JP6415907B2 - Non-aerosol foamer - Google Patents

Description

  The present invention relates to a hair styling agent in a non-aerosol foamer container.

  Conventionally, various compositions and dosage forms useful for hairdressing agents have been proposed, and examples include mist-like hairdressing agents, foamy hairdressing agents, waxes, gel-like hairdressing agents, and the like. Among these, non-aerosol foam hair styling agents are more environmentally friendly than other dosage forms and aerosol foam hair styling agents because they are easy to use as hair styling agents and do not require a propellant and are environmentally friendly.

  For example, in Patent Document 1, as a composition in which the foam discharged from the non-aerosol foamer container has a fine foam with a fine appearance and does not cause clogging of the pump mesh portion, In addition to surfactants having a polyoxyalkylene chain, it has been proposed to contain glycerin, polyglycerin and / or derivatives thereof.

  On the other hand, it is known that when a hair moisturizing component such as glycerin or polyglycerin is added to the hairdressing agent, the sticky feeling becomes strong. However, Patent Document 2 discloses a water-soluble polymer compound, glycerin and / or a derivative thereof, In addition, a hair cosmetic containing a C5-C10 1,2-alkanediol with a reduced stickiness has been proposed, and a non-aerosol type hair foam is also disclosed.

JP 2002-167315 A JP 2004-155724 A

  The function required for foam hairdressing agents is not only good foam quality at the time of discharge, but also to make the hairstyling agent fully blend into the whole hair, the foam is easy to spread during application, on the other hand, after spreading Must be easy to defoam. However, the foam hair styling agents described in Patent Documents 1 and 2 have good foam quality at the time of discharge, but in terms of both ease of spreading on the hair and ease of defoaming after spreading. It was insufficient.

  In addition, in the hair style that is becoming common in recent years, not only simply binding the hair and fixing it with a binding tool as in the past, but also the touch is natural, and further braiding and binding before and after binding the hair. There is also a strong demand to add arrangements such as twisting or pulling out part of the hair from the bundle.

  However, in the non-aerosol foam hair styling agent described in Patent Document 1 and the hair cosmetic composition described in Patent Document 2, short hair may spill out from the hair bundle collected by the binding tool when trying to make a combined hair style. It was. Furthermore, when trying to add an arrangement such as weaving, the hair bundles are likely to be scattered and it may be difficult to arrange. In addition, the hair after hair styling has been improved in stickiness, but still has a natural feel.

  In addition, when the hair is bound with a binding tool, there is no air flow in the vicinity of the binding part, so there may be a feeling of unpleasant stuffiness in the vicinity of the binding part especially when the humidity is high or when sweating. . In the non-aerosol type foam hair styling agent described in Patent Document 1 and the hair cosmetic composition of Patent Document 2, there is a case where the feeling of stuffiness in the vicinity of the binding portion is strong.

  Therefore, the present invention maintains the foam when applied to the hair and is easy to spread, and after spreading, it is easy to defoam and fits well into the hair. The present invention relates to a non-aerosol foam hair styling agent that does not spill short hair from a bundle, is easy to arrange, such as braiding, has little stuffiness around the knot after hair styling, and has a natural feel.

  The present inventors discharged a hair styling agent containing a film-forming polymer, a specific solvent, and a specific surfactant, and having a ratio of the film-forming polymer and the specific solvent within a certain range from the non-aerosol foamer container. Can be applied evenly from the root of the hair to the tip of the hair, and the entire surface and inside of the hair bundle, and when the hair is bundled, short hair spills out from the hair bundle bundled with a binding tool. In addition, it was found that it is easy to weave after being combined, the feeling of stuffiness in the vicinity of the bundling portion where the hair is combined is reduced, and the touch is also natural.

