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JP6069686B2 - Method and apparatus for producing active aqueous solution for animals and plants - Google Patents
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JP6069686B2 - Method and apparatus for producing active aqueous solution for animals and plants - Google Patents

Method and apparatus for producing active aqueous solution for animals and plants Download PDF

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JP6069686B2
JP6069686B2 JP2012054388A JP2012054388A JP6069686B2 JP 6069686 B2 JP6069686 B2 JP 6069686B2 JP 2012054388 A JP2012054388 A JP 2012054388A JP 2012054388 A JP2012054388 A JP 2012054388A JP 6069686 B2 JP6069686 B2 JP 6069686B2
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aqueous solution
hydrogen water
water
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reduced glutathione
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博 椛澤
博 椛澤
広 藤極
広 藤極
理沙 椛澤
理沙 椛澤
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有限会社 シリーズ
有限会社 シリーズ
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Description

本発明は、動物・植物の成長に寄与する水溶液の製造方法及び装置に関するものである。   The present invention relates to a method and apparatus for producing an aqueous solution that contributes to the growth of animals and plants.

従来、植物特に花卉など花瓶に挿した花を長持ちさせるには、水溶性の栄養剤を溶解した延命剤が用いられてきた。その延命剤の主な成分としては、高級アルコールエチレンオキサイド、脂肪酸エチレンオキサイド、脂肪酸アミドエチレンオキサイド、アルキルフェノールエチレンオキサイド、多価アルコール脂肪酸エステルエチレンオキサイド、高級アルキルアミンエチレンオキサイド、ポリプロピレングリコールエチレンオキサイドがある。このような花卉などの植物を長持ちさせる従来の技術としては、例えば下記特許文献1に記載されたものがある。   Conventionally, life prolonging agents in which water-soluble nutrients are dissolved have been used for long-lasting flowers inserted in a vase such as plants and flowers. Main components of the life prolonging agent include higher alcohol ethylene oxide, fatty acid ethylene oxide, fatty acid amide ethylene oxide, alkylphenol ethylene oxide, polyhydric alcohol fatty acid ester ethylene oxide, higher alkylamine ethylene oxide, and polypropylene glycol ethylene oxide. As a conventional technique for prolonging plants such as flower buds, for example, there is one described in Patent Document 1 below.

また、動物においての水溶性活性効果のある水溶液として、ペクチン、カラギーナン、カゼイン、カードラン、アルギン酸類、大豆多糖類、プルラン、セルロース類、キサンタンガム、カルメロース塩、ポリグリセリンエステル類、ショ糖脂肪酸エステル類、ソルビタン脂肪酸エステル類、グリコール脂肪酸エステル類がある。その他、動物においての水溶性活性効果のある水溶液として、ビタミンB群として、B1 (チアミン) 、 B2 (リボフラビン)、B3 (ナイアシン、ニコチンアミド)、 B5 (パントテン酸, デクスパンテノール、パンテチン)、 B6 (ピリドキシン、ピリドキサールリン酸、ピリドキサミン)、B7 (ビオチン) 、 B9 (葉酸、ジヒドロ葉酸) 、 B12 (シアノコバラミン、ヒドロキソコバラミン、メチルコバラミン)がある。また、さらに他の、動物においての水溶性活性効果のある水溶液として、ビタミンC群として; アスコルビン酸 ・ デヒドロアスコルビン酸等があった。   In addition, aqueous solutions having water-soluble activity effects in animals include pectin, carrageenan, casein, curdlan, alginic acids, soybean polysaccharides, pullulan, celluloses, xanthan gum, carmellose salts, polyglycerin esters, sucrose fatty acid esters. And sorbitan fatty acid esters and glycol fatty acid esters. In addition, as an aqueous solution with water-soluble activity effect in animals, as vitamin B group, B1 (thiamine), B2 (riboflavin), B3 (niacin, nicotinamide), B5 (pantothenic acid, dexpantenol, pantethine), B6 (Pyridoxine, pyridoxal phosphate, pyridoxamine), B7 (biotin), B9 (folic acid, dihydrofolic acid), B12 (cyanocobalamin, hydroxocobalamin, methylcobalamin). As other aqueous solutions having water-soluble activity effects in animals, there were vitamin C group; ascorbic acid / dehydroascorbic acid and the like.

動物の生物種により、たとえばビタミンCはヒトではビタミンであるが、犬はビタミンCを体内で合成できる。その他、活性物質としては、抗酸化作用のある物質として酵素、ビタミン、植物栄養素の3種類がある。   Depending on the animal species, for example, vitamin C is a vitamin in humans, but dogs can synthesize vitamin C in the body. In addition, as active substances, there are three types of substances having an antioxidant action, enzymes, vitamins, and phytonutrients.

