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JP6115403B2 - Pressure gradient type plasma gun - Google Patents
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JP6115403B2 - Pressure gradient type plasma gun - Google Patents

Pressure gradient type plasma gun Download PDF

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JP6115403B2
JP6115403B2 JP2013175547A JP2013175547A JP6115403B2 JP 6115403 B2 JP6115403 B2 JP 6115403B2 JP 2013175547 A JP2013175547 A JP 2013175547A JP 2013175547 A JP2013175547 A JP 2013175547A JP 6115403 B2 JP6115403 B2 JP 6115403B2
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main electrode
flat plate
auxiliary electrode
pressure gradient
plasma gun
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JP2015045038A (en
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勝 園部
園部  勝
健志 高井
健志 高井
嗣紀 佐藤
嗣紀 佐藤
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Nachi Fujikoshi Corp
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Description

本発明は、電子ビームを発生させるための圧力勾配型プラズマガンに関し、特に補助電極の改良に関する。   The present invention relates to a pressure gradient plasma gun for generating an electron beam, and more particularly to improvement of an auxiliary electrode.

真空プラズマ成膜装置等においては、電子ビームにより、ハース上の成膜材料を加熱し、溶融又は蒸発あるいは昇華させ、基板上に金属やセラミック薄膜を成膜する。かかる電子ビーム又はプラズマを発生させるプラズマガンの1つに圧力勾配型プラズマガンがある。圧力勾配型プラズマガンの例としては、特許文献1の図6及び従来技術の段落0002においては、主電極と補助電極とからなる電極構造を採用することにより、低電圧かつ大電流の高効率放電を目的とするものが開示されている。圧力勾配型プラズマガンを備えるプラズマ成膜装置では、カソード領域内の圧力を成膜室内の圧力よりも高くするようカソード領域内と成膜室内との間に圧力勾配を形成させることにより、主電極及び補助電極等へのプラズマの直撃が緩和されるので、プラズマによる主電極及び補助電極等の損傷が防止される。このように、圧力勾配型プラズマガンを備えるプラズマ成膜装置によれば、主電極及び補助電極等の損傷が防止されるので、所望の成膜品質を長期間に渡り安定して確保することができると記載されている。   In a vacuum plasma film forming apparatus or the like, a film forming material on a hearth is heated by an electron beam and melted, evaporated or sublimated to form a metal or ceramic thin film on a substrate. One of the plasma guns that generate such an electron beam or plasma is a pressure gradient type plasma gun. As an example of the pressure gradient type plasma gun, in FIG. 6 of Patent Document 1 and paragraph 0002 of the prior art, a high-efficiency discharge with a low voltage and a large current is achieved by adopting an electrode structure composed of a main electrode and an auxiliary electrode. What is aimed at is disclosed. In a plasma film forming apparatus equipped with a pressure gradient type plasma gun, a main electrode is formed by forming a pressure gradient between the cathode region and the film forming chamber so that the pressure in the cathode region is higher than the pressure in the film forming chamber. Since the direct hit of plasma on the auxiliary electrode and the like is alleviated, damage to the main electrode and auxiliary electrode due to the plasma is prevented. As described above, according to the plasma film forming apparatus equipped with the pressure gradient type plasma gun, the main electrode and the auxiliary electrode are prevented from being damaged, so that the desired film forming quality can be secured stably over a long period of time. It is stated that it can be done.

より詳述すると、図4に示すように、従来の圧力勾配型プラズマガン51は、図示しないカソードに接続される基体10に一端20bが気密接続され他端部20aに開口部21を有する筒状のカソード保護管20が設けられている。このカソード保護管20内に、基体10側より、基体のガス源連通穴10aに連通する貫通穴12aを有するガス誘導管52が開口部21に向かってカソード保護管と同軸に設けられている。ガス誘導管52の先端部52bには、ガス誘導管の先端部外周が貫通する開口40aを備えた円盤状の主電極40が設けられており、主電極40とカソード保護管の開口部21との間に放電空間41を形成している。また、主電極40の開口40aから突出するガス誘導管52の先端部52bが補助電極となる。なお、各部材の材料は、使用温度、価格、加工性等の観点から、カソード保護管はモリブデン又はタングステン材、ガス誘導管はタンタル、主電極は6ホウ化ランタンが多用される。   More specifically, as shown in FIG. 4, a conventional pressure gradient type plasma gun 51 has a cylindrical shape having one end 20b hermetically connected to a base 10 connected to a cathode (not shown) and an opening 21 at the other end 20a. The cathode protection tube 20 is provided. In the cathode protection tube 20, a gas induction tube 52 having a through hole 12 a communicating with the gas source communication hole 10 a of the substrate from the substrate 10 side is provided coaxially with the cathode protection tube toward the opening 21. The tip 52b of the gas guide tube 52 is provided with a disk-shaped main electrode 40 having an opening 40a through which the outer periphery of the tip of the gas guide tube passes, and the main electrode 40 and the opening 21 of the cathode protection tube A discharge space 41 is formed between the two. Further, the tip 52b of the gas guide tube 52 protruding from the opening 40a of the main electrode 40 serves as an auxiliary electrode. From the viewpoints of operating temperature, price, workability, etc., the material of each member is frequently made of molybdenum or tungsten material for the cathode protective tube, tantalum for the gas induction tube, and lanthanum hexaboride for the main electrode.

かかる従来の圧力勾配型プラズマガン51の放電は次のように行われる。図5(a)に示すように放電開始直後、すなわち補助電極52bおよび主電極40が十分に加熱されていない状態では印加用補助電極13と距離が一番近いカソード保護管20の他端部20aとの間でグロー放電によるプラズマ42が発生する。そして、グロー放電により空間41に十分な電子が供給されると、開口40aより突出するガス誘導管の先端部52bが補助電極として中空放電を始め、図5(b)に示すようにプラズマ43が発生するようになる。さらに、放電開始から数十秒が経過すると補助電極52bからの熱輻射により主電極40の温度が上がる。すると主電極40から十分な量の熱電子が放出され、プラズマ放電は図5(c)に示すように主電極40からの熱電子放電によるプラズマが支配的になる。これにより、安定した高圧のプラズマ46を発生させ、アノード側に引き込み制御して、成膜材料等のターゲットを加熱する。   The conventional pressure gradient type plasma gun 51 is discharged as follows. As shown in FIG. 5A, immediately after the start of discharge, that is, in a state where the auxiliary electrode 52b and the main electrode 40 are not sufficiently heated, the other end portion 20a of the cathode protective tube 20 closest to the application auxiliary electrode 13 is provided. Plasma 42 is generated by glow discharge. Then, when sufficient electrons are supplied to the space 41 by glow discharge, the tip 52b of the gas induction tube protruding from the opening 40a starts hollow discharge as an auxiliary electrode, and the plasma 43 is generated as shown in FIG. To occur. Furthermore, when several tens of seconds have elapsed from the start of discharge, the temperature of the main electrode 40 rises due to heat radiation from the auxiliary electrode 52b. Then, a sufficient amount of thermionic electrons are emitted from the main electrode 40, and plasma due to thermionic discharge from the main electrode 40 becomes dominant in the plasma discharge as shown in FIG. As a result, a stable high-pressure plasma 46 is generated and drawn into the anode side, and a target such as a film forming material is heated.

