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JP6480711B2 - Rolling device - Google Patents
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JP6480711B2 - Rolling device - Google Patents

Rolling device Download PDF

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JP6480711B2
JP6480711B2 JP2014231380A JP2014231380A JP6480711B2 JP 6480711 B2 JP6480711 B2 JP 6480711B2 JP 2014231380 A JP2014231380 A JP 2014231380A JP 2014231380 A JP2014231380 A JP 2014231380A JP 6480711 B2 JP6480711 B2 JP 6480711B2
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Prior art keywords
rolling
steel member
components
outer ring
steel
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JP2016094990A (en
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直哉 長谷川
直哉 長谷川
工 藤田
工 藤田
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NTN Corp
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NTN Corp
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Priority to PCT/JP2015/081890 priority patent/WO2016076401A1/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C19/00Bearings with rolling contact, for exclusively rotary movement
    • F16C19/02Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
    • F16C19/04Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly
    • F16C19/06Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly with a single row or balls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/32Balls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/62Selection of substances
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/64Special methods of manufacture
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/66Special parts or details in view of lubrication

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Rolling Contact Bearings (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Description

本発明は転がり軸受などの転動装置に関する。   The present invention relates to a rolling device such as a rolling bearing.

転がり軸受をはじめとする転動装置は、転動部の潤滑状態が悪く油膜形成が不十分になる環境で使用されるとピーリングや焼き付き等の表面損傷やこれらを起点としたはく離が発生する。例えば非特許文献1によれば、転がり軸受の内外輪ところの間で、潤滑状態の過酷さを示す油膜パラメータΛが約1.2以上になる条件では転がり軸受の寿命は長くなるが、Λが1.2以下となる条件では、転動部に表面起点型のはく離が起き、転がり軸受寿命は低下する。実際に転動部の油膜形成が不十分になる環境で使用される転がり軸受に、自動車等のトランスミッションやエアコンディショナーのコンプレッサーに使用されるものがある。   When a rolling device such as a rolling bearing is used in an environment in which the rolling portion is poorly lubricated and the oil film is not sufficiently formed, surface damage such as peeling and seizure, and peeling starting from these damages occur. For example, according to Non-Patent Document 1, the life of a rolling bearing becomes longer when the oil film parameter Λ indicating the severity of the lubrication state is about 1.2 or more between the inner and outer rings of the rolling bearing. Under the condition of 1.2 or less, surface-origin type peeling occurs at the rolling part, and the rolling bearing life is reduced. Some rolling bearings used in an environment where oil film formation in the rolling part is actually insufficient are used in transmissions for automobiles and compressors for air conditioners.

トランスミッション用転がり軸受では、使用温度が高くかつ粘度の低い潤滑油が使用されるため、油膜形成性が悪く表面損傷が起こりやすい。トランスミッション用転がり軸受の表面損傷対策としては、特許文献1に記載されている、針状ころ軸受のころもしくは内外輪の転動部に微小凹部を形成させ、その凹部に固体潤滑剤を被覆する方法が知られている。   In a rolling bearing for a transmission, since a lubricating oil having a high operating temperature and a low viscosity is used, oil film formation is poor and surface damage is likely to occur. As a countermeasure for surface damage of a rolling bearing for a transmission, a method of forming a minute recess in a roller or inner and outer ring rolling portion of a needle roller bearing and coating the recess with a solid lubricant as described in Patent Document 1 It has been known.

エアコンディショナーのコンプレッサー内部では、冷媒中に潤滑油が存在しており、コンプレッサーの圧縮時に冷媒の液化が起こる。潤滑油と液化した冷媒の混合は、転がり軸受の油膜形成性を悪化させるため、表面損傷が発生しやすくなる。コンプレッサー用転がり軸受の表面損傷対策としては、特許文献2に記載されている、転動部に微小凹部をランダムに形成し、油膜形成性を向上させる方法が知られている。   Inside the compressor of the air conditioner, lubricating oil is present in the refrigerant, and the refrigerant liquefies when the compressor is compressed. The mixing of the lubricating oil and the liquefied refrigerant deteriorates the oil film forming property of the rolling bearing, so that surface damage is likely to occur. As a countermeasure against surface damage of a rolling bearing for a compressor, there is known a method described in Patent Document 2 in which minute concave portions are randomly formed in a rolling portion to improve oil film formation.

この他、油膜形成性が悪い状態で使われる転がり軸受の表面損傷対策としては、特許文献3に記載されている摺接する二面のどちらか片側を浸炭窒化処理することで表層の残留オーステナイト組織を富化させる方法や、特許文献4等に記載されている転動部にリン酸マンガン塩被膜処理を施して油膜形成性を向上させる方法が知られている。   In addition, as a countermeasure against surface damage of a rolling bearing used in a state where the oil film formation is poor, the residual austenite structure of the surface layer is formed by carbonitriding one of the two surfaces in sliding contact described in Patent Document 3. A method of enriching and a method of improving oil film formation by applying a manganese phosphate salt coating treatment to the rolling part described in Patent Document 4 and the like are known.

特開2006−161887号公報JP 2006-161887 A 特許第2997074号Japanese Patent No. 2997074 特開2004−144279号公報JP 2004-144279 A 特許第3538519号Japanese Patent No. 3538519

高田浩年, 鈴木進, 前田悦生, 潤滑, 26, 9 (1981) 645-650Takada Hirotoshi, Suzuki Susumu, Maeda Yasuo, Lubrication, 26, 9 (1981) 645-650

しかしながら、特許文献1および特許文献2における上記の転動部に凹部を形成する処理や、特許文献3における上記の浸炭窒化処理は、加工工程が複雑で処理時間も長いことから、加工コストが高くなる。   However, the processing for forming a recess in the rolling part in Patent Document 1 and Patent Document 2 and the carbonitriding process in Patent Document 3 have a complicated processing process and a long processing time. Become.

また、特許文献4における上記のリン酸マンガン塩処理の場合、処理後の排水処理費用が高価である。   In addition, in the case of the above-described manganese phosphate treatment in Patent Document 4, wastewater treatment costs after the treatment are expensive.

本発明はこのような問題に対処するためになされたものであり、上記のような表面損傷を防止するための複雑な加工や長時間の処理、費用のかかる処理等をすることなく製造でき、転動部の油膜形成性が悪い状態で使用されても表面損傷による早期故障を起こさず長寿命を実現する転動装置を提供することを目的とする。   The present invention has been made to cope with such problems, and can be manufactured without complicated processing, long-time processing, costly processing, etc. to prevent surface damage as described above, An object of the present invention is to provide a rolling device that realizes a long life without causing an early failure due to surface damage even when used in a state where the oil film forming property of the rolling portion is poor.

