料の塗膜上に上塗水系塗料として下記組成の2液型水系ポリウレタン樹脂塗料を乾燥膜厚が約30μmになるように2回で塗装し、塗装後、温度23℃に保たれた恒温室内で48時間乾燥させた。このようにしてサンドブラスト板上にエポキシ系樹脂を含有する水系防錆塗料の塗膜及びポリウレタン樹脂を含有する上塗水系塗料の塗膜をこの順で形成した参考例1の試験板を作製した。
<2液型水系ポリウレタン樹脂塗料>
第一液:「自家製アクリルポリオール樹脂」(大日本塗料株式会社製)、溶剤「水」、顔料「酸化チタン」、樹脂濃度30質量%、固形分濃度50質量%
第二液:「イソホロンジイソシアネート」、固形分濃度100質量%、第一液との混合割合(質量比) 第一液:第二液=4:1
A two-component water-based polyurethane resin paint having the following composition is applied as a top-coat water-based paint on the coating film of the water-based anticorrosive paint formed in this manner twice so that the dry film thickness is about 30 μm. It was dried for 48 hours in a thermostatic chamber kept at 23 ° C. In this way, a test plate of Reference Example 1 in which a coating film of an aqueous rust-proof coating material containing an epoxy-based resin and a coating film of a top-coating water-based coating material containing a polyurethane resin was formed in this order on a sandblast plate.
<Two-component water-based polyurethane resin paint>
First liquid: “Homemade acrylic polyol resin” (manufactured by Dainippon Paint Co., Ltd.), solvent “water”, pigment “titanium oxide”, resin concentration 30 mass%, solid content concentration 50 mass%
Second liquid: “Isophorone diisocyanate”, solid content concentration 100% by mass, mixing ratio with first liquid (mass ratio) First liquid: second liquid = 4: 1
(比較例1)
前記2液型水系エポキシ樹脂塗料を有機溶剤系防錆塗料として下記組成の2液型有機溶剤系エポキシ樹脂系塗料に変更し、かつ上塗有機溶剤系塗料として前記組成の2液型水系ポリウレタン樹脂塗料を下記組成の2液型有機溶剤系ポリウレタン樹脂系塗料に変更したこと以外は参考例1と基本的に同様にして比較例1の試験板を作製した。
<2液型有機溶剤系エポキシ樹脂系塗料>
第一液:商品名「エピコート1001」(ジャパン・エポキシレジン社製)、防錆成分「リン酸カルシウム」、有機溶剤「トルエン」、樹脂濃度30質量%、固形分濃度60質量%
第二液:商品名「ポリアミドアミン TXK−659」(富士化成工業社製)、有機溶剤「キシレン」、固形分濃度60質量%、第一液との混合割合(質量比) 第一液:第二液=4:1
<2液型有機溶剤系ポリウレタン樹脂系塗料>
第一液:「自家製エポキシポリオール樹脂」(大日本塗料株式会社製)、有機溶剤「トルエン」、顔料「酸化チタン」、樹脂濃度30質量%、固形分濃度50質量%
第二液:「トリレンジイソシアネート」、固形分濃度100質量%、第一液との混合割合(質量比) 第一液:第二液=4:1
(Comparative Example 1)
The two-component water-based epoxy resin paint is changed to a two-component organic solvent-based epoxy resin paint having the following composition as an organic solvent-based anticorrosive paint, and the two-component water-based polyurethane resin paint having the above composition is used as an overcoat organic solvent-based paint. A test plate of Comparative Example 1 was prepared basically in the same manner as in Reference Example 1 except that was changed to a two-component organic solvent-based polyurethane resin-based paint having the following composition.
<Two-pack type organic solvent epoxy resin paint>
First liquid: Trade name “Epicoat 1001” (manufactured by Japan Epoxy Resin Co., Ltd.), rust preventive ingredient “calcium phosphate”, organic solvent “toluene”, resin concentration 30% by mass, solid content concentration 60% by mass.
Second liquid: trade name “polyamideamine TXK-659” (manufactured by Fuji Kasei Kogyo Co., Ltd.), organic solvent “xylene”, solid content concentration 60 mass%, mixing ratio with first liquid (mass ratio) first liquid: first Two liquids = 4: 1
<Two-pack type organic solvent-based polyurethane resin-based paint>
First liquid: “Homemade epoxy polyol resin” (Dainippon Paint Co., Ltd.), organic solvent “toluene”, pigment “titanium oxide”, resin concentration 30% by mass, solid content concentration 50% by mass
Second liquid: “tolylene diisocyanate”, solid content concentration of 100 mass%, mixing ratio with first liquid (mass ratio) first liquid: second liquid = 4: 1
(耐食性試験)
作製した参考例1及び比較例1の試験板それぞれをJIS K 5600−7−1(塗料一般試験方法−第7部:塗膜の長期耐久性−第1節:耐中性塩水噴霧性)に従い、700時間の評価を行った。結果を下記第1表に示す。
(Corrosion resistance test)
Each of the prepared test plates of Reference Example 1 and Comparative Example 1 was subjected to JIS K 5600-7-1 (Paint General Test Method-Part 7: Long-term Durability of Coating Film-Section 1: Neutral Salt Water Spray Resistance). 700 hours. The results are shown in Table 1 below.