しかし、このものは、補助電極52bは筒又は管状であり、かつ、主電極40の中心の開口40aを貫通しており、主電極の中央から熱電子が放出されないため、プラズマの放出効率を悪化させているという問題があった。また、特許文献1に記載はないが、主放電中の主電極の温度は2000℃近くなるため、図6の楕円で囲んだ部分に示すように、主電極放電中に放電空間に暴露された補助電極(ガス導入管の先端)52bの消耗が激しいという問題があった。   However, in this device, the auxiliary electrode 52b is cylindrical or tubular and penetrates through the opening 40a at the center of the main electrode 40, so that thermionic electrons are not emitted from the center of the main electrode. There was a problem of letting it. Although not described in Patent Document 1, the temperature of the main electrode during the main discharge is close to 2000 ° C., so that the main electrode was exposed to the discharge space during the main electrode discharge as shown in the part surrounded by the ellipse in FIG. There was a problem that the consumption of the auxiliary electrode (tip of the gas introduction pipe) 52b was severe.

そこで、特許文献1においては、ガス誘導管の先端を後退させ、主電極及び放電空間からガス導入管の先端を離隔した。結果として補助電極を無くしている。さらに、主電極形状をカソード保護管の軸心を直角方向面で遮断する貫通穴のない平板状とした。さらに、ガスをカソード保護管他端と主電極間との間の放電空間に導くため、主電極とカソード保護管内周面との間にガス導入穴を設けるようにした。また、ガス導入管の後退によりなくなる補助電極の代替のため、主電極外縁のガス導入穴近傍から放電空間に向かって突出する突出部を設けてそれを補助電極の代替としている。   Therefore, in Patent Document 1, the tip of the gas induction tube is retracted, and the tip of the gas introduction tube is separated from the main electrode and the discharge space. As a result, the auxiliary electrode is eliminated. Furthermore, the main electrode was formed into a flat plate shape without a through hole that cuts off the axis of the cathode protective tube at a right angle plane. Further, in order to introduce the gas into the discharge space between the other end of the cathode protective tube and the main electrode, a gas introduction hole is provided between the main electrode and the inner peripheral surface of the cathode protective tube. In addition, in order to replace the auxiliary electrode that disappears due to the retraction of the gas introduction tube, a protrusion that protrudes from the vicinity of the gas introduction hole on the outer edge of the main electrode toward the discharge space is provided and used as an alternative to the auxiliary electrode.

また、特許文献2においては、ガス導入管の先端を後退させるとともに、フィラメントを設けて補助電極とし、フィラメントを加熱して積極的に熱電子を発生させ、放電持続能力を増している。さらに、主電極を2枚設け、放電空間を複数とし、実効的な主電極の面積を増やし、主放電中のプラズマ放電効率を改善している。   In Patent Document 2, the tip of the gas introduction tube is retracted, and a filament is provided as an auxiliary electrode, and the filament is heated to actively generate thermoelectrons to increase the discharge sustainability. Further, two main electrodes are provided, a plurality of discharge spaces are provided, the effective area of the main electrode is increased, and the plasma discharge efficiency during the main discharge is improved.

特開2010−262835号公報JP 2010-262835 A 特許4359597号公報Japanese Patent No. 4359597

しかし、特許文献1のものでは、従来のものに対してガス誘導管の先端の消耗は無くなるものの、新たに設けた主電極外縁の突出部を放電しやすい突起状にすると、主電源側が高熱となるので、突起部が消耗しやすくなるという新たな問題があった。また、ガス導入口を主電極外縁に設けるので、導入口の形状、面積計算、放電空間内でのガスの流れも複雑になり、放電空間への安定したガス供給が困難となる虞れがある。また、外縁に損耗が発生して、形状が変化すると放電空間内の圧力勾配が大きく変化し安定した放電条件を得るのが困難である。   However, in Patent Document 1, the tip of the gas guide tube is not consumed as compared with the conventional one, but if the projecting portion of the newly provided outer edge of the main electrode is formed into a protruding shape that is easy to discharge, the main power source side becomes hot. Therefore, there has been a new problem that the protrusions are easily consumed. In addition, since the gas introduction port is provided at the outer edge of the main electrode, the shape of the introduction port, the area calculation, and the gas flow in the discharge space become complicated, and there is a possibility that stable gas supply to the discharge space may be difficult. . Further, when the outer edge is worn and the shape changes, the pressure gradient in the discharge space changes greatly, making it difficult to obtain stable discharge conditions.

一方、主電極の外縁に突起部を設け、中央の貫通穴を遮断したので、主電極全体としての電極面積を増加できる。しかし、突起部は主電極の外縁となるため、カソード保護管の他端の開口部との距離は主電極の中心部より長くなるので、放電初期の補助電極としての機能が低下する等の問題があった。   On the other hand, since the projection is provided on the outer edge of the main electrode and the central through hole is blocked, the electrode area of the entire main electrode can be increased. However, since the protrusion is the outer edge of the main electrode, the distance from the opening at the other end of the cathode protective tube is longer than the center of the main electrode, so that the function as an auxiliary electrode at the initial stage of discharge is deteriorated. was there.

また、特許文献2においては、主電極の面積を大きくできるが、タングステンフィラメントを追加するため構造、制御も複雑となる。さらには、フィラメント加熱の為の別電源が必要である等の問題があった。さらに、特許文献2の二枚の主電極の基体側を特許文献1のものにおきかえることも考えられるが、この場合はフィラメントを取り付けることはできない。また、カソード保護管が長くなり、装置が大きくなるという問題があった。さらには、前述した特許文献1の問題点を解消できない。   In Patent Document 2, the area of the main electrode can be increased. However, since a tungsten filament is added, the structure and control are complicated. Furthermore, there is a problem that a separate power source is required for heating the filament. Further, although it is conceivable to replace the base side of the two main electrodes of Patent Document 2 with that of Patent Document 1, in this case, a filament cannot be attached. Further, there is a problem that the cathode protective tube becomes long and the apparatus becomes large. Furthermore, the above-described problem of Patent Document 1 cannot be solved.

