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JP6267431B2 - Latent heat recovery type heat source machine and neutralizer - Google Patents
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JP6267431B2 - Latent heat recovery type heat source machine and neutralizer - Google Patents

Latent heat recovery type heat source machine and neutralizer Download PDF

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JP6267431B2
JP6267431B2 JP2013060516A JP2013060516A JP6267431B2 JP 6267431 B2 JP6267431 B2 JP 6267431B2 JP 2013060516 A JP2013060516 A JP 2013060516A JP 2013060516 A JP2013060516 A JP 2013060516A JP 6267431 B2 JP6267431 B2 JP 6267431B2
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water
drain
neutralizer
water storage
pressure
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JP2014185807A (en
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寿久 斉藤
寿久 斉藤
優介 藤枝
優介 藤枝
吉田 輝
輝 吉田
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株式会社ガスター
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Description

本発明は、燃焼排気から顕熱および潜熱を回収する潜熱回収型の熱源機およびドレンの中和器に関する。   The present invention relates to a latent heat recovery type heat source device that recovers sensible heat and latent heat from combustion exhaust and a drain neutralizer.

バーナーで加熱された空気(燃焼排気)から主に顕熱を回収する顕熱回収用熱交換器の下流に、排気の潜熱をさらに回収する潜熱回収用熱交換器を設けて熱回収効率を高めるように構成された潜熱回収型の給湯機などの熱源機がある。   Heat recovery efficiency is improved by providing a latent heat recovery heat exchanger that further recovers the latent heat of the exhaust downstream of the sensible heat recovery heat exchanger that mainly recovers sensible heat from the air heated by the burner (combustion exhaust). There is a heat source machine such as a latent heat recovery type water heater configured as described above.

このような潜熱回収型の熱源機では、排気に含まれる水蒸気が潜熱回収時に結露して凝縮水(ドレン)が生じる。このドレンは、排気中の窒素酸化物や硫黄酸化物を吸収して酸性となる。そのため、潜熱回収型の熱源機では、ドレンを回収し、中和器で中和した後、ドレン排出口から排水するようになっている。   In such a latent heat recovery type heat source machine, water vapor contained in the exhaust gas condenses during the recovery of latent heat to generate condensed water (drain). This drain becomes acidic by absorbing nitrogen oxides and sulfur oxides in the exhaust gas. Therefore, in the latent heat recovery type heat source machine, drain is recovered, neutralized by a neutralizer, and then drained from a drain outlet.

通常、中和器は、水封構造を備えた容器の中に中和剤を入れて構成される。中和器にドレンが貯まって水封された状態では、排気が中和器を通ってドレン排出口から外部へ漏れ出ることはない。しかし、工場出荷時は中和器は乾燥した状態にされており、内部にドレンがなく、水封されていないので、熱源機を設置した後、そのまま最初の運転を行うと、排気が中和器を通って外部へ漏れ出てしまう。ドレン排出口から漏れた排気は、周囲の者に不快感を与えるだけでなく、結露すると酸性のドレンを発生させるので、パイプシャフトなどに熱源機が設置されて、配管やガスメータなどが近くにあると、これらを腐食させてしまう。   Usually, the neutralizer is configured by putting a neutralizer in a container having a water seal structure. In a state where drain is accumulated in the neutralizer and sealed with water, the exhaust does not leak out from the drain outlet through the neutralizer. However, since the neutralizer is in a dry state at the time of shipment from the factory, there is no drain inside and it is not sealed with water. Leaks out through the vessel. Exhaust leaked from the drain outlet not only causes discomfort to the people around you but also generates acidic drainage when condensed, so a heat source device is installed on the pipe shaft, etc., and piping and gas meters are nearby. And it will corrode them.

そこで、設置後の運転開始前に作業者が中和器に水を入れて水封状態を確保する、といった作業を設置手順に規定することが行われる。   Therefore, an operation in which an operator puts water into the neutralizer to ensure a water-sealed state before starting operation after installation is defined in the installation procedure.

また、特許文献1には、給水管から分岐させた注水配管を中和器に接続し、該注水配管の途中に設けた電磁弁を開くことで中和器へ注水できるようにした給湯機が開示されている。この給湯機では中和器の水封が確保されるまで燃焼を禁止するように制御している。   Patent Document 1 discloses a water heater that connects a water injection pipe branched from a water supply pipe to a neutralizer, and opens a solenoid valve provided in the middle of the water injection pipe so that water can be injected into the neutralizer. It is disclosed. This water heater is controlled so as to inhibit combustion until the water seal of the neutralizer is secured.

なお、下記特許文献2には、潜熱回収用熱交換器を通る水管がドレンによって腐食されて孔が開いた場合でも、この孔から漏れた水がドレンパンに回収され中和器を通って排水されてしまうので腐食に気付かないという課題を解決するために、中和器の上流側のドレン配管の途中に、該ドレン配管を流れる水の量を検出する水量センサを設けた給湯機が開示されている。この水量センサは、底部に絞りを有する溜め空間と、溜め空間内で上下するフロートと、フロートの位置を検出するセンサとを有して構成される。   In Patent Document 2 below, even if the water pipe passing through the latent heat recovery heat exchanger is corroded by the drain and the hole is opened, the water leaked from the hole is recovered in the drain pan and drained through the neutralizer. In order to solve the problem of not recognizing corrosion, a water heater provided with a water amount sensor for detecting the amount of water flowing through the drain pipe is disclosed in the middle of the drain pipe upstream of the neutralizer. Yes. This water amount sensor includes a reservoir space having a throttle at the bottom, a float that moves up and down in the reservoir space, and a sensor that detects the position of the float.

特開2009−109085号公報JP 2009-109085 A 特開2002−147847号公報JP 2002-147847 A

設置後の運転開始前に作業者が中和器に水を入れることを設置手順に規定しても、作業者のミスや懈怠によりこの作業が実施されない恐れがある。一方、特許文献1に開示されたように注水配管や電磁弁を設けると、熱源機の製造コストが嵩む。   Even if the installation procedure stipulates that the operator put water into the neutralizer prior to the start of operation after installation, this work may not be performed due to the operator's mistakes or fatigue. On the other hand, when a water injection pipe or a solenoid valve is provided as disclosed in Patent Document 1, the manufacturing cost of the heat source device increases.

