JP6504652B2 - Cosmetics for eyebrows - Google Patents

Description

  The present invention relates to a cosmetic for eyebrows and, more particularly, to a cosmetic for eyebrows which is excellent in volume effect, non-sticky, smooth in use and easy to drop.

The main effect required for cosmetic for eyebrows is a cosmetic effect (volume effect) that makes the eyes beautiful and distinctive by making the eyelids look thick and thick. In recent years, there has been an increasing demand for reducing the burden of eyebrows due to the trend of cosmetic solutions for eyebrows, and there is no stickiness that causes friction to the eyebrows, as well as good finish for eyebrow cosmetics Also, it is required from the viewpoint of not putting a burden on the eyebrows that the mascara brush can be applied to the eyebrows smoothly without causing the wrinkles that cause the eyebrows to be rubbed many times. Furthermore, when dropping makeup, the ease of removing with light liquid isoparaffin, isododecane, or a cleansing agent that does not contain volatile oil such as cyclomethicone also does not burden the eyelid and surrounding skin. It has been demanded.
Conventionally, cosmetic products for eyebrows are composed mainly of solid oil such as wax, film forming agent such as resin or synthetic polymer, powder, etc., in order to have functionality meeting consumer's requirements, Various studies have been conducted.
For example, a co-polymer of an alkene and a vinyl acetate, a polar wax, and a specific surfactant which is used in combination to improve the volume effect, good lubricity, and cosmetic durability (see Patent Document 1), volatile hydrocarbons, By using a combination of non-ionic surfactant, non-volatile non-silicone liquid oil, organic silicone resin, high melting point wax with melting point of 95 to 130 ° C, semi-solid oil and organically modified clay mineral, curl keeping effect and sebum resistance Techniques (see Patent Document 2) for improving the properties, cleansing properties and adhesiveness are known.

JP, 2010-83890, A JP, 2012-188394, A

However, in the technology of improving the feeling of volume by the copolymer of solid components and the wax as in the technology of Patent Document 1, since the cosmetic film becomes hard, a special removing agent such as an eye makeup remover is required, and the volume effect is achieved. The problem is that when the amount of solid component increases, it becomes difficult to fall off and the burden on the brows at the time of removal is large. In addition, in the cosmetic obtained in Patent Document 2, a special release agent such as an eye makeup remover is required because the film formed by the high melting point wax is hard, and the non-volatile non-silicone liquid oil agent is crumpled Because it is strong, it has a drawback of impairing the smooth feeling of use.
The present invention relates to a cosmetic for eyebrows, and more specifically, it is an object of the present invention to provide a cosmetic for eyebrows which is excellent in volume effect, non-sticky, smooth in use and easy to drop.

  Under these circumstances, the inventor of the present invention has intensively studied and, as a result, focused on the fact that liquid branched higher alcohols having 20 to 26 carbon atoms provide a smooth and light feeling of use without wrinkles on the heel, In search of solid oil to solidify high alcohol, solid oil extracted from sunflower seeds solidifies these high alcohol, and it is easy to adhere to the cocoon and can not only give volume but also not stickiness, with small shear stress The inventors have found that they form a cosmetic film that is easy to drop because they spread smoothly and conform to a cleansing agent, and that the volume effect is significantly improved by combining an oil-soluble film forming agent, and the present invention is completed. It came to

That is, the present invention
[1] The following components (A) to (C):
(A) 0.1 to 3% by mass of sunflower wax (B) octyl dodecanol and / or decyl tetradecanol
(C) at least one selected from trimethylsiloxysilicate, polymethylsilsesquioxane, (acryates / dimethicone) copolymer, and dextrin isostearate ;
Said components (A) and the content weight ratio of (B) is (A) :( B) = 30 : 1~1: 3 der Ru eyelash cosmetics,
[2] is found, it relates to the eyelashes for cosmetic according to the containing component (D) Silicone Powder [1].

