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JP6524032B2 - How to handle flushing drainage - Google Patents
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JP6524032B2 - How to handle flushing drainage - Google Patents

How to handle flushing drainage Download PDF

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JP6524032B2
JP6524032B2 JP2016137779A JP2016137779A JP6524032B2 JP 6524032 B2 JP6524032 B2 JP 6524032B2 JP 2016137779 A JP2016137779 A JP 2016137779A JP 2016137779 A JP2016137779 A JP 2016137779A JP 6524032 B2 JP6524032 B2 JP 6524032B2
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flushing drainage
zinc
turbidity
drainage
amount
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JP2016179473A (en
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佐藤 峰彦
峰彦 佐藤
孝輔 大迫
孝輔 大迫
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Takasago Thermal Engineering Co Ltd
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Description

本発明は、フラッシング排水の処理方法に関するものである。   The present invention relates to a method of treating flushing drainage.

フラッシングとは、空調設備、給水・給湯設備、プラント、その他配管システム等の試運転前に、配管の接続、切断、溶接作業などによって生じた鉄粉、切削油、酸化亜鉛、接合材料等を、配管系から除去することを目的として、配管内に流体を流して清浄することであり、その方法としては、
(1)配管に水を張りそのまま抜く方法
(2)水を張った後に循環させてから抜く方法
(3)少量の水を吸引等により流速を高くして配管中に流通させてから抜く方法
がある。
With flushing, iron powder, cutting oil, zinc oxide, joining material, etc. generated by connecting, cutting and welding work of piping before trial operation of air conditioning equipment, water supply / hot water supply equipment, plant, other piping system etc. In order to remove from the system, it is to flow and clean the fluid in the piping, and the method is
(1) Method to put water in the pipe as it is and drain it as it is (2) Method to put in water after circulation and then drain it out (3) There is a method to make small amount of water flow in pipe by increasing flow velocity by suction etc. is there.

これらのいずれの方法で配管をフラッシングしても、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水中には高濃度の亜鉛、製造時及びネジ加工時に使用する油、微量の重金属が含まれている。このような亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水を場外へ排出する場合、排水規制値以上になる主成分は亜鉛であり、油分(ノルマルヘキサン抽出物質として検出される)、他の重金属もまれに規制値以上になる。   No matter which of these methods is used to flush the piping, flushing drainage from the piping system of the facility with the galvanized steel pipe contains high concentrations of zinc, oil used during manufacturing and screw processing, and a trace amount of heavy metal It is done. When flushing drainage from the piping system of a facility to which such galvanized steel pipes are piped, zinc is the main component that exceeds the drainage regulation value, and oil (detected as a normal hexane extract), and others Heavy metals are also rarely above regulatory limits.

排水規制値以上の亜鉛、油分、重金属が含まれているフラッシング排水は、そのままでは排出できないため、一般的には希釈処理をしたのち敷地外に排出しており、現状では、亜鉛除去処理を行った上で排出している例は極めてまれである。そのため、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水中の亜鉛を除去する直接の従来既存の技術は見当たらない(非特許文献1)。   Flushing drainage containing zinc, oil, and heavy metals above the regulation level can not be discharged as it is, so it is generally diluted and then discharged outside the site, and under the present circumstances, zinc removal treatment is performed. There are very few cases where they are discharged. Therefore, there is no direct existing technology for removing zinc in the flushing drainage from the piping system of the facility piping the galvanized steel pipe (Non-patent Document 1).

社団法人 空気調和・衛生工学会 施工保全委員会 「施工保全情報と空調配管システム信頼性向上に関する調査研究」平成21年3月Association of Air Conditioning and Sanitation Engineering Construction Maintenance Committee "Study and research on improvement of construction maintenance information and air conditioning piping system reliability" March 2009

前記したように、従来はフラッシング排水を希釈処理した後に敷地外に排出しているので、問題があった。   As described above, conventionally, there is a problem because flushing drainage is discharged after being subjected to dilution treatment.

本発明は、かかる点に鑑みてなされたものであり、配管系からのフラッシング排水を処理するに際して、前記フラッシング排水を処理するシステムと配管系との間でフラッシング排水を循環させるようにして前記問題の解決を図ることを目的としている。   The present invention has been made in view of such a point, and when the flushing drainage from the piping system is treated, the flushing drainage is circulated between the system for treating the flushing drainage and the piping system. The purpose is to solve the problem.

前記目的を達成するため、本発明は、空調設備における空調用の水の配管系を、水でフラッシングする際の前記配管系からのフラッシング排水を処理する方法であって、前記フラッシング排水をろ過するフィルタを有するシステムと前記配管系とを接続し、前記配管系と前記システムとの間でフラッシング排水を循環させ、前記システムでフラッシング排水を処理した後に再度前記配管系に戻し、その後前記システムを前記配管系から外し、前記配管系内に戻した処理水をそのまま前記配管系で空調用の水として使用することを特徴としている。 In order to achieve the above object, the present invention is a method of treating flushing drainage from the piping system when flushing piping system for water for air conditioning in an air conditioning facility with water, and filtering the flushing drainage. A system having a filter is connected to the piping system, circulating flushing drainage between the piping system and the system, treating the flushing drainage with the system, and then returning it back to the piping system, and then the system It is characterized in that the treated water removed from the piping system and returned into the piping system is used as it is as water for air conditioning in the piping system .

かかる場合、フラッシング排水を前記配管系と前記システムとを通して数回循環させた後に、前記システムを前記配管系から外すようにしてもよい。   In such a case, the flushing drainage may be circulated several times through the piping system and the system, and then the system may be removed from the piping system.

前記処理水の濁度の測定結果が所定値以上になった場合に、前記処理水を前記システム外に排出しないようにしてもよい。When the measurement result of the turbidity of the treated water becomes equal to or more than a predetermined value, the treated water may not be discharged out of the system.

本発明によれば、フラッシング排水を処理するシステムを記配管系に接続して、前記システムでフラッシング排水を処理した後に再度配管系に戻すようにしたので、前記フラッシング排水を処理するシステムと配管系との間でフラッシング排水を循環させることができる。   According to the present invention, the system for treating the flushing drainage is connected to the piping system, and after the flushing drainage is treated by the system, it is returned to the piping system again. Therefore, the system and the piping system for treating the flushing drainage Between which the flushing drainage can be circulated.