第1表に示されるように、防錆剤を含有しない2液型水系ポリウレタン樹脂塗料を塗布乾燥してなる仕上げ塗膜を有する参考例1の試験板は耐食性に優れていたことから、この仕上げ塗膜のない試験板、すなわちサンドブラスト板に水系防錆塗料である2液型水系エポキシ樹脂塗料を塗布乾燥してなる塗膜を有する試験板であっても参考例1と同様に耐食性に優れることが理解できる。 As shown in Table 1, the test plate of Reference Example 1 having a finished coating film formed by applying and drying a two-component water-based polyurethane resin paint not containing a rust inhibitor was excellent in corrosion resistance. Even with a test plate having no coating film, that is, a test plate having a coating formed by applying and drying a two-component water-based epoxy resin coating, which is a water-based anti-corrosion coating, on a sandblast plate, it has excellent corrosion resistance as in Reference Example 1. Can understand.
(付着性試験)
作製した参考例1及び比較例1の試験板それぞれを24時間、水道水に浸漬した後水道水から取り出して1時間放置し、その後、JIS K 5600−5−6(塗料一般試験方法−第5部:塗膜の機械的性質−第6節:付着性(クロスカット法))に従って行い評価した。結果を下記第2表に示す。なお、本願出願人らはこの付着性試験が塗膜の躯体への密着性の評価に代用できることを確認している。
(Adhesion test)
Each of the prepared test plates of Reference Example 1 and Comparative Example 1 was immersed in tap water for 24 hours, then removed from the tap water and allowed to stand for 1 hour, and then JIS K 5600-5-6 (Paint General Test Method No. 5). Part: Mechanical properties of coating film-Section 6: Adhesion (cross-cut method)) and evaluated. The results are shown in Table 2 below. The present applicants have confirmed that this adhesion test can be substituted for the evaluation of the adhesion of the coating film to the housing.
(耐湿性)
上記のように作製した参考例1及び比較例1の試験片を50℃で98%RH以上の恒温恒湿槽に120時間放置後、上記クロスカット法試験と同様に評価した。結果を下記第3表に示す。
(Moisture resistance)
The test pieces of Reference Example 1 and Comparative Example 1 produced as described above were left in a constant temperature and humidity chamber of 98% RH or higher at 50 ° C. for 120 hours, and then evaluated in the same manner as in the cross-cut method test. The results are shown in Table 3 below.
(耐候性)
上記のように作製した参考例1及び比較例1の試験片をサンシャインウエザロメーターによって促進耐候性試験を行い、1000時間後の塗膜外観の変化を試験前の塗膜状態と比較し評価した。結果を下記第3表に示す。
(Weatherability)
The specimens of Reference Example 1 and Comparative Example 1 produced as described above were subjected to an accelerated weather resistance test using a sunshine weatherometer, and the change in coating film appearance after 1000 hours was compared with the coating film state before the test and evaluated. . The results are shown in Table 3 below.
なお、参考例1において、前記付着性試験とは異なる「躯体への密着性」評価及び「安全衛生面及び環境保全」評価については後述する参考例3及び4で評価し、その効果を確認した。 In Reference Example 1, “adhesion to the housing” evaluation and “safety and health aspect and environmental conservation” evaluation different from the adhesion test were evaluated in Reference Examples 3 and 4 to be described later, and the effects were confirmed. .
(参考例2)
駐車設備のひとつであるターンテーブル(屋外設置、鉄鋼製)の改修工事においてこの発明の水系防錆塗料で塗り替えを実施した。具体的には、下地調整として、水系洗浄剤(界面活性剤成分含有)でエンジンオイル等の油分を脱脂し、脆弱な旧塗膜や腐食生成物を動力工具で除去した。なお、健全な旧塗膜表面は、水系防錆塗料の付着性を確保するため、手工具や動力工具でサンディング処理した。下地調整が終了後、水系防錆塗料として下記組成の1液型水系エポキシ樹脂系塗料を乾燥膜厚が30μmになるように1回で塗装して一日放置した。
<1液型水系エポキシ樹脂系塗料>
樹脂「ウォーターゾール」(DIC社製)、防錆顔料「リン酸カルシウム」、溶剤「水」、樹脂濃度30質量%、固形分濃度60質量%
( Reference Example 2)
In the renovation work of the turntable (outdoor installation, steel) which is one of the parking facilities, the water-based anticorrosive paint of the present invention was applied. Specifically, as a base preparation, oil such as engine oil was degreased with an aqueous cleaning agent (containing a surfactant component), and fragile old paint films and corrosion products were removed with a power tool. The surface of the old paint film was sanded with a hand tool or power tool to ensure the adhesion of the water-based anti-corrosion paint. After the base preparation was completed, a one-component water-based epoxy resin-based paint having the following composition was applied as a water-based anticorrosive paint at a time so as to have a dry film thickness of 30 μm and left for one day.