特開2007−153793JP2007-153793

動植物の生命体の細胞レベルにおいては、過度な活性物質は、生命体の各部位において、ときにはリスクを伴う場合がある。   At the cellular level of animal and plant life forms, excessively active substances can sometimes be risky at each part of the life form.

速やかな活性化物質としては、動物、植物に共通する活性特性を示す抗酸化作用のある水素水が近年見直されてきたが、製造後の時間経過に伴い分解、酸化により酸化還元電位の変化(劣化)により動植物に対する効果、つまりその抗酸化力だけ見てもその作用にバラ付きがあった。このような現状から動植物生体用の安定した抗酸化力、さらに新たな活性特性物質が含まれる水溶液の製造方法が望まれていた。   As a rapid activator, hydrogen water having an antioxidative action showing activity characteristics common to animals and plants has been reviewed in recent years. However, with the passage of time after production, the redox potential changes due to decomposition and oxidation ( The effect on animals and plants, that is, its anti-oxidation power, varies due to deterioration. Under such circumstances, there has been a demand for a method for producing an aqueous solution containing a stable antioxidant power for animals and plants and a new active characteristic substance.

本発明は上記従来の課題に鑑みてなされたもので、その目的は、動物・植物の成長、或いは長期間の生存に寄与する生体用活性水溶液の製造方法及び装置を提供することである。   The present invention has been made in view of the above-described conventional problems, and an object thereof is to provide a method and apparatus for producing a biologically active aqueous solution that contributes to animal / plant growth or long-term survival.

本発明は、上述のような課題を解決する動物・植物の成長に寄与する水溶液の製造方法であり、生体の成長に妨げとなる活性酸素を除去する抗酸化物質が含まれる水溶液の製造方法であり、非常に安価で確実に動物・植物の成長と代謝、及び延命など生体細胞の活性化に効果のある水溶液を提供する。本生体用活性水溶液に含まれる成分の還元型グルタチオンは、生命体内で解毒作用と抗酸化作用に機能し、グルタチオンと細胞内タンパク質の結合を促進する酸化型グルタチオンが農作物の収穫量を大幅に向上させる。また、還元型グルタチオンは、活性酸素などにより酸化型グルタチオンとなり、後に生命体の活性物質となる。   The present invention is a method for producing an aqueous solution that contributes to the growth of animals and plants that solves the above-described problems, and a method for producing an aqueous solution containing an antioxidant that removes active oxygen that hinders the growth of a living body. The present invention provides an aqueous solution that is very inexpensive and surely effective in activating living cells such as growth and metabolism of animals and plants, and life extension. Reduced glutathione, a component of this biologically active aqueous solution, functions as a detoxification and antioxidant effect in living organisms. Oxidized glutathione, which promotes the binding of glutathione and intracellular proteins, greatly improves crop yields. Let Reduced glutathione becomes oxidized glutathione by active oxygen or the like, and later becomes an active substance of a living organism.

また、本発明は上述のような課題を解決するため、新たな活性特性を示す生体用活性水溶液の製造方法として、活性水溶液製造から6ヵ月〜1年は安定であり、酸化還元電位が、-350mVを維持することが可能な動植物生体用活性水溶液を製造するものである。   Further, in order to solve the above-mentioned problems, the present invention is a method for producing a biologically active aqueous solution exhibiting new activity characteristics, which is stable for 6 months to 1 year from the production of the active aqueous solution, and the redox potential is- An active aqueous solution for animal and plant organisms capable of maintaining 350 mV is produced.

本発明によれば、花卉などの植物を生体用活性水溶液に挿しておくことにより、1週間以上は長持ちさせることができる。本発明の生体用活性水溶液は、植物の根付苗、挿し木、花卉などに有効であり、挿し木の場合冠水してから苗床に挿した場合の成功率が格段に上がる。また、根付苗・花卉は開花後も長期に咲かせることができ、その果実(種)の成長もよく、採取した種による実生の発芽発生率も向上する。さらに、果樹、園芸品種、種苗産業の研究者など開花後も長期に咲かせることができ、花の延命、及び結実の成功率向上により、果樹・種子の生産量の増加が期待できる。   According to the present invention, by inserting a plant such as a flower bud into a biologically active aqueous solution, it can last longer than one week. The biologically active aqueous solution of the present invention is effective for plant rooting seedlings, cuttings, flower buds, etc., and in the case of cuttings, the success rate when submerged and then inserted into the nursery is significantly increased. In addition, rooted seedlings and flower buds can be made to bloom for a long time after flowering, the fruit (seed) grows well, and the germination rate of seedlings by the collected seeds improves. In addition, fruit trees, horticultural varieties, seedling industry researchers, etc. can be made to bloom for a long time after flowering, and the increase in fruit tree / seed production can be expected by extending the life of flowers and improving the success rate of fruit set.