本発明の課題は、前述した問題点に鑑みて、簡単な構造で、ガス誘導管の消耗がなく、代替された補助電極の消耗が少なく、安定したプラズマを持続できる圧力勾配型プラズマガンを提供し、プラズマガンのメンテナンス費用を削減すると同時に高価なプラズマ真空成膜装置の稼働率向上を提供することである。   In view of the above-mentioned problems, an object of the present invention is to provide a pressure gradient type plasma gun that has a simple structure, does not consume a gas induction tube, consumes an alternative auxiliary electrode, and can maintain a stable plasma. In addition, the maintenance cost of the plasma gun is reduced, and at the same time, the operating rate of the expensive plasma vacuum film forming apparatus is improved.

本発明においては、カソードに接続される基体と、前記基体に一端が気密接続され他端部に開口部を有する筒状のカソード保護管と、を有し、前記カソード保護管内に、前記基体側より、前記基体のガス源連通穴に連通する貫通穴を有するガス誘導管と、前記ガス誘導管と離隔して前記カソード保護管の軸心を直角方向面で遮断する補助電極平板と、前記補助電極平板の前記開口部側に設けられ、前記開口部と同芯の開口を有する主電極と、が順次配設され、前記補助電極平板の外縁部には、該外縁部を貫通又は切り欠くガス導入口が設けられ、前記補助電極平板と前記主電極との距離が前記補助電極平板と前記主電極との間でグロー放電可能な距離にされている圧力勾配型プラズマガンを提供することにより前述した課題を解決した。   In the present invention, there is provided a base connected to the cathode, and a cylindrical cathode protective tube having one end hermetically connected to the base and having an opening at the other end. A gas induction tube having a through hole communicating with the gas source communication hole of the base; an auxiliary electrode flat plate that is spaced apart from the gas induction tube and blocks the axis of the cathode protective tube at a right angle plane; and A main electrode having an opening concentric with the opening provided on the opening side of the electrode plate, and a gas penetrating or notching the outer edge of the auxiliary electrode plate By providing a pressure gradient type plasma gun provided with an introduction port, the distance between the auxiliary electrode flat plate and the main electrode being a distance capable of glow discharge between the auxiliary electrode flat plate and the main electrode. Solved the problem.

即ち、主電極の開口に近接して補助電極平板を配置し、補助電極外周側から主電極開口にガスを通過させ、主電極と補助電極平板の間でグロー放電を可能とした。これにより、主電極の開口内部および主電極裏面の一部、補助電極平板を主電極の加熱のための初期グロー放電加熱源として用いることができる。さらに、主電極及び主電極の開口内部および主電極裏面の一部を主プラスマ放電時のプラズマ放電面積として用いることができる。また、主電極及び補助電極平板とガス誘導管は離隔されている。   That is, the auxiliary electrode flat plate is disposed in the vicinity of the opening of the main electrode, gas is passed from the outer peripheral side of the auxiliary electrode to the main electrode opening, and glow discharge is enabled between the main electrode and the auxiliary electrode flat plate. Accordingly, the inside of the opening of the main electrode, a part of the back surface of the main electrode, and the auxiliary electrode flat plate can be used as an initial glow discharge heating source for heating the main electrode. Furthermore, the inside of the main electrode, the opening of the main electrode, and a part of the back surface of the main electrode can be used as a plasma discharge area during main plasma discharge. The main electrode and auxiliary electrode flat plate and the gas guide tube are separated from each other.

主電極と補助電極平板の間でグロー放電を可能とするために、請求項2記載の発明においては、前記補助電極平板と前記主電極との距離は、前記主電極の開口径の2倍以下0.3倍以上とした。なお、この値は具体例としての好ましい値であり、グロー放電を可能にする絶対条件ではない。さらに、請求項3記載の発明においては、前記補助電極平板の材料の耐熱温度が前記主電極の材料の耐熱温度より低い材料とした。主電極の材質は、一般に6ホウ化ランタン(LaB6)が多用されるが、本発明の補助電極平板は高温にさらされる部位が少ないので、従来のガス誘導管と同様のタンタルでよい。また、ガス誘導管は補助電極としての役割は不要なので、カソード保護管と同様なモリブデン、タングステン等の材料でよい。   In order to enable glow discharge between the main electrode and the auxiliary electrode flat plate, the distance between the auxiliary electrode flat plate and the main electrode is not more than twice the opening diameter of the main electrode. 0.3 times or more. This value is a preferable value as a specific example, and is not an absolute condition that enables glow discharge. According to a third aspect of the invention, the heat resistance temperature of the auxiliary electrode flat plate material is lower than the heat resistance temperature of the main electrode material. As the material of the main electrode, lanthanum hexaboride (LaB6) is generally used. However, since the auxiliary electrode flat plate of the present invention has few parts exposed to high temperature, the same tantalum as that of the conventional gas induction tube may be used. Further, since the gas induction tube does not need to serve as an auxiliary electrode, it may be made of a material such as molybdenum or tungsten similar to the cathode protective tube.

また、ガス誘導管の全長が従来に対して短くなるため、グロー放電に好適な圧力を得るため、管の内径を従来に対して細い管を用いたほうがよい。さらに、ガス誘導管は熱電子を放出する必要がない。そこで、請求項4に記載の発明においては、前記ガス誘導管をセラミックス材料とした。また、請求項5に記載の発明においては、前記補助電極板の中央に主電極板に向かって突起部が設けられている圧力勾配型プラズマガンとした。突起部を設けることにより、初期グロー放電の発生を容易にする。また、請求項6に記載の発明においては、前記突起形状は前記軸心を軸とする円錐形状とした。   In addition, since the overall length of the gas induction tube is shorter than that of the conventional one, it is better to use a tube whose inner diameter is smaller than that of the conventional one in order to obtain a pressure suitable for glow discharge. Furthermore, the gas induction tube does not need to emit thermal electrons. Therefore, in the invention described in claim 4, the gas induction tube is made of a ceramic material. According to a fifth aspect of the present invention, a pressure gradient plasma gun is provided in which a protrusion is provided in the center of the auxiliary electrode plate toward the main electrode plate. Providing the protrusions facilitates the generation of initial glow discharge. In the invention described in claim 6, the shape of the protrusion is a conical shape having the axis as an axis.

また、請求項7に記載の発明においては、前記補助電極平板は円盤の一部が複数か所切欠かれた形状であって、前記円盤の外縁部が前記カソード保護管内周面に固定され、前記切欠かれた部分と前記カソード保護管内周面とで、前記ガス導入口が形成されている圧力勾配型プラズマガンとした。ガス導入口はドリル穴加工等でもよいが、切削屑等の発生の少ない切り欠き形状とする。   Further, in the invention according to claim 7, the auxiliary electrode flat plate has a shape in which a part of the disk is cut out at a plurality of positions, and an outer edge portion of the disk is fixed to the inner peripheral surface of the cathode protective tube, A pressure gradient type plasma gun in which the gas inlet is formed by the notched portion and the inner peripheral surface of the cathode protective tube. The gas inlet may be a drill hole or the like, but has a notch shape with less generation of cutting waste.