本発明の転動装置は、転がり接触する2つの構成部品を含む転動装置であって、該2つの構成部品のうち、一方の構成部品は、鋼製部材に多価アルコール化合物による被膜処理を施してなり、他方の構成部品は、鋼製部材からなるか、または鋼製部材に多価アルコール化合物による被膜処理を施してなり、該一方の構成部品の該鋼製部材と、該他方の構成部品の該鋼製部材との間には硬度差があることを特徴とする。   The rolling device of the present invention is a rolling device including two components that are in rolling contact, and one of the two components is subjected to a coating treatment with a polyhydric alcohol compound on a steel member. The other component is made of a steel member, or the steel member is coated with a polyhydric alcohol compound, and the steel member of the one component and the other component There is a difference in hardness between the steel members of the parts.

上記多価アルコール化合物が、クロロゲン酸またはその誘導体であることを特徴とする。   The polyhydric alcohol compound is chlorogenic acid or a derivative thereof.

上記被膜処理が、水および/または有機溶剤に上記多価アルコール化合物を分散または溶解させた処理液の中に処理対象を浸漬する処理であることを特徴とする。   The coating treatment is characterized in that the treatment target is immersed in a treatment liquid in which the polyhydric alcohol compound is dispersed or dissolved in water and / or an organic solvent.

上記一方の構成部品の上記鋼製部材と、上記他方の構成部品の上記鋼製部材との間には、ロックウェル硬さHRCで1ポイント以上の硬度差があることを特徴とする。   There is a hardness difference of 1 point or more in Rockwell hardness HRC between the steel member of the one component and the steel member of the other component.

上記転がり接触する2つの構成部品間の潤滑油膜の膜厚比Λが1.2以下になるような条件で使用されることを特徴とする。   The lubricating oil film thickness ratio Λ between the two components in rolling contact is 1.2 or less.

上記転動装置が、外周に内輪軌道面を有する内輪と、内周に外輪軌道面を有する外輪と、上記内輪軌道面と上記外輪軌道面との間を転動する複数の転動体とを備える転がり軸受であって、上記内輪と上記各転動体とが上記2つの構成部品であるか、上記外輪と上記各転動体とが上記2つの構成部品であるか、または、これらの両方であることを特徴とする。   The rolling device includes an inner ring having an inner ring raceway surface on an outer periphery, an outer ring having an outer ring raceway surface on an inner periphery, and a plurality of rolling elements that roll between the inner ring raceway surface and the outer ring raceway surface. It is a rolling bearing, and the inner ring and the rolling elements are the two components, or the outer ring and the rolling elements are the two components, or both. It is characterized by.

本発明の転動装置は、転がり接触する2つの構成部品うち、一方の構成部品が、鋼製部材に多価アルコール化合物による被膜処理を施してなるものであり、他方の構成部品が鋼製部材からなるか、または鋼製部材に多価アルコール化合物による被膜処理を施してなるものであり、該一方の構成部品の該鋼製部材と該他方の構成部品の該鋼製部材との間には硬度差があるので、運転開始から短時間後における転動部の表面粗さが小さい。すなわち、転動部がなじみやすい。   In the rolling device according to the present invention, one of the two components that are in rolling contact is one in which a steel member is coated with a polyhydric alcohol compound, and the other component is a steel member. Or a steel member subjected to a coating treatment with a polyhydric alcohol compound, and between the steel member of the one component and the steel member of the other component Since there is a difference in hardness, the surface roughness of the rolling part after a short time from the start of operation is small. That is, the rolling part is easy to adjust.

そのため、本発明の転動装置は、転動部の油膜形成性が悪い状態で使用されても表面損傷が発生しにくく、表面損傷による早期故障を起こしにくく長寿命となり得る。本発明の転動装置の製造には、上記のような複雑な加工や長時間の処理等は不要である。   Therefore, even if the rolling device of the present invention is used in a state where the oil film forming property of the rolling portion is poor, surface damage is unlikely to occur, premature failure due to surface damage is unlikely to occur, and long life can be achieved. The manufacture of the rolling device of the present invention does not require complicated processing as described above, long-time processing, and the like.

本発明の転動装置の一例である深溝玉軸受の断面図である。It is sectional drawing of the deep groove ball bearing which is an example of the rolling device of this invention. 各試験に用いる二円筒試験機の概略図である。It is the schematic of the two cylinder test machine used for each test. 表2のL18直交表の試験片に対する転動試験の結果をもとに作成された品質工学の要因効果図である。It is a factor effect figure of quality engineering created based on the result of the rolling test to the specimen of L18 orthogonal table of Table 2. 表7の試験片の試験後の転動部顕微鏡拡大写真である。It is a rolling part microscope enlarged photograph after the test of the test piece of Table 7.

本発明者らは、転動部の油膜形成性が悪い状態で使用される転がり軸受等の転動装置において、転動部における表面損傷の発生を防止して長寿命化を実現するために、転動部をなじみやすくすること、すなわち、転動装置の運転開始から短時間後の転動部の表面粗さを小さくすることを考えた。そして、本発明者らは、転動装置において、転がり接触する2つの構成部品の鋼製部材に硬度差を設け、少なくとも一方の鋼製部材に多価アルコール化合物による被膜処理を施すことで、転動部がなじみやすくなることを見出した。その結果、表面損傷の発生が防止され長寿命が実現された。本発明はこのような知見に基づくものである。   In the rolling device such as a rolling bearing used in a state where the oil film forming property of the rolling part is poor, in order to prevent the occurrence of surface damage in the rolling part and realize a long life, It was considered to make the rolling part easy to adapt, that is, to reduce the surface roughness of the rolling part after a short time from the start of operation of the rolling device. Then, in the rolling device, the present inventors provide a hardness difference in the steel members of the two components that are in rolling contact, and at least one of the steel members is subjected to a coating treatment with a polyhydric alcohol compound, whereby the rolling is performed. I found that the moving part becomes easy to get used to. As a result, the occurrence of surface damage was prevented and a long life was realized. The present invention is based on such knowledge.

本願において、構成部品間の転がり接触には、構成部品間のすべりを伴う転がり接触も含まれ、構成部品の表面に形成された潤滑剤成分等の膜が介在する場合も含まれる。また、本願において「転がり接触する2つの構成部品」というときの転がり接触は、その2つの構成部品間の転がり接触をさす。   In the present application, the rolling contact between the component parts includes a rolling contact accompanied by sliding between the component parts, and also includes a case where a film of a lubricant component or the like formed on the surface of the component part is interposed. Further, in the present application, the term “two components in rolling contact” refers to a rolling contact between the two components.

