JP6161408B2 - Contaminated soil mixing method - Google Patents
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本発明は、汚染土に少なくとも汚染土中の微生物を活性化させるための栄養分を加えて混ぜ合わせる汚染土混合方法に関する。 The present invention relates to a contaminated soil mixing method in which a nutrient for activating at least microorganisms in the contaminated soil is added to and mixed with the contaminated soil.
汚染土中の微生物を活性化させて汚染土を浄化する汚染土浄化方法としては、主として、
(1)汚染された土壌に元々生息している土着の微生物に対して当該微生物を活性化させるための栄養分等を加えて汚染土中の微生物を活性化させることで汚染土を浄化するバイオスティミュレーション。
(2)汚染された土壌に予め効果が認められた微生物及び栄養分等を加えて汚染土中の微生物を活性化させることで汚染土を浄化するバイオオーグメンテーション。
が知られている。
そして、汚染土浄化方法の具体的な手法として、汚染土に栄養分等を加えてこれらを混練りして混ぜ合わせた汚染土を盛土状に盛り立てたバイオパイルを形成し、当該バイオパイルを静置して、バイオパイル中の微生物を活性化させて汚染土中の汚染物質の分解を促進させるバイオパイル工法が知られている(例えば特許文献1等参照)。
また、汚染土に栄養分等を加えてこれらを攪拌、切り替えし等により混ぜ合わせて、当該汚染土中の微生物を活性化させて汚染土中の汚染物質の分解を促進させるランドファーミング工法も知られている。
As a contaminated soil purification method that activates microorganisms in the contaminated soil and purifies the contaminated soil,
(1) Biosti that purifies the contaminated soil by activating the microorganisms in the contaminated soil by adding nutrients to activate the microorganism to the indigenous microorganisms originally inhabiting the contaminated soil Simulation.
(2) Bioaugmentation that purifies contaminated soil by activating microorganisms in contaminated soil by adding microorganisms, nutrients, and the like that have been recognized in advance to the contaminated soil.
It has been known.
Then, as a specific method of the contaminated soil purification method, a nutrient is added to the contaminated soil, and these are kneaded and mixed to form a biopile in which the contaminated soil is raised in an embankment form. In addition, there is known a biopile construction method that activates microorganisms in the biopile to promote the decomposition of the pollutants in the contaminated soil (see, for example, Patent Document 1).
There is also a land farming method that adds nutrients to contaminated soil and mixes them by agitation, switching, etc., and activates microorganisms in the contaminated soil to promote the decomposition of contaminants in the contaminated soil. ing.
汚染土中の微生物を活性化させるためには、汚染土の透水性や通気性が重要になる。特に、微生物が好気性の菌である場合には、汚染土の通気性がきわめて重要になる。
しかしながら、例えば関東ローム層や沖縄の赤土などのシルト質や粘性土を多く含む汚染土壌の場合、土質的にも通気性及び透水性が悪く、当該汚染土に水及び栄養分等を加えてこれらを混ぜ合わせると汚染土による拳大程度の大きさの塊が発生して、栄養分や酸素が塊内に侵入できなくなって汚染土中の微生物を活性化させることが困難となり、汚染土中の汚染物質の分解が促進されないという問題点があった。
本発明は、汚染土に少なくとも栄養分を加えて混ぜた場合に、汚染土の団塊化を防止でき、汚染土の通気性及び透水性を良好にできて、汚染土中の微生物を活性化させることができる汚染土混合方法を提供する。
In order to activate microorganisms in the contaminated soil, the water permeability and air permeability of the contaminated soil are important. In particular, when the microorganism is an aerobic bacterium, the air permeability of the contaminated soil is extremely important.
However, in the case of contaminated soil that contains a lot of silty or viscous soil such as the Kanto Loam Formation and Okinawa's red soil, the soil is also poorly breathable and water permeable, and water and nutrients are added to the contaminated soil. When mixed, a fist-sized lump of contaminated soil is generated, making it difficult for nutrients and oxygen to enter the lump and activating microorganisms in the contaminated soil. There was a problem that the decomposition of was not promoted.
The present invention can prevent agglomeration of contaminated soil, improve air permeability and water permeability of the contaminated soil, and activate microorganisms in the contaminated soil when at least nutrients are added to and mixed with the contaminated soil. Provide a contaminated soil mixing method.
