JP6211112B2 - Decomposition-processed food material and manufacturing method - Google Patents
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- Edible Seaweed (AREA)
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Description
本発明は、分解処理食品素材、及びその製造方法に関するものであり、特に、風味が改善された分解処理食品素材、及びその製造方法に関する。 The present invention relates to a decomposed food material and a method for producing the same, and more particularly to a decomposed food material with improved flavor and a method for producing the same.
従来、昆布や昆布加工品はアルギン酸由来のぬめりが強く、またアルギン酸は食物繊維からなる植物組織の周囲を取り囲み、食物繊維の分解に対する保護効果を有しており、分解が非常に困難であるという課題があった。 Traditionally, kelp and processed kombu products have strong sliminess derived from alginic acid, and alginic acid surrounds the plant tissue consisting of dietary fiber and has a protective effect against the degradation of dietary fiber, and it is very difficult to decompose There was a problem.
具体的には、昆布を物理的に破砕する場合、水分を含んだ状態では、アルギン酸のぬめりにより組織がすべりやすく、微細片にまで至らせることも著しく効率が悪かった。 Specifically, in the case of physically crushing kelp, in a state containing moisture, the tissue easily slips due to the slimming of alginic acid, and it was extremely inefficient to reach fine pieces.
乾燥させた状態においては、破砕は可能なものの、アルギン酸の存在によって、ざらつきを感じさせないほどの微粉状にまで微粉末化することも困難であった。さらに、粉末化してもアルギン酸の吸湿効果によってぬめりが生じたり、保存性が悪くなってしまったりするという課題もあった。 Although it can be crushed in the dried state, it has been difficult to pulverize it into a fine powder that does not feel rough due to the presence of alginic acid. Furthermore, even when powdered, there is a problem that slime occurs due to the hygroscopic effect of alginic acid, and the storage stability deteriorates.
従って、従来昆布やその加工品はだしを採るものであって、残渣の有効活用方法の開発はそれほど検討されてきていなかった。 Therefore, conventionally, kelp and its processed products have been used for soup stock, and development of an effective utilization method of the residue has not been so much studied.
これを活用する方法として、植物体を構成するセルロース等の食物繊維成分を分解する酵素を直接作用させる方法もあったが、アルギン酸の存在により、食物繊維成分を分解する効率は著しく低いものであった。 As a method of utilizing this, there is also a method in which an enzyme that decomposes dietary fiber components such as cellulose constituting the plant body is directly acted, but due to the presence of alginic acid, the efficiency of decomposing dietary fiber components is extremely low. It was.
また、アルギン酸リアーゼによって植物組織を取り巻くアルギン酸を分解、低分子化させる方法もあったが、アルギン酸の影響がなくなるまで分解させるためにはアルギン酸リアーゼが多量に必要であったり、処理時間が長くなったりして、非現実的であった。 There was also a method of decomposing and reducing the molecular weight of alginic acid surrounding plant tissues with alginic acid lyase, but a large amount of alginic acid lyase was required to degrade alginic acid until the influence of alginic acid disappeared, and the treatment time was prolonged. And it was unrealistic.
一般的にこれらアルギン酸に起因する課題に対して、水浸漬や煮沸処理によって、アルギン酸を溶媒に抽出、分離した後、植物体を分解する方法がなされてきた。 In general, with respect to the problems caused by these alginic acids, there has been a method of decomposing plants after extracting and separating alginic acid in a solvent by water immersion or boiling treatment.
しかしながら、この方法では、水浸漬や煮沸処理の過程でアルギン酸と同時にアミノ酸等の遊離の旨み成分や好ましい上品な昆布特有の香り成分も除かれてしまい、これを原料とした風味の良い昆布分解物を得ることはできなかった。 However, in this method, free savory components such as amino acids and preferable scent components unique to refined kelp are removed at the same time as alginic acid in the course of water immersion and boiling treatment, and a flavorful kelp degradation product using this as a raw material Could not get.
以上のように、昆布や昆布加工品自体には旨み成分、風味成分、栄養成分が多く含まれているものの、呈味性を損なうことなく、これら総てを含んだ風味食品素材として昆布や昆布加工品を丸ごと活用する課題は解決されていない。 As described above, although kelp and processed kombu products themselves contain a lot of umami, flavor and nutritional components, they can be used as a flavored food material containing all of these without compromising taste. The problem of utilizing the entire processed product has not been solved.
これらに関して、上記の課題に鑑みてなされた技術が従来いくつか提案されている(例えば、特許文献1〜2を参照)。 In these respects, several techniques that have been made in view of the above problems have been proposed in the past (see, for example, Patent Documents 1 and 2).
すなわち、味付けした昆布破片を押出処理することで、本来の昆布の味に加え、他の原料を加えることにより、食感及び風味に優れた、昆布を主体とするシート状あるいは素麺状に成型された昆布原料全体を活用した新規食品の製造方法に関する技術が知られている(特許文献1)。 That is, by extruding seasoned kelp fragments, in addition to the original taste of kelp, by adding other ingredients, it is molded into a sheet or raw noodle-like form that is excellent in texture and flavor and is mainly made of kelp. A technique relating to a method for producing a new food utilizing the whole kelp raw material is known (Patent Document 1).
また、海藻の粉末に加水し、押出すること、さらにはこれを食物繊維分解酵素で分解することによって、海藻全体の分解度を高め、フコイダンを効率よく抽出する技術が知られている(特許文献2)。 In addition, a technique is known in which water is extruded into seaweed powder, extruded, and further decomposed with dietary fiber-degrading enzymes to increase the degree of degradation of the whole seaweed and efficiently extract fucoidan (Patent Literature). 2).
しかしながら、上記特許文献1の技術においては、昆布全体を食品化する技術ではあるものの、昆布を味付けしたり、他の風味原料を加えたりなどの前処理を行うことが必要であり、昆布のみを処理した場合の風味については、何ら言及されておらず、昆布自体の風味食品素材化には必ずしも適しているとは想定できない。また、最終製品はシート状あるいは素麺状に成型されたものであって、天然の昆布組織を昆布自体に含まれるアルギン酸やラミナリン等の多糖類を結着剤として再構成したものであるとの記載があり、アルギン酸やその他食物繊維を含めた多糖類の分解度は低いものと推察される。したがって、昆布だけを処理した場合には、その分解率の低さにより、上述のざらつきや吸湿によるぬめりなどの風味食品素材としての適性は低いことが想定され、課題解決には至っていないと考えられる。 However, in the technique of the above-mentioned Patent Document 1, although it is a technique for making whole kelp into food, it is necessary to perform a pretreatment such as seasoning kelp or adding other flavor raw materials. There is no mention of the flavor in the case of treatment, and it cannot be assumed that it is necessarily suitable for making a kombu itself as a flavor food material. In addition, it is described that the final product is formed into a sheet or raw noodle shape, and a natural kelp tissue is reconstituted with a polysaccharide such as alginic acid or laminarin contained in the kelp itself as a binder. It is assumed that the degradation of polysaccharides including alginic acid and other dietary fibers is low. Therefore, when only kelp is processed, due to the low decomposition rate, it is assumed that the above-mentioned rough foods and slime due to moisture absorption are not suitable for flavored food materials, and the problem has not been solved. .
