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JP6765002B2 - Insulation equipment, cold insulation equipment, distribution packaging container, distribution system and distribution method - Google Patents
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JP6765002B2 - Insulation equipment, cold insulation equipment, distribution packaging container, distribution system and distribution method - Google Patents

Insulation equipment, cold insulation equipment, distribution packaging container, distribution system and distribution method Download PDF

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JP6765002B2
JP6765002B2 JP2019509756A JP2019509756A JP6765002B2 JP 6765002 B2 JP6765002 B2 JP 6765002B2 JP 2019509756 A JP2019509756 A JP 2019509756A JP 2019509756 A JP2019509756 A JP 2019509756A JP 6765002 B2 JP6765002 B2 JP 6765002B2
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temperature
storage material
latent heat
heat storage
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JPWO2018181096A1 (en
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勝一 香村
勝一 香村
輝心 黄
輝心 黄
恭平 勢造
恭平 勢造
夕香 内海
夕香 内海
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Sharp Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/02Devices using other cold materials; Devices using cold-storage bodies using ice, e.g. ice-boxes
    • F25D3/06Movable containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/38Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2303/00Details of devices using other cold materials; Details of devices using cold-storage bodies
    • F25D2303/08Devices using cold storage material, i.e. ice or other freezable liquid
    • F25D2303/082Devices using cold storage material, i.e. ice or other freezable liquid disposed in a cold storage element not forming part of a container for products to be cooled, e.g. ice pack or gel accumulator
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2303/00Details of devices using other cold materials; Details of devices using cold-storage bodies
    • F25D2303/08Devices using cold storage material, i.e. ice or other freezable liquid
    • F25D2303/085Compositions of cold storage materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Packages (AREA)

Description

本発明は、潜熱蓄熱材を用いた保温具、保冷具、物流梱包容器、物流システムおよび物流方法に関する。 The present invention relates to a heat insulator, a cold insulator, a physical distribution packing container, a physical distribution system, and a physical distribution method using a latent heat storage material.

食料品、医薬品、電子部品等を輸送する際に、それらの鮮度の悪化や品質の劣化を防ぐ目的から、荷送人から荷受人に届くまで、一貫して一定の温度で管理された物流システムやサービスが現在の豊かな生活を支えている。 A logistics system that is consistently controlled at a constant temperature from the shipper to the consignee in order to prevent deterioration of freshness and quality when transporting food, pharmaceuticals, electronic parts, etc. And services support the current affluent life.

上記のような定温物流システムでは、一般に被輸送物は、環境温度と被輸送物との熱の流出入を抑制するための断熱性の箱内に梱包され、さらに環境温度との温度差が大きく、熱流出入が大きくなった場合に備えて、その熱を吸収または放出するための蓄熱材(蓄冷材)とを同梱し輸送される。 In the constant temperature distribution system as described above, the transported object is generally packed in a heat insulating box for suppressing the inflow and outflow of heat between the environmental temperature and the transported object, and the temperature difference from the environmental temperature is large. , A heat storage material (cold storage material) for absorbing or releasing the heat is bundled and transported in case the heat inflow and outflow become large.

また、現状の定温物流システムでは、荷送人から荷受人へは、直接輸送されることは少なく、輸送スケジュールの調整や検品、被輸送物の再仕分け等の理由から、仲介拠点を経由する。仲介拠点においても温度管理が必要となり、冷凍冷蔵倉庫のような電気的な保温保冷機能を有する設備内にて、一時的に保管される。さらに、荷送人から仲介拠点間などの輸送期間においても長時間にわたる場合には、電気的な保温保冷機能を備えた車両にて輸送される。 In addition, in the current constant temperature distribution system, it is rarely directly transported from the consignor to the consignee, and it goes through an intermediary base for reasons such as adjustment of transportation schedule, inspection, and resorting of consigned items. Temperature control is also required at the brokerage base, and it is temporarily stored in equipment that has an electrical heat and cold insulation function, such as a freezing and refrigerating warehouse. Further, if the transportation period from the shipper to the brokerage base is long, the vehicle is transported by a vehicle having an electric heat and cold insulation function.

しかし、これまでの物流システムでは、被輸送物の保持したい温度域に対して、蓄熱材の放熱や吸熱する温度および、輸送期間中や仲介拠点での保持温度については考慮されていたが、蓄熱材と輸送期間中や仲介拠点での温度とについては考慮されてはいなかった。 However, in conventional logistics systems, the heat dissipation and endothermic temperatures of the heat storage material and the holding temperature during the transportation period and at the intermediary base have been taken into consideration for the temperature range in which the object to be transported is desired to be retained. No consideration was given to the material and the temperature during transportation or at the intermediary base.

そのため、輸送期間中や仲介拠点において、蓄熱材が不必要に放熱や吸熱を行ない、エネルギーの浪費があり、蓄熱材の増量や、仲介拠点での蓄熱材の交換が必要となり、コスト削減が課題となっている。 Therefore, during the transportation period and at the brokerage base, the heat storage material unnecessarily dissipates heat and absorbs heat, resulting in wasted energy, and it is necessary to increase the amount of heat storage material and replace the heat storage material at the brokerage base. It has become.

特許文献1では、物品を収容する保冷庫本体と、庫内を冷却する蓄冷器とを備えた保冷庫において、前記蓄冷器を、蓄冷機能を有する流体からなる蓄冷材を出し入れ自在にし、各輸送拠点にそれぞれ蓄冷材入替装置を配置し、保冷庫の蓄冷に要する時間を短縮する技術が開示されている。 In Patent Document 1, in a cold storage provided with a cold storage main body for accommodating articles and a cold storage for cooling the inside of the storage, the cold storage can be freely taken in and out of a cold storage material made of a fluid having a cold storage function, and each can be transported. A technology for shortening the time required for cold storage in a cold storage is disclosed by arranging a cold storage material replacement device at each base.

特許文献2では、保冷車を用いることなく、要保冷品を保冷配送時に求められるプラスの温度からなる保冷温度に維持して配送可能な方法として、保冷箱に蓄冷材と要保冷品を収容し、第一蓄冷体をプラス温度で予冷(凍結させない)し、凍結した第二蓄冷体と要保冷品の間に断熱材と第一蓄冷体を配置する技術が開示されている。 In Patent Document 2, a cold storage material and a cold insulation product are stored in a cold insulation box as a method of maintaining and delivering a cold insulation product at a cold insulation temperature consisting of a positive temperature required for cold insulation delivery without using a cold insulation vehicle. Disclosed is a technique in which a first cold storage body is precooled (not frozen) at a positive temperature, and a heat insulating material and a first cold storage body are arranged between the frozen second cold storage body and a cold storage required product.

特開2001−66028号公報Japanese Unexamined Patent Publication No. 2001-66028 特開2005−300052号公報Japanese Unexamined Patent Publication No. 2005-300052

しかしながら、特許文献1記載の技術では、それぞれの拠点で蓄冷材を入れ替える必要があり、蓄冷材入替装置を有する拠点を介さなければ輸送できないので、輸送ルートは著しく制限される。また、流体の蓄冷材のため、貯蔵する熱エネルギーは顕熱であり、エネルギー量として極めて少ない。そのため、各拠点での入替が必須である。 However, in the technique described in Patent Document 1, it is necessary to replace the cold storage material at each base, and the transport cannot be performed without passing through the base having the cold storage material replacement device, so that the transportation route is significantly limited. Moreover, since it is a fluid cold storage material, the heat energy to be stored is sensible heat, and the amount of energy is extremely small. Therefore, replacement at each base is essential.

また、特許文献2記載の技術では、要保冷品よりも低温に融解温度がある蓄冷体を用いているので、たとえ保冷された倉庫を経由したとしても、倉庫での温度は蓄冷体の融解温度より高くせざるを得ず、蓄冷体は融解が促進されていくため、長時間にわたる配送に対応するには、蓄冷体を大量に搭載するしかない。そのため、梱包容器の容量に比して、配送できる要保冷品の容積が小さくなってしまう。なお、上記の課題は保温に関しても共通であり、各拠点での蓄熱材の入替や、蓄熱体の量が多いという課題がある。 Further, in the technique described in Patent Document 2, since a cold storage body having a melting temperature at a lower temperature than that of a cold storage product is used, the temperature in the warehouse is the melting temperature of the cold storage body even if it passes through a cold storage. Since the cold storage body has to be made higher and melting is promoted, a large amount of cold storage body must be installed in order to cope with long-term delivery. Therefore, the volume of the cold-required item that can be delivered is smaller than the capacity of the packing container. The above-mentioned problems are also common to heat retention, and there are problems such as replacement of heat storage materials at each base and a large amount of heat storage bodies.