さらに、請求項8記載の発明においては、前記補助電極平板と前記ガス導入口は一体成型され、前記補助電極平板の外縁部の周方向の複数か所が前記主電極側に折り曲げ延出され、前記補助電極平板の延出部端が前記主電極に当接かつ軸方向に位置決め固定され、前記延出部と前記カソード保護管内周面とで、前記ガス導入口が形成されている圧力勾配型プラズマガンとした。即ち、補助電極平板の外縁を折り曲げることにより、位置決めとガス導入口を同時に形成した。   Furthermore, in the invention according to claim 8, the auxiliary electrode flat plate and the gas introduction port are integrally molded, and a plurality of circumferential positions of the outer edge portion of the auxiliary electrode flat plate are bent and extended to the main electrode side, A pressure gradient type in which the end of the extended portion of the auxiliary electrode flat plate is in contact with the main electrode and is positioned and fixed in the axial direction, and the gas inlet is formed by the extended portion and the inner peripheral surface of the cathode protective tube A plasma gun was used. That is, the outer edge of the auxiliary electrode flat plate was bent to form the positioning and the gas inlet at the same time.

本発明においては、主電極の開口に近接して補助電極平板を配置し、補助電極外周側から主電極開口にガスを通過させ、主電極の開口内部および主電極裏面の一部、補助電極平板を初期グロー放電加熱源、主電極及び主電極の開口内部および主電極裏面の一部をプラズマ放電面積として用いるので、放電効率のよい圧力勾配型プラズマガンを提供するものとなった。また、プラズマ放電面積が増えるため、主電極の温度が低下し、主電極の消耗時間を延長することができ、長寿命となった。   In the present invention, an auxiliary electrode flat plate is disposed close to the opening of the main electrode, gas is passed from the outer peripheral side of the auxiliary electrode to the main electrode opening, a part of the main electrode opening and a part of the back surface of the main electrode, the auxiliary electrode flat plate Is used as the initial glow discharge heating source, the main electrode, the inside of the opening of the main electrode, and a part of the back surface of the main electrode as the plasma discharge area, thereby providing a pressure gradient type plasma gun with good discharge efficiency. Further, since the plasma discharge area is increased, the temperature of the main electrode is lowered, the consumption time of the main electrode can be extended, and the life is prolonged.

また、ガス誘導管の先端を主電極の開口から突出することなく、離隔させたので、主電極による高熱の影響がなくガス誘導管の先端の損傷はない。さらに、ガス誘導管を通じての熱の逃げが無い。ガス誘導管からの熱の逃げがないので、速やかに所定温度に達することができ、プラズマ点火時間を短縮する効果も得られる。また、補助電極平板外縁から中央に向けて安定して流れるガスを開口に導入できるので、プラズマがより安定する。   Further, since the tip of the gas guide tube is separated without protruding from the opening of the main electrode, there is no influence of high heat by the main electrode, and the tip of the gas guide tube is not damaged. Furthermore, there is no heat escape through the gas induction tube. Since there is no heat escape from the gas induction tube, it is possible to quickly reach a predetermined temperature, and the effect of shortening the plasma ignition time can be obtained. In addition, since the gas that flows stably from the outer edge of the auxiliary electrode flat plate toward the center can be introduced into the opening, the plasma becomes more stable.

さらに、補助電極平板は主電極と離隔、後退しているので、主電極による高熱の影響が少ないので、補助電極平板の消耗も少ない。このように、本発明によれば、安定したプラズマを持続できるものとなった。さらに、消耗品は主電極がほとんどであり、さらなる長寿命化を得ることが可能となり、生産設備の点検交換周期延長によるランニングコスト低減を図ることができる。この効果をさらに高めるためには主電極の厚さを増やすと尚良く、設定した圧力条件で中空放電が維持されるように貫通孔および補助電極板との距離を最適化されればなお良い。   Further, since the auxiliary electrode flat plate is spaced apart from the main electrode and recedes, the influence of high heat by the main electrode is small, so that the consumption of the auxiliary electrode flat plate is also small. Thus, according to the present invention, stable plasma can be sustained. Further, most of the consumables are main electrodes, and it is possible to obtain a longer life, and it is possible to reduce the running cost by extending the inspection and replacement cycle of the production equipment. In order to further enhance this effect, it is better to increase the thickness of the main electrode, and it is better to optimize the distance between the through hole and the auxiliary electrode plate so that the hollow discharge is maintained under the set pressure condition.

なお、特許文献1のものでは、補助電極をなくし、主電極を開口のない平板としただけなので、本発明のような主電極の開口内部および主電極裏面の一部を熱電子供給源として用いることができないので、本発明のような効率的な放電面積を増すことはできない。また、特許文献2の2つの主電極の基体側を特許文献1のような電極平板としても、電極間が広いので、カソード保護管長さが長く装置が大きくなるという問題は解決しない。また、高額な6ホウ化ランタン等の主電極を複数枚用いなくても同等の効果を得ることが可能となる。     In addition, in the thing of patent document 1, since an auxiliary electrode is lost and only the main electrode was made into the flat plate without an opening, the inside of opening of a main electrode like this invention and a part of back surface of a main electrode are used as a thermoelectron supply source. Therefore, the effective discharge area as in the present invention cannot be increased. Further, even if the base side of the two main electrodes of Patent Document 2 is an electrode flat plate as in Patent Document 1, the problem that the length of the cathode protective tube is long and the device becomes large is not solved because the distance between the electrodes is wide. Further, the same effect can be obtained without using a plurality of expensive main electrodes such as lanthanum hexaboride.

請求項2記載の発明においては、補助電極平板と主電極との距離を主電極の開口径の2倍以下0.3倍以上としてグロー放電を発生し易くしたので、所定温度への立ち上がりが早くなる。また、請求項3記載の発明においては、補助電極平板の材料をタンタル(Ta)等とし、主電極の材料の6ホウ化ランタン等の耐熱温度より低い材料としたので、低コストとなる。さらには、ガス誘導管が熱電子を放出する必要がなくなるため、ガス誘導管の材料にモリブデン(Mo)、タングステン(W)に加えてセラミック等の耐熱素材を採用することも可能となり、より低コストで長寿命にすることができる(請求項4)。   In the invention described in claim 2, since the distance between the auxiliary electrode flat plate and the main electrode is set to be not more than twice the opening diameter of the main electrode and not less than 0.3 times to facilitate the occurrence of glow discharge, the rise to the predetermined temperature is quick. Become. In the invention described in claim 3, since the auxiliary electrode flat plate material is tantalum (Ta) or the like, and the material is lower than the heat resistant temperature such as lanthanum hexaboride which is the material of the main electrode, the cost is reduced. Furthermore, since there is no need for the gas induction tube to emit thermoelectrons, it is possible to adopt a heat-resistant material such as ceramic in addition to molybdenum (Mo) and tungsten (W) as the material of the gas induction tube. A long service life can be achieved at a low cost (claim 4).

