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JP6105437B2 - Heat dissipation device - Google Patents
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JP6105437B2 - Heat dissipation device - Google Patents

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JP6105437B2
JP6105437B2 JP2013169032A JP2013169032A JP6105437B2 JP 6105437 B2 JP6105437 B2 JP 6105437B2 JP 2013169032 A JP2013169032 A JP 2013169032A JP 2013169032 A JP2013169032 A JP 2013169032A JP 6105437 B2 JP6105437 B2 JP 6105437B2
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JP2015037162A (en
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南 和彦
和彦 南
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Resonac Holdings Corp
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Showa Denko KK
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Description

本発明は、電子素子を搭載する回路基板とヒートシンクとを一体化した放熱装置に関する。   The present invention relates to a heat dissipation device in which a circuit board on which an electronic element is mounted and a heat sink are integrated.

本明細書および特許請求の範囲の記載において、「アルミニウム」の語はアルミニウムおよびその合金の両者を含む意味で用いられる。   In the present specification and claims, the term “aluminum” is used to include both aluminum and its alloys.

電子素子が発生する熱を放散させる方法として、電子素子を搭載する回路基板をヒートシンクにろう付してこれらを一体化した放熱装置が知られている(特許文献1参照)。   As a method for dissipating the heat generated by an electronic element, a heat radiating device is known in which a circuit board on which the electronic element is mounted is brazed to a heat sink and these are integrated (see Patent Document 1).

特許文献1に記載された放熱装置は、セラミックからなる絶縁層の一方の面に回路層を積層し、他方の面にアルミニウム層を介して金属製ヒートシンクを積層し、各層をろう付することによって一体化したものである。このような積層構造の放熱装置は、各層間にろう材を挟んで放熱装置を仮組みし、仮組体を加熱することによって各層が一括してろう付される。   In the heat dissipation device described in Patent Document 1, a circuit layer is laminated on one surface of an insulating layer made of ceramic, a metal heat sink is laminated on the other surface via an aluminum layer, and each layer is brazed. It is an integrated one. In such a heat dissipation device having a laminated structure, the heat dissipation device is temporarily assembled with a brazing material sandwiched between the layers, and the temporary assembly is heated to be brazed together.

特開2004−153075号公報JP 2004-153075 A

一般に、セラミックと金属のろう付は金属同士のろう付よりも難しく、接合されにくい。   In general, brazing ceramic and metal is more difficult than metal-to-metal brazing and is less likely to be joined.

前記放熱装置は、セラミック製絶縁層とアルミニウム層、アルミニウム層と金属製ヒートシンクというろう付性に難易差のある接合部を有しているため、仮組体を一括ろう付すると接合されにくい絶縁層とアルミニウム層との間のろう材がヒートシンク側に流れる傾向があり、ろう材が不足することがある。   The heat dissipation device has a ceramic insulating layer and an aluminum layer, and an aluminum layer and a metal heat sink, which have joint portions that are difficult to be brazed. The brazing material between the aluminum layer and the aluminum layer tends to flow toward the heat sink, and the brazing material may be insufficient.

絶縁層−アルミニウム層間のろう材不足を解消するためにろう材量を増やすと、これらの接合界面でろう材による侵食が増大するおそれがある。ヒートシンク側への流出量も増えるので、流出したろう材によるヒートシンクへの侵食が発生するおそれがある。また、アルミニウム層は絶縁層とヒートシンクとの間の応力緩和層であり応力吸収力の大きいパンチングメタルを使用することがあるが、パンチングメタルを用いた放熱装置では流出したろう材で穴が塞がることがある。パンチングメタルの穴がろう材で塞がると応力吸収力が低下する。このように、絶縁層とアルミニウム層のろう付性をろう材量を増やすことによって改善しようとすると、余剰ろう材による弊害も増大することになる。   When the amount of the brazing material is increased in order to eliminate the shortage of the brazing material between the insulating layer and the aluminum layer, there is a risk that erosion by the brazing material may increase at these joint interfaces. Since the outflow amount to the heat sink side also increases, there is a possibility that the erosion to the heat sink by the outflow brazing material may occur. In addition, the aluminum layer is a stress relaxation layer between the insulating layer and the heat sink, and a punching metal with a large stress absorption capacity may be used. However, in the heat dissipation device using the punching metal, the hole is blocked by the leaked brazing material. There is. If the hole in the punching metal is blocked with a brazing material, the stress absorption capacity decreases. As described above, if the brazing property between the insulating layer and the aluminum layer is improved by increasing the amount of the brazing material, the harmful effect due to the surplus brazing material also increases.

本発明は上述した技術背景に鑑みて、ろう付性に難易差のある複数の接合部を有する放熱装置のろう付において、余剰ろう材による弊害を増大させることなく良好にろう付する技術の提供を目的とする。   In view of the above-described technical background, the present invention provides a technique for brazing a heat dissipation device having a plurality of joints having difficulty in brazing without increasing the adverse effects caused by excess brazing material. With the goal.

即ち、本発明は下記[1]〜[9]に記載の構成を有する。   That is, the present invention has the configurations described in [1] to [9] below.

[1]絶縁層の一方の面側に電子素子を搭載する回路層が積層され、他方の面側にアルミニウム層を介してヒートシンクが積層されて、これらが一体化された放熱装置であって、
前記絶縁層とアルミニウム層とが第1ろう材によって接合され、前記アルミニウム層とヒートシンクとが第2ろう材によって接合され、
前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とがX<Yの関係を満たしていることを特徴とする放熱装置。
[1] A heat dissipation device in which a circuit layer for mounting an electronic element is laminated on one surface side of an insulating layer, and a heat sink is laminated on the other surface side through an aluminum layer, and these are integrated,
The insulating layer and the aluminum layer are joined by a first brazing material, and the aluminum layer and the heat sink are joined by a second brazing material,
A heat dissipation device, wherein the solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy a relationship of X <Y.

[2]前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とが0.5<Y−X<30の関係を満たしている前項1に記載の放熱装置。   [2] The heat radiation according to item 1, wherein the solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy a relationship of 0.5 <Y−X <30. apparatus.

[3]前記第1ろう材の固相線温度Xが500〜565℃であり、第2ろう材の固相線温度Yが520〜577℃である前項1または2に記載の放熱装置。   [3] The heat dissipating device according to item 1 or 2, wherein the solidus temperature X of the first brazing material is 500 to 565 ° C., and the solidus temperature Y of the second brazing material is 520 to 577 ° C.

[4]前記第1ろう材は、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である前項1〜3のうちのいずれか1項に記載の放熱装置。   [4] The first brazing material is one selected from the group of an Al—Si—Zn alloy brazing material, an Al—Si—Cu based alloy brazing material, and an Al—Si—Cu—Zn based alloy brazing material. 4. The heat dissipation device according to any one of items 1 to 3.

[5]前記第2ろう材は、Al−Si系合金ろう材、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である前項1〜4のうちのいずれか1項に記載の放熱装置。   [5] The second brazing material is made of an Al—Si based alloy brazing material, an Al—Si—Zn based alloy brazing material, an Al—Si—Cu based alloy brazing material and an Al—Si—Cu—Zn based alloy brazing material. 5. The heat dissipation device according to any one of the preceding items 1 to 4, which is one type selected from the group.

