JP6180294B2 - Liquid cosmetic composition for sheet and sheet cosmetic - Google Patents

Description

  The present invention relates to a liquid cosmetic composition for a sheet and a sheet-like cosmetic.

  Sebum plays a useful role in preventing excessive transpiration of moisture from the skin and maintaining the amount of skin moisture necessary for the skin moisturizing function. Giving it sticky and closing the pores can cause acne. In particular, the T zone on the face (portion from the forehead to the nasal muscles) has a large amount of sebum secretion, and skin troubles caused by excessive sebum are likely to occur. Development of technology to remove is desired.

As a means for removing sebum, sheet cosmetics have been studied. For example, in Patent Document 1, a sheet-like base material is impregnated with a liquid composition containing two types of nonionic surfactants and powder. Sheet-like cosmetics are described, and it is described that the persistence of powder is high and smoothness can be maintained. Patent Document 2 discloses a sheet-like substrate formed by impregnating a sheet-like base material containing cellulosic fibers with a liquid composition containing a quaternary cationic disinfectant, a nonionic surfactant, a cationic polymer, and ethanol. Cosmetics are described, and it is described that there is little roughness and stickiness and that the skin feel is good.
These sheet-like cosmetics are generally obtained by impregnating a sheet-like base material with a liquid composition, but nothing is described regarding the stability of the liquid composition as an intermediate of the sheet-like cosmetic.

JP 2013-116868 A JP 2012-197250 A

In response to the recent increase in beauty consciousness, particularly skin consciousness, a cosmetic composition having more excellent sebum removal properties has been demanded.
Furthermore, the storage stability of the liquid cosmetic composition as an intermediate agent is required from the viewpoint of productivity.

  The inventors of the present invention provide a liquid cosmetic composition containing a specific polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyethylene glycol and water, having excellent storage stability and impregnating the liquid cosmetic composition. It has been found that the sheet-like cosmetic composition has good usability and excellent sebum removability.

The present invention includes the following components (A) to (D):
(A) HLB 10-13, polyoxyethylene alkyl ether having an alkyl group having 10 to 18 carbon atoms or polyoxyethylene alkenyl ether having an alkenyl group having 10 to 18 carbon atoms, 0.01 to 1% by mass,
(B) 0.01-1% by mass of polyoxyethylene hydrogenated castor oil,
(C) 0.1 to 5% by mass of polyethylene glycol which is liquid at 25 ° C.
(D) It is related with the liquid cosmetic composition for sheets containing water.
Moreover, this invention relates to the sheet-like cosmetics which make a sheet-like base material impregnate the liquid cosmetic composition containing the said component (A)-(D).
Moreover, this invention relates to the usage method of a sheet-like cosmetics which apply | coats the said sheet-like cosmetics to skin.

  The liquid cosmetic composition of the present invention is excellent in storage stability, and the sheet-like cosmetic formed by impregnating the liquid cosmetic composition has high sebum removability, good skin fit, and no stickiness. In addition, the feeling of use is good and the effect of suppressing shine is also excellent.

[Liquid cosmetic composition]
The polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether of the component (A) used in the present invention (hereinafter also referred to as polyoxyethylene alkyl ether in the present invention) has an alkyl group or alkenyl group having 10 to 18 carbon atoms. , HLB 10-13.
In the present invention, the HLB value is an index indicating a hydrophilic-lipophilic balance, and in the present invention, a value calculated by the following equation by Oda and Teramura et al. Is used.

The carbon number indicates the carbon number of the alkyl group or alkenyl group constituting the polyoxyethylene alkyl ether in the present invention, and preferably has 10 to 16 carbon atoms from the viewpoint of enhancing storage stability, sebum wiping property, and shine prevention effect. More preferably, the carbon number is 12-14.
From the same viewpoint, polyoxyethylene alkyl ether having an alkyl group is preferable.
Moreover, 11-13 are preferable and 12-13 are more preferable from a viewpoint which the HLB of the polyoxyethylene alkyl ether in this invention improves sebum wiping off and a shine prevention effect.
Specifically, polyoxyethylene lauryl ether (carbon number 12, HLB 10-13), polyoxyethylene myristyl ether (carbon number 14, HLB 10-13), polyoxyethylene cetyl ether (carbon number 16, HLB 10-13), Examples thereof include polyoxyethylene oleyl ether (carbon number 18, HLB10 to 13) and the like, and polyoxyethylene lauryl ether is preferable from the viewpoint of sebum wiping property and shine prevention effect.
In the present invention, the number of added moles of ethylene oxide of the polyoxyethylene alkyl ether is preferably from 3 to 9, more preferably from 4 to 8, and even more preferably from 5 to 7, from the viewpoints of sebum wiping properties and shine suppression effect.