本発明の一実施形態は、このような事情に鑑みてなされたものであり、物流の過程で潜熱蓄熱材を再生することで、保温または保冷機能を延長させることができ、潜熱蓄熱材の相変化の際の温度変化を小さくすることで、保温または保冷対象物の保持されるべき温度範囲内にて確実に保温または保冷できる保温具または保冷具を提供することを目的とする。 One embodiment of the present invention has been made in view of such circumstances, and by regenerating the latent heat storage material in the process of distribution, the heat retention or cold retention function can be extended, and the phase of the latent heat storage material can be extended. By reducing the temperature change at the time of change, it is an object of the present invention to provide a heat insulating device or a cold insulating device that can surely keep warm or cool within the temperature range in which the heat retaining or cold retaining object should be held.

上記の目的を達成するために、本発明の一実施形態は、以下のような手段を講じた。即ち、本発明の一実施形態の保温具は、物流梱包容器に用いられ、保温対象物の温度調節を行なう保温具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備え、前記潜熱蓄熱材は、保温対象物の保持されるべき温度範囲に応じて、凝固温度が前記保温対象物の保持されるべき温度範囲に含まれ、前記融解開始温度が前記保温対象物の保持されるべき温度範囲の上限より低くなるよう選択されたものである。 In order to achieve the above object, one embodiment of the present invention has taken the following measures. That is, the heat insulating device according to the embodiment of the present invention is a heat insulating device used for a distribution packing container and controls the temperature of a heat insulating object, and is from the solidification temperature at which the phase changes from the liquid phase to the solid phase and the solid phase. The latent heat storage material is provided with a latent heat storage material having a difference of less than 1 ° C. from the melting start temperature at which the phase changes to the liquid phase, and an accommodating portion for accommodating the latent heat storage material, and the latent heat storage material retains the heat insulating object. Depending on the temperature range to be held, the solidification temperature is selected to be included in the temperature range to be held of the heat retaining object, and the melting start temperature is selected to be lower than the upper limit of the temperature range to be held of the heat retaining object. It is a thing.

また、本発明の一実施形態の保冷具は、物流梱包容器に用いられ、保冷対象物の温度調節を行なう保冷具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備え、前記潜熱蓄熱材は、保冷対象物の保持されるべき温度範囲に応じて、主たる融解温度が前記保冷対象物の保持されるべき温度範囲に含まれ、前記凝固温度が前記保冷対象物の保持されるべき温度範囲の下限より高くなるよう選択されたものである。 Further, the cold storage device according to the embodiment of the present invention is a cold storage device that is used for a distribution packing container and controls the temperature of an object to be cooled, from the solidification temperature at which the phase changes from the liquid phase to the solid phase and the solid phase. The latent heat storage material is provided with a latent heat storage material having a difference of less than 1 ° C. from the melting start temperature at which the phase changes to the liquid phase, and a storage portion for accommodating the latent heat storage material, and the latent heat storage material retains the object to be cooled. Depending on the temperature range to be kept, the main melting temperature is included in the temperature range to be held of the object to be kept cold, and the solidification temperature is selected to be higher than the lower limit of the temperature range to be held of the object to be kept cold. It is a thing.

本発明の一実施形態によれば、温度を制御しない時間帯は、潜熱蓄熱材の潜熱により凝固温度の近傍で保温対象物を保温できる。また、保温対象物の保持されるべき温度の上限が、融解開始温度よりも高いため、温度を制御する時間帯において、制御する温度を、融解開始温度よりも高く、かつ前記上限よりも低い温度で保温することによって、潜熱蓄熱材を固相から液相に相変化させることができ、再生させることができる。 According to one embodiment of the present invention, the heat-retaining object can be kept warm in the vicinity of the solidification temperature by the latent heat of the latent heat storage material during the time period when the temperature is not controlled. Further, since the upper limit of the temperature to be held of the heat-retaining object is higher than the melting start temperature, the temperature to be controlled is set to be higher than the melting start temperature and lower than the upper limit in the time zone for controlling the temperature. By keeping the temperature at, the latent heat storage material can be phase-changed from a solid phase to a liquid phase and can be regenerated.

また、本発明の一実施形態によれば、温度を制御しない時間帯は、潜熱蓄熱材の潜熱により主たる融解温度の近傍で保冷対象物を保冷できる。また、保冷対象物の保持されるべき温度の下限が、凝固温度よりも低いため、温度を制御する時間帯において、制御する温度を、凝固温度よりも低く、かつ前記下限よりも高い温度で冷却することによって、潜熱蓄熱材を液相から固相に相変化させることができ、再生させることができる。 Further, according to one embodiment of the present invention, the object to be kept cold can be kept cold in the vicinity of the main melting temperature by the latent heat of the latent heat storage material during the time period when the temperature is not controlled. Further, since the lower limit of the temperature to be retained of the object to be kept cold is lower than the solidification temperature, the controlled temperature is cooled at a temperature lower than the solidification temperature and higher than the lower limit in the time zone for controlling the temperature. By doing so, the latent heat storage material can be phase-changed from a liquid phase to a solid phase and can be regenerated.

第1または第2の実施形態に係る保温具または保冷具の断面図である。It is sectional drawing of the heat insulating tool or cold insulation device which concerns on 1st or 2nd Embodiment. DSC曲線の例と融解開始温度および主たる融解温度の求め方を示す概念図である。It is a conceptual diagram which shows the example of the DSC curve and how to obtain the melting start temperature and the main melting temperature. 第1または第2の実施形態に係る物流梱包容器の断面図である。It is sectional drawing of the physical distribution packing container which concerns on 1st or 2nd Embodiment. 第1または第2の実施形態に係る物流梱包容器の断面図である。It is sectional drawing of the physical distribution packing container which concerns on 1st or 2nd Embodiment. 第1または第2の実施形態に係る保温具または保冷具および物流梱包容器の使用状態を示す概念図である。It is a conceptual diagram which shows the use state of the heat insulation device or a cold insulation device, and a distribution packing container which concerns on 1st or 2nd Embodiment. 第3の実施形態に係る物流システムに用いられる潜熱蓄熱材と、物品の保持されるべき温度範囲に対して、加熱装置で温度を制御する際の温度範囲を示した概念図である。It is a conceptual diagram which showed the latent heat storage material used for the distribution system which concerns on 3rd Embodiment, and the temperature range when the temperature is controlled by the heating apparatus with respect to the temperature range which should hold an article. 第3の実施形態に係る物流システムに用いられる潜熱蓄熱材と、物品の保持されるべき温度範囲に対して、冷却装置で温度を制御する際の温度範囲を示した概念図である。It is a conceptual diagram which showed the latent heat storage material used for the distribution system which concerns on 3rd Embodiment, and the temperature range when the temperature is controlled by a cooling device with respect to the temperature range which should hold an article. 従来の蓄熱材を用いた物流システムの温度範囲を示した概念図である。It is a conceptual diagram which showed the temperature range of the distribution system using the conventional heat storage material. 第1または第2の実施形態に係る保温具または保冷具の製造の工程を示す概念図である。It is a conceptual diagram which shows the process of manufacturing the heat-retaining tool or the cold-retaining device which concerns on 1st or 2nd Embodiment. 第1または第2の実施形態に係る保温具または保冷具の製造の工程を示す概念図である。It is a conceptual diagram which shows the process of manufacturing the heat-retaining tool or the cold-retaining device which concerns on 1st or 2nd Embodiment. 第1または第2の実施形態に係る保温具または保冷具の製造の工程を示す概念図である。It is a conceptual diagram which shows the process of manufacturing the heat-retaining tool or the cold-retaining device which concerns on 1st or 2nd Embodiment. 実施例2、3に関する、潜熱蓄熱材の例とその蓄熱材を用いて輸送されることが想定される物品例を示した表である。It is a table which showed the example of the latent heat storage material which concerns on Examples 2 and 3 and the example of the article which is assumed to be transported using the heat storage material.

以下に本願での用語の定義を説明する。特記される場合を除き、以下の定義により解釈されるものとする。 The definitions of terms in the present application will be described below. Unless otherwise specified, it shall be construed according to the following definitions.

(1)凝固温度は、液体状態の潜熱蓄熱材が一定温度で保持された際に結晶核を生じ始める温度である。本発明においては、少なくとも50mlの潜熱蓄熱材をポリ瓶に入れた状態で、保冷庫(冷蔵庫、冷凍庫、プログラマブル恒温槽を含む)に配置し、保冷庫の温度を降下させながら熱電対によって計測した値である。液相状態の潜熱蓄熱材を凝固温度以下の温度におくと、潜熱蓄熱材が固相に相変化する間、潜熱蓄熱材は凝固温度の近傍の温度に保たれる。 (1) The solidification temperature is a temperature at which crystal nuclei begin to form when the latent heat storage material in a liquid state is held at a constant temperature. In the present invention, at least 50 ml of latent heat storage material is placed in a cold storage (including a refrigerator, a freezer, and a programmable constant temperature bath) in a plastic bottle, and measured by a thermocouple while lowering the temperature of the cold storage. The value. When the latent heat storage material in the liquid phase state is kept at a temperature equal to or lower than the solidification temperature, the latent heat storage material is maintained at a temperature close to the solidification temperature while the latent heat storage material undergoes a phase change to a solid phase.