また、養鶏、養豚、酪農などの飼育において成長に寄与し、有効で安全な飼育が可能で本発明の水溶液に含まれる成分により、インフルエンザの対策、家畜の繁殖(採卵、受胎)にも有効であり、動物園の種の保存として、絶滅危惧動物の繁殖に期待が持てる。尚、動物の場合は飲料水となる。   In addition, it contributes to growth in breeding such as poultry farming, pig farming, and dairy farming, enabling effective and safe breeding, and the ingredients contained in the aqueous solution of the present invention are effective for influenza countermeasures and livestock breeding (egg collection, conception). Yes, it can be expected to breed endangered animals as preservation of zoo species. In the case of animals, it is drinking water.

本発明の一実施の形態に係る動植物生体用活性水溶液の製造装置の全体構成を概略的に示す概念図である。BRIEF DESCRIPTION OF THE DRAWINGS It is a conceptual diagram which shows roughly the whole structure of the manufacturing apparatus of the active water solution for animal and plant biological bodies which concerns on one embodiment of this invention. 上記製造装置に組み込まれる水素水発生器を正面側から見た断面図である。It is sectional drawing which looked at the hydrogenous water generator integrated in the said manufacturing apparatus from the front side. 上記製造装置に組み込まれる水素水発生器のカソード電極槽平面図である。It is a cathode electrode tank top view of the hydrogen water generator integrated in the said manufacturing apparatus. 上記製造装置の水素水発生器に備えられたカソード電極及びアノード電極を示す平面図である。It is a top view which shows the cathode electrode and anode electrode with which the hydrogen water generator of the said manufacturing apparatus was equipped. 上記製造装置のエグゼクタ部分における流体の混合流れ部分を示す断面図である。It is sectional drawing which shows the fluid mixing flow part in the ejector part of the said manufacturing apparatus. 電流値を固定して時間経過に沿ってデューティを変えて電流を印加する例を示す図である。It is a figure which shows the example which fixes an electric current value and changes a duty along time passage and applies an electric current.

以下、本発明の一実施の形態について図面を参照して説明する。図1は本発明の実施に用いられる動植物生体用活性水溶液の製造装置の全体構成を概略的に示す概念図である。この実施の形態に係る製造装置は、水素水発生器1と、この水素水発生器1に管路6を介して接続され当該水素水発生器1により生成された水素水を還元型グルタチオン混合液と混合させるエグゼクタ2と、水素水発生器1に対して並列にエグゼクタ2に管路6を介して接続され還元型グルタチオン混合液を生成し又は保持するグルタチオン溶液タンク3と、エグゼクタ2に管路6を介して接続され当該エグゼクタ2において混合された水素水・還元型グルタチオン混合水溶液を管路6に沿って送給する定量ポンプ4と、定量ポンプ4に管路6を介して接続され定量ポンプ4により送給された水素水・還元型グルタチオン混合水溶液を貯留するタンク部材5を備えて成る。   Hereinafter, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a conceptual diagram schematically showing the overall configuration of an apparatus for producing an active aqueous solution for animals and plants used in the practice of the present invention. The manufacturing apparatus according to this embodiment includes a hydrogenated water generator 1 and hydrogen water generated by the hydrogenated water generator 1 connected to the hydrogenated water generator 1 via a pipe 6 in a reduced glutathione mixture. , The glutathione solution tank 3 for generating or holding the reduced glutathione mixed solution connected to the executor 2 via the pipe 6 in parallel to the hydrogen water generator 1, and the pipe to the executor 2. 6 and a metering pump 4 for feeding a hydrogen water / reduced glutathione mixed aqueous solution mixed in the executor 2 along the pipe 6 and a metering pump connected to the metering pump 4 via the pipe 6. 4 is provided with a tank member 5 for storing the hydrogen water / reduced glutathione mixed aqueous solution fed by 4.

