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JP6460559B2 - Preparation substrate, hair preparation and hair fluorescent X-ray apparatus - Google Patents
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JP6460559B2 - Preparation substrate, hair preparation and hair fluorescent X-ray apparatus - Google Patents

Preparation substrate, hair preparation and hair fluorescent X-ray apparatus Download PDF

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JP6460559B2
JP6460559B2 JP2014162865A JP2014162865A JP6460559B2 JP 6460559 B2 JP6460559 B2 JP 6460559B2 JP 2014162865 A JP2014162865 A JP 2014162865A JP 2014162865 A JP2014162865 A JP 2014162865A JP 6460559 B2 JP6460559 B2 JP 6460559B2
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小嶋 良種
良種 小嶋
彰男 市村
彰男 市村
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Description

本発明は、蛍光X線分析により毛髪の元素分布を導出するときに使用されるプレパラート基板に関し、更にプレパラート基板に毛髪を固定した毛髪プレパラート及び毛髪プレパラートを配置した毛髪蛍光X線装置に関する。   The present invention relates to a preparation substrate used when deriving the elemental distribution of hair by fluorescent X-ray analysis, and further relates to a hair preparation in which hair is fixed to the preparation substrate and a hair fluorescent X-ray apparatus in which the hair preparation is arranged.

従来から毛髪の元素分析を行って体調診断を行う各種の特許文献が知られている。従来の特許第4065734号公報(特許文献1)では、毛髪又は体毛の毛根に含有されているカルシウムを検出し、検出したカルシウムの含有比率が、健常人の含有比率と比較して高い場合に精密検査の指標となる体調の検査方法が開示されている。   Conventionally, various patent documents for performing physical condition diagnosis by performing elemental analysis of hair are known. In Japanese Patent No. 4065734 (Patent Document 1), calcium contained in the hair or root of hair is detected, and the precision is high when the content ratio of the detected calcium is higher than the content ratio of a healthy person. A physical condition inspection method serving as an inspection index is disclosed.

また、従来の特許第4612355号公報(特許文献2)では、被検者の毛髪又は体毛を元素分析し、前記毛髪又は体毛のCa濃度をCa不足又はCa充足にそれぞれ対応するCa濃度の高いレベル又は低いレベルと比較し、前記比較から前記被検者のカルシウム代謝異常の検出を行う毛髪又は体毛によるカルシウム代謝異常の検出方法が開示されている。   Further, in Japanese Patent No. 462355 (Patent Document 2), the hair or body hair of the subject is subjected to elemental analysis, and the Ca concentration of the hair or body hair is a high Ca concentration level corresponding to Ca deficiency or Ca sufficiency, respectively. Alternatively, a method for detecting an abnormality in calcium metabolism by hair or body hair, which detects a calcium metabolism abnormality in the subject based on the comparison as compared with a low level, is disclosed.

特に、特許文献1及び特許文献2の両者は、毛髪の元素分析を行うときに、SPRING−8等の放射光施設を使用し、X線領域の放射光を入射X線として毛髪に照射し、毛髪から発生する蛍光X線により毛髪に含まれる元素の分布を導出している。放射光は強度が極端に大きいためにサイズの小さな毛髪でも蛍光X線分析が短時間で終了し、元素分布を容易に導出できる長所を有している。
しかしながら、放射光施設は共同利用の大型施設であり、施設を継続的に利用できるとしても短時間であり、多数の毛髪検査を商業的規模で事業実施するには不向きであり、実態としては時間的に不可能と云わざるを得ない。
In particular, both Patent Document 1 and Patent Document 2 use a synchrotron radiation facility such as SPRING-8 when performing elemental analysis of hair, and irradiate the hair with synchrotron radiation in the X-ray region as incident X-rays. The distribution of the elements contained in the hair is derived from the fluorescent X-rays generated from the hair. Since synchrotron radiation has an extremely high intensity, fluorescent X-ray analysis can be completed in a short time even for hair with a small size, and the element distribution can be easily derived.
However, the synchrotron radiation facility is a large-scale facility for joint use, and even if the facility can be used continuously, it is a short time, and it is not suitable for conducting a large number of hair tests on a commercial scale. It must be said that it is impossible.

そこで、近年急速に進歩している卓上型の蛍光X線分析装置を利用した毛髪の元素分析法が開発されるに至った。従来の特許第5372304号公報では、蛍光X線分析装置により、被検者由来の毛髪に含有されるミネラルの、前記毛髪に含有される硫黄に対する信号比率PXRF(S)を測定し、前記信号比率PXRF(S)から、前記毛髪に含有される前記ミネラルの元素含有率MXRFを算出する為に、この算出に使用する変換係数Fを、前記信号比率PXRF(S)と乗算する生体内元素検査方法であって、前記蛍光X線分析により、前記被検者以外から由来する毛髪である基準毛髪に含有される前記ミネラルの、前記基準毛髪に含有される前記硫黄に対する基準信号比率P0,XRF(S)を測定し、誘導結合プラズマ質量分析により、前記基準毛髪に含有される前記ミネラルの基準元素含有率M0、ICPを測定し、F=M0、ICP/P0、XRF(S)の式から、前記変換係数Fを算出する生体内元素検査方法が開示されている。 Thus, an elemental analysis method for hair using a desktop fluorescent X-ray analyzer, which has been making rapid progress in recent years, has been developed. In the conventional patent No. 5372304, the signal ratio P XRF (S) of the mineral contained in the hair derived from the subject to the sulfur contained in the hair is measured by a fluorescent X-ray analyzer, and the signal the ratio P XRF (S), in order to calculate the elemental content M XRF of the minerals contained in the hair, raw multiplying the transformation coefficients F to be used for this calculation, the signal ratio P XRF and (S) A method for in-vivo element inspection, wherein a reference signal ratio P of the mineral contained in reference hair, which is hair derived from other than the subject, to the sulfur contained in the reference hair is determined by fluorescent X-ray analysis. 0, XRF and (S) were measured by inductively coupled plasma mass spectrometry, measuring the reference element content M 0, ICP of the minerals contained in the reference hair, F = M 0, IC / From P 0, the formula of XRF (S), in vivo element inspecting method for calculating the transformation coefficient F is disclosed.

