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JP6758179B2 - Ferrite-austenitic two-phase stainless steel sheet with excellent polishability and its manufacturing method - Google Patents
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JP6758179B2 - Ferrite-austenitic two-phase stainless steel sheet with excellent polishability and its manufacturing method - Google Patents

Ferrite-austenitic two-phase stainless steel sheet with excellent polishability and its manufacturing method Download PDF

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JP6758179B2
JP6758179B2 JP2016506480A JP2016506480A JP6758179B2 JP 6758179 B2 JP6758179 B2 JP 6758179B2 JP 2016506480 A JP2016506480 A JP 2016506480A JP 2016506480 A JP2016506480 A JP 2016506480A JP 6758179 B2 JP6758179 B2 JP 6758179B2
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stainless steel
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austenite
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石丸 詠一朗
詠一朗 石丸
真知 川
真知 川
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Nippon Steel Stainless Steel Corp
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Description

本発明は、光沢度および写像性の高い鏡面が要求される各種分野で使用される研磨性に優れたステンレス鋼板及びその製造方法に関する。 The present invention relates to a stainless steel sheet having excellent polishability and a method for producing the same, which is used in various fields where a mirror surface having high glossiness and high image quality is required.

美麗さの指向が高まりつつある最近では、意匠性や美麗さに優れた鏡面仕上ステンレス鋼が一般建材、内装材、外装パネルなどの外装材、装飾鏡やカーブミラー等の鏡面材、業務用キッチンの調理台、シンク天板、冷蔵庫の扉などの厨房機器、角バット、鍋などの調理器具に使用されている。これらの用途の中で、例として鏡に関連する用途について言えば、従来から使用されているガラスを主体にした製品では、衝撃を受けると破損し易く、破損が負傷の原因につながる可能性が高いことから、鏡面仕上したステンレス鋼をガラスに替わる鏡類として使用することが広まっている。 Recently, the orientation of beauty is increasing, and mirror-finished stainless steel with excellent design and beauty is used for general building materials, interior materials, exterior materials such as exterior panels, mirror surface materials such as decorative mirrors and curved mirrors, and commercial kitchens. It is used in kitchen equipment such as countertops, sink tops, refrigerator doors, and cooking utensils such as square bats and pots. Among these applications, for example, in the case of mirror-related applications, conventionally used glass-based products are easily damaged when subjected to impact, and the damage may lead to injury. Due to its high price, it is widely used to use mirror-finished stainless steel as a mirror to replace glass.

従来から上記用途に使用されているオーステナイト系ステンレス鋼は、焼鈍組織になっているため軟質であり、清掃時や取扱い時等に疵が発生し易く、美観が損なわれる。また、研磨に際しても、脱酸生成物であるAl系酸化物やSi系酸化物などが表面に存在すると地疵の原因となり研磨工程が増加する。 Austenitic stainless steel, which has been conventionally used for the above purposes, has an annealed structure and is therefore soft, and is liable to have flaws during cleaning and handling, which spoils the aesthetic appearance. Also, during polishing, if Al-based oxides or Si-based oxides, which are deoxidizing products, are present on the surface, it causes ground defects and increases the polishing process.

特許文献1には、製鋼段階で脱酸元素であるAl添加量を低減し、製品に含有されるAlの生成を抑制することで研磨時の地疵を無くし、研磨性を向上させた鋼が記載されている。In Patent Document 1, the amount of Al added as a deoxidizing element is reduced at the steelmaking stage, and the formation of Al 2 O 3 contained in the product is suppressed to eliminate ground defects during polishing and improve polishability. Steel is listed.

特許文献2には、光輝焼鈍材を用い最終工程である調質圧延で生じる微細な肌荒れを抑制して研磨性を改善するために、結晶粒径と母地のAl濃度を限定した鋼の製造方法が記載されている。 Patent Document 2 describes the production of steel in which the crystal grain size and the Al concentration of the base material are limited in order to suppress fine rough skin caused by temper rolling, which is the final process, and improve polishability by using a bright annealed material. The method is described.

一方、フェライト系ステンレス鋼においては、特許文献3に圧延速度を低下させて圧延潤滑油によって生じるオイルピットの生成を抑制し、オイルピット起因の白筋模様を軽減することで研磨性を改善する鋼が記載されている。 On the other hand, in ferritic stainless steel, Patent Document 3 states that the rolling speed is reduced to suppress the formation of oil pits caused by rolling lubricating oil, and the white streaks caused by the oil pits are reduced to improve the polishability. Is described.

さらに、特許文献4では、フェライト相+マルテンサイト相の複相鋼板を鏡面研磨へ適用することで、フェライト系の加工性とマルテンサイト系の耐疵付き性を両立した鋼が記載されている。 Further, Patent Document 4 describes a steel in which a ferrite phase + martensitic phase double-phase steel sheet is applied to mirror polishing to achieve both ferrite-based workability and martensitic-based flaw resistance.

しかしながら、特許文献1では、地疵の少ないオーステナイト系ステンレス鋼は得られるものの、取り扱い時に生じる疵を解消することはできない。特許文献2では、調質圧延後の表面うねりが解消され、研磨工程の削減が可能となるものの工程はBA工程に限定される。特許文献3では、圧延時のオイルピット生成が抑制され素材起因の研磨性低下は抑制されるものの、フェライト系ステンレス鋼であるため軟質で粗研磨時の研削疵が深くなった場合には、仕上研磨工程の負荷が増加してしまうので研磨性を劣化させてしまう。 However, in Patent Document 1, although austenitic stainless steel with few ground defects can be obtained, the defects that occur during handling cannot be eliminated. In Patent Document 2, the surface waviness after temper rolling is eliminated and the polishing process can be reduced, but the process is limited to the BA process. In Patent Document 3, although the formation of oil pits during rolling is suppressed and the deterioration of polishability due to the material is suppressed, since it is a ferritic stainless steel, it is soft and when the grinding flaw during rough polishing becomes deep, it is finished. Since the load of the polishing process increases, the polishability is deteriorated.

