JP6434348B2 - High strength steel plate with excellent workability - Google Patents

Description

  The present invention relates to a high-strength steel plate excellent in workability, and in particular, to a high-strength steel plate with improved strength-elongation balance and stretch flangeability. The steel plate types of the high-strength steel plates according to the present invention include cold-rolled steel plates as well as various plated steel plates such as hot-dip galvanized steel plates and galvannealed steel plates.

  High-strength steel sheets are used for automobile frame parts. Steel sheets used as frame parts for automobiles are required to be cold-rolled steel sheets and alloyed hot-dip galvanized steel sheets with increased strength for the purpose of improving fuel efficiency by reducing the weight of the vehicle body. On the other hand, excellent workability is also required in order to form a complex shaped part.

  For this reason, it has been desired to provide a high-strength steel sheet having high strength and enhanced elongation (total elongation; EL) and stretch flangeability (hole expansion rate: λ), for example, tensile strength (TS). For steel sheets of 980 MPa, TS × EL is 25000 MPa ·% or more, yield strength (YS) is 550 MPa or more, and λ is 20% or more.

  In order to answer the above-mentioned demand, various materials have been proposed as steel plate materials.

For example, in Patent Document 1, a hot rolled coil having a component composition approximate to that of the high-strength steel sheet according to the present invention and a structure mainly composed of bainite and martensite is held for 1 hour or more in the range of 550 ° C. to Ac1 point. The batch hot-rolled sheet annealing process, the cold-rolling process, and the cold-rolled sheet are heated to a temperature of Ac ₁ to Ac ₃ with an average temperature increase rate of Ac ₁ point to Ac ₁ point + 50 ° C being 5 ° C / s or more A continuous recrystallization annealing that holds for 5 s or more, and then a recrystallization annealing process that performs cooling to 350 to 500 ° C. at a cooling rate of 5 ° C./s or more, and austempering treatment that holds the temperature for 10 to 600 s. By applying, it has a composite structure composed of ferrite having a volume ratio of 70% or more as a main phase and a second phase having an average particle diameter of 3 μm or less containing at least 3% or more of retained austenite by volume ratio, and r value 1.1 or higher In addition, it is disclosed that a high-strength cold-rolled steel sheet having a strength-ductility balance TS × EL of 22000 MPa ·% or more can be obtained.

  This high-strength cold-rolled steel sheet is common to the high-strength steel sheet according to the present invention in that a batch hot-rolled sheet annealing step (corresponding to the pre-annealing process of the present invention) is performed in the production method.

  However, the austempering temperature at the time of quenching from the two-phase region temperature to the austempering temperature is 350 to 500 ° C., which is higher than 50 ° C. and less than 350 ° C. of the present invention.

  For this reason, the ferrite fraction in the final structure contains 70% or more of ferrite (corresponding to the polygonal ferrite of the present invention) more than 65% or less of the present invention. It is clearly different from high strength steel plate.

  In Patent Document 2, the component composition has a component composition similar to that of the present invention, and in terms of volume fraction, ferrite phase: 40 to 70%, bainite phase: 15 to 35%, tempered martensite phase: 5 to 5%. 25% and residual austenite phase: 2 to 20%, and the ratio of the martensite phase with the major axis length ≧ 10 μm in the total volume fraction of the tempered martensite phase is 30% or less. A high-strength cold-rolled steel sheet having a tensile strength TS of 1180 MPa or more with improved workability such as stretch flangeability and bendability is disclosed.

  This high-strength cold-rolled steel sheet is a high-strength steel sheet according to the present invention in that the first annealing (corresponding to the pre-annealing treatment of the present invention) is performed in the temperature range of 400 to 800 ° C. after the hot rolling in the manufacturing method. And in common.

  However, the cooling stop temperature at the time of rapid cooling from the two-phase region temperature, which is the second annealing, to the cooling stop temperature (corresponding to the austempering temperature of the present invention) is 300 to 500 ° C. (380 to 500 ° C. in the inventive examples of the examples). ) And higher than 50 ° C. or more and less than 350 ° C. of the present invention.

  For this reason, the fresh martensite fraction is lowered, and the formed fresh martensite is all tempered by the third annealing (corresponding to the tempering treatment of the present invention) to become only tempered martensite, and the final structure is not yet. There is no tempered fresh martensite, and therefore no MA, so at least in this respect it is clearly different from the high strength steel sheet according to the invention.