(2)融解開始温度は、示差走査熱量測定(DSC)により得られるDSC曲線において、吸熱ピークが始まる温度をベースラインへ外挿して求めた温度である。図2は、DSC曲線の例と融解開始温度および主たる融解温度の求め方を示す概念図である。固相状態の潜熱蓄熱材を融解開始温度以上の温度におくと、潜熱蓄熱材の融解が開始する。 (2) The melting start temperature is a temperature obtained by extrapolating the temperature at which the endothermic peak starts to the baseline in the DSC curve obtained by differential scanning calorimetry (DSC). FIG. 2 is a conceptual diagram showing an example of a DSC curve and how to obtain the melting start temperature and the main melting temperature. When the latent heat storage material in the solid phase state is kept at a temperature equal to or higher than the melting start temperature, the latent heat storage material starts melting.

(3)主たる融解温度は、示差走査熱量測定(DSC)により得られるDSC曲線において、吸熱ピークの温度である。固相状態の潜熱蓄熱材を主たる融解温度以上の温度におくと、潜熱蓄熱材が液相に相変化する間、潜熱蓄熱材は主たる融解温度の近傍の温度に保たれる。 (3) The main melting temperature is the temperature of the endothermic peak in the DSC curve obtained by differential scanning calorimetry (DSC). When the latent heat storage material in the solid phase state is kept at a temperature equal to or higher than the main melting temperature, the latent heat storage material is maintained at a temperature near the main melting temperature while the latent heat storage material undergoes a phase change to the liquid phase.

(4)再生期の温度範囲は、保温具においては潜熱蓄熱材の融解開始温度以上の温度範囲である。また、保冷具においては潜熱蓄熱材の凝固温度以下の温度範囲である。 (4) The temperature range in the regeneration period is a temperature range equal to or higher than the melting start temperature of the latent heat storage material in the heat insulating device. Further, in the cold insulation tool, the temperature range is equal to or lower than the solidification temperature of the latent heat storage material.

(5)潜熱蓄熱材の再生は、保温具においては潜熱蓄熱材を融解開始温度以上の温度におくことで、固相から液相に相変化することである。また、保冷具においては潜熱蓄熱材を凝固温度以下の温度におくことで、液相から固相に相変化することである。 (5) Regeneration of the latent heat storage material is a phase change from a solid phase to a liquid phase by keeping the latent heat storage material at a temperature equal to or higher than the melting start temperature in the heat insulating device. Further, in the cold insulation tool, by keeping the latent heat storage material at a temperature equal to or lower than the solidification temperature, the phase changes from the liquid phase to the solid phase.

本発明者らは、潜熱蓄熱材を有する保温具で保温対象物の温度調節を行なうに際し、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材は、液相から固相に相変化する過程での温度安定性が高いこと、および、このような潜熱蓄熱材を用いて、温度を融解開始温度以上の温度範囲内に制御することで、潜熱蓄熱材を再生させることができることを見出し、本発明に至った。 The present inventors control the temperature of a heat insulating object with a heat insulating device having a latent heat storage material, the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase. The latent heat storage material having a difference of less than 1 ° C. has high temperature stability in the process of changing the phase from the liquid phase to the solid phase, and the temperature is changed to the melting start temperature by using such a latent heat storage material. We have found that the latent heat storage material can be regenerated by controlling it within the above temperature range, and have reached the present invention.

これにより、本発明者らは、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を用いて、保温対象物を温度変化が小さい状態で保温可能とした。また、物流過程において潜熱蓄熱材を再生させることで、保温機能を延長させることを可能とした。以下、本発明の実施形態について、図面を参照しながら具体的に説明する。なお、以下の説明において、保温具および保冷具に関する記述があるが、それらの構造および構成する部材としてはほとんど同一で、保温具としても保冷具としても用いることができる場合があるため、同じ番号100を付して表すこととする。そして、保温を目的とするときは保温具100と、保冷を目的とするときは保冷具100と記載し、目的に応じて適宜読み替えるときは保温具(保冷具)100と記載する。保温具本体および保温具保持部も同様である。また、重複する説明は省略する。 As a result, the present inventors have made it possible to keep the heat-retaining object warm with a small temperature change by using the high temperature stability in the process of the latent heat storage material changing its phase from the liquid phase to the solid phase. In addition, by regenerating the latent heat storage material in the distribution process, it is possible to extend the heat retention function. Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings. In the following description, there is a description about the heat insulating tool and the cold insulation tool, but since their structures and constituent members are almost the same and may be used as both the heat insulating tool and the cold insulation tool, they have the same number. It is represented by adding 100. Then, when the purpose is to keep warm, it is described as a heat insulating device 100, when it is intended to keep cold, it is described as a cold insulating device 100, and when it is appropriately read according to the purpose, it is described as a heat insulating device (cold device) 100. The same applies to the heat insulating device main body and the heat insulating device holding portion. Also, duplicate description will be omitted.

[第1の実施形態]
[保温具の構成]
本発明の保温具は、物流梱包容器に用いられ、保温対象物の温度調節を行なう保温具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備える。図1は、本実施形態に係る保温具100の断面図である。図1に示すように、本実施形態に係る保温具100は、保温具本体110の内部に中空構造の領域である収容部120を有し、収容部120に、蓄熱層130を備える。
[First Embodiment]
[Structure of heat insulator]
The heat insulating device of the present invention is used for a distribution packing container and is a heat insulating device that controls the temperature of an object to be heat-retained. A latent heat storage material having a difference of less than 1 ° C. from the starting melting start temperature and an accommodating portion for accommodating the latent heat storage material are provided. FIG. 1 is a cross-sectional view of the heat insulating device 100 according to the present embodiment. As shown in FIG. 1, the heat insulating device 100 according to the present embodiment has an accommodating portion 120 which is a hollow structure region inside the heat insulating device main body 110, and the accommodating portion 120 includes a heat storage layer 130.

保温具本体110は、蓄熱層130を内包するための中空構造の収容部120を有する。保温具本体110は、ポリエチレン、ポリプロピレン、ポリエステル、ポリウレタン、ポリカーボネート、ポリ塩化ビニル、ポリアミドなどの樹脂材料や、アルミニウム、ステンレス、銅、銀などの金属、ガラス、陶磁器、セラミックなどの無機材料により形成することができる。中空構造の作り易さと、耐久性の観点から樹脂材料であることが好ましい。また、保温具本体110に、温度を示す示温材のシールを貼付すると、保温具の温度が判断可能となるため好ましい。 The heat insulating device main body 110 has a hollow structure accommodating portion 120 for containing the heat storage layer 130. The heat insulating device main body 110 is formed of a resin material such as polyethylene, polypropylene, polyester, polyurethane, polycarbonate, polyvinyl chloride, or polyamide, a metal such as aluminum, stainless steel, copper, or silver, or an inorganic material such as glass, ceramics, or ceramic. be able to. A resin material is preferable from the viewpoint of ease of forming a hollow structure and durability. Further, it is preferable to attach a sticker of a heat insulating material indicating the temperature to the heat insulating device main body 110 because the temperature of the heat insulating device can be determined.

蓄熱層130は、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材150を含む。潜熱蓄熱材150の材料としては、有機分子を主成分とするものが好ましく、これにより過冷却特性が極めて小さく、凝固温度と融解開始温度との差が1℃未満となる。過冷却特性が大きい潜熱蓄熱材を液相から固相への相変化させた場合には、潜熱蓄熱材の温度は凝固温度まで温度降下した後に、結晶生成の発熱により主たる融解温度付近まで昇温する。そのため、潜熱蓄熱材の温度変化が大きく、保温対象物の保持されるべき温度を逸脱する可能性があり温度調節が難しかった。しかし、凝固温度と融解開始温度との差が1℃未満である潜熱蓄熱材を用いた場合には液相から固相への相変化の時の温度変化が極めて小さく、凝固温度近傍にて温度を保持することができる。そのため、保温対象物の保持されるべき温度範囲内にて、確実に保温することができる。 The heat storage layer 130 includes a latent heat storage material 150 in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase begins is less than 1 ° C. The material of the latent heat storage material 150 preferably contains organic molecules as a main component, whereby the supercooling characteristics are extremely small, and the difference between the solidification temperature and the melting start temperature is less than 1 ° C. When a latent heat storage material with large supercooling characteristics is phase-changed from a liquid phase to a solid phase, the temperature of the latent heat storage material drops to the solidification temperature and then rises to near the main melting temperature due to the heat generated by crystal formation. To do. Therefore, the temperature change of the latent heat storage material is large, and the temperature of the heat-retaining object may deviate from the temperature to be held, which makes it difficult to control the temperature. However, when a latent heat storage material in which the difference between the solidification temperature and the melting start temperature is less than 1 ° C. is used, the temperature change at the time of phase change from the liquid phase to the solid phase is extremely small, and the temperature is near the solidification temperature. Can be retained. Therefore, the heat can be reliably maintained within the temperature range in which the heat-retaining object should be held.

