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JP6530889B2 - Method of producing beans - Google Patents
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JP6530889B2 - Method of producing beans - Google Patents

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JP6530889B2
JP6530889B2 JP2014026196A JP2014026196A JP6530889B2 JP 6530889 B2 JP6530889 B2 JP 6530889B2 JP 2014026196 A JP2014026196 A JP 2014026196A JP 2014026196 A JP2014026196 A JP 2014026196A JP 6530889 B2 JP6530889 B2 JP 6530889B2
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雅浩 林
雅浩 林
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Otsuka Pharmaceutical Co Ltd
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Description

本発明は、豆類の製造方法に関する。さらに詳しくは、豆類を酸性溶液の存在下で加熱し、次いで酵素処理する工程を含む豆類の製造方法に関する。   The present invention relates to a method of producing beans. More particularly, the present invention relates to a method for producing beans comprising heating beans in the presence of an acidic solution and then treating with enzymes.

豆類は乾燥された状態で流通することが多く、その調理には、まず豆類を水等に浸漬して吸水させた後、さらに調味液で煮込む、蒸煮する等の処理が必要となる。しかし、このような処理のみでは、幼児、高齢者、術後患者等の咀嚼・嚥下困難者が容易に摂取できる軟らかさを有する豆類は提供できないという問題があった。   Beans are often circulated in a dried state, and the preparation thereof requires treatment such as first immersing the beans in water or the like to absorb water and then simmering in seasoning liquid or steaming. However, there has been a problem that such treatment alone can not provide beans having softness that can be easily taken by persons with dysphagia such as infants, elderly people, and postoperative patients.

このような従来の方法に限らず、豆類の軟化を目的として様々な方法が開発されている。例えば、特許文献1では、納豆、味噌、醤油等の食品原料として、産地、種類、保存期間等が異なる大豆を使用する際に、いずれの大豆も十分に軟化されるように、尿素の0.05M以上の濃度の水溶液に大豆を浸漬した後、加圧蒸煮する方法が開示されている。
また、特許文献2では、グルコン酸のアルカリ金属塩を含有することを特徴とする豆類軟化剤が開示されており、煮豆や納豆、佃煮等の豆類の加工食品の製造において、この豆類軟化剤を添加した水中に豆類を一定時間浸漬して吸水させることが記載されている。
しかし、これらは軟化した豆類を一般的な加工食品に使用することを目的とするものであるため、これらの技術によって、咀嚼・嚥下困難者が容易に摂取できる軟らかさまで豆類を軟化させることは困難であった。
Not only such conventional methods but various methods have been developed for the purpose of softening beans. For example, in Patent Document 1, when soybeans having different production areas, types, storage periods, etc. are used as food raw materials such as natto, miso and soy sauce, 0. 0 of urea so that any soybeans are sufficiently softened. There is disclosed a method of immersing soybeans in an aqueous solution having a concentration of 05 M or more and then pressure-cooking.
Further, Patent Document 2 discloses a bean softener characterized by containing an alkali metal salt of gluconic acid, and the bean softener is used in the production of processed foods of beans such as boiled beans, natto, and boiled in soy sauce. It is described that the beans are immersed in water for a certain time to absorb water.
However, since these aim at using softened beans for general processed foods, it is difficult to soften beans to the softness that can be easily consumed by people with dysphagia by these techniques. Met.

特許文献3では、咀嚼・嚥下能力の低下した人も摂食できる、介護食に相当する柔らかな大豆の提供を目的として、外皮(表皮)を剥皮し内皮(薄皮)を有する大豆としたものを、一定温度、一定圧力および一定時間で蒸煮する方法が開示されている。この製造方法では大豆の硬さを5,000〜500,000N/cmまで軟化することが可能であるが、外皮の剥皮を必須とするものであるため生産性が悪く、蒸煮後の大豆の形状等の外観が損なわれやすいという問題があった。
本発明者も特許文献4において、咀嚼・嚥下困難者が容易に摂食できる豆類として、圧縮応力が6.0×10N/cmまで軟化された豆類の製造方法を開示している。この方法は、1)豆類をセルラーゼ等の酵素を二種以上含む酵素含有溶液に浸漬した後、2)一定条件下で酵素反応させ、さらに3)加熱する、という1)〜3)の工程を経るものであるが、大豆等の豆類において、上記2)の工程の酵素反応後、外皮の除去をした後で上記3)の工程を行うことも挙げており、外皮を有する豆類をいずれもそのまま軟化できる簡便な方法とはいえなかった。
In Patent Document 3, for the purpose of providing soft soybeans equivalent to a care food which can be eaten by persons with reduced chewing and swallowing ability, soybeans which are exfoliated from the skin (epidermis) and have endothelium (thin skin) are used. There is disclosed a method of cooking at a constant temperature, constant pressure and constant time. With this manufacturing method, it is possible to soften the hardness of soybean to 5,000 to 500,000 N / cm 2 , but since the peeling of the hull is essential, the productivity is poor, and the soybean after being steamed There is a problem that the appearance such as the shape is easily impaired.
The present inventor also discloses, in Patent Document 4, a method for producing beans softened to a compression stress of 6.0 × 10 4 N / cm 2 as beans that can be easily consumed by persons with dysphagia and dysphagia. This method comprises the steps 1) to 3) of 1) immersing beans in an enzyme-containing solution containing two or more enzymes such as cellulase, 2) enzymatic reaction under certain conditions, and 3) heating. In beans such as soybeans, it is also mentioned that the step of 3) is carried out after removing the shell after the enzyme reaction of the step 2), and the beans having the shell are all as they are. It can not be said that it is a simple method that can be softened.