JP 2008-291304 A JP 2012-237042 A

  Therefore, the object of the present invention is that the tensile strength (TS) is 980 MPa or more, the tensile strength-elongation balance (TS × EL) is 25000 MPa ·% or more, the yield strength (YS) is 550 MPa or more, and the stretch flangeability (λ) is An object of the present invention is to provide a high-strength steel sheet excellent in workability and capable of securing 20% or more.

The high-strength steel sheet excellent in workability according to the first invention of the present invention is
% By mass
C: 0.05 to 0.50%,
Si: 1.0-3.0%,
Mn: 1.0 to 5.0%
Al: 0.001 to 0.10%
Each
The balance consists of iron and inevitable impurities,
Among the inevitable impurities, P, S, and N are
P: 0.1% or less,
S: 0.01% or less,
N: each having a component composition limited to 0.01% or less,
The area ratio for all tissues
Polygonal ferrite: 40% or more
Tempered martensite: 10% or more,
Bainitic ferrite: 5% or more
Mixed structure of fresh martensite and retained austenite (hereinafter, this mixed structure is referred to as “MA”): 5% or more,
Polygonal ferrite + bainitic ferrite: having a structure consisting of 70% or less in total,
The Mn concentration in the MA is 1.2 times or more of the Mn content of the whole steel sheet.

The high-strength steel sheet excellent in workability according to the second invention of the present invention is
In the first invention,
Ingredient composition is further mass%,
Cr: 0.05 to 1.0%,
Mo: 0.05-1.0%,
Ni: 0.05 to 1.0%,
B: 0.0001 to 0.002%
Any one or two or more of these are included.

The high-strength steel sheet excellent in workability according to the third invention of the present invention is
In the first or second invention,
Ingredient composition is further mass%,
Ti: 0.01 to 0.15%,
Nb: 0.01 to 0.15%,
V: 0.01 to 0.15%
Any 1 type or 2 types or more of these are included.

  According to the present invention, a soft polygonal ferrite is used as a main phase, a predetermined amount of bainitic ferrite is introduced, and Mn is further concentrated in the MA to ensure elongation while maintaining the elongation in the MA. In addition to hard fresh martensite, a predetermined amount of tempered martensite is introduced to improve the strength (tensile strength, yield strength) and stretch flangeability due to the presence of the tempered martensite and bainitic ferrite. The tensile strength (TS) is 980 MPa or more, the tensile strength-elongation balance (TS × EL) is 25000 MPa ·% or more, the yield strength (YS) is 550 MPa or more, and the stretch flangeability (λ) is 20 % Can be secured, and a high-strength steel sheet excellent in workability can be provided.

It is a drawing substitute photograph which shows an example of the steel structure of the high strength steel plate which concerns on this invention.

  Hereinafter, the present invention will be described in more detail.

  First, a structure that characterizes a high-strength steel sheet excellent in workability according to the present invention (hereinafter also referred to as “the steel sheet of the present invention”) will be described.

[Structure of the steel sheet of the present invention]
As described above, the steel sheet of the present invention is characterized in that the parent phase is polygonal ferrite, and tempered martensite and bainitic ferrite are partially introduced into this, and further MA containing Mn is added. It is what.

<Polygonal ferrite: 40% or more>
Polygonal ferrite is a soft phase and is an effective structure for enhancing the ductility of a steel sheet. The content of polygonal ferrite with respect to the entire structure needs to be 40% or more, preferably 45% or more, and more preferably 50% or more in terms of area ratio in order to ensure the ductility of the steel sheet.
The “polygonal ferrite” in the present invention is a generic term for the polygonal ferrite structure and the quasi-polygonal ferrite structure described in “Japan Steel Association Basic Research Group's“ Bainite Photograph of Steel-1 ””. Is.

<Tempered martensite: 10% or more>
By partially introducing tempered martensite, stretch flangeability can be improved while maintaining tensile strength. The tempered martensite content in the entire structure needs to be 10% or more, preferably 12% or more, and more preferably 14% or more in terms of area ratio in order to ensure stretch flangeability.