これらの対策として、特許文献4に記載されている鋼が発明されたが、フェライト相+マルテンサイト相の二相ステンレス鋼では、軟質のフェライト相と硬質のマルテンサイト相からなる微細混合組織をもっているため両者の長所が活かされ、鏡面仕上後の光沢度が優れていると共に、適度な加工性及び強度を兼ね備えており、オーステナイト系に比較して耐疵付き性が良好であった。また、微細混合組織であることから、たとえばカーブミラーのように曲率をもつ鏡面にあっては、塑性加工後の表面肌荒れが小さく、肌荒れを除去するための研磨負荷は小さくなっていた。しかし、素材の硬度はHV350程度と著しく高いため、研磨目が付きにくく研磨装置の負荷と砥石の消費量が多くなってしまう課題があった。 As a countermeasure against these, the steel described in Patent Document 4 was invented, but the duplex stainless steel of ferrite phase + martensite phase has a fine mixed structure consisting of soft ferrite phase and hard martensite phase. Therefore, the advantages of both are utilized, the glossiness after mirror finishing is excellent, and the workability and strength are moderate, and the flaw resistance is better than that of the austenitic stainless steel. Further, since it is a fine mixed structure, in the case of a mirror surface having a curvature such as a curved mirror, the surface rough surface after plastic working is small, and the polishing load for removing the rough skin is small. However, since the hardness of the material is remarkably high, about HV350, there is a problem that the polishing grain is hard to be attached and the load of the polishing apparatus and the consumption of the grindstone are increased.

特開平4−99215号公報Japanese Unexamined Patent Publication No. 4-99215 特開平8−309405号公報Japanese Unexamined Patent Publication No. 8-309405 特開平2−173215号公報Japanese Unexamined Patent Publication No. 2-173215 特開平11−152550号公報Japanese Unexamined Patent Publication No. 11-152550

本発明は、このような問題を解消すべく案出されたものであり、反射像を精度良く反射するための鏡面研磨を施した場合であっても、光沢度が高く、かつ研磨装置の負荷および砥石の消費量を抑制できるフェライト・オーステナイト系二相ステンレス鋼板であって、長期間使用しても疵や割れが発生し難く、しかも高強度化による軽量化が可能な鏡面仕上鋼板を提供することを目的とする。また、当該鏡面仕上鋼板を用いた一般建材、内装材、外装パネルなどの外装材、装飾鏡やカーブミラー等の鏡類、業務用キッチンの調理台、シンク天板、冷蔵庫の扉などの厨房機器、角バット、鍋などの調理器具を提供することを目的とする。 The present invention has been devised to solve such a problem, and even when mirror polishing for accurately reflecting a reflected image is performed, the glossiness is high and the load of the polishing apparatus is high. To provide a mirror-finished stainless steel plate which is a ferrite / austenitic two-phase stainless steel plate capable of suppressing the consumption of a grindstone, is less likely to cause scratches and cracks even after long-term use, and can be reduced in weight by increasing its strength. The purpose is. In addition, general building materials using the mirror-finished steel plate, interior materials, exterior materials such as exterior panels, mirrors such as decorative mirrors and curved mirrors, kitchen countertops for commercial kitchens, sink top plates, and kitchen equipment such as refrigerator doors. , Square bats, pots and other cooking utensils.

本発明のフェライト・オーステナイト系二相ステンレス鋼板およびその製造方法は、以下の通りである。 The ferrite-austenitic two-phase stainless steel sheet of the present invention and its manufacturing method are as follows.

(1)質量%で、C:0.03%以下、Cr:19.0〜22.0%、N:0.06〜0.20%、Ni、Mn、Cu:1種又は2種以上を合計で5.0〜7.5%、Si、Al:1種又は2種を合計で1.0%以下、P:0.045%以下、Mo:1.0%以下、S:0.005%以下、O:0.01%以下、残部はFeおよび不可避的不純物である組成を有し、フェライト相とオーステナイト相との複相組織をもち、フェライトとオーステナイトの粒径差ΔGsが15μm以下であることを特徴とする研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (1) In mass%, C: 0.03% or less, Cr: 19.0 to 22.0%, N: 0.06 to 0.20%, Ni, Mn, Cu: 1 type or 2 or more types. 5.0-7.5% in total, Si, Al: 1 or 2 in total 1.0% or less, P: 0.045% or less, Mo: 1.0% or less, S: 0.005 % Or less, O: 0.01% or less, the balance has a composition of Fe and unavoidable impurities, has a double-phase structure of ferrite phase and austenitic phase, and the particle size difference ΔGs between ferrite and austenite is 15 μm or less. A ferrite / austenitic two-phase stainless steel plate with excellent polishability.

(2)前記組成が、さらに、質量%で、Sn:0.005〜0.2%、Nb:0.01〜0.2%、Ti:0.01〜0.2%、B:0.01%以下の1種または2種以上を含むことを特徴とする上記(1)に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (2) The composition further comprises, in mass%, Sn: 0.005 to 0.2%, Nb: 0.01 to 0.2%, Ti: 0.01 to 0.2%, B: 0. The ferrite-austenitic two-phase stainless steel plate having excellent polishability according to (1) above, which comprises one type or two or more types of 01% or less.

(3)前記組成が、さらに、質量%で、Y:0.01〜0.20%、REM:0.01〜0.20%、V:0.005〜0.20%、Al:0.005〜0.20%の1種または2種以上を含むことを特徴とする上記(1)または(2)に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (3) The composition further comprises, in mass%, Y: 0.01 to 0.20%, REM: 0.01 to 0.20%, V: 0.005 to 0.20%, Al: 0. The ferrite-austenitic two-phase stainless steel plate having excellent polishability according to the above (1) or (2), which contains one or more of 005 to 0.20%.

(4)鏡面材用である上記(1)〜(3)のいずれかに記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (4) The ferrite / austenitic two-phase stainless steel sheet having excellent polishability according to any one of (1) to (3) above, which is used for a mirror surface material.

(5)外装材用である上記(1)〜(3)のいずれかに記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (5) The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of (1) to (3) above, which is used for exterior materials.

(6)厨房機器用である上記(1)〜(3)のいずれかに記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (6) The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of (1) to (3) above, which is used for kitchen equipment.

(7)調理器具用である上記(1)〜(3)のいずれかに記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 (7) The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of (1) to (3) above, which is used for cooking utensils.

(8)上記(1)〜(3)のいずれかに記載の組成を有する鋼のスラブに熱間圧延を施し、次いで、熱延板焼鈍、酸洗した後、圧延率80%以上で最終パス後の板温度が80℃以上となる冷間圧延を実施した後、1000〜1100℃の温度で最終焼鈍し、その後500℃までの冷却速度を25℃/s以上とし、酸洗処理する上記(1)〜(7)のいずれかに記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板の製造方法。 (8) A steel slab having the composition according to any one of (1) to (3) above is hot-rolled, then annealed with a hot-rolled sheet and pickled, and then the final pass is performed at a rolling ratio of 80% or more. After cold rolling to a plate temperature of 80 ° C. or higher, final annealing is performed at a temperature of 1000 to 1100 ° C., and then the cooling rate to 500 ° C. is set to 25 ° C./s or higher, and pickling is performed. The method for producing a ferrite-austenite-based two-phase stainless steel sheet having excellent polishability according to any one of 1) to (7).