特許第4065734号公報Japanese Patent No. 4065734 特許第4612355号公報Japanese Patent No. 4612355 特許第5372304号公報Japanese Patent No. 5372304

特許文献3の技術は本願発明者等が開発した発明であり、本願発明者等は本願の図6に示す方法を用いて毛髪の蛍光X線分析を行った。
プレパラート基板101はアクリル製の樹脂基板であり、検査対象である毛髪111をプレパラート基板101の上に接触状態で配置する。次に、毛髪111の両端を粘着テープ112、112により接着し、毛髪111を緊張状態に張設した毛髪プレパラート110を作成した。更に、この毛髪111にX線源120から入射X線121を低角度で照射し、入射X線121がプレパラート基板101により全反射して、反射X線125も低角度で反射して放出される。毛髪111から蛍光X線123は上方に放射され、この蛍光X線123を検出器130で検出して、毛髪111の蛍光X線分析が行われた。
The technique of Patent Document 3 is an invention developed by the inventors of the present application, and the inventors of the present application performed fluorescent X-ray analysis of hair using the method shown in FIG. 6 of the present application.
The preparation substrate 101 is an acrylic resin substrate, and the hair 111 to be inspected is placed on the preparation substrate 101 in a contact state. Next, both ends of the hair 111 were adhered with adhesive tapes 112, 112, and a hair preparation 110 was prepared in which the hair 111 was stretched. Further, this hair 111 is irradiated with incident X-rays 121 from an X-ray source 120 at a low angle, the incident X-rays 121 are totally reflected by the preparation substrate 101, and the reflected X-rays 125 are also reflected and emitted at a low angle. . The fluorescent X-ray 123 was emitted upward from the hair 111, and this fluorescent X-ray 123 was detected by the detector 130, and the fluorescent X-ray analysis of the hair 111 was performed.

この研究を反復する中で、本願発明者等は、蛍光X線分析で得られる毛髪の元素分布に毛髪に元来含まれるはずが無い不純物元素が混入したり、毛髪に含まれる元素であっても異常にピーク値が高くなる事実を発見するに至った。この原因を追及する中で、毛髪をアクリル製のプレパラート基板に固定するときに、毛髪とプレパラート基板が相互に摩擦しあって毛髪が帯電し、空気中に浮遊する不純物元素やプレパラート基板表面に滞留する不純物元素が毛髪に静電吸着され、それらの不純物元素が元素分布に混入する事実を確認するに至った。しかも、全反射蛍光X線分析を行っても、プレパラート基板自体からの蛍光X線も僅かに混入する結果、不純物元素が増大することが分かった。
全反射型で無い蛍光X線分析装置を用いた場合には、入射X線がプレパラート基板を透過したり、プレパラート基板に浸入して反射したりするため、プレパラート基板自体から不純物蛍光X線が大量に放射され、毛髪からの蛍光X線の中に不純物蛍光X線がかなり含まれ結果、元素分布に大量の不純物元素が混入して毛髪の正確な元素分布の判断に間違いが生じる原因となっていた。
In repeating this research, the inventors of the present invention mixed in the elemental distribution of hair obtained by fluorescent X-ray analysis with an impurity element that should not be originally contained in hair, Even found the fact that the peak value is abnormally high. In pursuit of this cause, when fixing the hair to the acrylic preparation substrate, the hair and the preparation substrate rub against each other and the hair is charged and stays on the surface of the impurity element and the preparation substrate floating in the air. It has been confirmed that the impurity elements to be electrostatically adsorbed on the hair and that these impurity elements are mixed in the element distribution. In addition, even when total reflection X-ray fluorescence analysis was performed, it was found that the impurity elements increased as a result of the slight mixing of fluorescent X-rays from the preparation substrate itself.
When a fluorescent X-ray analyzer that is not a total reflection type is used, incident X-rays pass through the preparation substrate or enter and reflect the preparation substrate, so a large amount of impurity fluorescent X-rays are generated from the preparation substrate itself. As a result, a large amount of impurity fluorescent X-rays are included in the fluorescent X-rays from the hair, and as a result, a large amount of impurity elements are mixed in the element distribution, causing an error in the determination of the accurate element distribution of the hair. It was.

従って、本発明の第1の目的は、毛髪とプレパラート基板との相互摩擦による摩擦帯電を無くし、しかもプレパラート基板自体からの蛍光X線も発生させないプレパラート基板を提供し、このプレパラート基板を使用した毛髪プレパラートを提供することである。また、本発明の第2の目的は、サンプルである毛髪の高さ調整や位置調整、入射X線の入射角度調整等が容易になるプレパラート基板を提供することである。本発明の第3の目的は、前記毛髪プレパラートを蛍光X線装置内に配置して元素分析精度の高い毛髪蛍光X線装置を提供することである。   Accordingly, a first object of the present invention is to provide a preparation substrate that eliminates frictional charging due to mutual friction between the hair and the preparation substrate and that does not generate fluorescent X-rays from the preparation substrate itself, and hair using this preparation substrate. It is to provide a preparation. The second object of the present invention is to provide a preparation substrate that facilitates the height adjustment and position adjustment of hair as a sample, the incident angle adjustment of incident X-rays, and the like. A third object of the present invention is to provide a hair fluorescent X-ray apparatus with high elemental analysis accuracy by arranging the hair preparation in the fluorescent X-ray apparatus.

本発明者等は鋭意研究した結果、不純物元素の混入を予防するために、毛髪とプレパラート基板とが相互に摩擦接触することを無くす技術を着想するに至った。理想的には、毛髪を空気中に浮遊させて、浮遊状態の毛髪にX線を照射すれば摩擦帯電は生じず、しかもプレパラート基板自体からの蛍光X線もないはずである。このような浮遊配置に近い状態を実現すればよい。即ち、プレパラート基板に穴を開け、この穴を横断するように毛髪を掛け渡し、毛髪の両端を穴の周縁部に粘着テープなどで固定すれば、毛髪とプレパラート基板とが摩擦し合うことが無くなるから、静電吸着による不純物元素のノイズは除去できる。しかも、入射X線が照射される毛髪領域には穴があいているから、入射X線はプレパラート基板には照射されない。従って、プレパラート基板自体からの蛍光X線も消失させることができる。   As a result of diligent research, the present inventors have come up with a technique that eliminates the frictional contact between the hair and the preparation substrate in order to prevent contamination by impurity elements. Ideally, if the hair is suspended in air and X-rays are irradiated to the suspended hair, frictional charging will not occur, and there should be no fluorescent X-rays from the preparation substrate itself. A state close to such a floating arrangement may be realized. That is, if a hole is made in the preparation substrate, the hair is passed across the hole, and both ends of the hair are fixed to the peripheral portion of the hole with an adhesive tape or the like, the hair and the preparation substrate do not rub against each other. Therefore, the noise of the impurity element due to electrostatic adsorption can be removed. Moreover, since the hair region irradiated with the incident X-ray has a hole, the incident X-ray is not irradiated onto the preparation substrate. Therefore, the fluorescent X-rays from the preparation substrate itself can be eliminated.