本発明の転動装置は、次の2条件を満たす転がり接触する2つの構成部品を含む転動装置として規定される:
(1)該2つの構成部品のうち、一方の構成部品は、鋼製部材に多価アルコール化合物による被膜処理を施してなり、他方の構成部品は、鋼製部材からなるか、または鋼製部材に多価アルコール化合物による被膜処理を施してなる。
(2)該一方の構成部品の該鋼製部材と、該他方の構成部品の該鋼製部材との間には硬度差がある。
The rolling device of the present invention is defined as a rolling device that includes two components in rolling contact that satisfy the following two conditions:
(1) Of the two components, one component is a steel member that is coated with a polyhydric alcohol compound, and the other component is a steel member or a steel member. Is coated with a polyhydric alcohol compound.
(2) There is a difference in hardness between the steel member of the one component and the steel member of the other component.

上記2条件を満たす転がり接触する2つの構成部品を複数通り見いだせる転動装置は、本発明の転動装置に該当する。   A rolling device capable of finding a plurality of two components that are in rolling contact with the above two conditions corresponds to the rolling device of the present invention.

転動装置が、転がり接触する2つの構成部品を複数通り含む場合、その全部または一部が上記の2条件を満たせば、本発明の転動装置に該当する。   When the rolling device includes a plurality of two components that are in rolling contact with each other, if all or part of the rolling device satisfies the above two conditions, the rolling device corresponds to the rolling device of the present invention.

本発明における多価アルコール化合物による被膜処理は、鋼製部材の表面に施される。該被膜処理は、鋼製部材の表面全体に施してもよいし、鋼製部材の表面のうち少なくとも、該転動装置の他の構成部品との間で転がり接触をする面に施してもよい。   The coating treatment with the polyhydric alcohol compound in the present invention is performed on the surface of the steel member. The coating treatment may be performed on the entire surface of the steel member, or may be performed on at least a surface of the steel member that is in rolling contact with other components of the rolling device. .

本発明における多価アルコール化合物による被膜処理として、例えば、多価アルコール化合物を水および/または有機溶媒に分散または溶解させた処理液中に、被膜形成対象となる鋼製部材を浸漬することで、部材表面に被膜を形成する処理が挙げられる。この処理は、被膜形成を速めるため加温しながら行なうことが好ましい。また、本発明における多価アルコール化合物による被膜処理として、多価アルコール化合物を水および/または有機溶媒に分散または溶解させた処理液を、被膜形成対象となる鋼製部材の表面などに塗布することによって該面に被膜を形成する処理も挙げられる。これらの処理によって形成される被膜は、酸化物被膜、あるいは多価アルコール化合物および/またはその分解物の吸着膜であると考えられる。   As a coating treatment with a polyhydric alcohol compound in the present invention, for example, by immersing a steel member that is a coating formation target in a treatment liquid in which a polyhydric alcohol compound is dispersed or dissolved in water and / or an organic solvent, The process which forms a film on the member surface is mentioned. This treatment is preferably performed while heating in order to accelerate the film formation. Also, as a coating treatment with a polyhydric alcohol compound in the present invention, a treatment liquid in which a polyhydric alcohol compound is dispersed or dissolved in water and / or an organic solvent is applied to the surface of a steel member to be coated. A treatment for forming a film on the surface is also mentioned. The film formed by these treatments is considered to be an oxide film or an adsorption film of a polyhydric alcohol compound and / or a decomposition product thereof.

本発明の転動装置における上記の転がり接触する2つの構成部品の両方が、鋼製部材に多価アルコール化合物による被膜処理を施してなる場合、一方の構成部品の鋼製部材に用いられる多価アルコール化合物と、他方の構成部品の鋼製部材に用いられる多価アルコール化合物とは、同じであっても異なっていてもよい。   In the case where both of the two components that make rolling contact in the rolling device of the present invention are subjected to a coating treatment with a polyhydric alcohol compound on a steel member, the polyvalent amount used for the steel member of one component The alcohol compound and the polyhydric alcohol compound used for the steel member of the other component may be the same or different.

本発明において使用する多価アルコール化合物として、植物由来の多価アルコールを挙げることができる。植物由来の多価アルコールを用いる場合、環境負荷の低い転動装置を得ることができる。   Examples of the polyhydric alcohol compound used in the present invention include plant-derived polyhydric alcohols. When a plant-derived polyhydric alcohol is used, a rolling device with a low environmental load can be obtained.

本発明において使用できる多価アルコール化合物としては、例えば、没食子酸、エラグ酸、クロロゲン酸、コーヒー酸、キナ酸、クルクミン、ケルセチン、ピロガロール、テアフラビン、アントシアニン、ルチン、リグナン、カテキンなどが挙げられる。また、セサミン、イソフラボン、クマリンなどから得られる多価アルコール化合物も使用できる。以上のような多価アルコール化合物は、単独で用いても2種類以上を組み合わせて用いてもよい。また、これらは植物由来であることができる。   Examples of the polyhydric alcohol compound that can be used in the present invention include gallic acid, ellagic acid, chlorogenic acid, caffeic acid, quinic acid, curcumin, quercetin, pyrogallol, theaflavin, anthocyanin, rutin, lignan, and catechin. Polyhydric alcohol compounds obtained from sesamin, isoflavones, coumarins and the like can also be used. Such polyhydric alcohol compounds may be used alone or in combination of two or more. They can also be derived from plants.

これらの中で、被膜処理の際に、鋼製部材表面に被膜を形成しやすいことから、没食子酸またはその誘導体、エラグ酸またはその誘導体、クロロゲン酸またはその誘導体、コーヒー酸またはその誘導体、キナ酸またはその誘導体、クルクミンまたはその誘導体、ケルセチンまたはその誘導体を用いることが好ましい。   Among these, gallic acid or its derivative, ellagic acid or its derivative, chlorogenic acid or its derivative, caffeic acid or its derivative, quinic acid, because it is easy to form a film on the surface of the steel member during the film treatment. Alternatively, it is preferable to use a derivative thereof, curcumin or a derivative thereof, quercetin or a derivative thereof.

本発明における上記の転がり接触する2つの構成部品のうちの一方の構成部品の鋼製部材と他方の構成部品の鋼製部材は、硬度差があればよく、それぞれを構成する金属材料が同種であっても、異種であっても構わない。具体例としては、軸受鋼(高炭素クロム軸受鋼JIS G 4805)、肌焼鋼(JIS G4104等)、高速度鋼(AMS 6490)、ステンレス鋼(JIS G4303)、高周波焼入鋼(JIS G4051等)などが挙げられる。具体的な硬度差としては、ロックウェル硬さHRC(JIS Z2245)で1ポイント以上とすることが好ましい。   In the present invention, the steel member of one component part and the steel member of the other component part of the two component parts that are in rolling contact with each other need only have a hardness difference, and the metal materials constituting each of them are of the same type. It may be different or different. Specific examples include bearing steel (high carbon chromium bearing steel JIS G 4805), case hardening steel (JIS G4104, etc.), high speed steel (AMS 6490), stainless steel (JIS G4303), induction hardening steel (JIS G4051 etc.). ) And the like. The specific hardness difference is preferably 1 point or more in Rockwell hardness HRC (JIS Z2245).