図2及び図3は上記製造装置に組み込まれる水素水発生器1の構造を示す図で、図2は、上記製造装置に組み込まれる水素水発生器1を正面側から見た断面図、図3は上記製造装置に組み込まれる水素水発生器のカソード電極槽平面図である。また、図4は上記水素水発生器1の構成要素のうち、特にカソード電極及びアノード電極を示す平面図である。   2 and 3 are views showing the structure of the hydrogen water generator 1 incorporated in the production apparatus, and FIG. 2 is a cross-sectional view of the hydrogen water generator 1 incorporated in the production apparatus as seen from the front side. FIG. 4 is a plan view of a cathode electrode tank of a hydrogen water generator incorporated in the manufacturing apparatus. FIG. 4 is a plan view showing a cathode electrode and an anode electrode among the components of the hydrogen water generator 1.

本実施の形態に係る水素水発生器1は、装置本体としての電解槽10と、電解槽10の内部の中段部位付近に配置されたカソード電極11と、電解槽10の内部において、前記カソード電極11の下方位置に配置されたアノード電極12と、前記カソード電極11とアノード電極12との間に配置された隔膜13と、前記隔膜13の上側に近接して配置された容器部材14とを備えている。   The hydrogen water generator 1 according to the present embodiment includes an electrolytic cell 10 as an apparatus main body, a cathode electrode 11 disposed in the vicinity of a middle stage in the electrolytic cell 10, and the cathode electrode in the electrolytic cell 10. 11, an anode electrode 12 disposed below the diaphragm 11, a diaphragm 13 disposed between the cathode electrode 11 and the anode electrode 12, and a container member 14 disposed close to the upper side of the diaphragm 13. ing.

この水素水発生器1において、カソード電極11とアノード電極12とは平板構造を有し、また、上下位置関係で対(つい)の構成になっている。また、カソード電極11とアノード電極12とは、図4に示すように、平板構造の電極本体に枝状のスリット25が設けられている。さらに、カソード電極11は、その側方から見たとき、平板構造の電極本体部分が図1の正面図で見て左方から右方へ上がる傾斜構造に形成される一方、アノード電極12は、その側方から見たとき、平板構造の電極本体部分が図1の正面図で見て右方から左方へ上がる傾斜構造に形成されることにより、アノード電極12とカソード電極11とは相互に非平行に配置されている。   In the hydrogen water generator 1, the cathode electrode 11 and the anode electrode 12 have a flat plate structure, and have a paired configuration with respect to the vertical position. Moreover, as shown in FIG. 4, the cathode electrode 11 and the anode electrode 12 are provided with a branch-like slit 25 in an electrode body having a flat plate structure. Further, the cathode electrode 11 is formed in an inclined structure in which the electrode body portion of the flat plate structure rises from the left to the right as viewed in the front view of FIG. When viewed from the side, the electrode body portion of the flat plate structure is formed in an inclined structure that rises from the right to the left as viewed in the front view of FIG. 1, so that the anode electrode 12 and the cathode electrode 11 are mutually connected. They are arranged non-parallel.

隔膜13は水透過性の材料から構成されている。また容器部材14は、多孔質材料からなり、内部が空洞で開閉可能な閉鎖構造を有する一方、その端部に補充口15を有している。したがって、容器部材14は、内部に水反応性或いは水混合性の材料を収容可能である一方で、水が内部へ浸透することができる機能を有する。この実施の形態においては、容器部材14には、補充口15を通して還元型グルタチオン溶液16が封入される。
隔膜13と容器部材14とは上下関係にほとんど接するように配置されることにより、電解槽10の底部から供給された水をろ過させつつ還元型グルタチオン混合液と混合させるろ過・混合ユニットを形成する。なお、図2中、符号17はカソード電極11に電流を供給するカソードリード線、18はアノード電極12に電流を供給するアノードリード線をそれぞれ示す。カソードリード線17は電源のマイナス電極に接続され、アノードリード線18は電源のプラス電極に接続される。
The diaphragm 13 is made of a water permeable material. The container member 14 is made of a porous material and has a closed structure that can be opened and closed with a hollow inside, and has a replenishing port 15 at an end thereof. Accordingly, the container member 14 has a function of allowing water to permeate into the inside while accommodating a water-reactive or water-mixable material therein. In this embodiment, the reduced glutathione solution 16 is sealed in the container member 14 through the replenishing port 15.
The diaphragm 13 and the container member 14 are arranged so as to be almost in contact with each other in a vertical relationship, thereby forming a filtration / mixing unit that mixes the reduced glutathione mixed solution while filtering the water supplied from the bottom of the electrolytic cell 10. . In FIG. 2, reference numeral 17 denotes a cathode lead wire that supplies current to the cathode electrode 11, and 18 denotes an anode lead wire that supplies current to the anode electrode 12. The cathode lead wire 17 is connected to the negative electrode of the power source, and the anode lead wire 18 is connected to the positive electrode of the power source.