また、上記特許文献2の技術の場合、海藻のみを原料とし、押出機で混練し、かつその処理物をさらに食物繊維分解酵素により分解させていること、還元糖量の数値からも、海藻組織の分解率は高いと想定される。しかしながら、本技術はこの分解物からフコイダンを効率よく抽出させるものであって、海藻の風味などの呈味性の維持については何ら配慮されていないことから、風味食品素材としての適性には疑問が残り、課題解決には至っていないと考えられる。 Further, in the case of the technique of Patent Document 2, the seaweed tissue is obtained from the fact that only seaweed is used as a raw material, the mixture is kneaded by an extruder, and the processed product is further decomposed by dietary fiber-degrading enzymes. The decomposition rate of is assumed to be high. However, this technology efficiently extracts fucoidan from this decomposed product, and since there is no consideration for maintaining the taste such as the flavor of seaweed, there is doubt about its suitability as a flavored food material. It seems that the remaining issues have not been solved.
そこで、本発明は上記の課題に鑑みてなされたものであり、その目的は、呈味性を損なうことなく、昆布及び/又はその加工品を丸ごと活用した、旨み成分、風味成分、栄養成分総てを含んだ分解処理食品素材を提供することにある。 Therefore, the present invention has been made in view of the above-mentioned problems, and its purpose is to make use of the whole kelp and / or processed product thereof without sacrificing the taste, and the umami component, flavor component, and total nutrient component. It is to provide a decomposed food material containing the food.
また、本発明の別の目的は、風味が改善された分解処理食品素材及びその製造方法を提供することにある。 Another object of the present invention is to provide a decomposed food material with improved flavor and a method for producing the same.
上記目的を達成するために、本発明者は、押出成形機、及びその処理条件について鋭意検討を行った結果、本発明を見出すに至った。 In order to achieve the above object, the present inventor has intensively studied the extruder and its processing conditions, and as a result, has found the present invention.
すなわち、本発明の昆布及び/又は昆布加工品の分解処理食品素材は、昆布及び/又は昆布加工品の加熱押出機処理及び酵素処理分解物であって、前記加熱押出機処理及び酵素処理分解物は、遊離還元糖を8.4mg/g〜40mg/gの範囲で含有することを特徴とする。
That is, the decomposition processed food material of kelp and / or processed kelp according to the present invention is a heat- extruded process and an enzyme-processed decomposed product of kelp and / or processed kelp, wherein the heated- extruder processed and enzyme-processed decomposed product. Contains free reducing sugar in the range of 8.4 mg / g to 40 mg / g .
また、本発明の昆布及び/又は昆布加工品の分解処理食品素材の好ましい実施態様において、前記昆布及び/又は昆布加工品の加熱押出機処理及び酵素処理分解物は、遊離アルギン酸を9.8質量%〜40質量%の範囲で含有することを特徴とする。
Further, in a preferred embodiment of the kelp and / or processed kelp processed food material of the present invention, the heat- extruded and enzyme-treated decomposed product of the kelp and / or processed kelp is 9.8 masses of free alginic acid. It is characterized by containing in the range of % -40 mass%.
また、本発明の昆布及び/又は昆布加工品の分解処理食品素材の好ましい実施態様において、前記昆布及び/又は昆布加工品の押出機処理分解物は、粉末状であることを特徴とする。 In a preferred embodiment of the kelp and / or processed food product of kelp processed product according to the present invention, the extruder processed decomposed product of kelp and / or processed kelp product is in the form of powder.
また、本発明の昆布及び/又は昆布加工品の分解処理食品素材の好ましい実施態様において、前記粉末状の昆布及び/又は昆布加工品の押出機処理分解物は、平均粒径100μm以下であることを特徴とする。 Moreover, in a preferred embodiment of the food material for decomposing processed kelp and / or processed kelp according to the present invention, the powdered kelp and / or processed product of processed kelp processed by an extruder has an average particle size of 100 μm or less. It is characterized by.
また、本発明の飲食品は、本発明の分解処理食品素材を含有することを特徴とする。 Moreover, the food / beverage products of this invention are characterized by including the decomposition | disassembly processed food raw material of this invention.
また、本発明の分解処理食品素材の製造方法は、昆布及び/又は昆布加工品を加熱押出機で加熱処理する工程と、前記加熱処理した前記昆布及び/又は昆布加工品を、酵素添加の下、再度押出機で処理する工程とを含む、ことを特徴とする分解処理食品素材の製造方法であって、前記加熱処理において、前記押出機のシリンダー温度は、200℃〜350℃であることを特徴とする。
Further, the method for producing a decomposed food material according to the present invention comprises a step of heat-treating kelp and / or processed kelp with a heating extruder, and the heat-treated kelp and / or processed kelp under the addition of an enzyme. A process for producing a decomposition-processed food material, characterized in that, in the heat treatment, the cylinder temperature of the extruder is 200 ° C to 350 ° C. Features.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記酵素は、セルラーゼ、ペクチナーゼ、グルカナーゼ、アルギン酸リアーゼ、β-グルコシダーゼ、プロテアーゼ、アミラーゼ、リパーゼ、キシラナーゼ、ヘミセルラーゼ、ペプチダーゼ、植物組織崩壊酵素からなる群から選択される少なくとも1種であり、前記酵素添加の下、再度押出機で処理する工程において、前記押出機のシリンダー温度は20〜80℃であることを特徴とする。 Moreover, in a preferred embodiment of the method for producing a degradation-processed food material of the present invention, the enzyme is cellulase, pectinase, glucanase, alginate lyase, β-glucosidase, protease, amylase, lipase, xylanase, hemicellulase, peptidase, plant tissue. It is at least one selected from the group consisting of disintegrating enzymes, and the cylinder temperature of the extruder is 20 to 80 ° C. in the step of processing with an extruder again after the addition of the enzyme.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記酵素添加の下、再度押出機で処理する工程において、前記押出機に酵素を投入する酵素処理を行い、再度押出機で処理するか、又は前記加熱処理後に押し出された吐出物に、酵素を添加して分散手段を用いて酵素分散処理を行い、酵素添加吐出物を再度押出機で処理することを特徴とする。 Moreover, in a preferred embodiment of the method for producing a degradation-processed food material according to the present invention, in the step of treating with an extruder again after the addition of the enzyme, an enzyme treatment is performed in which the enzyme is introduced into the extruder, and again in the extruder. It is characterized in that an enzyme is added to the discharged material that has been processed or extruded after the heat treatment, an enzyme dispersion treatment is performed using a dispersing means, and the discharged enzyme-added material is processed again with an extruder.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記押出機による処理は、2〜8軸同方向回転押出機を2つ以上用いて処理するものであるか、又は2段以上のシリンダーを有するタンデム型押出機によって連続処理するものであることを特徴とする。 Moreover, in the preferable embodiment of the manufacturing method of the decomposition | disassembly processing foodstuff material of this invention, the process by the said extruder is processed using two or more 8-8 axis | shaft co-rotating extruders, or 2 steps | paragraphs. It is characterized by being continuously processed by a tandem extruder having the above cylinder.
また、本発明の分解処理食品粉末の製造方法は、本発明の分解処理食品素材の製造方法によって得られた分解処理食品素材を、粉砕及び乾燥する工程を含むことを特徴とする。 Moreover, the manufacturing method of the decomposition-processed food powder of this invention is characterized by including the process of grind | pulverizing and drying the decomposition-processed food material obtained by the manufacturing method of the decomposition-processed food material of this invention.
また、本発明の分解処理食品粉末の製造方法の好ましい実施態様において、前記粉砕を、胴搗き製粉、ロール製粉、石臼製粉、気流粉砕製粉、ピンミル製粉、又はジェットミルから選択されるいずれか1つ以上の方法により行うことを特徴とする。 Moreover, in a preferred embodiment of the method for producing a decomposition-processed food powder of the present invention, the pulverization is any one selected from body milling, roll milling, stone mill milling, airflow milling milling, pin mill milling, or jet milling. It is characterized by the above method.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記乾燥を、流動乾燥、真空乾燥、又は乾燥機能付き気流粉砕機から選択されるいずれか1つ以上の方法で行うことを特徴とする。 Moreover, in a preferred embodiment of the method for producing a decomposition-processed food material of the present invention, the drying is performed by any one or more methods selected from fluid drying, vacuum drying, or an airflow crusher with a drying function. Features.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記粉砕及び乾燥により得られた分解処理食品粉末は、平均粒径100μm以下であることを特徴とする。 Moreover, in a preferred embodiment of the method for producing a degradation-processed food material of the present invention, the degradation-process food powder obtained by pulverization and drying has an average particle size of 100 μm or less.