  Component (A) can be used alone or in combination of two or more thereof, and the content thereof is 0.01% by mass or more in the liquid cosmetic composition from the viewpoint of enhancing storage stability and feeling of use. Yes, 0.013 mass% or more is preferable, 0.015 mass% or more is more preferable, 0.017 mass% or more is more preferable, 1 mass% or less is preferable, 0.7 mass% or less is preferable, 0.5 The mass% or less is more preferable, and 0.3 mass% or less is still more preferable. Moreover, content of a component (A) is 0.01-1 mass% in a liquid cosmetic composition, 0.013-0.7 mass% is preferable, 0.015-0.5 mass% is More preferred is 0.017 to 0.3% by mass.

The polyoxyethylene hydrogenated castor oil as the component (B) can enhance the storage stability and enhance the shine prevention effect by the interaction with the components (A) and (C).
The component (B) polyoxyethylene hydrogenated castor oil contains polyoxyethylene hydrogenated castor oil and derivatives thereof, such as polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene Examples include hardened castor oil triisostearate, polyoxyethylene hardened castor oil maleic acid, and the like. Among these, polyoxyethylene hydrogenated castor oil and polyoxyethylene hydrogenated castor oil monoisostearate are preferable, and polyoxyethylene hydrogenated castor oil is more preferable from the viewpoint of enhancing storage stability and enhancing the effect of suppressing shine.

In addition, the number of moles of ethylene oxide added to the polyoxyethylene hydrogenated castor oil is preferably 25 to 80, more preferably 30 to 75, still more preferably 35 to 70, from the viewpoint of enhancing the storage stability and the anti-shine effect. -68 is still more preferable, and 42-65 is still more preferable.
More specifically, polyoxyethylene (40) hydrogenated castor oil and polyoxyethylene (60) hydrogenated castor oil are preferable, and polyoxyethylene (60) hydrogenated castor oil is more preferable.
The HLB of the polyoxyethylene hydrogenated castor oil is preferably 10-16, more preferably 11-16, still more preferably 12-15, and more preferably 12.5-14. 5 is even more preferable.

  A component (B) can be used 1 type or in combination of 2 or more types, and the content is 0.01 mass% or more in a liquid cosmetic composition from a viewpoint of improving a usability | use_condition and a shine prevention effect. Yes, 0.02 mass% or more is preferable, 0.03 mass% or more is more preferable, 1 mass% or less is preferable, 0.8 mass% or less is preferable, and 0.7 mass% or less is more preferable. Moreover, content of a component (B) is 0.01-1 mass% in a liquid cosmetic composition, 0.02-0.8 mass% is preferable, and 0.03-0.7 mass% is More preferred.

  In the present invention, the mass ratio of the components (A) and (B) ((A) / (B)) is preferably 0.01 or more, from the viewpoint of enhancing the sebum wiping property and enhancing the shine prevention effect. Or more, more preferably 0.15 or more, still more preferably 0.18 or more, still more preferably 0.2 or more, preferably 1 or less, more preferably 0.95 or less, and even more preferably 0.9 or less. 0.8 or less is more preferable, and 0.6 or less is more preferable. Moreover, 0.01-1 are preferable, as for mass ratio ((A) / (B)) of component (A) and (B), 0.1-0.95 is more preferable, 0.15-0.9. Is more preferable, 0.18 to 0.8 is still more preferable, and 0.2 to 0.6 is still more preferable.

The component (C) polyethylene glycol is liquid at 25 ° C. Here, the liquid state at 25 ° C. means that the viscosity at 25 ° C. is 10,000 mPa · s or less. By using polyethylene glycol that is liquid at 25 ° C., it is possible to obtain a non-sticky feeling of use and a shine suppression effect due to the interaction with the components (A) and (B). The viscosity is measured by the method described in the examples below.
Polyethylene glycol of component (C) is liquid at 25 ° C., but from the viewpoint of obtaining a non-sticky feeling of use, from the viewpoint of enhancing sebum wiping properties, and from the viewpoint of enhancing the effect of suppressing shine, the viscosity is 30 ° C. The pressure is preferably 1 to 5000 mPa · s, more preferably 10 to 1000 mPa · s, still more preferably 40 to 500 mPa · s, and still more preferably 60 to 100 mPa · s.
From the same viewpoint, the number average molecular weight (Mn) is preferably 200 to 600, more preferably 200 to 500, and still more preferably 300 to 500. The number average molecular weight (Mn) is measured by the method described in Examples below.