本発明の複相組織ステンレス鋼板は、フェライト相+オーステナイト相の混合組織をもっていることから、微細な粒径および研磨性を損なわない程度の高硬度を有し、表面疵の付き難い各種鏡面製品として使用される。また、鏡面仕上した複相組織ステンレス鋼板は、光沢度が高く、SUS304に代表されるオーステナイト系ステンレス鋼板及びSUS430に代表されるフェライト系ステンレス鋼板では表面疵が発生し易いために使用不可能であった分野においても鏡面材、外装材、厨房機器、調理器具用として使用が可能である。 Since the double-phase structure stainless steel sheet of the present invention has a mixed structure of a ferrite phase and an austenite phase, it has a high hardness that does not impair the fine particle size and polishability, and can be used as various mirror-finished products that are less likely to have surface defects. used. Further, the mirror-finished double-phase structure stainless steel sheet has a high glossiness, and the austenitic stainless steel sheet represented by SUS304 and the ferritic stainless steel sheet represented by SUS430 are liable to cause surface defects and cannot be used. It can also be used for mirror surface materials, exterior materials, kitchen equipment, and cooking utensils in various fields.

フェライトとオーステナイトの粒径差と研磨1パス後の表面粗さの関係を示す図である。It is a figure which shows the relationship between the particle size difference of ferrite and austenite, and the surface roughness after one pass of polishing. 研磨1パス後の表面粗さと光沢度の関係を示す図である。It is a figure which shows the relationship between the surface roughness and glossiness after one pass of polishing.

以下、本発明が対象とするステンレス鋼に含まれる合金成分、含有率等を説明する。なお、成分の含有率の%は、質量%を示す。 Hereinafter, the alloy components, content, etc. contained in the stainless steel targeted by the present invention will be described. In addition,% of the content rate of a component shows mass%.

C:0.03%以下
Cは、強力なオーステナイト生成元素であると共に強化能が大きいことから、高強度化に有効に作用する。しかし、0.03%を超える多量のCが含まれると、熱処理後に多量の炭化物が生成するようになり、耐食性や靭性が低下する。したがって、0.03%以下とした。望ましくは、0.01〜0.02%の範囲である。
C: 0.03% or less C is a strong austenite-forming element and has a large strengthening ability, so that it effectively acts to increase the strength. However, if a large amount of C exceeding 0.03% is contained, a large amount of carbides will be generated after the heat treatment, and the corrosion resistance and toughness will be lowered. Therefore, it was set to 0.03% or less. Desirably, it is in the range of 0.01 to 0.02%.

Cr:19.0〜22.0%
Crは、ステンレス鋼としての耐食性を維持する上で、重要な元素である。フェライト相及びオーステナイト相からなる二相ステンレス鋼では、オーステナイト相へのCr分配が抑制されるので、オーステナイト相の耐食性を確保するためには、19.0%以上が必要である。しかし、22.0%を超える過剰のCrが含まれると、靭性が低下する。過剰なCr含有は、製造性の低下を招く。望ましくは、20.0〜21.0%の範囲である。
Cr: 19.0 to 22.0%
Cr is an important element in maintaining the corrosion resistance of stainless steel. In a two-phase stainless steel composed of a ferrite phase and an austenite phase, Cr distribution to the austenite phase is suppressed, so that 19.0% or more is required to ensure the corrosion resistance of the austenite phase. However, if an excess of Cr exceeding 22.0% is contained, the toughness decreases. Excessive Cr content causes a decrease in manufacturability. Desirably, it is in the range of 20.0 to 21.0%.

Ni、Mn、Cu:1種又は2種以上を合計で5.0〜7.5%
何れもオーステナイト生成元素として作用し、常温でフェライト+オーステナイトの組織を得るために必要な合金元素である。Ni、Mn及び/又はCuの含有率増加に応じてオーステナイト相が多くなり、硬さ(強度)が上昇する。Ni、Mn、Cuの1種又は2種以上を合計で5.0%以上含ませたときに、オーステナイト相の硬度がフェライト相に等しい値となる。しかし、7.5%を超える過剰なNi、Mn及び/又はCuを含有させると、高温でのオーステナイト量が多くなりすぎ、熱間加工性が低下する。望ましくは、5.5〜6.5%の範囲である。
Ni, Mn, Cu: 1 type or 2 or more types in total 5.0-7.5%
Both are alloying elements that act as austenite-forming elements and are necessary to obtain a ferrite + austenite structure at room temperature. As the content of Ni, Mn and / or Cu increases, the austenite phase increases and the hardness (strength) increases. When one or more of Ni, Mn, and Cu are contained in a total amount of 5.0% or more, the hardness of the austenite phase becomes a value equal to that of the ferrite phase. However, if an excess of Ni, Mn and / or Cu exceeding 7.5% is contained, the amount of austenite at high temperature becomes too large and the hot workability is lowered. Desirably, it is in the range of 5.5 to 6.5%.

N:0.06〜0.20%
Nは、Cと同様にオーステナイト生成元素であり、そのためN含有率は、他のフェライト生成元素との兼ね合いのもとでの成分含有率から定める必要がある。また、このNは、耐孔食性を向上させる効果もあり、Nの含有率は少なくとも、0.06%必要である。しかし、0.20%を超えると熱間加工性を悪化させるため、0.06〜0.20%とした。望ましくは0.10〜0.18%の範囲である。
N: 0.06 to 0.20%
Like C, N is an austenite-forming element, and therefore the N content needs to be determined from the component content in consideration of other ferrite-forming elements. Further, this N also has an effect of improving the pitting corrosion resistance, and the content of N needs to be at least 0.06%. However, if it exceeds 0.20%, the hot workability deteriorates, so the ratio was set to 0.06 to 0.20%. It is preferably in the range of 0.10 to 0.18%.