特許文献2に開示された水量センサは、ドレンが流れないときはフロートが下がって絞りに蓋をするので、中和器が水封されていない状態において排気が絞りから中和器を通って外部へ漏れ出ることを防ぐ役割を果たす。しかし、ドレンパンに貯まったゴミや土埃などがドレンと共にドレン配管へ流入すると、絞りが直ぐに詰まってしまうという問題がある。   In the water amount sensor disclosed in Patent Document 2, when the drain does not flow, the float is lowered and the throttle is covered. Therefore, in the state where the neutralizer is not sealed with water, the exhaust gas passes through the neutralizer and passes through the neutralizer. Plays a role in preventing leaks. However, there is a problem that when the dust or dirt accumulated in the drain pan flows into the drain pipe together with the drain, the throttle is immediately clogged.

本発明は、上記の問題を解決しようとするものであり、水封される前のドレン排出路を通じて排気が外部へ漏れ出ることを防止することのできる潜熱回収型の熱源機およびドレンの中和器を提供することを目的としている。   The present invention is intended to solve the above problem, and a latent heat recovery type heat source device and neutralization of drain capable of preventing exhaust from leaking outside through a drain discharge path before being sealed with water. The purpose is to provide a vessel.

かかる目的を達成するための本発明の要旨とするところは、次の各項の発明に存する。   The gist of the present invention for achieving the object lies in the inventions of the following items.

[1]燃焼部と、
前記燃焼部の排気から顕熱および潜熱を回収する熱交換器と、
前記熱交換器で生じたドレンを回収するドレン回収部と、
前記ドレン回収部で回収されたドレンを外部へ排出するドレン排出路と、
前記ドレン排出路の途中に設けられた水封部と、
前記ドレン排出路の途中であって前記水封部の下流に設けられた貯水部と、
水封が完了して前記水封部から溢れたドレンが前記貯水部に溜まる前から前記貯水部の出口を封鎖すると共に、前記貯水部に溜まったドレンによる所定値以上の水圧で前記封鎖を解除する封鎖部と、
前記水封部の後室側の最高水位時の水面から貯水部に貯まり得る最高水位時の水面までの間の空間を、前記水封部の前室の最高水位時の水面より上流側の前記ドレン排出路に連通させる連通部と、
を有する
ことを特徴とする潜熱回収型の熱源機。
[1] a combustion part;
A heat exchanger that recovers sensible heat and latent heat from the exhaust of the combustion section;
A drain recovery section for recovering drain generated in the heat exchanger;
A drain discharge path for discharging the drain recovered by the drain recovery unit to the outside;
A water seal provided in the middle of the drain discharge path;
A water storage part provided in the middle of the drain discharge path and downstream of the water seal part,
Before the water sealing is completed and the drain overflowing from the water sealing part is collected in the water storage part, the outlet of the water storage part is blocked, and the sealing is released by a water pressure higher than a predetermined value by the drain accumulated in the water storage part. A blockade to perform,
The space between the water surface at the highest water level on the rear chamber side of the water seal portion and the water surface at the highest water level that can be stored in the water storage portion is the upstream side of the water surface at the highest water level of the front chamber of the water seal portion. A communication part communicating with the drain discharge path;
A latent heat recovery type heat source machine characterized by comprising:

上記発明および下記[5]に記載の発明では、水封部が水封されていない状態のままで設置後に熱源機の運転が開始されても、水封部の下流に設けた貯水部の出口を封鎖部が封鎖しているので、排気がドレン排出路を通じて外部へ流出することが阻止される。また、水封完了後は、水封部から溢れ出たドレンが貯水部に貯まるとその水圧で封鎖部30による封鎖が自動的に解除されるので、ドレン排出路を通じたドレンの排水が確保される。   In the above-described invention and the invention described in [5] below, even if the operation of the heat source unit is started after installation without installing the water seal portion, the outlet of the water storage portion provided downstream of the water seal portion Since the sealing part is blocking, exhaust is prevented from flowing out through the drain discharge path. In addition, after the water sealing is completed, when drain overflowing from the water sealing part is stored in the water storage part, the sealing by the sealing part 30 is automatically released by the water pressure, so that drain drainage through the drain discharge passage is secured. The

[2]前記水封部は、中和剤が入れられて、前記ドレンを中和する中和器の機能を果たす
ことを特徴とする[1]に記載の潜熱回収型の熱源機。
[2] The latent heat recovery type heat source device according to [1], wherein the water seal portion functions as a neutralizer in which a neutralizer is inserted to neutralize the drain.

上記発明および下記[5]に記載の発明では、水封部は中和器の機能を兼ねる。   In the above invention and the invention described in [5] below, the water seal portion also functions as a neutralizer.

[3]前記所定値は、前記燃焼部での排気圧力の最大値に室内負圧を加算した圧力より大きく、かつ、前記貯水部の最大水位での水頭圧未満である
ことを特徴とする[1]または[2]に記載の潜熱回収型の熱源機。
[3] The predetermined value is larger than a pressure obtained by adding an indoor negative pressure to a maximum value of the exhaust pressure in the combustion section, and less than a water head pressure at the maximum water level in the water storage section. The latent heat recovery type heat source machine according to [1] or [2].

上記発明および下記[6]に記載の発明では、排気圧力に室内のドアの開け閉め等による負圧が加わった場合でも封鎖状態が維持されると共に、貯水部が満水になる前に封鎖が解除される。   In the above invention and the invention described in [6] below, the sealed state is maintained even when negative pressure is applied to the exhaust pressure due to opening / closing of an indoor door, etc., and the blockage is released before the water storage part becomes full. Is done.

[4]前記封鎖部は、閉じるように付勢された、繰り返し開閉可能な開閉弁である
ことを特徴とする[1]乃至[3]のいずれか1つに記載の潜熱回収型の熱源機。
[4] The latent heat recovery type heat source device according to any one of [1] to [3], wherein the blocking portion is an on-off valve that is urged to be closed and can be repeatedly opened and closed. .

上記発明および下記[7]に記載の発明では、封鎖部が繰り返し開閉する構造なので、設置後の最初の運転におけるドレン排出路からの排ガス漏れのほか、凍結予防のために水抜きをした後の運転においてもドレン排出路からの排ガス漏れを防止することができる。   In the above-mentioned invention and the invention described in [7] below, since the blocking portion is repeatedly opened and closed, the exhaust gas leaks from the drain discharge passage in the first operation after installation, and after draining for freezing prevention. Even in operation, exhaust gas leakage from the drain discharge path can be prevented.