本発明に係る汚染土混合方法は、汚染土に汚染土中の微生物を活性化させるための栄養分と汚染土の団塊化を防止するための団塊化防止物質とを加えて混ぜ合わせる汚染土混合方法であって、容器内に前記団塊化防止物質を投入した後、団塊化防止物質が投入された容器内のかき混ぜ手段を作動させながら汚染土と栄養分とを容器内に投入して混ぜ合わせたので、汚染土の団塊化を防止できて汚染土の通気性及び透水性を良好にでき、汚染土中の微生物を活性化させることができる。
また、団塊化防止物質として籾殻を用いたので、汚染土の団塊化を防止できて汚染土の通気性及び透水性を良好にでき、汚染土中の微生物を活性化させることができる汚染土混合方法を安価に実現できる。
Contaminated soil mixing method according to the present invention, it Nodules prevention materials and the addition by Ru polluted soil mixing mixing for preventing Nodules of the nutrients for activating the contaminating soil microbial polluted soil polluted soil In this method, after the agglomeration preventing substance is introduced into the container, the contaminated soil and nutrients are introduced into the container and mixed while operating the agitation means in the container into which the agglomeration preventing substance is introduced . Therefore, the agglomeration of the contaminated soil can be prevented, the air permeability and water permeability of the contaminated soil can be improved, and the microorganisms in the contaminated soil can be activated.
Also, because rice husk is used as an agglomeration-preventing substance, the contaminated soil can be prevented from agglomeration, the air permeability and water permeability of the contaminated soil can be improved, and the microorganisms in the contaminated soil can be activated. The method can be realized at low cost .
実施形態1
汚染土に汚染土中の微生物を活性化させるための栄養分と汚染土の団塊化を防止するための団塊化防止物質とを加えて混ぜ合わせる実施形態1の汚染土混合方法は、図1に示すように、籾殻投入ステップS1と、混練りステップS2とを備える。
Embodiment 1
The contaminated soil mixing method according to the first embodiment is shown in FIG. 1 in which the nutrient for activating microorganisms in the contaminated soil and the agglomeration preventing substance for preventing the agglomeration of the contaminated soil are added to and mixed with the contaminated soil. Thus, the rice husk throwing step S1 and the kneading step S2 are provided.
籾殻投入ステップS1では、混練り装置における混練り作業が行われる容器としての混練り作業容器内に団塊化防止物質の一例としての籾殻(もみがら)を投入する。
混練り作業容器内には、かき混ぜ手段としての複数の混練り棒が設けられる。
混練り棒は、例えば、棒の周面に攪拌羽根を有し、棒の中心線を回転中心として回転できるように、棒の両端が混練り作業容器の互いに対向する側壁に回転可能に支持された構成である。即ち、回転駆動源としてのモーター等の回転出力により回転するように構成された複数の混練り棒が混練り作業容器内で回転した場合、混練り作業容器内に収容されている混練り対象物が攪拌羽根により攪拌されて混練りされるように構成されている。
籾殻投入ステップS1では、混練り作業によって作成される混合汚染土を基準として重量比10%以下程度(例えば1%〜2%)の量の籾殻を混練り作業容器内に入れる。
In the rice husk charging step S1, rice husk (rice chaff) as an example of an agglomeration preventing substance is charged into a kneading work container as a container in which the kneading work is performed in the kneading apparatus.
A plurality of kneading rods as stirring means are provided in the kneading work container.
The kneading rod has, for example, a stirring blade on the circumferential surface of the rod, and both ends of the rod are rotatably supported on opposite side walls of the kneading work container so as to be able to rotate around the center line of the rod. It is a configuration. That is, when a plurality of kneading rods configured to rotate by rotation output of a motor or the like as a rotation drive source rotate in the kneading work container, the kneading object accommodated in the kneading work container Is agitated by a stirring blade and kneaded.
In the rice husk charging step S1, the rice husk in an amount of about 10% or less (for example, 1% to 2%) by weight based on the mixed contaminated soil created by the kneading operation is placed in the kneading work container.
混練りステップS2では、籾殻が投入された混練り作業容器内の複数の攪拌羽根付きの混練り棒を回転させながら(即ち、空練りさせながら)、汚染土、水分、分解菌等の微生物、当該微生物を活性化させるための栄養分等を混練り作業容器内に投入して混練りする。混練り時間は、数分程度(例えば、約2分〜3分程度)でよい。
尚、微生物としては、例えば燃料系油分(ジェット燃料、ガソリン、軽油、重油等)や機械油(潤滑油等)で汚染された汚染土中の油分のほか、溶剤など(たとえば、トリクロロエチレン、テトラクロロエチレン等)で汚染された汚染土中の揮発性有機化合物を分解する分解菌(例えば石油分解菌、VOC分解菌等)を用いればよい。また、栄養分としては、栄養塩や堆肥等を用いればよい。
In the kneading step S2, while rotating a kneading rod with a plurality of stirring blades in the kneading work container into which the rice husks are charged (that is, while kneading), microorganisms such as contaminated soil, moisture, and decomposing bacteria, Nutrients or the like for activating the microorganisms are kneaded and put into a working container and kneaded. The kneading time may be about several minutes (for example, about 2 to 3 minutes).