フラッシング排水の濁度と亜鉛濃度との相関を示すグラフである。It is a graph which shows correlation with the turbidity of flushing drainage, and a zinc concentration. システムの系統の概略を模式的に示した説明図である。BRIEF DESCRIPTION OF THE DRAWINGS It is explanatory drawing which showed the outline of the system | strain of a system typically. 処理水量と亜鉛濃度との関係を示すグラフである。It is a graph which shows the relationship between a treated water amount and zinc concentration. 流入水濁度に基づく、凝結剤量および返送汚泥量の制御例を示すグラフである。It is a graph which shows the example of control of the amount of coagulating agents and the amount of return sludge based on inflow water turbidity. 処理水量と亜鉛濃度との関係を沈殿物の返送の有無について示したグラフである。It is the graph which showed the relationship between the amount of treated water and the zinc concentration about the presence or absence of return of a precipitate. 流入水濁度に基づく、凝結剤量および返送汚泥量の他の制御例を示すグラフである。It is a graph which shows the other control example of the amount of coagulating agents and the amount of return sludge based on inflow water turbidity. 他のシステムの系統の概略を模式的に示した説明図である。It is explanatory drawing which showed typically the outline of the system | strain of other systems. 懸濁物質濃度と亜鉛濃度との関係を、フラッシング排水(原水)と処理水について各々示したグラフである。It is the graph which showed the relationship between the suspended matter density | concentration and zinc concentration about the flushing drainage (raw water) and treated water, respectively.

既述した排水規制値以上の亜鉛、油分、重金属が含まれているフラッシング排水に関し、一般的な亜鉛含有排水の処理方法自体は、従来から下記のような技術が提案されている。すなわち、亜鉛含有排水に対して、まずアルカリ化処理した後、無機凝結剤を添加し、その後高分子凝集剤を添加して沈殿槽で汚泥を分離し、場合によってはろ過をした後、処理水のpHを排水処理基準まで中和して、排水する方法である(特開昭58−19498号公報、特開平11−188208号公報、特開平11−290865号公報)。   With regard to flushing drainage containing zinc, oil, and heavy metals above the above-mentioned drainage regulation value, the following techniques have conventionally been proposed as a general method for treating zinc-containing drainage. That is, after subjecting the zinc-containing wastewater to an alkali treatment first, an inorganic coagulant is added, and then a polymer flocculant is added to separate the sludge in the sedimentation tank, and in some cases, after filtration, the treated water The method is to neutralize the pH of the solution to the wastewater treatment standard and drain it (JP-A-58-19498, JP-A-11-188208, JP-A-11-290865).

これら従来技術は、いずれも凝結剤を定量供給するものであり、流入濃度に変化がある場合は、一番濃厚な排水が流入する事を想定し、それに相応した凝結剤、凝集剤量を添加する必要がある。   All of these prior art technologies supply coagulant quantitatively, and if there is a change in inflow concentration, it is assumed that the most concentrated drainage flows in, and the amount of coagulant and flocculant corresponding to it is added There is a need to.

すなわち、凝結剤、凝集剤を適正量供給するためには、亜鉛濃度を直接測定し、その濃度に比例して適正量の凝結剤を添加すればよいが、現状では、現場にて連続的に排水中の亜鉛濃度を簡易に測定する方法がないのが実情である。JISにおける亜鉛の分析方法には、フレーム原子吸光法、電気加熱原子吸光法、ICP発光分光分析法、ICP質量分析法があるが、これらはいずれも分析装置が高価な上、連続分析には適していない。また簡易な分析方法として、比色法があるが、やはり連続して分析ができない。   That is, in order to supply an appropriate amount of coagulant and coagulant, it is sufficient to directly measure the zinc concentration and add an appropriate amount of the coagulant in proportion to the concentration. The fact is that there is no simple way to measure the concentration of zinc in waste water. Methods of analyzing zinc in JIS include flame atomic absorption, electric heating atomic absorption, ICP emission spectrometry, and ICP mass spectrometry, all of which are suitable for continuous analysis since the analyzer is expensive. Not. Moreover, although there is a colorimetric method as a simple analysis method, analysis can not be performed continuously either.

そのため従来既存の技術の下では、凝結剤を定量供給するしかなく、その結果、仮に途中で亜鉛濃度が希薄な排水が流入しても、過剰な凝結剤を投入することになり、本来必要な凝結剤量よりも多くの凝結剤を投入するため、発生汚泥量も多くなっていた。亜鉛の凝集物は沈降性が悪いため、凝結剤及び凝集剤の添加量は安全を見て多めに入れる事が多く、さらに発生汚泥量が多くなっていた。   Therefore, under the existing technology, there is only a way to quantitatively supply the coagulant, and as a result, even if drainage water with a low zinc concentration flows in during the process, an excess of the coagulant will be introduced, which is essentially necessary. The amount of generated sludge was also large because the amount of the coagulant was higher than that of the coagulant. Since zinc aggregates have poor settling properties, the addition amount of the coagulant and the coagulant is often added in view of safety, and the amount of generated sludge is further increased.

この点に関し、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水中の亜鉛の濃度を容易に推定でき、それに基づいて凝結剤及び凝集剤の添加量を適切に制御することがよい。   In this regard, it is possible to easily estimate the concentration of zinc in the flushing drainage from the piping system of the installation piping the galvanized steel pipe, and based on that, it is preferable to appropriately control the addition amount of the coagulant and the coagulant.

そこで本発明者は種々の施設から排出されるフラッシング排水を様々な項目について分析し、亜鉛濃度と相関のある項目を見つけ、それにより亜鉛濃度を容易にかつ連続して推定できることを新たに知見した。すなわち、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水中の亜鉛濃度と濁度との間に相関があることを見出した。   Therefore, the present inventor analyzed flushing drainage discharged from various facilities for various items, found items correlated with the zinc concentration, and found that it was possible to estimate the zinc concentration easily and continuously. . That is, it has been found that there is a correlation between the concentration of zinc in the flushing drainage from the piping system of the facility piping the galvanized steel pipe and the turbidity.

図1は、その結果を示している。亜鉛濃度の測定には、バリアン社製ICP発光分光分析装置 720−ES型を用い、濁度の測定には、HACH製濁度色度計 2100ANを用いて各々分析)した。この図1の結果によれば、フラッシング排水の原水、処理後の処理水にかかわらず、濁度と亜鉛メッキ鋼管からなる配管系のフラッシング排水中の亜鉛濃度とは、比例関係にあり、約0.99の相関関係があることが判明した。   FIG. 1 shows the result. The zinc concentration was measured using a Varian ICP emission spectrometer 720-ES, and the turbidity was measured using a HACH turbidity color meter 2100AN. According to the results shown in FIG. 1, regardless of the raw water of the flushing drainage and the treated water after the treatment, the turbidity and the zinc concentration in the flushing drainage of the piping system made of galvanized steel pipe are in a proportional relationship, It was found that there was a correlation of .99.

しかもフラッシング方法が異なる場合においても、亜鉛濃度と濁度には相関があったことも確認された。したがって、あらかじめ濁度と亜鉛濃度を測定してその相関を知っておくことで、処理原水あるいは処理後の処理水の濁度から亜鉛濃度を速やかにかつ連続して求めることができる。   Moreover, it was also confirmed that there was a correlation between the zinc concentration and the turbidity even when the flushing method was different. Therefore, by measuring the turbidity and the zinc concentration in advance and knowing the correlation thereof, the zinc concentration can be determined promptly and continuously from the turbidity of the treated raw water or the treated water after the treatment.