[6]前記Al−Si−Zn系合金ろう材およびAl−Si−Cu−Zn系合金ろう材中のZn濃度が1.5〜20質量%である前項4または5に記載の放熱装置。   [6] The heat dissipation device according to item 4 or 5, wherein a Zn concentration in the Al—Si—Zn alloy brazing material and the Al—Si—Cu—Zn alloy brazing material is 1.5 to 20% by mass.

[7]前記Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材中のCu濃度が0.3〜15質量%である前項4または5に記載の放熱装置。   [7] The heat radiating device according to item 4 or 5, wherein a Cu concentration in the Al—Si—Cu-based alloy brazing material and the Al—Si—Cu—Zn-based alloy brazing material is 0.3 to 15% by mass.

[8]絶縁層、第1ろう材、アルミニウム層、第2ろう材、ヒートシンクの順に重ねて仮組みし、この仮組体を加熱して絶縁層、アルミニウム層およびヒートシンクをろう付する放熱装置の製造方法であって、
前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とがX<Yの関係を満たし、
前記ろう付の温度プロファイルにおいて、前記仮組体を第1ろう材の固相線温度X℃以上で第2ろう材の固相線温度Y℃未満の中間温度域に保持することを特徴とする放熱装置の製造方法。
[8] A heat dissipation device in which an insulating layer, a first brazing material, an aluminum layer, a second brazing material, and a heat sink are temporarily stacked and temporarily assembled, and the temporary assembly is heated to braze the insulating layer, the aluminum layer, and the heat sink. A manufacturing method comprising:
The solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy the relationship X <Y,
In the brazing temperature profile, the temporary assembly is held in an intermediate temperature range not lower than the solidus temperature XC of the first brazing material and lower than the solidus temperature YC of the second brazing material. Manufacturing method of heat dissipation device.

[9]前記中間温度域の保持時間は0.5〜10分である前項8に記載の放熱装置の製造方法。   [9] The method for manufacturing a heat radiating device according to [8], wherein the holding time in the intermediate temperature range is 0.5 to 10 minutes.

[1]に記載の発明は、接合され難い絶縁層とアルミニウム層とを接合する第1ろう材の固相線温度X℃と、接合され易いアルミニウム層とヒートシンクとを接合する第2ろう材の固相線温度Y℃とがX<Yの関係を満たしている。X<Yなる関係により、ろう付過程初期においては第1ろう材が先に溶融し、第2ろう材の固相線温度Y℃に達するまでは第1ろう材のみが溶融しているので、接合界面からはみ出した第1ろう材がアルミニウム層の側面で第2ろう材と繋がることはない。第2ろう材は第1ろう材と繋がらない限り第1ろう材の流出を促すことはないので、第1ろう材は接合界面から失われることなく絶縁層とアルミニウム層との接合に費やされる。ろう付過程が進行して第2ろう材の固相線温度Y℃に達すると第2ろう材も溶融しはじめ、溶融の進んだ第1ろう材がヒートシンク側に流れ、あるいは第1ろう材と第2ろう材と繋がるが、その時点では絶縁層とアルミニウム層との接合に必要な量のろう材が接合界面に保持されているのでろう材不足となることはない。   In the invention described in [1], the solidus temperature X ° C. of the first brazing material that joins the insulating layer and the aluminum layer that are difficult to be joined, and the second brazing material that joins the aluminum layer and the heat sink that are easy to join. The solidus temperature Y ° C. satisfies the relationship X <Y. Because of the relationship X <Y, the first brazing material is melted first in the initial stage of the brazing process, and only the first brazing material is melted until the solidus temperature Y ° C. of the second brazing material is reached. The first brazing material protruding from the joint interface is not connected to the second brazing material on the side surface of the aluminum layer. Since the second brazing material does not promote the outflow of the first brazing material unless it is connected to the first brazing material, the first brazing material is consumed for joining the insulating layer and the aluminum layer without being lost from the joining interface. When the brazing process proceeds and the solidus temperature YC of the second brazing material is reached, the second brazing material also starts to melt, and the first brazing material that has been melted flows toward the heat sink, or the first brazing material The brazing material is connected to the second brazing material, but at that time, an amount of brazing material necessary for joining the insulating layer and the aluminum layer is held at the joining interface, so that there is no shortage of the brazing material.

このようにろう付性に難易差のある2つの接合部が共に良好に接合されるので、流出を見越した過剰量のろう材を供給する必要がなく、余剰ろう材による侵食を抑えることができる。また、アルミニウム層に貫通孔を設けた場合は貫通孔が余剰ろう材で塞がることがなく、応力吸収力が低下することもない。   In this way, since the two joints having a difficulty difference in brazability are well joined together, it is not necessary to supply an excessive amount of brazing material in anticipation of outflow, and erosion due to surplus brazing material can be suppressed. . Moreover, when a through-hole is provided in the aluminum layer, the through-hole is not blocked with an excess brazing material, and the stress absorption capacity is not reduced.

[2]に記載の発明によれば、厳密なろう付の温度管理を要せず、上述した効果を得ることができる。   According to the invention described in [2], the above-described effects can be obtained without requiring strict brazing temperature control.

[3][4][5][6][7]に記載の各発明によれば、絶縁層、アルミニウム層、ヒートシンクの材料に鑑みてろう付性に難易差のある2つの接合部を良好に接合できる。   According to each invention described in [3], [4], [5], [6], and [7], two joints having a difference in difficulty in brazing are preferable in view of the materials of the insulating layer, the aluminum layer, and the heat sink. Can be joined.

[8]に記載の発明によれば、ろう付の温度プロファイルにおいて、仮組体が第1ろう材の固相線温度X℃以上で第2ろう材の固相線温度Y℃未満の中間温度域に保持されることによって、第1ろう材が第2ろう材よりも先に溶融し、絶縁層とアルミニウム層との接合がアルミニウム層とヒートシンクとの接合に先んじて進むので、第2ろう材が第1ろう材流出を促すことがない。このため、第1ろう材は接合界面から失われることなく絶縁層とアルミニウム層との接合に費やされる。ろう付過程が進行して第2ろう材の固相線温度Y℃に達すると第2ろう材も溶融しはじめ、溶融の進んだ第1ろう材がヒートシンク側に流れ、あるいは第1ろう材と第2ろう材と繋がるが、その時点では絶縁層とアルミニウム層との接合に必要な量のろう材が接合界面に保持されているのでろう材不足となることはない。   According to the invention described in [8], in the brazing temperature profile, the intermediate temperature of the temporary assembly is not less than the solidus temperature X ° C. of the first brazing material and less than the solidus temperature Y ° C. of the second brazing material. The first brazing material is melted before the second brazing material by being held in the region, and the joining of the insulating layer and the aluminum layer proceeds prior to the joining of the aluminum layer and the heat sink. Does not promote the outflow of the first brazing filler metal. For this reason, the first brazing material is consumed for joining the insulating layer and the aluminum layer without being lost from the joining interface. When the brazing process proceeds and the solidus temperature YC of the second brazing material is reached, the second brazing material also starts to melt, and the first brazing material that has been melted flows toward the heat sink, or the first brazing material The brazing material is connected to the second brazing material, but at that time, an amount of brazing material necessary for joining the insulating layer and the aluminum layer is held at the joining interface, so that there is no shortage of the brazing material.

[9]に記載の発明によれば、第1ろう材による絶縁層とアルミニウム層との接合を十分に進行させた後に第2ろう材を溶融させることができる。   According to the invention described in [9], the second brazing material can be melted after sufficiently joining the insulating layer and the aluminum layer by the first brazing material.

