JP6509020B2 - Method of observing the surface shape of the object to be measured - Google Patents
Method of observing the surface shape of the object to be measured Download PDFInfo
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Description
本発明は、凸部を表面に有する樹脂層を備えた被測定物の表面に、当接部材を当接させたときの被測定物の表面形状を観察する方法に関する。 The present invention relates to a method of observing the surface shape of an object to be measured when a contact member is brought into contact with the surface of an object to be measured provided with a resin layer having convex portions on the surface.
表面に微細な凸部を形成することによって、放電性能の安定化を図った帯電部材が知られている。ここで、帯電部材が電子写真感光体などの被帯電体との当接部においては、帯電部材の凸部が変形し、その変形の程度が、被帯電体の帯電状態に影響を与えることが分かっている。しかしながら、これまで、当接部における帯電部材の変形の程度を正確に知ることはできなかった。したがって、帯電部材の帯電性能のより一層の向上のための表面形状の最適化を図るうえで、当接状態における帯電部材の表面の三次元形状を正確に知ることが有効である。 There is known a charging member in which the discharge performance is stabilized by forming fine projections on the surface. Here, in the contact portion of the charging member with the object to be charged such as an electrophotographic photosensitive member, the convex portion of the charging member is deformed, and the degree of the deformation affects the charged state of the member to be charged. I know. However, so far, it has not been possible to accurately know the degree of deformation of the charging member at the contact portion. Therefore, in order to optimize the surface shape for the further improvement of the charging performance of the charging member, it is effective to accurately know the three-dimensional shape of the surface of the charging member in the contact state.
これまでに、二次元で当接状態を観察する方法は幾つか提案されており、特許文献1は、一般的に知られている観察対象物と当接部材の当接部における接触点の観察方法である。観察対象物とプリズムを当接させ、当接部に対して全反射する角度でプリズム側より光を入射する。前記当接部では、光の吸収により輝度が低下し、非当接部では、当接部材の裏面から全反射することとなる。
これにより、当接部のコントラストが向上し、接触面積を観察すことが可能となる。また、特許文献2は、特許文献1に記載の方法では困難とされる液中において、観察対象物と当接部材の当接部を観察する方法、及び装置を開示している。特許文献2に開示の方法及び装置では、当接部を観察するために同軸照明を採用し、当接部材の一方の面に反射防止フィルムを張り付け、当接部材と液体の界面における反射光を低減することで、当接部のコントラストを向上させている。
Heretofore, several methods for observing the contact state in two dimensions have been proposed, and Patent Document 1 observes the contact point at the contact portion between the generally observed object and the contact member. It is a method. The observation object and the prism are brought into contact with each other, and light is made incident from the prism side at an angle of total reflection with respect to the contact portion. At the contact portion, the luminance is reduced due to the absorption of light, and at the non-contact portion, the light is totally reflected from the back surface of the contact member.
Thereby, the contrast of the contact portion is improved, and the contact area can be observed. Further, Patent Document 2 discloses a method and apparatus for observing the contact portion between the observation object and the contact member in the liquid which is considered to be difficult by the method described in Patent Document 1. In the method and apparatus disclosed in Patent Document 2, coaxial illumination is employed to observe the contact portion, an antireflective film is attached to one surface of the contact member, and reflected light at the interface between the contact member and the liquid is detected. By reducing it, the contrast of the contact portion is improved.
特許文献1及び特許文献2は、当接状態として、当接面積、当接点サイズを評価する平面的な方法であるが、特許文献1及び特許文献2ともに、観察対象物と当接部材を当接させた時の、観察対象物の表面における非当接部分を同時に観察することはできない。これは、当接部材の非当接部からの反射光量が大きいことによる。そのため、当接状態の三次元形状を観察することは困難とされてきた。 Although Patent Document 1 and Patent Document 2 are planar methods for evaluating the contact area and the contact point size as the contact state, both Patent Document 1 and Patent Document 2 apply the observation object and the contact member. When brought into contact, it is not possible to simultaneously observe non-contacting portions on the surface of the observation object. This is because the amount of reflected light from the non-contacting portion of the contact member is large. Therefore, it has been considered difficult to observe the three-dimensional shape in the contact state.
本発明の目的は、凸部を表面に有する樹脂層を備えた被測定物の表面に当接部材を当接させたときの被測定物の表面形状を観察する方法を提供することにある。 An object of the present invention is to provide a method of observing the surface shape of an object to be measured when the contact member is brought into contact with the surface of the object to be measured provided with a resin layer having convex portions on the surface.
本発明によれば、表面に凸部を有する樹脂層を表面層として具備する被測定物の表面に当接部材を当接させたときの該被測定物の表面形状を観察する方法であって、下記(1)〜(3)の工程を含むことを特徴とする被測定物の表面形状の観察方法が提供される。
(1):下記条件(i)〜(iii)を満たす当接部材を用意する工程:
(i)日本工業規格(JIS) R 3106 1998に基づく可視光域の全域の透過率が90%以上;
(ii)少なくとも一方の表面における、日本工業規格(JIS) R 3106 1998に基づく可視光反射率が、該被測定物の表面における日本工業規格(JIS) R 3106 1998に基づく可視光反射率に対して80%以下;
(iii)該表面における、可視光の波長域内の波長λ1において示される最も高い反射率をR1%とし、可視光の波長域内の波長λ2において示される最も低い反射率をR2%としたとき、R1とR2との差が、0.5%以上;
(2)該当接部材の該表面側と、該被測定物の表面とを当接させる工程、
(3)該当接部材の該表面とは反対側の表面から該波長λ1及び該波長λ2を含む光を入射させ、該被測定物からの該光の反射光を分光検出する工程。
According to the present invention, there is provided a method of observing the surface shape of an object to be measured when the contact member is brought into contact with the surface of the object to be measured provided with a resin layer having convex portions on the surface as the surface layer. A method of observing the surface shape of an object to be measured is provided, which comprises the following steps (1) to (3).