<One-component water-based epoxy resin-based paint>
Resin “Watersol” (manufactured by DIC), anticorrosive pigment “calcium phosphate”, solvent “water”, resin concentration 30% by mass, solid content concentration 60% by mass
このようにして形成した水系防錆塗料の塗膜上に上塗水系塗料として下記組成の1液型水系アクリル樹脂系塗料を乾燥膜厚が30μmになるように2回で塗装して、ターンテーブルの改修を完了した。
<1液型水系アクリル樹脂系塗料>
商品名「自家製化アクリルエマルジョン」(大日本塗料株式会社製)、顔料「酸化チタン」、耐候性添加剤「紫外線吸収剤」、溶剤「水」、樹脂濃度30質量%、固形分濃度55質量%
On the coating film of the water-based anticorrosive paint thus formed, a one-component water-based acrylic resin-based paint having the following composition is applied twice as a top coat water-based paint so that the dry film thickness is 30 μm. Renovation completed.
<One-component water-based acrylic resin-based paint>
Product name “homemade acrylic emulsion” (Dainippon Paint Co., Ltd.), pigment “titanium oxide”, weathering additive “ultraviolet absorber”, solvent “water”, resin concentration 30% by mass, solid content concentration 55% by mass
(タイヤによる耐剥離・摩耗性)
このターンテーブルの塗膜における、車輌タイヤによる剥離や摩耗の程度を上記比較例1の有機溶剤系塗料を塗装した部分と比較し、塗膜外観を目視により以下のようにして評価した。この評価は改修後のターンテーブルを使用開始約半年後に行った。その結果を下記第4表に示す。
(Peeling resistance and wear resistance by tire)
The degree of peeling and abrasion due to vehicle tires in the coating film of the turntable was compared with the portion where the organic solvent-based paint of Comparative Example 1 was applied, and the appearance of the coating film was visually evaluated as follows. This evaluation was conducted about half a year after the use of the refurbished turntable. The results are shown in Table 4 below.
この結果から本願発明の水系防錆塗料を硬化した塗膜は躯体への密着性が高いことが分かった。また参考例2の水系防錆塗料は、強靱なエマルジョン塗膜を形成するため、比較例1の有機溶剤系の塗膜より車輌タイヤによる摩耗状態が少なかったと思われる。 From this result, it was found that the coating film obtained by curing the water-based anticorrosive paint of the present invention has high adhesion to the casing. Moreover, since the water-based anticorrosive paint of Reference Example 2 forms a tough emulsion coating film, it seems that the wear state by the vehicle tire was less than that of the organic solvent-based paint film of Comparative Example 1.
参考例2についても参考例1と基本的に同様にして耐湿性及び耐候性を評価したところ参考例1の試験片と同様の傾向が確認できた。 It was also Reference Example 1 is basically similar to to confirmed the same tendency as the test piece of Reference Example 1 was evaluated for moisture resistance and weather resistance for Reference Example 2.
(参考例3)
機械式駐車設備のひとつである多段式駐車設備(屋外設置)のパレット(鉄鋼製)の改修工事においてこの発明の水系防錆塗料で塗り替えを実施した。具体的には、参考例2と同様にしてパレットを下地調整した後に水系防錆塗料として上記参考例1と同じ2液型水系エポキシ樹脂塗料を乾燥膜厚約50μmになるように1回で塗装して一日放置した。
( Reference Example 3)
In the repair work of the pallet (made of steel) of the multistage parking facility (outdoor installation) which is one of the mechanical parking facilities, the water-based anticorrosive paint of the present invention was applied. Specifically, after preparing the base of the pallet in the same manner as in Reference Example 2, the same two-component water-based epoxy resin paint as in Reference Example 1 above is applied once as a water-based anti-corrosion paint so that the dry film thickness is about 50 μm. And left for a day.
このようにして形成した水系防錆塗料の塗膜上に上塗水系塗料として上記参考例1と同じ2液型水系ポリウレタン樹脂塗料を乾燥膜厚が30μmになるように2回で塗装して、温度25℃で乾燥させて、多段式駐車設備を改修した。 The same two-component water-based polyurethane resin paint as that in Reference Example 1 was applied twice on the coating film of the water-based anticorrosive paint formed in this way so as to have a dry film thickness of 30 μm. The multistage parking facility was renovated by drying at 25 ° C.