That is, the present invention includes components (A) to (D), and the mass ratio (A) / (B) of component (A) to component (B) is 0.3 or more and 5 or less. An agent is provided.
(A) A film-forming polymer containing at least one selected from (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylic acid amide, vinyl alcohol, vinyl alkyl ether and vinyl pyrrolidone as a constituent monomer
(B) one or more selected from glycerin, diglycerin, propylene glycol and butylene glycol
(C) one or more selected from cationic surfactants and nonionic surfactants
(D) Water

  Furthermore, the present invention provides a hair styling method in which the above-described hair styling agent is applied to the hair and then the combined hair is made.

  The foam of the non-aerosol foamer container of the present invention has a feature that it is easy to defoam after application to the hair even though it has a firm feel when applied to the hair. Since it is easy to apply and conforms to the hair, it can be applied uniformly from the root of the hair to the end of the hair. In addition, after application, the hair is not sticky, and even when the hair is bundled with a tying tool, short hair does not spill from the hair bundle, it has an appropriate unit, making it easy to make hair, and arranging operations such as braiding and twisting Sometimes hair bundles are difficult to break. Further, after making the hair together, moisture hardly remains in the hair bundle, and the effect of reducing the feeling of stuffiness in the vicinity of the binding portion where the hair is gathered is obtained.

[Component (A): Film-forming polymer containing at least one selected from (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylic acid amide, vinyl alcohol, vinyl alkyl ether and vinyl pyrrolidone) as a constituent monomer]
The film-forming polymer of component (A) is not particularly limited, and any of those having a high setting power to those having a relatively low setting power as commonly used in aerosol hair styling agents are used. can do. Specific examples of such a film-forming polymer include (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymers such as Yuka Former R205, M-75 (Mitsubishi Chemical), and RAM Resin (Osaka Organic Chemical); (Acrylates / Lauryl acrylate / Stealyl acrylate / Ethylamine oxide oxide) Copolymers such as Mer Z-712 (Mitsubishi Chemical Co.); (Acrylates / Stearyl acrylate / Methacrylic) such as Diaformer Z-732 (Mitsubishi Chemical) Acid vinylamine oxide) copolymer; (vinylamine / vinyl alcohol) copolymer such as Diafix C-601 (Mitsubishi Chemical); acrylic resin alkanolamine liquid such as plus size L-9540B (Kohyo Chemical); Ultrahold 8, Strong Acrylic acid such as (above BASF) / Acrylic amide / ethyl acrylate copolymer; Alkyl acrylate / methacrylic acid / silicone copolymer liquid such as Rubyflex Silk (BASF); Polyacrylate-22 such as Ruby Set Shape (BASF); Rubymer 100P, 30E (Above, BASF) alkyl acrylate copolymers, such as Amformers SH-701, 28-4910, LV-71, LV-47 (above, National Starch & Chemical) Acrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymer; (alkyl acrylate / octyl acrylamide) copolymer such as Anformer V-42 (National Starch &Chemical); Resin 28-2930 (National Starch & (VA / Crotonic acid / Vinyl neodecanoate) copolymer; Dynam X (National Star) Polyurethane-14 and AMP-acrylate copolymers such as Gachkat 440, 734 (Ashland), etc .; Polyquaternium-11 such as Guffcut HS-100 (Ashland); Gantrez ES- (Vinyl methyl ether / ethyl maleate) copolymer such as 225 (Ashland); (PVP / vinyl caprolactam / DMAPA acrylic acid) copolymer such as Aquaflex SF-40 (Ashland); Stylee W-20 (Ashland), etc. Polyquaternium-55; (vinyl pyrrolidone / DMAPA DMAPA) copolymer such as Stylize CC-10 (Ashland); (vinyl pyrrolidone / VA) copolymer such as PVP / VA735 (Ashland); Polyvinylpyrrolidone such as 30, 60, 80, 90 (above, BASF), PVP K-15, 30, 60, 90 (above, Ashland) and the like.