  The present invention provides a cosmetic for eyebrows which is excellent in volume effect, non-sticky, smooth in use and easy to drop.

Hereinafter, the present invention will be described in detail. In addition, in this specification, "-" shall mean the range including the numerical value before and behind that.
The sunflower wax of the component (A) used in the present invention is mainly obtained from long-chain fatty acids and long-chain alcohols and obtained from sunflower seeds and is monoester having a total carbon number of 32-62 and having a melting point of 70 It is a natural solid oil in the range of -85 ° C. Specifically, although not particularly limited, Helianthus Annuus (Sunflower) Seed Wax (Japanese name: sunflower seed wax) and the like can be mentioned under the name of INCI (International Nomenclature of Cosmetic Ingredient), and as a commercial product, purified sunflower wax ( Yokoseki Yushi Kogyo Co., Ltd.) and the like.

  The content of the component (A) in the present invention is not particularly limited, but is preferably 0.5 to 20% by mass (hereinafter simply referred to as%), more preferably 1 to 15%. If it is this range, it is more preferable at the point which the volume effect of a cosmetic film, non-stickiness, smooth feeling of use, ease of dropping etc. are more excellent.

The branched higher alcohol having 20 to 26 carbon atoms of the component (B) used in the present invention is a higher alcohol having a total carbon number of 20 to 26, and has at least one branch in the hydrocarbon portion, It can be used without particular limitation as long as it is usually used for cosmetics. The number of carbon atoms in the side chain of the branched higher alcohol is preferably 1 to 13. The number of branches is not particularly limited, but is preferably 1 to 3, and more preferably 1.
Examples of such component (B) include, but are not limited to, octyldodecanol, decyltetradecanol and the like, and among them, decyltetradecanol is combined with component (A). It is more preferable at the point which is excellent in the smooth use feeling at the time. Examples of commercially available products include Oitanol G (manufactured by Cognis Japan Ltd.), Lisolol 24SP (manufactured by High Alcohol Co., Ltd.), Enjecor 240A (manufactured by Shin Nippon Rika Co., Ltd.), and the like.

  The content of the component (B) in the present invention is not particularly limited, but is preferably 0.1 to 5%, and more preferably 0.5 to 3%. If it is this range, it is more preferable at the point which the non-stickiness, the ease of dropping, etc. are more excellent.

  The oil-soluble film-forming agent of the component (C) used in the present invention forms a film which is soluble in an oil such as volatile oil and has no flowability, and is generally used in cosmetics. There is no particular limitation, and it can be used. Here, the film having no fluidity means, for example, a mixture of an oil-soluble film-forming agent dissolved in a volatile oil is applied to a glass plate and the volatile oil is volatilized and then the glass plate is tilted. It is a film whose shape does not change. For example, terpene resin, silicone resin, hydrocarbon resin, vinyl acetate resin, esterified product of dextrin and fatty acid, the average degree of polymerization of dextrin glucose is 3 to 150, and fatty acid has 4 to 26 carbon atoms Of one or two or more of the branched saturated fatty acids with respect to the total fatty acid and a linear saturated fatty acid having 2 to 22 carbon atoms, a linear or One or two or more selected from the group consisting of saturated fatty acids and cyclic saturated or unsaturated fatty acids having 6 to 30 carbon atoms, containing 0 mol% or more and less than 50 mol% with respect to total fatty acids, of fatty acids per glucose unit The dextrin fatty acid ester etc. whose substitution degree is 1.0-3.0 are mentioned. Specifically, INCI name, TRIMETHYLSI LOXY SILICATE (Japanese name: trimethylsiloxysilicic acid), POLYMETHYLSILSESQUIOXANE (Japanese name: polymethylsilsesquioxane), ACRYLATES / DIMETHICONE COPOLYMER (Japanese name: (acryates / dimethicone) copolymer), DEXTRIN ISOSTEARATE (Japanese name: isostearic acid dextrin) is mentioned, and these are more preferable in terms of volume effect, non-stickiness and ease of dropping. Commercially available products include KF7312J (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KF-9021 (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), BY11-018. (Solid content: 30%, solvent: cyclopentasiloxane, manufactured by Toray Dow Corning Co., Ltd.), KP 541 (solid content: 60%, solvent: isopropanol, manufactured by Shin-Etsu Chemical Co., Ltd.), SR-1000 (Momentive Performance Materials Japan) KP 545 (solid content 30%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KP 575 (solid content 30%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), SILFORM FLEXIBLE RESIN (momentive · · Performance Materials Japan Ltd.), Propanol B-100 (manufactured by BASF), Yunifiruma HVY (manufactured by Chiba Flour Milling Co., Ltd.).