また、本発明の飲食品の風味を改善する方法は、本発明の昆布及び/又は昆布加工品の分解処理食品素材を飲食品へ添加することを特徴とする。 Moreover, the method of improving the flavor of the food / beverage products of this invention is characterized by adding the decomposition processed food material of the kelp and / or processed kelp product of this invention to the food / beverage products.
本発明の分解処理食品素材によれば、特定の温度範囲による極短時間の押出処理をすること、または、さらに押出処理物を酵素処理することによって、昆布及び/又はその加工品を高効率で分解し、呈味性を損なわないだけでなく、磯臭さや雑味などの不快味が解消され品質が向上し、かつ、昆布を丸ごと活用しながら、ざらつきや粘性の影響がなく、溶解性の優れた、旨み成分、風味成分、栄養成分全てを含む、原料由来の上品な昆布風味を有する風味食品素材を提供することができるという有利な効果を奏する。また、本発明の分解処理食品素材によれば、前記分解処理食品素材を他の飲食品に含有させることによって、飲食品の食味向上効果を効果的に改善することができるという有利な効果を奏する。 According to the decomposed food material of the present invention, kelp and / or processed products thereof can be efficiently obtained by performing an extremely short time extrusion process in a specific temperature range, or by further enzymatically treating the extruded product. Not only does it degrade and taste is not impaired, but also unpleasant taste such as odor and miscellaneous taste is eliminated and quality is improved. There is an advantageous effect that it is possible to provide an excellent flavored food material having an elegant kelp flavor derived from raw materials, which includes all excellent umami components, flavor components and nutritional components. Moreover, according to the decomposition-processed food material of this invention, there exists an advantageous effect that the taste improvement effect of food-drinks can be improved effectively by containing the said decomposition-processed food material in other food-drinks. .
本発明の昆布及び/又は昆布加工品の分解処理食品素材は、昆布及び/又は昆布加工品の押出機処理分解物であって、前記押出機処理分解物は、遊離還元糖を6mg/g〜40mg/gの範囲で含有することを特徴とする。本発明の昆布及び/又は昆布加工品の分解処理食品素材は、押出機により分解処理された素材であって、遊離還元糖を6mg/g〜40mg/gの範囲で含有する。通常、アルギン酸の存在によって、昆布及び/又は昆布加工品の分解が難しく、風味が良好な分解物を得られなかったが、本発明の押出機処理分解物によれば、旨味成分や昆布特有の香り成分を維持したまま良好な分解処理食品素材を実現できたことによる。したがって、押出機で加熱処理する工程において、よりせん断力の高いスクリューエレメントを選択すること、押出機で酵素分解処理する工程において、より滞留性の高いスクリューエレメントを選択すること、軸数の多い押出機を選択して滞留時間を長くすること、使用する酵素として、アモルファス状セルロースを分解する適性を有するセルラーゼ、および結晶状セルロースを分解する適性を有するセルラーゼを併用すること、酵素添加量を増やすこと、によって、さらに食品素材の分解度を上げ、呈味成分含量や食味向上効果を高めることができ、よって、旨味成分を向上させるという観点から、遊離還元糖を6mg/g〜40mg/gの範囲、好ましくは、7.6mg/g〜40mg/g、より好ましくは10mg/g〜40mg/gである。すなわち、本発明によれば、押出処理により、原料組織に強力な崩壊力を作用させることにより、強固な細胞壁の分解を向上することができ、結果として還元糖の比率が増加し、ひいては、原料組織に含まれる旨み成分や昆布特有の芳香成分等の風味向上成分の遊離を促進し、これらを含有する分解処理食品素材の顕著な食味向上効果を付与させることができるものである。なお、本発明においては、昆布及び/又は昆布加工品には、従来において、だしを取り出した昆布及び/又は昆布加工品の残渣も含まれる。これらの残渣であって、従来処分されていたものであっても、本発明の押出処理によれば、さらに、旨味成分をひきだすことができるからである。例えば、昆布を熱水抽出した後、残渣を除いて(除いたものは廃棄)だしを採る方法があるが、当該廃棄される昆布残渣も含有成分が十分に残っており、本発明により残渣をさらに分解して有用な素材を提供することができる。 Decomposition-processed food material of kelp and / or processed kelp according to the present invention is an extruder-processed decomposition product of kelp and / or processed-kombu product, wherein the extruder-processed decomposition product contains 6 mg / g or more of free reducing sugar. It contains in the range of 40 mg / g. The decomposition processed food material of the kelp and / or processed kombu product of the present invention is a material decomposed by an extruder and contains free reducing sugar in the range of 6 mg / g to 40 mg / g. Usually, the presence of alginic acid makes it difficult to decompose kelp and / or processed kombu products, and a decomposed product having a good flavor could not be obtained. This is due to the fact that it was possible to realize a good food material for decomposition treatment while maintaining the scent component. Therefore, in the process of heat treatment with an extruder, a screw element with higher shearing force is selected. In the process of enzymatic degradation with an extruder, a screw element with higher retention is selected. Select a machine to increase the residence time, use as the enzyme to be used cellulase having the ability to decompose amorphous cellulose, and cellulase having the ability to decompose crystalline cellulose, and increase the amount of enzyme added Can further increase the degree of decomposition of the food material and enhance the taste component content and the effect of improving the taste, and from the viewpoint of improving the umami component, the free reducing sugar is in the range of 6 mg / g to 40 mg / g. , Preferably 7.6 mg / g to 40 mg / g, more preferably 10 mg / g to 40 mg / g A. That is, according to the present invention, by causing a strong disintegration force to act on the raw material structure by the extrusion process, it is possible to improve the strong cell wall decomposition, resulting in an increase in the ratio of reducing sugars, and consequently the raw material. The release of flavor-improving components such as umami components contained in tissues and aroma components peculiar to kelp can be promoted, and a remarkable taste-enhancing effect of a decomposed food material containing these can be imparted. In the present invention, the kelp and / or the kelp processed product conventionally includes the kelp from which the stock is taken out and / or the residue of the kelp processed product. Even if it is these residues and was conventionally disposed of, according to the extrusion treatment of the present invention, it is possible to further extract umami components. For example, after extracting kombu with hot water, there is a method of removing the residue (excluding the discarded material) and taking out the stock. However, the discarded kombu residue contains sufficient components, and the present invention removes the residue. It can be further decomposed to provide useful materials.