  Among the above-mentioned film forming polymers, by combining with the component (B) described later, it is possible to suppress short hair from spilling from the hair bundle when the hair is bundled with a binding tool, and from the viewpoint of giving a natural feel after hair styling, (Methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / lauryl acrylate / stearyl acrylate / ethyl amine oxide oxide) copolymers, (acrylates / stearyl acrylate / ethyl amine methacrylate oxide) copolymers, acrylic resin alkanolamine liquid, Alkyl acrylate / methacrylic acid / silicone copolymer solution, polyacrylate-22, (VA / crotonic acid / vinyl neodecanoate) copolymer, polyurethane-14 / AMP-acrylate copolymer, polyquaternium-11, polyquatani Arm -55, vinylpyrrolidone / acrylic acid DMAPA) copolymers, polyvinyl pyrrolidone are preferred. Among these, methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymers, (acrylates / stearyl acrylate / ethyl methacrylate oxide) copolymers, polyquaternium-11, and polyvinylpyrrolidone are preferable.

  These film-forming polymers can be used in combination of two or more as the component (A), and the content in the hair styling agent of the present invention is not sticky after application, and the hair is collected with a binding tool. From the viewpoint of suppressing the spilling of short hair from the hair bundle and ease of arranging operations such as braiding and twisting, it is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and further preferably 0.5% by mass. % Or more, preferably 5% by mass or less, more preferably 4% by mass or less, still more preferably 3% by mass or less, and further preferably 2% by mass or less.

[Component (B): glycerin, diglycerin, propylene glycol, butylene glycol]
Component (B) is a good foam that is easy to apply at the time of discharge, a point that bubbles tend to disappear after application, a point that reduces stickiness of hair after application, a point that reduces stuffiness, and a bundle of hair is scattered. It contributes to the fact that it is difficult to arrange operations such as braiding and twisting. The component (B) is selected from glycerin, diglycerin, propylene glycol, and butylene glycol, and glycerin is preferable from the viewpoint of softening the hair feel and facilitating hair binding.

  The component (B) can be used alone or in combination of two or more, and the content in the hair styling agent of the present invention is such that short hair spills out from the bundle of hair bundled together with a binding tool when making the bundled hair. From the viewpoint of suppressing hair loss, it is preferably 0.15% by mass or more, more preferably 0.2% by mass or more, and still more preferably 0.5% by mass or more. From the viewpoint of suppressing spillage, no stickiness after coating, and no stuffiness in the vicinity of the knot, preferably 5% by mass or less, more preferably 4% by mass or less, and further preferably 3% by mass or less. More preferably, it is 2% by mass or less.

  The mass ratio (A) / (B) of the component (A) to the component (B) in the hair styling agent of the present invention has good foam quality when applied to the hair and good applicability. It is 0.3 or more from the point that it is easy to adjust, the point that it is not sticky after application, the point that short hair does not spill when the hair is bundled with a binding tool, the hair is easy to make, and the feeling of stuffy hair is reduced. Preferably it is 0.5 or more, more preferably 0.7 or more. In addition, the mass ratio (A) / (B) is that the hair after application has an appropriate feeling of unity, and when the hair is bundled with a tying tool, there is little spilling of the short hair and it is easy to make hair. 5 or less, preferably 4 or less, more preferably 3 or less, and even more preferably 2.5 or less.

[Component (C): Cationic surfactant or nonionic surfactant]
The hair styling agent of the present invention contains a cationic surfactant or a nonionic surfactant as component (C) in order to discharge the hair styling agent in a suitable foam state from a non-aerosol foamer. Component (C) can be used alone or in combination of two or more, but it is preferable to use a cationic surfactant and a nonionic surfactant in combination.

  Quaternary surfactants include quaternary ammonium salts, and mono long-chain alkyl quaternary ammonium from the viewpoint of improving the feel of hair after knitting using the hair styling agent of the present invention or after hair styling. Salts are preferred. Specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, aralkyltrimethylammonium chloride, and behenyltrimethylammonium chloride. Stearyltrimethylammonium chloride and cetyltrimethylammonium chloride are particularly preferable.