[5]燃焼部と、前記燃焼部の排気から顕熱および潜熱を回収する熱交換器と、前記熱交換器で生じたドレンを回収するドレン回収部と、前記ドレン回収部で回収されたドレンを外部へ排出するドレン排出路とを備えた潜熱回収型の熱源機の前記ドレン排出路に介装される中和器であって、
中和剤が入れられる水封部と、
前記水封部から溢れたドレンを貯水する貯水部と、
水封が完了して前記水封部から溢れたドレンが前記貯水部に溜まる前から前記貯水部の出口を封鎖すると共に、前記貯水部に溜まったドレンによる所定値以上の水圧で前記封鎖を解除する封鎖部と、
前記水封部の後室側の最高水位時の水面から貯水部に貯まり得る最高水位時の水面までの間の空間を、前記水封部の前室の最高水位時の水面より上流側の前記ドレン排出路に連通させる連通部と、
を有する
ことを特徴とする中和器。
[5] A combustion part, a heat exchanger that recovers sensible heat and latent heat from the exhaust gas of the combustion part, a drain recovery part that recovers drain generated in the heat exchanger, and a drain recovered by the drain recovery part A neutralizer that is interposed in the drain discharge path of the latent heat recovery type heat source device including a drain discharge path that discharges to the outside,
A water seal portion into which a neutralizing agent is placed;
A water storage part for storing drainage overflowing from the water seal part;
Before the water sealing is completed and the drain overflowing from the water sealing part is collected in the water storage part, the outlet of the water storage part is blocked, and the sealing is released by a water pressure higher than a predetermined value by the drain accumulated in the water storage part. A blockade to perform,
The space between the water surface at the highest water level on the rear chamber side of the water seal portion and the water surface at the highest water level that can be stored in the water storage portion is the upstream side of the water surface at the highest water level of the front chamber of the water seal portion. A communication part communicating with the drain discharge path;
The neutralizer characterized by having.

[6]前記所定値は、前記燃焼部での排気圧力の最大値に室内負圧を加算した圧力より大きく、かつ、前記貯水部の最大水位での水頭圧未満である
ことを特徴とする[5]に記載の中和器。
[6] The predetermined value is larger than a pressure obtained by adding an indoor negative pressure to a maximum value of the exhaust pressure in the combustion section, and less than a water head pressure at the maximum water level in the water storage section. 5].

[7]前記封鎖部は、閉じるように付勢された、繰り返し開閉可能な開閉弁である
ことを特徴とする[5]または[6]に記載の中和器。
[7] The neutralizer according to [5] or [6], wherein the blocking portion is an on-off valve that is urged to be closed and can be repeatedly opened and closed.

本発明に係る潜熱回収型の熱源機および中和器によれば、水封される前のドレン排出路を通じて排気が外部へ漏れ出ることを防止できると共に、水封完了後は自動的に封鎖が解除されてドレンの排水が確保される。   According to the latent heat recovery type heat source device and neutralizer according to the present invention, it is possible to prevent the exhaust from leaking to the outside through the drain discharge passage before being sealed with water, and the sealing is automatically performed after the water sealing is completed. It is released and drainage is secured.

本発明の実施の形態に係る熱源機の概略の構成を示す図である。It is a figure showing the composition of the outline of the heat source machine concerning an embodiment of the invention. 中和器の構成を示す図である。It is a figure which shows the structure of a neutralizer. 工場から出荷された熱源機を設置して最初に運転した際の中和器の状態変化を示す図である。It is a figure which shows the state change of the neutralizer at the time of installing the heat-source equipment shipped from the factory and operating for the first time. 水封部の後室側の容器の上部に通気用細孔を設けた中和器の例を示す図である。It is a figure which shows the example of the neutralizer which provided the pore for ventilation | gas_flowing in the upper part of the container of the back chamber side of a water seal part. 水封部の仕切り板に前室と後室とを連通させる通気用細孔を設けた中和器の例を示す図である。It is a figure which shows the example of the neutralizer which provided the pore for ventilation | gas_flowing which connects a front chamber and a back chamber in the partition plate of a water seal part.

以下、図面に基づき本発明の実施の形態を説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

図1は、本発明の実施の形態に係る熱源機3の概略の構成を示している。熱源機3は、給水を加熱して出湯する給湯機能を備えている。熱源機3は、燃焼ガスを燃焼させるバーナー4と、バーナー4へ空気を送り込む燃焼ファン5と、バーナー4の上方に設置されてバーナー4で加熱された空気(燃焼排気)から主に顕熱を回収して給水を加熱する顕熱熱交換器6と、バーナー4からの空気の流れで顕熱熱交換器6の下流に配置され、主として排気の潜熱を回収して給水を加熱する潜熱熱交換器7を有する。   FIG. 1 shows a schematic configuration of a heat source device 3 according to an embodiment of the present invention. The heat source unit 3 has a hot water supply function of heating the supplied water and discharging it. The heat source unit 3 mainly generates sensible heat from a burner 4 that burns combustion gas, a combustion fan 5 that sends air to the burner 4, and air (combustion exhaust) that is installed above the burner 4 and heated by the burner 4. A sensible heat exchanger 6 that collects and heats the feed water, and a latent heat heat exchanger that is arranged downstream of the sensible heat exchanger 6 by the air flow from the burner 4 and mainly collects the latent heat of the exhaust to heat the feed water. A container 7 is provided.

熱源機3の内部にはさらに、上記のバーナー4、顕熱熱交換器6、潜熱熱交換器7を下からこの順に並べて収めた燃焼室8と、燃焼室8の上端に連通した排気筒9が設けてある。   The heat source unit 3 further includes a combustion chamber 8 in which the burner 4, the sensible heat exchanger 6, and the latent heat exchanger 7 are arranged in this order from the bottom, and an exhaust pipe 9 communicating with the upper end of the combustion chamber 8. Is provided.

