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JP6488560B2 - Microwave-compatible paper molding container - Google Patents
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JP6488560B2 - Microwave-compatible paper molding container - Google Patents

Microwave-compatible paper molding container Download PDF

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JP6488560B2
JP6488560B2 JP2014112616A JP2014112616A JP6488560B2 JP 6488560 B2 JP6488560 B2 JP 6488560B2 JP 2014112616 A JP2014112616 A JP 2014112616A JP 2014112616 A JP2014112616 A JP 2014112616A JP 6488560 B2 JP6488560 B2 JP 6488560B2
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paper
resin
container
powder
coating layer
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JP2015227171A (en
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國廣 一郎
一郎 國廣
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Toyo Seikan Group Holdings Ltd
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Toyo Seikan Group Holdings Ltd
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Priority to JP2014112616A priority Critical patent/JP6488560B2/en
Application filed by Toyo Seikan Group Holdings Ltd filed Critical Toyo Seikan Group Holdings Ltd
Priority to US15/314,578 priority patent/US20170191151A1/en
Priority to EP15800664.3A priority patent/EP3150502A4/en
Priority to CN201580027343.XA priority patent/CN106414252B/en
Priority to PCT/JP2015/065631 priority patent/WO2015182760A1/en
Priority to KR1020167033841A priority patent/KR101877275B1/en
Priority to KR1020187004758A priority patent/KR101894755B1/en
Priority to CN201810184719.3A priority patent/CN108284995A/en
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Description

本発明は、紙材を主体とする電子レンジ対応の紙成形容器に関する。   The present invention relates to a microwave-compatible paper molding container mainly made of paper.

近年環境負荷の観点から循環型資源としての紙材を主体する紙成形容器が注目され、密封性を高めてスープや飲料或いは固形物等の内容物を保存でき、且つ電子レンジで加熱できる電子レンジ対応の紙成形容器が求められている。従来、紙成形容器として、一部に絞り成形容器も実用化されているが、多くはブランクを貼り合わせ加工して容器を成形している。ブランクの貼り合わせ部を有する紙成形容器を電子レンジで加熱する場合、貼り合わせ部等マイクロ波が集中しやすい部位では焦げが発生しやすい現象が生じる。特に、糸尻部(脚部)を有するカップ状の紙成形容器の場合、マイクロ波加熱時に糸尻部内周面に焦げが発生しやすいという問題がある。   In recent years, from the viewpoint of environmental impact, paper-molded containers mainly made of paper as a recycling resource have attracted attention. Microwave ovens that can improve the sealing performance and store contents such as soups, beverages or solids and can be heated in a microwave oven Corresponding paper forming containers are required. Conventionally, as a paper-molded container, a part-drawn container has also been put into practical use, but in many cases, a container is molded by bonding a blank. When a paper molding container having a blank bonding portion is heated by a microwave oven, a phenomenon in which scorching is likely to occur occurs in a portion where microwaves tend to concentrate, such as a bonding portion. In particular, in the case of a cup-shaped paper molding container having a yarn bottom portion (leg portion), there is a problem that the inner surface of the yarn bottom portion is likely to be burned during microwave heating.

そのため、従来このような紙成形容器の電子レンジ加熱時における焦げ発生を防止するように工夫した紙製容器が提案されている。たとえば、カップ型紙容器において、胴部と底部を一体化して脚部を形成し、脚部よりも内側の環状平板部を介して、下方に突出する中空部を底部に形成したものが提案されている(特許文献1参照)。また、他の手段として、胴部内側と下方部分の内側の間に空隙を残す傾斜角度で内方に折り曲げて環状傾斜壁を形成し、この環状傾斜壁の上に底部材を配置し、底部材の周辺部を環状傾斜壁に熱接着したものが提案されている(特許文献2参照)。   For this reason, paper containers that have been devised so as to prevent the occurrence of scorching during the microwave heating of such paper molded containers have been proposed. For example, in a cup type paper container, a body part and a bottom part are integrated to form a leg part, and a hollow part protruding downward is formed at the bottom part via an annular flat plate part inside the leg part. (See Patent Document 1). Further, as another means, an annular inclined wall is formed by bending inward at an inclination angle that leaves a gap between the inner side of the trunk portion and the inner side of the lower portion, and a bottom member is disposed on the annular inclined wall, and the bottom portion A material in which the periphery of a material is thermally bonded to an annular inclined wall has been proposed (see Patent Document 2).