(比較例2)
参考例2と同様にしてパレットを下地調整した後に有機溶剤系防錆塗料として下記組成の1液型湿気硬化型ポリウレタン樹脂系塗料を乾燥膜厚約50μmになるように1回で塗装して一日放置した。
<1液型湿気硬化型ポリウレタン樹脂系塗料>
商品名「スミジュール」(住友バイエルウレタン社製)、防錆顔料「亜鉛末」、有機溶剤「キシレン」、樹脂濃度30質量%、固形分濃度55質量%
(Comparative Example 2)
After preparing the base of the pallet in the same manner as in Reference Example 2, a one-component moisture-curable polyurethane resin-based paint having the following composition as an organic solvent-based rust-proof coating was applied once to a dry film thickness of about 50 μm. I left it for a day.
<One-component moisture-curable polyurethane resin-based paint>
Product name “Sumijoule” (manufactured by Sumitomo Bayer Urethane Co., Ltd.), anticorrosive pigment “zinc powder”, organic solvent “xylene”, resin concentration 30% by mass, solid content concentration 55% by mass
このようにして形成した水系防錆塗料の塗膜上に上塗有機溶剤系塗料として下記組成の2液型ポリウレタン樹脂系塗料を乾燥膜厚が30μmになるように2回で塗装して、温度25℃で乾燥させて、多段式駐車設備を改修した。
<2液型ポリウレタン樹脂系塗料>
第一液:「自家製ポリエステルポリオール樹脂」(大日本塗料株式会社製)、有機溶剤「トルエン」、顔料「酸化チタン」、樹脂濃度30質量%、固形分濃度55質量%
第二液:「イソホロンジイソシアネート」、固形分濃度100質量%、第一液との混合割合(質量比) 第一液:第二液=4:1
A two-component polyurethane resin-based paint having the following composition was applied as an overcoat organic solvent-based paint on the water-based anti-corrosive paint film formed in this manner twice so that the dry film thickness was 30 μm. It was dried at ℃ and the multistage parking facility was renovated.
<Two-component polyurethane resin paint>
First liquid: “Homemade polyester polyol resin” (manufactured by Dainippon Paint Co., Ltd.), organic solvent “toluene”, pigment “titanium oxide”, resin concentration 30 mass%, solid content concentration 55 mass%
Second liquid: “Isophorone diisocyanate”, solid content concentration 100% by mass, mixing ratio with first liquid (mass ratio) First liquid: second liquid = 4: 1
(臭気測定)
このようにして改修された多段式駐車設備において、参考例3の水系防錆塗料と比較例2の有機溶剤系防錆塗料との塗装中の雰囲気の臭気を計測した。装置は新コスモス電機製のポータブル型ニオイセンサを用いた。本装置はニオイの強弱をデジタル表示できるものである。これにより、揮発性有機化合物の放散量の程度が把握可能である。測定した結果を下記第5表に示す。臭気成分の種類にもよるが、通常の有機溶剤であれば測定された値がおよそ500以下であると、一般的に市街地であっても安全衛生面及び環境保全に十分に配慮できる。
(Odor measurement)
In the multistage parking facility thus modified, the odor of the atmosphere during the coating of the water-based anticorrosive paint of Reference Example 3 and the organic solvent-based anticorrosive paint of Comparative Example 2 was measured. The device used was a portable odor sensor made by Shin Cosmos Electric. This device can digitally display the odor intensity. Thereby, it is possible to grasp the degree of emission of volatile organic compounds. The measurement results are shown in Table 5 below. Although it depends on the kind of odor component, if the measured value is about 500 or less in the case of a normal organic solvent, sufficient consideration can be given to health and safety and environmental protection even in an urban area.
(参考例4)
機械式駐車設備のひとつである地下式駐車設備(屋内設置、鉄鋼製)の改修工事において、この発明の水系塗料で塗り替えを実施した。具体的には、参考例2と同様にして地下式駐車設備の床面を下地調整した後に水系防錆塗料として上記参考例1と同じ2液型水系エポキシ樹脂塗料を乾燥膜厚約50μmになるように1回で塗装して一日放置した。
( Reference Example 4)
In the renovation work of the underground parking facility (indoor installation, made of steel) which is one of the mechanical parking facilities, the paint was repainted with the water-based paint of the present invention. Specifically, comprising the above Reference Example 1 and the same two-aqueous epoxy resin paint as an aqueous anticorrosive paint after the floor of the underground parking in the same manner as in Reference Example 2 was base adjustment to a dry film thickness of about 50μm I painted it at once and left it for a day.
このようにして形成した水系防錆塗料の塗膜上に上塗水系塗料として上記参考例1と同じ2液型水系ポリウレタン樹脂塗料を乾燥膜厚が30μmになるように2回で塗装して、温度25℃で乾燥させて、地下式駐車設備の改修を完了した。 The same two-component water-based polyurethane resin paint as that in Reference Example 1 was applied twice on the coating film of the water-based anticorrosive paint formed in this way so as to have a dry film thickness of 30 μm. Drying at 25 ° C completed the renovation of the underground parking facility.