  The content of the component (C) in the present invention is preferably 0.5 to 25% as a solid content concentration, and more preferably 1 to 15%. Within this range, it is more preferable in that the volume effect, the non-stickiness, the ease of dropping, and the like are more excellent.

  The silicone powder of component (D) used in the present invention may be spherical, plate-like, spindle-like, needle-like or the like, or in the form of aerosol, fine particles, pigment grade, etc. No particular limitation is imposed on its particle size, or its particle structure such as porous or nonporous, and any silicone powder can be used as long as it is present as particles in a cosmetic. Specifically, the INCI name, POLYMETHYLSILSESQUIOXANE (Japanese name: polymethylsilsesquioxane), VINYL DIMETHICONE / METHICONE SILSES QUIOXANE CROSSPOLYMER (Japanese name: (vinyl dimethicone / methicone silsesquioxane) cross polymer), DIPHENYL DIMETHICONE / VINYLL DIPHENYL DIMETHICONE / SILSESQUIOXANE CROSSPOLYMER (Japanese name: (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) crosspolymer), DIMETHICONE / VINYLDIMETHICONE CROSSPOLYMER (Japanese name: (dimethicone / vinyl dimethicone) crosspolymer), and the like. Commercial products include Tospearl 145A, Tospearl 150KA (manufactured by Momentive Performance Materials Japan), KSP-100, KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd.), EP-5500, and EP-2601 (Toray Dow Corning) And the like. Although not particularly limited, those having an average particle diameter of 3 to 10 μm are preferable in terms of feel, and spherical or substantially spherical ones are preferably used in terms of smooth feeling in use and non-stickiness. Among them, substantially spherical particles having silicon microprotrusions over the entire surface of the particle are more preferable in terms of smooth feeling in use and non-stickiness. These powders are characterized in their shape and have a plurality of scientifically coupled microprotrusions on the entire particle surface with a plurality of microprotrusions, and the projections are not easily lost. For the projections, the average value of the diameter of the projections / the diameter of the base particle is 0.01 to 0.3, and the average value of the height of the projections / the diameter of the base particles is 0.01 to 0 Preferably, .3. Commercially available products of such approximately spherical silicone particles include Tospearl 150KA (manufactured by Momentive Performance Materials Japan Co., Ltd.) and the like.

  The content of the component (D) in the present invention is preferably 0.5 to 20%, more preferably 1 to 15%. Within this range, volume effect, no stickiness, smooth feeling in use, and the like are more preferable in that they are more excellent.

  In the present invention, although not particularly limited, the content mass ratio of the component (A) to the component (B) is preferably (A) :( B) = 30: 1 to 1: 3, and more preferably (A): (B) = 20: 1 to 1: 1. Within this range, the effects of the present invention can be maximized in terms of volume effect, non-stickiness, smooth feeling of use, ease of dropping, and the like.

  In addition to the above components (A) to (D), the cosmetic for wrinkles of the present invention is a component generally used for cosmetics, for example, an oil component other than the above component, a powder component, a fiber, a surfactant Film-forming polymer emulsion, water-based component, ultraviolet light absorber, moisturizing agent, anti-fading agent, antioxidant, anti-foaming agent, cosmetic component, preservative, spice, etc. in the range not to impair the effect of the present invention be able to.