特開2003−95352号公報JP 2003-95352 A 特開2005−88955号公報JP 2005-88955 A

上記提案されている従来のカップ型紙容器における焦げ防止は、いずれも従来のカップ型紙容器の底部構造を変更するものであり、構造が複雑であり、従来の製造ラインに代わる新たな製造設備を必要としコスト高になるという問題点があった。
そこで、本発明は、従来の紙成形容器の基本的構造を変更することなく簡易な手段により容易にマイクロ波加熱時の焦げ発生を防止できるようにした電子レンジ対応の紙成形容器を提供することを目的するものである。
The above-mentioned proposed prevention of scoring in conventional cup-type paper containers is to change the bottom structure of the conventional cup-type paper containers, and the structure is complicated, requiring new manufacturing equipment to replace the conventional manufacturing line. There was a problem that the cost was high.
Accordingly, the present invention provides a paper-molded container for microwave ovens that can easily prevent the occurrence of scorching during microwave heating by a simple means without changing the basic structure of a conventional paper-molded container. It is intended.

上記問題点を解決する本発明の紙成形容器は、電子レンジ加熱対応の紙成形容器であって、該紙成形容器の局所領域に焦げ防止物質を含有する樹脂被覆層を形成してなり、該樹脂被覆層は、樹脂粉末に焦げ防止物質粉末を混合した粉体を溶射して形成したものであることを特徴とするものである。
前記局所領域は、コップ状紙成形容器の場合、電子レンジ加熱時に焦げが発生しやすい糸尻部内周面であるのが望ましい。
前記局所領域が、コップ状紙成形容器の糸尻部内周面である請求項1に記載の電子レンジ加熱対応の紙成形容器であって、該紙容器の局所領域に焦げ防止物質を含有する樹脂被覆層を形成してなることを特徴とするものである。
前記樹脂被覆層は、樹脂粉末に焦げ防止物質粉末を混合した粉体を溶射して形成することによって、所定位置に少ない被覆材料で効果的に被覆層を形成できる。
前記樹脂粉末は、その種類特に限定されないが、粒径100〜300μmのポリエチレンやポリプロピレン等のポリオレフィン樹脂粉末やPET、PEN、PLA、PBT等のポリエステル樹脂粉末が効果的に採用できる。
一方、焦げ防止物質粉末としては、安価な低誘電率物質である炭酸カルシウムやタルクが採用できる。
Molded paper vessel of the present invention to solve the above problems, a molded paper vessel microwave heating corresponding, Ri Na to form a resin coating layer containing the inhibiting substance burnt to a localized area of the paper forming the container, The resin coating layer is formed by spraying a powder obtained by mixing a non-burning substance powder with a resin powder .
In the case of a cup-shaped paper molding container, the local region is desirably the inner peripheral surface of the yarn bottom portion that is likely to be burned when heated in a microwave oven.
2. The paper-molding container for microwave heating according to claim 1, wherein the local region is an inner peripheral surface of a thread bottom portion of a cup-shaped paper-molding container, wherein the local region of the paper container contains a non-burning substance. A coating layer is formed.
The resin coating layer can be effectively formed with a small amount of coating material at a predetermined position by thermal spraying a powder obtained by mixing a non-burning substance powder with a resin powder.
The type of the resin powder is not particularly limited, but a polyolefin resin powder such as polyethylene or polypropylene having a particle diameter of 100 to 300 μm or a polyester resin powder such as PET, PEN, PLA, or PBT can be effectively employed.
On the other hand, as the non-burning substance powder, calcium carbonate and talc, which are inexpensive low dielectric constant substances, can be used.