<Bainitic ferrite: 5% or more>
By partially introducing bainitic ferrite, the tensile strength-elongation balance can be improved. The content of bainitic ferrite with respect to the entire structure needs to be 5% or more, preferably 7% or more, and more preferably 9% or more in terms of an area ratio in order to ensure a tensile strength-elongation balance.
In the present invention, “bainitic ferrite” means that the bainite structure has a lower structure having a lath-like structure with a high dislocation density, and has no carbide in the structure. Is clearly different, and is also different from a polygonal ferrite structure with a substructure with little or no dislocation density, or a quasi-polygonal ferrite structure with a substructure such as fine subgrains. Issued by the Society “Steel Bainite Photobook-1”).

<MA: 5% or more>
By introducing a part of MA, the yield strength and tensile strength-elongation balance can be improved. The MA content in the entire structure needs to be 5% or more, preferably 7% or more, and more preferably 9% or more in terms of area ratio in order to ensure the yield strength and tensile strength-elongation balance.
Note that “MA” in the present invention is a mixed structure of fresh martensite and retained austenite, and it is difficult to separate (discriminate) fresh martensite and retained austenite by microscopic observation. Fresh martensite refers to a state in which untransformed austenite is martensitic transformed in the process of cooling the steel sheet from the heating temperature to the MS point or less, and is distinguished from tempered martensite after tempering.

<Polygonal ferrite + Bainitic ferrite: 70% or less in total>
If the total amount of polygonal ferrite and bainitic ferrite is too large, the amount of tempered martensite and MA is insufficient, and at least one of yield strength, tensile strength-elongation balance, and stretch flangeability cannot be secured. The total content of polygonal ferrite and bainitic ferrite with respect to the entire structure must be limited to 70% or less, preferably 69% or less, and more preferably 68% or less in terms of area ratio.

<Mn concentration in MA: 1.2 times or more of Mn content of whole steel plate>
By concentrating Mn in MA, the retained austenite constituting MA is stabilized, work-induced transformation can be performed in a higher strain region, and the work hardening degree in the high strain region is increased, so that ductility is improved. . In order to effectively exhibit such an action, the Mn concentration in the MA is 1.2 times or more, preferably 1.25 times or more, more preferably 1.3 times or more of the Mn content of the whole steel sheet. And

[Each measurement method of area ratio of each phase and Mn concentration in MA]
Here, each measuring method of the area ratio of each phase and the Mn concentration in MA will be described.

  The area ratios of polygonal ferrite, MA, and tempered martensite were measured as follows. That is, after the steel plate was mirror-polished and corroded with 3% nital solution to reveal the metal structure, a secondary electron image of a field emission scanning electron microscope (FE-SEM) was obtained for approximately 5 fields of 24 μm × 18 μm region. It was observed (magnification 5000 times). An example of the observation photograph is shown in FIG. And by image analysis, the region that does not contain cementite and appears concave due to corrosion is polygonal ferrite, the region that does not contain cementite and appears to be convex on the polygonal ferrite is MA, and the region that contains cementite They were identified as tempered martensite and the respective area ratios were calculated.

  By subtracting the total area ratio of polygonal ferrite, MA and tempered martensite from 100% with the remaining structure other than “polygonal ferrite”, “MA” and “tempered martensite” as bainitic ferrite, The area ratio of nittic ferrite was calculated.

  About Mn density | concentration in MA, the Mn density | concentration distribution in MA was measured using the field emission electron beam microanalyzer (FE-EPMA), and the average value was made into Mn density | concentration in MA.

[Component composition of the steel sheet of the present invention]
Below, the component composition which comprises this invention steel plate is demonstrated. Hereinafter, all the units of chemical components are mass%. In addition, “content” of each component may be simply referred to as “amount”.

C: 0.05 to 0.50%
C is an important element for improving the strength of the steel sheet. In order to exhibit the effect of improving the strength effectively, it is necessary to contain C 0.05% or more, preferably 0.08% or more, more preferably 0.12% or more. However, when the amount of C is excessive, coarse carbides are likely to precipitate during tempering, and the stretch flangeability is deteriorated and the weldability is also adversely affected. Therefore, the amount of C is preferably 0.50% or less, preferably Is 0.45% or less, more preferably 0.40% or less.