本発明は上記課題を解決するために為されたものであり、本発明の第1の形態は、毛髪の蛍光X線分析に使用されるプレパラート基板であり、前記プレパラート基板に毛髪を張設する穴を開口し、前記穴を取り囲む周縁部に毛髪の両端を固定するプレパラート基板である。   The present invention has been made to solve the above problems, and a first embodiment of the present invention is a preparation substrate used for fluorescent X-ray analysis of hair, and the hair is stretched on the preparation substrate. It is a preparation substrate which opens a hole and fixes both ends of the hair to the peripheral portion surrounding the hole.

本発明の第2の形態は、前記プレパラート基板が樹脂基板から構成されるプレパラート基板である。   The second aspect of the present invention is a preparation substrate in which the preparation substrate is made of a resin substrate.

本発明の第3の形態は、第1形態又は第2形態に記載のプレパラート基板と、前記穴を横断するように掛け渡された毛髪と、前記毛髪の両端を前記穴を取り囲む周縁部に固定する固定手段から構成される毛髪プレパラートである。   According to a third aspect of the present invention, the preparation substrate according to the first aspect or the second aspect, the hair stretched across the hole, and both ends of the hair are fixed to a peripheral portion surrounding the hole. A hair preparation composed of fixing means.

本発明の第4の形態は、第3形態に記載の毛髪プレパラートを配置し、前記毛髪プレパラートの毛髪に入射X線を照射するX線源と、前記毛髪から放出される蛍光X線を検出する検出器を少なくとも有する毛髪蛍光X線装置である。   According to a fourth aspect of the present invention, the hair preparation described in the third aspect is disposed, and an X-ray source that irradiates incident X-rays to the hair of the hair preparation and fluorescent X-rays emitted from the hair are detected. It is a hair fluorescent X-ray apparatus having at least a detector.

本発明の第1の形態によれば、毛髪の蛍光X線分析に使用されるプレパラート基板であり、前記プレパラート基板に毛髪を張設する穴を開口し、前記穴を取り囲む周縁部に毛髪の両端を固定するプレパラート基板を提供できる。
プレパラート基板には穴が開いているから、この穴に試料である毛髪を掛け渡して毛髪の両端を周縁部に固定すれば、毛髪と穴の間には摩擦が生じない。従って、毛髪は摩擦帯電することが無いから、空気中の不純物元素を静電吸着することが無くなり、蛍光X線分析を行っても不純物元素がノイズとして混入することが無い。また、毛髪に入射X線を照射しても、毛髪の下側には穴しかないので、プレパラート基板からの蛍光X線が発生せず、プレパラート基板からの蛍光X線がノイズとして混入することが無くなるから、毛髪の元素分布を正確に精度よく導出することが可能になる。
また、プレパラート基板に穴があるから、プレパラート基板を上から見ても下から見ても、穴を通して前方を見ることができ、プレパラート基板の上下調整が容易になる。また、毛髪が穴に掛け渡されて浮遊した状態にあるから、毛髪に照射される入射X線の入射角度調整も容易になる利点がある。総じて、X線の調整効率が良くなる。
穴の形状については、丸形、四角形、三角形など種々の形状を採用できるが、回転対称性が一番高い円形が最も好適である。
According to the first aspect of the present invention, there is provided a preparation substrate used for fluorescent X-ray analysis of hair, wherein a hole for stretching the hair is opened in the preparation substrate, and both ends of the hair are surrounded by a peripheral portion surrounding the hole. Can be provided.
Since the prepared substrate has a hole, if the sample hair is placed over the hole and both ends of the hair are fixed to the peripheral edge, friction does not occur between the hair and the hole. Accordingly, since the hair is not frictionally charged, the impurity element in the air is not electrostatically adsorbed, and the impurity element is not mixed as noise even when the fluorescent X-ray analysis is performed. In addition, even if incident X-rays are applied to the hair, there are only holes on the lower side of the hair, so fluorescent X-rays from the preparation substrate are not generated, and fluorescent X-rays from the preparation substrate may be mixed as noise. Therefore, it is possible to accurately and accurately derive the hair element distribution.
Further, since the preparation substrate has a hole, the front can be seen through the hole regardless of whether the preparation substrate is viewed from above or from below, and the preparation substrate can be easily adjusted up and down. Further, since the hair is suspended over the hole, there is an advantage that it is easy to adjust the incident angle of incident X-rays applied to the hair. Overall, X-ray adjustment efficiency is improved.
As for the shape of the hole, various shapes such as a round shape, a square shape, and a triangular shape can be adopted, but a circular shape having the highest rotational symmetry is most preferable.

本発明の第2の形態によれば、前記プレパラート基板が樹脂基板から構成されるプレパラート基板である。樹脂から基板を成形すると、樹脂は柔軟性を有するから、穴を開ける途中でプレパラート基板が割れたり、欠けたりする危険性が少なく、穴を安全に開け易い利点がある。
また、樹脂基板の中でも透明樹脂基板が効果的である。透明樹脂基板を介して前方や後方が透いて見えるから位置調整や入射X線の入射角度調整などが容易に行える利点を有する。透明樹脂には、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、塩化ビニール、ポリスチレン、ABS樹脂、アクリル、メタクリア、ポリアミド、ポリカポネード、四フッ化エチレン、エチレン酸ビコポリマー、フィノール樹脂、メラミン、不飽和ポリエステル、エポキシ等があるが、これ以外の透明樹脂も利用できる。
According to the 2nd form of this invention, the said preparation substrate is a preparation substrate comprised from a resin substrate. When the substrate is molded from the resin, since the resin has flexibility, there is little risk that the prepared substrate is cracked or chipped while the hole is being formed, and there is an advantage that the hole can be safely opened.
Moreover, a transparent resin substrate is effective among the resin substrates. Since the front and rear can be seen through the transparent resin substrate, there is an advantage that position adjustment and incident X-ray incident angle adjustment can be easily performed. Transparent resins include polyethylene, polypropylene, polyethylene terephthalate, vinyl chloride, polystyrene, ABS resin, acrylic, methclear, polyamide, polycapade, tetrafluoroethylene, ethylene acid bicopolymer, finol resin, melamine, unsaturated polyester, epoxy, etc. However, other transparent resins can be used.