本発明の電子レンジ対応の紙成形容器によれば、従来の紙成形容器の基本的構造を変更することなく簡易な手段により容易にマイクロ波加熱時の焦げの発生を防止できる。
そして、コップ状紙成形容器の場合、糸尻部内周面に焦げ防止物質を含有する樹脂被覆層を形成するのみで、従来のカップ状成形容器の底部形状を変更することなく、容易に焦げの発生を防止できる。
さらに、前記樹脂被覆層は、プラスチック粉末に無機物粉末を混合した粉体を溶射して形成することによって、糸尻部内周面に確実に且つ安価に焦げ防止層を形成することができる。
前記粉末樹脂としてポリエチレンやポリプロピレン等のポリオレフィン樹脂やPET、PEN、PLA、PBT等のポリエステル樹脂、前記焦げ防止物質粉末として安価な低誘電率物質である炭酸カルシウムやタルクを採用することによって、効果的に焦げ防止層を形成することができる。
そして、被覆層は、平均膜厚さが1mm以下とすることによって、安価に且つ確実に焦げ防止層を形成することができる。
According to the paper-molding container compatible with the microwave oven of the present invention, it is possible to easily prevent the occurrence of scorching during microwave heating by simple means without changing the basic structure of the conventional paper-molding container.
And in the case of a cup-shaped paper-molded container, it is easy to burn without changing the bottom shape of the conventional cup-shaped molded container, only by forming a resin coating layer containing a charring prevention substance on the inner peripheral surface of the yarn bottom part. Occurrence can be prevented.
Furthermore, the resin coating layer is formed by spraying a powder obtained by mixing an inorganic powder with a plastic powder, whereby a burn prevention layer can be reliably and inexpensively formed on the inner peripheral surface of the yarn bottom.
Effective by adopting polyolefin resin such as polyethylene and polypropylene as the powder resin, polyester resin such as PET, PEN, PLA, PBT, and calcium carbonate and talc which are inexpensive low dielectric constant materials as the anti-burning substance powder An anti-burning layer can be formed.
And a coating layer can form an anti-burning layer cheaply and reliably by making an average film thickness into 1 mm or less.

(a)は本発明の実施形態に係る紙成形容器の斜視図であり、(b)は(a)におけるA−A断面図である。(A) is a perspective view of the paper molding container which concerns on embodiment of this invention, (b) is AA sectional drawing in (a).

以下、本発明に係る紙成形容器の実施形態を図面を基に詳細に説明する。
図1は、本発明の実施形態に係る紙成形容器としての紙を主体とするコップ状紙成形容器(以下、単にコップ状容器という)を示す。該コップ状容器1は、胴部2となる扇形状のブランクの両端縁を貼り合わせて接着して円錐台状或いは円筒状に成形し、その上端部をカール成形して開口カール部3とし、下端部を内側に折り返して折り返し片6を形成し、その間に断面コ字状に絞り成形した底板8の環状屈曲部9を圧着して糸尻部10となっており、開口カール部3にはブランク両端縁の貼り合わせによる段差4ができている。また、胴部には貼り合わせ部5ができ、該貼り合わせ部の両端縁には紙端がコップ内側及び外側で露出している。以上の構造は、従来周知のコップ状容器と同様である。
Hereinafter, embodiments of a paper molding container according to the present invention will be described in detail with reference to the drawings.
FIG. 1 shows a cup-shaped paper forming container (hereinafter simply referred to as a cup-shaped container) mainly composed of paper as a paper forming container according to an embodiment of the present invention. The cup-shaped container 1 is formed by attaching and bonding both end edges of a fan-shaped blank serving as the body portion 2 to form a truncated cone shape or a cylindrical shape, and curling the upper end portion to form an open curled portion 3. A lower end portion is folded inward to form a folded piece 6, and an annular bent portion 9 of a bottom plate 8 drawn into a U-shaped cross section is crimped between them to form a yarn bottom portion 10. A step 4 is formed by pasting both edges of the blank. Further, a bonding portion 5 is formed on the body portion, and paper edges are exposed at both ends of the bonding portion on the inner side and the outer side of the cup. The above structure is the same as that of a conventionally known cup-shaped container.

このような紙成形容器は、電子レンジ加熱対応容器として、胴部ブランク材及び底部材とも紙を主体とするが、内面及び外面を液状内容物から保護するためにポリオレフィン樹脂やポリエステル樹脂等がラミネートあるいはコーティングされ、または含浸させた複合紙材、あるいは必要に応じてガスバリア層を内層に有する複合層からなる材料が採用でき、電子レンジ加熱ができる材料であれば、その材質は特に限定されない。   Such a paper molding container is a microwave heating container, and the body blank and the bottom member are mainly made of paper, but a polyolefin resin or a polyester resin is laminated to protect the inner and outer surfaces from liquid contents. Alternatively, a composite paper material coated or impregnated, or a material composed of a composite layer having a gas barrier layer as an inner layer as required can be employed, and the material is not particularly limited as long as it can be heated in a microwave oven.