Si、Al: 1種又は2種の合計で1.0%以下
SiとAlは、脱酸に必要な元素として知られており、鋼中の清浄度を上げ地疵を低減するために非常に重要な元素である。一方、Siはσ相の析出を促進し、脆化の原因となり、Alは鋼中のNと結合してAlNを生成させる原因にもなる。従って、これらの元素は、合計で1.0%以下、好ましくは0.2〜0.6%の範囲内とする。但し、過度の低減は精錬コストの増加に繋がる他、脱酸不良につながるため、下限は0.05%以上が望ましい。
Si, Al: 1.0% or less in total of 1 or 2 types Si and Al are known as elements required for deoxidation, and are very important for improving the cleanliness of steel and reducing burrs. It is an important element. On the other hand, Si promotes the precipitation of the σ phase and causes embrittlement, and Al also causes the formation of AlN by combining with N in the steel. Therefore, these elements are in the range of 1.0% or less, preferably 0.2 to 0.6% in total. However, excessive reduction leads to an increase in refining cost and poor deoxidation, so the lower limit is preferably 0.05% or more.

P:0.045%以下
Pは、耐食性に有害な元素であるため少ないほど良い。しかし、過度に含有率を低減するには特殊な製錬技術を要し製造コストアップにつながるため、Pは、0.045%以下に制御する必要がある。
P: 0.045% or less P is an element harmful to corrosion resistance, so the smaller the amount, the better. However, in order to excessively reduce the content, a special smelting technique is required, which leads to an increase in manufacturing cost. Therefore, P needs to be controlled to 0.045% or less.

S: 0.005%以下
Sは、フェライトとオーステナイトの粒界に析出して熱間加工性を劣化させるとともに、耐食性にも悪影響を及ぼす元素であるので、低いほど良い。特に、このS含有率が0.005%を超えるとその影響が顕著になるので、Sは、0.005%以下とする。好ましくは、0.002%以下とする。
S: 0.005% or less S is an element that precipitates at the grain boundaries of ferrite and austenite to deteriorate hot workability and adversely affect corrosion resistance, so the lower the value, the better. In particular, when the S content exceeds 0.005%, the effect becomes remarkable, so S is set to 0.005% or less. Preferably, it is 0.002% or less.

Mo:1.0%以下
Moは、耐孔食性や耐隙間腐食性などの耐食性の向上に、またフェライト相の固溶強化に寄与する元素である。一方、1.0%を超えると硬化にともなう延性の低下および靭性を劣化させ、製造コストの上昇を招く。従って、Moは1.0%以下の範囲で含有させる。望ましくは、0.5%以下とする。なお、Moは添加量に応じて効果を発揮するが、Moの耐食性向上の効果を十分に得るためには0.01%以上含有させることが好ましい。
Mo: 1.0% or less Mo is an element that contributes to the improvement of corrosion resistance such as pitting corrosion resistance and crevice corrosion resistance, and to the solid solution strengthening of the ferrite phase. On the other hand, if it exceeds 1.0%, the ductility and toughness deteriorate with hardening, which leads to an increase in manufacturing cost. Therefore, Mo is contained in the range of 1.0% or less. Desirably, it is 0.5% or less. Although Mo exerts an effect depending on the amount of Mo added, it is preferably contained in an amount of 0.01% or more in order to sufficiently obtain the effect of improving the corrosion resistance of Mo.

O:0.01%以下
Oは、鋼中に酸化物として存在する。酸化物は、一般的に硬度が高く研磨時に鋼表面の疵の原因となりやすいので少ないことが望ましいが、脱酸時間や脱酸に必要な元素により、生産性やコストに多大な影響を与える。したがって、0.01%以下とした。望ましくは、0.006%以下とする。
O: 0.01% or less O exists as an oxide in steel. Oxides are generally high in hardness and easily cause scratches on the steel surface during polishing, so it is desirable that the amount is small. However, the deoxidation time and the elements required for deoxidation have a great influence on productivity and cost. Therefore, it was set to 0.01% or less. Desirably, it is 0.006% or less.

以上を、本発明が対象とするステンレス鋼の基本成分とし、残部および不可避的不純物よりなるものとして、必要に応じて以下の成分も含有できる。 The above is the basic component of the stainless steel targeted by the present invention, and it is composed of the balance and unavoidable impurities, and the following components can be contained as necessary.

Sn:0.005〜0.2%
Snは、耐食性を向上させる元素であるがフェライト相の固溶強化元素でもあり、硬度差低下から上限を0.2%とした。耐食性を向上させる効果は、0.005%から発揮されるため、0.005〜0.2%とした。望ましくは、0.03〜0.1%の範囲である。
Sn: 0.005-0.2%
Sn is an element that improves corrosion resistance, but it is also a solid solution strengthening element of the ferrite phase, and the upper limit was set to 0.2% due to the decrease in hardness difference. Since the effect of improving the corrosion resistance is exhibited from 0.005%, it was set to 0.005 to 0.2%. Desirably, it is in the range of 0.03 to 0.1%.

Nb:0.01〜0.2%、Ti:0.01〜0.2%
Nb、Tiはともにフェライト相における安定化元素であり、耐局部腐食性の向上に有効な元素である。しかし、何れも0.01%以下の添加では効果はなく、一方0.2%を超えると多量の析出物が析出するため靭性の劣化により、熱間加工性を劣化させるほか、製造コストの面で不利となる。従って、NbとTiの添加量は、いずれも0.01〜0.2%、望ましくは0.05〜0.12%の範囲とする。
Nb: 0.01 to 0.2%, Ti: 0.01 to 0.2%
Both Nb and Ti are stabilizing elements in the ferrite phase and are effective elements for improving local corrosion resistance. However, addition of 0.01% or less has no effect, while if it exceeds 0.2%, a large amount of precipitates are precipitated, resulting in deterioration of toughness, which deteriorates hot workability and manufacturing cost. It becomes disadvantageous. Therefore, the amount of Nb and Ti added is in the range of 0.01 to 0.2%, preferably 0.05 to 0.12%.

B:0.01%以下
Bは、微量の添加で合金の粒界に存在し、熱間加工性を向上させる元素である。しかし同時に、粒界腐食などの耐食性も劣化させる元素でもある。従って、Bの含有率は、0.01%以下とした。
B: 0.01% or less B is an element that exists at the grain boundaries of the alloy with a small amount of addition and improves hot workability. However, at the same time, it is also an element that deteriorates corrosion resistance such as intergranular corrosion. Therefore, the content of B was set to 0.01% or less.

本発明が対象とするステンレス鋼は、以上の合金成分の外に、さらに、耐酸化性の向上に有効な0.01〜0.20%のY及び0.01〜0.20%のREM(Yを除く希土類金属)、耐酸化性の向上に有効な0.005〜0.20%のV、脱酸に有効な0.005〜0.20%のAlを含むことができる。
また、本発明の効果を損なわない範囲で、その他元素も添加することができる。
In addition to the above alloy components, the stainless steel targeted by the present invention has 0.01 to 0.20% Y and 0.01 to 0.20% REM, which are effective for improving oxidation resistance. Rare earth metal excluding Y), 0.005 to 0.20% V effective for improving oxidation resistance, and 0.005 to 0.20% Al effective for deoxidation can be contained.
In addition, other elements can be added as long as the effects of the present invention are not impaired.