  Component (C) can be used singly or in combination of two or more thereof, and the content thereof is 0.1% by mass or more in the liquid cosmetic composition from the viewpoint of the feeling of use and the anti-shine effect. 0.15 mass% or more is preferable, 0.2 mass% or more is more preferable, 5 mass% or less is preferable, 3 mass% or less is preferable, and 1 mass% or less is more preferable. Moreover, content of a component (C) is 0.1-5 mass% in a liquid cosmetic composition, 0.15-3 mass% is preferable, and 0.2-1 mass% is more preferable.

  The mass ratio [(A) + (B)] / (C) of the total content of the component (A) and the component (B) with respect to the component (C) increases the sebum wiping property and increases the shine prevention effect. From the viewpoint, 0.01 or more is preferable, 0.015 or more is more preferable, 0.02 or more is further preferable, 8 or less is preferable, 7 or less is more preferable, 4 or less is further preferable, and 3 or less is even more preferable. Further, the mass ratio [(A) + (B)] / (C) of the total content of the component (A) and the component (B) with respect to the component (C) is preferably 0.01 to 8, and 0 .015 to 7 is more preferable, 0.02 to 4 is still more preferable, and 0.02 to 3 is still more preferable.

  As the water of component (D), ion-exchanged water, distilled water, or the like can be used. Component (D) constitutes the remainder of the other components, and the content is preferably 50% by mass or more, and more preferably 60 to 95% by mass in the liquid cosmetic composition.

  The liquid cosmetic composition of the present invention preferably further contains (E) an alcohol having 1 to 5 carbon atoms, that is, a lower alcohol. The lower alcohol of component (E) helps dissolve components (A), (B) and (C), and dissolves or disperses components (A), (B) and (C) in the liquid cosmetic composition. Can be improved. Furthermore, by containing the component (E), the component (E) volatilizes when the sheet cosmetic of the present invention is applied to the skin, and the components (A), (B) and (C) Can be uniformly attached to the surface. As a result, stickiness can be suppressed and a refreshing feeling during use can be enhanced. From the same viewpoint, (E) the number of carbon atoms in the alcohol having 1 to 5 carbon atoms is preferably 2 to 4, and specifically ethanol is preferred.

  The content of the lower alcohol of the component (E) is the solubility of the component (A), the viewpoint of not giving a feeling of bulk and irritation due to the use of the sheet-like cosmetic of the present invention, storage stability, and further at high temperature. From the viewpoint of enhancing the storage stability, it is preferably 1% by mass or more, more preferably 10% by mass or more, still more preferably 13% by mass or more, still more preferably 15% by mass or more, and 40% by mass in the liquid cosmetic composition. Or less, more preferably 35% by mass or less, still more preferably 30% by mass or less, and even more preferably 28% by mass or less. Moreover, it is preferable that content of a component (E) is 1-40 mass% in a liquid cosmetic composition, 10-35 mass% is more preferable, 13-30 mass% is still more preferable, 15-28 A mass% is even more preferable.

In addition to the above components, the liquid cosmetic composition of the present invention includes components used in normal cosmetics, for example, surfactants other than those described above, oily components, powders, moisturizers, anti-inflammatory agents, and whitening agents. , UV care agents, bactericides, antiperspirants, cooling agents, antioxidants, perfumes and the like.
The liquid cosmetic composition of the present invention can be produced by a usual method. Specifically, for example, the components (A), (B), (C), (D), and other components can be obtained by adding them to the mixer independently or simultaneously and mixing them. it can.