以上のようなコップ状容器において、本実施形態では、電子レンジ加熱時に焦げが発生しやすい糸尻部内周面7の全周に図1(b)に示すように焦げ防止物質を含有する樹脂被覆層11を形成し、電子レンジ加熱時に焦げの発生を防止するようにした。該樹脂被覆層は、本実施形態では粒径100〜300μmの合成樹脂粉末と焦げ防止物質の粉末を混合した粉体を溶射して、糸尻部内周面7に樹脂被覆層11を形成した。
本発明に使用される粉末としては、以下に限定されないが、紙を主体とする紙成形容器に対して易接着性を有する材料を用いる。一般的な紙成形容器は、下地である紙基材に樹脂がコートされており、表面樹脂層と同種の樹脂、又は、表面樹脂層よりも融点の低い樹脂を用いることが易接着性の点で好ましい。
ここで、合成樹脂としては、熱可塑性樹脂であれば特に限定されないが、高−中−低密度ポリエチレン、ポリプロピレン等のポリオレフィン、PET、PEN、PLA、PBT等のポリエステル樹脂の一種または複数種の樹脂粉末が採用できる。また、焦げ防止粉末物質としては、比誘電率の低い物質として、例えば炭酸カルシウム、タルク等が採用できる。これにより、糸尻部でのマイクロ波の吸収による発熱が減少し、焦げの発生を防止できる。
In the cup-shaped container as described above, in the present embodiment, a resin coating containing an anti-burning substance as shown in FIG. Layer 11 was formed to prevent the occurrence of scorching during microwave heating. In this embodiment, the resin coating layer is formed by spraying a powder obtained by mixing a synthetic resin powder having a particle size of 100 to 300 μm and a non-burning substance powder to form the resin coating layer 11 on the inner peripheral surface 7 of the yarn bottom portion.
Although not limited to the following as a powder used for this invention, the material which has easy-adhesion with respect to the paper molding container which has paper as a main component is used. In general paper-molded containers, the base paper substrate is coated with a resin, and it is easy to use a resin of the same type as the surface resin layer or a resin having a lower melting point than the surface resin layer. Is preferable.
Here, the synthetic resin is not particularly limited as long as it is a thermoplastic resin, but it is a high-medium-low density polyethylene, a polyolefin such as polypropylene, a polyester resin such as PET, PEN, PLA, PBT, or a plurality of types of resins. Powder can be used. In addition, as the non-burning powder material, for example, calcium carbonate, talc or the like can be adopted as a material having a low relative dielectric constant. As a result, heat generation due to absorption of microwaves at the yarn bottom portion is reduced, and the occurrence of scorching can be prevented.

上記の紙成形容器の局所領域に焦げ防止物質を含有する樹脂被覆層の形成は、ホットメルト、ホットランナー、あるいはフレーム溶射等による方法が考えられる。しかし、本実施形態のように塗布領域がきわめて狭く且つ少量の樹脂で容器の高速製造ラインで形成するには、前記のいずれの方法でも塗布樹脂の糸引き現象が生じるため、サイクルアップに制限を受けると共に正確な塗布が難しい。それを克服するために、本実施形態では、製造ラインにおいて成形されて搬送されるコップ状形容器に後加工工程として、予備加熱工程と樹脂溶射工程を設け、予備加熱工程で樹脂塗布領域に熱風を吹き付けて糸尻部内周面を被覆樹脂の融点近傍まで予備加熱し、次いで樹脂溶射工程で該部に前記樹脂粉体を溶射した。樹脂粉体の溶射は、前記したように粒径100〜300μmの合成樹脂粉末と焦げ防止物質の粉末を混合した粉体樹脂粉末を原材料とし、該原材料を樹脂の溶融温度以下に加熱した加圧加熱ガス(本実施形態では熱風)で、噴射ノズルにより糸尻部内周面に間欠的又は連続的に溶射して樹脂盛りすることにより形成することができる。
以上のような方法で糸尻部内周面に樹脂被覆をすることによって、糸引き現象が生じることなく所定の小領域に樹脂被覆を的確にすることができ、使用材料を最小限にすることができる。
The formation of the resin coating layer containing the non-burning substance in the local region of the paper-molded container may be a method using hot melt, hot runner, flame spraying, or the like. However, as in this embodiment, in order to form a container with a very small coating area and a high-speed production line of a container with a small amount of resin, the stringing phenomenon of the coating resin occurs in any of the above methods, and thus the cycle up is limited. It is difficult to apply accurately. In order to overcome this, in the present embodiment, a pre-heating step and a resin spraying step are provided as post-processing steps on the cup-shaped container that is molded and transported in the production line, and hot air is applied to the resin application region in the pre-heating step. Was sprayed to preheat the inner peripheral surface of the yarn bottom part to near the melting point of the coating resin, and then the resin powder was sprayed onto the part in a resin spraying step. As described above, the thermal spraying of the resin powder uses a powder resin powder obtained by mixing a synthetic resin powder having a particle size of 100 to 300 μm and a non-burning substance powder as a raw material, and pressurizing the raw material at a temperature lower than the melting temperature of the resin. It can be formed by thermally spraying a resin gas intermittently or continuously on the inner peripheral surface of the yarn bottom with a spray nozzle (hot air in this embodiment).
By applying the resin coating to the inner peripheral surface of the yarn bottom portion by the method as described above, the resin coating can be accurately performed in a predetermined small area without causing the yarn drawing phenomenon, and the material used can be minimized. it can.