このように、従来開示されている技術では、外皮の除去等の煩雑な工程を必要とせず、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有する豆類を提供する方法が十分に得られているとはいえず、このような方法の提供が望まれている。   Thus, the techniques disclosed in the prior art do not require complicated processes such as removal of the outer skin, and maintain the original shape of the beans while having softness that can be easily consumed even by persons who have difficulty in chewing and swallowing. It can not be said that the provided method is sufficiently obtained, and provision of such a method is desired.

特開平7−177860号公報Japanese Patent Application Laid-Open No. 7-177860 国際公開第99/51113号パンフレットWO 99/51 113 pamphlet 特開2009−95305号公報JP, 2009-95305, A 特許第5272072号Patent No. 5272072

本発明は、外皮の除去等の煩雑な工程を必要とせず、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有する豆類を提供することを課題とする。   An object of the present invention is to provide beans having the softness which can be easily taken even by persons having difficulty in swallowing and swallowing while maintaining the original shape of the beans without requiring complicated steps such as removal of the outer coat.

本発明者らは上記課題を解決すべく鋭意研究を行った結果、豆類を酸性溶液の存在下で加熱し、次いで酵素処理する工程を含み、かつ、豆類本来の形状を維持しつつ軟化することで、外皮の除去等の煩雑な工程を必要とせず、本発明の課題とする豆類が提供できることを見出し、本発明を完成するに至った。本発明の豆類の製造方法では、豆類の内皮のみならず外皮までそのまま軟化することができるため、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる豆類の提供が可能となる。   As a result of conducting earnest research to solve the above problems, the present inventors include steps of heating beans in the presence of an acidic solution and then treating with enzymes, and softening the beans while maintaining their original shape. Therefore, it has been found that the beans to be the subject of the present invention can be provided without requiring complicated processes such as removal of the outer coat, and the present invention has been completed. According to the method for producing beans of the present invention, it is possible to soften not only the endothelium but also the outer coat of the beans as it is, and it is possible to provide the beans which can be easily consumed even by persons with difficult chewing and swallowing while maintaining the original shape of the beans. Become.

即ち、本発明は次の(1)〜(8)の豆類の製造方法、および該製造方法によって得られる軟化された豆類等に関する。
(1)豆類を酸性溶液の存在下で加熱し、次いで酵素処理する工程を含み、かつ、豆類本来の形状を維持しつつ軟化する豆類の製造方法。
(2)豆類が外皮を有するものである上記(1)に記載の豆類の製造方法。
(3)酸性溶液がpH6以下である上記(1)または(2)に記載の豆類の製造方法。
(4)100℃〜130℃で10分〜120分加熱する上記(1)〜(3)のいずれかに記載の豆類の製造方法。
(5)セルラーゼ活性、ヘミセルラーゼ活性、ペクチナーゼ活性のいずれか一種以上の活性を有する酵素を用い、豆類に対して0.1%〜10%の濃度で酵素処理する上記(1)〜(4)のいずれかに記載の豆類の製造方法。
(6)豆類が大豆、小豆、黒豆または金時豆から選ばれるいずれか一種以上である上記(1)〜(5)のいずれかに記載の豆類の製造方法。
(7)上記(1)〜(6)のいずれかに記載の豆類の製造方法によって得られる、かたさが6×10N/m以下の軟化された豆類。
(8)咀嚼・嚥下困難者用食品用である上記(7)に記載の軟化された豆類。
That is, the present invention relates to the following methods (1) to (8) for producing beans, and softened beans and the like obtained by the method.
(1) A method for producing beans, comprising the steps of heating beans in the presence of an acidic solution and then treating with enzymes, and softening the beans while maintaining their original shape.
(2) The method for producing beans according to the above (1), wherein the beans have a coat.
(3) The method for producing beans according to the above (1) or (2), wherein the acidic solution has a pH of 6 or less.
(4) The manufacturing method of the beans in any one of said (1)-(3) heated at 100 degreeC-130 degreeC for 10 minutes-120 minutes.
(5) Using the enzyme having any one or more of cellulase activity, hemicellulase activity and pectinase activity, the enzyme treatment is carried out at a concentration of 0.1% to 10% with respect to legumes (1) to (4) The manufacturing method of the beans in any one of-.
(6) The method for producing beans according to any one of the above (1) to (5), wherein the beans are any one or more selected from soybeans, azuki beans, black beans and golden toki beans.
(7) Softened beans having a hardness of 6 × 10 4 N / m 2 or less obtained by the method for producing beans according to any one of the above (1) to (6).
(8) Softened beans according to the above (7), which are for food for people with dysphagia and dysphagia.