さらに、請求項5に記載の発明においては、補助電極板の中央に突起部を設け、初期グロー放電の発生を容易にしたので、安定して早期に所定温度に達することができる。また、請求項6に記載の発明においては、突起形状を円錐形状としたので、放電をさらに誘導し易くできる。   Furthermore, in the invention described in claim 5, since the projection is provided at the center of the auxiliary electrode plate to facilitate the generation of the initial glow discharge, the predetermined temperature can be reached stably and early. In the invention according to claim 6, since the projection shape is a conical shape, it is possible to further easily induce the discharge.

また、請求項7に記載の発明においては、補助電極平板のガス導入口は円盤の一部を切欠かいた切削屑等の発生の少ない形状とし、さらに、請求項8記載の発明においては、補助電極平板の外縁を折り曲げて補助電極平板とガス導入口を一体成型したので、低コスト、環境にも優しいものとなった。   Further, in the invention described in claim 7, the gas inlet of the auxiliary electrode flat plate has a shape in which the generation of cutting waste or the like obtained by cutting a part of the disk is small. Since the outer edge of the electrode flat plate is bent and the auxiliary electrode flat plate and the gas inlet are integrally formed, the cost is low and the environment is friendly.

本発明の実施の形態における圧力勾配型プラズマガンの(a)は断面図、(b)は内部を透視する斜視図である。(A) of a pressure gradient type | mold plasma gun in embodiment of this invention is sectional drawing, (b) is a perspective view which sees through the inside. 本発明の圧力勾配型プラズマガンの電極からのプラズマ放出状態を示す(a)は印加直後、(b)は遷移状態、(c)は主放電状態の部分断面図である。FIG. 4A is a partial sectional view of a plasma discharge state from an electrode of a pressure gradient plasma gun according to the present invention, FIG. 本発明に他の実施の形態における圧力勾配型プラズマガンの(a)は断面図、(b)は内部を透視する斜視図である。(A) of the pressure gradient type | mold plasma gun in other embodiment of this invention is sectional drawing, (b) is a perspective view which sees through the inside. 従来の圧力勾配型プラズマガンの(a)は断面図、(b)は内部を透視する斜視図である。(A) of the conventional pressure gradient type plasma gun is sectional drawing, (b) is a perspective view which sees through the inside. 従来の圧力勾配型プラズマガンの電極からのプラズマ放出状態を示す(a)は印加直後、(b)は遷移状態、(c)は主放電状態の部分断面説明図である。(A) which shows the plasma emission state from the electrode of the conventional pressure gradient type | mold plasma gun is immediately after application, (b) is a transition state, (c) is partial explanatory drawing of a main discharge state. 従来の圧力勾配型プラズマガンの補助電極管の損傷状態を示す図面代用写真である。It is a drawing substitute photograph which shows the damage state of the auxiliary electrode tube of the conventional pressure gradient type plasma gun.

本発明の実施の形態について図面を参照して説明する。なお、図においては、圧力勾配型プラズマガンの主要な構成要素のみを抜粋して模式的に示しており、その他の構成要素は省略している。また、従来の説明で述べたと同様な構成については同符号を付し、説明の一部又は全部を省略する。図1(a)、(b)に示すように、本発明の実施の形態の圧力勾配型プラズマガン1は、図示しないカソードに接続される基体10と、この基体一端が気密接続され他端部20aに開口部21を有する筒状のカソード保護管20と、カソード保護管を取り囲み一端が気密接続され他端にガン開口11aを有するガラス管11を有している。さらに、ガラス管のガン開口11aには、図示しない電磁コイル、永久磁石等が配置され、プラズマガン1で発生するプラズマを成膜容器内のターゲットあるいは基板等に照射等できるようにされている。   Embodiments of the present invention will be described with reference to the drawings. In the figure, only main components of the pressure gradient type plasma gun are extracted and schematically shown, and other components are omitted. The same reference numerals are given to the same components as those described in the conventional description, and a part or all of the description is omitted. As shown in FIGS. 1A and 1B, a pressure gradient type plasma gun 1 according to an embodiment of the present invention includes a base 10 connected to a cathode (not shown) and one end of the base hermetically connected. A cylindrical cathode protection tube 20 having an opening 21 at 20a, and a glass tube 11 surrounding the cathode protection tube and hermetically connected at one end and having a gun opening 11a at the other end. Further, an electromagnetic coil (not shown), a permanent magnet or the like (not shown) is disposed in the gun opening 11a of the glass tube so that plasma generated by the plasma gun 1 can be irradiated to a target or a substrate in the film forming container.

カソード保護管20内の基体側20bに支持部材22が嵌挿されている。支持部材端面側22aは基体10側に嵌挿固定され、支持部材22が基体10に対しカソード保護管20を保持する。支持部材22の中心貫通穴22bは、基体10に設けられた図示しないガス源(アルゴンガスボンベ等)に連通するガス源連通穴10aに連通している。また、支持部材22の中心貫通穴22bに管状のガス誘導管12の一端(基体側)12cが挿入され、ガス導入管の他端(先端)12bが支持仕切り板23により保持される。支持仕切り板23はカソード保護管内の中程20cに外周縁23aで固定されている。支持仕切り板23中央に支持穴23bが開けられガス導入管12の先端12bが突出又はつら面になるようにされる。   A support member 22 is fitted into the base body side 20 b in the cathode protective tube 20. The support member end face side 22 a is fitted and fixed to the base 10 side, and the support member 22 holds the cathode protective tube 20 with respect to the base 10. The central through hole 22 b of the support member 22 communicates with a gas source communication hole 10 a that communicates with a gas source (not shown) (such as an argon gas cylinder) provided in the base 10. In addition, one end (base side) 12 c of the tubular gas guide tube 12 is inserted into the central through hole 22 b of the support member 22, and the other end (tip) 12 b of the gas introduction tube is held by the support partition plate 23. The support partition plate 23 is fixed to the middle 20c in the cathode protective tube with an outer peripheral edge 23a. A support hole 23b is opened in the center of the support partition plate 23 so that the tip 12b of the gas introduction pipe 12 protrudes or has a icicle surface.