なお、本発明において使用可能な原料の昆布は、特に限定されない。例えば、昆布の例としては、不等毛植物門褐藻綱コンブ目コンブ科に分類される、マコンブ、ヤヤンコンブ、ホソメコンブ、リシリコンブ、オニコンブ、エナガオニコンブ、クキナガコンブ、エナガコンブ、ミツイシコンブ、ナガコンブ、ガッガラコンブ、カラフトコンブ、チヂミコンブ、カラフトトロロコンブ、エンドウコンブ、ゴヘイコンブ、ヒダカコンブなどの属するコンブ属、ネコアシコンブなどの属するネコアシコンブ属、アツバスジコンブなどの属するミスジコンブ属、トロロコンブやガゴメコンブなどの属するトロロコンブ属、スジメなどの属するスジメ属、アナメ、オオノアナメなどの属するアナメ属、クロシオメなどの属するクロシオメ属、アラメ、サガラメなどの属するアラメ属、カジメ、クロメ、ツルアラメなどの属するカジメ属、アントクメなどの属するアントクメ属、ジャイアントケルプの属するMacrocystis 属に含まれる海藻等を挙げることができる。 In addition, the raw material kelp which can be used in the present invention is not particularly limited. For example, as an example of kombu, it is classified into the family of the Irregular plant phylum Brown algae Coleoptera, Macombu, Yayan Kombu, Hosome Kombu, Resibubu, Oni Kombu, Enaga Oni Kombu, Kukinaga Kombu, Enaga Kombu, Mitsuishi Kombu, Nagacomb, Gagara Kombu, Carafu Kombu, Chijimi Kombu, Caraft Trollo Kombu, Pea Kombu, Gohei Kombu, Hidaka Kombu, etc. Genus such as sage genus such as shark genus, black sage genus such as black squirrel That beforehand the genus, such as belongs Antokume genus Antokume, mention may be made of seaweed or the like contained in the Macrocystis genus belonging to the giant kelp.
また、本発明において使用可能な昆布加工品についても特に限定されない。例えば、昆布加工品の例としては、冷凍昆布、塩蔵昆布、乾燥昆布、焼き昆布、ボイル昆布、カット昆布や、酢昆布、おぼろ昆布、ばってら昆布、汐吹き昆布、昆布茶、昆布佃煮などの調味されたものを挙げることができる。また、昆布や昆布加工品の残渣の例としては、昆布だしや昆布エキスの抽出残渣(例えば昆布だしのだし粕)、昆布加工時の副生物(例えば煮汁及び/又はこれを煮詰めたもの、附着器(根部))、昆布加工品の成型残渣(例えば昆布〆の端材やカット昆布端材や爪昆布)を挙げることができる。 Moreover, it is not specifically limited about the processed kelp which can be used in this invention. For example, examples of processed kelp products include frozen kelp, salted kelp, dried kelp, baked kelp, boiled kelp, cut kelp, vinegar kelp, boro-kombu, battela kelp, simmered kelp, kelp tea, kelp-boiled stew The seasoned ones can be mentioned. In addition, examples of the residue of kelp and processed kelp products include kombu dashi and kelp extract extract residue (eg, kelp dashi stock), by-products during kelp processing (eg, boiled juice and / or stuffed this, attached Container (root)), and molding residue of processed kelp (for example, kelp milled material, cut kelp milled material and nail kelp).
前記昆布、前記昆布加工品、それらの残渣を、単独で使用しても良いし、2種以上を併用しても良い。 The kelp, the processed kelp product, and their residues may be used alone or in combination of two or more.
また、本発明における分解処理食品素材とは、そのまま食材に加えたり、加えた後に液体に分散・溶解させたり、調味料等の飲食品に含有させたりして、食材や飲食品に対して、風味やその他の効果を与えて、食材の嗜好性を高めたり、食品に味付けをすることを目的とする食品素材を総称する概念である。 In addition, the decomposition-treated food material in the present invention is added to the food as it is, or after being added, dispersed or dissolved in a liquid, or contained in a food or drink such as a seasoning, It is a concept that generically refers to food materials for the purpose of giving taste and other effects to enhance the palatability of foods or to season foods.
また、本発明の昆布及び/又は昆布加工品の分解処理食品素材の好ましい実施態様において、前記昆布及び/又は昆布加工品の押出機処理分解物は、遊離アルギン酸を7.5質量%〜40質量%の範囲で含有することを特徴とする。還元糖、及びエキス分は、旨味成分となるが、通常、アルギン酸はこれらの溶出を阻害する。本発明によれば、押出処理により、効率よく分解して、アルギン酸を遊離させることができる。かかる観点から、前記昆布及び/又は昆布加工品の押出機処理分解物は、好ましくは、8質量%以上、より好ましくは10質量%以上〜40質量%の範囲とすることができる。このように、本発明においては、押出処理により、遊離アルギン酸を7.5質量%〜40質量%の範囲で含有させることによって、相乗効果として、押出処理により、原料組織を保護するように取り囲む非遊離アルギン酸ポリマーの分解を行わなければ、本来的には内部に閉じ込められていた還元糖、及びエキス分などの旨味成分を溶出させ、ひいては、食味向上効果を有する新しい分解処理食品素材を提供することができる。なお、押出機で加熱処理する工程において、よりせん断力の高いスクリューエレメントを選択することによって、さらに食品素材の分解度を上げ、後の工程における呈味成分含量や食味向上効果を高めることができる。 Moreover, in the preferable embodiment of the decomposition-processed food material of the kelp and / or the processed kelp of the present invention, the extruder-processed decomposed product of the kelp and / or the processed kelp is 7.5% by mass to 40% by mass of free alginic acid. % Content. The reducing sugar and the extract are umami components, but alginic acid usually inhibits their elution. According to the present invention, alginic acid can be liberated efficiently by extrusion. From this point of view, the above-described kelp and / or the processed product of the processed kelp is preferably 8% by mass or more, more preferably 10% by mass to 40% by mass. Thus, in the present invention, by containing free alginic acid in the range of 7.5% by mass to 40% by mass by the extrusion process, as a synergistic effect, the non-surrounding material surrounding the raw material structure is protected by the extrusion process. If the free alginic acid polymer is not decomposed, it is possible to elute umami components such as reducing sugar and extract that were originally confined in the interior, and thus provide a new decomposed food material that has an effect of improving the taste. Can do. In addition, in the process of heat-processing with an extruder, by selecting a screw element having a higher shearing force, the degree of decomposition of the food material can be further increased, and the taste component content and the taste improvement effect in the subsequent process can be enhanced. .
また、本発明の昆布及び/又は昆布加工品の分解処理食品素材の好ましい実施態様において、前記昆布及び/又は昆布加工品の押出機処理分解物は、粉末状であることを特徴とする。また、本発明の好ましい実施態様において、前記粉末状の昆布及び/又は昆布加工品の押出機処理分解物は、平均粒径100μm以下であることを特徴とする。なお、平均粒径の測定には、方式として、レーザ回折式粒度分布測定を用いて、例えば、装置として、SALD-200V ER(島津製作所製)を用いて測定することができる。 In a preferred embodiment of the kelp and / or processed food product of kelp processed product according to the present invention, the extruder processed decomposed product of kelp and / or processed kelp product is in the form of powder. Moreover, in a preferred embodiment of the present invention, the powdered kelp and / or the processed product of the kelp processed by the extruder has an average particle size of 100 μm or less. The average particle diameter can be measured using laser diffraction particle size distribution measurement as a method, for example, using SALD-200V ER (manufactured by Shimadzu Corporation) as an apparatus.
また、本発明の飲食品は、本発明の分解処理食品素材を含有することを特徴とする。本発明の分解処理食品素材は、アルギン酸を効率よく遊離化できて、ひいては、還元糖、エキス分等による旨み成分や、昆布特有の芳香成分等の、風味向上成分も増加し、本発明の分解処理食品素材の添加により、飲食品に対して風味等を向上させるという有利な効果を奏する。本発明の分解処理食品素材の含有量としては、特に限定されず、調味料等の常法による含有量を適用することができる。 Moreover, the food / beverage products of this invention are characterized by including the decomposition | disassembly processed food raw material of this invention. The degradation-treated food material of the present invention can efficiently liberate alginic acid, and as a result, flavor-improving components such as umami components due to reducing sugars, extracts, etc., and aroma components peculiar to kelp increase, and the degradation of the present invention The addition of the processed food material has an advantageous effect of improving the flavor and the like of the food and drink. It does not specifically limit as content of the decomposition | disassembly processed food material of this invention, Content by the usual methods, such as a seasoning, can be applied.