(1): A step of preparing a contact member satisfying the following conditions (i) to (iii):
(I) 90% or more of the transmittance of the entire visible light range based on Japanese Industrial Standard (JIS) R 3106 1998;
(Ii) The visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on at least one surface is the visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on the surface of the object to be measured Less than 80%;
(Iii) When the highest reflectance shown at wavelength λ1 in the visible light wavelength range is R1% and the lowest reflectance shown at wavelength λ2 in the visible light wavelength range is R2% on the surface, R1 And the difference between R2 and 0.5% or more;
(2) bringing the surface side of the contact member into contact with the surface of the object to be measured;
(3) A step of causing light containing the wavelength λ1 and the wavelength λ2 to be incident from the surface opposite to the surface of the contact member, and spectrally detecting the reflected light of the light from the object to be measured.
本発明によれば、凸部を表面に有する樹脂層を表面層として備えた被測定物の表面に当接部材を当接させたときの被測定物の表面形状を観察することが可能となる。 According to the present invention, it is possible to observe the surface shape of the object to be measured when the contact member is brought into contact with the surface of the object to be measured provided with the resin layer having the convex portion on the surface as the surface layer. .
図1は、本発明である当接状態における被測定物の表面の三次元形状を観察する方法を表す模式図である。以下では、被測定物として、金属シャフト(芯金3)に樹脂層としてのゴム弾性層2を有した弾性ローラ1を例に説明するが、研磨処理や、粗し粒子添加などの公知の手法により凸部を表面に有する樹脂層を表面層として備えた被測定物であれば、その限りではない。図1に示す例では、当接部材4は透明板5と反射防止膜6とからなり、反射防止膜6は弾性ローラ1に当接させられる側の面に設けられている。 FIG. 1 is a schematic view showing a method of observing the three-dimensional shape of the surface of an object to be measured in the contact state according to the present invention. In the following, the elastic roller 1 having the rubber elastic layer 2 as the resin layer on the metal shaft (core metal 3) is described as an example of the object to be measured. However, known methods such as polishing and roughening particle addition are described. As long as it is a to-be-measured object provided with the resin layer which has a convex part on the surface by this as a surface layer, it is not the limitation. In the example shown in FIG. 1, the contact member 4 is composed of the transparent plate 5 and the anti-reflection film 6, and the anti-reflection film 6 is provided on the surface on which the elastic roller 1 is in contact.
<当接状態観察方法>
弾性ローラ1に対して、当接状態における被測定物の表面の三次元形状を観察する方法について説明する。
本観察方法は、
(1)弾性ローラ1に当接させる当接部材4を用意する工程と、
(2)当接部材4の表面と弾性ローラ1の表面とを当接させる工程と、
(3)当接部材4の弾性ローラ1とは反対側の表面から、波長λ1及び波長λ2を含む光を入射させ、弾性ローラ1からの光の反射光を分光検出する工程と、を有する。
<Abutment state observation method>
A method of observing the three-dimensional shape of the surface of the object in the contact state with respect to the elastic roller 1 will be described.
This observation method is
(1) preparing a contact member 4 to be brought into contact with the elastic roller 1;
(2) bringing the surface of the contact member 4 into contact with the surface of the elastic roller 1;
(3) Allowing light containing wavelength λ1 and wavelength λ2 to be incident from the surface of the contact member 4 on the opposite side to the elastic roller 1, and spectrally detecting the reflected light of the light from the elastic roller 1.
図5に示すように、「当接部材4と弾性ローラ1の非当接部からの反射光」は「反射防止膜6とゴム弾性層2との非当接部52を透過し、反射防止膜6の表面とゴム弾性層2の表面との間の空間を通過した後に、ゴム弾性層2の表面で反射した反射光」を多く含む。
一方、「当接部材4と弾性ローラ1の当接部からの反射光」は、「反射防止膜6とゴム弾性層2との非当接部52を透過し、反射防止膜6の表面とゴム弾性層2の表面との間の空間を通過した後に、ゴム弾性層2の表面で反射した反射光」をほとんど含まない。
As shown in FIG. 5, “the reflected light from the non-contacting portion of the contact member 4 and the elastic roller 1” is transmitted through the non-contacting portion 52 of the anti-reflection film 6 and the rubber elastic layer 2 to prevent reflection. After passing through the space between the surface of the film 6 and the surface of the rubber elastic layer 2, the light reflected by the surface of the rubber elastic layer 2 is included in a large amount.
On the other hand, “the reflected light from the contact portion between the contact member 4 and the elastic roller 1” is transmitted through the non-contact portion 52 between the antireflective film 6 and the rubber elastic layer 2. After passing through the space between the surface of the rubber elastic layer 2, it hardly contains the light reflected by the surface of the rubber elastic layer 2.
<当接部材を用意する工程>
先ず、弾性ローラ1と当接させる当接部材4を用意する工程について説明する。
当接部材4は、条件(i)〜(iii)を満たす。
(i)日本工業規格(JIS) R 3106 1998に基づく可視光域の全域の透過率が90%以上;
(ii)少なくとも一方の表面における、日本工業規格(JIS) R 3106 1998に基づく可視光反射率が、該被測定物の表面における日本工業規格(JIS) R 3106 1998に基づく可視光反射率に対して80%以下;
(iii)該表面における、可視光の波長域内の波長λ1において示される最も高い反射率をR1%とし、可視光の波長域内の波長λ2において示される最も低い反射率をR2%としたとき、R1とR2との差が、0.5%以上:
<Step of preparing contact member>
First, the process of preparing the contact member 4 to be in contact with the elastic roller 1 will be described.