本発明の方法により、外皮の除去等の煩雑な工程を必要とせず、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有する豆類を提供することが容易となる。本発明によって得られる豆類は一般の加工食品に限らず、離乳食、介護食や病院食等の咀嚼・嚥下困難者用の食品等にも利用することができるため、これらの食品の製造を容易とできる。   According to the method of the present invention, it is easy to provide beans having a softness that can be easily consumed even by persons with difficulty in chewing and swallowing while maintaining the original shape of the beans without requiring complicated steps such as removal of the outer skin. Become. The beans obtained by the present invention can be used not only for general processed food but also for food for people with difficulty in swallowing and swallowing food such as baby food, nursing care food, hospital food etc. it can.

本発明の「豆類の製造方法」は、「豆類を酸性溶液の存在下で加熱し、次いで酵素処理する工程を含み、かつ、豆類本来の形状を維持しつつ軟化する」工程を含むものである。
本発明の製造方法における「酸性溶液」とは、食品の加工に使用できる酸性の溶液であればいずれのものであっても良いが、pH7未満の酸性溶液であれば良く、pH0.1以上pH6以下の酸性溶液であることが好ましい。本発明の「豆類の製造方法」に使用できればpH3以下の酸性溶液であっても良く、pH2以下の酸性溶液であっても良い。このような酸性溶液として、例えば、クエン酸、リン酸、乳酸、酒石酸、塩酸、コハク酸、酢酸、グルコン酸またはリンゴ酸を一種以上含む水溶液等が挙げられる。
本発明の酸性溶液は、これらの酸性物質を5mM以上の濃度で含むことが好ましく、10mM以上の濃度で含むことがより好ましい。酸性溶液に含まれる酸性物質の濃度が濃ければ濃い程、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有する豆類の製造が容易となる。このような本発明の酸性溶液は、例えば酸性物質を10M以下の濃度で含んでいても良く、5M以下の濃度で含んでいても良い。
The “process for producing beans” of the present invention is a process comprising “heating beans in the presence of an acidic solution and then treating with enzymes, and softening the beans while maintaining their original shape”.
The "acidic solution" in the production method of the present invention may be any acidic solution that can be used for processing food, but it may be an acidic solution with a pH of less than 7, and a pH of 0.1 or more. The following acidic solutions are preferred. As long as it can be used in the “manufacturing method of beans” of the present invention, it may be an acidic solution having a pH of 3 or less, or may be an acidic solution having a pH of 2 or less. As such an acidic solution, for example, an aqueous solution containing one or more of citric acid, phosphoric acid, lactic acid, tartaric acid, hydrochloric acid, succinic acid, acetic acid, gluconic acid or malic acid, and the like can be mentioned.
The acidic solution of the present invention preferably contains these acidic substances at a concentration of 5 mM or more, more preferably at a concentration of 10 mM or more. The higher the concentration of the acidic substance contained in the acidic solution, the easier it is to produce beans having a softness that can be easily consumed even by persons having difficulty in chewing and swallowing while maintaining the original shape of the beans. Such an acidic solution of the present invention may contain, for example, an acidic substance at a concentration of 10 M or less, and may contain 5 M or less.

「豆類を酸性溶液の存在下で加熱」とは、上記のような酸性溶液を豆類に塗布、注入したり、豆類を酸性溶液に浸漬したり、浸漬後引き上げる等して、酸性溶液が存在する状態とした上で「加熱」することをいう。
「加熱」は本発明の「豆類の製造方法」において有効であれば、どのような機器を用いてもよく、どのような条件で行っても良い。例えば、飽和蒸気調理機により加熱する場合には、庫内温度100℃〜130℃で10分〜120分の条件で加熱することが好ましく、庫内温度120℃〜130℃で30分〜60分の条件で加熱することがさらに好ましい。
"Heating beans in the presence of an acidic solution" means that an acidic solution exists by applying or pouring the above acidic solution onto beans, immersing beans in an acidic solution, pulling up after immersion, etc. It says to "heat" after making it a state.
As long as "heating" is effective in the "manufacturing method of beans" of the present invention, any apparatus may be used, and it may be performed under any conditions. For example, when heating with a saturated steam cooker, it is preferable to heat at conditions of 100 ° C. to 130 ° C. for 10 minutes to 120 minutes, and temperatures of 120 ° C. to 130 ° C. for 30 minutes to 60 minutes It is further preferable to heat under the conditions of