電解槽10には、当該電解槽10の底部付近に設けられ当該電解槽10に原水19を供給する第1原水供給口21と、電解槽10の中段部位付近に設けられ当該電解槽10に原水19を供給する第2原水供給口22と、電解槽10の上端部付近に設けられ当該電解槽10において生成された水素水20を排出する水素水取出し口23と、電解槽10の中段部位付近に、上記第2原水供給口22とは別に設けられ、電解槽10内に滞留した水を排出する排水口24とが設けられている。第2原水供給口22は、容器部材14よりも上側の電解槽10の部位に設けられている。また、排水口24は、隔膜13及び容器部材14のユニットよりも下側の電解槽10の部位に設けられている。   The electrolytic cell 10 is provided in the vicinity of the bottom of the electrolytic cell 10, a first raw water supply port 21 that supplies the raw water 19 to the electrolytic cell 10, and is provided in the vicinity of the middle part of the electrolytic cell 10. 19, a second raw water supply port 22 for supplying 19, a hydrogen water outlet 23 provided near the upper end of the electrolytic cell 10 for discharging the hydrogen water 20 generated in the electrolytic cell 10, and a vicinity of the middle part of the electrolytic cell 10 In addition, a drain port 24 is provided separately from the second raw water supply port 22 and discharges the water remaining in the electrolytic cell 10. The second raw water supply port 22 is provided in a portion of the electrolytic cell 10 above the container member 14. Further, the drain port 24 is provided in a portion of the electrolytic cell 10 below the unit of the diaphragm 13 and the container member 14.

以上のような構成を有する動植物生体用活性水溶液の製造装置について、動作を説明する。容器部材14には還元型グルタチオン水溶液16が封入されるがこの還元型グルタチオン水溶液16は、濃度40〜70%のエタノール水溶液に還元型グルタチオン粉末を5〜10%混合させて生成される混合溶液(基材1)である。他方グルタチオン溶液タンク3には、事前に採取された水素水100重量部に、基材1を10〜20重量部添加して生成された還元型グルタチオン混合溶液28(基材2)が収容されている。電解槽10には、第1原水供給口21及び第2原水供給口22に原水19が供給され、電解槽10に満たされる。原水19が電解槽10に満たされると、カソード電極11(マイナス側)にはカソードリード線17を介して電流が供給され、アノード電極12(プラス側)にはアノードリード線18を介して電流が供給される。これにより原水19は、電解槽10内で電気分解され、カソード電極11付近には水素とヒドリド(hydride,H-)の濃度が高い水(水素水20)が生成される一方、アノード電極12付近には酸素濃度が高い水(酸素水)が生成される。そして、水素水20は、水素水取出し口23の下流側に接続された定量ポンプ4の吸引動作と第2原水供給口22の原水19により電解槽10内で生じる流体の流れにより、電解槽10内において、容器部材14から流出した還元型グルタチオン水溶液16と混合される。水素水20は水素水取出し口23から流出し、管路6を通ってエグゼクタ2に到達し、そこでグルタチオン溶液タンク3から供給された還元型グルタチオン混合溶液28と混合する。
還元型グルタチオン混合溶液28と水素水20との混合割合は、エグゼクタ2の構成により、水素水100重量部に、基材2を10〜20重量部添加した混合割合であり、これにより本発明の生体用活性水溶液が生成される。この生体用活性水溶液はタンク部材5に貯留される。
図5は、エゼクタ2(混合器)の動作原理を説明する図である。この図に示されているように、水素水20と還元型グルタチオン混合液28は、管内の所定のスロート部(のど)26と合流部のノズル27により形成されたエグゼクタ2により上述した混合割合で混合される。混合されてできた生体用活性水溶液は定量ポンプ4の吸引動作により取り出され、タンク部材5に貯留される。
Operation | movement is demonstrated about the manufacturing apparatus of the active water solution for animal and plant living bodies which has the above structures. The reduced glutathione aqueous solution 16 is sealed in the container member 14, and this reduced glutathione aqueous solution 16 is a mixed solution produced by mixing 5 to 10% of reduced glutathione powder with an aqueous ethanol solution having a concentration of 40 to 70% ( Substrate 1). On the other hand, the glutathione solution tank 3 contains a reduced glutathione mixed solution 28 (base material 2) produced by adding 10 to 20 parts by weight of the base material 1 to 100 parts by weight of hydrogen water collected in advance. Yes. In the electrolytic cell 10, the raw water 19 is supplied to the first raw water supply port 21 and the second raw water supply port 22 to fill the electrolytic cell 10. When the raw water 19 is filled in the electrolytic cell 10, current is supplied to the cathode electrode 11 (minus side) via the cathode lead wire 17, and current is supplied to the anode electrode 12 (plus side) via the anode lead wire 18. Supplied. As a result, the raw water 19 is electrolyzed in the electrolytic cell 10, and water (hydrogen water 20) having a high concentration of hydrogen and hydride (hydride, H−) is generated in the vicinity of the cathode electrode 11, while in the vicinity of the anode electrode 12. In this case, water having a high oxygen concentration (oxygen water) is generated. Then, the hydrogen water 20 is produced by the suction operation of the metering pump 4 connected to the downstream side of the hydrogen water outlet 23 and the flow of fluid generated in the electrolytic cell 10 by the raw water 19 of the second raw water supply port 22. Inside, it is mixed with the reduced glutathione aqueous solution 16 that has flowed out of the container member 14. The hydrogen water 20 flows out from the hydrogen water outlet 23, reaches the executor 2 through the pipe 6, and is mixed therewith with the reduced glutathione mixed solution 28 supplied from the glutathione solution tank 3.
The mixing ratio of the reduced glutathione mixed solution 28 and the hydrogen water 20 is a mixing ratio in which 10 to 20 parts by weight of the base material 2 is added to 100 parts by weight of the hydrogen water depending on the configuration of the executor 2. A bioactive aqueous solution is produced. This biologically active aqueous solution is stored in the tank member 5.
FIG. 5 is a diagram for explaining the operating principle of the ejector 2 (mixer). As shown in this figure, the hydrogen water 20 and the reduced glutathione mixed liquid 28 are mixed at the mixing ratio described above by the executor 2 formed by a predetermined throat portion (throat) 26 in the pipe and the nozzle 27 of the merging portion. Mixed. The bioactive aqueous solution formed by mixing is taken out by the suction operation of the metering pump 4 and stored in the tank member 5.