本発明の第3の形態によれば、第1形態又は第2形態に記載のプレパラート基板と、前記穴を横断するように掛け渡された毛髪と、前記毛髪の両端を前記穴を取り囲む周縁部に固定する固定手段から構成される毛髪プレパラートを提供できる。
毛髪をサンプルとして本発明のプレパラート基板に固定するには、まず毛髪の一端をプレパラート基板の穴を取り囲む周縁部に固定する。固定手段として粘着テープが有効であるが、瞬間接着剤でもよいし、周縁部に切り込まれたスリットに引っ掛けてもよいなど、種々の固定手段がある。一端を固定したら、毛髪をピンと緊張させた状態(張設状態)で他端を周縁部に固定する。他端の固定も粘着テープ、瞬間接着剤、スリットに引っ掛けるなどの種々の固定手段が利用できる。
このように、本発明のプレパラート基板にサンプルである毛髪を張設した毛髪プレパラートは、蛍光X線分析に際し有効である。全国からサンプルである毛髪を郵送すると、毛髪自体が微細であるため途中で消失する危険性がある。そこで、被験者が自分の毛髪をプレパラート基板に装着した毛髪プレパラートを作成し、この毛髪プレパラートを分析機関に郵送すれば、毛髪サンプルが消失する危険性は極めて低くなる。毛髪プレパラートは一定の大きさを有するから自然に消失してしまうことは極めて少ないから、安心である。しかも、分析機関では毛髪プレパラートを作成する手間が省け、送られてきた毛髪プレパラートを直ちに蛍光X線分析に掛けることができる利点がある。
According to the 3rd form of this invention, the preparation board as described in the 1st form or the 2nd form, the hair spanned across the said hole, and the peripheral part which surrounds the said hole at the both ends of the said hair A hair preparation comprising fixing means for fixing to the hair can be provided.
In order to fix the hair as a sample to the preparation substrate of the present invention, first, one end of the hair is fixed to the peripheral portion surrounding the hole of the preparation substrate. An adhesive tape is effective as the fixing means, but there are various fixing means such as an instantaneous adhesive or hooking on a slit cut in the peripheral edge. When one end is fixed, the other end is fixed to the peripheral edge in a state where the hair is tensioned with a pin (stretched state). For fixing the other end, various fixing means such as an adhesive tape, an instantaneous adhesive, and a hook can be used.
As described above, the hair preparation in which the sample hair is stretched on the preparation substrate of the present invention is effective in the fluorescent X-ray analysis. When the sample hair is mailed from all over the country, there is a risk that the hair itself disappears in the middle because it is fine. Therefore, if the subject creates a hair preparation with his hair attached to the preparation substrate and mails the hair preparation to the analysis organization, the risk of the hair sample disappearing is extremely low. Since the hair preparation has a certain size, it does not easily disappear naturally, so it is safe. In addition, there is an advantage that the laboratories for preparing the hair preparation can be saved and the sent hair preparation can be immediately subjected to fluorescent X-ray analysis.

本発明の第4の形態によれば、第3形態に記載の毛髪プレパラートを配置し、前記毛髪プレパラートの毛髪に入射X線を照射するX線源と、前記毛髪から放出される蛍光X線を検出する検出器を少なくとも有する毛髪蛍光X線装置を提供できる。
前述したように、本発明の毛髪プレパラートでは、掛け渡された毛髪の下部には穴が開口されており、入射X線は上方から毛髪に照射されて透過X線は穴を通過してもよいし、また入射X線は下方から穴を通過して毛髪に照射され透過X線は上方へと逃げ去ってもよく、更に基板に対し極めて低角度で毛髪に照射され透過X線は反射X線として極めて低角度で反射してもよく、また更には鋭角度で毛髪に入射されてもよい等、種々の形態をとることができる。しかも、毛髪の下部は穴が開いており、この穴を視認しながら入射X線の入射角度を調整でき、プレパラート基板の高さ調整や位置調整が容易になり、蛍光X線装置として独特の利点を有するものである。
According to the fourth aspect of the present invention, the hair preparation described in the third aspect is arranged, an X-ray source that irradiates the hair of the hair preparation with incident X-rays, and fluorescent X-rays emitted from the hair. A hair fluorescent X-ray apparatus having at least a detector for detection can be provided.
As described above, in the hair preparation of the present invention, a hole is opened in the lower part of the hair that has been stretched, and the incident X-ray may be applied to the hair from above, and the transmitted X-ray may pass through the hole. In addition, incident X-rays may pass through the hole from below and irradiate the hair, and transmitted X-rays may escape upward, and the hair is irradiated at a very low angle with respect to the substrate, and the transmitted X-rays are reflected X-rays. As such, it may be reflected at an extremely low angle, or may be incident on the hair at an acute angle. In addition, there is a hole in the lower part of the hair, and the incident angle of incident X-rays can be adjusted while visually recognizing this hole, making it easy to adjust the height and position of the preparation substrate. It is what has.

図1は、本発明に係るプレパラート基板において各種形状の穴が開口された状態を示す斜視図である。FIG. 1 is a perspective view showing a state where holes of various shapes are opened in a preparation substrate according to the present invention. 図2は、本発明に係るプレパラート基板の穴に毛髪を張設固定した各種の毛髪プレパラートの斜視図である。FIG. 2 is a perspective view of various hair preparations in which hair is stretched and fixed in the holes of the preparation substrate according to the present invention. 図3は、本発明に係る毛髪プレパラートの毛髪に対し低角度で入射X線を照射して、上方へ放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。FIG. 3 is a schematic explanatory diagram of a hair fluorescent X-ray apparatus that detects X-rays emitted upward by irradiating the hair of the hair preparation according to the present invention with incident X-rays at a low angle. 図4は、本発明に係る毛髪プレパラートの毛髪に対し高角度で入射X線を照射して、高角度で上方に放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。FIG. 4 is a schematic explanatory view of a hair fluorescent X-ray apparatus that irradiates the hair of the hair preparation according to the present invention with incident X-rays at a high angle and detects fluorescent X-rays emitted upward at a high angle. . 図5は、本発明に係る毛髪プレパラートの毛髪に対し下方から穴を透過して入射X線を照射して、高角度で下方に放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。FIG. 5 shows an outline of a hair fluorescent X-ray apparatus that detects X-ray fluorescence radiated downward at a high angle by irradiating incident X-rays through the hole from below with respect to the hair of the hair preparation according to the present invention. It is explanatory drawing. 図6は、従来の穴無しプレパラート基板に毛髪を貼り付けて、毛髪に対し超低角度で入射X線を照射して上方へ放射される蛍光X線を検出する全反射型蛍光X線装置の概略説明図である。FIG. 6 shows a total reflection type fluorescent X-ray apparatus in which hair is attached to a conventional holeless preparation substrate, and incident X-rays are irradiated to the hair at an ultra-low angle to detect fluorescent X-rays emitted upward. It is a schematic explanatory drawing.