ガス誘導管12の先端12bと離隔してカソード保護管20の軸心を直角方向面で遮断する補助電極平板30が設けられている。補助電極平板30の外縁は、カソード保護管の内周面20dと同径の4箇所の円弧状の外縁部30aと切り欠かれた部分(切り欠き部)30bとが交互に4箇所設けられている。カソード保護管の内周面20dと切り欠き部30bとで、ガス導入口35が形成されている。なお、補助電極平板30は正方形のタンタル板の四隅をカソード保護管の内周面に合わせて切除又は成形することにより容易に製作できる。カソード保護管20の開口部21側に補助電極平板30に隣接してカソード保護管の内周面20dに嵌合する環状部材24が設けられている。   An auxiliary electrode flat plate 30 is provided that is spaced apart from the distal end 12b of the gas induction tube 12 and blocks the axis of the cathode protective tube 20 at a right angle plane. On the outer edge of the auxiliary electrode flat plate 30, four arc-shaped outer edge portions 30a having the same diameter as the inner peripheral surface 20d of the cathode protective tube and four notched portions (notched portions) 30b are provided alternately. Yes. A gas introduction port 35 is formed by the inner peripheral surface 20d of the cathode protective tube and the cutout portion 30b. The auxiliary electrode flat plate 30 can be easily manufactured by cutting or shaping the four corners of a square tantalum plate in accordance with the inner peripheral surface of the cathode protective tube. An annular member 24 is provided adjacent to the auxiliary electrode flat plate 30 on the opening 21 side of the cathode protection tube 20 to be fitted to the inner peripheral surface 20d of the cathode protection tube.

環状部材24に隣接して、主電極40がカソード保護管20の開口部21側に設けられている。主電極の形状は従来と同様、貫通穴40aを備えた円盤状である。また、主電極40とカソード保護管20の開口部21との間に放電空間41が形成されている。また、図2(b)の符号dで示す補助電極平板30と主電極40との距離は、補助電極平板と主電極との間でグロー放電可能な距離にされている。この距離は補助電極平板と主電極との間に環状部材24を挟持させることにより所定の距離に保たれる。なお、カソード保護管20、開口部21、ガス誘導管12、支持仕切り板23の支持穴23b、主電極40の開口40a等は、ほぼ同芯(同軸)にされている。   Adjacent to the annular member 24, the main electrode 40 is provided on the opening 21 side of the cathode protective tube 20. The shape of the main electrode is a disk shape having a through hole 40a as in the conventional case. A discharge space 41 is formed between the main electrode 40 and the opening 21 of the cathode protection tube 20. Further, the distance between the auxiliary electrode flat plate 30 and the main electrode 40 indicated by the symbol d in FIG. 2B is a distance that allows glow discharge between the auxiliary electrode flat plate and the main electrode. This distance is maintained at a predetermined distance by sandwiching the annular member 24 between the auxiliary electrode flat plate and the main electrode. The cathode protective tube 20, the opening 21, the gas guide tube 12, the support hole 23b of the support partition plate 23, the opening 40a of the main electrode 40, and the like are substantially concentric (coaxial).

基体10、カソード保護管20、ガス誘導管21、補助電極平板30、主電極40等は、直接又は適宜な配線を介して、図示しない直流電源の負極と電気的に接続されている。また、外部とは気密となるようにされている。また、開口部21を除くカソード保護管20の内外及び基体10との間、カソード保護管20内と主電極40外周又は環状部材24の外周、及び支持仕切り板23外周は気密であるのが好ましい。主電極40の材料は耐熱温度が高く、電子放出力が大きな6ホウ化ランタン(LaB6)を用いる。また、補助電極平板は6ホウ化ランタンより低温度でグロー放電を発生し易いタンタル(Ta)を用いる。カソード保護管は従来と同様モリブデン(Mo)又はタングステン(W)である。ガス誘導管はタンタルである必要はなくなり、モリブデン又はタングステン等よく、セラミックスでもよい。   The base 10, the cathode protection tube 20, the gas induction tube 21, the auxiliary electrode flat plate 30, the main electrode 40 and the like are electrically connected to a negative electrode of a direct current power source (not shown) directly or via appropriate wiring. In addition, the outside is airtight. Further, it is preferable that the inside and outside of the cathode protection tube 20 excluding the opening 21 and the base 10, the inside of the cathode protection tube 20 and the outer periphery of the main electrode 40 or the outer periphery of the annular member 24, and the outer periphery of the support partition plate 23 are airtight. . The material of the main electrode 40 is lanthanum hexaboride (LaB6), which has a high heat resistant temperature and a large electron emission power. Further, the auxiliary electrode flat plate is made of tantalum (Ta) that easily generates glow discharge at a lower temperature than lanthanum hexaboride. The cathode protective tube is made of molybdenum (Mo) or tungsten (W) as in the conventional case. The gas induction tube need not be tantalum, but may be molybdenum or tungsten, or ceramics.

かかる本発明の実施の形態における圧力勾配型プラズマガン1をプラズマ成膜装置に用いた場合のプラズマについて説明する。図2(a)に示すように、従来と同様にパッシェンの法則に従って、カソード保護管20の他端部20aからグロー放電42が開始される。グロー放電により、十分な量の電子が供給されると、引き続き図2(b)に示すように、従来のプラズマ成膜装置のガス誘導管の先端を補助電極とした中空放電に代えて、補助電極平板30と主電極40の間にグロー放電(補助放電)43が発生する。これは、主電極と補助電極平板との間の間隙dがグリム型の電極構造を形成し、補助放電が開始されるものと推察する。この補助放電により、主電極40が加熱される。   The plasma when the pressure gradient type plasma gun 1 in the embodiment of the present invention is used in a plasma film forming apparatus will be described. As shown in FIG. 2A, glow discharge 42 is started from the other end 20a of the cathode protective tube 20 in accordance with Paschen's law as in the prior art. When a sufficient amount of electrons are supplied by glow discharge, as shown in FIG. 2 (b), instead of hollow discharge using the tip of the gas induction tube of the conventional plasma film forming apparatus as an auxiliary electrode, auxiliary A glow discharge (auxiliary discharge) 43 is generated between the electrode flat plate 30 and the main electrode 40. This is presumed that the gap d between the main electrode and the auxiliary electrode flat plate forms a Grimm-type electrode structure, and auxiliary discharge is started. The main electrode 40 is heated by this auxiliary discharge.