  Nonionic surfactants include higher fatty acid sucrose esters, polyglycerin fatty acid esters, higher fatty acid mono- or diethanolamides, polyoxyalkylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbite fatty acid esters, alkyl saccharides Examples include surfactants, alkylamine oxides, alkylamidoamine oxides, and alkylene oxide addition polymers represented by the following general formula (1). Among these, the alkylene oxide addition polymer represented by the general formula (1) is preferable from the viewpoint of adjusting the foam quality of the hairdressing agent of the present invention to make the foam easy to spread during application.

[Wherein, R ¹ represents a linear or branched alkyl group or alkenyl group having 1 to 24 carbon atoms, m and n represent an integer of 0 or more, and m + n represents an integer of 2 or more and 200 or less. ]

Of the alkylene oxide addition polymers represented by the general formula (1), the following components (C-1) and (C-2) are more preferable, and further, the components (C-1) and (C-2) ) Are preferably included.
(C-1) In the general formula (1), R ¹ is a linear or branched alkyl group having 1 to 24 carbon atoms, m is an integer of 1 or more, n is an integer of 0 or more, m + n Alkylene oxide addition polymer having 10 to 200
(C-2) In the general formula (1), with R ¹ is a linear or branched alkyl group having 1 to 24 carbon atoms, m is 0, and n is an integer of 1 to 40 Polymer

<Ingredient (C-1)>
Ingredient (C-1) improves the foam quality of the hairdressing agent of the present invention, and prevents short hair from spilling from the hair bundle at the time of binding, making it difficult for the hair to break even during an arranging operation such as braiding, and further binding Reduces the feeling of stuffiness.

In component (C-1), the chain length of the alkyl group represented by R ¹ is 1 or more, preferably 2 or more, more preferably 4 or more, and 24 or less, preferably 18 or less, More preferably, it is 12 or less, More preferably, it is 8 or less, More preferably, it is 6 or less.

  M in the component (C-1) is 1 or more, preferably 3 or more, more preferably 5 or more, still more preferably 10 or more, and 200 or less, preferably 150 or less, More preferably, it is an integer of 100 or less, more preferably 70 or less. n is an integer of 0 or more, preferably 3 or more, more preferably 5 or more, more preferably 10 or more, and 199 or less, preferably 50 or less, more preferably 40 or less, The integer is preferably 30 or less, more preferably 20 or less. m + n is 10 or more, preferably 20 or more, more preferably 30 or more, and 200 or less, preferably 150 or less, more preferably 100 or less, and still more preferably 70 or less. Further, it is more preferable that m ≧ n.

  Specific examples of component (C-1) include polyoxypropylene (30) butyl ether, polyoxypropylene (33) butyl ether, polyoxypropylene (40) butyl ether, polyoxypropylene (52) butyl ether, polyoxypropylene (30) Polyoxypropylene alkyl ethers such as oleyl ether, polyoxypropylene (30) isocetyl ether; polyoxyethylene (17) polyoxypropylene (17) butyl ether, polyoxyethylene (3) polyoxypropylene (35) stearyl ether, poly And polyoxyethylene polyoxypropylene alkyl ethers such as oxyethylene (3) polyoxypropylene (20) cetyl ether and polyoxyethylene (5) polyoxypropylene (40) behenyl ether.

<Ingredient (C-2)>
Component (C-2) improves the foam quality of the hairdressing agent of the present invention and makes it easier to apply the foam to the hair.

In Component (C-2), the chain length of the alkyl group represented by R ¹ is 1 or more, preferably 6 or more, more preferably 8 or more, still more preferably 10 or more, and still more preferably 12 or more. 24 or less, preferably 18 or less, more preferably 16 or less, and still more preferably 14 or less.

  N in the component (C-2) is 1 or more, preferably 3 or more, more preferably 5 or more, still more preferably 7 or more, and 40 or less, preferably 30 or less, more The integer is preferably 20 or less, more preferably 15 or less, and still more preferably 12 or less.