潜熱蓄熱材の材料の具体例としては、炭素数13〜30の直鎖アルカン、炭素数13〜20の直鎖アルキルアルコール、分子量400〜800のポリエチレングリコールや炭素数10〜14の直鎖脂肪酸を用いることができる。これらの潜熱蓄熱材は、熱伝導率が低く、液相から固相への相転移する速度が遅いため、凝固温度近傍を長時間保持することができる。また、これらの潜熱蓄熱材は炭素数を1つずつ増減させることで、凝固温度および融解開始温度が精度よく定まる。そのため、炭素数を正しく選択することで厳密な温度管理が可能となる。また、炭素数13〜30の直鎖アルカンの中でも、炭素数15〜24の直鎖アルカンは、潜熱値が高く、チョコレートの保温に適した温度帯(15〜18℃)や、米飯類の保温に適した温度帯(20〜25℃)、精密機器・部品や美術品の保温に適した温度帯(25〜30℃)、血液や臓器の保温に適した温度帯(35〜37℃)に凝固温度を有し、適宜、直鎖アルカンの炭素数を選択することで、厳密な温度管理が可能となる。 Specific examples of the material of the latent heat storage material include linear alkanes having 13 to 30 carbon atoms, linear alkyl alcohols having 13 to 20 carbon atoms, polyethylene glycol having a molecular weight of 400 to 800, and linear fatty acids having 10 to 14 carbon atoms. Can be used. Since these latent heat storage materials have low thermal conductivity and a slow phase transition from the liquid phase to the solid phase, they can maintain the vicinity of the solidification temperature for a long time. Further, by increasing or decreasing the number of carbon atoms of these latent heat storage materials one by one, the solidification temperature and the melting start temperature are accurately determined. Therefore, strict temperature control is possible by selecting the correct number of carbon atoms. Among the linear alkanes having 13 to 30 carbon atoms, the linear alkanes having 15 to 24 carbon atoms have a high latent heat value and are in a temperature range suitable for keeping chocolate warm (15 to 18 ° C.) and keeping rice and rice warm. Suitable temperature range (20 to 25 ° C), suitable temperature range for heat retention of precision equipment / parts and fine arts (25 to 30 ° C), suitable temperature range for heat retention of blood and organs (35 to 37 ° C) Strict temperature control is possible by having a solidification temperature and appropriately selecting the carbon number of the linear alkane.

上記材料は、炭素数により凝固温度が精度よく定まるため、凝固温度が段階的であるが、これらの材料を二つ以上、任意の割合で混合することで凝固温度の調整が可能であり、凝固温度を線形的に変えることができる。また、潜熱蓄熱材として水分子を含有するものは、一般に過冷却特性が大きく用いることは難しいが、過冷却抑制剤を添加することで、凝固温度と融解開始温度との差を1℃未満に制御したものであれば用いることができる。また、本実施形態に係る潜熱蓄熱材は潜熱蓄熱材を液相から固相への相転移を利用するものであり、使用する環境温度により、適切な凝固温度を有する潜熱蓄熱材が選択されることが好ましい。例えば、気温が氷点下の寒冷地での使用を考慮した場合には、保温対象物の保温を目的に0℃以上に凝固温度を有する潜熱蓄熱材を選択する。 Since the solidification temperature of the above materials is accurately determined by the number of carbon atoms, the solidification temperature is stepwise. However, the solidification temperature can be adjusted by mixing two or more of these materials at an arbitrary ratio, and solidification occurs. The temperature can be changed linearly. In addition, it is generally difficult to use a latent heat storage material containing water molecules because of its large supercooling characteristics, but by adding a supercooling inhibitor, the difference between the solidification temperature and the melting start temperature is reduced to less than 1 ° C. Any controlled material can be used. Further, the latent heat storage material according to the present embodiment utilizes the phase transition of the latent heat storage material from the liquid phase to the solid phase, and the latent heat storage material having an appropriate solidification temperature is selected depending on the environmental temperature used. Is preferable. For example, when considering use in a cold region where the air temperature is below freezing, a latent heat storage material having a solidification temperature of 0 ° C. or higher is selected for the purpose of keeping the heat insulating object warm.

また、蓄熱層130を形成する材料に防腐剤や抗菌剤が添加されていることが好ましい。また、蓄熱層130を形成する材料にキサンタンガム、グアガム、カルボキシメチルセルロース、ヒドロキシプロピルセルロース、ポリアクリル酸ナトリウムなどの増粘剤が添加されていてもよい。なお、本発明の材料は、上記の例示した材料に限定されるものではない。 Further, it is preferable that an antiseptic or an antibacterial agent is added to the material forming the heat storage layer 130. Further, a thickener such as xanthan gum, guar gum, carboxymethyl cellulose, hydroxypropyl cellulose or sodium polyacrylate may be added to the material forming the heat storage layer 130. The material of the present invention is not limited to the materials exemplified above.

潜熱蓄熱材150は、保温対象物ごとに定められた保持されるべき温度範囲に応じて選択される。潜熱蓄熱材150は、潜熱蓄熱材150の凝固温度が保温対象物の保持されるべき温度範囲に含まれ、潜熱蓄熱材150の融解開始温度が保温対象物の保持されるべき温度範囲の上限より低くなるように選択される。このように選択することで、温度を制御する時間帯において、制御する温度を再生期の温度範囲と保温対象物の保持されるべき温度範囲とが重複する範囲内の温度にすることができ、潜熱蓄熱材150を固相から液相に相変化させることができ、再生させることができる。また、潜熱蓄熱材150は、潜熱蓄熱材150の主たる融解温度が保温対象物の保持されるべき温度範囲の上限より低くなるように選択されることが好ましい。 The latent heat storage material 150 is selected according to the temperature range to be maintained, which is determined for each heat insulating object. In the latent heat storage material 150, the solidification temperature of the latent heat storage material 150 is included in the temperature range in which the heat retention object should be held, and the melting start temperature of the latent heat storage material 150 is above the upper limit of the temperature range in which the heat retention object should be held. Selected to be low. By selecting in this way, in the time zone for controlling the temperature, the temperature to be controlled can be set to a temperature within a range in which the temperature range in the regeneration period and the temperature range to be held of the heat retention object overlap. The latent heat storage material 150 can be phase-changed from a solid phase to a liquid phase and can be regenerated. Further, the latent heat storage material 150 is preferably selected so that the main melting temperature of the latent heat storage material 150 is lower than the upper limit of the temperature range in which the heat retaining object should be held.

[物流梱包容器の構成]
図3Aは、本実施形態に係る物流梱包容器200の断面図である。物流梱包容器200は、物流梱包容器本体210と、物流梱包容器本体210の内部に設けられ保温具を保持する保温具保持部220と、梱包される物品の保持されるべき温度範囲に応じて選択された保温具100と、物流梱包容器本体210の内部に設けられ物品を収容する物品収容部230とを備える。
[Structure of logistics packing container]
FIG. 3A is a cross-sectional view of the distribution packing container 200 according to the present embodiment. The distribution packing container 200 is selected according to the distribution packing container main body 210, the heat insulating device holding unit 220 provided inside the distribution packing container main body 210 and holding the heat insulating device, and the temperature range in which the goods to be packed should be held. The heat insulating device 100 is provided, and an article accommodating portion 230 provided inside the distribution packing container main body 210 for accommodating articles is provided.

物流梱包容器本体210は、収容部240および蓋部250により構成される。収容部240は、物品および保温具100を出し入れする開口部を有し、蓋部250は、開口部を閉塞する。収容部240および蓋部250は、連結されていてもよいし、分離されていてもよい。物流梱包容器200の内部との熱の出入りを低減するために、蓋部250は収容部240と密着する構造であることが好ましい。 The distribution packing container main body 210 is composed of a storage portion 240 and a lid portion 250. The accommodating portion 240 has an opening for inserting and removing the article and the heat insulating device 100, and the lid portion 250 closes the opening. The accommodating portion 240 and the lid portion 250 may be connected or separated. In order to reduce the inflow and outflow of heat from the inside of the distribution packing container 200, it is preferable that the lid portion 250 has a structure in close contact with the storage portion 240.

物流梱包容器本体210は、発泡スチロール、発泡ウレタン、真空断熱材などの断熱性を有する材料で形成されていることが好ましい。断熱性を考慮しない材料で形成された本体の内側や外側に、断熱性を有する材料で形成された断熱層を設けてもよい。また、物流梱包容器本体210は、人が持ち運びできる大きさであってもよいし、例えば、コンテナなどの巨大な容器が物流梱包容器本体210としての機能を有していてもよい。また、コンテナに加熱機構が備わっていてもよい。 The distribution packing container main body 210 is preferably formed of a heat insulating material such as styrofoam, urethane foam, or a vacuum heat insulating material. A heat insulating layer made of a material having heat insulating properties may be provided inside or outside the main body made of a material not considering heat insulating properties. Further, the distribution packing container main body 210 may have a size that can be carried by a person, or for example, a huge container such as a container may have a function as the distribution packing container main body 210. Further, the container may be provided with a heating mechanism.