また「酵素処理する工程」とは、上記のように加熱した豆類に対し、酵素または酵素を含む溶液等を接触させて、酵素反応や酵素失活処理を行うことをいう。
この工程に使用する酵素は、食品の加工に使用できる酵素であればいずれのものであっても良いが、特にセルラーゼ活性、ヘミセルラーゼ活性、またはペクチナーゼ活性のいずれか一種以上の活性を有する酵素であることが好ましく、これらの活性を二種以上有する酵素であっても良い。このような酵素として、市販の酵素製剤を使用することもできる。また、酵素を含む溶液は、これらの活性を有する酵素を水等の溶媒に溶解したものを使用することができる。
Moreover, an "process to process an enzyme" means making the solution which contains an enzyme or an enzyme, etc. contact the beans heated as mentioned above, and performing an enzyme reaction and an enzyme inactivation process.
The enzyme used in this step may be any enzyme that can be used for food processing, and in particular, an enzyme having one or more of cellulase activity, hemicellulase activity, or pectinase activity. It is preferable that there be an enzyme having two or more of these activities. Commercially available enzyme preparations can also be used as such enzymes. Further, as a solution containing an enzyme, a solution obtained by dissolving an enzyme having these activities in a solvent such as water can be used.

酵素は加熱した豆類に対して0.1%〜10%の濃度で接触させ、酵素反応させることが好ましく、0.5%〜5%の濃度で接触させることが特に好ましい。
この接触は、加熱した豆類に酵素または酵素を含む溶液等を塗布、注入したり、加熱した豆類を酵素または酵素を含む溶液等に浸漬したり、浸漬後引き上げる等したりして行うことが好ましい。加熱した豆類は酸性溶液を塗布、注入等で加えている場合はそのまま、または水洗い等した上で酵素を接触させることができ、酸性溶液を浸漬または浸漬後引き上げる等により加えている場合は、酸性溶液を除いた上で、または酸性溶液を除いた後水洗い等した上で酵素を接触させることができる。
The enzyme is preferably brought into contact with the heated beans at a concentration of 0.1% to 10% and subjected to an enzyme reaction, particularly preferably at a concentration of 0.5% to 5%.
This contact is preferably carried out by applying or injecting an enzyme or a solution containing an enzyme to heated beans, immersing the heated beans in an enzyme or a solution containing an enzyme, or pulling up after immersion . The heated beans can be brought into contact with the enzyme as it is or after being washed with water if it is added by application, injection or the like with an acidic solution, and it is acidic if it is added by immersion or pulling up after immersion. After removing the solution or after removing the acid solution, it can be washed with water and the like, and then the enzyme can be contacted.

「酵素処理する工程」は本発明の「豆類の製造方法」において有効であれば、どのような機器を用いてもよく、どのような条件で行っても良い。例えば、スチームコンベクションにより酵素処理する場合は、30℃〜80℃で1分〜120分、湿度50%〜100%の条件で酵素反応行うことが好ましく、40℃〜60℃で20分〜60分、湿度75%〜100%の条件で行うことが特に好ましい。
酵素反応後、さらに70℃〜100℃で1分〜60分、湿度0%〜100%の条件でスチームコンベクションにより酵素失活処理を行っても良く、80℃〜100℃で10分〜30分、湿度50%〜100%の条件で行うことが特に好ましい。
Any apparatus may be used as long as it is effective in the "manufacturing method of beans" of this invention, and the "process to process an enzyme" may be performed on what conditions. For example, when carrying out the enzyme treatment by steam convection, it is preferable to carry out the enzyme reaction at 30 ° C. to 80 ° C. for 1 minute to 120 minutes under the conditions of 50% to 100% humidity, and 40 ° C. to 60 ° C. for 20 minutes to 60 minutes It is particularly preferable to carry out at a humidity of 75% to 100%.
After the enzyme reaction, the enzyme inactivation treatment may be carried out by steam convection under the conditions of 70 ° C. to 100 ° C. for 1 minute to 60 minutes and humidity of 0% to 100%, and 80 ° C. to 100 ° C. for 10 minutes to 30 minutes It is particularly preferable to carry out at a humidity of 50% to 100%.

「豆類本来の形状を維持しつつ軟化する」とは、上記の「加熱」および「酵素処理」を経ながらも、外皮を有した豆類がその乾燥状態、水等に浸漬して吸水させた状態、または煮豆等の豆類の形状を維持している一般の加工食品とした状態にある場合と同等の形状を維持していることをいう。
ここで「豆類本来」とは、豆類の種類に応じて、例えば大豆を軟化したものは大豆の形状として視認でき、小豆を軟化したものは小豆の形状として視認でき、また、黒豆を軟化したものは黒豆の形状として視認できること等をいう。
The phrase "softening while maintaining the original shape of beans" means that beans having a shell are immersed in water or the like in the dry state while absorbing the above-mentioned "heating" and "enzyme treatment". Or refers to maintaining the same shape as when it is in a state of being a general processed food maintaining the shape of beans such as boiled beans.
Here, according to the type of beans, "beans naturally" means, for example, those obtained by softening soybeans as visible in the form of soybeans, those obtained by softening red beans as the shape of red beans, and those obtained by softening black beans. Means that it can be visually recognized as the shape of black beans.