  Specific examples of the component (C-2) include polyoxyethylene (3) alkyl (sec-C12-14) ether, polyoxyethylene (5) alkyl (sec-C12-14) ether, polyoxyethylene (7) Alkyl (sec-C12-14) ether, polyoxyethylene (9) alkyl (sec-C12-14) ether, polyoxyethylene (12) alkyl (sec-C12-14) ether, polyoxyethylene (15) alkyl ( and polyoxyethylene alkyl ethers such as sec-C12-14) ether, polyoxyethylene (20) alkyl (sec-C12-14) ether, and polyoxyethylene (30) alkyl (sec-C12-14) ether.

  The content of the component (C) in the hairdressing agent of the present invention is preferably 0.1% by mass or more from the viewpoint of good foam quality, ease of foam expansion during application, and ease of defoaming after application. More preferably 0.5% by mass or more, further preferably 1% by mass or more, and further preferably 2% by mass or more. Ease of spreading bubbles during application, ease of defoaming after application, good after hair styling From the viewpoint of the feel of the hair, it is preferably 5% by mass or less, more preferably 4.5% by mass or less, and still more preferably 4% by mass or less.

  Moreover, the mass ratio (A) / [(B) + (C)] of the component (A) with respect to the total mass of the component (B) and the component (C) reduces the feeling of stuffiness at the binding part, and arranges knitting etc. From the viewpoint of preventing the hair from spilling during operation or spilling short hair when binding the hair with a binding tool, and preferably improving the feel of the hair after styling, preferably 0.09 or more, more preferably It is 0.1 or more, more preferably 0.15 or more, further preferably 0.2 or more, preferably 0.31 or less, more preferably 0.30 or less, and further preferably 0.29 or less.

[Component (D): Water]
The hairdressing agent of the present invention contains water as a medium. When the hair styling agent of the present invention contains water, it is possible to make a good collective hair that suppresses splashing hair and floating hair even when applied to dry hair due to the effect of so-called water set.

[Component (E): Polyoxypropylene alkyl glycoside]
The hair styling agent of the present invention preferably further contains a polyoxypropylene alkyl glycoside as component (E) from the viewpoint of making the hair difficult to disperse even during an arranging operation such as braiding. Polyoxypropylene alkyl glucoside is obtained by addition polymerization of propylene oxide to alkyl glucoside. For example, polyoxypropylene methyl glucoside can be obtained by synthesizing methyl glucoside using glucose as a starting material and then addition polymerization of propylene oxide. The alkyl group of this alkyl glucoside is preferably an alkyl group having 1 to 4 carbon atoms. The average number of moles of oxypropylene groups added is preferably 5 or more, more preferably 10 or more, and preferably 50 or less, more preferably 30 or less.

  Specifically, polyoxypropylene methyl glucoside, polyoxypropylene ethyl glucoside, polyoxypropylene propyl glucoside and the like are mentioned, among which polyoxypropylene methyl glucoside and polyoxypropylene ethyl glucoside are preferable, and among them polyoxypropylene methyl glucoside is preferable. preferable. As the component (E) polyoxypropylene alkyl glucoside, McBiolide MG-10P, McBiolide MG-20P (above, made by NOF Corporation), Glucam P-10, Gurucam P-20 (above, made by Amacol) ) Etc. can be used.

  The component (E) polyoxypropylene alkyl glucoside can be used alone or in combination of two or more. The content of the component (E) in the hair styling agent of the present invention is preferably 0.1% by mass or more from the viewpoint of ease of foam expansion during application, ease of grouping, and ease of arranging operations such as braiding and twisting. More preferably, it is 0.2% by mass or more, more preferably 0.5% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less, still more preferably 5% by mass or less, still more preferably 3% by mass. It is as follows.

[Other ingredients]
In the hairdressing agent of the present invention, various components usually used in hairdressing agents, for example, chelating agents, vitamins, proteins, amino acids, herbal medicines, coolness-imparting agents (menthol etc.), antiseptics, ultraviolet absorbers, Antioxidants, colorants, fragrances and the like can be blended according to the purpose within a range not impairing the effects of the present invention.