潜熱熱交換器7の下方には、排気の潜熱を回収することで生じた酸性の凝縮水(ドレン)を受け止めて回収するための受け皿11が設けてある。また、排気筒9の出口近傍の底部には、ドレン回収口12が設けてある。ドレン回収部(受け皿11およびドレン回収口12)で回収されたドレンはドレン排出管13を通じて排水される。このドレン排出管13の途中には水封機能とドレンを中和する機能とを備えた中和器20が設けてある。中和器20の出口28には、該出口28を封鎖すると共に、所定以上の水圧で封鎖を解除する封鎖部30が取り付けてある。なお、工場出荷時は、中和器20の内部はドレンがなく乾燥した状態にされている。   Below the latent heat exchanger 7, a tray 11 is provided for receiving and collecting acidic condensed water (drain) generated by collecting the latent heat of the exhaust. A drain recovery port 12 is provided at the bottom near the outlet of the exhaust tube 9. The drain recovered by the drain recovery unit (the tray 11 and the drain recovery port 12) is drained through the drain discharge pipe 13. A neutralizer 20 having a water sealing function and a function of neutralizing the drain is provided in the middle of the drain discharge pipe 13. The outlet 28 of the neutralizer 20 is provided with a sealing portion 30 that seals the outlet 28 and releases the sealing with a predetermined or higher water pressure. In addition, at the time of factory shipment, the inside of the neutralizer 20 is in a dry state without drain.

図2は、中和器20の構成をより詳細に示している。中和器20は、水封機能を果たす水封部21(図2のグレー部分)と、水封部21の流出口22に連通した貯水部23とから構成される。水封部21は、中空の容器を、下部が連通するように仕切り板24で2室(前室25と後室26)に区切った構造をなしている。   FIG. 2 shows the configuration of the neutralizer 20 in more detail. The neutralizer 20 includes a water seal portion 21 (gray portion in FIG. 2) that performs a water seal function, and a water storage portion 23 that communicates with the outlet 22 of the water seal portion 21. The water seal portion 21 has a structure in which a hollow container is divided into two chambers (a front chamber 25 and a rear chamber 26) by a partition plate 24 so that the lower portion communicates therewith.

前室25の上部には、中和器20より上流側のドレン排出管13aからドレンを受け入れるドレン入口27が設けてある。ドレン入口27には、ドレン排出管13aの終端が接続される。後室26の上部には中和したドレンを排出する前述の流出口22が設けてある。この流出口22に連通する貯水部23は、流出口22から水封部21に沿って下方へ所定長だけ延設された中空筒状の縦長の容器を成すと共に、その下端には出口28が設けられている。この出口28には前述した封鎖部30の入り側が接続され、封鎖部30の出側には中和器20より下流側のドレン排出管13bの始端が接続される。   A drain inlet 27 that receives drain from a drain discharge pipe 13 a upstream of the neutralizer 20 is provided in the upper portion of the front chamber 25. The drain inlet 27 is connected to the end of the drain discharge pipe 13a. In the upper part of the rear chamber 26, the aforementioned outlet 22 for discharging the neutralized drain is provided. The water storage portion 23 communicating with the outlet 22 is a hollow cylindrical vertically long container extending downward from the outlet 22 along the water seal portion 21 by a predetermined length, and an outlet 28 is formed at the lower end thereof. Is provided. The outlet 28 is connected to the entrance side of the above-described blocking portion 30, and the outlet side of the blocking portion 30 is connected to the start end of the drain discharge pipe 13 b on the downstream side of the neutralizer 20.

封鎖部30は、貯水部23の出口28を封鎖すると共に、出口28側から所定値(開弁圧力)以上の水圧が加わると封鎖を解除するように構成されている。図2に示す封鎖部30は、出口28を封鎖する弁体31と、弁体31を出口28に押圧するように付勢する弾性体としてのバネ32で構成される。   The blocking unit 30 is configured to block the outlet 28 of the water storage unit 23 and to release the blocking when a water pressure equal to or higher than a predetermined value (valve opening pressure) is applied from the outlet 28 side. 2 includes a valve body 31 that seals the outlet 28 and a spring 32 as an elastic body that biases the valve body 31 so as to press the outlet 31 against the outlet 28.

弁体31は出口28に当接する面がゴムなどの弾性体で形成された平板状の部材である。弁体31は、出口28の脇に一端が回動可能に軸支されており、出口28に平らな部分を当接させて出口28を封鎖する閉位置と、該閉位置から下方へ略90度回動した開位置とに変位する。バネ32は、弁体31を支持する軸と同軸に設けられたねじりバネなどで構成され、弁体31を閉位置に向けて付勢する。   The valve body 31 is a flat plate member whose surface that contacts the outlet 28 is formed of an elastic body such as rubber. One end of the valve body 31 is pivotally supported on the side of the outlet 28, and a closed position in which a flat portion is brought into contact with the outlet 28 to seal the outlet 28, and approximately 90 downward from the closed position. It is displaced to the open position that has been rotated. The spring 32 is configured by a torsion spring or the like provided coaxially with the shaft that supports the valve body 31, and biases the valve body 31 toward the closed position.

封鎖部30の弁体31の開弁圧力は、バーナー4からドレン排出管13等を経由して封鎖部30へ到達する排気の圧力の最大値に室内負圧を加算した圧力より大きく、かつ、貯水部23の最大水位での水頭圧未満にされる。   The valve opening pressure of the valve body 31 of the blocking part 30 is larger than the pressure obtained by adding the indoor negative pressure to the maximum value of the exhaust pressure reaching the sealing part 30 from the burner 4 via the drain discharge pipe 13 and the like, and It is made less than the water head pressure at the maximum water level of the water reservoir 23.

たとえば、封鎖部30の弁体31の開弁圧力の下限は、封鎖部30に到達する排気圧力の最大値(約20mmH2O)に室内負圧(たとえば、ドアの開け閉めによる負圧で、約−20mmH2Oと想定される)を考慮して、20〜50mmH2O程度に設定する(室内負圧を加算した40mmH2O以上が好ましい)。また、開弁圧力の上限は貯水部23の最大水位での水頭圧より低い値に設定する。たとえば、貯水部23の最大水位での水頭圧が120mmH2Oの場合、一定の余裕を見て、開弁圧力の上限は100mmH2O程度に設定する。 For example, the lower limit of the valve opening pressure of the valve body 31 of the blocking portion 30 is the maximum value of exhaust pressure reaching the blocking portion 30 (about 20 mmH 2 O), which is a negative pressure caused by opening and closing the door, taking into account the approximately -20MmH 2 O and is assumed) is set to 2 O about 20~50MmH (preferably 40MmH 2 O or more obtained by adding the room negative pressure). Further, the upper limit of the valve opening pressure is set to a value lower than the water head pressure at the maximum water level of the water reservoir 23. For example, when the water head pressure at the maximum water level of the water storage unit 23 is 120 mmH 2 O, the upper limit of the valve opening pressure is set to about 100 mmH 2 O with a certain margin.