  The oil component other than the above components is not particularly limited as long as it can be used for cosmetics, and sources of animal oil, vegetable oil, synthetic oil etc., and solid oil, semisolid oil, liquid oil, volatile oil etc. Hydrocarbons, fats and oils, hydrogenated oils, ester oils, fatty acids, higher alcohols other than component (B), silicone oils, fluorinated oils, lanolin derivatives, oily gelation regardless of the nature of And the like.

  Specifically, hydrocarbons such as paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, liquid paraffin, isododecane, hydrogenated polyisobutene, squalane, vaseline, polybutene, etc. Oils such as hydrogenated jojoba oil, beeswax, carnauba wax, candelilla wax, rice wax, geyrow, wax, such as olive oil, castor oil, jojoba oil, mink oil, macadamian oil, cetyl isooctanate , Isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate Esters such as glyceryl tribehenate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L-glutamic acid di (cholesteryl / behenyl / octyldodecyl), low polymerization degree dimethylpolysiloxane, high polymerization degree dimethylpolysiloxane, methyl Phenylpolysiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, crosslinked organopolysiloxane, fluorine-modified polysiloxane, silicone such as dimethiconol, perfluorodecane, perfluorooctane , Fluorinated oils such as perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, stearin Fatty acids such as lauric acid, myristic acid, behenic acid, oleic acid, palmitic acid and isostearic acid, dextrin fatty acid esters other than component (C), sucrose fatty acid esters, oily gelling agents such as aluminum isostearate and calcium stearate Etc. These oily components can be used alone or in combination of two or more as needed.

  The powder component is a component other than the component (D), and in the case of a powder generally used for cosmetics, particles such as spherical, plate-like and needle-like shapes, smoke-like, fine particles and pigment grade It is not particularly limited by particle structure such as diameter, porous and non-porous, etc., and inorganic powders, bright powders, organic powders, pigment powders, metal powders, composite powders, etc. Can be mentioned. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, chromium hydroxide, bitumen, ultramarine etc. Colored inorganic pigments, talc, muscovite, phlogopite, flash mica, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, White matter powder such as antimony oxide, diatomaceous earth, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium oxide coated mica , Titanium oxide coated bismuth oxychloride, iron oxide mica Bright powder such as tan, bitumen-treated mica titanium, carmine-treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder Body, Organic low molecular weight powder such as zinc stearate and N-acyl lysine, Natural organic powder such as silk powder, cellulose powder and dextrin powder, Red No. 201, Red No. 202, Red No. 205, Red No. 226, Red No. 228, Orange 203, Orange 204, Blue 404, Yellow 401 etc., Red 3, Red 104, Red 106, Orange 205, Yellow 4, Yellow 5, Yellow 5, Green 3, Blue Zirconium, barium or aluminum lakes such as No. 1 etc. Organic pigment powder or metal powder such as aluminum powder, gold powder or silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide containing silicon dioxide, etc. And powders of nylon, polyester, rayon, cellulose and the like. These may be surface-treated with a fluorine compound, silicone oil, powder, oil, gelling agent, emulsion polymer, surfactant and the like. These powders may be used alone or in combination of two or more, and may be used in combination.

  The fibers include synthetic fibers such as nylon, polypropylene and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate human silk, etc. The shape is not particularly limited, and the cross section is a circle Any of shapes, ovals, polygons, wells, T-shapes, Y-shapes, etc. can be used. Furthermore, these fibers may be colored with a coloring agent if necessary, and the surface treatment agent may be surface-treated with a fluorine compound, silicone oil, powder, oil, gelling agent, emulsion polymer, surfactant, etc. You may use it.