2つの鋼製部材の硬度は、それらの表面粗さの大きさに差がある場合は、表面粗さの大きい方が軟らかく、表面粗さの小さい方が硬いことが好ましい。   When the hardness of the two steel members is different in the surface roughness, it is preferable that the surface roughness is softer and the surface roughness is softer.

2つの鋼製部材の硬度差を設ける方法は特に限定されない。例えば、SUJ2(JIS G 4805)で構成された焼入れ焼戻し前の2つの鋼製部材の双方に対し、共通の条件で焼入れを行った後、焼戻し温度は共通にし焼戻し時間は差をつけて焼戻しを行えば、焼戻し時間が長い方は軟らかくなり焼戻し時間が短い方は硬くなって、硬度差を得ることができる。   The method for providing the difference in hardness between the two steel members is not particularly limited. For example, both of two steel members before quenching and tempering composed of SUJ2 (JIS G 4805) are quenched under the same conditions, and then tempered at a common tempering time with different tempering times. If it does, the one where tempering time is long will become soft, and the one where tempering time is short will become hard, and a hardness difference can be obtained.

本発明の転動装置の一例として転がり軸受が挙げられる。具体的には、深溝玉軸受、アンギュラ玉軸受、自動調心玉軸受、針状ころ軸受、円筒ころ軸受、自動調心ころ軸受等のラジアル形の転がり軸受や、スラスト玉軸受、スラストころ軸受等のスラスト形の転がり軸受が挙げられる。   An example of the rolling device of the present invention is a rolling bearing. Specifically, radial rolling bearings such as deep groove ball bearings, angular contact ball bearings, self-aligning ball bearings, needle roller bearings, cylindrical roller bearings, self-aligning roller bearings, thrust ball bearings, thrust roller bearings, etc. Thrust type rolling bearings.

本発明の転動装置の一例である転がり軸受は、外周に内輪軌道面を有する内輪と、内周に外輪軌道面を有する外輪と、内輪軌道面と外輪軌道面との間を転動する複数の転動体とを備えてなり、内輪と各転動体とが上記条件(1)および(2)を満たす転がり接触する2つの構成部品であるか、外輪と各転動体とが上記条件(1)および(2)を満たす転がり接触する2つの構成部品であるか、または、これらの両方である。   A rolling bearing which is an example of a rolling device according to the present invention includes an inner ring having an inner ring raceway surface on the outer periphery, an outer ring having an outer ring raceway surface on the inner periphery, and a plurality of rolling between the inner ring raceway surface and the outer ring raceway surface. Or the inner ring and each rolling element are two components in rolling contact that satisfy the above conditions (1) and (2), or the outer ring and each rolling element are in the above condition (1). And two components in rolling contact that satisfy (2) and / or both.

内輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合は、その被膜処理は鋼製部材の表面の全体に施されてもよいし、鋼製部材の表面の少なくとも内輪軌道面にあたる面に施されてもよい。また、外輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合は、その被膜処理は鋼製部材の表面の全体に施されてもよいし、鋼製部材の表面の少なくとも外輪軌道面にあたる面に施されてもよい。   When the inner ring is formed by coating a steel member with a polyhydric alcohol compound, the coating may be applied to the entire surface of the steel member, or at least the inner ring raceway surface of the steel member. It may be applied to the surface. Further, when the outer ring is formed by coating a steel member with a polyhydric alcohol compound, the coating may be performed on the entire surface of the steel member, or at least the outer ring raceway on the surface of the steel member. It may be applied to the surface corresponding to the surface.

被膜処理の具体例としては、(a)該内輪、該外輪、および該複数の転動体の全てが鋼製部材に上記被膜処理を施されてなる場合、(b)該複数の転動体の全てが上記被膜処理をされていない鋼製部材からなり、かつ、内輪と外輪の両方が鋼製部材に上記被膜処理を施されてなる場合、(c)該複数の転動体の全てが上記被膜処理をされていない鋼製部材からなり、かつ、内輪と外輪のうちの一方が鋼製部材に上記被膜処理を施されてなり、もう一方が上記被膜処理をされていない鋼製部材からなる場合、(d)該複数の転動体の全てが鋼製部材に上記被膜処理を施されてなり、かつ、内輪と外輪の両方が上記被膜処理をされていない鋼製部材からなる場合、(e)該複数の転動体の全てが鋼製部材に上記被膜処理を施されてなり、かつ、内輪と外輪のうちの一方が鋼製部材に上記被膜処理を施されてなり、もう一方が上記被膜処理をされていない鋼製部材からなる場合、等がある。   Specific examples of the coating treatment include: (a) when all of the inner ring, the outer ring, and the plurality of rolling elements are subjected to the coating treatment on a steel member, and (b) all of the plurality of rolling elements. Is made of a steel member not subjected to the coating treatment, and both the inner ring and the outer ring are subjected to the coating treatment on the steel member, (c) all of the plurality of rolling elements are subjected to the coating treatment. When it is made of a steel member that has not been coated, and one of the inner ring and the outer ring has been subjected to the coating treatment on the steel member, and the other is made of a steel member that has not been coated with the coating, (D) When all of the plurality of rolling elements are subjected to the coating treatment on a steel member, and both the inner ring and the outer ring are made of a steel member not subjected to the coating treatment, (e) the All of the plurality of rolling elements are subjected to the above-mentioned coating treatment on a steel member, and And one of the outer ring is being subjected to the coating treatment on a steel member, when the other is made of a steel member that is not the coating process, and the like.

硬度差に関しては、該複数の転動体の鋼製部材の全てが該内輪および該外輪の鋼製部材よりも硬い場合や、該複数の転動体の鋼製部材の全てが該内輪および該外輪の鋼製部材よりも軟らかい場合や、該複数の転動体の鋼製部材の全てが該内輪(外輪)の鋼製部材よりも硬く、該外輪(内輪)の鋼製部材よりも軟らかい場合等がある。   Regarding the hardness difference, all of the steel members of the plurality of rolling elements are harder than the steel members of the inner ring and the outer ring, or all of the steel members of the plurality of rolling elements are the inner ring and the outer ring. In some cases, the steel member is softer than the steel member, or the steel members of the plurality of rolling elements are all harder than the steel member of the inner ring (outer ring) and softer than the steel member of the outer ring (inner ring). .