本発明にかかる放熱装置の一実施形態の断面図である。It is sectional drawing of one Embodiment of the thermal radiation apparatus concerning this invention.

[放熱装置の構成]
図1は本発明の放熱装置の一実施形態を、構成部材が積層する方向で切断した断面で示している。
[Configuration of heat dissipation device]
FIG. 1 shows an embodiment of a heat dissipation device of the present invention in a cross section cut in a direction in which constituent members are laminated.

放熱装置(1)は、絶縁層(11)の一方の面側に電子素子(14)を搭載する回路層(12)が積層され、他方の面側にはアルミニウム層(13)を介してヒートシンク(20)が積層され、これらが一体に接合されている。前記回路層(12)および絶縁層(11)とヒートシンク(13)とはアルミニウム層(13)を介して熱的に結合され、回路層(12)に搭載された電子素子(14)が発する熱はヒートシンク(20)に排熱される。   In the heat dissipation device (1), a circuit layer (12) on which an electronic element (14) is mounted is laminated on one surface side of an insulating layer (11), and a heat sink is disposed on the other surface side via an aluminum layer (13). (20) are stacked and joined together. The circuit layer (12), the insulating layer (11), and the heat sink (13) are thermally coupled via the aluminum layer (13), and the heat generated by the electronic element (14) mounted on the circuit layer (12). Is exhausted by the heat sink (20).

前記放熱装置(1)は、回路層(12)、絶縁層(11)、アルミニウム層(13)およびヒートシンク(20)をそれぞれの部材間にろう材を配置して仮組みし、仮組体を一括ろう付し、その後に電子素子(14)をはんだ付したものである。以下の説明において、前記絶縁層(11)とアルミニウム層(13)との接合部を第1接合部(31)、前記アルミニウム層(13)とヒートシンク(20)との接合部を第2接合部(32)、前記絶縁層(11)と回路層(12)との接合部を第3接合部(33)と略称し、第1接合部(31)、第2接合部(32)および第3接合部(33)を接合するためのろう材をそれぞれ第1ろう材(41)、第2ろう材(42)および第3ろう材(43)と称する。   The heat dissipating device (1) includes a circuit layer (12), an insulating layer (11), an aluminum layer (13), and a heat sink (20), which are temporarily assembled with a brazing material disposed between the members. It is soldered together and then soldered with the electronic element (14). In the following description, the junction between the insulating layer (11) and the aluminum layer (13) is the first junction (31), and the junction between the aluminum layer (13) and the heat sink (20) is the second junction. (32), a joint between the insulating layer (11) and the circuit layer (12) is abbreviated as a third joint (33), and the first joint (31), the second joint (32), and the third The brazing materials for joining the joint portions (33) are referred to as a first brazing material (41), a second brazing material (42) and a third brazing material (43), respectively.

前記放熱装置(1)を構成する各層の好ましい材料は以下のとおりである。   Preferred materials for each layer constituting the heat dissipation device (1) are as follows.

前記絶縁層(11)を構成する材料としては、窒化アルミニウム、酸化アルミニウム、窒化ケイ素、炭化ケイ素、酸化ジルコニウム等のセラミックを例示できる。これらのセラミックは電気絶縁性が優れていることはもとより、熱伝導性が良く放熱性が優れている点で推奨できる。   Examples of the material constituting the insulating layer (11) include ceramics such as aluminum nitride, aluminum oxide, silicon nitride, silicon carbide, and zirconium oxide. These ceramics are recommended not only because of their excellent electrical insulation, but also because they have good thermal conductivity and excellent heat dissipation.

前記回路層(12)を構成する金属としては、導電性が高くかつ絶縁層(11)とろう付またははんだ付が可能な金属を用いるものとし、特に高純度アルミニウムを推奨できる。   As the metal constituting the circuit layer (12), a metal having high conductivity and capable of being brazed or soldered to the insulating layer (11) is used, and particularly high-purity aluminum can be recommended.

前記アルミニウム層(13)は、剛性の高いセラミック製の絶縁層(11)とヒートシンク(20)との接合界面に発生する熱応力を緩和するための層であるから、軟質の金属を用いることが好ましく、特に高純度アルミニウムが好ましい。また、図示例のアルミニウム層(13)のように、応力吸収空間として複数の円形貫通穴(13a)を有するパンチングメタルを用いることも好ましい。   Since the aluminum layer (13) is a layer for relieving thermal stress generated at the bonding interface between the ceramic insulating layer (11) having high rigidity and the heat sink (20), a soft metal is used. High purity aluminum is particularly preferable. It is also preferable to use a punching metal having a plurality of circular through holes (13a) as a stress absorbing space, like the aluminum layer (13) in the illustrated example.

前記ヒートシンク(20)を構成する金属は、軽量性、強度維持、成形性、耐食性に優れた材料を用いることが好ましく、これらの特性を有するものとしてAl−Mn系合金やAl−Fe系合金等のアルミニウム合金を推奨できる。ヒートシンク(20)はアルミニウム層(13)側の外面がフラットであればアルミニウム層(20)と広い面積でろう付して高い放熱性能が得られるので、アルミニウム層(20)側の面以外の外部形状や内部形状は問わない。図示例のヒートシンク(20)は膨出部を有する上板(21)と平板からなる底板(22)とを組み合わせて形成される冷媒室(23)にインナーフィン(24)をはめ込んで接合したものである。ヒートシンクの他の形状として、平板、平板の他方の面にフィンをろう付したヒートシンク、中空部を有する形材で構成したチューブ型ヒートシンク等を例示できる。   As the metal constituting the heat sink (20), it is preferable to use a material excellent in lightness, strength maintenance, formability, and corrosion resistance. Al-Mn based alloys, Al-Fe based alloys and the like have these characteristics. Aluminum alloy can be recommended. If the heat sink (20) has a flat outer surface on the aluminum layer (13) side, it can be brazed in a large area with the aluminum layer (20) to obtain high heat dissipation performance. There is no limitation on the shape or internal shape. The heat sink (20) in the example shown in the figure is a refrigerant chamber (23) formed by combining an upper plate (21) having a bulging portion and a bottom plate (22) consisting of a flat plate, and an inner fin (24) is fitted and joined. It is. Other shapes of the heat sink include a flat plate, a heat sink in which fins are brazed to the other surface of the flat plate, a tube heat sink formed of a shape member having a hollow portion, and the like.

[放熱装置のろう付]
本発明は上述した3つのろう材のうちの第1ろう材(41)および第2ろう材(42)の固相線温度に関して規定する。
[Brazing of heat dissipation device]
The present invention is defined with respect to the solidus temperature of the first brazing material (41) and the second brazing material (42) of the three brazing materials described above.

第1接合部(31)と第2接合部(32)はアルミニウム層(13)の両面に位置し、これらはアルミニウム層(13)によって隔てられており、その隔たりはアルミニウム層(13)の厚み分である。アルミニウム層(13)の側面は平坦であるから、接合界面からはみ出した溶融ろう材は妨げられることなくアルミニウム層(13)の側面を伝うことができる状態である。また、接合界面から貫通穴(13a)にはみ出した溶融ろう材も貫通穴(13a)の壁面を伝うことができる状態である。   The first joint portion (31) and the second joint portion (32) are located on both sides of the aluminum layer (13), which are separated by the aluminum layer (13), and the distance is the thickness of the aluminum layer (13). Minutes. Since the side surface of the aluminum layer (13) is flat, the molten brazing material protruding from the bonding interface is in a state where it can travel along the side surface of the aluminum layer (13) without being blocked. In addition, the molten brazing material that protrudes from the joint interface into the through hole (13a) can also travel along the wall surface of the through hole (13a).