[Sheet cosmetic]
The sheet-like cosmetic of the present invention can be obtained by impregnating the liquid cosmetic composition into a sheet-like base material.
The method for impregnating the sheet-like base material with the liquid cosmetic composition is not limited. For example, a method of spraying and impregnating a liquid cosmetic composition onto a sheet base material using a spray or an air gun, or a liquid cosmetic composition applied directly to a sheet base material using a slit type nozzle or the like There is a method to make it.
In the sheet-like cosmetic of the present invention, the impregnation ratio of the liquid cosmetic composition is 20 to 500 parts by mass with respect to 100 parts by mass of the sheet-like base material from the viewpoint of enhancing the feeling of use and improving the feel during application. Is preferable, and 50-400 mass parts is more preferable.

  As the sheet-like substrate used in the present invention, any of natural fibers or synthetic fibers and non-woven fabrics or woven fabrics obtained by blending them can be used. Specifically, for example, lyocell, cupra, rayon, acetate, acrylic, polyester, polyethylene, polypropylene, polyurethane, polyamide, cotton, and non-woven fabrics or woven fabrics of these blends, wet and dry pulp sheets, thermoplastic resins ( And pulp sheets reinforced with polyethylene, polypropylene, polyethylene terephthalate, etc.). In the ratio of pulp, cotton and thermoplastic resin, the mass ratio of pulp and cotton is preferably 50% by mass or more, more preferably 80% by mass or more, and further preferably 90% by mass or more.

These base materials are preferable because powders gather on the sheet surface as the fiber spacing is as close as possible. Moreover, pulp and cotton are more preferable as the base material because of ease of processing during production. Moreover, it is preferable if it is a pulp or cotton since it is excellent in the retainability of the liquid cosmetic composition. As for the pulp, it is preferable to use a thin pulp in order to achieve both softness and strength. Further, the pulp reinforced with the thermoplastic resin can give an appropriate thickness (bulkness) by embossing treatment, and the skin. It is preferable because it does not get wet too much. Furthermore, by sticking together a plurality of sheets by heat sealing, it is possible to provide a good usability with a soft and wiping thick sheet.
The basis weight of the sheet is preferably ²⁰ to 200 g / m ² from the viewpoint that the retainability of the liquid cosmetic composition and the feel during wiping are good. The thickness of the sheet is preferably 0.15 to 1.30 mm (measured with a dial gauge with a pressure of 20 gf / cm ² load) from the viewpoint that it has a wiping response and gives a good feeling during wiping.

  The sheet-like cosmetic of the present invention is used by being applied to the skin, and is preferably clean by removing sweat and sebum dirt by wiping the skin other than the scalp, more preferably the face, body other than the head, limbs, etc. In addition, it is possible to suppress shine and to clean the skin and keep the skin comfortable.

The sheet-like cosmetic of the present invention, for example, when used on the face, effectively removes sebum and, when blended with powder and moisturizer, not only keeps these skins comfortable, The shine prevention effect can be further improved. Moreover, when an antiperspirant and a bactericidal agent are blended, these active ingredients remain on the skin for a long time after cleansing the skin, so that a continuous antiperspirant and deodorant effect can be expected.
This invention discloses the following compositions further regarding embodiment mentioned above.

<1> The following components (A) to (D):
(A) HLB 10-13, polyoxyethylene alkyl ether having an alkyl group having 10 to 18 carbon atoms or polyoxyethylene alkenyl ether having an alkenyl group having 10 to 18 carbon atoms, 0.01 to 1% by mass,
(B) 0.01-1% by mass of polyoxyethylene hydrogenated castor oil,
(C) 0.1 to 5% by mass of polyoxyethylene glycol which is liquid at 25 ° C.
(D) A liquid cosmetic composition for sheets containing water.

<2> The liquid cosmetic composition according to <1>, wherein in the component (A), the alkyl group or the alkenyl group preferably has 10 to 16 carbon atoms, and more preferably 12 to 14 carbon atoms. .
<3> The liquid cosmetic composition according to <1> or <2>, wherein the component (A) is preferably HLB 11 to 13 and more preferably HLB 12 to 13.
<4> The liquid cosmetic composition according to any one of <1> to <3>, wherein the component (A) is preferably a polyoxyethylene alkyl ether having an alkyl group having 10 to 16 carbon atoms.
<5> The number of moles of ethylene oxide added as component (A) is preferably 3 to 9, preferably 4 to 8, and more preferably 5 to 7. Any one of the above <1> to <4> The liquid cosmetic composition as described.
The content of the <6> component (A) is preferably 0.013% by mass or more, more preferably 0.015% by mass or more, and still more preferably 0.003% by mass or more in the liquid cosmetic composition. 0% by mass or more, preferably 0.7% by mass or less, more preferably 0.5% by mass or less, and further preferably 0.3% by mass or less, according to any one of the above items <1> to <5>. Liquid cosmetic composition.