次いで、主電極40が加熱されると、熱電子が放出され、加熱も促進され、高温状態で主電極40による主放電が開始される。そして、図2(c)に示すように、圧力勾配型プラズマガン1(カソード保護管20内)に対して、供給されるルゴン(Ar)ガス44がガス誘導管12、支持仕切り板23と補助電極平板30との間、補助電極平板の外縁のガス導入口35、補助電極平板30と主電極40との間、主電極40の開口40a、放電室41、カソード保護管の他端部20aの開口部21を順次通過して、成膜装置内に導入され、これに合わせて、プラズマ成膜装置が備える成膜室内(図示せず)に向けてプラズマ45が放出される。   Next, when the main electrode 40 is heated, thermoelectrons are emitted, heating is also accelerated, and main discharge by the main electrode 40 is started at a high temperature. Then, as shown in FIG. 2C, the supplied LUGON (Ar) gas 44 is supplied to the pressure gradient type plasma gun 1 (inside the cathode protective tube 20) with the gas induction tube 12, the support partition plate 23 and the auxiliary. Between the electrode flat plate 30, the gas inlet 35 on the outer edge of the auxiliary electrode flat plate, between the auxiliary electrode flat plate 30 and the main electrode 40, the opening 40 a of the main electrode 40, the discharge chamber 41, and the other end 20 a of the cathode protective tube. Passing through the opening 21 sequentially, it is introduced into the film forming apparatus, and accordingly, the plasma 45 is emitted toward a film forming chamber (not shown) provided in the plasma film forming apparatus.

この際、従来のガス誘導管の先端を補助電極の一部とした場合は、主電極40の開口40aを閉ざしてしまう。これに対して、本実施の形態においては、主電極の開口40aにより、主電極40の円環状領域40bに加えて、開口40aの内周および、主電極40の裏側の一部40cからも熱電子が放出される。これにより、従来の主電極の円環状領域40bの面積よりも高い効率で、プラズマが放出される。また、ガス誘導管12の先端12bの損傷はなく、補助電極平板30も主電極40とは離隔しているので、損傷も少なく、また、アルゴンガスの流路や、放電面積の変化が少なく安定したプラズマを供給できる。   At this time, if the tip of the conventional gas guide tube is used as a part of the auxiliary electrode, the opening 40a of the main electrode 40 is closed. On the other hand, in the present embodiment, heat is also generated from the inner periphery of the opening 40a and a part 40c on the back side of the main electrode 40 in addition to the annular region 40b of the main electrode 40 by the opening 40a of the main electrode. Electrons are emitted. Thereby, plasma is emitted with higher efficiency than the area of the annular region 40b of the conventional main electrode. Further, the tip 12b of the gas induction tube 12 is not damaged, and the auxiliary electrode flat plate 30 is also separated from the main electrode 40. Therefore, the damage is small, and the flow path of the argon gas and the change in the discharge area are small and stable. Plasma can be supplied.

次に、本発明の他の実施の形態について、図面を参照して説明する。図3に示すように本発明の他の実施の形態は、補助電極平板を一体とし、さらに中心部に突起を設けたものであり、補助電極平板及び環状部材とが異なり他の構成は同一である。従来例、前述した実施の形態と同様な構成については、同符号を付し、説明の一部又全部を省略する。図3に示すように、本発明の他の実施の形態の圧力勾配型プラズマガン2には、補助電極平板31の中央、主電極40の開口40aと同軸上に開口に向かって円錐状の突起部32が設けられている。突起部の高さは好ましくは補助電極平板と主電極の間隙(図2(b)符号d)より短い。これにより、主電極40の高温でのプラズマ放電の突起部32への影響を少なくする。   Next, another embodiment of the present invention will be described with reference to the drawings. As shown in FIG. 3, in another embodiment of the present invention, an auxiliary electrode flat plate is integrated, and a protrusion is provided at the center, and the other configurations are the same except for the auxiliary electrode flat plate and the annular member. is there. Configurations similar to those of the conventional example and the above-described embodiment are denoted by the same reference numerals, and a part or all of the description is omitted. As shown in FIG. 3, the pressure gradient type plasma gun 2 according to another embodiment of the present invention has a conical protrusion toward the opening coaxially with the opening 40a of the main electrode 40 at the center of the auxiliary electrode flat plate 31. A part 32 is provided. The height of the protrusion is preferably shorter than the gap between the auxiliary electrode flat plate and the main electrode (reference symbol d in FIG. 2B). Thereby, the influence of the plasma discharge at the high temperature of the main electrode 40 on the protrusion 32 is reduced.

補助電極平板31の外縁部31aはカソード保護管20の内周面20dの内径とほぼ同径の外径を有しており、外縁部がカソード保護管の内周面に固定されている。外縁部31a間の4箇所が主電極側に折り曲げられ延出部31bを形成している。また、折り曲げ(延出部)31bとカソード保護管の内周面20dとでガス導入口35を形成している。折り曲げ(延出部)端31cを主電極後面40cに当接させ、前述した環状部材24の代わりとし、主電極40と補助電極平板30との距離(図2(b)符号d)を保持するように軸方向に位置決め固定される。   The outer edge portion 31a of the auxiliary electrode flat plate 31 has an outer diameter substantially the same as the inner diameter of the inner peripheral surface 20d of the cathode protective tube 20, and the outer edge portion is fixed to the inner peripheral surface of the cathode protective tube. Four portions between the outer edge portions 31a are bent to the main electrode side to form extended portions 31b. Further, a gas introduction port 35 is formed by the bent (extending portion) 31b and the inner peripheral surface 20d of the cathode protective tube. The bent (extending portion) end 31c is brought into contact with the main electrode rear surface 40c, and the distance between the main electrode 40 and the auxiliary electrode flat plate 30 (symbol d in FIG. 2B) is maintained instead of the annular member 24 described above. Thus, the positioning is fixed in the axial direction.

なお、補助電極平板31は、円形の外縁部に8箇所の切り込みを入れ、一つおきに4箇所の部分を主電極側に折り曲げたり、または一体で成型、鋳造等してもよい。また、主電極40の固定および主電極周囲からのガス導入と中空放電を防止するために、主電極押さえリング25を配置している。主電極押さえリング25を設置しない場合は、アルゴンガスの漏れによる放電のため主電極外周の損耗が発生する。主電極外周の損耗は圧力勾配を大きく変化させるため、放電条件の変わらない安定した長寿命放電を得るためには好ましくない。   In addition, the auxiliary electrode flat plate 31 may be formed by making eight cuts in a circular outer edge portion and bending four portions every other portion to the main electrode side, or integrally molding, casting, or the like. In addition, a main electrode pressing ring 25 is disposed in order to fix the main electrode 40 and prevent gas introduction and hollow discharge from the periphery of the main electrode. When the main electrode holding ring 25 is not installed, the outer periphery of the main electrode is worn due to discharge due to leakage of argon gas. The wear on the outer periphery of the main electrode greatly changes the pressure gradient, which is not preferable for obtaining a stable long-life discharge that does not change the discharge conditions.