また亜鉛メッキ鋼管からなる配管系からのフラッシング排水の成分割合は、どの設備でも常にほぼ均一であることから、亜鉛濃度と濁度の相関があると考えられ、これは他の亜鉛含有排水と異なり、亜鉛メッキ鋼管の配管系のフラッシング排水特有のものと考えられる。たとえばフラッシング排水と異なり、メッキ工場、亜鉛精錬工場等から排出される亜鉛含有排水は、製造工場によりその組成が様々であるとともに、排出口では様々な工程で発生した排水が混合するため、亜鉛濃度と濁度との相関が日々異なると共に、亜鉛以外の物質が濁度に影響を与える事も多く、亜鉛濃度と濁度に相関が見られない事が多い。   Moreover, since the component ratio of the flushing drainage from the piping system which consists of galvanized steel pipes is almost always uniform at any equipment, it is considered that there is a correlation between the zinc concentration and the turbidity, which is different from other zinc-containing drainages. It is considered to be unique to flushing drainage of piping system of galvanized steel pipe. For example, unlike flushing wastewater, zinc-containing wastewater discharged from a plating plant, a zinc smelting factory, etc. varies in composition depending on the manufacturing factory, and since the wastewater generated in various processes is mixed at the discharge port, the zinc concentration The correlation between the turbidity and the turbidity differs from day to day, and substances other than zinc often affect the turbidity, and often there is no correlation between the zinc concentration and the turbidity.

以下の実施の形態についての説明は、かかる知見にも鑑みてなされた、システム、フラッシング排水を処理する方法について行っている。   The following description of the embodiment is directed to a system, a method for treating flushing drainage, which has been made in view of such findings.

図2は、フラッシング排水の処理方法を実施するための処理システムの系統の概略を示しており、溶融亜鉛メッキ鋼管等、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水は、流入管1から、流入ポンプ2によってシステム内に流入する。   FIG. 2 shows an outline of a system of a treatment system for carrying out the method of treating flushing drainage, and flushing drainage from a piping system of a facility having a galvanized steel pipe, such as a galvanized steel pipe, is an inflow pipe 1 From the inlet pump 2 into the system.

そして最初にpH調整槽11において、フラッシング排水に対してpH調整がなされる。pH調整は、pH調整剤供給源(図示せず)から、ポンプ12によって、pH調整槽11内にpH調整剤が供給され、pH調整槽11内に設けられた攪拌装置13によって、攪拌される。pH調整剤の投入量は、pH調整槽11内に設けられたpH計測装置14によるpH値に基づいて制御され、たとえばpHが8.5〜11.0となるように、ポンプ12の動作が制御される。pH調整剤(アルカリ)としては水酸化ナトリウム(NaOH)、消石灰(Ca(OH))、ソーダ灰(NaCO)等の公知のアルカリ薬剤が使用できる。 Then, pH adjustment is performed on the flushing drainage in the pH adjustment tank 11 first. The pH adjustment is carried out by supplying a pH adjusting agent into the pH adjusting tank 11 from the pH adjusting agent supply source (not shown) by the pump 12 and stirring by the stirring device 13 provided in the pH adjusting tank 11 . The input amount of the pH adjusting agent is controlled based on the pH value by the pH measuring device 14 provided in the pH adjusting tank 11. For example, the operation of the pump 12 is performed so that the pH is 8.5 to 11.0. It is controlled. As a pH adjuster (alkali), known alkali chemicals such as sodium hydroxide (NaOH), slaked lime (Ca (OH) 2 ), soda ash (Na 2 CO 3 ) and the like can be used.

pH調整槽11内でpH調整された後の排水は、凝結槽21において凝結処理に付される。凝結槽21には、無機凝結剤供給源(図示せず)から、ポンプ22によって無機凝結剤が供給され、凝結槽21内に設けられた攪拌装置23によって、攪拌される。凝結剤としては、鉄系凝結剤が好ましく、硫酸第一鉄、硫酸第二鉄、塩化第二鉄、塩化コッパラス、ポリ塩化第二鉄、ポリ硫酸鉄、鉄−シリカ無機高分子凝集剤のいずれか、または組み合わせて使用すればよい。また鉄系凝結剤に対して凝結性能は劣るがPAC(ポリ塩化アルミニウム)、硫酸バンド(硫酸アルミニウム)等のアルミ系凝結剤でも良い。   The wastewater after pH adjustment in the pH adjustment tank 11 is subjected to a condensation treatment in a condensation tank 21. An inorganic coagulant is supplied to the coagulating tank 21 from an inorganic coagulant supply source (not shown) by a pump 22 and is agitated by an agitator 23 provided in the condensing tank 21. As a coagulant, an iron-based coagulant is preferable, and any of ferrous sulfate, ferric sulfate, ferric chloride, copperous chloride, polyferric chloride, polyiron sulfate, iron-silica inorganic polymer coagulant Or in combination. In addition, although the coagulation performance is inferior to that of an iron-based coagulant, an aluminum-based coagulant such as PAC (polyaluminum chloride) or a sulfuric acid band (aluminum sulfate) may be used.

凝結槽21において凝結処理された排水は、凝集槽31において凝集処理に付される。凝集槽31には、高分子凝集剤供給源(図示せず)から、ポンプ32によって高分子凝集剤が供給され、凝集槽31内に設けられた攪拌装置33によって、攪拌される。高分子凝集剤としてはアニオン系凝集剤が好ましい。また、凝結剤と併せて、活性珪酸、粉末活性炭、ベントナイト、アルギン酸ナトリウム等の公知の凝集助剤を加えても良いが、本発明の方法に従えば、凝結剤・凝集剤のみで排水基準値以下まで処理する事が可能であるため、その必要性は低い。   The waste water subjected to the condensation treatment in the coagulation tank 21 is subjected to the aggregation treatment in the aggregation tank 31. The polymer flocculant is supplied to the flocculation tank 31 from a polymer flocculant supply source (not shown) by a pump 32 and is stirred by a stirring device 33 provided in the flocculation tank 31. An anionic flocculant is preferred as the polymer flocculant. In addition to the coagulant, known flocculation aids such as activated silica, powdered activated carbon, bentonite, sodium alginate and the like may be added, but according to the method of the present invention, only the coagulant and coagulant are drainage standard values. The necessity is low because it is possible to process up to the following.