(臭気官能評価)
参考例4の水系防錆塗料及び上塗水系塗料の塗装中の雰囲気を、2液型水系エポキシ樹脂塗料及び2液型水系ポリウレタン樹脂塗料それぞれについて、官能評価を実施した。評価者は、塗装業者1名、駐車設備メーカー3名、塗料メーカー営業担当1名の合計5名で実施した。その結果を下記第6表及び第7表に示す。
(Odor sensory evaluation)
Sensory evaluation was carried out for the two-component water-based epoxy resin paint and the two-component water-based polyurethane resin paint in the atmosphere during the application of the water-based anticorrosive paint and the top-coat water-based paint of Reference Example 4. The evaluators were conducted by a total of five people: one painter, three parking equipment manufacturers, and one paint manufacturer sales representative. The results are shown in Tables 6 and 7 below.
(躯体への密着性評価)
参考例2〜4及び比較例2で改修した各駐車設備の状態を使用開始約半年後に確認した結果を下記第8表に示す。
(Evaluation of adhesion to the housing)
Table 8 below shows the results of confirming the state of each parking facility refurbished in Reference Examples 2 to 4 and Comparative Example 2 about six months after the start of use.
以上のように、駐車設備の多くは、市街地にあり、従来からの有機溶剤系塗料では刺激臭や異臭の問題があり、改修工事が実施できていない設備もある。それらは設備の老朽化が激しく、腐食も進み、鋼板が欠落しているものまである。また美観も悪い。これに対して、この発明によれば、水系防錆塗料で施工することにより、塗装中、塗装後に刺激臭や異臭を放つことなく、この発明の方法は安全衛生面及び環境保全面に配慮された耐食性を付与できる表面処理方法である。 As described above, most parking facilities are located in urban areas, and conventional organic solvent-based paints have problems of irritating odors and odors, and there are some facilities that cannot be renovated. They are severely aging, corroded, and even missing steel plates. The beauty is also bad. On the other hand, according to the present invention, by applying the water-based anticorrosive paint, the method of the present invention is considered in terms of health and safety and environmental protection without giving off an irritating odor or a strange odor during and after painting. It is a surface treatment method capable of imparting high corrosion resistance.
(参考例5) ( Reference Example 5)
サンドブラスト板(150mm×70mm×t3.2mm、軟鋼板)に下記組成の1液型水系ジンクリッチ塗料を乾燥膜厚が約50μmになるように1回で塗装し、塗装後、温度23℃に保たれた恒温室内で24時間乾燥させた。
<水系ジンクリッチ塗料>
商品名「水性ゼッタールEP−2 HB」(大日本塗料株式会社製)、亜鉛末成分「亜鉛」、結合剤「ポリアミドアミン」、溶剤「水」、消泡剤(サンノプコ株式会社製)、亜鉛末濃度75質量%、結合剤濃度25質量%、固形分濃度85質量%
A one-component water-based zinc-rich paint having the following composition is applied to a sandblast plate (150 mm x 70 mm x t3.2 mm, mild steel plate) at a time so that the dry film thickness is about 50 µm. It was dried for 24 hours in a constant temperature chamber.
<Water-based zinc rich paint>
Product name "Aqueous Zettall EP-2 HB" (Dainippon Paint Co., Ltd.), Zinc powder component "Zinc", Binder "Polyamideamine", Solvent "Water", Antifoam (San Nopco Co., Ltd.), Zinc powder Concentration 75% by mass, binder concentration 25% by mass, solid content concentration 85% by mass
このようにして形成した水系ジンクリッチ塗料の塗膜上に水系防錆塗料として下記組成の2液型水系エポキシ樹脂塗料を乾燥膜厚が約50μmになるように1回で塗装し、塗装後、温度23℃に保たれた恒温室内で24時間乾燥させた。
<2液型水系エポキシ樹脂塗料>
第一液:商品名「エピコート828」(ジャパン・エポキシレジン社製)、防錆成分「リン酸カルシウム」、溶剤「水」、樹脂濃度30質量%、固形分濃度60質量%
第二液:商品名「変性ポリアミン樹脂FXI−919」(富士化成工業社製)、溶剤「水」、固形分濃度50質量%、第一液との混合割合(質量比) 第一液:第二液=3:1
On the coating film of the water-based zinc rich paint thus formed, a two-component water-based epoxy resin paint having the following composition as a water-based anti-corrosion paint is applied once so that the dry film thickness is about 50 μm. It was dried for 24 hours in a constant temperature room maintained at a temperature of 23 ° C.