Examples of microorganisms include oils in contaminated soil contaminated with fuel oils (jet fuel, gasoline, light oil, heavy oil, etc.) and machine oils (lubricant oil, etc.), and solvents (eg, trichloroethylene, tetrachloroethylene, etc.) Decomposing bacteria (for example, petroleum degrading bacteria, VOC degrading bacteria, etc.) that decompose volatile organic compounds in the contaminated soil contaminated with) may be used. Moreover, nutrient salts, compost, etc. may be used as nutrients.
実施形態1では、混練り作業の前に混練り作業容器内に籾殻を投入してから混練り作業を行ったことにより、混練り作業の過程で汚染土が塊となる前に汚染土の土粒子が籾殻に吸着されることで汚染土の団塊化が防止される。換言すれば、混練り作業の過程で汚染土が塊となる前に籾殻が汚染土の土粒子同士の結合を防止して汚染土の団塊化が防止される。 In the first embodiment, before the kneading work, the rice husks are put into the kneading work container and then the kneading work is performed. Aggregation of contaminated soil is prevented by adsorbing particles to rice husk. In other words, before the contaminated soil is agglomerated in the process of kneading, the rice husk prevents the soil particles of the contaminated soil from being bonded to each other, thereby preventing agglomeration of the contaminated soil.
実施形態1では、汚染土と水分と微生物と栄養分等とを混練する際の副資材として、汚染土の団塊化を防止して汚染土に通気性及び透水性を保有させる籾殻を使用したので、汚染土の粒径を数mm程度にでき、汚染土の通気性及び透水性が良くなって、汚染土中の微生物を活性化させることができ、汚染土中の汚染物質の分解を促進できる混合汚染土を作成することができるようになる。
また、混練り作業によって作成される混合汚染土を基準として重量比10%以下程度の量の籾殻を混練り作業容器内に入れるようにしたので、籾殻の量を少なくできて、籾殻が嵩張らず、混練り作業を容易に行える。
また、安価な籾殻を用いるので、通気性及び透水性の良好な混合汚染土を安価に作成できるようになる。
In Embodiment 1, as an auxiliary material when kneading contaminated soil, moisture, microorganisms, nutrients, etc., rice husks that prevent the agglomeration of the contaminated soil and retain the breathability and water permeability of the contaminated soil are used. Mixing that can reduce the particle size of contaminated soil to several millimeters, improve the air permeability and water permeability of the contaminated soil, activate microorganisms in the contaminated soil, and promote the decomposition of contaminants in the contaminated soil It will be possible to create contaminated soil.
In addition, since the rice husk in an amount of about 10% by weight or less based on the mixed contaminated soil created by the kneading operation is put into the kneading work container, the amount of rice husk can be reduced and the rice husk is not bulky. The kneading operation can be easily performed.
In addition, since cheap rice husks are used, mixed contaminated soil having good air permeability and water permeability can be produced at low cost.
実施形態2
汚染土を混練り作業容器内に入れて混練りする前に、汚染土を乾燥させる。
そして、籾殻が投入されて空練り動作が行われている混練り作業容器内に、乾燥させた汚染土、水分、微生物、栄養分等を投入して混練りすることにより混合汚染土を作成する。
汚染土の水分含有度が高い場合には、混練りによって汚染土が団塊化しやすくなるので、本実施形態2のように、汚染土を乾燥させた後に、混練りすることで、汚染土の団塊化防止効果が高くなり、汚染土の通気性及び透水性が良くなって、汚染土中の微生物を活性化させることができ、汚染土中の汚染物質の分解を促進できる混合汚染土を作成することができるようになる。
Embodiment 2
The contaminated soil is dried before being kneaded and put into a working container and kneaded.
Then, mixed contaminated soil is prepared by adding dried kneaded soil, moisture, microorganisms, nutrients, and the like into a kneading work container in which rice husk is added and empty kneading operation is performed.
When the contaminated soil has a high water content, the contaminated soil is likely to agglomerate by kneading. Thus, after the contaminated soil is dried and kneaded as in the second embodiment, the contaminated soil agglomerates. Create mixed contaminated soil that can increase the prevention of contamination, improve the air permeability and water permeability of the contaminated soil, activate microorganisms in the contaminated soil, and promote the decomposition of contaminants in the contaminated soil Will be able to.