そして凝集槽31において凝集処理された後の排水は、沈殿槽41へ移送される。沈殿槽41において沈殿した沈殿物(汚泥)は、ポンプ42によって戻し管43を通じて、pH調整槽11の前段側に戻すことが可能になっている。戻し管43には、排出管44が分岐接続されている。戻し管43、排出管44には、各々バルブ43a、44aが設けられている。また沈殿槽41の上澄み水は、配管45を通じて、システム下流側のpH調整槽51へと送られる。配管45には、流出バルブ45aが設けられている。   Then, the waste water subjected to the aggregation treatment in the aggregation tank 31 is transferred to the sedimentation tank 41. The precipitate (sludge) deposited in the settling tank 41 can be returned to the front side of the pH adjusting tank 11 through the return pipe 43 by the pump 42. A discharge pipe 44 is branch-connected to the return pipe 43. The return pipe 43 and the discharge pipe 44 are provided with valves 43a and 44a, respectively. Further, the supernatant water of the settling tank 41 is sent to the pH adjusting tank 51 on the downstream side of the system through the pipe 45. The piping 45 is provided with an outflow valve 45 a.

pH調整槽51では、pH調整剤供給源(図示せず)から、ポンプ52によって、pH調整槽51内にpH調整剤(酸)が供給され、pH調整槽51内に設けられた攪拌装置53によって、攪拌される。pH調整剤の投入量は、pH調整槽51内に設けられたpH計測装置54によるpH値に基づいて制御され、たとえばpHが5.8〜8.6となるように、ポンプ52の動作が制御される。pH調整剤(酸)としては一般的に用いられている硫酸HSO、塩酸HCl、炭酸CO等の公知の酸が使用できる。 In the pH adjustment tank 51, a pH adjuster (acid) is supplied into the pH adjustment tank 51 by a pump 52 from a pH adjuster supply source (not shown), and a stirring device 53 provided in the pH adjustment tank 51. Is stirred. The input amount of the pH adjusting agent is controlled based on the pH value by the pH measuring device 54 provided in the pH adjusting tank 51. For example, the operation of the pump 52 is performed such that the pH is 5.8 to 8.6. It is controlled. As a pH adjuster (acid), commonly known acids such as sulfuric acid H 2 SO 4 , hydrochloric acid HCl, carbon dioxide CO 2 and the like can be used.

配管45には、沈殿槽41の排水(上澄み水)、すなわち凝集処理後の処理水を、流入管1に戻すための返送管46が分岐接続されており、返送ポンプ47によって、pH調整槽11の前段側に、配管45からの処理水を戻すことが可能になっている。返送管46には、返送バルブ46aが設けられている。これによって処理水を再処理することができる。   A return pipe 46 for returning the drainage (supernatant water) of the sedimentation tank 41, ie, the treated water after aggregation treatment, to the inflow pipe 1 is branched and connected to the pipe 45, and the pH adjustment tank 11 is operated by the return pump 47. It is possible to return the treated water from the piping 45 to the front side of. The return pipe 46 is provided with a return valve 46 a. Treated water can be reprocessed by this.

そしてこの図2のシステム例では、流入管1における返送管46との接続点下流側であって、戻し管43との接続点上流側に、濁度計Aが設けられ、また沈殿槽41の排水(上澄み水)の出口側、すなわち配管45の沈殿槽41側に、濁度計Bが設けられている。   In the system example of FIG. 2, a turbidimeter A is provided on the downstream side of the connection point of the inflow pipe 1 with the return pipe 46 and on the upstream side of the connection point with the return pipe 43. A turbidity meter B is provided on the outlet side of the drainage (supernatant water), that is, on the settling tank 41 side of the pipe 45.

各濁度計A、Bの測定結果は、制御装置Zへと出力され、制御装置Zでは、予め求めてあった濁度−亜鉛濃度の相関に基づき、流入ポンプ2、ポンプ22、32、42、バルブ43a、44a、流出バルブ45a、返送バルブ46a、返送ポンプ47等の制御を行なう。   The measurement results of the respective turbidity meters A and B are output to the control device Z, and the control device Z determines the inflow pump 2, the pumps 22, 32, 42 based on the correlation of the turbidity-zinc concentration previously obtained. , Valves 43a and 44a, outflow valve 45a, return valve 46a, return pump 47 and the like.

かかるシステムによれば、流入管1から流入するフラッシング排水の濁度を濁度計Aで連続計測し、凝結槽21に投入する凝結剤の量、および凝集槽31に投入する凝集剤の量を即座に調整することができる。たとえば、フラッシング排水の濁度が高い、すなわち亜鉛濃度が高い場合は凝結剤量を増やし、低い場合は凝結剤量を減らす制御を行うことができ、それによって凝結剤を無駄に投入することを防止することができる。   According to this system, the turbidity of the flushing drainage flowing in from the inflow pipe 1 is continuously measured by the turbidity meter A, and the amount of the coagulant introduced into the coagulation tank 21 and the amount of the coagulant introduced into the aggregation tank 31 It can be adjusted immediately. For example, if the turbidity of the flushing drainage is high, that is, if the zinc concentration is high, the amount of coagulant can be increased, and if it is low, the amount of coagulant can be controlled, thereby preventing wasteful introduction of the coagulant can do.

また、沈殿槽41からの処理水(上澄み水)の濁度を濁度計Bで連続計測し、濁度が一定値以上になった場合、流入ポンプ2の停止、流出バルブ45aの閉止、返送バルブ46aの開放、返送ポンプ47の動作ONという一連の動作を行うことも可能である。その結果、排出水亜鉛濃度は0.5mg/L以下となり、一定に処理することができた。その結果を図3の表に示す。   In addition, the turbidity of the treated water (supernatant water) from the sedimentation tank 41 is continuously measured by the turbidity meter B, and when the turbidity reaches a certain value or more, the inflow pump 2 is stopped, the outflow valve 45a is closed, and returned It is also possible to perform a series of operations such as opening the valve 46a and turning on the operation of the return pump 47. As a result, the zinc concentration of discharged water was 0.5 mg / L or less, and could be treated constantly. The results are shown in the table of FIG.