第1接合部(31)はセラミックと金属の異種材料の接合であるから、金属同士の第2接合部(32)よりも接合されにくく接合に時間がかかる。このため、第1接合部(31)と第2接合部(32)に同じろう材を用いた場合、ろう付過程において、溶融した第2ろう材(41)は接合に費やされて接合界面に保持されているが、溶融した第1ろう材(41)は接合界面における保持力が第2ろう材(42)よりも弱いために接合界面から流出し易い、という状態にある時期がある。ろう付過程の初期にこのような状態になると、第1ろう材(41)が接合に費やされることなく接合界面からアルミニウム層(13)の側面および貫通穴(13a)に流出し易くなる。また、このとき、第2ろう材(42)がアルミニウム層(13)の側面および貫通穴(13a)にはみ出していると、はみ出した第2ろう材(42)と第1ろう材(41)とがアルミニウム層(13)の側面上および貫通穴(13a)の壁面上で繋がることがある。しかも、第2接合部(32)の接合界面からはみ出す第2ろう材(42)の量が多いほど、第2ろう材(42)はアルミニウム層(13)の側面を第1接合部(31)側に伝い流れる量が増えて第1接合部(31)に近づき、第2ろう材(42)が第1ろう材(41)を迎えに行くことになって第1ろう材(41)と繋がり易くなる。両方の溶融ろう材が繋がってろう材の道すじが形成されると、接合界面での保持力の弱い第1ろう材(41)は第2ろう材(42)が呼び水となって接合界面からの流出が促され、第1ろう材(41)が単独で流出するよりも多量のろう材が接合界面から流出する。その結果、第1接合部(31)はろう材が不足して接合不良となる。   Since the first joining portion (31) is a joining of different materials of ceramic and metal, it is less likely to be joined than the second joining portion (32) between the metals, and the joining takes time. For this reason, when the same brazing material is used for the first joint portion (31) and the second joint portion (32), the melted second brazing material (41) is consumed for joining in the brazing process. However, there is a time when the melted first brazing material (41) is in a state where it easily flows out from the joining interface because the holding power at the joining interface is weaker than that of the second brazing material (42). If such a state occurs in the initial stage of the brazing process, the first brazing material (41) is likely to flow out from the joining interface to the side surface of the aluminum layer (13) and the through hole (13a) without being consumed for joining. At this time, if the second brazing material (42) protrudes into the side surface of the aluminum layer (13) and the through hole (13a), the protruding second brazing material (42) and the first brazing material (41) May be connected on the side surface of the aluminum layer (13) and on the wall surface of the through hole (13a). In addition, as the amount of the second brazing material (42) protruding from the joining interface of the second joining portion (32) increases, the second brazing material (42) causes the side surface of the aluminum layer (13) to face the first joining portion (31). The amount that flows to the side increases, approaches the first joint (31), the second brazing material (42) is picked up by the first brazing material (41), and is connected to the first brazing material (41). It becomes easy. When both brazing filler metals are connected to form a braided streak, the first brazing filler metal (41), which has a weak holding power at the bonding interface, becomes the second brazing filler metal (42) as the priming water and the The outflow is promoted, and a larger amount of brazing material flows out from the joining interface than the first brazing material (41) flows out alone. As a result, the first joint portion (31) has insufficient brazing material, resulting in poor bonding.

本発明は、ろう付過程初期において第2ろう材(42)を第1ろう材(41)流出の呼び水にしないために、第1ろう材(41)の固相線温度X℃と第2ろう材(42)の固相線温度Y℃とがX<Yの関係を満たすことを要件とする。   In the present invention, in order to prevent the second brazing material (42) from becoming the priming water flowing out of the first brazing material (41) at the initial stage of the brazing process, the solidus temperature X ° C. of the first brazing material (41) It is a requirement that the solidus temperature Y ° C. of the material (42) satisfies the relationship X <Y.

ろう付の温度プロファイルにおいて、仮組体の実体温度はろう付の設定温度に到達するまで昇温する。この温度プロファイルにおいて、固相線温度の低い第1ろう材(41)が先に溶融し、接合されにくい第1接合部(31)の接合が第2接合部(32)よりも早い時期に始まる。第2ろう材(42)の固相線温度Y℃に達するまでは第1ろう材(31)のみが溶融して第2ろう材(42)は溶融していないので、第1接合部(31)の接合界面から第1ろう材(41)がアルミニウム層(13)の側面にはみ出したとしても、側面上で第2ろう材(42)と繋がることはない。第2ろう材(42)は第1ろう材(41)と繋がらない限り第1ろう材(41)流出の呼び水になることはないので、第1ろう材(41)は接合界面から失われることなく接合に費やされる。ろう付過程が進行して第2ろう材(42)の固相線温度Y℃に達すると第2ろう材(42)も溶融しはじめる。第2ろう材(42)の固相線温度Y℃以上の温度域では、先に溶融が始まって溶融の進んだ第1ろう材(41)が第2接合部(32)側に流れ、あるいは第1ろう材(41)が接合界面からアルミニウム層(13)の側面にはみ出した第2ろう材(42)と繋がることもあるが、その時点では第1接合部(31)の接合に必要な量のろう材が接合界面に保持されているのでろう材不足となることはない。しかも、第2ろう材(42)の溶融が遅れることで第2ろう材(42)のアルミニウム層(13)の側面へのはみ出し量が少ないことも、第1ろう材(41)と繋がり難くなる要因である。また、第2接合部(32)はもとよりろう付性が良く、しかも第2接合部(32)側に流れた第1ろう材(41)が第2接合部(32)の接合界面に入り込んで接合に供されるので、第2接合部(32)に十分な量のろう材が供給されて良好にろう付される。   In the brazing temperature profile, the actual temperature of the temporary assembly is increased until the brazing set temperature is reached. In this temperature profile, the first brazing material (41) having a low solidus temperature is melted first, and the joining of the first joining part (31), which is difficult to join, starts earlier than the second joining part (32). . Until the solidus temperature Y 2 C of the second brazing material (42) is reached, only the first brazing material (31) is melted and the second brazing material (42) is not melted. ) Even if the first brazing material (41) protrudes from the side surface of the aluminum layer (13) from the joining interface, the second brazing material (42) is not connected to the side surface. Since the second brazing filler metal (42) will not be the priming water for the first brazing filler metal (41) outflow unless it is connected to the first brazing filler metal (41), the first brazing filler metal (41) is lost from the joint interface. Without spending on joining. When the brazing process proceeds to reach the solidus temperature Y ° C. of the second brazing material (42), the second brazing material (42) also begins to melt. In the temperature range of the solidus temperature Y ° C. or higher of the second brazing material (42), the first brazing material (41) that has started melting and has proceeded to the melting flows to the second joint (32) side, or The first brazing material (41) may be connected to the second brazing material (42) protruding from the joining interface to the side surface of the aluminum layer (13), but at that time, it is necessary for joining the first joining portion (31). Since the amount of brazing material is held at the joining interface, there is no shortage of brazing material. In addition, since the melting of the second brazing material (42) is delayed, the amount of protrusion of the second brazing material (42) to the side surface of the aluminum layer (13) is small, and it is difficult to connect to the first brazing material (41). It is a factor. Also, the brazing property is good as well as the second joint portion (32), and the first brazing material (41) flowing to the second joint portion (32) side enters the joint interface of the second joint portion (32). Since it is used for joining, a sufficient amount of brazing material is supplied to the second joint portion (32) and brazed well.