保温具保持部220は、物流梱包容器本体210の内部に設けられる。物流梱包容器200は、保温具保持部220に保温具100を載置することにより用いられる。これにより、物流梱包容器本体210の内部が、保温具100に応じた温度に保持される。保温具保持部220は、保温具100の固定が可能な構造となっていてもよい。また、保温具100が、物流梱包容器本体210に内蔵されていてもよいし、保温具100自体が、物流梱包容器200となっていてもよい。 The heat insulating device holding portion 220 is provided inside the distribution packing container main body 210. The distribution packing container 200 is used by placing the heat insulating device 100 on the heat insulating device holding unit 220. As a result, the inside of the distribution packing container main body 210 is maintained at a temperature corresponding to the heat insulating device 100. The heat insulating device holding portion 220 may have a structure capable of fixing the heat insulating device 100. Further, the heat insulating device 100 may be built in the distribution packing container main body 210, or the heat insulating device 100 itself may be the distribution packing container 200.

物流梱包容器200に用いられる保温具100は、梱包される物品の保持されるべき温度範囲に応じて選択される。保温具100は、保温具100に用いられる潜熱蓄熱材150の凝固温度が物品の保持されるべき温度範囲に含まれ、融解開始温度が物品の保持されるべき温度範囲の上限より低くなるような潜熱蓄熱材150を用いた保温具100が選択される。このように選択することで、物流過程で温度を制御する時間帯において、制御する温度を再生期の温度範囲と保温対象物の保持されるべき温度範囲とが重複する範囲内の温度にすることができる。その結果、潜熱蓄熱材150を固相から液相に相変化させることができ、再生させることができる。これにより、保温機能の延長ができる。 The heat insulating device 100 used in the distribution packing container 200 is selected according to the temperature range in which the goods to be packed are to be held. In the heat insulating device 100, the solidification temperature of the latent heat storage material 150 used in the heat insulating device 100 is included in the temperature range in which the article should be held, and the melting start temperature is lower than the upper limit of the temperature range in which the article should be held. A heat insulating device 100 using the latent heat storage material 150 is selected. By selecting in this way, in the time zone in which the temperature is controlled in the distribution process, the temperature to be controlled is set to a temperature within the range where the temperature range in the regeneration period and the temperature range to be maintained of the heat insulating object overlap. Can be done. As a result, the latent heat storage material 150 can be phase-changed from a solid phase to a liquid phase and can be regenerated. As a result, the heat retention function can be extended.

また、保温具100は、上記のような温度範囲を有する潜熱蓄熱材150を用いたものを選択する際、さらに、物流に用いられる一般的な加熱装置(加温(保温)車、加温(保温)倉庫)で通常設定される制御温度(設定温度)が、再生期の温度範囲と物品の保持されるべき温度範囲とが重複する範囲に含まれるように選択されることが好ましい。このように選択することで、一般的な設定温度の加熱装置を用いた物流過程で物流梱包容器200を用いた物流を行なうことができ、輸送ルートを柔軟に設定することができる。 Further, when selecting a heat insulating device 100 using the latent heat storage material 150 having the above temperature range, a general heating device (warming (heat retaining) car, heating (warming (heat retaining) car, heating (warming)) used for physical distribution is further selected. It is preferable that the control temperature (set temperature) normally set in the heat storage) warehouse) is selected so as to be included in a range in which the temperature range in the regeneration period and the temperature range in which the article should be held overlap. By selecting in this way, it is possible to carry out physical distribution using the physical distribution packing container 200 in the physical distribution process using a heating device having a general set temperature, and it is possible to flexibly set the transportation route.

物品収容部230は、物流梱包容器本体210の内部に設けられ、保持されるべき温度範囲が定められた物品が収容される。これにより、物品が保持されるべき温度範囲の温度に保持される。 The article storage unit 230 is provided inside the distribution packing container main body 210, and stores articles having a temperature range to be held. This keeps the article in a temperature range that should be held.

物流梱包容器200は、図3Bに示すように、複数の保温具100が配置されていてもよい。 As shown in FIG. 3B, a plurality of heat insulating devices 100 may be arranged in the distribution packing container 200.

[第2の実施形態]
本実施形態は、保冷具に関するものである。本発明者らは、潜熱蓄熱材を有する保冷具で保冷対象物の温度調節を行なうに際し、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材は、液相から固相に相変化する過程での温度安定性が高いこと、および、このような潜熱蓄熱材を用いて、温度を凝固温度以下の温度範囲内に制御することで、潜熱蓄熱材を再生させることができることを見出し、本発明に至った。
[Second Embodiment]
The present embodiment relates to a cold insulation device. The present inventors have set the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase when the temperature of the object to be kept cold is controlled by a cold insulation device having a latent heat storage material. The latent heat storage material having a difference of less than 1 ° C. has high temperature stability in the process of phase change from the liquid phase to the solid phase, and the temperature is kept below the solidification temperature by using such a latent heat storage material. We have found that the latent heat storage material can be regenerated by controlling it within the temperature range of the above, and have reached the present invention.

これにより、本発明者らは、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を用いて、液体状態になった潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷可能とした。また、物流過程において潜熱蓄熱材を再生させることで、保冷機能を延長させることを可能とした。以下、本発明の実施形態について、図面を参照しながら具体的に説明する。 As a result, the present inventors use the high temperature stability in the process of changing the phase of the latent heat storage material from the liquid phase to the solid phase to regenerate the latent heat storage material in a liquid state. Can be kept cold with a small temperature change. In addition, by regenerating the latent heat storage material in the distribution process, it is possible to extend the cold insulation function. Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings.

[保冷具の構成]
本発明の保冷具は、物流梱包容器に用いられ、保冷対象物の温度調節を行なう保冷具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備える。本実施形態に係る保冷具および保冷具本体は、第1の実施形態に係る保温具および保温具本体と同様の構成であるため、重複する部分の説明は省略する。本実施形態に係る保冷具100は、保冷具本体110の内部に中空構造の領域である収容部120を有し、収容部120に、蓄熱層130を備える。
[Composition of cold storage device]
The cold insulation tool of the present invention is used for a distribution packing container and is a cold storage device that controls the temperature of an object to be kept cold. A latent heat storage material having a difference of less than 1 ° C. from the starting melting start temperature and an accommodating portion for accommodating the latent heat storage material are provided. Since the cold insulation device and the cold insulation device main body according to the present embodiment have the same configuration as the heat insulation device and the heat insulation device main body according to the first embodiment, the description of the overlapping portion will be omitted. The cold storage device 100 according to the present embodiment has a storage unit 120 which is a hollow structure region inside the cold storage tool main body 110, and the storage unit 120 includes a heat storage layer 130.

蓄熱層130は、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材150を含む。潜熱蓄熱材150の材料としては、有機分子を主成分とするものが好ましく、これにより過冷却特性が極めて小さく、凝固温度と融解開始温度との差が1℃未満となる。具体的には、炭素数13〜30の直鎖アルカン、炭素数13〜20の直鎖アルキルアルコール、分子量400〜800のポリエチレングリコールや炭素数10〜14の直鎖脂肪酸を用いることができる。また、炭素数14〜16の直鎖アルカンであるテトラデカン、ペンタデカン、ヘキサデカンは、潜熱値が高く、チルド温度帯(2〜8℃)、青果品の保存に適した温度帯(8〜15℃)に主たる融解温度もしくは凝固温度を有しているため有用性が高く好ましい。 The heat storage layer 130 includes a latent heat storage material 150 in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase begins is less than 1 ° C. The material of the latent heat storage material 150 preferably contains organic molecules as a main component, whereby the supercooling characteristics are extremely small, and the difference between the solidification temperature and the melting start temperature is less than 1 ° C. Specifically, a linear alkane having 13 to 30 carbon atoms, a linear alkyl alcohol having 13 to 20 carbon atoms, polyethylene glycol having a molecular weight of 400 to 800, and a linear fatty acid having 10 to 14 carbon atoms can be used. In addition, tetradecane, pentadecane, and hexadecane, which are linear alkanes having 14 to 16 carbon atoms, have a high latent heat value and are in a chilled temperature range (2 to 8 ° C.) and a temperature range suitable for storing fruits and vegetables (8 to 15 ° C.). It is highly useful and preferable because it has a main melting temperature or solidification temperature.