なお、上述のカソード電極11(マイナス側)及びアノード電極12(プラス側)への電流供給に際して、アノード電極とカソード電極間には、例えば直流でデューティ70〜90%の電流を印加すると効果的である。図6は電流値を固定して時間経過に沿ってデューティを変えて電流を印加する例を示す図である。図6に示す例では電流値を20A(アンペア)とし、デューティ75%として電流を印加している。この他にも、例えばパラメータとして20Aとか25Aどちらか一方を選択しデューティ70・75・80・90%を選択する事により電解の仕事量を変化させることもできる。電解の仕事量は、電解の運転中の水温の上昇、原水水質の違い、大気圧によっても変化する為に原水に合う経験値を探す必要がある。消費電力の増大と、水素水20の生成量との関係は必ずしも比例の関係にはらず、熱エネルギーで消費される部分もある。   When supplying current to the cathode electrode 11 (minus side) and the anode electrode 12 (plus side) described above, it is effective to apply, for example, a current of 70 to 90% with a direct current between the anode electrode and the cathode electrode. is there. FIG. 6 is a diagram illustrating an example in which the current is fixed and the current is applied while changing the duty over time. In the example shown in FIG. 6, the current value is 20 A (ampere) and the current is applied with a duty of 75%. In addition to this, for example, by selecting either 20A or 25A as a parameter and selecting a duty of 70, 75, 80, or 90%, the work of electrolysis can be changed. Since the work of electrolysis changes depending on the rise of water temperature, the difference in raw water quality, and atmospheric pressure during electrolysis, it is necessary to find an experience value that matches the raw water. The relationship between the increase in power consumption and the amount of hydrogen water 20 produced is not necessarily a proportional relationship, and there is a portion consumed by thermal energy.

また、水素水20の劣化についての実験を行った。この実験では、酸化還元電位は、HANNA-Instrument社製の測定器「HI 98121/Combo 3」を使って測定した。また、試料サンプルとして、水素水生成機(株式会社ササキ社製の水素水生成機「SR-1600C)」で生成した水素水を専用容器に500ml入れた物と、同じ水素水500mlに還元型グルタチオン(この実験説明においてのみ、GSHと表記する)粉末0.03gを添加した水溶液と、同じ水素水500mlにGSH粉末0.28g添加した水溶液との3種を用意して比較した。その結果は下記に示す通りである。   In addition, an experiment on deterioration of the hydrogen water 20 was performed. In this experiment, the oxidation-reduction potential was measured using a measuring instrument “HI 98121 / Combo 3” manufactured by HANNA-Instrument. In addition, as a sample sample, 500 ml of hydrogen water produced by a hydrogen water generator (hydrogen water generator “SR-1600C” manufactured by Sasaki Co., Ltd.) is put in a dedicated container, and reduced glutathione is added to 500 ml of the same hydrogen water. Three types of an aqueous solution added with 0.03 g of powder (denoted as GSH only in this experimental description) and an aqueous solution added with 0.28 g of GSH powder in 500 ml of the same hydrogen water were prepared and compared. The results are as shown below.