コップ状容器の糸尻部内周面に全周にわたって以下の条件で樹脂被覆を行った。
供試容器:コップ状容器(材質:胴部及び底部とも同じ)
材質層構成:
胴部:(内)ポリエチレン(20μm)//スラッシュスラッシュ紙(250g/m
底部:(内)ポリエチレン(40μm)//紙250g/m//ポリエチレン(15μm)
満杯内容量:565ml、 糸尻部高さ:10mm
溶射条件:
粉体樹脂:平均粒径120μmの粉体ポリエチレン
焦げ防止物質:炭酸カルシウム
樹脂塗膜:糸尻部内周全周に沿って幅約10mm、被膜厚さ1mm以下
以上のようにして糸尻部内周面に焦げ防止物質を含有する樹脂被覆層を形成した。コップ状容器の焦げの発生状況を確認するために、次のような試験を行った。
容器充填内容物:水330ml
電子レンジ出力:500W
加熱時間:6min
上記加熱条件は、内容物(うどん食品)を食するのに最適な通常の加熱温度である。
焦げの発生状況:被覆層を形成した本実施例の容器の方が糸底部に発生した焦げの色が、比較例として被覆層を設けていない容器よりも薄く範囲が狭かった。
Resin coating was performed on the inner peripheral surface of the thread bottom portion of the cup-shaped container over the entire circumference under the following conditions.
Test container: cup-shaped container (material: same for trunk and bottom)
Material layer structure:
Body: (Inner) Polyethylene (20μm) // Slash slash paper (250g / m 2 )
Bottom: (inside) polyethylene (40 μm) // paper 250 g / m 2 // polyethylene (15 μm)
Full capacity: 565ml, thread bottom height: 10mm
Thermal spraying conditions:
Powder resin: Powdered polyethylene with an average particle size of 120 μm Anti-burning substance: Calcium carbonate Resin coating film: Width of about 10 mm along the entire inner circumference of the yarn bottom and a film thickness of 1 mm or less. A resin coating layer containing an anti-burning substance was formed. In order to confirm the occurrence of scorching of the cup-shaped container, the following test was conducted.
Container filling contents: 330 ml of water
Microwave oven output: 500W
Heating time: 6 min
The said heating conditions are the normal heating temperature optimal for eating the contents (Udon food).
Situation of scoring: The container of the present example in which the coating layer was formed was thinner in the color of the scoring color generated at the bottom of the yarn than the container without the coating layer as a comparative example.

以上、本発明の電子レンジ対応の紙成形容器の実施形態及び実施例を説明したが、本発明はこれらのものに限るものでなく、紙成形容器としては必ずしも糸尻部を有するカップ形状の容器に限るものでなく、電子レンジ対応の紙成形容器の焦げが発生しやすい部位を有する種々の構造のものに適用可能である。   As mentioned above, although the embodiment and the Example of the paper-molding container corresponding to a microwave oven of the present invention were explained, the present invention is not limited to these, and a cup-shaped container having a yarn end portion is not necessarily used as a paper-molding container. The present invention is not limited to this, and the present invention can be applied to a variety of structures having a portion that is likely to cause scoring of a microwave-compatible paper-molded container.