以下に、本発明に係るプレパラート基板、毛髪プレパラート及び毛髪蛍光X線装置の実施形態を図面に従って詳細に説明する。
図1は、本発明に係るプレパラート基板において各種形状の穴が開口された状態を示す斜視図である。穴の形状は特に限定されないが、典型例として(1A)〜(1C)を次に示す。具体的には、(1A)は、中央に丸形の穴3を開口したプレパラート基板1の斜視図である。穴3を取り囲んで周縁部5が形成されており、この周縁部5に後述する毛髪の両端が固定される。(1B)は、中央に四角形の穴3を開口したプレパラート基板1の斜視図である。穴3を取り囲んで周縁部5が形成され、この周縁部5に後述する毛髪の両端が固定される。(1C)は、中央に三角形の穴3を開口したプレパラート基板1の斜視図である。穴3を取り囲んで周縁部5が形成され、この周縁部5に後述する毛髪の両端が固定される。
Hereinafter, embodiments of a preparation substrate, a hair preparation, and a hair fluorescent X-ray apparatus according to the present invention will be described in detail with reference to the drawings.
FIG. 1 is a perspective view showing a state where holes of various shapes are opened in a preparation substrate according to the present invention. Although the shape of a hole is not specifically limited, (1A)-(1C) are shown as a typical example below. Specifically, (1A) is a perspective view of the prepared substrate 1 having a circular hole 3 opened in the center. A peripheral edge 5 is formed surrounding the hole 3, and both ends of the hair described later are fixed to the peripheral edge 5. (1B) is a perspective view of the prepared substrate 1 having a square hole 3 opened at the center. A peripheral edge 5 is formed surrounding the hole 3, and both ends of the hair described later are fixed to the peripheral edge 5. (1C) is a perspective view of the prepared substrate 1 having a triangular hole 3 opened in the center. A peripheral edge 5 is formed surrounding the hole 3, and both ends of the hair described later are fixed to the peripheral edge 5.

プレパラート基板1の材質は特に限定されないが、穴3を開口するときにプレパラート基板が割れたり、開口した穴の周りが欠けたりしない材質が選択される。また、プレパラート基板1として、透明基板が推奨される。透明基板では、基板を透かして前方や後方の状態が確認でき、プレパラート基板の高さ調整や位置調整が容易になり、入射X線の入射方向も透かして調整できるから調整効率が良い利点がある。更に、摩擦帯電し難い/又はしない材質が望まれ、金属基板や導電性樹脂基板が良い。従って、価格的に安価なのは柔軟性がある樹脂基板で、また透明樹脂基板が良く、更には導電性透明樹脂基板が最も良い。ガラスやセラミック等の無機基板は割れ欠けの無い開口法で穴が形成される。金属基板は穴の開口時に割れ欠けせず、しかも導電性があるが、不透明の弱点がある。   The material of the preparation substrate 1 is not particularly limited, but a material that does not break the preparation substrate when the hole 3 is opened or does not chip around the opened hole is selected. A transparent substrate is recommended as the preparation substrate 1. With a transparent substrate, the front and rear states can be confirmed through the substrate, the height and position of the slide substrate can be easily adjusted, and the incident X-ray incident direction can also be adjusted through the adjustment. . Furthermore, a material that is difficult and / or free from frictional charging is desired, and a metal substrate or a conductive resin substrate is preferable. Accordingly, the inexpensive resin substrate is a flexible resin substrate, a transparent resin substrate is preferable, and a conductive transparent resin substrate is the best. In an inorganic substrate such as glass or ceramic, holes are formed by an opening method without cracks. The metal substrate does not crack when the hole is opened, and is conductive, but has an opaque weakness.

樹脂基板としては、現有の全ての樹脂が利用される。特に、透明樹脂としては、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、塩化ビニール、ポリスチレン、ABS樹脂、アクリル、メタクリア、ポリアミド、ポリカポネード、四フッ化エチレン、エチレン酸ビコポリマー、フィノール樹脂、メラミン、不飽和ポリエステル、エポキシ等や、これ以外の透明樹脂も利用できる。導電性樹脂としては、ポリチオフェン系樹脂、ポリアセチレン系樹脂、ポリアニリン系樹脂、ポリピロール系樹脂が利用できる。   As the resin substrate, all existing resins are used. In particular, transparent resins include polyethylene, polypropylene, polyethylene terephthalate, vinyl chloride, polystyrene, ABS resin, acrylic, metaclear, polyamide, polycapade, tetrafluoroethylene, ethylene acid bicopolymer, finol resin, melamine, unsaturated polyester, epoxy Other transparent resins can also be used. As the conductive resin, polythiophene resin, polyacetylene resin, polyaniline resin, or polypyrrole resin can be used.

図2は、本発明に係るプレパラート基板の穴に毛髪を張設固定した各種の毛髪プレパラートの斜視図である。
典型例として(1A)〜(1C)を次に示す。具体的には、(1A)は、中央に丸形の穴3を開口したプレパラート基板1を用いた毛髪プレパラート10を示し、毛髪11の両端が粘着テープからなる固定手段12により周縁部5、5で張設状態で固定されている。(1B)は、中央に四角形の穴3を開口したプレパラート基板1を用いた毛髪プレパラート10を示し、毛髪11の両端が瞬間接着剤からなる固定手段12により周縁部5、5で張設状態に固定されている。(1C)は、中央に三角形の穴3を開口したプレパラート基板1を用いた毛髪プレパラート10を示し、毛髪11の両端がコ字型針のステープルからなる固定手段12により周縁部5、5で張設状態で固定されている。従って、固定手段12としては種々存在し、上記以外の固定手段も本発明には包含される。
以上のように、毛髪11の両端が固定手段12により周縁部5、5で固定され、毛髪11は穴3に掛け渡された状態でピンと張設されている。従って、毛髪11は周縁部5以外ではプレパラート基板1と接触しておらず、毛髪11が擦過により摩擦帯電することは物理的に回避できる。また、穴3を通して入射X線を出し入れできるため、プレパラート基板1からの蛍光X線は遮断され、毛髪11以外の蛍光X線は遮断され、不純物元素が元素分布に含まれない為、毛髪11の正確で精密な元素分布を導出できる。
FIG. 2 is a perspective view of various hair preparations in which hair is stretched and fixed in the holes of the preparation substrate according to the present invention.
As typical examples, (1A) to (1C) are shown below. Specifically, (1A) shows a hair preparation 10 using a preparation substrate 1 having a round hole 3 in the center, and the peripheral portions 5 and 5 are fixed by fixing means 12 having both ends of the hair 11 made of adhesive tape. It is fixed in tension. (1B) shows a hair preparation 10 using a preparation substrate 1 having a square hole 3 opened in the center, and both ends of the hair 11 are stretched around the peripheral portions 5 and 5 by fixing means 12 made of instantaneous adhesive. It is fixed. (1C) shows a hair preparation 10 using a preparation substrate 1 having a triangular hole 3 opened in the center, and both ends of the hair 11 are stretched at the peripheral portions 5 and 5 by fixing means 12 made of staples of U-shaped needles. It is fixed in the installed state. Therefore, various fixing means 12 exist, and fixing means other than those described above are also included in the present invention.
As described above, both ends of the hair 11 are fixed at the peripheral portions 5 and 5 by the fixing means 12, and the hair 11 is stretched around the pin 3 in a state of being stretched over the hole 3. Accordingly, the hair 11 is not in contact with the preparation substrate 1 except for the peripheral portion 5, and the hair 11 can be physically avoided from being frictionally charged by rubbing. In addition, since the incident X-rays can be taken in and out through the hole 3, the fluorescent X-rays from the preparation substrate 1 are blocked, the fluorescent X-rays other than the hair 11 are blocked, and the impurity element is not included in the element distribution. Accurate and precise element distribution can be derived.