水封部21の流出口22はドレン入口27より低い位置にされている。また、貯水部23は水封部21の流出口22より低くされており、流出口22から貯水部23の下端の出口28までの落差は、封鎖部30の開弁圧力より大きな水頭圧が得られるように設定される。   The outlet 22 of the water seal portion 21 is set at a position lower than the drain inlet 27. Moreover, the water storage part 23 is made lower than the outflow port 22 of the water sealing part 21, and the drop from the outflow port 22 to the outlet 28 at the lower end of the water storage part 23 gives a water head pressure larger than the valve opening pressure of the sealing part 30. To be set.

水封部21の前室25および後室26には、凝縮水(ドレン)を中和するための中和剤29が装填されている。中和剤29は、炭酸カルシウムなどであり、直径1cmほどの豆粒大の粒状を成している。ドレン入口27から流入したドレンは、水封部21の前室25および後室26に装填された多数の粒状の中和剤29の隙間を通る際に中和される。   The front chamber 25 and the rear chamber 26 of the water seal portion 21 are loaded with a neutralizing agent 29 for neutralizing condensed water (drain). The neutralizing agent 29 is calcium carbonate or the like, and has a bean-sized size of about 1 cm in diameter. The drain that has flowed in from the drain inlet 27 is neutralized when passing through the gaps between a number of granular neutralizing agents 29 loaded in the front chamber 25 and the rear chamber 26 of the water seal portion 21.

次に、封鎖部30の作用について説明する。   Next, the effect | action of the blocking part 30 is demonstrated.

図3は、工場から出荷された熱源機3を設置して最初に運転した際の中和器20および封鎖部30の状態変化を示している。   FIG. 3 shows changes in the state of the neutralizer 20 and the blocking unit 30 when the heat source device 3 shipped from the factory is installed and operated for the first time.

工場出荷時は、図3(a)に示すように、中和器20の内部は、ドレンが空で乾燥した状態にされている。この状態で運転を開始すると、排気の一部がドレン排出管13aを通じて中和器20側へ流れ込もうとするが、中和器20の出口が封鎖部30で封鎖されているので、流れ込みはほとんどなく、かつまた、ドレン排出管13bを通じて外部へ排気が流出することも阻止される。なお、封鎖部30で封鎖していなければ、排気の一部がドレン排出管13を通じて外部へ流出してしまい、背景技術の項で説明したような不具合を生じさせる。図3(a)の破線は、封鎖部30を設けない場合の排気の流れを示している。   At the time of shipment from the factory, as shown in FIG. 3A, the inside of the neutralizer 20 is in a state where the drain is empty and dried. When the operation is started in this state, a part of the exhaust gas tries to flow into the neutralizer 20 side through the drain discharge pipe 13a. However, since the outlet of the neutralizer 20 is blocked by the blocking portion 30, Almost no exhaust gas is also prevented from flowing out through the drain discharge pipe 13b. If the block 30 is not sealed, a part of the exhaust gas flows out to the outside through the drain discharge pipe 13 and causes a problem as described in the background art section. The broken line in FIG. 3A indicates the flow of exhaust when the blocking portion 30 is not provided.

熱源機3の運転を継続すると、ドレンが中和器20の水封部21に貯まりはじめる。そして、図3(b)に示すように、中和器20の水封部21内の水位が上昇して水封部21がドレンによって水封された状態になると、以後は、この水封によって排気がドレン排出管13を通じて外部へ流出することが阻止される。   When the operation of the heat source device 3 is continued, the drain begins to accumulate in the water seal portion 21 of the neutralizer 20. And as shown in FIG.3 (b), when the water level in the water seal part 21 of the neutralizer 20 rises and the water seal part 21 is in a state sealed with drainage, the water seal is thereafter used. Exhaust gas is prevented from flowing out through the drain discharge pipe 13.

その後さらに運転を続けてドレンが中和器20へ流入し続けると、図3(c)に示すように、水封部21の流出口22からドレンが溢れて貯水部23へ流出し、貯水部23に貯水される。さらに運転を続けると、貯水部23内の水位が上昇し、水頭圧が封鎖部30の弁体31の開弁圧力を超えると、図3(d)に示すように、弁体31が開位置に変位して封鎖部30による出口28の封鎖が解除される。これにより、貯水部23に貯まっていたドレンがドレン排出管13bを通じて外部へ排出される。   Thereafter, when the operation is further continued and the drain continues to flow into the neutralizer 20, as shown in FIG. 3C, the drain overflows from the outlet 22 of the water seal portion 21 and flows out to the water storage portion 23, and the water storage portion 23 is stored. When the operation is further continued, when the water level in the water storage section 23 rises and the water head pressure exceeds the valve opening pressure of the valve body 31 of the blocking section 30, the valve body 31 is opened as shown in FIG. And the blocking of the outlet 28 by the blocking portion 30 is released. Thereby, the drain stored in the water storage unit 23 is discharged to the outside through the drain discharge pipe 13b.

貯水部23に貯まっていたドレンが排出されると、弁体31はバネ32に付勢されて再び閉位置に戻って出口28を封鎖する。その後は、貯水部23内の水位が上昇し、その水頭圧が弁体31の開弁圧力を超えると弁体31が開き、貯水部23に貯まっていたドレンが排出され、ドレンが排出されると弁体31が閉じる、という動作が繰り返し行われる。   When the drain accumulated in the water storage section 23 is discharged, the valve body 31 is urged by the spring 32 and returns to the closed position again to block the outlet 28. Thereafter, when the water level in the water storage section 23 rises and the water head pressure exceeds the valve opening pressure of the valve body 31, the valve body 31 opens, drainage stored in the water storage section 23 is discharged, and drainage is discharged. The operation of closing the valve body 31 is repeated.

このように、工場出荷後に設置されて、中和器20が水封されていない状態のままで熱源機3の運転が開始されても、封鎖部30での封鎖により、排気がドレン排出管13を通じて外部へ流出することが阻止される。また、水封完了後に中和器20から溢れて貯水部23に貯まったドレンの水圧が開弁圧力を超えると封鎖部30の弁体31が開いて封鎖が自動的に解除されるので、ドレン排出管13を通じたドレンの排水が確保される。   As described above, even if the operation of the heat source unit 3 is started after the factory is shipped and the neutralizer 20 is not sealed with water, the exhaust is drained by the blockade at the block 30. Through the outside is prevented. Further, when the water pressure of the drain overflowing from the neutralizer 20 after completion of water sealing and stored in the water storage part 23 exceeds the valve opening pressure, the valve body 31 of the sealing part 30 is opened and the sealing is automatically released. Drain drainage through the discharge pipe 13 is ensured.