内輪と各転動体とが上記条件(1)および(2)を満たす転がり接触する2つの構成部品である場合の例として、
該複数の転動体の鋼製部材の全てが該内輪の鋼製部材よりも硬く、該複数の転動体の全ておよび/または該内輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合、
該複数の転動体の鋼製部材の全てが該内輪の鋼製部材よりも軟らかく、該複数の転動体の全ておよび/または該内輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合等がある。
As an example of the case where the inner ring and each rolling element are two components that make rolling contact satisfying the above conditions (1) and (2),
All of the steel members of the plurality of rolling elements are harder than the steel member of the inner ring, and all of the plurality of rolling elements and / or the inner ring are coated with a polyhydric alcohol compound on the steel member. If
All of the steel members of the plurality of rolling elements are softer than the steel member of the inner ring, and all of the plurality of rolling elements and / or the inner ring are coated with a polyhydric alcohol compound on the steel member. There are cases.

また、外輪と各転動体とが上記条件(1)および(2)を満たす転がり接触する2つの構成部品である場合の例として、
該複数の転動体の鋼製部材の全てが該外輪の鋼製部材よりも硬く、該複数の転動体の全て、および/または、該外輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合、
該複数の転動体の鋼製部材の全てが該外輪の鋼製部材よりも軟らかく、該複数の転動体の全て、および/または、該外輪が鋼製部材に多価アルコール化合物による被膜処理を施してなる場合等がある。
In addition, as an example in the case where the outer ring and each rolling element are two components that are in rolling contact satisfying the above conditions (1) and (2),
All of the steel members of the plurality of rolling elements are harder than the steel member of the outer ring, and all of the plurality of rolling elements and / or the outer ring subject the steel member to a coating treatment with a polyhydric alcohol compound. If
All of the steel members of the plurality of rolling elements are softer than the steel member of the outer ring, and all of the plurality of rolling elements and / or the outer ring subject the steel member to a coating treatment with a polyhydric alcohol compound. There are some cases.

本発明の転がり軸受を図面に基づいて説明する。図1は本発明の転がり軸受の一例である深溝玉軸受の断面図である。図1に示すように深溝玉軸受(転がり軸受)1は、外周に内輪軌道面2aを有する内輪2と、内周に外輪軌道面3aを有する外輪3と、前記内輪軌道面2aと前記外輪軌道面3aとの間を転動する複数の転動体4と、この転動体4を保持する保持器5を備える。外輪3等に固定されるシール部材6が、内輪2および外輪3の軸方向両端開口部8a、8bにそれぞれ設けられており、転動体4の周囲にグリース7が封入されている。   A rolling bearing according to the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view of a deep groove ball bearing which is an example of a rolling bearing of the present invention. As shown in FIG. 1, a deep groove ball bearing (rolling bearing) 1 includes an inner ring 2 having an inner ring raceway surface 2a on the outer periphery, an outer ring 3 having an outer ring raceway surface 3a on the inner periphery, the inner ring raceway surface 2a and the outer ring raceway. A plurality of rolling elements 4 that roll between the surfaces 3 a and a cage 5 that holds the rolling elements 4 are provided. Seal members 6 fixed to the outer ring 3 and the like are respectively provided in the axially opposite end openings 8 a and 8 b of the inner ring 2 and the outer ring 3, and grease 7 is sealed around the rolling elements 4.

内輪2と各転動体4は転がり接触をし、また、外輪2と各転動体4も転がり接触をするので、深溝玉軸受1は、転がり接触する2つの構成部品を複数通り含む。内輪2および外輪3は鋼製部材に多価アルコールにて被膜処理を施してなり、各転動体4は鋼製部材からなり、内輪2の鋼製部材と各転動体4の鋼製部材との間、および、外輪3の鋼製部材と各転動体4の鋼製部材との間にはロックウェル硬さHRCで1ポイント以上の硬度差がある。   Since the inner ring 2 and each rolling element 4 are in rolling contact, and the outer ring 2 and each rolling element 4 are also in rolling contact, the deep groove ball bearing 1 includes a plurality of two components that are in rolling contact. The inner ring 2 and the outer ring 3 are made by coating a steel member with polyhydric alcohol, each rolling element 4 is made of a steel member, and the steel member of the inner ring 2 and the steel member of each rolling element 4 There is a hardness difference of 1 point or more in Rockwell hardness HRC between the steel member of the outer ring 3 and the steel member of each rolling element 4.

本発明における上記の転がり接触する2つの構成部品の好ましい作成条件としては、上記の一方の構成部品が、鋼製部材にクロロゲン酸化合物による被膜処理を施されてなり、該鋼製部材はSUJ2材に焼入れおよび焼戻しを施したものであり、その焼入れ方法は水冷であって、その焼戻し温度は高温(例えば200〜230℃)、焼戻し時間は長時間(例えば5〜10時間)であり、上記の他方の構成部品が、鋼製部材からなり、該鋼製部材はSUJ2材に焼入れおよび焼戻しを施したものであり、その焼入れ方法は水冷であって、その焼戻し温度は高温(例えば200〜230℃)、焼戻し時間は短時間(例えば1〜3時間)であることが挙げられる。
また、上記の一方の構成部品が、鋼製部材にクロロゲン酸化合物による被膜処理を施されてなり、該鋼製部材はSUJ2材に焼入れおよび焼戻しを施したものであり、その焼入れ方法は水冷であって、その焼戻し温度は高温(例えば200〜230℃)、焼戻し時間は短時間(例えば1〜3時間)であり、上記の他方の構成部品が、鋼製部材からなり、該鋼製部材はSUJ2材に焼入れおよび焼戻しを施したものであり、その焼入れ方法は水冷であって、その焼戻し温度は高温(例えば200〜230℃)、焼戻し時間は長時間(例えば5〜10時間)であることが挙げられる。これらの作成条件は、転動部のなじみやすさ、コストメリット等の総合的な観点から好ましい。
As a preferable production condition of the two component parts that are in rolling contact with each other in the present invention, one of the above component parts is a steel member that is coated with a chlorogenic acid compound, and the steel member is a SUJ2 material. The quenching method is water-cooling, the tempering temperature is high (for example, 200 to 230 ° C.), the tempering time is long (for example, 5 to 10 hours), The other component part is made of a steel member, and the steel member is obtained by quenching and tempering SUJ2 material. The quenching method is water cooling, and the tempering temperature is high (for example, 200 to 230 ° C.). ), And tempering time is short (for example, 1 to 3 hours).
In addition, one of the above components is a steel member that is coated with a chlorogenic acid compound. The steel member is a SUJ2 material that has been quenched and tempered. The tempering temperature is high (eg, 200 to 230 ° C.), the tempering time is short (eg, 1 to 3 hours), and the other component is made of a steel member. The SUJ2 material is quenched and tempered, the quenching method is water cooling, the tempering temperature is high (eg, 200 to 230 ° C.), and the tempering time is long (eg, 5 to 10 hours). Is mentioned. These creation conditions are preferable from the comprehensive viewpoints such as compatibility of the rolling part and cost merit.