次に、本発明の分解処理食品素材の製造方法について説明する。本発明の分解処理食品素材の製造方法は、昆布及び/又は昆布加工品を押出機で加熱処理する工程と、前記加熱処理した前記昆布及び/又は昆布加工品を、酵素添加の下、再度押出機で処理する工程とを含む、ことを特徴とする。本発明においては、昆布及び/又は昆布加工品には、従来において、だしを取り出した昆布及び/又は昆布加工品の残渣も含まれる。これらの残渣であって、従来処分されていたものであっても、従来のだし採り方法によっては抽出されない風味成分が多量に残存しており、本発明の押出処理によれば、さらに旨味成分や昆布特有の芳香成分等の、風味向上成分をひきだすことができるからである。まず、本発明においては、昆布及び/又は昆布加工品を押出機で加熱処理する。押出機については、特に限定されない。好ましい実施態様において、前記加熱処理において、前記押出機のシリンダー温度は、焦げつきなどの品質の低下を生じさせず、強固な細胞壁の分解を効率的、効果的に行うという観点から、100℃〜350℃であることが好ましく、150℃〜350℃がより好ましく、200℃〜350℃がさらに好ましく、330℃付近が特に好ましい。 Next, the manufacturing method of the decomposition | disassembly processing food material of this invention is demonstrated. The method for producing a decomposed food material according to the present invention includes a step of heat-treating kelp and / or processed kelp with an extruder, and extruding the heat-treated kelp and / or kelp-processed product again with the addition of an enzyme. And processing with a machine. In the present invention, the kelp and / or the kelp processed product conventionally includes the kelp and / or the kelp processed residue from which the dashi is taken out. Even if these residues are disposed of in the past, a large amount of flavor components that are not extracted by the conventional dashi collection method remain, and according to the extrusion process of the present invention, further umami components and This is because flavor-enhancing ingredients such as fragrant ingredients peculiar to kelp can be extracted. First, in the present invention, kelp and / or processed kelp is heat-treated with an extruder. The extruder is not particularly limited. In a preferred embodiment, in the heat treatment, the cylinder temperature of the extruder is 100 ° C. to 350 ° C. from the viewpoint of efficiently and effectively decomposing a strong cell wall without causing deterioration in quality such as scorching. Preferably, the temperature is 150 ° C to 350 ° C, more preferably 200 ° C to 350 ° C, and particularly preferably around 330 ° C.
次いで、本発明においては、押出機で加熱処理する工程によって、強固な植物組織を崩壊させて調製した分解処理食品素材の、旨味成分や昆布特有の芳香成分等の、風味向上成分について、さらなる増強を図るという観点から、前記加熱処理した前記昆布及び/又は昆布加工品を、酵素添加の下、再度押出機で処理する。なぜなら、押出機で加熱処理する工程によって、強固な植物組織を崩壊させられた原料は組織が微細に分解されており、酵素作用が顕著に働き易くなっているからである。また、好ましい実施態様において、前記酵素は、セルラーゼ、ペクチナーゼ、グルカナーゼ、アルギン酸リアーゼ、β-グルコシダーゼ、プロテアーゼ、アミラーゼ、リパーゼ、キシラナーゼ、ヘミセルラーゼ、ペプチダーゼ、植物組織崩壊酵素からなる群から選択される少なくとも1種である。さらに、より好ましい実施態様において、植物組織におけるセルロースの構造は多様であるため、より分解度を上げるためには、アモルファス状セルロースを分解する適性を有するセルラーゼ、結晶状セルロースを分解する適性を有するセルラーゼ、および、アルギン酸リアーゼを併用すること、酵素添加量を増やすことができる。これらによって、呈味成分含量や食味向上効果を高めることができる。また、好ましい態様において、前記酵素添加の下、再度押出機で処理する工程において、添加した酵素の作用が最も効率的に働く至適温度で作用させるという観点から、前記押出機のシリンダー温度は、20〜80℃、より好ましくは、45〜65℃である。前記酵素添加の下、再度押出機で処理する工程の一つの利点は、非常に短時間で反応させることができる点である。すなわち、通常、押出処理を伴わなければ、何十時間、何百時間等を要するが、酵素添加の下、再度押出機で処理することにより、例えば、20秒〜2分で行うことができる。なお、酵素の失活条件としては、80℃〜90℃以上であれば良いが流通速度の観点から確実な処理を行うためには130℃程度がより好ましく、酵素処理反応を行う押出機の出口において前記温度を適宜設定して失活処理すれば良い。 Next, in the present invention, further enhancing the flavor-improving components such as the umami component and the kelp-specific fragrance component of the decomposed food material prepared by disintegrating the strong plant tissue by the heat treatment step with an extruder. From the viewpoint of achieving the above, the heat-treated kelp and / or processed kelp product is treated again with an extruder under the addition of an enzyme. This is because the raw material in which the strong plant tissue is disintegrated by the heat treatment step in the extruder has been finely decomposed, and the enzyme action is remarkably easy to work. In a preferred embodiment, the enzyme is at least one selected from the group consisting of cellulase, pectinase, glucanase, alginate lyase, β-glucosidase, protease, amylase, lipase, xylanase, hemicellulase, peptidase, plant tissue disrupting enzyme. It is a seed. Furthermore, in a more preferred embodiment, since the structure of cellulose in plant tissue is diverse, cellulase having the ability to degrade amorphous cellulose, cellulase having the ability to degrade crystalline cellulose in order to further increase the degree of degradation , And using alginate lyase together, the amount of enzyme added can be increased. By these, a taste ingredient content and a taste improvement effect can be heightened. Further, in a preferred embodiment, the cylinder temperature of the extruder is from the viewpoint of operating at an optimum temperature at which the action of the added enzyme works most efficiently in the step of processing in the extruder again after the enzyme addition, 20-80 degreeC, More preferably, it is 45-65 degreeC. One advantage of the process in the extruder again after the addition of the enzyme is that it can be reacted in a very short time. That is, it usually takes tens of hours or hundreds of hours without an extrusion process, but can be performed in, for example, 20 seconds to 2 minutes by treating with an extruder again after addition of an enzyme. In addition, the enzyme deactivation condition may be 80 ° C. to 90 ° C. or more, but in order to perform reliable treatment from the viewpoint of the flow rate, about 130 ° C. is more preferable, and the outlet of the extruder for performing the enzyme treatment reaction In this case, the deactivation treatment may be performed by appropriately setting the temperature.
また、前記加熱処理工程において、加水しながら押出処理することができる。加水量は、押出機内での流動性確保という観点から、前記昆布及び/又は昆布加工品、それら残渣100重量部に対して、水0〜200重量部、好ましくは0〜150重量部、より好ましくは、水0〜100重量部である。0〜としているのは、だし殻のようなものは最初から加水する必要が無いためである。 Moreover, in the said heat processing process, it can extrude, adding water. The amount of water added is 0 to 200 parts by weight, preferably 0 to 150 parts by weight, more preferably 0 to 150 parts by weight with respect to 100 parts by weight of the kelp and / or processed kelp from the viewpoint of ensuring fluidity in the extruder. Is 0 to 100 parts by weight of water. The reason for setting it to 0 is that there is no need to add water from the beginning of the husk.