本発明では、ステンレス鋼に含まれる各種合金成分の含有率を以上のように規制すると共に、常温でフェライト相+オーステナイト相の複相組織が得られるように各合金成分を相互に調整している。常温で得られる複相組織としては、実質的に50〜60体積%の展伸フェライト相及び40〜50体積%の粒状オーステナイト相からなる組織が好ましい。 In the present invention, the content of various alloy components contained in stainless steel is regulated as described above, and the alloy components are mutually adjusted so that a double phase structure of a ferrite phase + an austenite phase can be obtained at room temperature. .. As the multiphase structure obtained at room temperature, a structure composed of substantially 50 to 60% by volume of a wrought ferrite phase and 40 to 50% by volume of a granular austenite phase is preferable.

フェライトとオーステナイト粒径差ΔGsが15μm
表1に示す成分の鋼を供試材として、後述の実施例に示されるように、さまざまな粒径を有するフェライト相とオーステナイト相よりなる二相ステンレス鋼の冷延製品を製造し、フェライトとオーステナイトの粒径を電子線後方散乱回折法(EBSD)により測定した。なお、粒径の測定は、1000倍の視野中にある全てのフェライトおよびオーステナイトの粒径を円相当径に換算して行った。測定したフェライトおよびオーステナイトの粒径の平均値をそれぞれ求めて、フェライト平均粒径およびオーステナイト平均粒径とした。フェライト平均粒径とオーステナイト平均粒径の差を当該視野のΔGsとした。これを任意の5視野について行い、5視野のΔGsの平均値を鋼板のΔGsとした。次いで、#400バフ研磨を1パス実施した前後の表面粗さRzおよび光沢度Gs60を測定し、粒径差と表面粗さの関係を比較した。図1に示すように、フェライトとオーステナイトの粒径差ΔGs(フェライトの粒径−オーステナイトの粒径)が15μm以下である場合、表面粗さは安定して低下している。表面粗さと光沢度の関係を図2に示すが、表面粗さが低いほど光沢度は良好である。図1及び2より、粒径差が15μm以内である場合には光沢度は350以上を示している。
Difference in particle size between ferrite and austenite ΔGs is 15 μm
Using the steels of the components shown in Table 1 as test materials, cold-rolled products of two-phase stainless steel consisting of ferrite phase and austenite phase having various particle sizes were manufactured as shown in Examples described later, and ferrite was used as a test material. The particle size of austenite was measured by electron backscatter diffraction (EBSD). The particle size was measured by converting the particle sizes of all ferrites and austenites in a 1000-fold visual field into circle-equivalent diameters. The average values of the measured ferrite and austenite particle sizes were obtained and used as the ferrite average particle size and the austenite average particle size, respectively. The difference between the ferrite average particle size and the austenite average particle size was defined as ΔGs in the field of view. This was performed for any 5 visual fields, and the average value of ΔGs in the 5 visual fields was taken as ΔGs of the steel sheet. Next, the surface roughness Rz and the glossiness Gs60 before and after one pass of # 400 buffing were measured, and the relationship between the particle size difference and the surface roughness was compared. As shown in FIG. 1, when the particle size difference ΔGs between ferrite and austenite (ferrite particle size-austenite particle size) is 15 μm or less, the surface roughness is stably reduced. The relationship between the surface roughness and the glossiness is shown in FIG. 2. The lower the surface roughness, the better the glossiness. From FIGS. 1 and 2, when the particle size difference is within 15 μm, the glossiness is 350 or more.

このような粒径差によって研磨後の表面粗さが安定して低下する現象は、次のように考えられる。冷延製品を研磨した際の表面粗さ低下を阻害する要因は、酸洗処理によって生じる粒界浸食溝と内在する介在物による地疵と推定される。この粒界浸食溝は、粒界が選択的に溶解する現象でありオーステナイト相で一般的に生じる。本発明鋼の製品表面には約50%のオーステナイト相が存在しており、この部分の粒界浸食溝を軽減することにより研磨後の表面粗さは改善される。しかしながら、オーステナイト粒径のみを制御することは不可能である。 The phenomenon that the surface roughness after polishing is stably reduced due to such a difference in particle size is considered as follows. It is presumed that the factors that hinder the decrease in surface roughness when the cold-rolled product is polished are the grain boundary erosion grooves caused by the pickling treatment and the ground defects caused by the inclusions. This grain boundary erosion groove is a phenomenon in which grain boundaries are selectively dissolved and generally occurs in the austenite phase. About 50% of the austenite phase is present on the product surface of the steel of the present invention, and the surface roughness after polishing is improved by reducing the intergranular erosion grooves in this portion. However, it is not possible to control only the austenite particle size.

そこで、フェライトとオーステナイトの粒径差を制御することが重要となる。オーステナイトの粒界浸食溝を軽減するためには、オーステナイト粒径が8μm以下であることが望ましいが、同時にフェライトが粒成長する。本発明鋼のフェライト相はオーステナイト相よりも軟質であるため、粗大粒が存在すると地疵が発生しやすくなってしまう。これらを両立するため、粒径差を15μm以内とする必要がある。 Therefore, it is important to control the particle size difference between ferrite and austenite. In order to reduce the intergranular erosion groove of austenite, it is desirable that the austenite particle size is 8 μm or less, but at the same time, ferrite grows. Since the ferrite phase of the steel of the present invention is softer than the austenite phase, the presence of coarse particles tends to cause ground flaws. In order to achieve both of these, the particle size difference needs to be within 15 μm.

次に、本発明の二相ステンレス鋼板を得るための製造方法を説明する。
上記成分含有率に調整された鋼のスラブに熱間圧延を施し、次いで、熱延板焼鈍、酸洗した後、冷間圧延を実施した後、最終焼鈍し、酸洗処理して製造されるが、粒径差が15μm以下である二相ステンレス鋼にするためには、冷間圧延、最終焼鈍を次のようにする。
Next, a manufacturing method for obtaining the duplex stainless steel sheet of the present invention will be described.
A steel slab adjusted to the above component content is hot-rolled, then annealed and pickled on a hot-rolled plate, then cold-rolled, and then finally annealed and pickled. However, in order to obtain a two-phase stainless steel having a particle size difference of 15 μm or less, cold rolling and final annealing are performed as follows.