したがって、設置後の運転開始前に作業者が中和器に水を入れて水封状態を確保する、といった作業が不要になる。また、作業者に手動で水を入れさせる場合には、中和器に水位センサを設け、水封完了前の運転を禁止したり、水の入れ忘れを警告したりする等の対策を講じるべきであるが、本実施の形態の熱源機3では封鎖部30を取り付けることで、そのような対策も一切不要になる。あるいは、給水管から分岐させた注水配管を中和器に接続し、該注水配管の途中に設けた電磁弁を開くことで中和器へ自動的に注水する、といった構成も不要になる。   Therefore, the operation | work which an operator puts water into a neutralizer and ensures a water seal state before the operation | movement start after installation becomes unnecessary. In addition, when the operator manually puts water, a water level sensor should be installed in the neutralizer to take measures such as prohibiting operation before the completion of water sealing and warning that water has been forgotten. However, in the heat source device 3 according to the present embodiment, such a countermeasure is not required at all by attaching the blocking portion 30. Or the structure which connects the water injection piping branched from the water supply pipe to the neutralizer, and automatically injects water to the neutralizer by opening the electromagnetic valve provided in the middle of the water injection piping becomes unnecessary.

なお、図3(b)に示す状態(水封完了時)から図3(c)に示す状態へと水封部21内のドレンの水位が上昇すると、出側(後室26側)のドレンの水面から封鎖部30(あるいは貯水部23に貯まったドレンの水面)に至るまでの空間の容積が次第に減少して内圧が上昇する。内圧が過度に上昇すると、それ以上、水位が上昇しなくなってしまう。   When the drain level in the water seal 21 rises from the state shown in FIG. 3B (when the water seal is completed) to the state shown in FIG. 3C, the drain on the outlet side (rear chamber 26 side) The volume of the space from the water surface to the blocking part 30 (or the water surface of the drain stored in the water storage part 23) gradually decreases and the internal pressure increases. If the internal pressure rises excessively, the water level will no longer rise.

そこで、水封部21の後室26側の最高水位時の水面から貯水部23に貯まり得る最高水位時の水面までの間の空間を形成する部分の容器を、僅かに通気性が確保されるように、完全な気密に構成しないようにしている。たとえば、上記部分の容器が気密にならないように隙間を設けたり、通気用の細孔を設けたりする。なお、水封部21の後室26側の最高水位時の水面より低い箇所や貯水部23の最高水位時の水面より低い箇所に通気用の細孔や隙間を設けると、その部分からドレンが漏れ出たり、通気用の細孔より水位が高くなると空気を逃がすことができなくなったりする。   Therefore, a slight air permeability is ensured in the container of the portion forming the space from the water surface at the highest water level on the rear chamber 26 side of the water seal portion 21 to the water surface at the highest water level that can be stored in the water storage portion 23. So that it is not completely airtight. For example, a gap is provided so that the container in the above portion does not become airtight, or pores for ventilation are provided. In addition, if ventilation pores or gaps are provided at a location lower than the water surface at the highest water level on the rear chamber 26 side of the water seal portion 21 or a location lower than the water surface at the highest water level of the water storage portion 23, drainage is generated from that portion. If it leaks out or the water level becomes higher than the ventilation pores, the air cannot escape.

図4は、水封部21の後室26側の容器の上部に通気用細孔44を設けた例を示している。この通気用細孔44は熱源機3の本体内に開口されている。水封完了前の熱源機3の運転中は、通気用細孔44を通じて、極めて僅かであるが、排ガスが外部へ漏れることになる。そこで、図4に示すような位置に通気用細孔44を設ける場合は、熱源機3は屋外設置式であることが望ましい。また、通気用細孔44は熱源機3の本体内に開口されているので、たとえば、熱源機3がパイプシャフトに設けられた場合でも、通気用細孔44からの排ガスが直接、パイプシャフト内に流れ出ないので、パイプシャフト内のガス管等を腐食させることがない。   FIG. 4 shows an example in which vent holes 44 are provided in the upper part of the container on the rear chamber 26 side of the water seal portion 21. The ventilation pores 44 are opened in the main body of the heat source unit 3. During the operation of the heat source unit 3 before completion of water sealing, the exhaust gas leaks to the outside through the ventilation pores 44, though very little. Therefore, when the ventilation pores 44 are provided at positions as shown in FIG. 4, it is desirable that the heat source device 3 is an outdoor installation type. Further, since the ventilation pores 44 are opened in the main body of the heat source unit 3, for example, even when the heat source unit 3 is provided on the pipe shaft, the exhaust gas from the ventilation pores 44 directly flows into the pipe shaft. Therefore, gas pipes in the pipe shaft are not corroded.

一方、熱源機3が屋内設置式の場合には、通気用細孔44を通じて、排ガスが室内に僅かでも漏れないようにすることが望ましい。そこで、通気用細孔44を熱源機3の排気経路に開放する。たとえば、図5に示すように、最高水位より高い位置の仕切り板24に前室25と後室26とを連通させる通気用細孔45を形成すると、通気用細孔45を通じた排ガスの出口が排気経路に開放されることになる。この構成では、水封完了前の熱源機3の運転中に排ガスが外部に漏れ出ることはない。また、水封完了後は、中和器20内の水位が上昇する際に後室26内の空気が通気用細孔45を通じて前室25側へ移動し、ドレン排出管13aおよび排気筒9を通じて外部へ排出される。   On the other hand, when the heat source device 3 is of an indoor installation type, it is desirable that even a slight amount of exhaust gas does not leak into the room through the ventilation pores 44. Therefore, the ventilation pores 44 are opened to the exhaust path of the heat source unit 3. For example, as shown in FIG. 5, when vent holes 45 for communicating the front chamber 25 and the rear chamber 26 are formed in the partition plate 24 at a position higher than the maximum water level, the outlet of the exhaust gas through the vent holes 45 is formed. It will be opened to the exhaust path. In this configuration, the exhaust gas does not leak to the outside during the operation of the heat source unit 3 before completion of water sealing. Further, after the water sealing is completed, when the water level in the neutralizer 20 rises, the air in the rear chamber 26 moves to the front chamber 25 side through the ventilation pores 45, and passes through the drain discharge pipe 13 a and the exhaust tube 9. It is discharged outside.