The abutting member 4 satisfies the conditions (i) to (iii).
(I) 90% or more of the transmittance of the entire visible light range based on Japanese Industrial Standard (JIS) R 3106 1998;
(Ii) The visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on at least one surface is the visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on the surface of the object to be measured Less than 80%;
(Iii) When the highest reflectance shown at wavelength λ1 in the visible light wavelength range is R1% and the lowest reflectance shown at wavelength λ2 in the visible light wavelength range is R2% on the surface, R1 The difference between R2 and R2 is 0.5% or more:
例えば、当接部材4は、透明板5と、透明板5の被測定物の側の表面に反射防止膜6とを備えている。
透明板5は、日本工業規格(JIS) R 3106 1998に基づく可視光域の全域(波長λ1及び波長λ2の光を含む。)の透過率が90%以上の透明板である。
For example, the contact member 4 includes the transparent plate 5 and the anti-reflection film 6 on the surface of the transparent plate 5 on the side of the object to be measured.
The transparent plate 5 is a transparent plate having a transmittance of 90% or more over the entire visible region (including light of wavelength λ1 and wavelength λ2) based on Japanese Industrial Standard (JIS) R 3106 1998.
反射防止膜6は、日本工業規格(JIS) R 3106 1998に基づく、当接部材における弾性ローラ(被測定物)側の反射率が、可視光域の全域において、弾性ローラ1の表面における可視光域の反射率の中で最も低い反射率の80%以下である。
つまり、弾性ローラ1の表面の反射率であって、可視光域において最も低い反射率を100とすると、反射防止膜6の弾性ローラ1側の反射率であって、可視光域において最も高い反射率は80以下である。
The reflection preventing film 6 is based on Japanese Industrial Standard (JIS) R 3106 1998, and the reflectance on the elastic roller (object to be measured) side of the contact member is visible light on the surface of the elastic roller 1 over the entire visible light range. It is 80% or less of the lowest reflectance among the area reflectances.
That is, assuming that the reflectance of the surface of the elastic roller 1 is 100%, the reflectance of the antireflective film 6 on the elastic roller 1 side is the highest reflectance in the visible light region. The rate is less than 80.
当接部材における被測定物側の反射率は、可視光の波長域内の波長λ1において最も高くなり、このときの反射率を反射率R1とし、
当接部材における被測定物側の反射率は、可視光の波長域内の波長λ2において最も低くなり、このときの反射率を反射率R2とすると、
反射率R1と反射率R2との差は、0.5%以上である。
The reflectance of the contact member on the side of the object to be measured is the highest at the wavelength λ1 in the wavelength range of visible light, and the reflectance at this time is referred to as the reflectance R1.
The reflectance of the contact member on the side of the object to be measured is the lowest at the wavelength λ2 within the wavelength range of visible light, and the reflectance at this time is the reflectance R2,
The difference between the reflectance R1 and the reflectance R2 is 0.5% or more.
透明板5の材質としては、可視光の波長域内(波長450nm以上700nm以下)において透過率が90%以上のガラス、樹脂、などがあるが、使用する光の波長λ1及び波長λ2を含む光の透過率が高ければ特に限定されるものではない。
反射防止膜6に関しては、フィルムタイプ、単層膜タイプ、多層膜タイプ、などがあるが、いずれのものでも良い。
Examples of the material of the transparent plate 5 include glass, resin, and the like having a transmittance of 90% or more in the visible light wavelength range (wavelength 450 nm to 700 nm), and light of wavelength λ1 and wavelength λ2 of light used. It is not particularly limited as long as the transmittance is high.
With regard to the antireflective film 6, there are a film type, a single layer film type, a multilayer film type and the like, and any may be used.
反射防止膜6が当接部材の両面に施されていると、観察感度がより良好となるため好ましい。観察感度がより良好となる理由は、以下のとおりである。
当接部材の光を照射する側(光が入射する側。被測定物に当接させる面とは反対側。)の面に施されている反射防止膜6は、当接部材の光を照射する側の面における反射光の影響を抑制することができる。
当接部材の光を反射する側の面に施されている反射防止膜6は、
当接部材と弾性ローラとの当接部からの反射光の強度と、
当接部材と弾性ローラとの非当接部からの反射光の強度と
の差を大きくすることができる。
It is preferable that the antireflective film 6 be provided on both sides of the contact member, because the observation sensitivity is further improved. The reason why the observation sensitivity is better is as follows.
The anti-reflection film 6 applied to the surface of the contact member on the side to be irradiated with the light (the side on which the light is incident; the side opposite to the surface to be in contact with the object to be measured) It is possible to suppress the influence of the reflected light on the surface on the side of
The antireflection film 6 applied to the surface of the contact member on the side of reflecting light is
Intensity of light reflected from the contact portion between the contact member and the elastic roller;
The difference between the intensity of the reflected light from the non-contacting portion between the contact member and the elastic roller can be increased.
<当接部材と被測定物とを当接させる工程>
次に、当接部材の表面側と、被測定物の表面とを当接させる工程について説明する。
当接部材4の被測定物(弾性ローラ1)側に反射防止膜6が設けられている場合は、反射防止膜6の表面と弾性ローラ1の表面とが接するように当接させる。
例えば、当接部材4の方向へ弾性ローラ1の両端の金属シャフト(芯金3)を押圧する。ここで当接荷重は、特に限定されるものではなく、実使用条件に近い条件であることが好ましい。例えば、実施例1に挙げる電子写真用の弾性ローラでは片側1000g以下であれば良い。
<Step of bringing the contact member into contact with the object to be measured>
Next, the process of bringing the surface side of the contact member into contact with the surface of the object to be measured will be described.