図3は、本発明に係る毛髪プレパラートの毛髪に対し低角度で入射X線を照射して、上方へ放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。
本発明の第1形態に係る毛髪蛍光X線装置40は、装置内に配置された毛髪プレパラート10と、この毛髪11に入射X線21を照射するX線源20と、毛髪11から放射された蛍光X線23を入射させて検出する検出器30から構成されている。
特に、上記第1形態の蛍光X線装置は、一般に全反射型蛍光X線装置と呼ばれているが、穴の開いていないプレパラート基板1を用いたときに、低角度でプレパラート基板1に入射すると、入射X線21は基板1で全反射するため、プレパラート基板1からの蛍光X線は放射され難い特性を有する。しかし、毛髪11とプレパラート基板1が相互に接触するため、基板1からの蛍光X線を完全に遮断できるものではなく、プレパラート基板1から若干の蛍光X線がノイズとして混入する性質を有している。
他方、本実施形態の毛髪蛍光X線装置40は、入射X線21の入射角度は極めて低角度に設定されるが、入射X線21は毛髪11で反射して反射X線25となるか、穴3を透過するだけだからプレパラート基板1に入射せず、プレパラート基板1からの蛍光X線は全く発生しない。従って、毛髪11からの蛍光X線だけが発生し、この蛍光X線23だけが検出器30に入射するから、蛍光X線23を分析して得られる毛髪11の元素分布には不純物元素は含有されず、毛髪11内の正確な元素分布を導出することができる。
また、蛍光X線装置を初期調整するときに、穴3を透かして内部構造が確認できるから、入射X線21の入射角度の調整や毛髪プレパラート10の高さ調整と位置調整が容易に行える利点を有する。毛髪11は穴3と接触していないから、摩擦帯電は無く、毛髪11は空気中の不純物元素を静電吸着することは無い。従って、本形態の毛髪蛍光X線装置40を使用すれば、ノイズをほぼ完全に遮断した蛍光X線装置40を提供でき、毛髪11の元素分布を正確かつ精密に導出できる効果を有する。
FIG. 3 is a schematic explanatory diagram of a hair fluorescent X-ray apparatus that detects X-rays emitted upward by irradiating the hair of the hair preparation according to the present invention with incident X-rays at a low angle.
The hair fluorescent X-ray device 40 according to the first embodiment of the present invention is radiated from the hair 11, the X-ray source 20 that irradiates the hair 11 with the incident X-ray 21, and the hair 11. It comprises a detector 30 that detects by making fluorescent X-rays 23 incident.
In particular, the fluorescent X-ray apparatus of the first embodiment is generally called a total reflection type fluorescent X-ray apparatus. However, when the prepared preparation substrate 1 having no holes is used, it enters the preparation substrate 1 at a low angle. Then, since the incident X-rays 21 are totally reflected by the substrate 1, the fluorescent X-rays from the preparation substrate 1 have a characteristic that is not easily emitted. However, since the hair 11 and the preparation substrate 1 are in contact with each other, the fluorescent X-rays from the substrate 1 cannot be completely blocked, and some fluorescent X-rays are mixed from the preparation substrate 1 as noise. Yes.
On the other hand, in the hair fluorescent X-ray device 40 of the present embodiment, the incident angle of the incident X-ray 21 is set to a very low angle, but the incident X-ray 21 is reflected by the hair 11 and becomes the reflected X-ray 25, Since it only passes through the hole 3, it does not enter the preparation substrate 1, and no fluorescent X-rays are generated from the preparation substrate 1. Accordingly, only the fluorescent X-rays from the hair 11 are generated, and only the fluorescent X-rays 23 enter the detector 30. Therefore, the elemental distribution of the hair 11 obtained by analyzing the fluorescent X-rays 23 contains an impurity element. The exact element distribution in the hair 11 can be derived.
Further, when the fluorescent X-ray apparatus is initially adjusted, the internal structure can be confirmed through the hole 3, so that the incident angle of the incident X-ray 21 and the height and position of the hair preparation 10 can be easily adjusted. Have Since the hair 11 is not in contact with the hole 3, there is no frictional charge, and the hair 11 does not electrostatically adsorb impurity elements in the air. Therefore, if the hair fluorescent X-ray apparatus 40 according to the present embodiment is used, the fluorescent X-ray apparatus 40 in which noise is almost completely blocked can be provided, and the element distribution of the hair 11 can be derived accurately and precisely.