<7> Polyoxyethylene hydrogenated castor oil of component (B) is preferably polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene Any of the above <1> to <6>, which is an ethylene hydrogenated castor oil maleic acid, more preferably polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, and still more preferably polyoxyethylene hydrogenated castor oil. The liquid cosmetic composition according to claim 1.
<8> The number of moles of ethylene oxide added as component (B) is preferably 25 to 80, more preferably 30 to 75, still more preferably 35 to 70, still more preferably 40 to 68, 42 to 65. The liquid cosmetic composition according to any one of <1> to <7>, wherein 65 is further preferred.
<9> Component (B) is preferably HLB 10-15, more preferably HLB 11-16, still more preferably HLB 12-15, and still more preferably HLB 12.5-14.5 <1>-< The liquid cosmetic composition according to any one of 8>.
The content of the <10> component (B) is preferably 0.02% by mass or more, more preferably 0.03% by mass or more, and preferably 0.8% by mass or less in the liquid cosmetic composition. The liquid cosmetic composition according to any one of <1> to <9>, more preferably 0.7% by mass or less.

<11> The mass ratio ((A) / (B)) of the components (A) and (B) is preferably 0.01 or more, more preferably 0.1 or more, and further more preferably 0.15 or more. Preferably, 0.18 or more is more preferable, 0.2 or more is more preferable, 1 or less is preferable, 0.95 or less is more preferable, 0.9 or less is further preferable, 0.8 or less is more preferable, 0 The liquid cosmetic composition according to any one of the above items <1> to <10>, more preferably .6 or less.
<12> The viscosity of the component (C) polyethylene glycol is preferably 1 to 5000 mPa · s, more preferably 10 to 1000 mPa · s, still more preferably 40 to 500 mPa · s, at 30 ° C., and more preferably 60 to The liquid cosmetic composition according to any one of <1> to <11>, wherein 100 mPa · s is still more preferable.
<13> The number average molecular weight (Mw) of the polyethylene glycol of component (C) is preferably 200 to 600, more preferably 200 to 500, and even more preferably 300 to 500. <1> to <12> The liquid cosmetic composition according to any one of the above.
The content of <14> component (C) is preferably 0.15% by mass or more in the liquid cosmetic composition, more preferably 0.2% by mass or more, and preferably 3% by mass or less. The liquid cosmetic composition according to any one of the above items <1> to <13>, which is more preferably at most mass%.

<15> The mass ratio [(A) + (B)] / (C) of the total content of the component (A) and the component (B) to the component (C) is preferably 0.01 or more. And more preferably 0.015 or more, more preferably 0.02 or more, preferably 8 or less, more preferably 7 or less, still more preferably 4 or less, and even more preferably 3 or less <1> to <14> The liquid cosmetic composition according to any one of the above.
The content of <16> component (D) is preferably 50% by mass or more in the liquid cosmetic composition, and more preferably 60 to 95% by mass, any one of <1> to <15> The liquid cosmetic composition as described.
<17> The liquid cosmetic composition according to any one of <1> to <16>, further comprising (E) an alcohol having 1 to 5 carbon atoms, more preferably ethanol.
<18> The content of the alcohol having 1 to 5 carbon atoms in the component (E) is preferably 1% by mass or more in the liquid cosmetic composition, more preferably 10% by mass or more, and 13% by mass. The above is more preferable, 15% by mass or more is further preferable, 40% by mass or less is preferable, 35% by mass or less is more preferable, 30% by mass or less is further preferable, and 28% by mass or less is more preferable. Liquid cosmetic composition.

<19> A sheet-like cosmetic prepared by impregnating a sheet-like base material with the liquid cosmetic composition according to any one of <1> to <18>.
<20> The sheet according to <19>, wherein the impregnation ratio of the liquid cosmetic composition is preferably 20 to 500 parts by mass and more preferably 50 to 400 parts by mass with respect to 100 parts by mass of the sheet-like base material. Cosmetics.
<21> A sheet-like makeup to be applied to the skin, preferably to the skin other than the scalp, more preferably to the body other than the face, head, or limbs. How to use the fee.
<22> Use of the liquid cosmetic composition according to any one of <1> to <18> to enhance sebum wiping property.
<23> Use of the liquid cosmetic composition according to any one of the above items <1> to <18> for enhancing skin shine prevention.
<24> Use of the liquid cosmetic composition according to any one of the above items <1> to <18> for enhancing the cleanliness of the sebum wipe skin.