When the anti-reflection film 6 is provided on the side of the contact member 4 to be measured (elastic roller 1), the surface of the anti-reflection film 6 and the surface of the elastic roller 1 are brought into contact with each other.
For example, the metal shafts (core metal 3) at both ends of the elastic roller 1 are pressed in the direction of the contact member 4. Here, the contact load is not particularly limited, and is preferably a condition close to actual use conditions. For example, in the case of the elastic roller for electrophotography mentioned in the first embodiment, it may be 1000 g or less per side.
<当接部からの反射光と、非当接部からの反射光とを区別して検出する工程>
次に、当接部材4を通して弾性ローラ1に対して、波長λ1及び波長λ2を含む光を照射し、光を入射させる。そして、当接部材4と弾性ローラ1の当接部からの反射光と、当接部材4と弾性ローラ1との非当接部を透過した後、弾性ローラ1の表面で反射した光とを区別して検出(分光検出)する工程について説明する。
<Step of Distinguishing and Detecting the Reflected Light from the Contact Part and the Reflected Light from the Non-Contact Part>
Next, the elastic roller 1 is irradiated with light including the wavelength λ1 and the wavelength λ2 through the contact member 4 to make the light incident. Then, the reflected light from the contact portion between the contact member 4 and the elastic roller 1 and the light reflected by the surface of the elastic roller 1 after passing through the non-contact portion between the contact member 4 and the elastic roller 1 The process of distinguishing and detecting (spectral detection) will be described.
まず、弾性ローラ1に対して、当接部材4を通して波長λ1及び波長λ2を含む光を照射する。当接部材4を透過した光は、当接部材4と弾性ローラの界面において、当接部材における弾性ローラ側の反射率R1、反射率R2に対応した波長λ1、波長λ2の強度で、反射光と透過光に分かれる。当接部材を透過した光は、弾性ローラ1の表面で反射した後、再度、反射防止膜により反射率R1、反射率R2に対応した波長λ1、波長λ2の強度で、反射光と透過光に分けられる。 First, the elastic roller 1 is irradiated with light including the wavelength λ1 and the wavelength λ2 through the contact member 4. The light transmitted through the contact member 4 is reflected light at the interface between the contact member 4 and the elastic roller, at the intensity of the wavelength λ1 and the wavelength λ2 corresponding to the reflectance R1 and reflectance R2 of the contact member on the elastic roller side. And transmitted light. The light transmitted through the contact member is reflected by the surface of the elastic roller 1, and then again reflected light and transmitted light with an intensity of wavelength λ1 and wavelength λ2 corresponding to the reflectance R1 and reflectance R2 by the anti-reflection film. It is divided.
本発明では、弾性ローラ1の表面の反射率に対して、当接部材における弾性ローラ側の反射率が80%以下となる反射防止膜を使用することで、弾性ローラ1の表面を観察可能とした。
また、反射率R1と反射率R2に0.5%以上の差を持たせることで、弾性ローラ1の表面と当接部材の表面との当接部又は非当接部からの反射光に含まれる波長λ1と波長λ2の成分に強度差を生じさせる。
According to the present invention, the surface of the elastic roller 1 can be observed by using an anti-reflection film in which the reflectance on the elastic roller side of the contact member is 80% or less of the reflectance of the surface of the elastic roller 1 did.
Further, by making the reflectance R1 and the reflectance R2 have a difference of 0.5% or more, the reflected light from the contact portion or non-contact portion between the surface of the elastic roller 1 and the surface of the contact member is included. An intensity difference is generated between the components of the wavelength λ1 and the wavelength λ2.
具体的には、
最も高い反射率R1に対応する波長λ1は相対的に長く、最も低い反射率R2に対応する波長λ2は相対的に短い。すなわち、波長λ1は、波長λ2に対して長波長である。
非当接部への入射光は、弾性ローラ1の表面の凹部内で乱反射を繰り返し、減衰していく。相対的に、波長λ1の光は波長が長いため減衰が進み、波長λ2の光は波長が短いため減衰は進まない。
そして、当接部材から非当接部へ入射した入射光が、反射光として当接部材へ再び入射する際、波長λ1の光の反射率R1は高く、波長λ2の光の反射率R2は低いため、波長λ1の光は再び入射し難く、波長λ2の光は再び入射し易い。
その結果、非当接部からの反射光には、波長の短いλ2が、波長の長いλ1よりも多く含まれ、分光検出することによって当接部と非当接部とを観察することができる。
In particular,
The wavelength λ1 corresponding to the highest reflectance R1 is relatively long, and the wavelength λ2 corresponding to the lowest reflectance R2 is relatively short. That is, the wavelength λ1 is longer than the wavelength λ2.
The light incident on the non-contact portion repeats irregular reflection within the concave portion on the surface of the elastic roller 1 and attenuates. Relatively, the light of the wavelength λ1 is attenuated because the wavelength is long, and the light of the wavelength λ2 is not attenuated because the wavelength is short.
And when incident light which entered into a non-contacting part from a contact member enters into a contact member again as reflected light, reflectance R1 of light of wavelength λ1 is high, reflectance R2 of light of wavelength λ2 is low Therefore, it is difficult for the light of wavelength λ1 to be incident again, and the light of wavelength λ2 is likely to be incident again.
As a result, the reflected light from the non-contacting part contains λ2 having a short wavelength more than the λ1 having a long wavelength, and it is possible to observe the contacting part and the non-contacting part by spectral detection. .