また、これら材料が任意の割合で混合されていてもよく、混合することで主な融解開始温度や凝固温度を調整することが可能となる。また、潜熱蓄熱材として水分子を含有するものは、一般に過冷却特性が大きく用いることは難しいが、過冷却抑制剤を添加することで、凝固温度と融解開始温度との差を1℃未満に制御したものであれば用いることができる。本発明の潜熱蓄熱材は、液相から固相に相変化する過程での温度変化が小さいため、潜熱蓄熱材による保冷時に潜熱をすべて使い果たし、液体状態になったとしても、潜熱蓄熱材を再生させる際に、保冷対象物の温度変化が小さくなる。一般に、過冷却特性を有する潜熱蓄熱材は、固相と液相が共存する状態から再生させる場合には、融解開始温度よりも低い温度であれば、固相を核成長点として凝固が進むため、温度変化が小さい。しかし、完全な液体状態から再生させる場合には、凝固温度まで低下させなければ凝固が起こらないため、温度変化が大きい。そのため、過冷却特性を有する潜熱蓄熱材を用いて保冷および再生する場合には、完全に融解させないように、保冷時間に見合った潜熱蓄熱材の量よりも増量して用いる。しかし、本発明の潜熱蓄熱材を用いた場合には、完全に液体状態になったとしても、温度変化が小さく再生することができるため、潜熱蓄熱材による保冷時に本来の潜熱量をすべて使用することができる。その結果、物流梱包容器に収容する潜熱蓄熱材の量を減らすことができる。なお、本発明の材料は、上記の例示した材料に限定されるものではない。 Further, these materials may be mixed in an arbitrary ratio, and by mixing, it becomes possible to adjust the main melting start temperature and solidification temperature. In addition, it is generally difficult to use a latent heat storage material containing water molecules because of its large supercooling characteristics, but by adding a supercooling inhibitor, the difference between the solidification temperature and the melting start temperature is reduced to less than 1 ° C. Any controlled material can be used. Since the latent heat storage material of the present invention has a small temperature change in the process of changing the phase from the liquid phase to the solid phase, all the latent heat is exhausted during cold insulation by the latent heat storage material, and even if the latent heat storage material becomes liquid, the latent heat storage material is regenerated. The temperature change of the object to be kept cold becomes small. Generally, when a latent heat storage material having supercooling characteristics is regenerated from a state in which a solid phase and a liquid phase coexist, solidification proceeds with the solid phase as a nuclear growth point if the temperature is lower than the melting start temperature. , The temperature change is small. However, when regenerating from a completely liquid state, solidification does not occur unless the temperature is lowered to the solidification temperature, so that the temperature change is large. Therefore, when the latent heat storage material having supercooling characteristics is used for cold insulation and regeneration, the amount is increased more than the amount of the latent heat storage material commensurate with the cold insulation time so as not to completely melt. However, when the latent heat storage material of the present invention is used, even if it is completely in a liquid state, the temperature change can be small and the heat can be regenerated. Therefore, all the original latent heat amount is used when the latent heat storage material keeps cold. be able to. As a result, the amount of latent heat storage material contained in the distribution packing container can be reduced. The material of the present invention is not limited to the materials exemplified above.

潜熱蓄熱材150は、保冷対象物ごとに定められた保持されるべき温度範囲に応じて選択されている。潜熱蓄熱材150は、潜熱蓄熱材150の主たる融解温度が保冷対象物の保持されるべき温度範囲に含まれ、潜熱蓄熱材150の凝固温度が保冷対象物の保持されるべき温度範囲の下限より高くなるように選択される。このように選択することで、温度を制御する時間帯において、制御する温度を再生期の温度範囲と保冷対象物の保持されるべき温度範囲とが重複する範囲内の温度にすることができ、潜熱蓄熱材150を液相から固相に相変化させることができ、再生させることができる。また、保冷時に潜熱をすべて使い果たし、液体状態になったとしても、潜熱蓄熱材150を再生させる際に、保冷対象物を温度変化が小さい状態で保冷することができるため、保冷対象物の保持されるべき温度範囲を逸脱する虞が少なくなる。 The latent heat storage material 150 is selected according to the temperature range to be maintained, which is determined for each cold insulation object. In the latent heat storage material 150, the main melting temperature of the latent heat storage material 150 is included in the temperature range in which the cold insulation object should be held, and the solidification temperature of the latent heat storage material 150 is from the lower limit of the temperature range in which the cold insulation object should be held. Selected to be higher. By selecting in this way, in the time zone for controlling the temperature, the temperature to be controlled can be set to a temperature within a range in which the temperature range of the regeneration period and the temperature range of the object to be kept cold overlap. The latent heat storage material 150 can be phase-changed from a liquid phase to a solid phase and can be regenerated. Further, even if all the latent heat is exhausted during cold storage and the latent heat storage material 150 is regenerated, the cold storage object can be kept cold in a state where the temperature change is small, so that the cold storage object is retained. There is less risk of deviation from the desired temperature range.

[物流梱包容器の構成]
本実施形態に係る物流梱包容器200は、図3Aおよび図3Bに示す第1の実施形態に係る物流梱包容器の断面図の中で、保温具100を保冷具100に置き換えることで適用することができる。物流梱包容器200は、物流梱包容器本体210と、物流梱包容器本体210の内部に設けられ保冷具100を保持する保冷具保持部220と、梱包される物品の保持されるべき温度範囲に応じて選択された保冷具100と、物流梱包容器本体210の内部に設けられ物品を収容する物品収容部230とを備える。
[Structure of logistics packing container]
The distribution packing container 200 according to the present embodiment can be applied by replacing the heat insulating device 100 with the cold insulating tool 100 in the cross-sectional view of the distribution packing container according to the first embodiment shown in FIGS. 3A and 3B. it can. The distribution packing container 200 is provided according to the distribution packing container main body 210, the cold storage device holding portion 220 provided inside the distribution packing container main body 210 and holding the cold storage tool 100, and the temperature range in which the goods to be packed should be held. The selected cold storage device 100 and an article accommodating portion 230 provided inside the distribution packing container main body 210 for accommodating articles are provided.

物流梱包容器本体210は、人が持ち運びできる大きさであってもよいし、例えば、コンテナなどの巨大な容器が物流梱包容器本体210としての機能を有していてもよい。また、物流梱包容器200はリーファーコンテナのように冷却装置を備えた容器であっても構わない。リーファーコンテナは、物品を大量に収容することが可能であり、輸送時の電源供給が可能な期間は保冷庫として機能することができる。そのため、物品の輸送に長時間が必要となる輸出入に用いることが好ましい。従来のリーファーコンテナは、例えば税関での検閲時などの無電源期間では、物品の温度を保持することが困難となり、物品の鮮度や品質の劣化が問題であった。しかし、本発明の物流梱包容器200としてリーファーコンテナを用いた場合には、荷送人が本発明の保冷具100と物品をリーファーコンテナに収容することで、電源供給時は本発明の保冷具100は再生期となり、無電源期間は保冷具100の潜熱蓄熱材150が活動し、物品の温度を保持されるべき温度範囲に維持することが可能となる。そのため、例えばワインや、チョコレート、果物などの保持されるべき温度範囲を逸脱すると鮮度や品質の劣化が著しい物品を長時間にわたって輸出入することや、柔軟な輸送ルートを設定することが可能となる。 The distribution packing container main body 210 may have a size that can be carried by a person, or for example, a huge container such as a container may have a function as the distribution packing container main body 210. Further, the distribution packing container 200 may be a container provided with a cooling device such as a reefer container. The reefer container can store a large amount of goods and can function as a cold storage during a period during which power can be supplied during transportation. Therefore, it is preferable to use it for import / export, which requires a long time for transporting goods. In the conventional reefer container, it is difficult to maintain the temperature of the article during a non-power supply period such as during censorship at customs, and there is a problem of deterioration of the freshness and quality of the article. However, when the reefer container is used as the distribution packing container 200 of the present invention, the shipper accommodates the cold storage device 100 of the present invention and the article in the reefer container, so that the cold storage device 100 of the present invention is supplied when power is supplied. Is the regeneration period, and the latent heat storage material 150 of the cold insulation tool 100 is active during the non-power supply period, and the temperature of the article can be maintained in the temperature range in which it should be maintained. Therefore, for example, it is possible to import / export goods whose freshness and quality are significantly deteriorated when they deviate from the temperature range to be maintained, such as wine, chocolate, and fruits, and to set a flexible transportation route. ..

物流梱包容器200に用いられる保冷具100は、梱包される物品の保持されるべき温度範囲に応じて選択される。保冷具100は、保冷具100に用いられる潜熱蓄熱材150の主たる融解温度が物品の保持されるべき温度範囲に含まれ、凝固温度が物品の保持されるべき温度範囲の下限より高くなるような潜熱蓄熱材150を用いた保冷具100が選択される。このように選択することで、物流過程で温度を制御する時間帯において、制御する温度を再生期の温度範囲と保冷対象物の保持されるべき温度範囲とが重複する範囲内の温度にすることができる。その結果、潜熱蓄熱材150を液相から固相に相変化させることができ、再生させることができる。これにより、保冷機能の延長ができる。また、保冷時に潜熱をすべて使い果たし、液体状態になったとしても、潜熱蓄熱材150を再生させる際に、保冷対象物を温度変化が小さい状態で保冷することができるため、保冷対象物の保持されるべき温度範囲を逸脱する虞が少なくなる。 The cooler 100 used in the distribution packing container 200 is selected according to the temperature range in which the goods to be packed are to be held. In the cold insulator 100, the main melting temperature of the latent heat storage material 150 used in the cold insulator 100 is included in the temperature range in which the article should be held, and the solidification temperature is higher than the lower limit of the temperature range in which the article should be held. The cold insulation tool 100 using the latent heat storage material 150 is selected. By selecting in this way, in the time zone in which the temperature is controlled in the distribution process, the temperature to be controlled is set to a temperature within the range where the temperature range in the regeneration period and the temperature range to be maintained of the object to be kept cold overlap. Can be done. As a result, the latent heat storage material 150 can be phase-changed from a liquid phase to a solid phase and can be regenerated. As a result, the cold insulation function can be extended. Further, even if all the latent heat is exhausted during cold storage and the latent heat storage material 150 is regenerated, the cold storage object can be kept cold in a state where the temperature change is small, so that the cold storage object is retained. There is less risk of deviation from the desired temperature range.