また、前記酵素添加の下、再度押出機での処理工程において、加水しながら押出処理することができる。加水量は、押出機内の流動性及び酵素の均一な分散確保という観点から、前記昆布及び/又は昆布加工品、それら残渣100重量部に対して、水10〜200重量部、好ましくは、水30〜170重量部、より好ましくは、水50〜150重量部である。流動性ならびに酵素の均一な分散確保の観点から多いほうが良く、昆布などのように粘度が高くなるものは加水しながら押出処理することができる。 Moreover, it is possible to extrude while adding water in the processing step in the extruder again with the addition of the enzyme. From the viewpoint of ensuring fluidity in the extruder and uniform dispersion of the enzyme, the amount of water added is 10 to 200 parts by weight of water, preferably 30 parts of water with respect to 100 parts by weight of the kelp and / or processed kombu products. -170 weight part, More preferably, it is 50-150 weight part of water. From the viewpoint of ensuring fluidity and uniform dispersion of the enzyme, it is better to increase the amount, and those having a high viscosity such as kelp can be extruded while adding water.
また、押出機内での、酵素処理の利点について、従来のバッチ式(押出機外での酵素処理)による酵素処理による方法によっても、本発明における押出機で100℃〜350℃の加熱処理する工程によって得られた分解処理食品素材は強固な植物組織が崩壊されているため、従来の酵素処理に所用する時間が大幅に短縮でき、工程の効率化が可能であり、より高水分下での酵素反応を行うことができ、酵素分散性と反応性を高くし、反応時間を長くすることで、呈味成分含量や食味向上効果を著しく高められることが可能であるが、再度押出機で処理する工程のもう一つの利点は、従来のバッチ式では液状あるいはスラリー状の態様で処理されるため、処理産物を分離回収するための工程(例えばフィルタープレスや遠心分離による固液分離とその後の乾燥処理等)が必要であり、煩雑な工程を有するのに対し、本押出処理による方法では、処理産物をそのまま回収できるため、分離回収工程の必要がなく工程の大幅な合理化が可能である点である。 Moreover, about the advantage of the enzyme treatment in an extruder, the process of heat-processing 100 to 350 degreeC with the extruder in this invention also by the method by the enzyme treatment by the conventional batch type (enzyme treatment outside an extruder). Since the plant material of the decomposition-treated food material obtained by the above method has collapsed, the time required for conventional enzyme treatment can be greatly shortened, the process can be made more efficient, and the enzyme under higher moisture The reaction can be performed, the enzyme dispersibility and reactivity are increased, and the reaction time can be lengthened to significantly increase the taste component content and the taste-improving effect. Another advantage of the process is that it is processed in a liquid or slurry form in the conventional batch method, so that a process for separating and recovering the processed product (for example, solid-liquid separation by a filter press or centrifugal separation and subsequent processes). However, the process by this extrusion process can recover the processed product as it is, and there is no need for a separate recovery process, and the process can be greatly rationalized. It is.
また、押出処理における加圧/非加圧については以下の通りである。すなわち、押出処理時の圧力については、加圧/非加圧を問わず処理可能であるが、加圧した場合には処理物が押出機の出口から吐出される際に膨化し、容積が大きくなり、その後の処理に煩雑な操作を要する。一方、非加圧で処理した場合には処理物が処理前とほとんど変わらない容積で吐出されるため、その後の処理に特別な操作を要さず、取扱いが容易でより好ましい。 The pressurization / non-pressurization in the extrusion process is as follows. In other words, the pressure during the extrusion process can be processed regardless of whether it is pressurized or non-pressurized, but when pressurized, the processed material expands when discharged from the outlet of the extruder, resulting in a large volume. Therefore, a complicated operation is required for the subsequent processing. On the other hand, when the treatment is performed under non-pressurization, the treated product is ejected in a volume that is almost the same as that before the treatment, so that a special operation is not required for the subsequent treatment, and the handling is easy and more preferable.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記酵素添加の下、再度押出機で処理する工程において、前記押出機に酵素を投入する酵素処理を行い、再度押出機で処理するか、又は前記加熱処理後に押し出された吐出物に、酵素を添加して分散手段を用いて酵素分散処理を行い、酵素添加吐出物を再度押出機で処理することを特徴とする。すなわち、本発明の好ましい態様において、前記酵素添加の下、再度押出機で処理する工程において、前記押出機のシリンダー内へ酵素を直接投入する、連続式の酵素処理を行うことができる。また、本発明において、前記酵素添加の下、再度押出機で処理する工程において、前記加熱処理後の吐出物(加熱処理後に押し出された昆布及び/又は昆布加工品)に酵素を添加して、ヘンシェルミキサー、リボンミキサー、ロッキングミキサー、ナウターミキサー等の一般的な乾燥粉粒混合用機械などの分散手段を用いてバッチ式で酵素分散処理を行い、押出機内で分解処理を行うことができる。なお、押出機で酵素分解処理する工程において、より滞留性の高いスクリューエレメントを選択すること、軸数の多い押出機を選択して滞留時間を長くすることによって、呈味成分含量や食味向上効果を高めることができる。 Moreover, in a preferred embodiment of the method for producing a degradation-processed food material according to the present invention, in the step of treating with an extruder again after the addition of the enzyme, an enzyme treatment is performed in which the enzyme is introduced into the extruder, and again in the extruder. It is characterized in that an enzyme is added to the discharged material that has been processed or extruded after the heat treatment, an enzyme dispersion treatment is performed using a dispersing means, and the discharged enzyme-added material is processed again with an extruder. That is, in a preferred embodiment of the present invention, continuous enzyme treatment can be performed in which the enzyme is directly fed into the cylinder of the extruder in the step of treating with the extruder again after the addition of the enzyme. Further, in the present invention, in the step of processing again with the extruder under the addition of the enzyme, an enzyme is added to the discharged material after the heat treatment (the kelp and / or the processed kelp extruded after the heat treatment), The enzyme dispersion treatment can be performed batchwise using a dispersing means such as a general dry powder mixing machine such as a Henschel mixer, a ribbon mixer, a rocking mixer, and a nauter mixer, and the decomposition treatment can be performed in the extruder. In addition, in the process of enzymatic decomposition with an extruder, by selecting a screw element with a higher retention property, selecting an extruder with a larger number of shafts and lengthening the residence time, the taste component content and the taste-enhancing effect Can be increased.
また、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記押出機による処理は、酵素分散性及びその失活温度の厳密な管理という観点から、2〜8軸同方向回転押出機を2つ以上用いて処理するものであるか、又は、これら工程の一元化、作業スピードの向上の為という観点から、2段以上のシリンダーを有するタンデム型押出機によって連続処理するものであることを特徴とする。本発明においては、まず、加熱押出処理を行い、次に酵素添加の下、押出処理をする限り、2〜8軸の押出機や、2段以上のシリンダーを有する押出機を用いることができる。 Moreover, in a preferred embodiment of the method for producing a decomposition-processed food material according to the present invention, the treatment by the extruder is a 2- to 8-shaft co-rotating extruder from the viewpoint of strict control of enzyme dispersibility and its deactivation temperature. From the viewpoint of centralizing these processes and improving the working speed, or to continuously process by a tandem type extruder having two or more stages of cylinders. Features. In the present invention, a 2-8-axis extruder or an extruder having two or more cylinders can be used as long as the heat-extrusion process is performed first and then the extrusion process is performed with the addition of enzyme.