冷延率:80%以上で最終パス後の板温度80℃以上
冷延鋼帯を製造するに際しては、結晶粒径差を小さくするため冷延率(冷間圧延における圧延率)を80%以上とする必要がある。冷延により粗大なフェライトの集合組織を粉砕し微細な再結晶粒を得るためである。冷延率が80%未満では粗大なフェライト粒の残存が確認できるため、冷延率を80%以上とした。
Cold rolling rate: 80% or more and plate temperature after final pass 80 ° C or higher When manufacturing cold rolled steel strips, the cold rolling rate (rolling rate in cold rolling) is 80% or more in order to reduce the difference in crystal grain size. Must be. This is because the coarse ferrite texture is crushed by cold rolling to obtain fine recrystallized grains. If the cold rolling ratio is less than 80%, residual coarse ferrite grains can be confirmed, so the cold rolling ratio was set to 80% or more.

また、冷延時の歪導入は再結晶粒の生成核となるが、本発明のような高強度鋼では、加工硬化が進むと冷延工程に多大な負荷が生じる。そこで、冷間圧延時の板温度を上昇させることによって負荷を軽減する。この効果は、冷延工程負荷の増加のみならず、再結晶の生成核を過大としないため、結晶粒径の制御においても有用であり、結晶粒径差を15μm以下にするためには、最終パス後の板温度を80℃以上に制御することが必要である。板温度の上限は300℃程度である。なお、最終パス後の板温度は1パス当たりの圧延率や圧延速度を変更することによって制御することが可能である。 Further, the introduction of strain during cold rolling becomes a nucleation of recrystallized grains, but in a high-strength steel such as the present invention, a large load is generated in the cold rolling process as work hardening progresses. Therefore, the load is reduced by raising the plate temperature during cold rolling. This effect is useful not only for increasing the load on the cold rolling process but also for controlling the crystal grain size because it does not overstate the recrystallized nuclei. It is necessary to control the plate temperature after passing to 80 ° C. or higher. The upper limit of the plate temperature is about 300 ° C. The plate temperature after the final pass can be controlled by changing the rolling rate and rolling speed per pass.

最終焼鈍:1000〜1100℃
1000〜1100℃の温度域に加熱する仕上熱処理を施す。1000〜1100℃の温度域は、結晶粒の粒成長挙動について本発明者等が種々調査・研究した結果、見い出されたものであり、研磨性を向上させるために必要なフェライトとオーステナイトの結晶粒径差と硬度差を制御するために重要な要件である。1000℃に達しない加熱温度では、オーステナイトの再結晶が十分に完了しきれず、一部のオーステナイトが回復展伸粒として残存する。粗大粒の粒界浸食溝は深くなるため、研磨仕上後の表面粗さを劣化させる。一方、1100℃を超える高温に加熱すると、材質が軟化すると共にフェライトの粗粒化が生じるため、結晶粒径差と硬度差が大きくなり耐疵付き性の低下が生じ、表面粗さの劣化を招き、研磨性の大幅な低下につながる。
Final annealing: 1000-1100 ° C
A finish heat treatment is performed by heating to a temperature range of 1000 to 1100 ° C. The temperature range of 1000 to 1100 ° C. was found as a result of various investigations and studies by the present inventors regarding the grain growth behavior of crystal grains, and is a ferrite and austenite crystal grains necessary for improving polishability. It is an important requirement for controlling the difference in diameter and hardness. At a heating temperature of less than 1000 ° C., the recrystallization of austenite cannot be completed sufficiently, and some austenite remains as recovery swelling granules. Since the intergranular erosion grooves of the coarse grains become deep, the surface roughness after polishing is deteriorated. On the other hand, when heated to a high temperature exceeding 1100 ° C., the material is softened and ferrite is coarse-grained, so that the difference in crystal grain size and hardness becomes large, the scratch resistance is lowered, and the surface roughness is deteriorated. This leads to a significant decrease in polishability.

冷却速度:25℃/s以上(500℃まで)
1000〜1100℃の温度域に加熱された後、緩冷却されるとフェライト相のN固溶限低下にともない粒界のNが増加し、Cr窒化物の析出が生じる。このCr窒化物はその後のデスケール工程で粒界浸食溝の原因となり、研磨性を劣化させる。したがって、冷却速度は25℃/sとした。また、500℃以下でCr窒化物の析出が抑制されるため、500℃までとした。
Cooling rate: 25 ° C / s or more (up to 500 ° C)
When the ferrite phase is heated to a temperature range of 1000 to 1100 ° C. and then slowly cooled, the grain boundary N increases as the N solid solution limit of the ferrite phase decreases, and Cr nitride precipitation occurs. This Cr nitride causes intergranular erosion grooves in the subsequent descaling process and deteriorates polishability. Therefore, the cooling rate was set to 25 ° C./s. Further, since the precipitation of Cr nitride is suppressed at 500 ° C. or lower, the temperature is set to 500 ° C. or lower.

この仕上熱処理によって、フェライト相約50〜60体積%及びオーステナイト相約40〜50体積%からなる微細混合組織が得られ、フェライトとオーステナイト粒径差ΔGsが15μm以下をもつ材料となる。 By this finish heat treatment, a fine mixed structure composed of about 50 to 60% by volume of the ferrite phase and about 40 to 50% by volume of the austenite phase is obtained, and the material has a ferrite and austenite particle size difference ΔGs of 15 μm or less.

仕上熱処理されたステンレス鋼は、粗研磨仕上、中仕上研磨、最終鏡面研磨仕上が施され、鏡面をもつ製品となる。このようにして得られた製品は、ガラス製の鏡のような衝撃による破損がないため、破損による負傷等のトラブルが防止される。また、表面硬度が高いことから、清掃時や取扱い時等に発生しがちな表面疵も軽減される。したがって、自動車、二輪車、各種車両等の交通運輸関連や航空機関連、住宅、ビル、店舗、道路付帯設備等の建築・土木関連、光学、医療等の化学機器関連、機械、電気、電子等の各種機器関連、一般家庭用器具、厨房機器、調理器具、事務機器関連等の広範な分野に適した材料となる。 The finish heat-treated stainless steel is subjected to rough polishing finish, medium finish polishing, and final mirror polishing finish to obtain a product having a mirror surface. Since the product thus obtained is not damaged by an impact like a glass mirror, troubles such as injury due to the damage can be prevented. In addition, since the surface hardness is high, surface defects that tend to occur during cleaning and handling can be reduced. Therefore, transportation-related products such as automobiles, motorcycles, and various vehicles, aircraft-related products, construction / civil engineering-related products such as houses, buildings, stores, and roadside facilities, chemical equipment-related products such as optics and medical care, machinery, electricity, and electronics. It is a material suitable for a wide range of fields such as equipment-related, general household equipment, kitchen equipment, cooking equipment, and office equipment-related.