この波長λ1と波長λ2の強度差を、反射光を分光検出する波長分離観察手段7により観察することで、弾性ローラ1と当接部材4との当接部と非当接部との区別を可能とした。ここで波長分離観察手段7として、カラー撮像可能なエリアカメラであることが好ましい。例えば、反射光を赤色、緑色、青色の3色に分解する3CCDカメラが挙げられる。 By observing the intensity difference between the wavelength λ1 and the wavelength λ2 by the wavelength separation and observation means 7 that detects the reflected light, it is possible to distinguish the contact portion and the non-contact portion between the elastic roller 1 and the contact member 4 It was possible. Here, it is preferable that the wavelength separation observation means 7 be an area camera capable of color imaging. For example, there is a 3CCD camera that separates the reflected light into three colors of red, green and blue.
本観察方法により、弾性ローラ1と当接部材4との当接部と非当接部を波長(カラー画像上の色)により区別して観察することが可能となる。したがって、弾性ローラ1のゴム弾性層2に添加された粗し粒子の大きさによる当接の違いや、ゴム弾性層2の表面粗さの違いなどを明確に区別して観察することが可能となる。つまり、添加する材料によって、被帯電体と弾性ローラ1との当接部における当接状態(接触面積や、ニップ内三次元形状)を適正化することができる。 According to this observation method, it is possible to distinguish and observe the contact portion and the non-contact portion between the elastic roller 1 and the contact member 4 according to the wavelength (color on the color image). Therefore, it becomes possible to clearly distinguish and observe the difference in the contact depending on the size of the roughening particles added to the rubber elastic layer 2 of the elastic roller 1, the difference in the surface roughness of the rubber elastic layer 2, etc. . That is, the contact state (contact area or three-dimensional shape in the nip) at the contact portion between the member to be charged and the elastic roller 1 can be optimized by the material to be added.
また、当接部に到達した光の一部は弾性ローラ1の表面で吸収される。このため、弾性ローラ1の表面層である樹脂層が、カーボンブラックなどの波長の短い光の吸収に優れている材料を含む場合、当接部の反射光には波長の長い光が多く含まれる。この結果、分光検出した場合に、当接部と非当接部とのコントラストがより高くなる。 Further, part of the light reaching the contact portion is absorbed by the surface of the elastic roller 1. For this reason, when the resin layer which is the surface layer of the elastic roller 1 contains a material excellent in the absorption of light having a short wavelength such as carbon black, the reflected light of the contact portion contains a lot of light having a long wavelength. . As a result, when the spectral detection is performed, the contrast between the contact portion and the non-contact portion becomes higher.
さらに、前記波長分離観察手段7として、実施例1に挙げる白色共焦点顕微鏡を用いた場合には、図2および図3を用いて説明するように、当接部における三次元形状を直接測定することが可能となる。従来の接触面積だけでなく、ニップ内粗さ、空間体積、ニップ内高さなどのパラメータが測定可能となり、実測値から被帯電体と弾性ローラ1との当接部における当接状態(接触面積や、ニップ内三次元形状)を最適化することができる。 Furthermore, when the white confocal microscope listed in Example 1 is used as the wavelength separation observation means 7, as described with reference to FIGS. 2 and 3, the three-dimensional shape of the contact portion is directly measured. It becomes possible. In addition to the conventional contact area, parameters such as in-nip roughness, space volume, and in-nip height can be measured, and the contact state at the contact portion between the member to be charged and elastic roller 1 (contact area) And the three-dimensional shape in the nip) can be optimized.
以上、本観察方法によれば、反射防止膜の効果により当接部材からの反射光量を低減し、このとき生じる当接部と非当接部におけるコントラストの低下に対して、反射防止膜の特性と観察波長の選択により色の違いとしてコントラストをつけることができる。例えば、波長λ1が赤い帯域とした場合、図3(b)に示すように、当接部が赤く、非当接部が青緑のように観察することができる。その結果、例えば、表面に粗し粒子に由来する凸部を有する、帯電ローラの如き、電子写真用の帯電部材では、電子写真感光体の如き被帯電体と該帯電部材との当接部における、該帯電部材の変形の程度を正確に捉えることが可能となる。そのため、帯電部材の帯電性能のより一層の向上のための表面形状の最適化を図ることができる。 As described above, according to the present observation method, the amount of light reflected from the contact member is reduced by the effect of the anti-reflection film, and the characteristics of the anti-reflection film against the reduction in contrast between the contact portion and the non-contact portion generated at this time The contrast can be added as a difference in color by selecting the observation wavelength and the observation wavelength. For example, when the wavelength λ1 is in the red band, as shown in FIG. 3B, it can be observed that the contact portion is red and the non-contact portion is bluish green. As a result, for example, in a charging member for electrophotography such as a charging roller having a convex portion derived from roughening particles on the surface, in the contact portion between the charging member such as an electrophotographic photosensitive member and the charging member The degree of deformation of the charging member can be accurately detected. Therefore, it is possible to optimize the surface shape for further improvement of the charging performance of the charging member.
〔実施例1〕
(弾性ローラの作製)
下記手順にて、樹脂層を備えた被測定物としての弾性ローラを作製した。
NBR(アクリロニトリルブタジエンゴム)と球状シリカ粒子を含有する未加硫ゴム組成物を用意した。そして、未加硫ゴム組成物を、クロスヘッドを用いた押出成形装置を用いて、直径5mm、長さ250mmの円柱形ステンレス製の芯金3を中心として同軸状に円筒形に成形しつつ、芯金3と同時に押し出した。このようにして、芯金3の外周に未加硫ゴム組成物がコーティングされた直径8.8mmの未加硫ゴムローラを作製した。
成形した未加硫ゴムローラの未加硫ゴム組成物の層の幅方向の両端部を切断し、未加硫ゴム組成物の層の軸方向の長さを226mmとした。
Example 1
(Production of elastic roller)
The elastic roller as a to-be-measured object provided with the resin layer was produced in the following procedure.