次に、本発明の分解処理食品粉末の製造方法について説明する。本発明の分解処理食品粉末の製造方法は、本発明の分解処理食品素材の製造方法によって得られた分解処理食品素材を、粉砕及び乾燥する工程を含むことを特徴とする。粉砕方法について特に限定されないが、本発明の分解処理食品粉末の製造方法の好ましい実施態様において、前記粉砕を、胴搗き製粉、ロール製粉、石臼製粉、気流粉砕製粉、ピンミル製粉、又はジェットミルから選択されるいずれか1つ以上の方法により行うことができる。また、乾燥方法についても特に限定されないが、本発明の分解処理食品素材の製造方法の好ましい実施態様において、前記乾燥を、流動乾燥、真空乾燥、又は乾燥機能付き気流粉砕機から選択されるいずれか1つ以上の方法で行うことができる。 Next, the manufacturing method of the decomposition | disassembly process food powder of this invention is demonstrated. The manufacturing method of the decomposition-processed food powder of this invention is characterized by including the process of grind | pulverizing and drying the decomposition-processed food material obtained by the manufacturing method of the decomposition-processed food material of this invention. Although there is no particular limitation on the pulverization method, in a preferred embodiment of the method for producing the decomposition-processed food powder of the present invention, the pulverization is selected from body milling, roll milling, stone mill milling, airflow milling milling, pin mill milling, or jet mill It can be performed by any one or more methods. Also, the drying method is not particularly limited, but in a preferred embodiment of the method for producing a decomposed food material of the present invention, the drying is selected from fluid drying, vacuum drying, or an airflow crusher with a drying function. This can be done in one or more ways.
また、好ましい実施態様において、前記粉砕及び乾燥により得られた分解処理食品粉末は、他の飲食品への添加時の溶解・分散性の向上、および食感のざらつきにより喫食事に違和感を感じさせないという観点から、平均粒径100μm以下である。なお、平均粒径の測定には、方式として、レーザ回折式粒度分布測定を用いて、例えば、装置として、SALD-200V ER(島津製作所製)を用いて測定することができる。 Further, in a preferred embodiment, the decomposition-processed food powder obtained by pulverization and drying does not give a sense of incongruity to a meal due to an improvement in solubility and dispersibility when added to other foods and drinks and a rough texture. From this viewpoint, the average particle size is 100 μm or less. The average particle diameter can be measured using laser diffraction particle size distribution measurement as a method, for example, using SALD-200V ER (manufactured by Shimadzu Corporation) as an apparatus.
次に、本発明の飲食品の風味を改善する方法について説明すれば、以下の通りである。本発明の飲食品の風味を改善する方法は、上述の本発明の昆布及び/又は昆布加工品の分解処理食品素材を飲食品へ添加することを特徴とする。昆布及び/又は昆布加工品、分解処理食品素材については、上述の本発明の分解処理食品素材の説明をそのまま参照することができる。このように本発明の分解処理食品素材を、他の飲食品に含有させることによって、飲食品の食味向上効果を効果的に改善することができる。 Next, it will be as follows if the method of improving the flavor of the food / beverage products of this invention is demonstrated. The method for improving the flavor of a food or drink according to the present invention is characterized by adding the above-described kelp and / or the processed food material of the processed kelp according to the present invention to the food or drink. Regarding the kelp and / or the processed kelp and the decomposed food material, the description of the above-described decomposed food material of the present invention can be referred to as it is. Thus, the taste improvement effect of food / beverage products can be improved effectively by making the decomposition-processed food material of this invention contain in other food / beverage products.
ここで、本発明の実施例を説明するが、本発明は、下記の実施例に限定して解釈されるものではない。また、本発明の要旨を逸脱することなく、適宜変更することが可能であることは言うまでもない。 Examples of the present invention will now be described, but the present invention is not construed as being limited to the following examples. Moreover, it cannot be overemphasized that it can change suitably, without deviating from the summary of this invention.
<試験区1:実施例1〜3>
まず、長昆布を、2軸押出機で加水90%でシリンダー温度330℃で押出し後、その吐出物に以下の組みあわせで酵素添加を行い、再度同押出機に投入し、酵素反応温度の為シリンダー温度55℃で加水110%にて押出を行い、その再吐出物を乾燥、気流粉砕機にて粉砕を行った物の遊離アミノ酸、エキス分比較を行った。参照例は、長昆布を加熱押出処理のみ行った物である。
<Test Zone 1: Examples 1-3>
First, long kombu was extruded at 90% water with a twin screw extruder at a cylinder temperature of 330 ° C using a twin-screw extruder, and then the enzyme was added to the discharged product in the following combination, and the mixture was put into the extruder again to determine the enzyme reaction temperature. Extrusion was performed at a cylinder temperature of 55 ° C. at 110% water, the re-discharged product was dried, and the free amino acid and extract content of the product obtained by grinding with an airflow grinder were compared. The reference example is a product obtained by subjecting long kelp to only heat extrusion.
実施例1は、参照例1に対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製ペクチナーゼSPGと同社製ペクチナーゼPTEを添加し、再押出処理した物である。 Example 1 is a product obtained by re-extruding Cellulase AC, Cellulase CG, Cellulase CG, Company pectinase SPG, and Company pectinase PTE from Shin Nippon Chemical Co., Ltd. with respect to Reference Example 1 and reextruding.
実施例2は、参照例1に対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製ペクチナーゼSPGと同社製グルカナーゼTGを添加し、再押出処理した物である。 In Example 2, Cellulase AC manufactured by Shin Nippon Chemical Co., Ltd., Cellulase CG manufactured by the same company, Pectinase SPG manufactured by the same company, and Glucanase TG manufactured by the same company were added to Reference Example 1, and reextruded.
実施例3は、参照例1に対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製ペクチナーゼSPGと同社製ペクチナーゼPTEとナガセケムテックス(株)製アルギン酸リアーゼを添加し、再押出処理した物である。その結果を表1に示す。 In Example 3, Cellulase AC manufactured by Shin Nippon Chemical Co., Ltd., Cellulase CG manufactured by the same company, Pectinase SPG manufactured by the same company, Pectinase PTE manufactured by the same company, and Alginate lyase manufactured by Nagase ChemteX Co., Ltd. were added to Reference Example 1. Extruded product. The results are shown in Table 1.
その結果、昆布だし旨味成分である還元糖、エキス分が、その溶出を阻害するアルギン酸が遊離化するにつれ、増加していく事が観察された。次に、表1で得られた実施例1から3の分解処理食品素材を、自社製昆布つゆ(4倍)に添加し、以下表2の形で官能試験を行った。 As a result, it was observed that reducing sugars and extracts, which are components of konbu-dashi, increase as alginic acid that inhibits elution is liberated. Next, the decomposed food materials of Examples 1 to 3 obtained in Table 1 were added to in-house made kelp soup (4 times), and the sensory test was conducted in the form of Table 2 below.
その結果、温度処理のみの物より、酵素添加区の方が総合評価において、明らかな優位差が見られた。 As a result, a clear superior difference was seen in the comprehensive evaluation in the enzyme-added section than in the case of only the temperature treatment.
<試験区2:実施例4〜7>
次に、真昆布を2軸押出機で加水90%でシリンダー温度330℃で押出し後、その吐出物に以下の組みあわせで酵素添加を行い、再度同押出機に投入し、酵素反応温度の為シリンダー温度55℃で加水55%にて押出を行い、その再吐出物を乾燥、気流粉砕機にて粉砕を行った物の遊離アミノ酸、エキス分比較を行った。比較例1は、真昆布を単純に粉砕のみ行った物である。
<Test Zone 2: Examples 4-7>
Next, true kelp was extruded with a twin screw extruder at 90% water and cylinder temperature of 330 ° C, and then the enzyme was added to the discharged product in the following combination, and the mixture was put again into the same extruder for the enzyme reaction temperature. Extrusion was carried out at a cylinder temperature of 55 ° C. with a water content of 55%, and the re-discharged product was dried, and the free amino acid and extract content of the product obtained by pulverization with an airflow crusher were compared. Comparative Example 1 is a product obtained by simply crushing true kelp.