また、保冷具100は、上記のような温度範囲を有する潜熱蓄熱材150を用いたものを選択する際、さらに、物流に用いられる一般的な冷却装置(冷蔵(冷凍)車、冷蔵(冷凍)倉庫、冷蔵(冷凍)ロッカー、リーファーコンテナなど)で通常設定される冷蔵温度や冷凍温度などの制御温度(設定温度)が、再生期の温度範囲と物品の保持されるべき温度範囲とが重複する範囲に含まれるように選択されることが好ましい。このように選択することで、一般的な設定温度の冷却装置を用いた物流過程で物流梱包容器200を用いた物流を行なうことができ、輸送ルートを柔軟に設定することができる。 Further, when selecting a refrigerating tool 100 using the latent heat storage material 150 having the above temperature range, a general cooling device (refrigerating (freezing) car, refrigerating (freezing)) used for distribution is further selected. The control temperature (set temperature) such as the refrigerating temperature and freezing temperature normally set in a warehouse, refrigerating (freezing) rocker, reefer container, etc. overlaps with the temperature range during the regeneration period and the temperature range in which the article should be held. It is preferably selected to be included in the range. By selecting in this way, it is possible to carry out the physical distribution using the physical distribution packing container 200 in the physical distribution process using the cooling device having a general set temperature, and it is possible to flexibly set the transportation route.

図4は、本実施形態に係る保冷具100および物流梱包容器200の使用状態を示す概念図である。図4のように、本実施形態に係る保冷具100および物流梱包容器200は、物品および保冷具100が、物流梱包容器200に梱包された状態で使用される。第1の実施形態に係る保温具100および物流梱包容器200も同様である。 FIG. 4 is a conceptual diagram showing a usage state of the cold storage device 100 and the distribution packing container 200 according to the present embodiment. As shown in FIG. 4, the cold storage device 100 and the distribution packing container 200 according to the present embodiment are used in a state where the article and the cold storage container 100 are packed in the distribution packing container 200. The same applies to the heat insulating device 100 and the distribution packing container 200 according to the first embodiment.

[第3の実施形態]
[物流システムの構成]
本実施形態に係る物流システムは、保温具として、液相から固相への相変化を利用した潜熱蓄熱材を用いた場合には、保持されるべき温度範囲が定められた物品が、保温具100と共に物流梱包容器200に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、温度が制御されない時間帯の前後の少なくとも一方で、物流梱包容器200の外部の温度を物品の保持されるべき温度範囲に制御する加熱装置を備え、加熱装置が、保温具100に用いられた潜熱蓄熱材150の再生期の温度範囲と物品の保持されるべき温度範囲との重複範囲で物流梱包容器200を加熱する。
[Third Embodiment]
[Logistics system configuration]
In the distribution system according to the present embodiment, when a latent heat storage material utilizing a phase change from a liquid phase to a solid phase is used as a heat insulating tool, an article having a defined temperature range to be maintained is a heat insulating tool. A distribution system that is packed together with 100 in a distribution packaging container 200 and delivered from the shipper to the consignee by the carrier, at least before and after a time when the temperature is not controlled, the temperature outside the distribution packaging container 200. A heating device for controlling the temperature range of the article to be held is provided, and the heating device overlaps the temperature range of the latent heat storage material 150 used in the heat insulating device 100 during the regeneration period with the temperature range of the article to be held. Heats the distribution packing container 200 with.

また、本実施形態に係る物流システムは、保冷具として、固相から液相への相変化を利用した潜熱蓄熱材を用いた場合には、保持されるべき温度範囲が定められた物品が、保冷具100と共に物流梱包容器200に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、温度が制御されない時間帯の前後の少なくとも一方で、物流梱包容器200の外部の温度を物品の保持されるべき温度範囲に制御する冷却装置を備え、冷却装置が、保冷具100に用いられた潜熱蓄熱材150の再生期の温度範囲と物品の保持されるべき温度範囲との重複範囲で物流梱包容器200を冷却する。 Further, in the distribution system according to the present embodiment, when a latent heat storage material utilizing a phase change from a solid phase to a liquid phase is used as a cold insulation tool, an article in which a temperature range to be maintained is defined. A distribution system that is packed in a distribution packing container 200 together with a cold insulator 100 and delivered from a shipper to a consignee by a carrier, at least before and after a time when temperature is not controlled, outside the distribution packing container 200. A cooling device for controlling the temperature to a temperature range in which the article should be held is provided, and the cooling device has a temperature range of the latent heat storage material 150 used in the cold insulator 100 during the regeneration period and a temperature range in which the article should be held. The distribution packing container 200 is cooled in the overlapping range.

図5Aは、本実施形態に係る物流システムに用いられる潜熱蓄熱材150と、物品の保持されるべき温度範囲に対して、加熱装置で温度を制御する際の温度範囲を示した概念図である。図5Aは、潜熱蓄熱材150の凝固温度が物品の保持されるべき温度範囲に含まれ、融解開始温度が物品の保持されるべき温度範囲の上限より低くなるように選択された場合を示している。図5Aに示す場合は、加熱装置で温度を制御する際の温度範囲は、物品の保持されるべき温度範囲の上限よりも低く潜熱蓄熱材150の融解開始温度よりも高くすることができる。このような温度範囲で温度を制御することで、潜熱蓄熱材150を再生させることができ、物品の保温機能を延長させることができる。 FIG. 5A is a conceptual diagram showing the latent heat storage material 150 used in the distribution system according to the present embodiment and the temperature range when the temperature is controlled by the heating device with respect to the temperature range in which the article should be held. .. FIG. 5A shows the case where the solidification temperature of the latent heat storage material 150 is included in the temperature range in which the article should be held, and the melting start temperature is selected to be lower than the upper limit of the temperature range in which the article should be held. There is. In the case shown in FIG. 5A, the temperature range when the temperature is controlled by the heating device can be lower than the upper limit of the temperature range in which the article should be held and higher than the melting start temperature of the latent heat storage material 150. By controlling the temperature in such a temperature range, the latent heat storage material 150 can be regenerated, and the heat retention function of the article can be extended.

なお、凝固温度と融解開始温度の差が大きい、即ち、過冷却特性が大きい場合には、液相から固相に相転移するときに、潜熱蓄熱材の温度は、凝固温度まで温度が降下した後に、融解開始温度まで温度が上昇する。そのため、温度変化が大きく保持されるべき温度範囲を逸脱する恐れがあり、液相から固相への相転移を利用することは困難であった。しかし、本発明のように凝固温度と融解開始温度との差が1℃未満と小さい場合には、潜熱蓄熱材の温度変化が小さいため、液相から固相への相変化を利用することが可能である。これにより、物品の保持されるべき温度が環境温度(外気温)よりも高い場合に物品を保温することが可能となる。 When the difference between the solidification temperature and the melting start temperature is large, that is, when the supercooling characteristic is large, the temperature of the latent heat storage material drops to the solidification temperature when the phase transitions from the liquid phase to the solid phase. Later, the temperature rises to the melting start temperature. Therefore, there is a possibility that the temperature change deviates from the temperature range in which a large temperature change should be maintained, and it is difficult to utilize the phase transition from the liquid phase to the solid phase. However, when the difference between the solidification temperature and the melting start temperature is as small as less than 1 ° C. as in the present invention, the temperature change of the latent heat storage material is small, so that the phase change from the liquid phase to the solid phase can be utilized. It is possible. This makes it possible to keep the article warm when the temperature at which the article should be held is higher than the ambient temperature (outside air temperature).