An unvulcanized rubber composition containing NBR (acrylonitrile butadiene rubber) and spherical silica particles was prepared. Then, the unvulcanized rubber composition is coaxially formed into a cylindrical shape centering on a cylindrical stainless steel core metal 5 having a diameter of 5 mm and a length of 250 mm using an extrusion molding apparatus using a crosshead, It pushed out simultaneously with the core metal 3. Thus, an unvulcanized rubber roller having a diameter of 8.8 mm in which the unvulcanized rubber composition was coated on the outer periphery of the core metal 3 was produced.
Both ends in the width direction of the unvulcanized rubber composition layer of the molded unvulcanized rubber roller were cut, and the axial length of the unvulcanized rubber composition layer was 226 mm.
その後、電気炉にて加熱して未加硫ゴム組成物の層を加硫して加硫ゴム層とした。続いて、加硫ゴム層の表面をプランジカットの研削方式の研磨機で研磨し、端部直径8.35mm、中央部直径8.50mmのクラウン形状の球状粒子の一部が露出した加硫ゴム層を有する加硫ゴムローラを得た。
得られた研摩後の加硫ゴムローラの表面に電子線を照射して硬化処理を行い、凸部を表面に有する弾性ローラ1を得た。
Thereafter, the layer was heated in an electric furnace to vulcanize the unvulcanized rubber composition layer to form a vulcanized rubber layer. Subsequently, the surface of the vulcanized rubber layer is polished with a plunge grinding type polishing machine, and a vulcanized rubber in which a part of crown-shaped spherical particles having an end diameter of 8.35 mm and a central diameter of 8.50 mm is exposed A vulcanized rubber roller having a layer was obtained.
The surface of the resulting vulcanized rubber roller after polishing was cured by irradiating it with an electron beam to obtain an elastic roller 1 having convex portions on the surface.
(表面粗さの測定)
弾性ローラの表面の十点平均粗さRzを測定した。測定は JIS B0601:1982に基づき、表面粗さ測定器(商品名:サーフコーダーSE3400、(株)小坂研究所製)を用いて行った。測定には、先端半径2μmのダイヤモンド製接触針を用いた。測定スピードは0.5mm/秒、カットオフ周波数λcは0.8mm、基準長さは0.8mm、評価長さは8.0mmとした。測定は、軸方向3点×周方向2点の計6点について各々粗さ曲線を測定してRzの値を算出し、それらの6点のRzの平均値を求めてRzの値とした。その結果、Rzは15μmであった。
(Measurement of surface roughness)
The ten-point average roughness Rz of the surface of the elastic roller was measured. The measurement was performed based on JIS B0601: 1982 using a surface roughness measuring device (trade name: Surfcoder SE3400, manufactured by Kosaka Laboratory Ltd.). A diamond contact needle with a tip radius of 2 μm was used for the measurement. The measurement speed was 0.5 mm / sec, the cutoff frequency λc was 0.8 mm, the reference length was 0.8 mm, and the evaluation length was 8.0 mm. The measurement was carried out by measuring the roughness curve for each of six points at three points in the axial direction × two points in the circumferential direction to calculate the value of Rz, and the average value of Rz at these six points was determined to obtain the value of Rz. As a result, Rz was 15 μm.
(被測定物の表面に部材を当接させたときの被測定物の三次元形状の測定)
図1に示す当接状態の形状を観察する方法において、下記のガラス板の両面に下記の反射防止膜を備える当接部材を使用した。
ガラス板(BK7、シグマ光機(株)):波長450nm以上700nmの範囲で90%以上の透過率を有する。
反射防止膜(WBMAコート、シグマ光機(株)):
波長450以上700nm以下の範囲において、当接部材における弾性ローラ側の反射率は、
最も高い反射率が波長(λ1)700nmで0.7%、
最も低い反射率が波長(λ2)450nmで0.1%、
最も高い反射率と最も低い反射率との差が0.5%以上である。
当接部からの反射光と、非当接部からの反射光とを区別して検出する工程には、白色共焦点顕微鏡(OPTELICS HYBRID、レーザーテック(株))を用い、当接状態を観察した。
観察結果を図2および図3に示す。図3の画像の倍率は、(a)および(b)ともに、20倍である。
(Measurement of the three-dimensional shape of the object when the member is in contact with the surface of the object)
In the method of observing the shape of the contact state shown in FIG. 1, the contact member provided with the following anti-reflective film on both surfaces of the following glass plate was used.
Glass plate (BK7, manufactured by Sigma Kouki Co., Ltd.): A transmittance of 90% or more in a wavelength range of 450 nm to 700 nm.
Antireflection film (WBMA coat, Sigma light machine Co., Ltd.):
The reflectance on the elastic roller side of the contact member in the wavelength range of 450 to 700 nm is
The highest reflectance is 0.7% at a wavelength (λ1) of 700 nm,
The lowest reflectance is 0.1% at a wavelength (λ2) of 450 nm,
The difference between the highest reflectance and the lowest reflectance is 0.5% or more.
In the step of distinguishing and detecting the reflected light from the contact part and the reflected light from the non-contact part, the contact state was observed using a white confocal microscope (OPTELICS HYBRID, Lasertec Co., Ltd.).
The observation results are shown in FIG. 2 and FIG. The magnification of the image in FIG. 3 is 20 times for both (a) and (b).
ここで、弾性ローラの表面の可視光域における最も低い反射率が約1%であることから、波長700nmで当接部材における弾性ローラ側の反射率が約0.7%となる反射防止膜を使用することで、下記式(1)の値を80%以下としている。
(当接部材の被測定物側の反射率であって、可視光域で最も高い反射率)/(被測定物の表面の反射率であって、可視光域で最も低い反射率)×100[%] … 式(1)
Here, since the lowest reflectance in the visible light region of the surface of the elastic roller is about 1%, the reflection preventing film having a reflectance of about 0.7% on the elastic roller side in the abutting member at a wavelength of 700 nm is used. By using it, the value of following formula (1) is made into 80% or less.