  As the surfactant, any surfactant which is generally used in cosmetics can be used, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Can be mentioned. As a nonionic surfactant, for example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition , Fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene of lanolin Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether modified silicone And the like. Examples of anionic surfactants include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonated fatty acids Salt, acyl methyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl And phenyl ether phosphate. Examples of cationic surfactants include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, cyclic quaternary ammonium salts and the like. Amphoteric surfactants include amino acid type, betaine type carboxylic acid type, sulfuric acid ester type, sulfonic acid type and phosphoric acid ester type. One or more of these surfactants can be used, as necessary.

As a film-forming polymer emulsion, a liquid obtained by polymerizing monomers emulsified with a surfactant in a system in which fine particles of a polymer are stably dispersed in an aqueous solvent, or a milky sap existing in the natural world It is not particularly limited as long as it is generally used in cosmetics, and any one can be used.
For example, alkyl acrylate copolymer emulsion, alkyl acrylate / styrene copolymer emulsion, polyvinyl acetate emulsion, vinyl pyrrolidone / styrene copolymer emulsion etc. may be mentioned, and commercially available products include YODOSOL 32A 707, YODOSOL GH 810 F, YODOSOL GH 800 F (manufactured by Akzo Nobel), Plexitol B-500 (manufactured by ROHM GMBH), Rica Bond ET-F 527 (manufactured by Chuo Science Industry Co., Ltd.), vinibran 1080, vinibran 1128C, vinibran 1080M, vinibran 1080T, vinibran GV-5651, vinibran 1108 S / W (made by Nisshin Chemical Industry Co., Ltd.) and ANTARA 430 (made by ISP company) are mentioned. These polymer emulsions may be used alone or in combination of two or more, as required.

  The aqueous component may be any of water and water-soluble components, and examples thereof include lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, Glycols such as 2-pentanediol, glycerols such as glycerin, diglycerin and polyglycerin, plant extracts such as aloe vera, witch hazel, hamamelis, lavender and rose, guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, Sodium alginate, carrageenan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, alkylated carboxyvinyl polymer, polyacrylic acid sodium Arm, proteins, mucopolysaccharides, collagen, elastin, keratin, and the like.

  Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic acid UV absorbers such as methyl anthranilate, salicylic acid UV absorbers such as methyl salicylate, and octyl paramethoxycinnamate. Examples thereof include cinnamic acid-based ultraviolet light absorbers, benzophenone-based ultraviolet light absorbers such as 2,4-dihydroxybenzophenone, and urocanic acid-based ultraviolet light absorbers such as ethyl urocanic acid. In addition, hexyl diethylaminohydroxybenzoyl benzoate, dimethic acid diethyl benzyl malonate, 2,4-bis {[4- (2-ethylhexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1 3,5-Triazine, methylenebisbenzotriazole tetramethylbutylphenol, 4-tert-butyl-4'-methoxybenzoylmethane, octocrylene, octyl triazone and the like can be used. Examples of the antioxidant include α-tocopherol and ascorbic acid, and vitamins. Examples of the preservative include p-hydroxybenzoic acid ester and phenoxyethanol.

  The cosmetic for eyelids of the present invention includes mascara, mascara overcoat, mascara base and the like, and may be used for any of oil-based, oil-in-water type and water-in-oil type. The oil-based cosmetic for wrinkles of the present invention is one that contains substantially no water, with a water content of 1% or less.

  The present invention will be described in detail by way of examples. In addition, these do not limit the present invention at all.

Examples 1 to 10 and Comparative Examples 1 to 6: Oil-based mascara An oil-based mascara having the formulation shown in Table 1 below was prepared, and the volume effect, no stickiness and smooth feeling in use were evaluated by the following methods. Moreover, the ease of dropping was evaluated by the following method. The results are also shown in Table 1.