Si: 1.0-3.0%
Si is a useful element that has the effect of suppressing the coarsening of carbide particles during tempering, contributes to improvement in stretch flangeability, and also contributes to an increase in yield strength of the steel sheet as a solid solution strengthening element. In order to effectively exhibit such an action, it is necessary to contain Si by 1.0% or more, preferably 1.1% or more, and more preferably 1.2% or more. However, if the amount of Si becomes excessive, weldability is remarkably lowered, so the Si amount is 3.0% or less, preferably 2.9% or less, and more preferably 2.8% or less.

Mn: 1.0-5.0%
Mn, like Si, has an effect of suppressing the coarsening of cementite during tempering, contributes to the improvement of stretch flangeability, and is a useful element that also contributes to an increase in the yield strength of the steel sheet as a solid solution strengthening element. is there. Moreover, it has the effect of suppressing the ferrite transformation at the time of cooling by improving hardenability. In order to effectively exhibit such an action, it is necessary to contain Mn at 1.0% or more, preferably 1.1% or more, and more preferably 1.2% or more. However, if the amount of Mn becomes excessive, the amount of MA in the final structure becomes excessive, and conversely the stretch flangeability is lowered. Therefore, the amount of Mn is 5.0% or less, preferably 4.8% or less. Preferably it is 4.6% or less.

Al: 0.001 to 0.10%
Al is a useful element added as a deoxidizer. In order to effectively exhibit the action as a deoxidizer, it is necessary to contain Al 0.001% or more, preferably 0.003% or more, and more preferably 0.005% or more. However, if the amount of Al is excessive, the cleanliness of the steel is deteriorated, so the amount of Al is 0.10% or less, preferably 0.08% or less, and more preferably 0.06% or less.

  The steel sheet of the present invention contains the above elements as essential components, and the balance is iron and unavoidable impurities (P, S, N, O, etc.). Among the unavoidable impurities, P, S, and N are as follows: It can be contained up to each allowable range.

P: 0.1% or less P is unavoidably present as an impurity element, and contributes to an increase in strength by solid solution strengthening, but segregates at the prior austenite grain boundaries and makes the grain boundaries brittle, thereby improving the bendability. Since it deteriorates, the amount of P is limited to 0.1% or less, preferably 0.05% or less, and more preferably 0.03% or less.

S: 0.01% or less S is also unavoidably present as an impurity element, forms MnS inclusions, and becomes a starting point of a crack at the time of bending deformation, thereby lowering the bendability. % Or less, preferably 0.005% or less, more preferably 0.003% or less.

N: 0.01% or less N is also unavoidably present as an impurity element and lowers the workability of the steel sheet by strain aging. Therefore, the N content is 0.01% or less, preferably 0.005% or less, and more preferably. Is limited to 0.003% or less.

  In addition, Cr, Mo, Ti, Nb, V, B, Ni, Cu, Zr, and the like can be included as allowable components within the range not impairing the action of the present invention. Of these allowable components, Cr, Mo Ni, B, Ti, Nb and V are recommended to be contained within the following permissible ranges.

Cr: 0.05 to 1.0%,
Mo: 0.05-1.0%,
Ni: 0.05 to 1.0%,
B: 0.0001 to 0.002%
Any one or two or more of these elements are useful for enhancing the hardenability and improving the strength of the steel sheet. In order to effectively exhibit hardenability, the Cr, Mo, and Ni contents are each 0.05% or more, more preferably 0.1% or more, and the B content is 0.0001% or more, more preferably Is recommended to be 0.0002% or more. However, if these elements are contained excessively, the workability deteriorates and the cost becomes high, so the contents of Cr, Mo and Ni are 1.0% or less, further 0.8% or less, respectively. The content is desirably limited to 0.002% or less, more preferably 0.001% or less.

Ti: 0.01 to 0.15%,
Nb: 0.01 to 0.15%,
V: 0.01 to 0.15%
Any one or more of these elements are useful as precipitation strengthening elements for steel. In order to effectively exert the precipitation strengthening action, it is recommended that the content of these elements is 0.01% or more, more preferably 0.02% or more. However, if these elements are contained excessively, the workability deteriorates, so the content of these elements is preferably limited to 0.15% or less, and further to 0.10% or less.

  Next, preferable production conditions for obtaining the steel sheet of the present invention will be described below.