(The reflectance of the contact member on the side of the object to be measured, which is the highest reflectance in the visible light region) / (the reflectance of the surface of the object to be measured, the lowest reflectance in the visible light region) × 100 [%] ... Formula (1)
図3(a)は、弾性ローラと当接部材を当接させる前の、弾性ローラの表面観察画像である。
図2(a)は、弾性ローラと当接部材を当接させる前の、図3(a)の画像の中央に示す線31の位置における、弾性ローラの断面の輪郭を示す形状プロファイルである。
図3(b)は、弾性ローラと当接部材を当接させた後(当接中)の、弾性ローラの表面観察画像である。
図2(b)は、弾性ローラと当接部材を当接させた後(当接中)の、図3(b)の画像の中央に示す線32の位置における、弾性ローラの断面の輪郭を示す形状プロファイルである。
FIG. 3A is a surface observation image of the elastic roller before the elastic roller and the contact member abut.
FIG. 2A is a shape profile showing an outline of a cross section of the elastic roller at the position of a line 31 shown at the center of the image of FIG. 3A before the elastic roller and the contact member abut.
FIG. 3B is a surface observation image of the elastic roller after the elastic roller and the contact member abut (in contact).
FIG. 2 (b) shows the cross-sectional profile of the elastic roller at the position of the line 32 shown in the center of the image of FIG. 3 (b) after the elastic roller and the contact member abut (during contact) It is a shape profile shown.
観察画像上において、弾性ローラと当接部材の当接部と非当接部とを波長(カラー画像上の色に対応)により区別できている。また、当接前後を比較すると、当接により弾性ローラの表面の凸部が変形していること、凹部の多くが当接しない(変形しない)ことが確認できる。 On the observation image, the contact portion and the non-contact portion of the elastic roller and the contact member can be distinguished by the wavelength (corresponding to the color on the color image). In addition, comparing before and after the abutment, it can be confirmed that the convex portion on the surface of the elastic roller is deformed by the abutment and that many of the concave portions do not abut (do not deform).
非当接部は、グレースケール画像では濃い灰色に見える箇所、カラー画像では青緑又は緑色に見える箇所である。
当接部は、グレースケール画像では薄い灰色に見える箇所、カラー画像では赤色に見える箇所である。
また、凸部は、皺、鱗又は不規則な線のように見える箇所、及び黒色の箇所で取り囲まれた白色の点である。
凹部は、凸部を除く全ての箇所である。
表1に、当接部、非当接部の観察の可否、及び当接部における弾性ローラの三次元形状の測定の可否の結果を示す。
The non-contacting part is a part that appears dark gray in a grayscale image and a part that appears bluish green or green in a color image.
The abutments are locations that appear light gray in gray scale images and locations that appear red in color images.
Moreover, a convex part is a white point surrounded by a black spot where it looks like wrinkles, wrinkles or irregular lines.
Recesses are all locations except for the protrusion.
Table 1 shows the results of whether or not the contact portion and the non-contact portion are observed, and whether or not the three-dimensional shape of the elastic roller in the contact portion can be measured.
〔実施例2〕
当接機構の当接部材の両面に下記の反射防止膜を用いた以外は、実施例1と同様にして評価した。
反射防止膜:
波長450以上700nm以下の範囲において、当接部材における弾性ローラ側の反射率は、
最も高い反射率が波長(λ1)520nmで0.7%、
最も低い反射率が波長(λ2)450nmで0.1%、
最も高い反射率と最も低い反射率との差が0.5%以上である。
Example 2
Evaluation was carried out in the same manner as in Example 1 except that the following antireflection films were used on both surfaces of the contact member of the contact mechanism.
Antireflective film:
The reflectance on the elastic roller side of the contact member in the wavelength range of 450 to 700 nm is
The highest reflectance is 0.7% at a wavelength (λ1) of 520 nm,
The lowest reflectance is 0.1% at a wavelength (λ2) of 450 nm,
The difference between the highest reflectance and the lowest reflectance is 0.5% or more.
ここで、弾性ローラの表面の可視光域における最も低い反射率が約1%であることから、波長520nmで当接部材における弾性ローラ側の反射率が約0.7%となる反射防止膜を使用することで、前記式(1)の値を80%以下としている。
弾性ローラと当接部材との当接部と非当接部とを波長(カラー画像上の色)により区別し、かつ荷重負荷前後における形状変化を測定可能であることを確認した。
表1に、当接部、非当接部の観察の可否、及び当接部における弾性ローラの三次元形状の測定の可否の結果を示す。
Here, since the lowest reflectance in the visible light region of the surface of the elastic roller is about 1%, the reflection preventing film having a wavelength of 520 nm and the reflectance on the elastic roller side of the abutting member being about 0.7% is used. By using, the value of said Formula (1) is made into 80% or less.
It was confirmed that the contact portion and the non-contact portion between the elastic roller and the contact member were distinguished by the wavelength (color on the color image), and that the shape change before and after the load could be measured.
Table 1 shows the results of whether or not the contact portion and the non-contact portion are observed, and whether or not the three-dimensional shape of the elastic roller in the contact portion can be measured.
〔実施例3〕
当接機構の当接部材の両面に下記の反射防止膜を用いた以外は、実施例1と同様にして評価した。
反射防止膜:
波長450以上700nm以下の範囲において、当接部材における弾性ローラ側の反射率の中で、
最も高い反射率が波長(λ1)470nmで0.7%、
最も低い反射率が波長(λ2)700nmで0.1%、
最も高い反射率と最も低い反射率との差が0.5%以上である。
[Example 3]
Evaluation was carried out in the same manner as in Example 1 except that the following antireflection films were used on both surfaces of the contact member of the contact mechanism.