本発明の転動装置は、上記転がり接触する2つの構成部品の転がり接触部における潤滑油の油膜形成が不十分になる条件でも好適に使用することができる。例えば、該接触部が境界潤滑状態となるような条件での使用が挙げられる。また例えば、転がり接触する2つの構成部品間の表面の突起接触の程度を表すパラメータ膜厚比Λが1.2以下になるような条件での使用が挙げられる。この膜厚比Λは、油膜パラメータともよばれ、転がり接触する2物体の接触面に形成される潤滑油膜の最小膜厚hと接触面の合成二乗平均平方根粗さσの比h/σである。σは該2物体の二乗平均平方根粗さをそれぞれσ、σとしたとき、√(σ +σ )で表される。 The rolling device of the present invention can be suitably used even under conditions where the oil film formation of the lubricating oil is insufficient at the rolling contact portion of the two components that are in rolling contact. For example, use under conditions where the contact portion is in a boundary lubrication state can be mentioned. In addition, for example, it is used under the condition that the parameter film thickness ratio Λ representing the degree of protrusion contact on the surface between two components that are in rolling contact is 1.2 or less. This film thickness ratio Λ is also called an oil film parameter, and is a ratio h 0 / σ of the minimum film thickness h 0 of the lubricating oil film formed on the contact surface of the two objects in rolling contact and the combined root mean square roughness σ of the contact surface. is there. σ is represented by √ (σ 1 2 + σ 2 2 ), where the root mean square roughness of the two objects is σ 1 and σ 2 , respectively.

図2に示す二円筒試験機11を用いて、作成条件が異なる実験No.1〜18の試験片に対し転動試験を行った。各実験No.の試験片は、駆動側(以下D側と記す)試験片12と従動側(以下F側と記す)試験片13とからなる。D側試験片12は図示しないモーターにより回転させられる。   Using the two-cylinder testing machine 11 shown in FIG. A rolling test was performed on 1 to 18 test pieces. Each experiment No. The test piece comprises a driving side (hereinafter referred to as D side) test piece 12 and a driven side (hereinafter referred to as F side) test piece 13. The D-side test piece 12 is rotated by a motor (not shown).

表1は、8つの制御因子のそれぞれについて2水準または3水準を設定している。各実験No.の試験片の作成条件は、この8つの制御因子のそれぞれについて1つの水準を選択することにより決定される。実験No.1〜18の試験片の作成条件は、品質工学(タグチメソッド)のL18直交表(表2)に従って決定した。   Table 1 sets two or three levels for each of the eight control factors. Each experiment No. The test specimen preparation conditions are determined by selecting one level for each of the eight control factors. Experiment No. The preparation conditions of the test pieces 1 to 18 were determined according to the L18 orthogonal table (Table 2) of Quality Engineering (Taguchi Method).

D側とF側の鋼材の焼入れは、雰囲気炉で850℃で45分間均熱し、230℃の塩浴中で10分間冷却した後、各実験No.の試験片の作成条件にしたがって、深冷処理、水冷、または空冷で冷却した。   For the quenching of the steel materials on the D side and F side, soaking was performed at 850 ° C. for 45 minutes in an atmosphere furnace and cooled in a salt bath at 230 ° C. for 10 minutes. The sample was cooled by deep cooling, water cooling, or air cooling according to the test specimen preparation conditions.

D側とF側の鋼材の焼戻しは、各実験No.の試験片の作成条件の温度、時間により行った(表2)。   The tempering of the steel materials on the D side and the F side was performed in each experiment No. This was performed according to the temperature and time of the preparation conditions of the test piece (Table 2).

クロロゲン酸処理については、試験片の作成条件により、行わないか、または焼入れ焼戻し後にクロロゲン酸化合物(クロロゲン酸水和物)による被膜処理をD側、F側のうちどちらか一方の鋼材に施した。
この被膜処理は、10wt%のアルカリ洗浄によって鋼表面の油分を取り除いた処理試験片を、18wt%の塩酸に20秒浸漬して表面を活性化し、その後、その処理試験片をクロロゲン酸水和物の0.5wt%水溶液に、室温で撹拌しながら所定時間浸漬して成膜する処理である。
The chlorogenic acid treatment is not performed depending on the test piece preparation conditions, or after quenching and tempering, a coating treatment with a chlorogenic acid compound (chlorogenic acid hydrate) is applied to either the D side or the F side steel material. .
In this coating treatment, a treated test piece from which oil on the steel surface was removed by 10 wt% alkali cleaning was activated by immersing it in 18 wt% hydrochloric acid for 20 seconds, and then the treated test piece was treated with chlorogenic acid hydrate. The film is immersed in a 0.5 wt% aqueous solution at room temperature while stirring for a predetermined time.

各実験No.の試験片のD側試験片12およびF側試験片13はともに円筒形状であり、これらの試験片形状の詳細、および、二円筒試験機11による該転動試験の試験条件を表3に示す。表3においてRaは算術平均粗さを表し、RΔqは二乗平均平方根傾斜を表す(以下、この記号を用いる)。 なお、表3に示されたD側およびF側の表面粗さは、クロロゲン酸処理を行う試験片については、当該処理前の表面粗さである。   Each experiment No. Both the D-side test piece 12 and the F-side test piece 13 of this test piece have a cylindrical shape, and details of these test piece shapes and test conditions of the rolling test by the two-cylinder tester 11 are shown in Table 3. . In Table 3, Ra represents the arithmetic average roughness, and RΔq represents the root mean square slope (hereinafter, this symbol is used). In addition, the surface roughness of the D side and F side shown in Table 3 is the surface roughness before the said process about the test piece which performs a chlorogenic acid process.

二円筒試験機11による該転動試験においては、無添加のポリ-α-オレフィン油 (VG5相当)を染みこませたフェルトパッド14をD側、F側両円筒12、13の外径面に接触させることで、潤滑油を供給した(図2)。   In the rolling test by the two-cylinder testing machine 11, a felt pad 14 impregnated with an additive-free poly-α-olefin oil (equivalent to VG5) is applied to the outer diameter surfaces of both the D-side and F-side cylinders 12 and 13. Lubricating oil was supplied by making it contact (FIG. 2).