(Measurement of number average molecular weight)
The number average molecular weight (Mn) of polyethylene glycol is measured as follows.
(Measurement equipment and conditions)
Tosoh's integrated GPC device,
Apparatus: HLC-8220GPC,
Detector: RI (differential refractometer),
Column: TSK-gel G5000HxL (7.8 × 300 mm) × 1,
G4000HxL (7.8 × 300 mm) × 1,
G3000HxL (7.8 × 300mm) × 1,
G2000HxL (7.8 × 300 mm) × 1,
Mobile phase: THF (tetrahydrofuran),
Flow rate: 1.0 mL / min,
Set temperature: 40 ° C
Injection volume: 100 μL (sample concentration: 0.4%),
Measures the number average molecular weight in terms of polystyrene (*).
* Polystyrene: Tosoh Corporation, TSK standard polystyrene

(Measurement of viscosity)
The viscosity of polyethylene glycol is measured as follows.
The viscosity is measured under the following conditions after being kept at 30 ° C. for 24 hours.
Measuring device: B type viscometer (manufactured by Toki Sangyo Co., Ltd., model: TVB-10),
Measurement temperature: 30 ° C.
Rotor: M2,
Rotational speed: 100 rpm,
Measurement time: 1 minute

Examples 1-13, Comparative Examples 1-6
Liquid cosmetic compositions and sheet-shaped cosmetics having the compositions shown in Tables 1 and 2 were produced, and usability, stability, shine prevention effect and sebum wiping property were evaluated. The results are shown in Table 1 and Table 2 together.

(Production method)
Components (A), (B), (C) and (D) are mixed. The component (E) was added there, and it stirred and made uniform, and the liquid cosmetic composition was obtained.

(Evaluation method)
(1) Feeling of use:
Five male panels were subjected to a sensory evaluation on the following criteria based on the following criteria: “Feeling of skin familiarity” and “No stickiness” immediately after applying 0.5 g of each liquid cosmetic composition to the entire face after washing. The results are shown as the average value of 5 people.
(5-level evaluation)
5 points: Very good.
4 points: Good.
3 points: Somewhat good.
2 points: Bad.
1 point: Very bad.

(2) Storage stability:
In a glass bottle (diameter 4 cm, height 10 cm, volume 100 mL), 80 mL of each liquid cosmetic composition is placed, sealed, and subjected to high temperature conditions (temperature 50 ° C., relative humidity 10%), low temperature conditions (temperature −10 ° C.). And a relative humidity of 15%). The state of each liquid cosmetic composition one month later was visually evaluated according to the following criteria.
5: Separation of oil droplets is not observed.
4: Separation of oil droplets of less than about 1 mm is observed at the bottom.
3: Separation of oil droplets of about 1 mm or more and less than 3 mm is observed at the bottom.
2: Separation of oil droplets of about 3 mm or more and less than 5 mm is observed at the bottom.
1: Separation of oil droplets of about 5 mm or more is observed at the bottom.

(3) shine reduction effect:
(3-1) Sebum diffusibility:
30 μL of each liquid cosmetic composition was applied to a slide glass (7.6 × 2.6 × 1 mm) with a polyethylene sheet and dried. Thereafter, 10 μL of model sebum containing 1% by mass of red pepper pigment (high orange LH) was dropped, and after 1 hour, the diffusibility of the model sebum was evaluated. The evaluation was carried out by the following five steps on the area of the diffused model sebum in the photograph taken 1 hour after dropping. Here, a large area indicates that the sebum diffusibility is high. The diffusion of sebum means that the unevenness of the skin surface (skin and skin groove) appears more prominently, and the reflection intensity is suppressed.
(5-level evaluation)
5 points: 1.6 cm ² or more.
4 points: 1.4 cm ² or more and less than 1.6 cm ² .
3 points: 1.2 cm ² or more and less than 1.4 cm ² .
2 points: 1.0 cm ² or more and less than 1.2 cm ² .
1 point: less than 1.0 cm ² .