本発明の豆類の製造方法に使用する「豆類」は、食品としてヒト等の動物が摂取できる「豆類」であればいずれのものであっても良く、例えば、大豆、小豆、黒豆、金時豆、大福豆、ひよこ豆、ソラマメ又は枝豆等が挙げられ、これらの乾燥物や水煮であっても良い。
これらの豆類は、本発明の製造方法により、形状を維持しながら、口腔内に入れ、舌のみでつぶした場合に、なめらかなペースト状となるかたさ、食感を有することが好ましく、クリープメータを用いて測定した場合のかたさが6×10N/m以下であることが好ましく、5.5×10N/m以下であることがより好ましい。
The "beans" used in the method of producing beans of the present invention may be any "peas" that can be consumed by animals such as humans as food, and it may be, for example, soybeans, azuki beans, black beans, or gold time beans , Daifuku beans, chickpeas, fava beans or edamame, etc. may be mentioned, and may be dried products of these or boiled in water.
These beans are preferably put in the oral cavity while maintaining their shape by the production method of the present invention and have a smooth paste-like hardness and texture when crushed only with a tongue, and a creep meter The hardness when measured using it is preferably 6 × 10 4 N / m 2 or less, more preferably 5.5 × 10 4 N / m 2 or less.

このように本発明の「豆類の製造方法」により得られる「軟化された豆類」には、軟化された豆類そのものや、「軟化された豆類」を冷蔵・冷凍、乾燥等により保存状態としたのもの、保存後解凍や水戻ししたもの等も含まれる。
本発明の「軟化された豆類」は、そのまま一般の加工食品に利用することができるが、離乳食、介護食や病院食等の咀嚼・嚥下困難者用の食品等として利用することもできる。
Thus, in the "softened beans" obtained by the "manufacturing method of beans" of the present invention, the softened beans themselves and "softened beans" are kept in a stored state by refrigeration, freezing, drying or the like. Also included are those that have been thawed or rehydrated after storage.
The “softened beans” of the present invention can be used as it is as a general processed food, but can also be used as a baby food, a food for nursing care, a food for hospitals, etc.

以下、実施例、比較例をあげて本発明をさらに詳細に説明するが、本発明はこれらに限定されるものではない。   Hereinafter, the present invention will be described in more detail by way of Examples and Comparative Examples, but the present invention is not limited thereto.

1.本発明の実施例、比較例において、得られた豆類は次の評価方法により評価した。
官能評価
得られた豆類について視認される「形状」、得られた豆類を口腔内に含み、舌でつぶしたときの「軟らかさ」および「食感」について表1に示した5段階の基準に従い評価した。
この官能評価は10人で行い、評価結果の平均値が5に近いほど、本願発明の豆類として望ましいものとし、4以上であれば本願発明の豆類として適するものとした。
ここで「形状」の評価における“通常の豆類”とは次の1、2を経たもののことをいう。
1.乾燥大豆、乾燥小豆等の豆類を、外皮を除去せずそのまま容器に入れ、該豆類の重量の3倍量の水に浸して冷蔵(4℃)で16時間静置し、水戻しした。
2.上記1.の容器から水を捨て、水戻し後の豆類に対して該豆類の重量の2倍量の水に浸し、飽和蒸気調理機で庫内温度120℃、60分間加熱した。
1. In the Example of this invention, and the comparative example, the obtained beans were evaluated by the following evaluation methods.
Sensory evaluation The “shape” visually recognized for the obtained beans, the obtained beans in the oral cavity, and the “softness” and “feel” when crushed with the tongue are in accordance with the five-step criteria shown in Table 1 evaluated.
This sensory evaluation was conducted by 10 persons, and the closer the average value of the evaluation results to 5, the more desirable it was for the beans of the present invention, and the more suitable for the beans of the present invention.
Here, "normal beans" in the evaluation of "shape" refers to those which have passed through the following 1 and 2.
1. Beans such as dried soybeans and dried azuki beans were placed in a container without removing the hull, dipped in water of 3 times the weight of the beans, allowed to stand under refrigeration (4 ° C.) for 16 hours, and returned to water.
2. Above 1. The water was discarded from the vessel, immersed in water twice the weight of the beans after rehydration, and heated at a container temperature of 120 ° C. for 60 minutes with a saturated steam cooker.

Figure 0006530889
Figure 0006530889

2.かたさの評価
豆類のかたさをクリープメータ(山電製 RE2−33005B)によって測定した。
即ち、豆類(1粒)に対し、直径3mmのプランジャーを圧縮速度10mm/秒で該豆類の上端から厚さ70%まで押し込んだときの最大圧縮応力(N/m)をかたさの値とした。温度は20±2℃で、この測定を6回行い、その平均値をかたさ(測定値)とした。かたさ(測定値)が6x10N/m以下であれば、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有し、本願発明の豆類として適するものとした。
2. Evaluation of Hardness The hardness of beans was measured by a creep meter (RE 2-33005B manufactured by Yamaden Co., Ltd.).
That is, the maximum compressive stress (N / m 2 ) when pressing a plunger having a diameter of 3 mm from the upper end of the beans at a compression speed of 10 mm / sec to the value of the hardness is did. The temperature was 20 ± 2 ° C., and this measurement was performed six times, and the average value was taken as hardness (measured value). If the hardness (measured value) is 6 × 10 4 N / m 2 or less, it has a softness that can be easily consumed even by persons with dysphagia and dysphagia, and is suitable as the beans of the present invention.