試験後の試験片全てについて円筒軸方向の表面粗さを測定して、そのデータをもとに、どのような作成条件でD側およびF側円筒12、13を作成すれば、転動部がなじみやすいかを品質工学を用いて調べた。   The surface roughness in the cylindrical axis direction is measured for all the test pieces after the test, and if the D-side and F-side cylinders 12 and 13 are created based on the data, the rolling part is We investigated whether it was easy to get familiar with using quality engineering.

なお、なじみやすさの指標として、試験後のD側円筒12の軸方向表面粗さ(RΔq)とF側円筒13の軸方向表面粗さ(RΔq)の平均値を採用し、この値が小さい程なじみやすいとした。   As an index of familiarity, an average value of the axial surface roughness (RΔq) of the D-side cylinder 12 and the axial surface roughness (RΔq) of the F-side cylinder 13 after the test is adopted, and this value is small. It was easy to get used to.

このなじみやすさの指標は、望小特性である。回転数と荷重(表3)を誤差因子として、回転数と荷重によらず転動部がなじみやすい条件を、品質工学における望小特性の解析によって検討した。図3は、この解析で得られた要因効果図である。この要因効果図は、横軸に示す各制御因子について、縦軸のSN比の値が大きい水準ほどなじみやすいことを表している。   This index of familiarity is a small desired characteristic. Using the rotational speed and load (Table 3) as error factors, the conditions under which the rolling part is easy to adjust regardless of the rotational speed and load were examined by analyzing the desired characteristics in quality engineering. FIG. 3 is a factor effect diagram obtained by this analysis. This factor-effect diagram shows that, for each control factor shown on the horizontal axis, the greater the level of the SN ratio on the vertical axis, the easier it is to become familiar with.

また、表4の分散分析表は、各制御因子の、転動部のなじみやすさに及ぼす影響度を示している。この分散分析表に載っている制御因子はなじみやすさへの影響度が大きいものであり、その他の制御因子は誤差成分に含まれている。表中の分散比の値から優位度が推定され、優位度が高い制御因子ほど、なじみやすさへ影響を及ぼす可能性が高いことを示している。また、寄与度はなじみにおよぼす影響度の大きさを示している。この分散分析表から、クロロゲン酸処理の有無が最も大きくなじみに影響しており、次いでD側焼入れ方法と、D側とF側の焼戻し温度がなじみへの影響度が大きいことがわかった。   In addition, the analysis of variance table in Table 4 shows the degree of influence of each control factor on the familiarity of the rolling section. The control factors listed in this analysis of variance table have a great influence on the familiarity, and other control factors are included in the error component. The superiority is estimated from the value of the dispersion ratio in the table, and it is shown that a control factor with a higher superiority is more likely to affect the familiarity. The contribution level indicates the magnitude of the influence on familiarity. From this analysis of variance table, it was found that the presence or absence of the chlorogenic acid treatment had the greatest influence on the familiarity, and then the D-side quenching method and the tempering temperatures on the D-side and F-side had the greatest influence on the familiarity.

上記の要因効果図と分散分析表に加えてコストメリット等を考慮した結果、D側焼戻しを高温長時間で、F側焼戻しを高温短時間で行うことで、D側鋼材とF側鋼材との間に硬度差をつけ、さらにD側鋼材もしくはF側鋼材のいずれかにクロロゲン酸処理を施すことで最も効果的に転動部をなじみやすくできることがわかった。   As a result of considering cost merit in addition to the above factor effect diagram and analysis of variance table, D side tempering is performed at high temperature for a long time and F side tempering is performed at a high temperature for a short time. It was found that the rolling part can be most easily adjusted by applying a chlorogenic acid treatment to either the D-side steel material or the F-side steel material with a hardness difference between them.

次に、このような作成条件によって実際に転動部がなじみやすくなるかを確認実験で検証した。   Next, it was verified by a confirmation experiment whether or not the rolling part actually becomes easy to adjust according to such creation conditions.

確認実験では、表5に示すように、一般的な作成条件に近いものを標準水準とし、この標準水準から、D側焼戻しを高温長時間で行い、F側焼戻しを高温短時間で行い、F側にクロロゲン酸処理を施すように変更したものを最適水準として、これら2つの作成条件にしたがって、標準水準の試験片と最適水準の試験片とを作成した。表5は、表1で設定された水準番号を用いて表記されている。   In the confirmation experiment, as shown in Table 5, a material close to general preparation conditions is set as a standard level, and from this standard level, D-side tempering is performed at a high temperature for a long time, F-side tempering is performed at a high temperature for a short time, and F A test piece with a standard level and a test piece with an optimal level were prepared according to these two preparation conditions, with the one that was changed so as to be subjected to chlorogenic acid treatment on the side. Table 5 is described using the level numbers set in Table 1.

上記の標準水準の試験片と最適水準の試験片とに対して、図2の二円筒試験機を用いて前述の実験と同様に表3に示す条件で転動試験を行った。潤滑油の供給方法も前述の実験と同じフェルトパッドを用いる方法にした。   A rolling test was performed on the above-mentioned standard-level test piece and the optimal-level test piece using the two-cylinder tester shown in FIG. 2 under the conditions shown in Table 3 in the same manner as in the above-described experiment. The method for supplying the lubricating oil was the same as that used in the above-described experiment.

試験後の試験片全てについて円筒軸方向の表面粗さ(RΔq)を測定して、標準水準と最適水準のなじみやすさを比較した。前述と同様、なじみやすさの指標として、試験後のD側円筒12の軸方向表面粗さ(RΔq)とF側円筒13の軸方向表面粗さ(RΔq)の平均値を採用し、この値が小さい程なじみやすいとした。   The surface roughness (RΔq) in the cylindrical axis direction was measured for all test pieces after the test, and the compatibility of the standard level and the optimum level was compared. As described above, the average value of the axial surface roughness (RΔq) of the D-side cylinder 12 and the axial surface roughness (RΔq) of the F-side cylinder 13 after the test is adopted as an index of familiarity. The smaller the size, the easier it is to adapt.

解析では、回転数と荷重(表3)を誤差因子として、上記標準水準と最適水準について、SN比を算出した(表5)。SN比が大きいほど回転数や荷重によらず転動部がなじみやすい作成条件であることを表している。   In the analysis, the SN ratio was calculated for the standard level and the optimal level (Table 5) using the rotation speed and load (Table 3) as error factors. The larger the S / N ratio, the more it is a creation condition that allows the rolling part to become familiar regardless of the rotational speed and load.