表1に示した本発明の成分範囲を満足する鋼Aと、本発明の成分範囲を満足しない鋼Bよりなるステンレス鋼を溶製し、熱間圧延により板厚6.0mmの熱延鋼帯にした。次いで、熱延鋼帯に980℃×60分の熱延板焼鈍を施し、種々の冷延率となるように板厚を変更し冷間圧延した。得られた冷延鋼板を焼鈍炉に導入し、仕上熱処理として表2に示す温度で熱処理を施し、フェライト相+オーステナイト相の複相組織をもつステンレス鋼帯を製造した。 A stainless steel made of steel A satisfying the component range of the present invention shown in Table 1 and steel B not satisfying the component range of the present invention is melted and hot-rolled to a hot-rolled steel strip having a plate thickness of 6.0 mm. I made it. Next, the hot-rolled steel strip was annealed with a hot-rolled plate at 980 ° C. for 60 minutes, the plate thickness was changed so as to have various cold-rolling ratios, and cold rolling was performed. The obtained cold-rolled steel sheet was introduced into an annealing furnace and heat-treated at the temperatures shown in Table 2 as a finish heat treatment to produce a stainless steel strip having a double-phase structure of a ferrite phase and an austenite phase.

Figure 0006758179
Figure 0006758179

各複相組織ステンレス鋼帯から試験片を切り出し、#400バフ研磨を1パス施し、鏡面研磨仕上とした。試験片の硬度はHV250程度であるため、研磨装置への負荷が小さく、砥石の消費量を抑制できた。鏡面研磨した各試験片について、JIS B0601’1994の十点平均粗さRzに準拠して表面粗さを測定するとともに、JIS Z8741の鏡面光沢度測定法に準拠して光沢度を測定した。結果を表2に示す。 A test piece was cut out from each double-phase structure stainless steel strip and subjected to 1 pass of # 400 buffing to obtain a mirror-polished finish. Since the hardness of the test piece was about HV250, the load on the polishing apparatus was small, and the consumption of the grindstone could be suppressed. The surface roughness of each mirror-polished test piece was measured according to the ten-point average roughness Rz of JIS B0601'1994, and the glossiness was measured according to the mirror glossiness measurement method of JIS Z8741. The results are shown in Table 2.

Figure 0006758179
Figure 0006758179

表2から明らかなように成分範囲および製造条件が本発明範囲を満足する本発明例試験No.1、2、5、6、8、9、12、16、17、19、20、22、23、24、25、26は、フェライト相とオーステナイト相の粒径差が15μm以内となり、研磨後の光沢度Gs60が350以上と良好であった。一方、成分範囲が本発明範囲から外れる鋼Bの比較例試験No.1〜15は、製造条件を満たしていてもフェライト相とオーステナイト相の粒径差が15μm超となり、研磨後の光沢度も劣位な結果であった。 As is clear from Table 2, Example Test No. of the present invention in which the component range and the production conditions satisfy the range of the present invention. For 1, 2, 5, 6, 8, 9, 12, 16, 17, 19, 20, 22, 23, 24, 25, and 26, the particle size difference between the ferrite phase and the austenite phase is within 15 μm, and after polishing, The glossiness Gs60 was as good as 350 or more. On the other hand, Comparative Example Test No. of Steel B whose component range is out of the range of the present invention. In Nos. 1 to 15, the particle size difference between the ferrite phase and the austenite phase was more than 15 μm even if the production conditions were satisfied, and the glossiness after polishing was also inferior.

一方、成分が発明範囲を満足する鋼Aを用いても、製造方法が本発明を外れる場合は、研磨後の光沢度が劣位となる場合があった。鋼Aの比較例試験No.3、14、27は、最終パス後の板温度が低く、粒径差が大きくなった結果、研磨後の表面粗度が粗く、光沢度が低位となった。鋼Aの比較例試験No.4は、焼鈍後の冷却速度が遅く、γ相の粒界が酸洗後に粒界浸食溝を生成するため研磨後の表面粗度が粗く、光沢度は低位であった。鋼Aの比較例試験No.7および21は、冷延率が低く焼鈍温度が高いこと、鋼Aの比較例試験No.10および28は冷延率が低いこと、鋼Aの比較例試験No.15は焼鈍温度が高いことから、α相の粗粒化が顕著であり粒径差が本発明範囲を超え、研磨後の光沢度が向上しなかった。鋼Aの比較例試験No.13は、焼鈍温度が低くγ相の再結晶が不十分で展伸粒が残存したため粒界浸食溝が深く、研磨仕上後の表面粗さが劣化した。鋼Aの比較例試験No.11および18は、冷延率や最終パス後に熱処理条件が発明の範囲を超えている上に、冷却速度が遅く粒界浸食溝が顕著となっているため研磨後の表面粗度が粗く、研磨後の光沢が不良であった。 On the other hand, even if steel A whose composition satisfies the invention range is used, if the production method deviates from the present invention, the glossiness after polishing may be inferior. Comparative Example Test No. of Steel A In Nos. 3, 14 and 27, the plate temperature after the final pass was low and the particle size difference was large, and as a result, the surface roughness after polishing was coarse and the glossiness was low. Comparative Example Test No. of Steel A In No. 4, the cooling rate after annealing was slow, and the γ-phase grain boundaries formed grain boundary erosion grooves after pickling, so that the surface roughness after polishing was coarse and the glossiness was low. Comparative Example Test No. of Steel A Nos. 7 and 21 have a low cold rolling ratio and a high annealing temperature, and the comparative example test No. of steel A. No. 10 and 28 have a low cold rolling ratio, and Steel A has a comparative example test No. Since the annealing temperature of No. 15 was high, coarse graining of the α phase was remarkable, the particle size difference exceeded the range of the present invention, and the glossiness after polishing was not improved. Comparative Example Test No. of Steel A In No. 13, the annealing temperature was low, the recrystallization of the γ phase was insufficient, and the expanded grains remained, so that the intergranular erosion grooves were deep and the surface roughness after polishing was deteriorated. Comparative Example Test No. of Steel A In Nos. 11 and 18, the heat treatment conditions after the final pass and the cold rolling ratio exceed the range of the invention, and the cooling rate is slow and the intergranular erosion grooves are prominent, so that the surface roughness after polishing is rough and the polishing is performed. The later gloss was poor.