〔実施例1〕
1.乾燥大豆を、外皮を除去せずそのまま容器に入れ、乾燥大豆重量の3倍量の水に浸して冷蔵(4℃)で16時間静置し、水戻しした。
2.上記1.の容器から水を捨て、水戻し後の大豆に対して該大豆重量の2倍量の酸性溶液に浸し、飽和蒸気調理機で庫内温度120℃、60分間加熱した。表2に実施例1(A〜E)ごとに使用した酸性溶液の種類を示した。
3.上記2.の容器から酸性溶液を捨て、酸性溶液浸漬後の大豆に対して該大豆重量の2倍量の1%ヘミセルラーゼ水溶液に浸し、スチームコンベクションにて湿度100%、50℃、30分間の条件でインキュベートし、酵素反応させた。その後、さらに湿度100%、90℃、5分間の条件で加熱して酵素を失活させた。
4.上記3.の容器から1%ヘミセルラーゼ溶液を捨て、得られた大豆について、形状、かたさ等を評価した。
Example 1
1. The dried soybean was put into a container as it was without removing the hull, dipped in 3 times the weight of dried soybean weight, allowed to stand under refrigeration (4 ° C.) for 16 hours, and returned to water.
2. Above 1. The water was discarded from the container, immersed in an acid solution twice the weight of the soybean with respect to the soybean after water return, and heated at a container temperature of 120 ° C. for 60 minutes with a saturated steam cooker. Table 2 shows the types of acidic solutions used for each of Example 1 (A to E).
3. Above 2. Discard the acidic solution from the container, soak it in twice the weight of the soy bean with 1% hemicellulase aqueous solution with respect to soybean after immersion in the acidic solution, and incubate under conditions of 100% humidity, 50 ° C, 30 minutes in steam convection And the enzyme reaction. Thereafter, the enzyme was further inactivated by heating at conditions of 100% humidity and 90 ° C. for 5 minutes.
4. Above 3. The 1% hemicellulase solution was discarded from the container, and the shape, hardness and the like of the obtained soybean were evaluated.

〔比較例1〕
a.酸性溶液に48mMクエン酸−クエン酸ナトリウム緩衝液(pH7)を使用した以外は実施例1と同様に乾燥大豆を処理し、得られた大豆について形状、かたさ等を評価した。
b.乾燥大豆100gを、外皮を除去せずそのまま容器に入れ、1%セルラーゼ、1%ヘミセルラーゼ含有の10mMクエン酸緩衝液(pH5)300gに浸し、冷蔵(4℃)で18時間静置した。
これをそのままスチームコンベクションにて湿度100%、50℃、60分間の条件でインキュベートし、酵素反応させた。
その後、容器から1%セルラーゼ、1%ヘミセルラーゼ含有の10mMクエン酸緩衝液(pH5)を捨て、大豆を水洗いしてその外皮を除去した。
外皮除去後の大豆に水を250g添加し、飽和蒸気調理機で庫内温度120℃、60分加熱した。
その後、容器から水を捨て、得られた大豆について形状、かたさ等を評価した。
Comparative Example 1
a. The dried soybean was treated in the same manner as in Example 1 except that 48 mM citric acid-sodium citrate buffer solution (pH 7) was used for the acidic solution, and the shape, hardness and the like of the obtained soybean were evaluated.
b. 100 g of dried soybeans were put into the container without removing the shell, dipped in 300 g of 10 mM citrate buffer (pH 5) containing 1% cellulase and 1% hemicellulase, and allowed to stand under refrigeration (4 ° C.) for 18 hours.
This was directly incubated at 100% humidity at 50 ° C. for 60 minutes in steam convection to cause an enzyme reaction.
Thereafter, 1% cellulase, 1% hemicellulase-containing 10 mM citrate buffer (pH 5) was discarded from the container, and the soybean was washed with water to remove its hull.
250 g of water was added to the soybean after hulling removal, and it heated for 60 minutes in chamber temperature 120 degreeC with a saturated steam cooker.
Thereafter, the container was drained of water, and the shape, hardness and the like of the obtained soybean were evaluated.