また、推定利得と実利得も表5に示した。利得は、標準水準と最適水準のSN比の差で、推定利得は品質工学の結果から推定される利得、実利得は確認実験の結果から算出した実際の利得を表している。   The estimated gain and actual gain are also shown in Table 5. The gain is the difference between the S / N ratio between the standard level and the optimum level, the estimated gain is the gain estimated from the result of quality engineering, and the actual gain is the actual gain calculated from the result of the confirmation experiment.

一般的に品質工学では推定利得と実利得の差が30%以内であれば、再現性があるとされており、今回の確認実験ではこの差が22%であるので、最適水準の作成条件は、実際に転動部がなじみやすくなる効果があると判断した。   Generally, in quality engineering, if the difference between the estimated gain and the actual gain is within 30%, it is said that there is reproducibility. In this confirmation experiment, this difference is 22%. Therefore, it was judged that the rolling part was actually effective.

以上によって得られた転動部がなじみやすい作成条件の知見をもとに、次に、表面損傷に対する効果を確認するための試験を行った。   Next, a test for confirming the effect on the surface damage was performed based on the knowledge of the preparation conditions that the rolling part obtained by the above was easy to adapt.

試験は図2の二円筒試験機11を用いて、表6に示す条件で行った。この実験でも前述の実験と同じフェルトパッド14を用いた潤滑油の供給方法にした。   The test was performed under the conditions shown in Table 6 using the two-cylinder tester 11 of FIG. In this experiment, the same lubricating oil supply method using the felt pad 14 as in the previous experiment was adopted.

評価した作成条件を表7に示す。表7中のロックウェル硬さは、Cスケール硬さ(HRC)(JIS Z2245)である。標準品、実施例1、実施例2の試験後のF側円筒13の外径面の顕微鏡拡大写真(倍率200倍)を図4に示す。図4から、標準品では表面損傷が発生するが、実施例1と実施例2では表面損傷の発生が防止されることがわかる。この結果から、D側鋼材とF側鋼材の間にロックウェル硬さHRCで1ポイント以上の硬度差をつけ、さらにD側鋼材とF側鋼材のうち少なくとも一方にクロロゲン酸処理を施すことで耐表面損傷性能が向上することがわかった。   Table 7 shows the evaluated production conditions. The Rockwell hardness in Table 7 is C scale hardness (HRC) (JIS Z2245). FIG. 4 shows a microscope magnified photograph (magnification 200 times) of the outer diameter surface of the F-side cylinder 13 after the test of the standard product, Example 1 and Example 2. FIG. 4 shows that surface damage occurs in the standard product, but surface damage is prevented in Examples 1 and 2. From these results, it was confirmed that a Rockwell hardness HRC of 1 point or more was made between the D-side steel material and the F-side steel material, and at least one of the D-side steel material and the F-side steel material was subjected to chlorogenic acid treatment. It was found that the surface damage performance was improved.

本発明の転動装置は、運転開始から短時間後における転動部の表面粗さが小さい、すなわち、転動部がなじみやすいので、表面損傷の発生を防止でき、油膜形成が不十分になる環境等においても好適に利用できる。   In the rolling device of the present invention, the surface roughness of the rolling part is small after a short time from the start of operation, i.e., the rolling part is easy to adapt, so that the occurrence of surface damage can be prevented and the oil film formation is insufficient. It can be suitably used in the environment.

1 深溝玉軸受(転がり軸受)
2 内輪
3 外輪
4 転動体
5 保持器
6 シール部材
7 グリース
8a 両端開口部
8b 両端開口部
11 二円筒試験機
12 駆動側(D側)試験片
13 従動側(F側)試験片
14 給油用のフェルトパッド
1 Deep groove ball bearing (rolling bearing)
2 Inner ring 3 Outer ring 4 Rolling element 5 Cage 6 Seal member 7 Grease 8a Opening at both ends 8b Opening at both ends 11 Two-cylinder tester 12 Drive side (D side) test piece 13 Driven side (F side) test piece 14 For oil supply Felt pad

Claims (3)

転がり接触する2つの構成部品を含む転動装置であって、
前記転がり接触する2つの構成部品間の潤滑油膜の膜厚比Λが1.2以下になるような条件で使用され、
前記2つの構成部品のうち、一方の構成部品は、鋼製部材に多価アルコール化合物による被膜処理を施してなり、
他方の構成部品は、鋼製部材からなり、
前記多価アルコール化合物が、クロロゲン酸またはその誘導体であり、
前記一方の構成部品の前記鋼製部材と、前記他方の構成部品の前記鋼製部材との間には、ロックウェル硬さHRCで1ポイント以上の硬度差があり、前記一方の構成部品の前記鋼製部材の方が、前記他方の構成部品の前記鋼製部材よりも、前記ロックウェル硬さHRCが大きいことを特徴とする転動装置。
A rolling device comprising two components in rolling contact,
It is used under the condition that the film thickness ratio Λ of the lubricating oil film between the two components in rolling contact is 1.2 or less,
Of the two components, one component is formed by coating a steel member with a polyhydric alcohol compound,
The other component consists of steel members,
The polyhydric alcohol compound is chlorogenic acid or a derivative thereof;
Said steel member of the one component of, between the steel member of the other components, Rockwell hardness HRC at Ri hardness difference there more than one points, the components of the one The rolling device according to claim 1, wherein the steel member has a larger Rockwell hardness HRC than the steel member of the other component .
前記被膜処理が、水および/または有機溶剤に前記多価アルコール化合物を分散または溶解させた処理液の中に処理対象を浸漬する処理であることを特徴とする請求項1記載の転動装置。   The rolling device according to claim 1, wherein the coating treatment is a treatment of immersing the treatment target in a treatment liquid in which the polyhydric alcohol compound is dispersed or dissolved in water and / or an organic solvent. 前記転動装置が、外周に内輪軌道面を有する内輪と、内周に外輪軌道面を有する外輪と、前記内輪軌道面と前記外輪軌道面との間を転動する複数の転動体とを備える転がり軸受であり、
前記内輪と前記各転動体とが前記2つの構成部品であるか、
前記外輪と前記各転動体とが前記2つの構成部品であるか、または、これらの両方であることを特徴とする請求項1または請求項2記載の転動装置。
The rolling device includes an inner ring having an inner ring raceway surface on an outer periphery, an outer ring having an outer ring raceway surface on an inner periphery, and a plurality of rolling elements that roll between the inner ring raceway surface and the outer ring raceway surface. Rolling bearings,
Whether the inner ring and each rolling element are the two components;
Or said outer ring said each rolling element is the two component parts, or, the rolling device according to claim 1 or claim 2, wherein it is these both.
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