本発明は、紙成形容器における電子レンジ加熱時における焦げの発生部位に焦げ発生抑制物質を含む樹脂盛りをすることによって、簡単な構成で電子レンジ対応の紙成形容器の焦げ発生を抑制ができ、安価な構成で電子レンジ対応の紙成形容器を得ることができ産業上の利用可能性が高い。   The present invention can suppress the occurrence of scorching in a microwave-compatible paper-molded container with a simple configuration by placing a resin containing a scorch-generating suppression substance at the scorching occurrence site at the time of microwave oven heating in a paper-molded container, A paper-molded container compatible with a microwave oven can be obtained with an inexpensive configuration, and the industrial applicability is high.

1 コップ状容器
2 胴部
3 開口カール部
4 段差部
5 胴部貼り合わせ部
6 折返し片
7 糸尻部内周面
8 底部
9 環状屈曲部
10 糸尻部
11 樹脂被覆層
DESCRIPTION OF SYMBOLS 1 Cup-shaped container 2 trunk | drum 3 opening curl part 4 level | step difference part 5 trunk | drum bonding part 6 folding | turning piece 7 thread | yarn bottom part inner peripheral surface 8 bottom part 9 cyclic | annular bending part 10 thread | yarn bottom part 11 resin coating layer

Claims (5)

電子レンジ加熱対応の紙成形容器であって、該紙成形容器の局所領域に焦げ防止物質を含有する樹脂被覆層を形成してなり、該樹脂被覆層は、樹脂粉末に焦げ防止物質粉末を混合した粉体を溶射して形成したものであることを特徴とする紙成形容器。 A molded paper vessel microwave heating corresponding, Ri Na to form a resin coating layer containing the inhibiting substance burnt to a localized area of the paper forming the container, the resin coating layer, an anti-material powder burnt resin powder A paper-molded container formed by spraying mixed powder . 前記局所領域が、コップ状紙成形容器の糸尻部内周面である請求項1に記載の紙成形容器。   The paper forming container according to claim 1, wherein the local region is an inner peripheral surface of a thread bottom portion of the cup-shaped paper forming container. 前記樹脂粉末がポリオレフィンまたはポリエステル樹脂である請求項1又は2に記載の紙成形容器。 The paper molded container according to claim 1 or 2 , wherein the resin powder is a polyolefin or a polyester resin. 前記焦げ防止物質粉末が比誘電率2以下の無機物である請求項1〜3何れかに記載の紙成形容器。   The paper-molding container according to any one of claims 1 to 3, wherein the non-burning substance powder is an inorganic substance having a relative dielectric constant of 2 or less. 前記樹脂被覆層は、平均膜厚さが1mm以下である請求項1〜何れかに記載の紙成形容器。 The paper-molding container according to any one of claims 1 to 4 , wherein the resin coating layer has an average film thickness of 1 mm or less.
JP2014112616A 2014-05-30 2014-05-30 Microwave-compatible paper molding container Expired - Fee Related JP6488560B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2014112616A JP6488560B2 (en) 2014-05-30 2014-05-30 Microwave-compatible paper molding container
EP15800664.3A EP3150502A4 (en) 2014-05-30 2015-05-29 Shaped paper article, localized-region coating method, and coating device
CN201580027343.XA CN106414252B (en) 2014-05-30 2015-05-29 Paper formed body, local area covering method and covering device
PCT/JP2015/065631 WO2015182760A1 (en) 2014-05-30 2015-05-29 Shaped paper article, localized-region coating method, and coating device
US15/314,578 US20170191151A1 (en) 2014-05-30 2015-05-29 Formed paper article, local region coating method, and coating device
KR1020167033841A KR101877275B1 (en) 2014-05-30 2015-05-29 Shaped paper article, localized-region coating method, and coating device
KR1020187004758A KR101894755B1 (en) 2014-05-30 2015-05-29 Shaped paper article, localized-region coating method, and coating device
CN201810184719.3A CN108284995A (en) 2014-05-30 2015-05-29 Regional area coating method and coating device

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JPS587900U (en) * 1981-07-07 1983-01-19 株式会社興人 laminated paper
JPH11198923A (en) * 1998-01-13 1999-07-27 Toppan Printing Co Ltd Retort sterilizable paper container
JP2008105749A (en) * 2006-09-29 2008-05-08 Dainippon Printing Co Ltd Resin molded container for microwave oven and molded container with microwave heating liquid food
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