なお、仕切り板24に通気用細孔45を設ける代わりに、たとえば、図4の通気用細孔44を設け、該通気用細孔44の出口を管等でドレン入口27あるいはドレン排出管13aに連通させるようにしてもよい。   Instead of providing the ventilation pore 45 in the partition plate 24, for example, the ventilation pore 44 of FIG. 4 is provided, and the outlet of the ventilation pore 44 is connected to the drain inlet 27 or the drain discharge pipe 13a with a pipe or the like. You may make it communicate.

以上のように、本実施の形態の熱源機3では、水封部21の下流に設けた貯水部23の出口に、該出口を封鎖すると共に所定値以上の水圧で封鎖を解除する封鎖部30を取り付けたので、水封部21が水封される前の運転でドレン排出管13を通じて排気が外部へ漏れ出ることが防止される。また、水封完了後は、水封部21から溢れ出たドレンが貯水部23に一定以上貯まるとその水圧で封鎖部30の封鎖が自動的に解除されるので、中和器20から溢れるドレンを、ドレン排出管13bを通じて円滑に排出することができる。   As described above, in the heat source device 3 according to the present embodiment, the outlet 30 is closed at the outlet of the water reservoir 23 provided downstream of the water seal 21 and the seal 30 is released with water pressure equal to or higher than a predetermined value. Therefore, the exhaust gas is prevented from leaking outside through the drain discharge pipe 13 in the operation before the water seal portion 21 is sealed with water. Further, after completion of the water sealing, if the drain overflowing from the water sealing part 21 is stored in the water storage part 23 more than a certain amount, the sealing of the sealing part 30 is automatically released by the water pressure, so the drain overflowing from the neutralizer 20 Can be smoothly discharged through the drain discharge pipe 13b.

以上、本発明の実施の形態を図面によって説明してきたが、具体的な構成は実施の形態に示したものに限られるものではなく、本発明の要旨を逸脱しない範囲における変更や追加があっても本発明に含まれる。   The embodiment of the present invention has been described with reference to the drawings. However, the specific configuration is not limited to that shown in the embodiment, and there are changes and additions within the scope of the present invention. Are also included in the present invention.

実施の形態で示した封鎖部30は例示であり、貯水部23の出口28を封鎖すると共に、所定値以上の水圧で封鎖を解除する機能を果たせば他の構成であってもよい。たとえば、実施の形態では、封鎖部30を繰り返し開閉可能な開閉弁としたが、1度、封鎖を解除したら、再度、封鎖状態に戻らない構成であってもよい。たとえば、所定以上の水圧がかかると封鎖部30の一部が、折れる、破れるなどで破壊されて封鎖が解除される構成であってもかまわない。   The block 30 shown in the embodiment is an example, and other configurations may be used as long as the outlet 28 of the water storage unit 23 is blocked and the function of releasing the block with a water pressure equal to or higher than a predetermined value is achieved. For example, in the embodiment, the blocking portion 30 is an on-off valve that can be repeatedly opened and closed. However, once the blocking is released, a configuration that does not return to the blocking state again may be used. For example, when a predetermined or higher water pressure is applied, a part of the blocking part 30 may be broken and broken to be released and the blocking may be released.

なお、凍結予防の水抜きを考慮すると、封鎖部30は、繰り返し開閉可能に構成することが好ましい。すなわち、凍結予防のために中和器20内のドレンが排出されると、工場出荷時と同様に中和器20の水封部21は水封されていない状態になるので、水抜き後の運転時にドレン排出管13から排気が漏れるのを防ぐには、水抜きされた状態で封鎖部30が再び封鎖状態に戻ることが好ましい。   In consideration of freezing for freezing prevention, it is preferable that the blocking portion 30 is configured to be able to be repeatedly opened and closed. That is, when the drain in the neutralizer 20 is discharged to prevent freezing, the water seal portion 21 of the neutralizer 20 is not sealed in the same manner as at the time of factory shipment. In order to prevent the exhaust from leaking from the drain discharge pipe 13 during operation, it is preferable that the blocking portion 30 returns to the blocking state again after draining.

実施の形態では水封部21に中和剤29を入れて、水封部21を中和器20として兼用するようにしたが、ドレンを中和する中和器と水封部を別々に設けてもかまわない。   In the embodiment, the neutralizing agent 29 is added to the water sealing portion 21 so that the water sealing portion 21 is also used as the neutralizer 20. However, a neutralizer and a water sealing portion for neutralizing the drain are provided separately. It doesn't matter.

実施の形態では、水封部21と貯水部23とを一体とした中和器20を例示したが、水封部21の下流であれば、水封部21からある程度離れた場所に貯水部23が設けられてもよい。なお、貯水部23は水封部21の流出口22より下方に位置するように設けられる。   In the embodiment, the neutralizer 20 in which the water sealing part 21 and the water storage part 23 are integrated is illustrated. However, if the water sealing part 21 is downstream of the water sealing part 21, the water storage part 23 is located some distance away from the water sealing part 21. May be provided. In addition, the water storage part 23 is provided so that it may be located below the outflow port 22 of the water seal part 21.

本発明は、水封部21と貯水部23と該貯水部23の出口28に取り付けた封鎖部30とを含む中和器として構成されてもよい。   The present invention may be configured as a neutralizer including the water sealing part 21, the water storage part 23, and the sealing part 30 attached to the outlet 28 of the water storage part 23.

熱源機3は、給湯機に限定されず暖房機や乾燥機などでもよい。   The heat source unit 3 is not limited to a water heater, and may be a heater or a dryer.