実施例1(A〜E)および比較例1(a、b)について得られた大豆の評価結果も表2に示した。
形状:実施例1(A〜E)の豆類はいずれも評価結果が4.8以上と高く、通常の豆類と同様の形状を維持していた。また、比較例1、aの豆類も通常の豆類と同等の外観を維持していたが、比較例1、bの豆類は外皮を除去しているため割れが目立ち、形状の評価が低かった。
軟らかさ:実施例1(A〜E)の豆類はいずれも評価結果が4.0以上と高く、十分に軟らかいものであった。また、比較例1、bの豆類も十分に軟らかいものであったが、比較例1、aの豆類はやや硬いものであった。
食感:実施例1(A〜E)の豆類はいずれも評価結果が4.0以上と高く、滑らかで食感の良いものであった。また、比較例1、bの豆類も滑らかで食感の良いものであったが、比較例1、aの豆類は外皮が少し口に残る、食感がやや悪いものであった。
かたさ(測定値):実施例1(A〜E)の豆類はいずれもかたさ(測定値)が6.0×10N/m以下であり、十分に軟らかいものであることが確認できた。また、比較例1、bの豆類もかたさ(測定値)が6.0×10N/m以下であったが、比較例1、aの豆類は6.0×10N/mを超えており、本発明の豆類とするにはやや硬かった。
The evaluation results of soybeans obtained for Example 1 (A to E) and Comparative Example 1 (a, b) are also shown in Table 2.
Shape: All the beans in Example 1 (A to E) had high evaluation results of 4.8 or more, and maintained the same shape as ordinary beans. Moreover, although the beans of Comparative Example 1 and a maintained the same appearance as normal beans, since the beans of Comparative Example 1 and b removed the outer coat, cracks were noticeable and the evaluation of the shape was low.
Softness: The beans of Example 1 (A to E) all had high evaluation results of 4.0 or more, and were sufficiently soft. The beans of Comparative Example 1 and b were also sufficiently soft, but the beans of Comparative Example 1 and a were somewhat hard.
Texture: The beans of Example 1 (A to E) all had high evaluation results of 4.0 or more, and were smooth and had a good texture. In addition, the beans of Comparative Example 1 and b were also smooth and had a good texture, but the beans of Comparative Example 1 and a had a somewhat poor texture, with the outer skin remaining slightly in the mouth.
Hardness (measured value): It was confirmed that all beans in Example 1 (A to E) had a hardness (measured value) of 6.0 × 10 4 N / m 2 or less and were sufficiently soft. . Moreover, although the hardness (measured value) of the beans of Comparative Example 1 and b was 6.0 × 10 4 N / m 2 or less, the beans of Comparative Example 1 and a had 6.0 × 10 4 N / m 2 And was somewhat hard to make the beans of the present invention.

これらの評価結果より、実施例1(A〜E)の豆類は、外皮を除去していないにも関わらず、通常の豆類と同等の形状を維持しながら、官能評価およびかたさ(測定値)のいずれにおいても軟らかく、食感も良好な豆類であることが確認できた。
また、比較例1、aの豆類は、官能評価およびかたさ(測定値)のいずれにおいても十分な軟らかさが得られておらず、食感もやや悪いものであり、比較例1、bの豆類は形状の評価が低く、外皮の除去という煩雑な工程を必要とするものであった。
従って、これらの結果から、本発明の豆類本来の形状を維持しつつ軟化された豆類を製造するには、豆類を酸性溶液の存在下で加熱し、次いで酵素処理する工程を経る必要があることが確認できた。
From these evaluation results, the beans of Example 1 (A to E) maintained the same shape as ordinary beans despite the fact that the hulls were not removed, while the sensory evaluation and hardness (measured value) were obtained. In either case, it was confirmed that the beans were soft and the texture was good.
In addition, the beans of Comparative Example 1 a did not have sufficient softness in any of the sensory evaluation and hardness (measured value), and the texture was somewhat poor, and the beans of Comparative Example 1 b The evaluation of the shape was low, and the complicated process of removing the outer skin was required.
Therefore, from these results, in order to produce softened beans while maintaining the original shape of the beans of the present invention, it is necessary to go through the steps of heating the beans in the presence of an acidic solution and then treating with enzymes Was confirmed.

Figure 0006530889
Figure 0006530889

〔実施例2〕
酸性溶液の種類を表3に示したものに変えた以外は、実施例1、Aと同様に乾燥大豆を処理した。得られた大豆の評価結果も表3に示した。
表3に示されるように、酸性溶液として、リン酸水溶液、乳酸水溶液、リンゴ酸水溶液を使用した場合でも、クエン酸水溶液と同様に本発明の豆類本来の形状を維持しつつ軟化された豆類を製造できることが確認できた。
Example 2
The dried soybean was treated in the same manner as in Example 1, A except that the type of the acidic solution was changed to that shown in Table 3. The evaluation results of the obtained soybeans are also shown in Table 3.
As shown in Table 3, even when using an aqueous solution of phosphoric acid, an aqueous solution of lactic acid, and an aqueous solution of malic acid as the acidic solution, the beans softened while maintaining the original shape of the beans of the present invention in the same manner as the aqueous citric acid solution. It has been confirmed that it can be manufactured.