〔viscosity〕
The viscosity of the hairdressing agent of the present invention is preferably in a state of being present in the non-aerosol container (in a liquid state before being discharged as foam) from the viewpoint that it can be suitably discharged as a foam from the non-aerosol foamer container. Is 1 mPa · s or more, more preferably 2 mPa · s or more, further preferably 3 mPa · s or more, preferably 100 mPa · s or less, more preferably 30 mPa · s or less, and even more preferably 20 mPa · s or less. . The viscosity here is measured with a B-type viscometer TVB-10M (Toki Sangyo Co., Ltd.) at 30 ° C. using the following rotor and rotation speed.
The number of revolutions is 30 rpm for viscosity up to 10 mPa · s, 60 rpm for up to 10-20 mPa · s, and 30 rpm for 20 mPa · s or more, and the rotor is L / Adp up to 10 mPa · s, 10-200 mPa · s.・ Use M1 rotors up to s, and M2 rotors from 200mPa · s to 1,000mPa · s.

[Non-Aerosol Foamer Container]
The non-aerosol foamer container is used for mixing the hairdressing composition filled in the container with air without using a propellant and discharging it in the form of foam. By using the former container, an effect of preventing scattering of the discharged agent can be obtained. In particular, a non-aerosol type container can manufacture a product at a lower cost than an aerosol type container and does not require a high-pressure gas propellant. Therefore, the product can be handled more safely in distribution.

  As the former container, a known pump former container having a foam discharge means, a squeeze foamer container, an electric frother, a pressure accumulating pump former container or the like can be used. More specifically, for example, food and containers (vol. 35, No. 10, p588 to 593 (1994); vol. 35, No. 11, p624 to 627 (1994); vol. 36, No. 3, p154 ~ 158 (1995)) Pump former E3 type, F2 type (above, Daiwa Steel Co., Ltd.), squeeze foamer (Daiwa Steel Co., Ltd.), electric whisk (Matsushita Electric Works), air spray for Mar (Air Spray International). As the former container used in the hair styling agent of the present invention, a pump former container and a squeeze foamer container are preferable because they are inexpensive and easy to use.

The pump former container and the squeeze foamer container have foam homogenizing means such as a net, and preferably have a thin net from the viewpoint of preventing clogging. In this case, the mesh size of the net is preferably 50 to 400 mesh, more preferably 70 to 350 mesh, and further preferably 80 to 320 mesh. Here, the unit of mesh is expressed by the number of eyes per inch.
By using a mesh net in this range, creamy foam can be generated. Moreover, as a material of such a net, nylon, polyester and the like can be preferably exemplified.
The non-aerosol foamer container containing the hair styling agent of the present invention is provided with at least one, preferably a plurality of such nets, particularly from the viewpoints of economy, fineness of foam, difficulty in clogging, and the like. Two are preferably provided.

  The hair styling agent of the present invention can be suitably used in a hair styling method in which a hand or a hair styling tool is applied to hair, and then the hair is combined using a binding tool. Especially when adding additional arrangements before and after combining the hair, such as braiding before or after combining the hair with a binding tool, twisting the hair bundle, or pulling out part of the hair from the bundle. Can be more suitably used.

  The hair styling agent of the present invention can be applied to the hair in any state such as a wet state after shampooing and towel drying, a semi-dry state during drying, a dry state after drying, etc. However, it is preferable to apply to the hair in a semi-dried state such as during drying or in a dry state such as after drying, from the viewpoint of achieving both the natural nature of the combined hair and the suppression of stuffiness in the vicinity of the binding portion. It is preferable to apply to dry hair such as after.

  The amount of application (application) to the hair of the hairdressing agent of the present invention is not uniform depending on the content of the component (A) and the length of the hair, but it is preferably 0.001 as a ratio (bath ratio) to the mass of normal hair. More preferably, it is 0.005 or more, more preferably 0.007 or more, still more preferably 0.01 or more, and is preferably 1 or less, more preferably 0.7 or less, still more preferably 0.5 or less.