(3-2) Visual evaluation:
1.2 g of each liquid cosmetic composition was applied to the male face after face washing, and the shine condition after 3 hours was visually evaluated by five professional panels according to the following criteria. The result was shown by the total score of 5 persons.
(Evaluation criteria)
2: I do not feel shine.
1: I feel a little shining.
0: I feel strong.

(4) Sebum wiping property (sheet cosmetic):
A liquid cosmetic composition having the following composition (4.4 g) was impregnated into a sheet of cotton linter (basis weight 38 g / m ² , mass 1.1 g) to obtain a sheet-like cosmetic (impregnation rate 400%).
Apply 0.2g of model sebum mixed with carbon black (0.2% by mass) to artificial leather and wipe it at a constant speed (2.4cm / g) with a constant load (500g) with each sheet of cosmetic. did. The brightness (L value) after wiping was measured with a color difference meter and indicated by the following criteria. It shows that it is excellent in sebum wiping off property, so that L value is large.
(5-level evaluation)
5 points: 81 or more.
4 points: 79 or more and less than 81.
3 points: 77 or more and less than 79.
2 points: 75 or more and less than 77.
1 point: less than 75.

Example 14
4 g of a liquid cosmetic composition having the following composition was impregnated by spraying onto a 100% cotton non-woven fabric (basis weight 50 g / m ² , mass 2 g) to obtain a sheet-like cosmetic (impregnation rate 200%). .
The obtained sheet-like cosmetic material had high sebum wiping properties, and the shine on the face after wiping was suppressed.

<Liquid cosmetic composition>
Polyoxyethylene (6) lauryl ether (HLB12.1) ^{* 1} 0.02 (mass%)
Polyoxyethylene (60) hydrogenated castor oil (HLB14) ^{* 2} 0.05
Polyethylene glycol (number average molecular weight (Mn) 400) ^{* 3} 0.50
Alkyl acrylate / alkyl methacrylate copolymer 0.20
Sodium carbonate 0.02
Methylparaben 0.20
Perfume 0.08
Ethanol 25.0
Purified water balance
Total 100.00
* 1) Emanon 108, Kao Corporation * 2) Emanon CH-60 (K), Kao Corporation * 3) PEG400, NOF Corporation

Example 15
A liquid cosmetic composition having the following composition (4.4 g) was impregnated into a sheet of cotton linter (basis weight 38 g / m ² , mass 1.1 g) to obtain a sheet-like cosmetic (impregnation rate 400%).
The obtained sheet-like cosmetic material had high sebum wiping properties, and the shine on the face after wiping was suppressed.

<Liquid cosmetic composition>
Polyoxyethylene (8) oleyl ether (HLB 10.0) ^{* 4} 0.02 (mass%)
Polyethylene glycol (number average molecular weight (Mn) 200) ^{* 5} 0.50
Polyoxyethylene (40) hydrogenated castor oil (HLB 12.5) ^{* 6} 0.05
Isononyl isononanoate 0.50
Isopropyl methylphenol 0.10
Alkyl acrylate / methacrylate methacrylate copolymer 0.15
Fragrance 0.05
Triethanolamine 0.15
Ethylparaben 0.10
Ethanol 16.0
Purified water balance
Total 100.00
* 4) Emulgen 409PV, Kao Corporation * 5) PEG200, NOF Corporation * 6) Emanon CH-40 (K), Kao Corporation

Claims (5)

The following components (A) to (D):
(A) HLB 10-13, polyoxyethylene alkyl ether having an alkyl group having 10 to 18 carbon atoms or polyoxyethylene alkenyl ether having an alkenyl group having 10 to 18 carbon atoms, 0.01 to 1% by mass,
(B) 0.01-1% by mass of polyoxyethylene hydrogenated castor oil,
(C) 0.1 to 5% by mass of polyoxyethylene glycol which is liquid at 25 ° C.
(D) A liquid cosmetic composition for sheets containing water.   The liquid cosmetic composition for a sheet according to claim 1, wherein the component (B) is HLB 10-16.   The liquid cosmetic composition for a sheet according to claim 1 or 2, wherein the mass ratio ((A) / (B)) of the components (A) and (B) is 0.01 to 1.   A sheet-like cosmetic comprising a sheet-like base material impregnated with the liquid cosmetic composition according to any one of claims 1 to 3.   The usage method of the sheet-like cosmetic which apply | coats the sheet-like cosmetic of Claim 4 to skin.