実施例4は、比較例1を加熱押し出し処理のみ行った物である。実施例5は、実施例4のものに対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製ペクチナーゼSPGと同社製グルカナーゼTGを添加し、再押出処理した物である。 In Example 4, Comparative Example 1 was only subjected to the heat extrusion treatment. In Example 5, Cellulase AC made by Shin Nippon Chemical Co., Ltd., Cellulase CG made by the same company, Pectinase SPG made by the same company and Glucanase TG made by the same company were added to the product of Example 4 and reextruded.
実施例6は、実施例4のものに対し、新日本化学(株)製セルラーゼACとグルカナーゼTGとグルコシターゼBGAを添加し、再押出処理した物である。実施例7は、実施例4に対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製グルカナーゼTGを添加し、再押出処理した物である。 Example 6 is a product obtained by adding cellulase AC, glucanase TG, and glucosidase BGA manufactured by Shin Nippon Chemical Co., Ltd. to the product of Example 4 and performing a re-extrusion process. In Example 7, Cellulase AC manufactured by Shin Nippon Chemical Co., Ltd., Cellulase CG manufactured by the same company, and Glucanase TG manufactured by the same company were added to Example 4 and reextruded.
その結果、昆布だし旨味成分である還元糖、エキス分が、その溶出を阻害するアルギン酸が遊離化するにつれ、増加していく事が観察された。またSPME法にて分析した結果、昆布特有の磯臭さの要因であるヘキサナールの低下も認められた。なお、対Cont.%は、対比較例1に対する%表示を示す。次に、表3で得られた実施例4〜7の分解処理食品素材を自社製地鶏だしに添加し、以下表4の形で官能試験を行った。 As a result, it was observed that reducing sugars and extracts, which are components of konbu-dashi, increase as alginic acid that inhibits elution is liberated. In addition, as a result of analysis by SPME method, a decrease in hexanal, which is a factor of the odor characteristic peculiar to kelp, was also observed. Note that “Cont.%” Indicates “%” for the comparative example 1. Next, the decomposed food materials of Examples 4 to 7 obtained in Table 3 were added to the in-house local chicken stock, and the sensory test was conducted in the form shown in Table 4 below.
その結果、単純粉砕品(比較例1)より、酵素添加区(実施例4〜7)の方が総合評価において、明らかな優位差が見られた。 As a result, a clear superior difference was observed in the comprehensive evaluation in the enzyme-added section (Examples 4 to 7) than in the simple pulverized product (Comparative Example 1).
<試験区3:実施例8>
次に、日高昆布を2軸押出機で加水90%でシリンダー温度330℃で押出し後、その吐出物に以下の組みあわせで酵素添加を行い、再度同押出機に投入し、酵素反応温度の為シリンダー温度55℃で加水55%にて押出を行い、その再吐出物を乾燥、気流粉砕機にて粉砕を行った物の遊離アミノ酸、エキス分比較を行った。比較例2は、日高昆布を単純に粉砕のみ行った物である。参照例2は、比較例2のものに加熱押し出し処理のみ行った物である。
<Test Zone 3: Example 8>
Next, after extruding Hidaka kelp with 90% water and a cylinder temperature of 330 ° C in a twin-screw extruder, the enzyme was added to the discharged product in the following combination, and the mixture was put into the extruder again, and the enzyme reaction temperature was adjusted. For this reason, extrusion was performed at a cylinder temperature of 55 ° C. with a water content of 55%, the re-discharged product was dried, and the free amino acid and extract content of the product obtained by pulverization with an airflow pulverizer were compared. Comparative Example 2 is a product obtained by simply crushing Hidaka kelp. The reference example 2 is the thing which performed only the heat extrusion process to the thing of the comparative example 2.
実施例8は、参照例2に対し、新日本化学(株)製セルラーゼACと同社製セルラーゼCGと同社製グルカナーゼTGを添加し、再押出処理した物である。 In Example 8, Cellulase AC manufactured by Shin Nippon Chemical Co., Ltd., Cellulase CG manufactured by the same company, and Glucanase TG manufactured by the same company were added to Reference Example 2, and reextruded.
その結果、昆布だし旨味成分である還元糖、エキス分が、その溶出を阻害するアルギン酸が遊離化するにつれ、増加していく事が観察された。またSPME法にて分析した結果、昆布特有の磯臭さの要因であるヘキサナールの増加が認められた。なお、対Cont.%は、対比較例2に対する%表示を示す。次に表5で得られた実施例8の分解処理食品素材を自社製地鶏だしに添加し、以下の表6の形で官能試験を行った。 As a result, it was observed that reducing sugars and extracts, which are components of konbu-dashi, increase as alginic acid that inhibits elution is liberated. In addition, as a result of analysis by SPME method, an increase in hexanal, which is a cause of the odor characteristic of kelp, was observed. Note that “Cont.%” Indicates “%” for the comparative example 2. Next, the decomposition processed food material of Example 8 obtained in Table 5 was added to the in-house chicken stock, and the sensory test was performed in the form of Table 6 below.
その結果、単純粉砕品より、酵素添加区の方が総合評価において、優位差が見られた。ヘキサナールは増加する傾向が見られたが、未処理品より磯臭さが上回る事なく、全体として調和のある味である事が確認できた。 As a result, in the comprehensive evaluation, a superior difference was observed in the enzyme-added section than in the simple pulverized product. Hexanal showed a tendency to increase, but it was confirmed that the taste was harmonious as a whole without the odor exceeding that of the untreated product.
以上から、本発明によって、特定の温度範囲による極短時間の押出処理をすること、さらに押出処理物を酵素処理することによって、昆布及び/又はその加工品を高効率で分解し、呈味性を損なわないだけでなく、磯臭さや雑味などの不快味が解消され品質が向上し、かつ、昆布を丸ごと活用しながら、ざらつきや粘性の影響がなく、溶解性の優れた、旨み成分、風味成分、栄養成分全てを含む、原料由来の上品な昆布風味を有する風味食品素材を提供することができることが判明した。また、本発明の分解処理食品素材を他の飲食品に含有させることによって、飲食品の食味向上効果を効果的に改善する方法を提供することができることが判明した。また、本発明の分解処理食品素材を他の飲食品に含有させることによって、粘度の上昇や食感のざらつきを伴わずに、飲食品に好ましい昆布風味を付与及び/又は増強させることができること、有機酸の刺激を緩和させることができること、塩分を減らすことができることを新たに知見した。 As described above, according to the present invention, the kelp and / or the processed product thereof is decomposed with high efficiency by performing an extremely short time extrusion process in a specific temperature range, and further by subjecting the extruded product to an enzyme treatment, and thereby exhibiting taste. In addition to eliminating unpleasant tastes such as odor and miscellaneous taste, quality is improved, and the whole kombu is used, and there is no influence of roughness and viscosity, and it has excellent solubility, It has been found that a flavored food material having a refined kelp flavor derived from raw materials, including all flavor components and nutritional components, can be provided. Moreover, it turned out that the method of improving the taste improvement effect of food-drinks effectively can be provided by making the decomposition-processed food material of this invention contain in other food-drinks. Moreover, by including the decomposition-processed food material of the present invention in other foods and drinks, it is possible to impart and / or enhance a preferable kelp flavor to foods and drinks without increasing the viscosity and rough texture. It was newly discovered that the stimulation of organic acids can be alleviated and that the salinity can be reduced.
近年、食品に含まれる成分を最大限引出し有効利用することが要求されており、食品を丸ごと活用し得る本発明の分解処理食品素材は、広範な分野において応用可能である。 In recent years, it has been required to extract and effectively use ingredients contained in food as much as possible, and the degradation-processed food material of the present invention that can utilize the whole food can be applied in a wide range of fields.
Claims (14)
A method for improving the flavor of a food or drink, comprising adding the decomposition-treated food material of the kelp and / or processed kelp according to any one of claims 1 to 4 to the food or drink.
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