ところで、凝集沈殿法では、水に溶解していない浮遊物質が凝集物の核となるため、浮遊物質が多いほど凝集沈殿しやすくなる。この点に関し、図2のシステムにおいては、濁度計Aで測定したフラッシング排水の濁度に基づいてポンプ42を制御して、沈殿槽41から戻し管43を通じての沈殿物(汚泥)の返送量を制御することができる。この沈殿物(汚泥)の返送量制御によって返送した沈殿物が凝集のための核となって、安定した凝集沈殿が可能となる。また、特にフラッシング排水の亜鉛濃度が薄い場合には、凝集物が少なく凝集沈殿がしにくくなってしまう。濁度計Aによって測定される流入フラッシング排水の濁度が所定値より低い、すなわち亜鉛濃度が所定値より薄い場合には、ポンプ42を作動させて、沈殿槽41から戻し管43を通じてpH調整槽11の前段側に戻す沈殿物(汚泥)の量を、亜鉛濃度が薄いほど増加させるように制御することができる。   By the way, in the flocculation method, since the suspended matter which is not dissolved in water becomes the nucleus of the aggregate, the larger the suspended matter is, the more easily flocculated and precipitated. In this regard, in the system of FIG. 2, the pump 42 is controlled based on the turbidity of the flushing drainage measured by the turbidity meter A, and the amount of sediment (sludge) returned from the settling tank 41 through the return pipe 43 Can be controlled. Due to the control of the amount of sediment (sludge) returned, the returned sediment becomes a nucleus for aggregation, enabling stable aggregation and sedimentation. In addition, particularly when the zinc concentration of the flushing drainage is low, the amount of aggregates is small and aggregation and precipitation become difficult. When the turbidity of the inflow flushing drainage measured by the turbidity meter A is lower than a predetermined value, that is, the zinc concentration is thinner than the predetermined value, the pump 42 is operated and the pH adjustment tank through the return pipe 43 from the sedimentation tank 41 The amount of sediment (sludge) returned to the front side of 11 can be controlled to increase as the concentration of zinc decreases.

図4は、上記した凝結剤の投入量制御及び沈殿物(汚泥)の返送量制御について、流入水濁度と凝結剤の投入量及び沈殿物(汚泥)返送量との関係を模式的に示したものである。図4に示すように、流入フラッシング排水の濁度が所定値以下の場合は、濁度が低いほど返送汚泥量を増やし、濁度が高いほど返送汚泥量を減らす制御を行った。濁度が所定値以上の場合は、濁度が低いほど返送汚泥量を減らし、濁度が高いほど返送汚泥量を増やす制御を行った。また、返送汚泥量には、後述のように、上限を設けてある。所定値としては、たとえばおよそ10〜30NTU(亜鉛濃度で3〜10mg/L相当)を例示できる。   FIG. 4 schematically shows the relationship between the influent water turbidity, the input amount of the coagulant, and the return amount of the precipitate (sludge) with regard to the control of the input amount of the coagulant and the control of the return amount of the precipitate (sludge) described above. It is As shown in FIG. 4, when the turbidity of the inflow flushing drainage is below a predetermined value, the amount of returned sludge was increased as the turbidity was lower, and the amount of returned sludge was controlled as the turbidity was higher. When the turbidity was equal to or higher than a predetermined value, control was performed to reduce the amount of returned sludge as the turbidity was lower and to increase the amount of returned sludge as the turbidity was higher. In addition, as described later, an upper limit is provided for the amount of returned sludge. As a predetermined value, for example, about 10 to 30 NTU (corresponding to 3 to 10 mg / L in zinc concentration) can be exemplified.

このような沈殿物の返送量制御を実施することで、流入フラッシング排水の亜鉛濃度が薄く、その結果、添加凝結剤が少ない場合においても、排出水亜鉛濃度は0.5mg/L以下で一定に処理することができた。なお流入フラッシング排水の亜鉛濃度が薄いときにこの返送量制御を行わない場合、添加凝結剤が少なくなっているので、十分な亜鉛除去が行われなかった。その結果を図5の表に示す。   By carrying out such control of the amount of sediment returned, the zinc concentration in the inflow flushing drainage is thin, and as a result, even if the additive coagulant is small, the zinc concentration in the discharge water is constant at 0.5 mg / L or less. I was able to handle it. When the return amount control was not performed when the zinc concentration of the inflow flushing drainage was low, the amount of the added coagulant was small, and therefore sufficient zinc removal was not performed. The results are shown in the table of FIG.

このような例では、フラッシング排水の濁度を濁度計Aで測定する事で、必要とされる沈殿物(汚泥)返送量が求められるので、返送量を可変制御することができる。したがって処理の状態により、沈殿槽41の沈殿物を流入フラッシング排水と混合しなくても亜鉛を除去することが可能な場合には、沈殿槽41の沈殿物を、流入フラッシング排水へ混合するためのポンプ42を稼動させなくてもよく、その分ポンプ42の動力を節約できる。   In such an example, by measuring the turbidity of the flushing drainage with the turbidimeter A, the required amount of sediment (sludge) returned can be determined, so the amount of return can be variably controlled. Therefore, depending on the state of treatment, if it is possible to remove zinc without mixing the precipitate in the settling tank 41 with the inflow flushing drainage, to mix the sediment in the settling tank 41 into the inflow flushing drainage The pump 42 does not have to be operated, and the power of the pump 42 can be saved.

なお、返送量が多くなって、沈殿槽41への流入水量が多くなりすぎると、沈殿槽41の負荷が上昇し、沈殿物(汚泥)の沈降性が悪化して汚泥が流出するため、戻し管43を通じての返送量には上限を設けることがよい。   In addition, if the amount of return water increases and the amount of inflowing water to the settling tank 41 increases too much, the load on the settling tank 41 increases and the settling property of the precipitate (sludge) is deteriorated and the sludge flows out. An upper limit may be placed on the amount of return through tube 43.

またフラッシング排水の濁度が低い、すなわち亜鉛濃度が薄い場合は、凝集物の核となる浮遊物質が少ないので、前述した制御(亜鉛濃度が薄い場合には凝結剤量を減らす)の通りに凝結剤を減らすと凝集性が悪化するが、沈殿物(汚泥)の返送量を増やす事で凝集性が良好になる。このようにすると、凝結剤が少ないまま、凝集性を向上させる制御をすることで、汚泥発生量を減らす事もできる。   In addition, when the turbidity of the flushing drainage is low, that is, when the zinc concentration is low, since there are few suspended solids that form nuclei of aggregates, condensation is performed as described above (when the zinc concentration is low, the amount of coagulant is reduced). If the amount of the agent is reduced, the cohesion is deteriorated, but the cohesion becomes good by increasing the amount of returned sediment (sludge). In this way, the amount of sludge generated can be reduced by performing control to improve the cohesion while the amount of the coagulant is small.

なお、流入フラッシング排水の亜鉛濃度が薄い場合にも安定した凝集沈殿を行うための他の制御方法として、図6に示したように、流入フラッシング排水の濁度が所定値以下の場合に、沈殿物(汚泥)の返送量を増やさず凝結剤を一定量投入するようにしてもよい。なお図4、図6に示したのは、凝結剤量と返送汚泥量の制御例であったが、凝集剤量についても凝結剤量と同様である。   As another control method for performing stable aggregation and precipitation even when the zinc concentration in the inflow flushing drainage is low, as shown in FIG. A fixed amount of coagulant may be introduced without increasing the amount of material (sludge) returned. Although FIGS. 4 and 6 show control examples of the amount of coagulant and the amount of returned sludge, the amount of coagulant is also the same as the amount of coagulant.