  Application to the hair to the hairdressing agent of the present invention can be performed on the entire hair or a part of the hair, but from the viewpoint of making a good group hair and easy arrangement, It is preferable to apply.

  After applying the hair styling agent, while the hair is bound and fixed with the binding tool, the hair flow is adjusted by a method using a hand such as a comb or a method using a tool such as a comb or a brush, or a combination of both. However, from the viewpoint of making natural hair, it is preferable to use a method using a hand alone or a combination of a method using a hand and a method using a tool, and a method using only a hand is more preferable.

  After applying the hairdressing agent, it is preferable not to include a drying step between binding the hair and fixing it with a binding tool. Further, examples of the binding tool include a rubber ring, an elastic band, a hairpin, a hairpin, a barrette, a ribbon, and the like.

  Arrangement operations such as weaving before and after combining hair, twisting hair bundles, or pulling out part of hair from bundled hair bundles are methods using hands, methods using tools such as combs, brushes, etc. However, from the viewpoint of creating natural hair, a method using a hand alone or a method using a tool is preferable, and a method using only a hand is more preferable.

Examples 1-9, Comparative Examples 1-4
A hair styling agent shown in Tables 3 and 4 was prepared by a conventional method, and a pump former container (manufactured by Yoshino Seisakusho Co., Ltd. (the net part had two nets having a net hole size of 200 mesh), and the composition was composed of two sheets. The net is arranged so as to pass through the net in order.The amount of liquid discharged by one press is 1.0 g), and performance evaluation was performed according to the following methods and standards. The viscosity of each of the prepared compositions was 20 mPa · s or less.
In addition, Example 6 is a reference example and is not included in the scope of claims.

(Evaluation hair bundle)
Hair bundles of 25 cm, 10 g, and 5.5 cm in width were made of Chinese straight hair with no chemical treatment history. The first agent and the second agent of “Pretia Soft Bubble Bleach Hybrid” manufactured by Kao Corporation were mixed at a mass ratio of 1: 2. The hair bundle is immersed in this mixed stock solution at a bath ratio (mass ratio) of 1: 1, left at 40 ° C. for 30 minutes, and then rinsed with water. Next, this hair bundle is treated with the shampoo shown in Table 1, rinsed with water, then treated with plain rinse shown in Table 2, and rinsed with water. After towel drying, dry with a dryer at 70 ° C for 5 minutes. A hair bundle obtained by repeating this shampoo treatment and plain rinse treatment 30 times was used as an evaluation hair bundle.

(Evaluation method)
"Ease of spreading foam during application"
Wash each hair with the shampoo shown in Table 1, rinse it with the rinse shown in Table 2, rinse it, dry it with a dryer after towel drying, and each foamy hair styling agent discharged from the pump former An evaluation was made of the ease of extension of the hair styling agent to the hair when 0.5 g was taken and spread on the evaluation hair bundle.
The evaluation is alternative to whether the panelists of 7 people are “easy to stretch uniformly” / “cannot say either” / “difficult to stretch uniformly” when each composition is processed by the above operation. Tables 3 and 4 show the number of people selected for these options in order.

"Ease of disappearance of bubbles after application"
After processing by the same method as “Ease of spreading uniformly when applied to dry hair”, the ease of disappearance of bubbles on the hair bundle was evaluated.
As an evaluation, when one of the seven panelists treated each composition by the above-mentioned operation, the choice was either “foam is easy to disappear” / “neither” or “foam is difficult to disappear”. Tables 3 and 4 show the number of people selected for these options in order.

"No stickiness after application"
The evaluation hair bundle after evaluating the “ease of disappearance of bubbles after application” was evaluated from the viewpoint of non-stickiness of the hair bundle.
The evaluation was performed by letting seven panelists alternatively choose between “not sticky”, “neither”, or “sticky” when each composition was processed by the above operation. Tables 3 and 4 show the number of these options selected in order.