図示例のアルミニウム層(13)は応力吸収空間として貫通穴(13a)を有しており、貫通穴(13a)の壁面においても側面と同様の現象が起こる。即ち、第1ろう材の(41)の固相線温度X℃以上で第2ろう材(42)の固相線温度Y℃未満の温度域においては第2ろう材(42)よる呼び水作用を防いで第1接合部(31)の接合界面に接合に要する第1ろう材(41)を保持し、ろう付過程が進行すると第2接合部(32)に貫通穴(13a)を通じて第1ろう材(41)が供給される。   The aluminum layer (13) in the illustrated example has a through hole (13a) as a stress absorbing space, and the same phenomenon as that on the side surface occurs on the wall surface of the through hole (13a). That is, the priming action by the second brazing material (42) is performed in the temperature range where the solidus temperature of the first brazing material (41) is equal to or higher than the solidus temperature X ° C and lower than the solidus temperature Y ° C of the second brazing material (42). The first brazing material (41) required for joining is held at the joining interface of the first joining part (31) to prevent the first brazing through the through hole (13a) in the second joining part (32) as the brazing process proceeds. The material (41) is supplied.

上述したように、ろう付の温度プロファイルにおいて、第1ろう材(41)の固相線温度X℃以上で第2ろう材(42)の固相線温度Y(℃)未満の温度域は第1ろう材(41)のみが溶融している中間温度域である。前記中間温度域では、第1接合部(31)は第2接合部(32)に先んじて接合が進み、かつ第2ろう材(42)が第1ろう材(41)流出の呼び水になることがない。即ち、第2ろう材(42)が溶融し始める前に、第1ろう材(41)が接合界面から流れ出してもろう材不足が起きない状態になるまで第1接合部(31)の接合を進行させれば、第1接合部(31)および第2接合部(32)の両方を良好に接合させることができる。   As described above, in the brazing temperature profile, the temperature range of the first brazing material (41) above the solidus temperature X ° C. and lower than the solidus temperature Y (° C.) of the second brazing material (42) is It is an intermediate temperature range in which only one brazing material (41) is melted. In the intermediate temperature range, the first joining portion (31) is joined prior to the second joining portion (32), and the second brazing material (42) serves as a priming water for the outflow of the first brazing material (41). There is no. In other words, before the second brazing material (42) starts to melt, the first joining portion (31) is joined until the first brazing material (41) flows out from the joining interface until no brazing material shortage occurs. If it advances, both the 1st junction part (31) and the 2nd junction part (32) can be joined favorably.

本発明によれば、接合され難い第1接合部(31)はろう付過程初期の段階で接合界面に第1ろう材(41)が保持されるので良好にろう付される。第2接合部(31)はもとより接合され易い上に、ろう付過程の進行に伴って第1ろう材(41)が供給されるので良好にろう付される。このようにろう付性に難易差のある2つの接合部が共に良好に接合される。また、第1接合部(31)に流出を見越した過剰量のろう材を供給する必要がないので、余剰ろう材による侵食を抑えることができる。また、アルミニウム層(13)の貫通孔(13a)が余剰ろう材で塞がることがなく、応力吸収力が低下することもない。   According to the present invention, the first joint portion (31) that is difficult to be joined is brazed well because the first brazing material (41) is held at the joining interface at the initial stage of the brazing process. The second joint portion (31) is easily joined as well as the first brazing material (41) is supplied with the progress of the brazing process, so that the second joint portion (31) is brazed well. In this way, the two joint portions having a difficulty difference in brazability are well joined together. Further, since it is not necessary to supply an excessive amount of brazing material in anticipation of outflow to the first joint portion (31), erosion due to the surplus brazing material can be suppressed. Further, the through hole (13a) of the aluminum layer (13) is not blocked by the excess brazing material, and the stress absorption capacity is not reduced.

前記第3接合部(33)は絶縁層(11)と回路層(12)は異種材料の接合であり、第1接合部(31)と同様に接合され難い接合部である。しかし、回路層(12)の短絡を防止するために絶縁層(11)の寸法は回路層(12)よりも大きく設定されているので、第3接合部(33)は大きい絶縁層(11)によって第1接合部(31)および第2接合部(32)との間の連絡が完全に断ち切られている。このため、第3接合部(33)の接合に時間がかかったとしても第3ろう材(43)が接合界面から失われることなない。従って、第3ろう材(43)を第1ろう材(41)および第2ろう材(42)の固相線温度との関係に基づいて設定する必要はなく、第3ろう材(43)は絶縁層(11)と回路層(12)とのろう付性のみを考慮して選定すれば良い。また、本発明は絶縁層(11)と回路層(12)の接合方法をろう付に限定するものではなく、はんだ付によって接合する場合も本発明に含まれる。   In the third joint (33), the insulating layer (11) and the circuit layer (12) are joints of different materials, and are the joints that are difficult to be joined like the first joint (31). However, since the dimension of the insulating layer (11) is set larger than that of the circuit layer (12) in order to prevent a short circuit of the circuit layer (12), the third junction (33) has a large insulating layer (11). Thus, the communication between the first joint (31) and the second joint (32) is completely cut off. For this reason, even if it takes time to join the third joint portion (33), the third brazing material (43) is not lost from the joint interface. Therefore, it is not necessary to set the third brazing material (43) based on the relationship between the solidus temperature of the first brazing material (41) and the second brazing material (42), and the third brazing material (43) The selection should be made considering only the brazability between the insulating layer (11) and the circuit layer (12). In addition, the present invention does not limit the joining method of the insulating layer (11) and the circuit layer (12) to brazing, and includes the case of joining by soldering.

[ろう材およびろう付条件]
上述したように、前記第2ろう材(42)を第1ろう材(41)の呼び水にしないための条件は、ろう付の温度プロファイルにおいて前記第1ろう材(41)は溶融し始めているが第2ろう材(42)は溶融していない状態が存在することである。従って、本発明において第1ろう材(41)および第2ろう材(42)の条件は固相線温度がX<Yの関係を満たしていることである。X<Yの関係を満たしている限り、ろう材の組成や形態は限定されない。
[Brazing materials and brazing conditions]
As described above, the condition for preventing the second brazing material (42) from being the priming water of the first brazing material (41) is that the first brazing material (41) starts to melt in the brazing temperature profile. The second brazing material (42) is in an unmelted state. Therefore, in the present invention, the condition of the first brazing material (41) and the second brazing material (42) is that the solidus temperature satisfies the relationship of X <Y. As long as the relationship of X <Y is satisfied, the composition and form of the brazing material are not limited.

ろう付の温度プロファイルにおいて、第1ろう材(41)の固相線温度X℃以上で第2ろう材(42)の固相線温度Y℃未満の温度域は第1ろう材(41)のみが溶融し始めている中間温度域である。前記中間温度域では、第1接合部(31)は第2接合部(32)に先んじて接合が進み、かつ第2ろう材(42)が第1ろう材(41)流出の呼び水になることがない。即ち、第2ろう材(42)が溶融し始める前に、第1ろう材(41)が接合界面から流れ出してもろう材不足が起きない状態になるまで第1接合部(31)の接合を進行させれば、第1接合部(31)および第2接合部(32)の両方を良好に接合させることができる。かかる観点より、好ましいろう材およびろう付の条件は以下のとおりである。   In the brazing temperature profile, the first brazing material (41) is the only temperature range where the solidus temperature of the first brazing material (41) is not lower than X ° C and lower than the solidus temperature of the second brazing material (42). Is an intermediate temperature range where melting begins. In the intermediate temperature range, the first joining portion (31) is joined prior to the second joining portion (32), and the second brazing material (42) serves as a priming water for the outflow of the first brazing material (41). There is no. In other words, before the second brazing material (42) starts to melt, the first joining portion (31) is joined until the first brazing material (41) flows out from the joining interface until no brazing material shortage occurs. If it advances, both the 1st junction part (31) and the 2nd junction part (32) can be joined favorably. From this viewpoint, preferable brazing materials and brazing conditions are as follows.