[Preferred production method of the steel sheet of the present invention]
First, steel having the above component composition is melted and made into a slab (steel material) by ingot forming or continuous casting, and then hot-rolled (hot rolled) at a finishing temperature of 900 ° C. or less (preferably 880 ° C. or less). The coiling temperature after hot rolling is set to 600 to 700 ° C., and then cooled to room temperature to obtain a hot rolled sheet. In this way, the hot-rolled sheet has a bainite or pearlite single-phase structure or a two-phase structure containing ferrite.

Following this hot-rolled sheet, 500 ° C. to Ac ₁ (preferably _{510 ℃ ~ [A c1 -10 ℃} ]) pre-annealing temperature _{T pa} (unit: ° C.), the tempering parameters calculated by the following formula (1) Pre-annealing using a batch furnace, UAD (United Annealing Department) furnace, etc. under the condition of pre-annealing holding time t _pa (unit: h) where ξ is 16 to 20 (preferably 16.5 to 19.5). Apply processing.
ξ = (T _pa +273) · {log (t _pa ) +20} / 1000 (1)
By this preliminary annealing treatment, the carbide is coarsened and Mn is concentrated in the carbide.

Next, after removing the scale of this pre-annealed material by pickling or the like, cold rolling (cold rolling) is performed to obtain a cold rolled sheet. For example, a continuous annealing line (CAL) is used for this cold-rolled sheet, and Ac _{1 to} Ac ₃ (preferably [Ac ₁ + 10 ° C.] to [Ac ₃ − −], which are two-phase region temperatures in which polygonal ferrite and austenite are mixed. The carbide is austenitized by performing an annealing treatment under the condition that the annealing is performed for 10 hours at an annealing heating temperature of 10 ° C.] for an annealing holding time of 50 s or more (preferably 55 s or more). In this carbide, austenite having a high Mn concentration can be formed because Mn is concentrated by the preliminary annealing treatment.

  From this two-phase region temperature (annealing heating temperature) of polygonal ferrite and austenite, quenching is performed at a cooling rate of 10 to 50 ° C./s to a supercooling stop temperature of 50 ° C. or more and less than 350 ° C. (preferably 100 to 300 ° C.). Thus, an annealed material in which a mixed structure (MA) of fresh martensite and retained austenite in which Mn is concentrated is formed.

  By further subjecting this annealed material to an austempering treatment at austempering temperature of 400 to 500 ° C. (preferably 410 to 490 ° C.) for 30 to 1200 s (preferably 40 to 600 s) for holding the austempering time, The steel sheet of the present invention (cold rolled steel sheet) is obtained. By this austempering treatment, bainite is formed and a part of the fresh martensite formed by the rapid cooling is tempered to form tempered martensite. Thereby, the balance of strength, ductility, and stretch flangeability can be improved. Furthermore, by improving the stability of retained austenite constituting the MA by concentrating Mn in the final structure so that the Mn concentration is 1.2 times or more of the Mn content of the entire steel sheet. The tensile strength-elongation balance can be improved.

  In addition, this invention steel plate is good also as a plated steel plate by giving a plating process to the annealing material after the said annealing process, and giving the said austempering process after that.

  EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited by the following examples, but may be appropriately modified within a range that can meet the purpose described above and below. Of course, it is possible to implement them, and they are all included in the technical scope of the present invention.

  Test steels having the respective component compositions shown in Table 1 below were vacuum-melted to form a slab having a thickness of 30 mm, the slab was soaked to 1150 ° C., hot-rolled at a finishing temperature of 880 ° C., and then 600 ° C. Was rolled to prepare a hot-rolled sheet having a thickness of 2.5 mm. This hot-rolled sheet was pre-annealed under the conditions shown in Table 2 below using a batch furnace. After pickling this pre-annealed material, it was cold-rolled to a thickness of 1.5 mm, and further subjected to annealing treatment and austempering treatment under the conditions shown in Table 2 to produce a test steel sheet (cold rolled steel sheet) did.

  In addition, although description of N content was abbreviate | omitted in following Table 1, N content was an impurity level of 0.01% or less in all the steel types.