<Two-component water-based epoxy resin paint>
First liquid: Trade name “Epicoat 828” (manufactured by Japan Epoxy Resin Co., Ltd.), rust preventive component “calcium phosphate”, solvent “water”, resin concentration 30 mass%, solid content concentration 60 mass%
Second liquid: Trade name “modified polyamine resin FXI-919” (manufactured by Fuji Kasei Kogyo Co., Ltd.), solvent “water”, solid content concentration 50 mass%, mixing ratio with first liquid (mass ratio) first liquid: first Two liquids = 3: 1
このようにして形成した水系防錆塗料の塗膜上に上塗水系塗料として下記組成の1液型水系フッ素樹脂塗料を乾燥膜厚が約30μmになるように2回で塗装し、塗装後、温度23℃に保たれた恒温室内で48時間乾燥させた。このようにしてサンドブラスト板上に亜鉛末を含有する水系ジンクリッチ塗料の塗膜、エポキシ系樹脂を含有する水系防錆塗料の塗膜及びフッ素樹脂を含有する上塗水系塗料の塗膜をこの順で形成した参考例5の試験板を作製した。
<1液型水系フッ素樹脂塗料>
商品名「DNTビューフッソ」(大日本塗料株式会社製)、フッ素樹脂「ルミフロン」(旭硝子株式会社製)、溶剤「水」、顔料「酸化チタン等」、フッ素樹脂濃度5質量%、固形分濃度12質量%
On the water-based anti-corrosive paint film thus formed, a one-component water-based fluororesin paint having the following composition was applied twice as a top-coat water-based paint so that the dry film thickness was about 30 μm. It was dried for 48 hours in a thermostatic chamber kept at 23 ° C. Thus, a water-based zinc-rich paint film containing zinc dust, a water-based anticorrosive paint film containing an epoxy resin, and a paint film of a topcoat water-based paint containing a fluororesin in this order on the sandblast plate. The formed test plate of Reference Example 5 was produced.
<One-component water-based fluoropolymer paint>
Product name “DNT View Fluoro” (Dainippon Paint Co., Ltd.), fluororesin “Lumiflon” (Asahi Glass Co., Ltd.), solvent “water”, pigment “titanium oxide etc.”, fluororesin concentration 5 mass%, solid content concentration 12 mass%
(耐食性試験)
作製した参考例5及び比較対象として参考例1の試験板それぞれをJIS K 5600−7−1(塗料一般試験方法−第7部:塗膜の長期耐久性−第1節:耐中性塩水噴霧性)に従い、700時間の評価を行った。その結果、参考例1の試験板は前記の通り700時間経過後であってもふくれ、はがれ、われは認められなかったのに対して、参考例5の試験板はより長期間である900時間経過後であってもふくれ、はがれ、われは認められなかった。このように、水系防錆塗料の下層に水系ジンクリッチ塗料の塗膜を形成し、かつ水系防錆塗料の上層に水系フッ素樹脂塗料の塗膜を形成すると、水系防錆塗料による優れた耐食性をより一層長期間にわたって発揮させることができることが理解できる。
(Corrosion resistance test)
Each of the prepared reference example 5 and the test plate of reference example 1 as a comparative object was subjected to JIS K 5600-7-1 (General coating test method—Part 7: Long-term durability of the coating film—Section 1: Medium-resistant salt spray) For 700 hours. As a result, the test plate of Reference Example 1 was not blistered, peeled off, or cracked even after 700 hours, as described above, whereas the test plate of Reference Example 5 was 900 hours, which was longer. Even after the passage, blistering, peeling, and me were not recognized. In this way, when a water-based zinc rich paint film is formed in the lower layer of the water-based anti-corrosion paint, and a water-based fluororesin paint film is formed in the upper layer of the water-based anti-corrosion paint, excellent corrosion resistance due to the water-based anti-corrosion paint is obtained. It can be understood that it can be exhibited for a longer period of time.
(実施例6)
サンドブラスト板(150mm×70mm×t3.2mm、軟鋼板)の表面を研磨紙P280で研磨処理した後にシリコーングリース(商品名「シリコングリス」、竹中エンジニアリング株式会社製)を塗布厚が約2μmとなるように摺り込んで、駐車設備の通常使用によるシリコーン化合物の付着量を遥かに超える被検体を作製した。
(Example 6)
The surface of a sandblast plate (150 mm × 70 mm × t3.2 mm, mild steel plate) is polished with polishing paper P280, and then silicone grease (trade name “silicone grease”, manufactured by Takenaka Engineering Co., Ltd.) is applied to a thickness of about 2 μm. A specimen was produced that far exceeded the amount of silicone compound deposited by normal use of parking facilities.