図4は、本発明に係る毛髪プレパラートの毛髪に対し高角度で入射X線を照射して、高角度で上方に放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。
図示される本発明の第2形態に係る毛髪蛍光X線装置40は、装置内に配置された毛髪プレパラート10と、この毛髪11に高角度で入射X線21を照射するX線源20と、毛髪11から高角度に放射された蛍光X線23を入射させて検出する検出器30から構成されている。
第2形態の装置では、穴の開いていないプレパラート基板1を用いると、高角度でプレパラート基板1に入射するから、入射X線21は基板1を透過するため、プレパラート基板1から大量の蛍光X線が放射される弱点を有する。従って、穴無しプレパラート基板からの大量の蛍光X線がノイズとして混入するため、微細サンプルである毛髪の元素分析がノイズの中に埋没する弱点を有する。
これに対し、本実施形態の毛髪蛍光X線装置40では穴有り基板を用いるから、入射X線21の入射角度が高角度に設定されて、入射X線21が毛髪11を透過しても、入射X線21は穴3を透過するだけだからプレパラート基板1に入射せず、プレパラート基板1からの蛍光X線は全く発生しない。従って、毛髪11からの蛍光X線だけが発生し、この蛍光X線23だけが検出器30に入射するから、蛍光X線23を分析して得られる毛髪11の元素分布には不純物元素は全く含有されず、毛髪11内の正確な元素分布を導出することができる。
また、第1形態と同様に、蛍光X線装置を初期調整するときに、穴3を透かして内部構造が確認できるから、入射X線21の入射角度の調整や毛髪プレパラート10の高さ調整と位置調整が容易に行える利点を有する。毛髪11は穴3と接触していないから、摩擦帯電は無く、毛髪11は空気中の不純物元素を静電吸着することは無い。従って、本形態の毛髪蛍光X線装置40を使用すれば、ノイズをほぼ完全に遮断した蛍光X線装置40を提供でき、毛髪11の元素分布を正確かつ精密に導出できる利点を有する。
FIG. 4 is a schematic explanatory view of a hair fluorescent X-ray apparatus that irradiates the hair of the hair preparation according to the present invention with incident X-rays at a high angle and detects fluorescent X-rays emitted upward at a high angle. .
The hair fluorescent X-ray apparatus 40 according to the second embodiment of the present invention shown in the figure is a hair preparation 10 arranged in the apparatus, an X-ray source 20 that irradiates the hair 11 with incident X-rays 21 at a high angle, The detector 30 is configured to detect the fluorescent X-rays 23 emitted from the hair 11 at a high angle.
In the apparatus of the second embodiment, when the preparation substrate 1 having no holes is used, it enters the preparation substrate 1 at a high angle. Therefore, since the incident X-rays 21 are transmitted through the substrate 1, a large amount of fluorescent X is emitted from the preparation substrate 1. It has a weak point where the line is radiated. Therefore, since a large amount of fluorescent X-rays from the preparation substrate without holes is mixed as noise, the elemental analysis of hair as a fine sample has a weakness that is buried in the noise.
In contrast, since the hair fluorescent X-ray apparatus 40 of the present embodiment uses a substrate with holes, even if the incident angle of the incident X-ray 21 is set to a high angle and the incident X-ray 21 passes through the hair 11, Since the incident X-ray 21 only passes through the hole 3, it does not enter the preparation substrate 1, and no fluorescent X-rays are generated from the preparation substrate 1. Accordingly, only the fluorescent X-rays from the hair 11 are generated, and only the fluorescent X-rays 23 are incident on the detector 30. Therefore, there is no impurity element in the element distribution of the hair 11 obtained by analyzing the fluorescent X-rays 23. It is not contained, and an accurate element distribution in the hair 11 can be derived.
Similarly to the first embodiment, when the fluorescent X-ray apparatus is initially adjusted, the internal structure can be confirmed through the hole 3, so that the incident angle of the incident X-ray 21 and the height of the hair preparation 10 can be adjusted. There is an advantage that the position can be easily adjusted. Since the hair 11 is not in contact with the hole 3, there is no frictional charge, and the hair 11 does not electrostatically adsorb impurity elements in the air. Therefore, if the hair fluorescent X-ray apparatus 40 of this embodiment is used, the fluorescent X-ray apparatus 40 in which noise is almost completely blocked can be provided, and the element distribution of the hair 11 can be derived accurately and precisely.

図5は、本発明に係る毛髪プレパラートの毛髪に対し下方から穴を透過して入射X線を照射して、高角度で下方に放射される蛍光X線を検出する毛髪蛍光X線装置の概略説明図である。
図示される本発明の第3形態に係る毛髪蛍光X線装置40は、装置内に配置された毛髪プレパラート10と、この毛髪11に下側からほぼ垂直に入射X線21を照射するX線源20と、毛髪11から下側に高角度に放射された蛍光X線23を入射させて検出する検出器30から構成されている。
第3形態の装置では、穴の開いていないプレパラート基板1を用いると、入射X線21は垂直上方へとプレパラート基板1に入射するから、入射X線21は基板1を透過するため、プレパラート基板1から大量の蛍光X線が放射される弱点がある。つまり、穴無しプレパラート基板からの大量の蛍光X線が下方にノイズとして放射されて毛髪11からの蛍光X線に混入し、微細サンプルである毛髪の元素分析がノイズの中に埋没する弱点を有する。
これに対し、本実施形態の毛髪蛍光X線装置40では穴有り基板を用いるから、入射X線21がほぼ垂直上方に入射し、毛髪11を透過しても、入射X線21は穴3を透過するだけだからプレパラート基板1には入射せず、プレパラート基板1からの蛍光X線は全く発生しない。従って、毛髪11からの蛍光X線だけが発生し、この蛍光X線23だけが検出器30に入射するから、蛍光X線23を分析して得られる毛髪11の元素分布には不純物元素は全く含有されず、毛髪11内の正確な元素分布を導出することができる。
更に、第1形態と同様に、蛍光X線装置を初期調整するときに、穴3を透かして内部構造が確認できるから、入射X線21の入射角度の調整や毛髪プレパラート10の高さ調整と位置調整が容易に行える利点を有する。毛髪11は穴3と接触していないから、摩擦帯電は無く、毛髪11は空気中の不純物元素を静電吸着することは無い。従って、本形態の毛髪蛍光X線装置40を使用すれば、ノイズをほぼ完全に遮断した蛍光X線装置40を提供でき、毛髪11の元素分布を正確かつ精密に導出できる利点を有する。
FIG. 5 shows an outline of a hair fluorescent X-ray apparatus that detects X-ray fluorescence radiated downward at a high angle by irradiating incident X-rays through the hole from below with respect to the hair of the hair preparation according to the present invention. It is explanatory drawing.
The hair fluorescent X-ray device 40 according to the third embodiment of the present invention shown in the figure is a hair preparation 10 arranged in the device, and an X-ray source that irradiates the hair 11 with incident X-rays 21 almost vertically from below. 20 and a detector 30 that detects the fluorescent X-rays 23 radiated from the hair 11 downward at a high angle.
In the apparatus of the third embodiment, when the preparation substrate 1 having no holes is used, since the incident X-ray 21 enters the preparation substrate 1 vertically upward, the incident X-ray 21 passes through the substrate 1. There is a weak point where a large amount of fluorescent X-rays is emitted from 1. That is, a large amount of fluorescent X-rays from the preparation substrate without holes is emitted downward as noise and mixed into the fluorescent X-rays from the hair 11, and the elemental analysis of the hair, which is a fine sample, has a weakness that is buried in the noise. .
On the other hand, since the hair fluorescent X-ray apparatus 40 of this embodiment uses a substrate with holes, even if the incident X-rays 21 are incident almost vertically upward and pass through the hair 11, the incident X-rays 21 pass through the holes 3. Since it is only transmitted, it does not enter the preparation substrate 1 and no fluorescent X-rays are generated from the preparation substrate 1. Accordingly, only the fluorescent X-rays from the hair 11 are generated, and only the fluorescent X-rays 23 are incident on the detector 30. Therefore, there is no impurity element in the element distribution of the hair 11 obtained by analyzing the fluorescent X-rays 23. It is not contained, and an accurate element distribution in the hair 11 can be derived.
Further, as in the first embodiment, when the fluorescent X-ray apparatus is initially adjusted, the internal structure can be confirmed through the hole 3, so that the incident angle of the incident X-ray 21 and the height of the hair preparation 10 can be adjusted. There is an advantage that the position can be easily adjusted. Since the hair 11 is not in contact with the hole 3, there is no frictional charge, and the hair 11 does not electrostatically adsorb impurity elements in the air. Therefore, if the hair fluorescent X-ray apparatus 40 of this embodiment is used, the fluorescent X-ray apparatus 40 in which noise is almost completely blocked can be provided, and the element distribution of the hair 11 can be derived accurately and precisely.