前記第1ろう材(41)の固相線温度X℃と第2ろう材(42)の固相線温度Y℃とは、0.5<Y−X<30の関係を満たしていることが好ましい。固相線温度差(Y−X)が0.5℃以下では、第2ろう材(42)が溶融し始める前に第1接合部(31)の接合を十分に進行させるには仮組体を狭い温度範囲の保持しなければならない。このため、厳密なろう付の温度管理が必要となるので好ましくない。一方、固相線温度差(Y−X)が30℃以上になると、第2ろう材(42)を溶融させた際に、第1ろう材(41)が溶融し過ぎ、エロージョンとなるので好ましくない。特に好ましい固相線温度の関係は0.5<Y−X<20である。   The solidus temperature X ° C. of the first brazing material (41) and the solidus temperature Y ° C. of the second brazing material (42) satisfy the relationship of 0.5 <Y-X <30. preferable. When the solidus temperature difference (Y-X) is 0.5 ° C. or less, a temporary assembly is required to sufficiently advance the joining of the first joint (31) before the second brazing material (42) starts to melt. Must be maintained in a narrow temperature range. For this reason, since strict brazing temperature control is required, it is not preferable. On the other hand, when the solidus temperature difference (Y-X) is 30 ° C. or higher, the first brazing material (41) is excessively melted and eroded when the second brazing material (42) is melted. Absent. A particularly preferred solidus temperature relationship is 0.5 <Y-X <20.

また、上述した絶縁層(11)、アルミニウム層(13)、ヒートシンク(20)の材料に鑑みて、第1ろう材(41)の固相線温度Xが500〜565℃であり、第2ろう材(42)の固相線温度Yが520〜577℃であることが好ましい。さらに好ましい第1ろう材(41)の固相線温度Xは510〜565℃であり、さらに好ましい第2ろう材(42)の固相線温度Yは530〜577℃である。   In view of the materials of the insulating layer (11), the aluminum layer (13), and the heat sink (20) described above, the solidus temperature X of the first brazing material (41) is 500 to 565 ° C. The solidus temperature Y of the material (42) is preferably 520 to 577 ° C. The solidus temperature X of the first brazing material (41) is more preferably 510 to 565 ° C, and the solidus temperature Y of the second brazing material (42) is more preferably 530 to 577 ° C.

上述した固相線温度の条件を満たす第1ろう材(41)および第2ろう材(42)として、Al−Si系合金ろう材あるいはAl−Si系合金に融点降下のためにZnおよび/またはCuを添加したAl−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材、Al−Si−Cu−Zn系合金ろう材を例示できる。これらのろう材のうちで、固相線温度の低い第1ろう材(41)として好ましいろう材は、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である。また、固相線温度の高い第2ろう材(421)として好ましいろう材はAl−Si系合金ろう材、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である。   As the first brazing filler metal (41) and the second brazing filler metal (42) that satisfy the above-mentioned solidus temperature conditions, Zn and / or Al is added to the Al—Si based alloy brazing material or the Al—Si based alloy to lower the melting point. Examples include an Al—Si—Zn alloy brazing material to which Cu is added, an Al—Si—Cu alloy brazing material, and an Al—Si—Cu—Zn alloy brazing material. Of these brazing materials, preferable brazing materials as the first brazing material (41) having a low solidus temperature are Al-Si-Zn alloy brazing material, Al-Si-Cu alloy brazing material and Al-Si. -It is 1 type chosen from the group of a Cu-Zn type alloy brazing material. Also, brazing materials preferable as the second brazing material (421) having a high solidus temperature are Al—Si based alloy brazing material, Al—Si—Zn based brazing material, Al—Si—Cu based brazing material and Al—. This is one selected from the group of Si—Cu—Zn alloy brazing materials.

また、前記ろう材中のSi濃度、Zn濃度、Cu濃度は限定されず、所期する固相線温度が得られるように適宜設定することができる。前記ろう材中の好ましいSi濃度は8〜14質量%であり、特に好ましいSi濃度は9〜12質量%である。また、好ましいZn濃度は1.5〜20質量%であり、好ましいCu濃度は0.3〜15質量%である。ただし、Zn濃度およびCu濃度が高くなると加工性が低下するので、ろう材箔に加工する場合は、Zn濃度を10質量%以下、Cu濃度を5質量%以下とすることが好ましい。また、真空ろう付には上記組成にMgを添加したろう材を用いることが好ましい。また、ろう材の流動性を高めるために、上記組成にBiまたはSrを添加したろう材を使用することも好ましい。   Further, the Si concentration, Zn concentration, and Cu concentration in the brazing material are not limited, and can be set as appropriate so as to obtain a desired solidus temperature. A preferable Si concentration in the brazing material is 8 to 14% by mass, and a particularly preferable Si concentration is 9 to 12% by mass. Moreover, preferable Zn density | concentration is 1.5-20 mass%, and preferable Cu density | concentration is 0.3-15 mass%. However, since the workability decreases when the Zn concentration and the Cu concentration become high, when processing into a brazing material foil, it is preferable to set the Zn concentration to 10% by mass or less and the Cu concentration to 5% by mass or less. For vacuum brazing, it is preferable to use a brazing material in which Mg is added to the above composition. In order to enhance the fluidity of the brazing material, it is also preferable to use a brazing material in which Bi or Sr is added to the above composition.

また、固相線温度が500℃、520℃、565℃、577℃のろう材例として下記の組成を例示できる。   Moreover, the following composition can be illustrated as an example of the brazing filler metal having a solidus temperature of 500 ° C., 520 ° C., 565 ° C., and 577 ° C.

固相線温度500℃:Al−10質量%Si−15質量%Cu−20質量%Zn合金
固相線温度520℃:Al−10質量%Si−10質量%Cu−15質量%Zn合金
固相線温度565℃:Al−10質量%Si−8質量%Cu合金、Al−10質量%Si−6質量%Zn合金
固相線温度577℃:Al−10質量%Si合金
前記第1ろう材(41)および第2ろう材(42)の形態は何ら限定されす、ろう材箔やろう材粉末として接合部に配置しても良いし、アルミニウム層(13)をブレージングシートで構成しても良い。
Solidus temperature 500 ° C: Al-10 mass% Si-15 mass% Cu-20 mass% Zn alloy Solidus temperature 520 ° C: Al-10 mass% Si-10 mass% Cu-15 mass% Zn alloy Solid phase Linear temperature 565 ° C .: Al-10 mass% Si-8 mass% Cu alloy, Al-10 mass% Si-6 mass% Zn alloy Solidus temperature 577 ° C .: Al-10 mass% Si alloy The first brazing material ( 41) and the shape of the second brazing material (42) are not limited in any way, they may be arranged at the joint as brazing material foil or brazing material powder, and the aluminum layer (13) may be composed of a brazing sheet. .