In addition, Ac ₁ and Ac ₃ in Table 1 were determined using the following formulas (1) and (2) (see translation by Kosei Shigeyasu, “Leslie Steel Material Science”, Maruzen Co., Ltd., 1985, p. 273). .

Ac ₁ (° C.) = 723 + 29.1 [Si] −10.7 [Mn] +16.9 [Cr] −16.9 [Ni] (1)
Ac ₃ (° C.) = 910−203√ [C] +44.7 [Si] −30 [Mn] +700 [P] +400 [Al] +400 [Ti] +104 [V] −11 [Cr] +31.5 [Mo ] -20 [Cu] -15.2 [Ni] Formula (2)
However, [] shows content (mass%) of each element.

  About each said test steel plate, the area ratio of each phase and the Mn density | concentration in MA were measured with each measuring method demonstrated in the term of the said [form for inventing].

  Further, in order to evaluate the strength and workability of each of the test steel plates, the yield strength YS, the tensile strength TS, and the elongation (total elongation) EL were measured by a tensile test, and the stretch flangeability λ was measured by a hole expansion test. Was measured. In addition, the tensile test produced the No. 5 test piece as described in JISZ2201, taking a long axis in the direction orthogonal to a rolling direction, and implemented according to JISZ2241. Moreover, the hole expansion test was performed in accordance with the iron standard JFST001, the hole expansion rate was measured, and this was defined as stretch flangeability λ.

  The measurement results are shown in Table 3 below. In the table, the mechanical properties (hereinafter, also simply referred to as “characteristics”) of the test steel sheet are tensile strength (TS) of 980 MPa or more, YS: 550 MPa or more, TS × EL: 25000 MPa ·% or more, λ: 20% Those satisfying all of the above were accepted (◯), and those not satisfying at least one were rejected (x).

  As shown in Table 3 above, the steel No., which is an inventive steel (evaluation is ○). 1 to 3, 7, 11, 17, 21, 22, and 25 satisfy the requirements of the organization provision of the present invention as a result of manufacturing under recommended production conditions using steel types that satisfy the requirements of the composition provision of the present invention. It is an invented steel and its characteristics satisfy the acceptance criteria.

  On the other hand, steel No. which is a comparative steel (evaluation of x). 4-6, 8-10, 12-16, 18-20, 23, 24, 26, 27 do not satisfy at least one of the requirements of the component prescription and the structure prescription of the present invention, and the characteristics satisfy the acceptance criteria Not.

  That is, no. 4-6, 8-10, 12-16, 18, 23 are manufactured using conditions that deviate from the recommended manufacturing conditions, although steel types that satisfy the requirements of the component provisions of the present invention are used. The organization regulations are not met and the characteristics are inferior.

  On the other hand, Steel No. Although Nos. 19 and 24 are manufactured under recommended manufacturing conditions, steel types that partially deviate from the requirements of the component provisions of the present invention are used, so the requirements of the structure provisions are not satisfied and the characteristics are inferior.

  From the above results, the applicability of the present invention was confirmed.

Claims (2)

% By mass
C: 0.05 to 0.50%,
Si: 1.0-3.0%,
Mn: 1.0 to 5.0%
Al: 0.001 to 0.10%
Each
The balance consists of iron and inevitable impurities,
Among the inevitable impurities, P, S, and N are
P: 0.1% or less,
S: 0.01% or less,
N: each having a component composition limited to 0.01% or less,
Ingredient composition is further mass%,
Ti: 0.01 to 0.15%,
Nb: 0.01 to 0.15%,
V: 0.01 to 0.15%
Including any one or more of
The area ratio for all tissues
Polygonal ferrite: 40% or more
Tempered martensite: 10% or more,
Bainitic ferrite: 5% or more
Mixed structure of fresh martensite and retained austenite (hereinafter referred to as “
MA ". ): 7% or more,
Polygonal ferrite + bainitic ferrite: having a structure consisting of 70% or less in total,
A high-strength steel sheet excellent in workability, characterized in that the Mn concentration in the MA is 1.2 times or more the Mn content of the whole steel sheet. Ingredient composition is further mass%,
Cr: 0.05 to 1.0%,
Mo: 0.05-1.0%,
Ni: 0.05 to 1.0%,
B: 0.0001 to 0.002%
The high-strength steel plate excellent in workability of any one of Claim 1 or 2 types or more.