「水素水GSH添加量−経過時間比較」 酸化還元電位(単位mV)
水素水GSH添加量\経過時間 72h 96h 120h
GSH 0.00g −306mV −254mV −206mV
GSH 0.03g −456mV −416mV −324mV
GSH 0.28g −460mV −450mV −435mV
“Hydrogen water GSH addition amount vs. elapsed time”
Addition amount of hydrogen water GSH \ Elapsed time 72h 96h 120h
GSH 0.00g -306mV -254mV -206mV
GSH 0.03g -456mV -416mV -324mV
GSH 0.28g -460mV -450mV -435mV

この実験結果により、120時間経過後のGSH0.28g添加した水素水の酸化還元電位−435mVで劣化が少なく有効であった。   As a result of this experiment, the oxidation-reduction potential of -435 mV of hydrogen water added with 0.28 g of GSH after 120 hours was effective with little deterioration.

また、容器部材14に封入される還元型グルタチオン水溶液16には、この還元型グルタチオン水溶液16 (基材1)に対して、グリチルリチン酸2Kを、還元型グルタチオンとの混合比1:2〜1:5で混合、すなわち、
グリチルリチン酸2K:還元型グルタチオン=1:2〜1:5
の混合比で混合するとより効果の高い動植物生体用活性水溶液が得られる。
Further, in the reduced glutathione aqueous solution 16 enclosed in the container member 14, the mixing ratio of glycyrrhizic acid 2K and reduced glutathione to the reduced glutathione aqueous solution 16 (base material 1) is 1: 2 to 1: 5 mixed, ie
Glycyrrhizic acid 2K: reduced glutathione = 1: 2 to 1: 5
When mixed at a mixing ratio of 2, an active aqueous solution for animal and plant organisms with higher effectiveness can be obtained.

この点に関し、活性酸素は、植物や動物の生体内にあって、細菌やウィルス、カビなどの異物が体内に侵入してきた際には、それらから守ってくれる役割をしている為、活性酸素の働きで生体の健康を保つ上で適度に必要とされ、また余分な活性酸素を除去しバランスを保つ必要もある。活性水素水を大量に与えた場合生体の活性酸素の働きを阻害し、異物が体内に侵入してきた際には、それらから守ってくれる役割を担うことができない場合があり、グリチルリチン酸2Kの働きで、これらの細菌やウィルス、カビなどの異物を除去、抗炎症作用、殺菌する為に有効である。また、水素水と、還元型グルタチオンと、グリチルリチン酸2Kの3種混合水溶液は、水素水の還元力の低下を招くことが無い物質の為、生体の活性に特に有効である。
以上より、本発明の生体用活性水溶液は、植物の根付苗、挿し木、花卉などに有効であり、挿し木の場合冠水してから苗床に挿した場合の成功率が格段に上がる。また、根付苗・花卉は開花後も長期に咲かせることができ、その果実(種)の成長もよく、採取した種による実生の発芽発生率も向上する。
In this regard, active oxygen is in the living body of plants and animals, and when foreign substances such as bacteria, viruses, and mold enter the body, it plays a role in protecting it from active oxygen. Therefore, it is necessary to maintain a healthy body, and it is also necessary to remove excess active oxygen and maintain balance. When a large amount of active hydrogen water is given, it inhibits the action of active oxygen in the body, and when a foreign substance enters the body, it may not be able to play a role to protect it, and the action of glycyrrhizic acid 2K Therefore, it is effective for removing foreign substances such as bacteria, viruses and molds, anti-inflammatory action and sterilization. In addition, a three-component mixed aqueous solution of hydrogen water, reduced glutathione, and glycyrrhizic acid 2K is particularly effective for biological activity because it does not cause a reduction in the reducing power of hydrogen water.
As described above, the biologically active aqueous solution of the present invention is effective for plant rooting seedlings, cuttings, flower buds, and the like, and the success rate when the seedlings are submerged and then inserted into the nursery is significantly increased. In addition, rooted seedlings and flower buds can be made to bloom for a long time after flowering, the fruit (seed) grows well, and the germination rate of seedlings by the collected seeds improves.