Figure 0006530889
Figure 0006530889

〔実施例3〕
飽和蒸気による加熱条件を表4に示したものに変えた以外は、実施例1、Aと同様に乾燥大豆を処理した。得られた大豆の評価結果も表4に示した。
表4に示されるように、加熱条件を庫内温度100℃〜130℃、10分〜120分としても、本発明の豆類本来の形状を維持しつつ軟化された豆類を製造できることが確認できた。
[Example 3]
The dried soybean was treated in the same manner as in Example 1, A except that the heating conditions by saturated steam were changed to those shown in Table 4. The evaluation results of the obtained soybeans are also shown in Table 4.
As shown in Table 4, it was confirmed that the beans softened while maintaining the original shape of the beans of the present invention can be produced even if the heating conditions are 100 ° C. to 130 ° C. and 10 minutes to 120 minutes. .

Figure 0006530889
Figure 0006530889

〔実施例4〕
1%ヘミセルラーゼ水溶液を表5に示したものに変えた以外は、実施例1、Aと同様に乾燥大豆を処理した。得られた大豆の評価結果も表5に示した。
表5に示されるように、0.1%以上の酵素濃度で、ヘミセルラーゼ、セルラーゼ、またはペクチナーゼを使用することにより、本発明の豆類本来の形状を維持しつつ軟化された豆類を製造できることが確認できた。
Example 4
The dried soybean was treated in the same manner as in Example 1, A except that the 1% hemicellulase aqueous solution was changed to that shown in Table 5. The evaluation results of the obtained soybeans are also shown in Table 5.
As shown in Table 5, it is possible to produce softened beans while maintaining the original shape of the beans of the present invention by using hemicellulase, cellulase or pectinase at an enzyme concentration of 0.1% or more It could be confirmed.

Figure 0006530889
Figure 0006530889

〔実施例5〕
乾燥大豆を表6に示した豆類に変えた以外は、実施例1、Aと同様に豆類を処理した。得られた豆類の評価結果も表6に示した。
表6に示されるように、小豆、黒豆、金時豆および大福豆等の豆類においても、本発明の豆類本来の形状を維持しつつ軟化された豆類を製造できることが確認できた。
[Example 5]
Beans were treated in the same manner as Example 1, A except that the dried soybeans were changed to those shown in Table 6. The evaluation results of the obtained beans are also shown in Table 6.
As shown in Table 6, it has been confirmed that softened beans can be produced while maintaining the original shape of the beans of the present invention even with beans such as azuki beans, black beans, golden toki beans and dafuku beans.

Figure 0006530889
Figure 0006530889

本発明の方法によって得られる豆類は、豆類本来の形状を維持しつつ、咀嚼・嚥下困難者でも容易に摂取できる軟らかさを有する豆類であるため、一般の加工食品に限らず、離乳食、介護食や病院食等の咀嚼・嚥下困難者用の食品等にも利用でき、これらの食品の製造も容易とすることができる。   The beans obtained by the method of the present invention are beans having softness that can be easily consumed by people with chewing and swallowing while maintaining the original shape of the beans, and therefore are not limited to general processed foods, but may be baby food, care food Also, it can be used as food for people with dysphagia such as hospital food and the like who can not swallow or swallow, and these foods can be easily manufactured.

Claims (4)

次の1)及び2)の工程を含む、外皮を有する豆類であっても軟化できる、豆類本来の形状を維持しつつ、かたさが6×10N/m以下に軟化された豆類の製造方法。
1)豆類をpH4以下の酸性溶液の存在下で100℃〜130℃で10分〜120分加熱する工程、
2)上記1)の工程を経た豆類を次いで酵素処理する工程
Production of beans softened to a hardness of 6 × 10 4 N / m 2 or less while maintaining the original shape of beans which can be softened even if the beans having a shell can be softened including the following steps 1) and 2) Method.
1) heating beans at 100 ° C. to 130 ° C. for 10 minutes to 120 minutes in the presence of an acidic solution having a pH of 4 or less,
2) A step of subjecting the beans which has undergone the above step 1) to an enzyme treatment
豆類が外皮を有するものである請求項1に記載の豆類の製造方法。 The method for producing beans according to claim 1, wherein the beans have an outer coat. セルラーゼ活性、ヘミセルラーゼ活性、ペクチナーゼ活性のいずれか一種以上の活性を有する酵素を用い、豆類に対して0.1%〜10%の濃度で酵素処理する請求項1または2に記載の豆類の製造方法。 The process according to claim 1 or 2, wherein an enzyme having at least one of cellulase activity, hemicellulase activity, and pectinase activity is used to perform enzyme treatment at a concentration of 0.1% to 10% to beans. Method. 豆類が大豆、小豆、黒豆または金時豆から選ばれるいずれか一種以上である請求項1〜3のいずれかに記載の豆類の製造方法。 The method for producing beans according to any one of claims 1 to 3, wherein the beans are any one or more selected from soybeans, azuki beans, black beans and golden toki beans.
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