* 1: IP solvent 1620 MU (made by Idemitsu Kosan Co., Ltd.)
* 2: Leopearl TL (made by Chiba Powder Co., Ltd.)
* 3: Refined sunflower wax (Yokoshiki Yushi Industry Co., Ltd.)
* 4: BENTONE 27V (manufactured by ELEMENTIS)
* 5: Enjecor 240A (manufactured by Shin Nippon Rika Co., Ltd.)
* 6: KF7312J (Shin-Etsu Chemical Co., Ltd.) (solid content 50%, solvent: cyclopentasiloxane)
* 7: KP 541 (solid content 60%, solvent: isopropanol, Shin-Etsu Chemical Co., Ltd.)
* 8: Tospearl 2000 B * (average particle diameter 6 μm, manufactured by Momentive Performance Materials Japan)
* 9: KSP-300 (average particle size 5 μm, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 10: Silysia 550 (manufactured by Fuji Silysia Chemical Ltd.)

(Production method)
A. The components (1) to (7) are heated to 100 ° C. and mixed uniformly.
B. Ingredients (8) to (17) are added to A and dispersed uniformly.
C. Fill B into a container to make a product.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Volume effect b. No stickiness
c. Smooth feeling of use d. Ease of Dropping For the evaluation items a, b and c, each sample is subjected to a use test by 20 experts, and each panel evaluates and ranks it in 7 levels according to the following absolute evaluation criteria, and all panels of each sample The average value was calculated from the score total of and it determined by the following determination criteria.
<Absolute evaluation criteria>
(Score): (Evaluation)
6: very good 5: good 4: somewhat good 3: normal 2: somewhat bad 1: bad 0: very bad <criteria>
(Judgement): (average score)
:: more than 5 points: very good ○: 5 points or less over 3.5 points: good :: less than 1 point 3.5 points or less: slightly defective ×: 1 or less: defective

About evaluation item d, after taking about 2 g of cleansing of the prescription shown below to cotton, and making it use for about 30 seconds, ease of dropping when wiping off the cosmetic film by the action of dropping mascara usually, the following judgment criteria It judged by.
(Cleansing prescription for evaluation)
(Component) (%)
(1) Mineral oil balance (2) Ethyl ethyl hexanoic acid 20
(3) Triethylhexanoin 20
(4) Tetraoleate solves-30 8
(5) Phenoxyethanol 0.5
(Production method)
A. Ingredients (1)-(5) are mixed.
B. The container was filled with A to obtain cleansing.

<Judgment criteria (ease of dropping)>
(Judgment): (Evaluation criteria)
:: completely dropped ○: almost dropped :: half not dropped ×: not completely dropped

As apparent from the results of Table 1, the oil-based mascaras of Examples 1 to 10 of the present invention have all of the volume effect, non-stickiness, smooth feeling in use, and ease of dropping compared to the oil-based mascaras of Comparative Examples 1 to 6. Were excellent.
On the other hand, in Comparative Examples 1 to 3 in which another wax was used instead of the component (A), decyltetradecanol could not be held in the wax structure, so that it could stick to oil at the time of application. Satisfactory results were not obtained in terms of effects and smooth feeling of use. In Comparative Example 4 in which the component (B) was not contained, it was easy to feel the stickiness of the resin, and the cosmetic film was too hard to be removed because it became too hard. In Comparative Example 5 in which a low viscosity polar oil is used instead of the component (B), it is not retained in the wax structure of the component (A), so that it may stick to oil when applied, resulting in a volume effect and a smooth feeling of use. It was not enough. In Comparative Example 6 in which the component (C) was not contained, the adhesion to the eyelids was not sufficient, and a satisfactory one was not obtained in terms of the volume effect.

Examples 11 to 19 and Comparative Examples 7 to 12: Oil-in-water type mascara The oil-in-water type mascara of the formulation shown in Table 2 below is prepared, and the volume effect, no stickiness, smooth feeling of use, ease of dropping are examples. It evaluated using the evaluation method of 1-10, and comparative example 1-6. The results are also shown in Table 2.