次に他の例について説明する。図7は、他のフラッシング排水の処理方法を実施するための処理システムの系統の概略を示しており、この例は、基本的には図2に示したシステムに対して、pH調整槽51の後段側に、処理水の希釈系、及びフィルタ除去系を設けたものである。すなわち、図7のシステムでは、pH調整槽51からの処理水をそのまま系外に排出するのではなく、pH調整槽51に接続された排出管61に対して、希釈系配管62を接続し、この希釈系配管62に対して希釈水供給源(図示せず)から、ポンプ63によって希釈水、たとえば水を供給することが可能になっている。一方、フィルタ除去系については、排出管61に対してフィルタ除去系配管64を接続し、このフィルタ除去系配管64にフィルタ65を設け、ポンプ66によって排出管61からの処理水をフィルタ65に送水し、フィルタ65によって汚染物質を除去した後、系外に排出することが可能になっている。   Next, another example will be described. FIG. 7 shows an outline of a system of a treatment system for carrying out another method for treating flushing drainage, and this example is basically the same as the system shown in FIG. The downstream side is provided with a dilution system for treated water and a filter removal system. That is, in the system of FIG. 7, the dilution water pipe 62 is connected to the discharge pipe 61 connected to the pH adjustment tank 51 instead of discharging the treated water from the pH adjustment tank 51 as it is, A dilution water, for example, water can be supplied by a pump 63 from a dilution water supply source (not shown) to the dilution system piping 62. On the other hand, for the filter removal system, the filter removal system piping 64 is connected to the discharge pipe 61, the filter removal system piping 64 is provided with the filter 65, and the treated water from the discharge pipe 61 is supplied to the filter 65 by the pump 66 After removing the contaminants by the filter 65, it can be discharged out of the system.

このような希釈系、フィルタ除去系による処理水の処理は、制御装置Zによってなされる。すなわち、排出管61に設けた濁度計Cの測定結果に基づいて、そのまま系外への排出を可能にするバルブ61aの開閉、希釈系による処理を行なうためのバルブ62a、ポンプ63、フィルタ除去系による処理を行なうためのバルブ64a、ポンプ66の制御が行なわれる。   Such treatment of treated water by the dilution system and the filter removal system is performed by the controller Z. That is, based on the measurement result of the turbidimeter C provided in the discharge pipe 61, the valve 62a for discharging the system as it is, the valve 62a for processing by the dilution system, the pump 63, and the filter removal Control of the valve 64a and the pump 66 for performing processing by the system is performed.

そして図7のシステム例では、pH調整槽11、凝結槽21、凝集槽31、沈殿槽41、pH調整槽51をバイパスして、フラッシング排水を、直接pH調整槽51の下流側へと送水するバイパス管69が配管されている。バイパス管69のバルブ69aの開閉制御も濁度計Aの測定結果に基づいて、制御装置Zで行なわれる。   And in the system example of FIG. 7, the pH adjustment tank 11, the coagulation tank 21, the coagulation tank 31, the settling tank 41, and the pH adjustment tank 51 are bypassed, and flushing drainage is directly sent downstream of the pH adjustment tank 51. A bypass pipe 69 is provided. The open / close control of the valve 69 a of the bypass pipe 69 is also performed by the control device Z based on the measurement result of the turbidity meter A.

かかる構成を有するシステムによれば、たとえば濁度計Cによる測定結果(濁度に基づく亜鉛濃度)が、所定値以下であれば、バルブ61a開放、バルブ62a、64a閉止という制御により、pH調整槽51からの処理水は、排出管61からそのまま系外に排出される。   According to the system having such a configuration, for example, if the measurement result by the turbidity meter C (zinc concentration based on turbidity) is less than a predetermined value, the pH adjustment tank is controlled by opening the valve 61a and closing the valves 62a and 64a. The treated water from 51 is discharged from the discharge pipe 61 out of the system as it is.

そして濁度計Cによる測定結果が所定値を超えている場合、それが所定値を大きく超えないとき、たとえば所定の基準値(亜鉛濃度)が2mg/Lで測定値が2.5mg/Lだった場合には、さらに処理を実行するよりも希釈水によって希釈して排出した方がコスト的に有利な場合がある。この場合には、バルブ61a閉止、バルブ62a開放、64a閉止という制御により、pH調整槽51からの処理水は、希釈系配管62で希釈された後、系外に排出される。   And, when the measurement result by the turbidity meter C exceeds the predetermined value, when it does not greatly exceed the predetermined value, for example, the predetermined reference value (zinc concentration) is 2 mg / L and the measured value is 2.5 mg / L. In some cases, it may be more cost effective to dilute and discharge with dilution water than to carry out further processing. In this case, the treated water from the pH adjustment tank 51 is diluted by the dilution system piping 62 and discharged out of the system by the control of closing the valve 61a, opening the valve 62a, and closing 64a.

また同様に、濁度計Cによる測定結果が所定値を超えている場合、それが所定値を大きく超えないときには、バルブ61a閉止、バルブ62a閉止、64a開放という制御により、pH調整槽51からの処理水は、フィルタ除去系配管64のフィルタ65で汚染物が除去された後、系外に排出される。所定値としては、たとえば、あらかじめフィルタろ過試験を実施し、ろ過前の亜鉛濃度とろ過後の亜鉛濃度の相関を測定し、当該測定結果から求めることができる。例えば、基準値が2mg−Zn/Lの場合、フィルタ処理前の亜鉛濃度が5mg/Lでありフィルタ処理後の亜鉛濃度2mg/Lであるならば、所定値は5mg−Zn/Lとなる。実際には、安全をみて若干低めの値、たとえば4mg−Zn/L程度に設定される。   Similarly, when the measurement result by the turbidity meter C exceeds the predetermined value, if it does not greatly exceed the predetermined value, the valve 61a is closed, the valve 62a is closed, and the 64a is opened. Treated water is discharged out of the system after contaminants are removed by the filter 65 of the filter removal system piping 64. As the predetermined value, for example, a filter filtration test may be performed in advance, and the correlation between the zinc concentration before filtration and the zinc concentration after filtration may be measured and determined from the measurement result. For example, when the reference value is 2 mg-Zn / L, if the zinc concentration before filtering is 5 mg / L and the zinc concentration after filtering is 2 mg / L, the predetermined value is 5 mg-Zn / L. In practice, it is set to a slightly lower value for safety, for example, about 4 mg-Zn / L.