尚、本願では、汚染土、水分、微生物、栄養分等を混練りして汚染土が団塊化してしまった後に籾殻を投入しても効果はない。従って、団塊化防止物質としての籾殻を投入するタイミングは、汚染土が団塊化する前であればよい。例えば、汚染土、水分、微生物、栄養分等と籾殻とを同時に混練り作業容器内に入れて混練り作業を行うようにしてもよい。
ただ、同時に汚染土と籾殻を投入すると、その時点で塊が発生する恐れもあるので、籾殻は可能な限り事前に投入して空練を行いながら汚染土や水分、微生物、栄養分等を投入するほうがよい。
In addition, in this application, even if contaminated soil, a water | moisture content, microorganisms, a nutrient, etc. are knead | mixed and polluted soil is agglomerated, it does not have an effect. Therefore, the timing of adding rice husks as an agglomeration-preventing substance may be before the contaminated soil is agglomerated. For example, contaminated soil, moisture, microorganisms, nutrients, and the like and rice husk may be kneaded at the same time and placed in a working container to perform the kneading operation.
However, if contaminated soil and rice husks are added at the same time, lumps may be generated at that time, so add rice husks in advance as much as possible and pour contaminated soil, moisture, microorganisms, nutrients, etc. Better.
また、団塊化防止物質として、籾殻以外の物質を用いてもよい。例えば、藁、おが屑、サトウキビの搾りかす(バガス)等の植物性材料を用いてもよい。 A substance other than rice husk may be used as the agglomeration preventing substance. For example, plant materials such as straw, sawdust, and sugarcane pomace (bagasse) may be used.
尚、本発明の汚染土混合方法は、汚染土に少なくとも栄養分と汚染土の団塊化を防止するための団塊化防止物質とを加えて混ぜ合わせる方法であればよい。
即ち、本発明の汚染土浄化方法は、汚染土の通気性及び透水性を良好にするために、汚染土に、少なくとも栄養分、団塊化防止物質を加えてこれらを混練りしたり、攪拌、切り替え等して混ぜ合わせる方法であればよい。つまり、バイオスティミュレーションにおいて、汚染された土壌に元々生息している土着の微生物に対して当該微生物を活性化させるための栄養分等を加えて混合する際、あるいは、バイオオーグメンテーションにおいて、汚染された土壌に予め効果が認められた微生物及び栄養分等を加えて混合する際に、本発明のように、団塊化防止物質を加えて混合することにより、汚染土の団塊化を防止できて汚染土の通気性及び透水性を良好にでき、汚染土中の微生物を活性化させることができるので、汚染土中の汚染物質の分解を促進させることができるようになる。
また、混ぜ合わせる手段としては、専用のかき混ぜ機械、バックホーやスタビライザー等の機械、人力等を使用すればよい。
In addition, the contaminated soil mixing method of this invention should just be the method of adding and mixing at least a nutrient and the agglomeration prevention substance for preventing agglomeration of contaminated soil to contaminated soil.
That is, in the contaminated soil purification method of the present invention, in order to improve the air permeability and water permeability of the contaminated soil, at least nutrients and agglomeration preventing substances are added to the contaminated soil, and these are kneaded, stirred, and switched. Any method can be used as long as they are mixed together. In other words, in biostimulation, indigenous microorganisms that originally inhabit contaminated soil are mixed with nutrients to activate the microorganisms, or in bioaugmentation. When adding and mixing microorganisms, nutrients, etc. that have been confirmed to be effective in advance to the soil, mixing with an agglomeration-preventing substance as in the present invention can prevent agglomeration of the contaminated soil and contaminate it. Since the air permeability and water permeability of the soil can be improved and microorganisms in the contaminated soil can be activated, the decomposition of the contaminants in the contaminated soil can be promoted.
As a means for mixing, a dedicated stirring machine, a machine such as a backhoe or a stabilizer, human power, etc. may be used.
S1 籾殻投入ステップ、S2 混練りステップ。
S1 Rice husk charging step, S2 kneading step.
Claims (2)
容器内に前記団塊化防止物質を投入した後、団塊化防止物質が投入された容器内のかき混ぜ手段を作動させながら汚染土と栄養分とを容器内に投入して混ぜ合わせたことを特徴とする汚染土混合方法。 A nutrient with Nodules prevention materials and the addition Ru mixed polluted soil mixing method for preventing the baby boom of polluted soil in order to activate the contaminating soil microbial contaminated soil,
After the agglomeration preventing substance is introduced into the container, the contaminated soil and nutrients are introduced into the container and mixed while operating the agitation means in the container into which the agglomeration prevention substance is introduced. Contaminated soil mixing method.
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