"The difficulty of spilling hair from a bundle of bundles"
For the evaluation hair bundle after evaluating "Ease of disappearance of foam after application", bundle the hair bundle at about 3/4 from the root, hold it with a rubber band and let it stand for 10 minutes, then visually observe the hair bundle The evaluation was performed from the viewpoint of short hair spillage from the hair bundle.
The evaluation was that 7 panelists said “Short hair does not spill from the bundle of hair bundles” / “Short hair spills from the bundle of hair bundles” / “Short hair spills from the bundle of hair bundles significantly. The number of persons selected for these options is shown in order in Tables 3 and 4.

"Ease of weaving"
Evaluation of the hair bundle for evaluation after evaluating the “ease of disappearance of foam after application” from the viewpoint of the difficulty of loosening the hair bundle when braiding into three after dividing the hair bundle into three It was.
The evaluation was made by seven panelists as to whether the hair bundles were difficult to break and easy to knitting, or could not be said to be either, or “hair bundles were easy to break and difficult to braid.” Tables 3 and 4 show the number of people selected for these options in order.

"No stuffiness near the knot"
About the hair bundle for evaluation after evaluating "goodness of unity", the hair bundle was bundled together and stopped with a rubber band, and after 60 minutes, the vicinity of the knot of the hair bundle was touched to evaluate the lack of stuffiness. The evaluation was performed by having the seven panelists select either “no stuffiness” / “neither” or “steaminess” as shown in Tables 3 and 4. The number of choices for each option is shown in order.

* 1: Lubiscol K-30 (BASF)
* 2: Guffcut 734 (Ashland)
* 3: Yuka Former M-75 (Mitsubishi Chemical Corporation)
* 4: Diamond former Z-732 (Mitsubishi Chemical Corporation)
* 5: POLYGLYCEROL-3 (Sorvey)
* 6: Cotamine 86W (Kao Corporation)
* 7: Unilube 50MB-26
* 8: Softanol 90
* 9: MacBiolite MG-10P (manufactured by NOF Corporation)

Claims (6)

Contains the following components (A) to (D), the mass ratio (A) / (B) of the component (A) to the component (B) is 0.3 or more and 5 or less , the sum of the component (B) and the component (C) A non-aerosol former hair styling agent in which the mass ratio (A) / [(B) + (C)] of the component (A) to is 0.09 or more and 0.31 or less .
(A) A film-forming polymer containing at least one selected from (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylic acid amide, vinyl alcohol, vinyl alkyl ether and vinyl pyrrolidone as a constituent monomer
(B) one or more selected from glycerin, diglycerin, propylene glycol and butylene glycol
(C) one or more cationic surfactants and one or more non-ionic surfactants
(D) Water
However, the nonionic surfactant is an alkylene oxide addition polymer represented by the following general formula (1).

[Wherein, R ¹ represents a linear or branched alkyl group or alkenyl group having 1 to 24 carbon atoms, m and n represent an integer of 0 or more, and m + n represents an integer of 2 or more and 200 or less. ]   The hair styling agent in a non-aerosol foamer container according to claim 1, wherein the content of the component (A) is 0.1% by mass or more and 5% by mass or less.   The hair styling agent containing a non-aerosol foamer according to claim 1 or 2, wherein the content of the component (C) is 0.1 mass% or more and 5 mass% or less. The non-aerosol foamer-containing hair styling agent according to any one of claims 1 to 3 , wherein the nonionic surfactant contains both of the following components (C-1) and (C-2).
(C-1) In the general formula (1), R ¹ is a linear or branched alkyl group having 1 to 24 carbon atoms, m is an integer of 1 or more, n is an integer of 0 or more, m + n Alkylene oxide addition polymer having 10 to 200
(C-2) In the general formula (1), with R ¹ is a linear or branched alkyl group having 1 to 24 carbon atoms, m is 0, and n is an integer of 1 to 40 Polymer The hair styling agent in a non-aerosol foamer container according to any one of claims 1 to 4 , further comprising the following component (E):
(E) Polyoxypropylene alkyl glycoside A hair styling method for making hair after applying the hair styling agent according to any one of claims 1 to 5 to hair.