* 11: Unifilma HVY (manufactured by Chiba Powder Co., Ltd.)
* 12: Tospearl 150 KA (average particle size 5 μm, manufactured by Momentive Performance Materials Japan)
* 13: ACULYN 33A (solid content 28%) (manufactured by Rohm & Haas Co.)
* 14: Silososphere C-1504 (manufactured by Fuji Silysia Chemical Ltd.)
* 15: YODOSOL 810F (solid content 46%) (manufactured by Akzo Nobel)
* 16: Vinizole 1086WP (solid content 40%) (manufactured by Daido Chemical Industries, Ltd.)
* 17: Vinisole 2140 L (solid content 43%) (manufactured by Daido Chemical Industries, Ltd.)

(Production method)
A. The components (1) to (14) are heated to 100 ° C. and mixed uniformly.
B. Ingredients (15)-(22) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled to room temperature and filled in a container with an applicator to obtain a product.

As is clear from the results in Table 2, the oil-in-water mascaras of Examples 11 to 19 of the present invention have a volume effect, no stickiness, a smooth feeling of use, and drops compared to the oil-in-water mascaras of Comparative Examples 7 to 12. All of the ease was excellent.
On the other hand, in Comparative Examples 7 to 9 in which another wax was used instead of the component (A), decyltetradecanol could not be held in the wax structure, so that it could become oily after application. Satisfactory results were not obtained in terms of volume effect and smooth feeling of use. In Comparative Example 10 in which the component (B) was not contained, it was easy to feel the stickiness of the resin, and the cosmetic film was too hard to be removed because it became too hard. In Comparative Example 11 in which a low viscosity polar oil is used instead of the component (B), it is not retained in the wax structure of the component (A), so it becomes oily after application, resulting in a volume effect and a smooth feeling of use. It was not enough. In Comparative Example 12 in which the component (C) was not contained, the adhesion of the mascara liquid to the brow was not sufficient, and a satisfactory one in terms of the volume effect was not obtained.

Example 20: Water-in-oil mascara (creamy)
(Component) (%)
(1) Light liquid isoparaffin * 1 remaining amount (2) Isostearic acid dextrin * 11 4
(3) Dextrin palmitate * 2 5
(4) Sunflower wax * 3 3
(5) Polyethylene wax * 18 3
(6) Beeswax (melting point 65 ° C) 5
(7) Trimethylsiloxysilicic acid solution * 19 15
(8) Trimethylsilsesquioxane * 20 5
(9) Dimethiconol (100,000 mPa · s) * 21 3
(10) decyl tetradecanol * 5 0.5
(11) Organically Modified Bentonite * 22 4
(12) Silica * 23 2
(13) Black iron oxide 5
(14) N-lauroyl-L-lysine * 24 1
(15) Silicone powder * 8 3
(16) Purified water 5
(17) Alkyl acrylate copolymer emulsion * 25 5
* 18: Synthetic wax P-200 (made by Nippon Natural Products)
* 19: KF-9021 (solid content 50%, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 20: SILFORM FLEXIBLE RESIN (Momentive Performance Materials Japan)
* 21: X-21-5849 (Shin-Etsu Chemical Co., Ltd.)
* 22: Lucentite SAN-P (Coop Chemical Co., Ltd.)
* 23: AEROSIL 200 (made by Nippon Aerosil)
* 24: Ami Hope LL (made by Ajinomoto Co.)
* 25: Yodosol GH256F (solid content 29%) (manufactured by Akzo Nobel)

(Production method)
A. Ingredients (1) to (15) are heated to 100 ° C. and mixed uniformly.
B. B. Ingredients (16)-(17) are mixed uniformly.
C. Add B to A and emulsify.
D. Fill the container with C to make a product.

  The water-in-oil mascara (cream-like) of the present invention has excellent volume effect, no stickiness, smooth feeling of use, and is easy to drop.