処理水をフィルタ65でろ過することで、微細な粒子が除去され、処理水亜鉛濃度を下げる事ができる。しかし、この微細な粒子はフィルタに目詰まりし易いため、処理水全量をろ過することは、フィルタの交換、保守等に要する費用がかさむ。よって処理水の亜鉛濃度が高い場合のみろ過することが、最も経済的である。今までは処理水亜鉛濃度を連続的に測定することができなかったが、本発明によれば、濁度を測定する事で処理水亜鉛濃度を容易に推定できるため、このような経済的な制御方法が可能となる。   By filtering the treated water with the filter 65, fine particles can be removed and the concentration of zinc in the treated water can be lowered. However, since the fine particles are easily clogged in the filter, filtering the total amount of treated water increases the cost required for replacement and maintenance of the filter. Therefore, it is most economical to filter only when the zinc concentration of the treated water is high. Until now, it was not possible to continuously measure the concentration of zinc in treated water, but according to the present invention, it is possible to easily estimate the concentration of zinc in treated water by measuring turbidity, such economic A control method becomes possible.

フラッシング排水を凝集法で処理した水中の粒子状物質の粒径は1〜10μm程度が一番多いため、フィルタ65のろ過材としては、ろ過径0.1〜10μm程度の公知のろ過材を用いる事ができる。ろ過材としてはカートリッジフィルタの使用が最も安価で簡便である。   The particle size of the particulate matter in water obtained by treating the flushing drainage by coagulation is the largest in the range of about 1 to 10 μm. Therefore, as the filtering material of the filter 65, a known filtering material having a filtration diameter of about 0.1 to 10 μm is used I can do things. The use of a cartridge filter as the filter medium is the most inexpensive and convenient.

さらにまた濁度計Aで測定したフラッシング排水の亜鉛濃度が所定の基準値を大きく超えていないときには、上記と同様にして、希釈系、フィルタ除去系で処理した後、系外に排出することができる。もちろん濁度計Aで測定したフラッシング排水の亜鉛濃度が所定の基準値以下であれば、そのまま排出管61を通じて系外に排出される。なお、希釈系、フィルタ除去系の何れか一方を有したシステムであってもよい。   Furthermore, when the zinc concentration of the flushing drainage measured by the turbidimeter A does not greatly exceed the predetermined reference value, after being treated with the dilution system and the filter removal system in the same manner as above, it may be discharged out of the system. it can. Of course, if the zinc concentration of the flushing drainage measured by the turbidity meter A is less than a predetermined reference value, it is discharged out of the system through the discharge pipe 61 as it is. The system may have one of a dilution system and a filter removal system.

このように本発明では、フラッシング排水や処理水の濁度に基づいて、排水中、処理水中の亜鉛濃度を即座に、かつ連続して推定することができるので、以上のようなシステムにおいて採用したように、濃度に応じた好適な処理を実施することが可能である。   As described above, according to the present invention, since the zinc concentration in waste water and treated water can be estimated immediately and continuously based on the turbidity of flushing drainage and treated water, it is adopted in the above system. Thus, it is possible to carry out a suitable treatment depending on the concentration.

なお、フラッシング排水と異なり、メッキ工場、亜鉛精錬工場等から排出される亜鉛含有排水は、製造工場によりその組成が様々であるとともに、排出口では様々な工程で発生した排水が混合するため、亜鉛濃度と濁度との相関が日々異なると共に、亜鉛以外の物質が濁度に影響を与える事も多く、亜鉛濃度と濁度に相関が見られない事が多い。   Unlike flushing drainage, zinc-containing drainage discharged from plating plants, zinc smelting plants, etc. varies in composition depending on the manufacturing plant, and the drainage generated in various processes is mixed at the discharge port, so zinc While the correlation between concentration and turbidity differs from day to day, substances other than zinc often affect the turbidity, and often there is no correlation between the zinc concentration and the turbidity.

また、特開2002−28663号公報(以下、「参考技術」という)においては、処理水の懸濁物質濃度を測定し、それにより凝結剤量を制御する事が開示されている。しかしながら本発明者が様々な場所から排出されたフラッシング排水を分析した結果、フラッシング排水では懸濁物質量と亜鉛濃度に相関が無く、これと同様の制御を用いる事はできないことが判明した。図8は、その結果を示しており、懸濁物質濃度と亜鉛濃度とは、直接関係がない。したがって、参考技術に記載された技術をもってしては、本発明のように、濁度に基づいて即座にかつ連続的にフラッシング排水中の亜鉛濃度を知ることは不可能であり、またそのことについて格別有益な情報は、参考技術には見られない。また通常は、亜鉛濃度と濁度との間には、相関関係はないとされている。これは、水に溶解している亜鉛と溶解していない亜鉛の双方が亜鉛濃度に寄与するが、濁度に影響を及ぼすのは、溶解していない亜鉛のみであるから、フラッシング排水に固有の相関だと推察される。   Moreover, in Unexamined-Japanese-Patent No. 2002-28663 (henceforth "the reference technique"), it is disclosed that the suspended matter density | concentration of process water is measured and the amount of coagulants is controlled by it. However, as a result of the present inventor's analysis of the flushing drainage discharged from various places, it was found that the flushing drainage has no correlation with the amount of suspended matter and the concentration of zinc, and the same control can not be used. FIG. 8 shows the results, in which the suspended matter concentration and the zinc concentration are not directly related. Therefore, with the technology described in the reference technology, it is impossible to immediately and continuously know the zinc concentration in the flushing drainage based on the turbidity, as in the present invention, and concerning that matter Exceptionally useful information is not found in the reference technology. Also, there is usually no correlation between zinc concentration and turbidity. This is because both zinc dissolved in water and zinc not dissolved contribute to the concentration of zinc, but only zinc which does not dissolve affects turbidity, so it is unique to flushing drainage It is presumed to be a correlation.

既述したように、亜鉛メッキ鋼管からのフラッシング排水の濁度と亜鉛濃度との間に相関があることは、発明者らによって初めて発見されたものであり、本発明は、当該発見に基づいて、新たに構築されたものである。またこの種の設備に使用される溶融亜鉛メッキ鋼管は、JISで規定されているため、いずれのメーカへの製品でも、材質や製造方法はほぼ同じであり、また同様の施工方法によって施工されている。発明者らは、かかる点にも着目し、凡そどの設備においても、亜鉛メッキ鋼管のフラッシング排水の成分割合はほぼ同一であることから、前記した排水処理方法を発明するに至っている。   As described above, the correlation between the turbidity of the flushing drainage from the galvanized steel pipe and the zinc concentration was discovered for the first time by the inventors, and the present invention is based on the discovery. , Was newly built. In addition, since hot-dip galvanized steel pipes used for this type of equipment are defined in JIS, the products and the manufacturing method are almost the same regardless of the product to any maker, and they are constructed by the same construction method. There is. The inventors paid attention also to this point, and since the component ratio of the flushing drainage of the galvanized steel pipe is almost the same in almost all facilities, the above-mentioned drainage treatment method has been invented.