以上に説明したように、本発明の複相組織ステンレス鋼板は、フェライト相+オーステナイト相の混合組織をもっていることから、微細な粒径および研磨性を損なわない程度の高硬度を有し、表面疵の付き難い各種鏡面製品として使用される。また、鏡面仕上した複相組織ステンレス鋼板は、光沢度が高く、SUS304に代表されるオーステナイト系ステンレス鋼板及びSUS430に代表されるフェライト系ステンレス鋼板では表面疵が発生し易いために使用不可能であった分野においても鏡面材として使用が可能である。 As described above, since the double-phase structure stainless steel sheet of the present invention has a mixed structure of a ferrite phase and an austenite phase, it has a fine particle size and a high hardness that does not impair polishability, and has surface defects. It is used as various mirror surface products that are difficult to attach. Further, the mirror-finished double-phase structure stainless steel sheet has a high glossiness, and the austenitic stainless steel sheet represented by SUS304 and the ferritic stainless steel sheet represented by SUS430 are liable to cause surface defects and cannot be used. It can also be used as a mirror surface material in other fields.

本発明のステンレス鋼を用いれば、自動車、二輪車、各種車両等の交通運輸関連や航空機関連、住宅、ビル、店舗、道路付帯設備等の建築・土木関連、光学、医療等の化学機器関連、機械、電気、電子等の各種機器関連、一般家庭用器具、厨房機器、調理器具、事務機器関連等の鏡面材の破損による負傷等のトラブルの防止、清表面疵の軽減が可能となる。本発明による産業上の効果は極めて顕著である。 If the stainless steel of the present invention is used, it is related to transportation such as automobiles, motorcycles, and various vehicles, aircraft-related, construction / civil engineering-related such as houses, buildings, stores, road incidental facilities, chemical equipment-related such as optics and medical equipment, and machinery. It is possible to prevent troubles such as injuries caused by damage to mirror surface materials such as electric and electronic equipment, general household equipment, kitchen equipment, cooking equipment, office equipment, etc., and to reduce clean surface defects. The industrial effect of the present invention is extremely remarkable.

Claims (8)

質量%で、C:0.03%以下、Cr:19.0〜22.0%、N:0.06〜0.20%、Ni、Mn、Cu:1種又は2種以上を合計で5.0〜7.5%、Si、Al:1種又は2種を合計で1.0%以下、P:0.045%以下、Mo:1.0%以下、S:0.005%以下、O:0.01%以下、残部はFeおよび不可避的不純物である組成を有し、フェライト相とオーステナイト相との複相組織をもち、フェライトとオーステナイトの粒径差ΔGsが15μm以下であり、前記オーステナイトの粒径が5μm以下であることを特徴とする研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 By mass%, C: 0.03% or less, Cr: 19.0 to 22.0%, N: 0.06 to 0.20%, Ni, Mn, Cu: 1 type or 2 or more types in total 5 .0 to 7.5%, Si, Al: 1 or 2 in total 1.0% or less, P: 0.045% or less, Mo: 1.0% or less, S: 0.005% or less, O: 0.01% or less, the balance has a composition of Fe and unavoidable impurities, has a dual phase structure of a ferrite phase and an austenite phase, and the particle size difference ΔGs between ferrite and austenite is 15 μm or less. A ferrite austenite-based two-phase stainless steel plate having excellent polishability, characterized in that the particle size of austenite is 5 μm or less. 前記組成は、さらに、質量%で、Sn:0.005〜0.2%、Nb:0.01〜0.2%、Ti:0.01〜0.2%、B:0.01%以下の1種または2種以上を含むことを特徴とする請求項1に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The composition further includes Sn: 0.005 to 0.2%, Nb: 0.01 to 0.2%, Ti: 0.01 to 0.2%, B: 0.01% or less in mass%. The ferrite-austenitic two-phase stainless steel plate having excellent polishability according to claim 1, which comprises one or more of the above-mentioned. 前記組成は、さらに、質量%で、Y:0.01〜0.20%、REM:0.01〜0.20%、V:0.005〜0.20%、Al:0.005〜0.20%の1種または2種以上を含むことを特徴とする請求項1または2に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The composition further includes Y: 0.01 to 0.20%, REM: 0.01 to 0.20%, V: 0.005 to 0.20%, Al: 0.005 to 0 in mass%. The ferrite / austenite-based two-phase stainless steel sheet having excellent polishability according to claim 1 or 2, which comprises 20% of one or more. 鏡面材用である請求項1〜3のいずれか1項に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of claims 1 to 3, which is used for a mirror surface material. 外装材用である請求項1〜3のいずれか1項に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The ferrite / austenitic two-phase stainless steel sheet having excellent polishability according to any one of claims 1 to 3 for exterior materials. 厨房機器用である請求項1〜3のいずれか1項に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of claims 1 to 3, which is used for kitchen equipment. 調理器具用である請求項1〜3のいずれか1項に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板。 The ferrite-austenitic two-phase stainless steel sheet having excellent polishability according to any one of claims 1 to 3 for cooking utensils. 請求項1〜3のいずれか1項に記載の組成を有する鋼のスラブに熱間圧延を施し、次いで、熱延板焼鈍、酸洗した後、圧延率95%以上で最終パス後の板温度が80℃以上となる冷間圧延を実施した後、1000〜1100℃の温度で最終焼鈍し、その後500℃までの冷却速度を25℃/s以上とし、酸洗処理することにより、フェライト相とオーステナイト相との複相組織を持ち、フェライトとオーステナイトの粒径差ΔGsが15μm以下であり、前記オーステナイトの粒径がμm以下であるステンレス鋼板を得る、請求項1〜7のいずれか1項に記載の研磨性に優れたフェライト・オーステナイト系二相ステンレス鋼板の製造方法。 The steel slab having the composition according to any one of claims 1 to 3 is hot-rolled, then annealed and pickled, and then the plate temperature after the final pass at a rolling ratio of 95% or more. After cold rolling to a temperature of 80 ° C. or higher, final annealing is performed at a temperature of 1000 to 1100 ° C., and then the cooling rate to 500 ° C. is set to 25 ° C./s or higher, and pickling treatment is performed to obtain a ferrite phase. Any one of claims 1 to 7 to obtain a stainless steel sheet having a double-phase structure with an austenite phase, a particle size difference ΔGs between ferrite and austenite of 15 μm or less, and an austenite particle size of 2 μm or less. A method for producing a ferrite / austenite-based two-phase stainless steel sheet having excellent polishability as described in 1.
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