かかる他の実施の形態では、図2と同様に放電が行われるが、さらに、補助電極平板30の中央の突起部32の突起による付加による補助放電推移時間が短縮、または補助電極の実効的な表面積増加によって、補助放電の際に主電極を効率良く加熱することができる。これにより、主電極40を加熱する際の消費電力を抑制することが可能になると共に、プラズマの放出開始までの待機時間を短縮することが可能になる。   In such another embodiment, the discharge is performed in the same manner as in FIG. 2, but further, the auxiliary discharge transition time is shortened by the addition of the protrusion of the central protrusion 32 of the auxiliary electrode flat plate 30, or the effective of the auxiliary electrode is reduced. By increasing the surface area, the main electrode can be efficiently heated during auxiliary discharge. Thereby, it becomes possible to suppress the power consumption when heating the main electrode 40, and to shorten the waiting time until the plasma emission starts.

1、2 圧力勾配型プラズマガン。
10 基体
10a 基体のガス源連通穴
12 ガス誘導管
12a 貫通穴
20 カソード保護管
20a 他端部
20b 一端
20d カソード保護管内周面
21 開口部
30、31 補助電極平板
30a、31a 外縁部
30b 切り欠き部(切り欠かれた部分)
31b 折り曲げ延出部
31c 折り曲げ延出部端
32 突起部
35 ガス導入口
40 主電極
40a (主電極の)開口
1, 2 Pressure gradient type plasma gun.
DESCRIPTION OF SYMBOLS 10 Base | substrate 10a Gas source communication hole 12 of base | substrate Gas induction pipe | tube 12a Through hole 20 Cathode protection pipe 20a Other end part 20b One end 20d Cathode protection pipe inner peripheral surface 21 Opening part 30, 31 Auxiliary electrode flat plate 30a, 31a Outer edge part 30b Notch part (Notched part)
31b Folding extension part 31c Bending extension part end 32 Projection part 35 Gas introduction port 40 Main electrode 40a (main electrode) opening

Claims (8)

カソードに接続される基体と、前記基体に一端が気密接続され他端部に開口部を有する筒状のカソード保護管と、を有し、前記カソード保護管内に、前記基体側より、前記基体のガス源連通穴に連通する貫通穴を有するガス誘導管と、前記ガス誘導管と離隔して前記カソード保護管の軸心を直角方向面で遮断する補助電極平板と、前記補助電極平板の前記開口部側に設けられ、前記開口部と同芯の開口を有する主電極と、が順次配設され、前記補助電極平板の外縁部には、該外縁部を貫通又は切り欠くガス導入口が設けられ、前記補助電極平板と前記主電極との距離が前記補助電極平板と前記主電極との間でグロー放電可能な距離にされていることを特徴とする圧力勾配型プラズマガン。   A base connected to the cathode, and a cylindrical cathode protective tube having one end hermetically connected to the base and having an opening at the other end, and in the cathode protective tube from the substrate side, A gas induction tube having a through hole communicating with the gas source communication hole; an auxiliary electrode flat plate that is spaced apart from the gas induction tube and blocks the axis of the cathode protective tube at a right angle plane; and the opening of the auxiliary electrode flat plate A main electrode having an opening concentric with the opening, and a gas introduction port penetrating or notching the outer edge is provided at the outer edge of the auxiliary electrode flat plate. The pressure gradient plasma gun is characterized in that the distance between the auxiliary electrode flat plate and the main electrode is a distance capable of glow discharge between the auxiliary electrode flat plate and the main electrode. 前記補助電極平板と前記主電極との距離は、前記主電極の開口径の2倍以下0.3倍以上となるようにされていることを特徴とする請求項1記載の圧力勾配型プラズマガン。   2. The pressure gradient plasma gun according to claim 1, wherein a distance between the auxiliary electrode flat plate and the main electrode is set to be not more than twice the opening diameter of the main electrode and not less than 0.3 times. . 前記補助電極平板の材料の耐熱温度が前記主電極の材料の耐熱温度より低い材料であることを特徴とする請求項1又は2記載の圧力勾配型プラズマガン。   The pressure gradient type plasma gun according to claim 1 or 2, wherein the heat resistant temperature of the auxiliary electrode flat plate material is lower than the heat resistant temperature of the material of the main electrode. 前記ガス誘導管がセラミックスであることを特徴とする請求項1又は2又は3記載の圧力勾配型プラズマガン。   4. The pressure gradient type plasma gun according to claim 1, wherein the gas induction tube is made of ceramics. 前記補助電極板の中央に主電極板に向かって突起部が設けられていることを特徴とする請求項1又は2又は3又は4記載の圧力勾配型プラズマガン。   5. The pressure gradient plasma gun according to claim 1, wherein a projection is provided in the center of the auxiliary electrode plate toward the main electrode plate. 前記突起形状は前記軸心を軸とする円錐形状であることを特徴とする請求項5記載の圧力勾配型プラズマガン。   6. The pressure gradient plasma gun according to claim 5, wherein the protruding shape is a conical shape with the axis as an axis. 前記補助電極平板は円盤の一部が複数か所切欠かれた形状であって、前記円盤の外縁部が前記カソード保護管内周面に固定され、前記切欠かれた部分と前記カソード保護管内周面とで、前記ガス導入口が形成されていることを特徴とする請求項5又は6記載の圧力勾配型プラズマガン。   The auxiliary electrode flat plate has a shape in which a part of a disk is cut out at a plurality of positions, and an outer edge portion of the disk is fixed to the inner peripheral surface of the cathode protective tube, and the notched portion and the inner peripheral surface of the cathode protective tube 7. The pressure gradient plasma gun according to claim 5, wherein the gas inlet is formed. 前記補助電極平板と前記ガス導入口は一体成型され、前記補助電極平板の外縁部の周方向の複数か所が前記主電極側に折り曲げ延出され、前記補助電極平板の延出部端が前記主電極に当接かつ軸方向に位置決め固定され、前記延出部と前記カソード保護管内周面とで、前記ガス導入口が形成されていることを特徴とする請求項5又は6記載の圧力勾配型プラズマガン。   The auxiliary electrode flat plate and the gas introduction port are integrally formed, a plurality of circumferential positions of the outer edge portion of the auxiliary electrode flat plate are bent and extended toward the main electrode side, and the extension portion end of the auxiliary electrode flat plate is The pressure gradient according to claim 5 or 6, wherein the gas introduction port is formed by the extension part and the inner peripheral surface of the cathode protective tube, being in contact with the main electrode and positioned and fixed in the axial direction. Type plasma gun.
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