前記した開示技術によれば、フラッシング排水中の亜鉛の他に、油分や、鉛等の重金属も同時に安定的に除去することができる。またフラッシング排水を本システムで処理した後に、再度配管系に戻すことが可能なように(即ち、図2のシステムにおいてはpH調整槽51の下流側の配管を、図7のシステムにおいては排出管61を配管系に接続して、配管系と本システムとの間でフラッシング排水が循環できるように)配管系と本発明のシステムを接続し、例えば配管系と本発明のシステムとを通して水を数回循環させて充分に処理した後、本システムを配管系から外し、配管系内に戻した処理水をそのまま空調用の水として使用してもよい。   According to the above disclosed technology, oil and heavy metals such as lead can be stably removed at the same time in addition to zinc in the flushing drainage. Also, after the flushing drainage is treated with this system, it can be returned to the piping system again (that is, the piping on the downstream side of the pH adjustment tank 51 in the system of FIG. 2 and the drainage pipe in the system of FIG. 61 to connect the piping system so that flushing drainage can be circulated between the piping system and the present system) connecting the piping system and the system of the present invention, for example, the number of water through the piping system and the system of the present invention After circulation and sufficient treatment, the system may be removed from the piping system, and the treated water returned into the piping system may be used as it is as water for air conditioning.

以上説明した開示内容によれば、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水を処理する方法であって、前記フラッシング排水のpHを調整する工程と、当該調整後の水を無機凝結剤で凝結させる工程と、その後高分子凝集剤で凝集させて亜鉛を含む凝集物を分離除去する工程と、を有し、前記フラッシング排水(処理原水)または前記分離除去した後の処理水の濁度を測定し、当該測定結果に基づいて、前記無機凝結剤及び高分子凝集剤の投入量を調整することを特徴とした配管系からのフラッシング排水を処理する方法が提案できる。   According to the disclosure content described above, there is provided a method of treating flushing drainage from a piping system of a facility piping a galvanized steel pipe, comprising the steps of adjusting the pH of the flushing drainage, and adjusting the water after adjustment to inorganic condensation. And coagulating with a polymer flocculant to separate and remove the zinc-containing aggregates, and turbid of the flushing drainage (treated raw water) or the treated water after the separation and removal It is possible to propose a method of treating flushing drainage from a piping system characterized by measuring the degree and adjusting the input amount of the inorganic coagulant and the polymer coagulant based on the measurement result.

なお凝集物を分離除去する工程では、沈殿槽での沈殿凝集の他に、フィルタを用いてろ過するようにしてもよい。   In the step of separating and removing the aggregates, in addition to the precipitation and aggregation in the precipitation tank, filtration may be performed using a filter.

また前記した分離除去を、凝集物を沈殿槽に沈殿させることによって行なう場合、当該沈殿した凝集物を無機凝結剤で凝結させる工程の前段側に戻す工程をさらに有し、前記濁度の測定結果に基づいて、前記戻す凝集物の量及び/又は処理するフラッシング排水の量を調整するようにしてもよい。   In the case where the separation and removal described above are carried out by precipitating the aggregates in a settling tank, the method further comprises the step of returning the precipitated aggregates to the front side of the step of coagulating with the inorganic coagulant; The amount of agglomerates returned and / or the amount of flushing drainage to be treated may be adjusted based on

前記した測定結果が所定値以上になった場合に、処理水をシステム外に排出せず再処理したり、希釈した後に排出したり、フィルタでろ過した後に排出するようにしてもよい。   When the measurement result becomes equal to or more than a predetermined value, the treated water may be reprocessed without being discharged to the outside of the system, diluted and then discharged, or filtered and filtered and then discharged.

以上説明した開示技術によれば、亜鉛メッキ鋼管を配管した設備の配管系からのフラッシング排水を処理するにあたり、凝結剤及び凝集剤の添加量を適切に制御することができ、また予め濁度と亜鉛濃度との関係を調べておくことで排水、処理水中の亜鉛の濃度を容易に推定することができる。   According to the disclosed technology described above, the amount of addition of the coagulant and the coagulant can be appropriately controlled when treating the flushing drainage from the piping system of the installation piping the galvanized steel pipe, and the turbidity degree in advance By examining the relationship with the zinc concentration, it is possible to easily estimate the concentration of zinc in waste water and treated water.

本発明は、配管系からのフラッシング排水の処理に有用である。   The present invention is useful for the treatment of flushing drainage from piping systems.

1 流入管
2 流入ポンプ
11、51 pH調整槽
12、22、32、52 ポンプ
13、23、33 攪拌装置
21 凝結槽
31 凝集槽
41 沈殿槽
43 戻し管
45、61 排出管
46 返送管
47 返送ポンプ
62 希釈系配管
64 フィルタ除去系配管
65 フィルタ
69 バイパス管
A、B、C 濁度計
Z 制御装置
DESCRIPTION OF SYMBOLS 1 inflow pipe 2 inflow pump 11, 51 pH adjustment tank 12, 22, 32, 52 pump 13, 23, 33 stirring apparatus 21 condensation tank 31 coagulation tank 41 sedimentation tank 43 return pipe 45, 61 discharge pipe 46 return pipe 47 return pump 62 Dilution system piping 64 Filter removal system piping 65 Filter 69 Bypass pipe A, B, C Turbidimeter Z controller

Claims (3)

空調設備における空調用の水の配管系を、水でフラッシングする際の前記配管系からのフラッシング排水を処理する方法であって、
前記フラッシング排水をろ過するフィルタを有するシステムと前記配管系とを接続し、
前記配管系と前記システムとの間でフラッシング排水を循環させ、前記システムでフラッシング排水を処理した後に再度前記配管系に戻し、
その後前記システムを前記配管系から外し、
前記配管系内に戻した処理水をそのまま前記配管系で空調用の水として使用することを特徴とする、配管系からのフラッシング排水の処理方法。
A method of treating flushing drainage from the piping system at the time of flushing the water piping system for air conditioning in an air conditioning facility with water ,
Connecting a system having a filter for filtering the flushing drainage and the piping system;
The flushing drainage is circulated between the piping system and the system, and after the flushing drainage is treated by the system, it is returned to the piping system again,
Then remove the system from the piping system,
A method of treating flushing drainage from a piping system, characterized in that the treated water returned into the piping system is used as it is for air conditioning in the piping system.
フラッシング排水を前記配管系と前記システムとを通して数回循環させた後に、前記システムを前記配管系から外すことを特徴とする、請求項1に記載の配管系からのフラッシング排水の処理方法。 The method for treating flushing drainage from a piping system according to claim 1, wherein the system is removed from the piping system after circulating the flushing drainage through the piping system and the system several times. 前記処理水の濁度の測定結果が所定値以上になった場合に、前記処理水を前記システム外に排出しないことを特徴とする、請求項1または2のいずれか一項に記載の配管系からのフラッシング排水の処理方法。The piping system according to any one of claims 1 and 2, wherein the treated water is not discharged out of the system when the measurement result of the turbidity of the treated water becomes equal to or more than a predetermined value. How to handle flushing drainage from
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