本発明の穴開きプレパラート基板1を用いると、入射X線21の入射方向と蛍光X線23の放射方向がどんな配置の従来蛍光X線装置であっても、毛髪11の背面は穴3だけであり、プレパラート基板1からの蛍光X線はほぼ完全に発生せず、毛髪11からの蛍光X線だけを検出器30に入射させることができ、毛髪11の元素分布を正確且つ精密に測定できる利点を有する。   Using the perforated preparation substrate 1 of the present invention, the back surface of the hair 11 is only the hole 3 regardless of the arrangement of the incident direction of the incident X-ray 21 and the emission direction of the fluorescent X-ray 23. There is an advantage that the fluorescent X-rays from the preparation substrate 1 are not almost completely generated, and only the fluorescent X-rays from the hair 11 can be incident on the detector 30, and the element distribution of the hair 11 can be measured accurately and precisely. Have

本発明は、上記実施形態や変形例に限定されるものではなく、本発明の技術的思想を逸脱しない範囲における種々変形例、設計変更などをその技術的範囲内に包含するものであることは云うまでもない。   The present invention is not limited to the above-described embodiments and modifications, and includes various modifications and design changes within the technical scope without departing from the technical idea of the present invention. Needless to say.

以上詳述したように、本発明に係る穴有りのプレパラート基板、毛髪プレパラート及び毛髪蛍光X線装置を使用すれば、毛髪の正確且つ精密な元素分布を導出することができ、従来の穴無しプレパラート基板を用いて導出した毛髪の元素分布よりも正確性と精度において格段に優れた元素分布を導出できるようになった。   As described above in detail, if the preparation substrate with holes, hair preparation and hair fluorescent X-ray apparatus according to the present invention are used, an accurate and precise element distribution of hair can be derived, and the conventional preparation without holes is provided. It is now possible to derive an element distribution that is far superior in accuracy and precision than the elemental distribution of hair derived using a substrate.

1 プレパラート基板
3 穴
5 周縁部
10 毛髪プレパラート
11 毛髪
12 固定手段
20 X線源
21 入射X線
23 蛍光X線
25 反射X線
30 検出器
40 毛髪蛍光X線装置
101 プレパラート基板
110 毛髪プレパラート
111 毛髪
112 粘着テープ
120 X線源
121 入射X線
123 蛍光X線
125 反射X線
130 検出器
DESCRIPTION OF SYMBOLS 1 Preparation substrate 3 Hole 5 Peripheral part 10 Hair preparation 11 Hair 12 Fixing means 20 X-ray source 21 Incident X-ray 23 Fluorescence X-ray 25 Reflected X-ray 30 Detector 40 Hair fluorescence X-ray apparatus 101 Preparation substrate 110 Hair preparation 111 Hair 112 Adhesive tape 120 X-ray source 121 Incident X-ray 123 Fluorescent X-ray 125 Reflected X-ray 130 Detector

Claims (4)

毛髪の蛍光X線分析に使用されるプレパラート基板であり、
毛髪を張設する穴開口され
前記穴を取り囲む周縁部に毛髪の両端を固定して使用され、
前記穴に毛髪を張設した状態で郵送可能であり、
樹脂が利用された基板であることを特徴とするプレパラート基板。
It is a preparation substrate used for fluorescent X-ray analysis of hair,
Holes which stretched hair is opened,
Used to fix both ends of the hair to the periphery surrounding the hole ,
Can be mailed with the hair stretched in the hole,
A preparation substrate characterized by being a substrate using a resin .
毛髪の蛍光X線分析に使用されるプレパラート基板であり、
毛髪を張設する穴開口され
前記穴を取り囲む周縁部に毛髪の両端を固定して使用され、
導電性基板であることを特徴とするプレパラート基板。
It is a preparation substrate used for fluorescent X-ray analysis of hair,
Holes which stretched hair is opened,
Used to fix both ends of the hair to the periphery surrounding the hole ,
A preparation substrate, which is a conductive substrate.
請求項1又は2に記載のプレパラート基板と、前記穴を横断するように掛け渡された毛髪と、前記毛髪の両端を前記穴を取り囲む周縁部に固定する固定手段から構成されることを特徴とする毛髪プレパラート。 The preparation substrate according to claim 1, comprising hair prepared so as to cross the hole, and fixing means for fixing both ends of the hair to a peripheral portion surrounding the hole. Hair preparation. 請求項3に記載の毛髪プレパラートを配置し、前記毛髪プレパラートの毛髪に入射X線を照射するX線源と、前記毛髪から放出される蛍光X線を検出する検出器を少なくとも有することを特徴とする毛髪蛍光X線装置。
The hair preparation according to claim 3, wherein the hair preparation has at least an X-ray source that irradiates the hair of the hair preparation with incident X-rays, and a detector that detects fluorescent X-rays emitted from the hair. Hair fluorescent X-ray device.
JP2014162865A 2014-08-08 2014-08-08 Preparation substrate, hair preparation and hair fluorescent X-ray apparatus Expired - Fee Related JP6460559B2 (en)

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