本発明の生体用活性水溶液を使った実験用にバラの植木を使い開花後何日間花を咲かせられるか実験を行い、通常3〜4日で花弁が散り始めるが、本発明の生体用活性水溶液を根元に散布した結果、7.5日間咲いていた。また、サンシュユ(山茱萸、学名:Cornus officinalis Sieb. et Zucc.)の枝物花卉を活けて開花まで観察した。水道水で活けた方は、開花までに蕾が落ちてしまったが、本発明の生体用活性水溶液を使用した方は、開花してさらに3〜4日維持できた。   For experiments using the biologically active aqueous solution of the present invention, an experiment was conducted to determine how many days a flower can bloom after flowering using a rose plant, and the petals usually start to scatter in 3 to 4 days. As a result of spraying on the roots, it bloomed for 7.5 days. In addition, the branch flower buds of Sanshuyu (Yamabuchi, scientific name: Cornus officinalis Sieb. Et Zucc.) Were used and observed until flowering. Those who were able to make use of tap water had their wrinkles dropped by flowering, but those who used the biologically active aqueous solution of the present invention were able to bloom and maintain for 3 to 4 days.

本発明の生体用活性水溶液は、植物の根付苗、挿し木、花卉などに有効であり、挿し木の場合冠水してから苗床に挿した場合の成功率が格段に上がる。また、根付苗・花卉は開花後も長期に咲かせることができ、その果実(種)の成長もよく、採取した種による実生の発芽発生率も向上する等、利用可能性は大きい。   The biologically active aqueous solution of the present invention is effective for plant rooting seedlings, cuttings, flower buds, etc., and in the case of cuttings, the success rate when submerged and then inserted into the nursery is significantly increased. In addition, rooting seedlings and flower buds can be made to bloom for a long time after flowering, the growth of the fruit (seed) is good, and the germination rate of seedlings by the collected seeds is improved.

1 水素水発生器
2 エグゼクタ
3 グルタチオン溶液タンク
4 定量ポンプ
5 タンク部材
6 管路
10 電解槽
11 カソード電極
12 アノード電極
13 隔膜
14 容器部材
20 水素水
21 第1原水供給口
22 第2原水供給口
23 水素水取出し口
24 排水口
26 スロート部
27 ノズル部
28 グルタチオン混合液
DESCRIPTION OF SYMBOLS 1 Hydrogen water generator 2 Executor 3 Glutathione solution tank 4 Metering pump 5 Tank member 6 Pipe line 10 Electrolytic tank 11 Cathode electrode 12 Anode electrode 13 Diaphragm 14 Container member 20 Hydrogen water 21 First raw water supply port 22 Second raw water supply port 23 Hydrogen water outlet 24 Drain outlet 26 Throat section 27 Nozzle section 28 Glutathione mixture

Claims (3)

濃度40〜70%のエタノール水溶液に還元型グルタチオン粉末を5〜10%混合させて混合溶液(基材1)を生成し、
事前に採取された水素水100重量部に、基材1を10〜20重量部添加して混合溶液(基材2)を生成し、さらに
電解によって生成された水素水100重量部に基材2の10〜20重量部をエグゼクタ混合器に通して添加され、その後方に設置された定量ポンプで吸引されて得られる、
生体用活性水溶液の製造方法。
A mixed solution (base material 1) is produced by mixing 5 to 10% of reduced glutathione powder in an aqueous ethanol solution having a concentration of 40 to 70%,
10 to 20 parts by weight of base material 1 is added to 100 parts by weight of hydrogen water collected in advance to form a mixed solution (base material 2), and further, base material 2 is added to 100 parts by weight of hydrogen water generated by electrolysis. Is added through an executor mixer, and is sucked with a metering pump installed behind the executor mixer.
A method for producing a biologically active aqueous solution.
水素水を電解によって生成するためにアノード電極とカソード電極が用いられ、これらのアノード電極とカソード電極間には直流でデューティ70〜95%の電流が印加されることを特徴とする請求項1に記載の水素水の生体用活性水溶液の製造方法。   The anode electrode and the cathode electrode are used for generating hydrogen water by electrolysis, and a current of 70 to 95% in direct current is applied between the anode electrode and the cathode electrode according to claim 1. The manufacturing method of the biologically active aqueous solution of hydrogen water of description. 前記基材1にグリチルリチン酸2Kを、還元型グルタチオンとの混合比1:2〜1:5で混合することを特徴とする請求項1又は2に記載の生体用活性水溶液の製造方法。   The method for producing a biologically active aqueous solution according to claim 1 or 2, wherein glycyrrhizic acid 2K is mixed with the base material 1 in a mixing ratio of 1: 2 to 1: 5 with reduced glutathione.
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