この被検体の表面でメラミン系樹脂の多孔質体(商品名「お掃除消しゴム」、アズマ工業株式会社製)を水に湿らせた後に雑巾掛けの要領で摺動させて脱脂処理をした。その後、被検体の表面に水系防錆塗料として下記組成を有する1液型水系ポリウレタン樹脂塗料を乾燥膜厚が約25μmになるように1回で塗装し、塗装後、温度23℃に保たれた恒温室内で24時間乾燥させた。
<1液型水系ポリウレタン塗料>
商品名「DNTビューウレタン」、大日本塗料株式会社製、一液反応硬化形水系塗料、防錆剤「縮合リン酸アルミニウム」(テイカ株式会社製)、溶剤「水」、樹脂濃度30質量%、固形分濃度35質量%
A porous body of melamine resin (trade name “Cleaning Eraser”, manufactured by Azuma Kogyo Co., Ltd.) was moistened with water on the surface of the specimen, and then slid in the manner of a rag and degreased. Thereafter, a one-component water-based polyurethane resin paint having the following composition as a water-based anticorrosive paint was applied to the surface of the subject at a time so that the dry film thickness was about 25 μm, and the temperature was maintained at 23 ° C. after coating. It was dried in a thermostatic chamber for 24 hours.
<One-part water-based polyurethane paint>
Product name “DNT View Urethane”, manufactured by Dainippon Paint Co., Ltd., one-component reaction-curable water-based paint, rust preventive agent “condensed aluminum phosphate” (manufactured by Teika Co., Ltd.), solvent “water”, resin concentration 30% by mass, Solid content concentration 35% by mass
このようにして、被検体の表面に水系防錆塗料である1液型水系ポリウレタン樹脂塗料の塗膜を形成して、実施例6の試験板を作製した。 In this way, a test plate of Example 6 was prepared by forming a coating film of a one-component water-based polyurethane resin paint, which is a water-based anti-corrosion paint, on the surface of the subject.
(比較例3)
メラミン系樹脂の多孔質体での脱脂処理に代えて、実施例6で作製した被検体の表面を水系洗浄剤(商品名「グランダクリーナー312」の5%希釈液、ミリオン化学株式会社製)で「公共建築工事標準仕様書」に記載の「鉄鋼面の素地ごしらえC種」の条件で脱脂処理したこと以外は実施例6と基本的に同様にして比較例3の試験板を作製した。
(Comparative Example 3)
Instead of degreasing treatment with a porous melamine-based resin, the surface of the specimen prepared in Example 6 was washed with an aqueous cleaning agent (trade name “Granda Cleaner 312” 5% dilution, manufactured by Million Chemical Co., Ltd.). A test plate of Comparative Example 3 was produced basically in the same manner as in Example 6 except that the degreasing treatment was performed under the conditions of “Cement of steel surface preparation C type” described in “Public Building Construction Standard Specification”. .
(剥離試験)
実施例6及び比較例3の試験板を作製して3日経過後にカッターナイフで素地に到達するクロスカットを入れ、クロスカット部にセロハンテープ(登録商標)を貼着させた後に剥離して、1液型水系ポリウレタン樹脂塗料の塗膜が被検体から剥離するか否かを確認した。その結果、駐車設備の通常使用によるシリコーン化合物の付着量を遥かに超える被検体を用いた過酷試験において、比較例3ではクロスカット部分の大部分の塗膜が剥離したものの、実施例6ではクロスカット部分の塗膜は剥離しなかった。なお、比較例3においても過酷試験でなければ塗膜の密着性が優れることは前記の通りである。
(Peel test)
A test plate of Example 6 and Comparative Example 3 was prepared, and a crosscut reaching the substrate with a cutter knife after 3 days had passed, and after the cellophane tape (registered trademark) was adhered to the crosscut part, it was peeled off, It was confirmed whether or not the coating film of the one-component water-based polyurethane resin paint was peeled off from the specimen. As a result, in a severe test using a specimen far exceeding the amount of silicone compound deposited due to normal use of the parking facility, in Comparative Example 3, most of the coating film of the crosscut part was peeled off, but in Example 6, the cross-section was crossed. The cut film was not peeled off. In Comparative Example 3, as described above, the adhesion of the coating film is excellent unless it is a severe test.
ところで、実施例6において、メラミン系樹脂の多孔質体を水に湿らせなかった場合には実用上問題にならない程度のごく軽微な剥離を確認でき、また実施例6で作製した被検体の表面を何らの処理をすることなく1液型水系ポリウレタン樹脂塗料を塗布した場合にはクロスカット部分全体が剥離したことを確認した。 By the way, in Example 6, when the porous body of the melamine resin was not wetted with water, it was possible to confirm very slight peeling that would not cause a problem in practice, and the surface of the specimen prepared in Example 6 was confirmed. It was confirmed that the entire cross-cut portion was peeled off when the one-component water-based polyurethane resin paint was applied without any treatment.
実施例6の試験板は、参考例1等と同様に耐食性に優れていた。 The test plate of Example 6 was excellent in corrosion resistance as in Reference Example 1 and the like.