3…熱源機
4…バーナー
5…ファン
6…顕熱熱交換器
7…潜熱熱交換器
8…燃焼室
9…排気筒
11…受け皿
12…ドレン回収口
13、13a、13b…ドレン排出管
20…中和器
21…水封部
22…流出口
23…貯水部
24…仕切り板
25…前室
26…後室
27…ドレン入口
28…出口
29…中和剤
30…封鎖部
31…弁体
32…バネ
44…通気用細孔
45…通気用細孔
DESCRIPTION OF SYMBOLS 3 ... Heat source machine 4 ... Burner 5 ... Fan 6 ... Sensible heat exchanger 7 ... Latent heat exchanger 8 ... Combustion chamber 9 ... Exhaust tube 11 ... Sauce tray 12 ... Drain collection port 13, 13a, 13b ... Drain discharge pipe 20 ... Neutralizer 21 ... Water sealing part 22 ... Outlet 23 ... Water storage part 24 ... Partition plate 25 ... Front chamber 26 ... Rear chamber 27 ... Drain inlet 28 ... Outlet 29 ... Neutralizing agent 30 ... Sealing part 31 ... Valve 32 ... Spring 44 ... Ventilation pore 45 ... Ventilation pore

Claims (7)

燃焼部と、
前記燃焼部の排気から顕熱および潜熱を回収する熱交換器と、
前記熱交換器で生じたドレンを回収するドレン回収部と、
前記ドレン回収部で回収されたドレンを外部へ排出するドレン排出路と、
前記ドレン排出路の途中に設けられた水封部と、
前記ドレン排出路の途中であって前記水封部の下流に設けられた貯水部と、
水封が完了して前記水封部から溢れたドレンが前記貯水部に溜まる前から前記貯水部の出口を封鎖すると共に、前記貯水部に溜まったドレンによる所定値以上の水圧で前記封鎖を解除する封鎖部と、
前記水封部の後室側の最高水位時の水面から貯水部に貯まり得る最高水位時の水面までの間の空間を、前記水封部の前室の最高水位時の水面より上流側の前記ドレン排出路に連通させる連通部と、
を有する
ことを特徴とする潜熱回収型の熱源機。
A combustion section;
A heat exchanger that recovers sensible heat and latent heat from the exhaust of the combustion section;
A drain recovery section for recovering drain generated in the heat exchanger;
A drain discharge path for discharging the drain recovered by the drain recovery unit to the outside;
A water seal provided in the middle of the drain discharge path;
A water storage part provided in the middle of the drain discharge path and downstream of the water seal part,
Before the water sealing is completed and the drain overflowing from the water sealing part is collected in the water storage part, the outlet of the water storage part is blocked, and the sealing is released by a water pressure higher than a predetermined value by the drain accumulated in the water storage part. A blockade to perform,
The space between the water surface at the highest water level on the rear chamber side of the water seal portion and the water surface at the highest water level that can be stored in the water storage portion is the upstream side of the water surface at the highest water level of the front chamber of the water seal portion. A communication part communicating with the drain discharge path;
A latent heat recovery type heat source machine characterized by comprising:
前記水封部は、中和剤が入れられて、前記ドレンを中和する中和器の機能を果たす
ことを特徴とする請求項1に記載の潜熱回収型の熱源機。
The latent heat recovery type heat source device according to claim 1, wherein the water seal portion functions as a neutralizer in which a neutralizer is placed to neutralize the drain.
前記所定値は、前記燃焼部での排気圧力の最大値に室内負圧を加算した圧力より大きく、かつ、前記貯水部の最大水位での水頭圧未満である
ことを特徴とする請求項1または2に記載の潜熱回収型の熱源機。
The predetermined value is greater than a pressure obtained by adding an indoor negative pressure to a maximum value of an exhaust pressure in the combustion section, and less than a water head pressure at a maximum water level in the water storage section. The latent heat recovery type heat source machine according to 2.
前記封鎖部は、閉じるように付勢された、繰り返し開閉可能な開閉弁である
ことを特徴とする請求項1乃至3のいずれか1つに記載の潜熱回収型の熱源機。
The latent heat recovery type heat source device according to any one of claims 1 to 3, wherein the blocking portion is an on-off valve that is urged to close and can be repeatedly opened and closed.
燃焼部と、前記燃焼部の排気から顕熱および潜熱を回収する熱交換器と、前記熱交換器で生じたドレンを回収するドレン回収部と、前記ドレン回収部で回収されたドレンを外部へ排出するドレン排出路とを備えた潜熱回収型の熱源機の前記ドレン排出路に介装される中和器であって、
中和剤が入れられる水封部と、
前記水封部から溢れたドレンを貯水する貯水部と、
水封が完了して前記水封部から溢れたドレンが前記貯水部に溜まる前から前記貯水部の出口を封鎖すると共に、前記貯水部に溜まったドレンによる所定値以上の水圧で前記封鎖を解除する封鎖部と、
前記水封部の後室側の最高水位時の水面から貯水部に貯まり得る最高水位時の水面までの間の空間を、前記水封部の前室の最高水位時の水面より上流側の前記ドレン排出路に連通させる連通部と、
を有する
ことを特徴とする中和器。
A combustion unit, a heat exchanger that recovers sensible heat and latent heat from the exhaust of the combustion unit, a drain recovery unit that recovers drain generated in the heat exchanger, and the drain recovered by the drain recovery unit to the outside A neutralizer installed in the drain discharge path of a latent heat recovery type heat source device including a drain discharge path for discharging,
A water seal portion into which a neutralizing agent is placed;
A water storage part for storing drainage overflowing from the water seal part;
Before the water sealing is completed and the drain overflowing from the water sealing part is collected in the water storage part, the outlet of the water storage part is blocked, and the sealing is released by a water pressure higher than a predetermined value by the drain accumulated in the water storage part. A blockade to perform,
The space between the water surface at the highest water level on the rear chamber side of the water seal portion and the water surface at the highest water level that can be stored in the water storage portion is the upstream side of the water surface at the highest water level of the front chamber of the water seal portion. A communication part communicating with the drain discharge path;
The neutralizer characterized by having.
前記所定値は、前記燃焼部での排気圧力の最大値に室内負圧を加算した圧力より大きく、かつ、前記貯水部の最大水位での水頭圧未満である
ことを特徴とする請求項5に記載の中和器。
The predetermined value is larger than a pressure obtained by adding an indoor negative pressure to a maximum value of an exhaust pressure in the combustion section and less than a water head pressure at a maximum water level in the water storage section. The neutralizer described.
前記封鎖部は、閉じるように付勢された、繰り返し開閉可能な開閉弁である
ことを特徴とする請求項5または6に記載の中和器。
The neutralizer according to claim 5 or 6, wherein the blocking portion is an on-off valve that is urged to close and can be repeatedly opened and closed.
JP2013060516A 2013-03-22 2013-03-22 Latent heat recovery type heat source machine and neutralizer Expired - Fee Related JP6267431B2 (en)

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