Antireflective film:
Among the reflectances on the elastic roller side of the contact member in the wavelength range of 450 to 700 nm,
The highest reflectance is 0.7% at a wavelength (λ1) of 470 nm,
The lowest reflectance is 0.1% at a wavelength (λ2) of 700 nm,
The difference between the highest reflectance and the lowest reflectance is 0.5% or more.
ここで、弾性ローラの表面の可視光域における最も低い反射率が約1%であることから、波長470nmで当接部材における弾性ローラ側の反射率が約0.7%となる反射防止膜を使用することで、前記式(1)の値を80%以下としている。
弾性ローラと当接部材との当接部と非当接部とを波長(カラー画像上の色)により区別し、かつ荷重負荷前後における形状変化を測定可能であることを確認した。
表1に、当接部、非当接部の観察の可否、及び当接部における弾性ローラの三次元形状の測定の可否の結果を示す。
Here, since the lowest reflectance in the visible light region of the surface of the elastic roller is about 1%, an antireflection film having a reflectance of about 0.7% on the elastic roller side in the abutting member at a wavelength of 470 nm is used. By using, the value of said Formula (1) is made into 80% or less.
It was confirmed that the contact portion and the non-contact portion between the elastic roller and the contact member were distinguished by the wavelength (color on the color image), and that the shape change before and after the load could be measured.
Table 1 shows the results of whether or not the contact portion and the non-contact portion are observed, and whether or not the three-dimensional shape of the elastic roller in the contact portion can be measured.
〔比較例1〕
両面のいずれにも反射防止膜を施していない、波長400nm以上700nmの範囲で90%以上の透過率を有するガラス板を用いた以外は、実施例1と同様にして評価した。
その結果、図4に示すように当接部からの反射光量が、非当接部からの反射光量に比べて多いいために、当接部を観察することはできるが、弾性ローラの非当接部の観察、及び形状測定ができないことを確認した。
表1に、当接部、非当接部の観察の可否、及び当接部における弾性ローラの三次元形状の測定の可否の結果を示す。
Comparative Example 1
Evaluation was performed in the same manner as in Example 1 except that a glass plate having a transmittance of 90% or more in the wavelength range of 400 nm to 700 nm without using the anti-reflection film on either of the two surfaces was used.
As a result, as shown in FIG. 4, since the amount of light reflected from the contact portion is larger than the amount of light reflected from the non-contact portion, the contact portion can be observed. It was confirmed that observation of the contact area and shape measurement could not be performed.
Table 1 shows the results of whether or not the contact portion and the non-contact portion are observed, and whether or not the three-dimensional shape of the elastic roller in the contact portion can be measured.
1‥‥弾性ローラ
2‥‥ゴム弾性層
3‥‥芯金
4‥‥当接部材
5‥‥透明板
6‥‥反射防止膜
7‥‥波長分離観察手段
1. Elastic roller 2. Rubber elastic layer 3. Core metal 4. Abutment member 5. Transparent plate 6. Anti-reflection film 7. Means of wavelength separation observation
Claims (9)
下記(1)〜(3)の工程を含むことを特徴とする被測定物の表面形状の観察方法:
(1):下記条件(i)〜(iii)を満たす当接部材を用意する工程:
(i)日本工業規格(JIS) R 3106 1998に基づく可視光域の全域の透過率が90%以上;
(ii)少なくとも一方の表面における、日本工業規格(JIS) R 3106 1998に基づく可視光反射率が、該被測定物の表面における日本工業規格(JIS) R 3106 1998に基づく可視光反射率に対して80%以下;
(iii)該表面における、可視光の波長域内の波長λ1において示される最も高い反射率をR1%とし、可視光の波長域内の波長λ2において示される最も低い反射率をR2%としたとき、R1とR2との差が、0.5%以上;
(2)該当接部材の該表面側と、該被測定物の表面とを当接させる工程、
(3)該当接部材の該表面とは反対側の表面から該波長λ1及び該波長λ2を含む光を入射させ、該被測定物からの該光の反射光を分光検出する工程。 A method for observing the surface shape of an object to be measured when a contact member is brought into contact with the surface of an object to be measured having a resin layer having convex portions on the surface as a surface layer,
A method of observing the surface shape of an object to be measured, which comprises the following steps (1) to (3):
(1): A step of preparing a contact member satisfying the following conditions (i) to (iii):
(I) 90% or more of the transmittance of the entire visible light range based on Japanese Industrial Standard (JIS) R 3106 1998;
(Ii) The visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on at least one surface is the visible light reflectance based on Japanese Industrial Standard (JIS) R 3106 1998 on the surface of the object to be measured Less than 80%;
(Iii) When the highest reflectance shown at wavelength λ1 in the visible light wavelength range is R1% and the lowest reflectance shown at wavelength λ2 in the visible light wavelength range is R2% on the surface, R1 And the difference between R2 and 0.5% or more;
(2) bringing the surface side of the contact member into contact with the surface of the object to be measured;
(3) A step of causing light containing the wavelength λ1 and the wavelength λ2 to be incident from the surface opposite to the surface of the contact member, and spectrally detecting the reflected light of the light from the object to be measured.
前記波長λ2の光を用い、共焦点顕微鏡で該被測定物の三次元形状を測定する工程を含む請求項1に記載の該被測定物の表面形状の観察方法。 In the step (3),
The method for observing the surface shape of the object to be measured according to claim 1, comprising the step of measuring the three-dimensional shape of the object to be measured with a confocal microscope using the light of the wavelength λ2.
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