前記ろう付の温度プロファイルにおいて、前記中間温度域、即ち第1ろう材(41)の固相線温度X℃以上で第2ろう材(42)の固相線温度Y℃未満の温度域内の保持時間は0.5〜10分であることが好ましい。0.5分未満では第1接合部(31)の接合が十分進んでおらず、第1接合部(31)の接合が不十分な段階で第2ろう材(42)の溶融が始まると第1ろう材(31)が流出するおそれがある。一方、10分保持すれば第1接合部(31)の進行が十分に進むので、10分を超えて長く保持してもさらなるろう付性の向上に寄与しない。必要以上に長い保持時間はろう付時間を長引かせることになる。特に好ましい保持時間は1〜8分である。前記保持時間中はX℃以上でY℃未満であれば良いので、この温度範囲内の一定の温度に固定して保持しても良いし、温度範囲を超えないように昇温しながら保持しても良い。   In the brazing temperature profile, the intermediate temperature range, that is, holding in the temperature range of the first brazing material (41) above the solidus temperature X ° C and below the solidus temperature Y ° C of the second brazing material (42). The time is preferably 0.5 to 10 minutes. If it is less than 0.5 minutes, the joining of the first joint portion (31) is not sufficiently advanced, and the melting of the second brazing material (42) starts when the joining of the first joint portion (31) is insufficient. 1 There is a risk that the brazing filler metal (31) will flow out. On the other hand, if it is held for 10 minutes, the first joint portion (31) proceeds sufficiently, so even if it is held longer than 10 minutes, it does not contribute to further improvement of brazing. Holding times longer than necessary will increase the brazing time. A particularly preferable holding time is 1 to 8 minutes. Since the holding time may be X ° C. or more and less than Y ° C., the holding time may be fixed and held at a certain temperature within this temperature range, or held while raising the temperature so as not to exceed the temperature range. May be.

図1に示す放熱装置(1)をろう材を変えて仮組し、ろう付試験を行った。   The heat radiating device (1) shown in FIG. 1 was temporarily assembled by changing the brazing material, and a brazing test was performed.

[放熱装置の構成部材とろう材]
放熱装置(1)の仮組体は、各例で共通の回路層(12)、絶縁層(11)、アルミニウム層(13)およびヒートシンク(20)と、各例で異なるろう材とからなる。
[Components and brazing materials for heat dissipation devices]
The temporary assembly of the heat dissipating device (1) is composed of a common circuit layer (12), insulating layer (11), aluminum layer (13) and heat sink (20) in each example, and different brazing materials in each example.

前記回路層(12)は99.99%以上の高純度アルミニウムからなる28.3mm×28.3mm×厚さ0.6mmの平板である。   The circuit layer (12) is a flat plate of 28.3 mm × 28.3 mm × thickness 0.6 mm made of high-purity aluminum of 99.99% or more.

前記絶縁層(11)は窒化アルミニウムからなる30mm×30mm×厚さ0.6mmの平板である。   The insulating layer (11) is a flat plate made of aluminum nitride and having a size of 30 mm × 30 mm × thickness 0.6 mm.

前記アルミニウム層(13)は、99.99%以上の高純度アルミニウムからなり、28.3mm×28.3mm×厚さ1.6mmの平板に直径2mmの13個の貫通穴(13a)を穿設したパンチングメタルである。   The aluminum layer (13) is made of high-purity aluminum of 99.99% or more, and 13 through holes (13a) having a diameter of 2 mm are drilled on a flat plate of 28.3 mm × 28.3 mm × thickness 1.6 mm. Punched metal.

前記ヒートシンク(20)の上板(21)および底板(22)の材料は、A3003からなる心材にAl−10質量%Si−1質量%Zn合金からなるろう材をクラッドした片面ブレージングシートである。前記ブレージングシートの厚さは1.0mmであり、ろう材のクラッド率は5%である。上板(21)は前記ブレージングシートにプレス加工で平面視50mm×50mmの膨出部を形成し、膨出部の開口周縁を接合用継ぎ手部としたものである。底板(22)は前記ブレージングシートを上板(21)の接合用継ぎ手部の寸法に合わせて切断した平板である。インナーフィン(24)は厚さ0.3mmのA1100からなるベア材をコルゲート形に曲成したものである。前記ヒートシンク(20)は前記上板(21)および底板(22)をろう材側の面同士を対向させ、冷媒室(23)内にインナーフィン(24)を装填して組み立てたものである。   The material of the top plate (21) and the bottom plate (22) of the heat sink (20) is a single-sided brazing sheet in which a brazing material made of an Al-10 mass% Si-1 mass% Zn alloy is clad on a core material made of A3003. The brazing sheet has a thickness of 1.0 mm and the brazing material has a cladding ratio of 5%. The upper plate (21) is formed by forming a bulging portion having a plan view of 50 mm × 50 mm on the brazing sheet by pressing and using the peripheral edge of the opening of the bulging portion as a joint portion for joining. The bottom plate (22) is a flat plate obtained by cutting the brazing sheet in accordance with the dimensions of the joint portion of the upper plate (21). The inner fin (24) is formed by bending a bare material made of A1100 having a thickness of 0.3 mm into a corrugated shape. The heat sink (20) is assembled by placing the upper plate (21) and the bottom plate (22) with the brazing material-side surfaces facing each other and loading the inner fin (24) in the refrigerant chamber (23).

前記絶縁層(11)とアルミニウム層(13)とを接合する第1ろう材(41)、およびアルミニウム層(13)とヒートシンク(20)とを接合する第2ろう材(42)として、表1に示す組成で厚さ20μmのろう材箔を用いた。前記第1ろう材(41)および第2ろう材(42)の固相線温度X、Yおよび固相線温度差Y−Xは表1に示すとおりである。また、前記絶縁層(11)と回路層(12)とを接合する第3ろう材(33)は各例で共通であり、厚さが40μmのAl−10質量%Si−1質量%Mg合金ろう材箔を用いた。   Table 1 shows a first brazing material (41) for joining the insulating layer (11) and the aluminum layer (13), and a second brazing material (42) for joining the aluminum layer (13) and the heat sink (20). A brazing material foil having a thickness of 20 μm was used. Table 1 shows the solidus temperature X, Y and the solidus temperature difference Y-X of the first brazing material (41) and the second brazing material (42). Further, the third brazing material (33) for joining the insulating layer (11) and the circuit layer (12) is common in each example, and an Al-10 mass% Si-1 mass% Mg alloy having a thickness of 40 μm. A brazing foil was used.

[ろう付試験]
回路層(12)、第3ろう材(43)、絶縁層(11)、第1ろう材(41)、アルミニウム層(13)、第1ろう材(42)、ヒートシンク(20)をこの記載順に重ねて放熱装置(1)を仮組し、真空中で600℃×20分加熱して一括ろう付した。このろう付の温度プロファイルにおいて、仮組体の実体温度が室温から600℃まで昇温するのに50分を要し、600℃に達した後の20分を600℃に保持した。前記ろう付の温度プロファイルにおいて、実体温度が第1ろう材(41)の固相線温度X℃以上で第2ろう材(42)の固相線温度Y℃未満の中間温度域に保持された時間は表1に示す時間であった。
[Brazing test]
Circuit layer (12), third brazing material (43), insulating layer (11), first brazing material (41), aluminum layer (13), first brazing material (42), heat sink (20) in this order The heat dissipating device (1) was temporarily assembled, and then brazed by heating at 600 ° C. for 20 minutes in a vacuum. In this brazing temperature profile, it took 50 minutes for the actual temperature of the temporary assembly to rise from room temperature to 600 ° C., and 20 minutes after reaching 600 ° C. was maintained at 600 ° C. In the brazing temperature profile, the solid temperature was maintained in an intermediate temperature range that is not lower than the solidus temperature X ° C. of the first brazing material (41) and lower than the solidus temperature Y ° C. of the second brazing material (42). The time was the time shown in Table 1.