Example 21: Oily mascara (fiber-containing type)
(Component) (%)
(1) Cyclopentasiloxane balance (2) Hydrogenated abietic acid glyceryl * 26 3
(3) (Acrylate / Dimethicone) Copolymer Solution * 27 15
(4) Sucrose fatty acid ester * 28 3
(5) Sunflower wax * 3 4
(6) Rice wax (melting point 80 ° C) 3
(7) Paraffin wax (melting point 58 ° C) 5
(8) Stearyl dimethicone (melting point 40 ° C.) 2
(9) N-vinylpyrrolidone triacontane copolymer * 29 2
(10) decyl tetradecanol * 5 3
(11) Lecithin 1
(12) Silylation treated silica * 30 1
(13) Carbon black 1
(14) Polyethylene terephthalate powder * 31 3
(15) Silicone powder * 32 0.5
(16) Polypropylene fiber (5T, 2 mm) 0.5
(17) Nylon 12 fiber (5T, 1 mm) 1
(18) Nylon 66 fiber (17 T, 2 mm) 1
(19) Phenoxyethanol 1
* 26: Pine Crystal KE-311 (Arakawa Chemical Industries Co., Ltd.)
* 27: KP 545 (solid content 30%, solvent: cyclopentasiloxane) (Shin-Etsu Chemical Co., Ltd.)
* 28: Sugar wax S-10E (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)
* 29: ANTARON WP 660 (made by ISP)
* 30: AEROSIL R-972 (manufactured by Nippon Aerosil Co., Ltd.)
* 31: Snowleaf P (made by Orken)
* 32: KSP-100 (average particle size 5 μm, manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A. The components (1) to (11) are heated to 100 ° C. and mixed uniformly.
B. Ingredients (12) to (19) are added to A and dispersed uniformly.
C. Fill B into a container to make a product.

  The oil-based mascara (fiber-containing type) of the present invention is excellent in volume effect, non-sticky, smooth in use and easy to drop.

Example 22: oil-in-water mascara base (creamy)
(Component) (%)
(1) Cyclopentasiloxane 3
(2) Stearic acid 1
(3) Palmitic acid 1
(4) decyl tetradecanol * 5 0.1
(5) Sunflower wax * 3 3
(6) Microcrystalline wax * 33 3
(7) cholesterol 2
(8) Rice sterol 2
(9) Trimethylsiloxysilicate * 34 0.5
(10) Purified water remaining amount (11) Carboxymethylcellulose 1
(12) Alkyl acrylate / vinyl acetate copolymer emulsion * 17 10
(13) Triethanolamine 1.2
(14) Titanium oxide coated glass powder 1
(15) Polyethylene terephthalate, aluminum, epoxy laminated powder 0.5
(16) Trehalose 0.5
(17) Polyvinyl alcohol 1
(18) Silicone powder * 12 3
* 33: MULTIWAXW-835 MYCROCRYSTALLINEWAX (made by Sonneborn)
* 34: SR-1000 (manufactured by Momentive Performance Materials Japan)

(Production method)
A. Ingredients (1) to (9) are heated to 100 ° C and mixed uniformly.
B. Ingredients (10)-(18) are mixed uniformly and heated to 80 ° C.
C. Add B to A and emulsify.
D. C is cooled to room temperature and filled in a container with an applicator to obtain a product.

The oil-in-water type mascara base (cream-like) of the present invention is excellent in volume effect, non-sticky, smooth in use feeling, and easy to drop.

Claims (2)

The following components (A), (B) and (C);
(A) 0.1 to 3% by mass of sunflower wax (B) octyl dodecanol and / or decyl tetradecanol
(C) at least one selected from trimethylsiloxysilicate, polymethylsilsesquioxane, (acryates / dimethicone) copolymer, and dextrin isostearate ;
It said components (A) and the content weight ratio of (B) is (A) :( B) = 30 : 1~1: 3 der Ru eyelash cosmetics. The cosmetic for wrinkles according to claim 1, further comprising component (D) silicone powder.