(実施例7)
機械式駐車設備の既存のものである多段式駐車設備(屋外設置)のパレット(鉄鋼製)の改修工事において、シリコーン化合物が大量に付着しているパレット表面でメラミン系樹脂の多孔質体(商品名「激落ち君」、レック株式会社製)をそのまま、又は、水に湿らせた後に雑巾掛けの要領で摺動させて、パレット表面を脱脂処理した。その後、被検体の表面に実施例6と同様の1液型水系ポリウレタン樹脂塗料を乾燥膜厚が約25μmになるように1回で塗装し、塗装後、温度25℃で24時間乾燥させ、多段式駐車設備を改修した。
(Example 7)
A porous melamine resin (product) on the surface of a pallet to which a large amount of silicone compound is adhered in the repair work of a pallet (made of steel) of a multi-level parking facility (outdoor installation) which is an existing mechanical parking facility The pallet surface was degreased by slid the name “Gekiki-kun” (manufactured by Lek Co., Ltd.) as it was or after being dampened in water and sliding it with a rag. Thereafter, the same one-component water-based polyurethane resin paint as in Example 6 was applied to the surface of the subject at a time so that the dry film thickness was about 25 μm, and then dried at a temperature of 25 ° C. for 24 hours. Refurbished parking facilities.
(比較例4)
メラミン系樹脂の多孔質体での脱脂処理に代えて下記脱脂処理等をしたこと以外は実施例7と基本的に同様にして比較例4−1〜4−5の試験板それぞれを作製した。
比較例4−1:有機溶剤(ノルマルヘキサン50質量%、キシレン30質量%及びイソプロピルアルコール20質量%)での脱脂処理
比較例4−2:比較例3で使用した水系洗浄剤での脱脂処理
比較例4−3:不織布研磨材(商品名「スコッチブライト」、住友3M株式会社製、P320相当)でのケレン処理
比較例4−4:ウエス(乾燥済み)での拭き取り処理
比較例4−5:脱脂処理未実施
(Comparative Example 4)
Test plates of Comparative Examples 4-1 to 4-5 were prepared in substantially the same manner as in Example 7 except that the following degreasing treatment and the like were performed instead of the degreasing treatment with the porous body of the melamine resin.
Comparative Example 4-1: Degreasing treatment with organic solvent (normal hexane 50% by mass, xylene 30% by mass and isopropyl alcohol 20% by mass) Comparative Example 4-2: Comparison of degreasing treatment with aqueous detergent used in Comparative Example 3 Example 4-3: Keren treatment comparative example with nonwoven fabric abrasive (trade name “Scotch Bright”, manufactured by Sumitomo 3M Co., Ltd., P320 equivalent) 4-4: Wipe (dried) wiping treatment comparative example 4-5: No degreasing treatment
(はじき評価)
実施例7及び比較例4−1〜4−5において1液型水系ポリウレタン樹脂塗料を塗布したときに1液型水系ポリウレタン樹脂塗料がはじかれるか否かを目視で評価した。その結果、実施例7においてはメラミン系樹脂の多孔質体をそのまま用いても、また水に湿らせて用いても、1液型水系ポリウレタン樹脂塗料ははじかれることなく塗布されていた。また比較例4のうち、有機溶剤で脱脂処理した場合(比較例4−1)及び不織布研磨材で脱脂処理した場合(比較例4−3)には1液型水系ポリウレタン樹脂塗料ははじかれなかったが、水系洗浄剤で脱脂処理した場合(比較例4−2)、ウエスのみで拭き取り処理した場合(比較例4−4)、脱脂処理を実施しなかった場合(比較例4−5)は1液型水系ポリウレタン樹脂塗料ははじかれていた。
(Repel evaluation)
In Example 7 and Comparative Examples 4-1 to 4-5, it was visually evaluated whether or not the one-component aqueous polyurethane resin paint was repelled when the one-component aqueous polyurethane resin paint was applied. As a result, in Example 7, the one-component water-based polyurethane resin coating was applied without being repelled whether the melamine-based resin porous material was used as it was or wetted with water. In Comparative Example 4, the one-part aqueous polyurethane resin paint is not repelled when degreased with an organic solvent (Comparative Example 4-1) and when degreased with a nonwoven fabric abrasive (Comparative Example 4-3). However, when degreasing with an aqueous detergent (Comparative Example 4-2), when wiping with only a waste (Comparative Example 4-4), when not degreasing (Comparative Example 4-5) The one-component water-based polyurethane resin paint was repelled.
(剥離試験)
実施例6と同様にして剥離試験を実施したところ、実施例7の試験片はいずれも剥離しなかったのに対して、比較例4−1〜4−5の試験片はいずれも剥離した。なお、実施例7の試験板はいずれも参考例1等と同様に耐食性に優れていた。
(Peel test)
When a peel test was performed in the same manner as in Example 6, none of the test pieces of Example 7 peeled, whereas all of the test pieces of Comparative Examples 4-1 to 4-5 peeled. In addition, all the test plates of Example 7 were excellent in corrosion resistance as in Reference Example 1 and the like.
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