ろう付した放熱装置(1)について、絶縁層(11)とアルミニウム層(13)の第1接合部(31)、およびアルミニウム層(13)とヒートシンク(20)の第2接合部(32)の接合状態を超音波探傷して接合面積率を調べ、下記の基準で評価した。   For the brazed heat dissipation device (1), the first joint (31) between the insulating layer (11) and the aluminum layer (13) and the second joint (32) between the aluminum layer (13) and the heat sink (20). The joining state was examined by ultrasonic flaw detection to examine the joining area ratio, and evaluated according to the following criteria.

○:接合面積率が95%以上
△:接合面積率が85%以上95%未満
×:接合面積率が85%未満
○: Joining area ratio is 95% or more Δ: Joining area ratio is 85% or more and less than 95% ×: Joining area ratio is less than 85%

また、第1接合部(31)および第2接合部(32)を観察してろう材の余剰の度合い(エロ−ジョン)調べ、下記の基準で評価した。
○:エロ−ジョンが殆ど見られない
×:エロ−ジョンが激しい
これらの評価結果を表1に併せて示す。
Moreover, the 1st junction part (31) and the 2nd junction part (32) were observed, the excess degree (erosion) of brazing material was investigated, and the following reference | standard evaluated.
◯: Almost no erosion is observed. X: The erosion is intense. These evaluation results are also shown in Table 1.

Figure 0006105437
Figure 0006105437

表1に示すように、ろう材の固相線温度に基づいてろう材を選定することにより、ろう付性に難易差のある放熱装置を良好にろう付できることを確認した。   As shown in Table 1, it was confirmed that by selecting a brazing material based on the solidus temperature of the brazing material, it is possible to satisfactorily braze a heat radiating device having a difficulty in brazing.

本発明は、絶縁層とヒートシンクとをアルミニウム層を介して積層し、これらを一括ろう付して一体化した放熱装置の製造に利用できる。   INDUSTRIAL APPLICATION This invention can be utilized for manufacture of the heat sink which laminated | stacked the insulating layer and the heat sink via the aluminum layer, and integrated these by brazing collectively.

1…放熱装置
11…絶縁層
12…回路層
13…アルミニウム層
14…電子素子
20…ヒートシンク
41…第1ろう材
42…第2ろう材
43…第3ろう材
1 ... Heat dissipation device
11… Insulating layer
12 ... Circuit layer
13 ... Aluminum layer
14 ... Electronic elements
20 ... heat sink
41 ... 1st brazing filler metal
42 ... Second brazing material
43 ... Third brazing material

Claims (9)

絶縁層の一方の面側に電子素子を搭載する回路層が積層され、他方の面側にアルミニウム層を介してヒートシンクが積層されて、これらが一体化された放熱装置であって、
前記絶縁層とアルミニウム層とが第1ろう材によって接合され、前記アルミニウム層とヒートシンクとが第2ろう材によって接合され、
前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とがX<Yの関係を満たしていることを特徴とする放熱装置。
A circuit layer for mounting an electronic element is laminated on one surface side of the insulating layer, and a heat sink is laminated on the other surface side through an aluminum layer.
The insulating layer and the aluminum layer are joined by a first brazing material, and the aluminum layer and the heat sink are joined by a second brazing material,
A heat dissipation device, wherein the solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy a relationship of X <Y.
前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とが0.5<Y−X<30の関係を満たしている請求項1に記載の放熱装置。   2. The heat dissipation device according to claim 1, wherein the solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy a relationship of 0.5 <Y−X <30. 前記第1ろう材の固相線温度Xが500〜565℃であり、第2ろう材の固相線温度Yが520〜577℃である請求項1または2に記載の放熱装置。   The heat dissipation device according to claim 1 or 2, wherein the solidus temperature X of the first brazing material is 500 to 565 ° C, and the solidus temperature Y of the second brazing material is 520 to 577 ° C. 前記第1ろう材は、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である請求項1〜3のうちのいずれか1項に記載の放熱装置。   The first brazing material is one selected from the group consisting of an Al-Si-Zn alloy brazing material, an Al-Si-Cu alloy brazing material, and an Al-Si-Cu-Zn alloy brazing material. The heat radiating device according to any one of? 前記第2ろう材は、Al−Si系合金ろう材、Al−Si−Zn系合金ろう材、Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材の群から選ばれる1種である請求項1〜4のうちのいずれか1項に記載の放熱装置。   The second brazing material is selected from the group consisting of an Al—Si based brazing material, an Al—Si—Zn based brazing material, an Al—Si—Cu based brazing material, and an Al—Si—Cu—Zn based brazing material. The heat dissipating device according to claim 1, wherein the heat dissipating device is one type. 前記Al−Si−Zn系合金ろう材およびAl−Si−Cu−Zn系合金ろう材中のZn濃度が1.5〜20質量%である請求項4または5に記載の放熱装置。   The heat dissipation device according to claim 4 or 5, wherein a Zn concentration in the Al-Si-Zn-based alloy brazing material and the Al-Si-Cu-Zn-based alloy brazing material is 1.5 to 20% by mass. 前記Al−Si−Cu系合金ろう材およびAl−Si−Cu−Zn系合金ろう材中のCu濃度が0.3〜15質量%である請求項4または5に記載の放熱装置。   The heat dissipation device according to claim 4 or 5, wherein a Cu concentration in the Al-Si-Cu-based alloy brazing material and the Al-Si-Cu-Zn-based alloy brazing material is 0.3 to 15% by mass. 絶縁層、第1ろう材、アルミニウム層、第2ろう材、ヒートシンクの順に重ねて仮組みし、この仮組体を加熱して絶縁層、アルミニウム層およびヒートシンクをろう付する放熱装置の製造方法であって、
前記第1ろう材の固相線温度X℃と第2ろう材の固相線温度Y℃とがX<Yの関係を満たし、
前記ろう付の温度プロファイルにおいて、前記仮組体を第1ろう材の固相線温度X℃以上で第2ろう材の固相線温度Y℃未満の中間温度域に保持することを特徴とする放熱装置の製造方法。
In the method of manufacturing a heat dissipation device, the insulating layer, the first brazing material, the aluminum layer, the second brazing material, and the heat sink are stacked and temporarily assembled, and the temporary assembly is heated to braze the insulating layer, the aluminum layer, and the heat sink. There,
The solidus temperature X ° C. of the first brazing material and the solidus temperature Y ° C. of the second brazing material satisfy the relationship X <Y,
In the brazing temperature profile, the temporary assembly is held in an intermediate temperature range not lower than the solidus temperature XC of the first brazing material and lower than the solidus temperature YC of the second brazing material. Manufacturing method of heat dissipation device.
前記中間温度域の保持時間は0.5〜10分である請求項8に記載の放熱装置の製造方法。   The method for manufacturing a heat dissipation device according to claim 8, wherein a holding time of the intermediate temperature range is 0.5 to 10 minutes.
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