図5Bは、本実施形態に係る物流システムに用いられる潜熱蓄熱材150と、物品の保持されるべき温度範囲に対して、冷却装置で温度を制御する際の温度範囲を示した概念図である。図5Bは、潜熱蓄熱材150の主たる融解温度が物品の保持されるべき温度範囲に含まれ、凝固温度が物品の保持されるべき温度範囲の下限より高くなるように選択された場合を示している。図5Bに示す場合は、冷却装置で温度を制御する際の温度範囲は、物品の保持されるべき温度範囲の下限よりも高く潜熱蓄熱材150の凝固温度よりも低くすることができる。このような温度範囲で温度を制御することで、潜熱蓄熱材150を再生させることができ、冷却機能を延長させることができる。また、保冷時に潜熱をすべて使い果たし、液体状態になったとしても、潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷することができるため、保冷対象物の保持されるべき温度範囲を逸脱する虞が少なくなる。 FIG. 5B is a conceptual diagram showing the latent heat storage material 150 used in the distribution system according to the present embodiment and the temperature range when the temperature is controlled by the cooling device with respect to the temperature range in which the article should be held. .. FIG. 5B shows the case where the main melting temperature of the latent heat storage material 150 is included in the temperature range in which the article should be held, and the solidification temperature is selected to be higher than the lower limit of the temperature range in which the article should be held. There is. In the case shown in FIG. 5B, the temperature range when the temperature is controlled by the cooling device can be higher than the lower limit of the temperature range to be held by the article and lower than the solidification temperature of the latent heat storage material 150. By controlling the temperature in such a temperature range, the latent heat storage material 150 can be regenerated and the cooling function can be extended. Further, even if all the latent heat is exhausted during cold storage and the latent heat storage material is regenerated, the cold storage object can be kept cold with a small temperature change, so that the cold storage object is retained. There is less risk of deviation from the expected temperature range.

なお、凝固温度と融解開始温度が1℃未満と小さく、相変化の温度変化が小さいため、チョコレート(保持されるべき温度範囲:15〜18℃)やいちご(保持されるべき温度範囲:1〜2℃)などの果実のように保持されるべき温度範囲が狭い物品を輸送する場合でも、確実に保冷および再生することができる。また、物品の保持されるべき温度範囲と再生期とが重複する温度範囲が広くなるため、冷却装置の厳密な温度制御が不要であることや、冷却装置の制御する温度範囲の上限を凝固温度付近まで上昇しても再生することができるため、冷却装置のコスト削減や省エネルギー化に繋がる。 Since the solidification temperature and the melting start temperature are as small as less than 1 ° C and the temperature change of the phase change is small, chocolate (temperature range to be retained: 15-18 ° C) and strawberry (temperature range to be retained: 1 to 1). Even when transporting an article having a narrow temperature range to be maintained, such as a fruit (2 ° C.), it can be reliably cooled and regenerated. In addition, since the temperature range in which the article should be held and the regeneration period overlap is widened, strict temperature control of the cooling device is not required, and the upper limit of the temperature range controlled by the cooling device is the solidification temperature. Since it can be regenerated even if it rises to the vicinity, it leads to cost reduction and energy saving of the cooling device.

加熱装置または冷却装置で温度を制御する時間や回数のうち、一部のみが重複範囲で制御することとなっていてもよい。その場合でも、重複範囲で温度を制御するときには、潜熱蓄熱材150を再生させることができ、保温機能または保冷機能を延長させることができるからである。 Of the time and number of times the temperature is controlled by the heating device or the cooling device, only a part may be controlled within the overlapping range. Even in that case, when the temperature is controlled in the overlapping range, the latent heat storage material 150 can be regenerated, and the heat retention function or the cold retention function can be extended.

図5Cは、従来の蓄熱材を用いた物流システムの温度範囲を示した概念図である。図5Cに示すように、従来の蓄熱材を用いた物流システムでは、物品の保持されるべき温度範囲に対して、蓄熱材の保持可能な温度範囲や仲介拠点での制御温度については考慮されていたが、蓄熱材と仲介拠点での制御温度の関係については考慮されてはいない。 FIG. 5C is a conceptual diagram showing a temperature range of a distribution system using a conventional heat storage material. As shown in FIG. 5C, in the conventional distribution system using the heat storage material, the temperature range in which the heat storage material can be held and the control temperature at the brokerage base are taken into consideration with respect to the temperature range in which the article should be held. However, the relationship between the heat storage material and the control temperature at the intermediary base is not considered.

上記物流システムにおいて、保温具100に用いられる潜熱蓄熱材150は、融解開始温度が物品の保持されるべき温度範囲の上限より低くなるように選択されるが、主たる融解温度も物品の保持されるべき温度範囲の上限より低くなるように選択された場合は、環境温度に応じて保温具100を保冷具100としても用いることができる。 In the above distribution system, the latent heat storage material 150 used in the heat insulating device 100 is selected so that the melting start temperature is lower than the upper limit of the temperature range in which the article should be held, but the main melting temperature is also held in the article. When selected to be lower than the upper limit of the power temperature range, the heat insulator 100 can also be used as the cold insulator 100 depending on the ambient temperature.

具体的には、次のような例を考えることができる。例えば、チョコレートの保温に適した温度帯(15〜18℃)において、潜熱蓄熱材150の凝固温度が16℃、融解開始温度が16℃、主たる融解温度が17℃に制御されている場合を考える。このとき、環境温度が15℃以下であれば、潜熱蓄熱材150を16〜18℃で液相にして保温具100として用いることができる。一方、環境温度が18℃以上であれば、潜熱蓄熱材150を15〜16℃で固相にして保冷具100として用いることができる。加熱装置および冷却装置も目的に応じて変更する。 Specifically, the following example can be considered. For example, consider a case where the solidification temperature of the latent heat storage material 150 is controlled to 16 ° C., the melting start temperature is controlled to 16 ° C., and the main melting temperature is controlled to 17 ° C. in a temperature range (15 to 18 ° C.) suitable for keeping chocolate warm. .. At this time, if the environmental temperature is 15 ° C. or lower, the latent heat storage material 150 can be used as the heat insulating tool 100 in a liquid phase at 16 to 18 ° C. On the other hand, when the environmental temperature is 18 ° C. or higher, the latent heat storage material 150 can be solid-phased at 15 to 16 ° C. and used as the cold insulation tool 100. The heating device and cooling device are also changed according to the purpose.

[保温具および保冷具の製造方法]
次に、本実施形態に係る保温具(保冷具)100の製造方法について説明する。図6A〜図6Cは、本実施形態に係る保温具100の製造の工程を示す概念図である。まず、図6Aに示すような、中空構造の領域を有する保温具本体(保冷具本体)110を準備する。保温具本体110は、潜熱蓄熱材150を注入できる注入口170が付いていることが好ましい。次に、潜熱蓄熱材150を注入する。注入方法は問わないが、シリンダーポンプやモーノポンプを用いた注入方法が好ましい。図6Bはシリンダーポンプを用いた例を示す。図6Bに示すように、シリンダーポンプの充填ホースを保温具本体110の注入口170にセットし、吸上げホースを潜熱蓄熱材150の入った容器にセットする。次に、シリンダーポンプのピストンを下降することにより潜熱蓄熱材150を吸上げ、ピストン内に蓄熱材を充填した後に、ピストンを上昇させることで保温具本体110に潜熱蓄熱材150を注入する。
[Manufacturing method of heat insulator and cold insulator]
Next, a method of manufacturing the heat insulating device (cold insulating device) 100 according to the present embodiment will be described. 6A to 6C are conceptual diagrams showing a process of manufacturing the heat insulating device 100 according to the present embodiment. First, a heat insulating device main body (cooling device main body) 110 having a hollow structure region as shown in FIG. 6A is prepared. The heat insulating device main body 110 preferably has an injection port 170 capable of injecting the latent heat storage material 150. Next, the latent heat storage material 150 is injected. The injection method is not limited, but an injection method using a cylinder pump or a mono pump is preferable. FIG. 6B shows an example using a cylinder pump. As shown in FIG. 6B, the filling hose of the cylinder pump is set in the injection port 170 of the heat insulating device main body 110, and the suction hose is set in the container containing the latent heat storage material 150. Next, the latent heat storage material 150 is sucked up by lowering the piston of the cylinder pump, the heat storage material is filled in the piston, and then the latent heat storage material 150 is injected into the heat insulating device main body 110 by raising the piston.

そして、図6Cに示すように、保温具本体110の注入口170に栓190をする。栓190をする方法としては、超音波溶着や熱溶着などの既存の手法で密栓する方法や、ネジ栓としておき、手で自由に開閉できる栓とする方法がある。超音波溶着や熱溶着などで密栓する場合は、潜熱蓄熱材150などが漏れる虞がなく好ましい。 Then, as shown in FIG. 6C, a stopper 190 is attached to the injection port 170 of the heat insulating device main body 110. As a method of plugging 190, there are a method of sealing by an existing method such as ultrasonic welding or heat welding, and a method of setting as a screw plug and making it a plug that can be freely opened and closed by hand. When the plug is sealed by ultrasonic welding or heat welding, there is no risk of the latent heat storage material 150 or the like leaking, which is preferable.

最後に、保温具100として使用する場合には、潜熱蓄熱材150の融解開始温度以上の環境温度で保温具を静置し、融解した状態にしておく。一方で、保冷具100として使用する場合には、潜熱蓄熱材150の凝固温度以下の温度環境で保冷具100を静置し、潜熱蓄熱材150を凝固させる。このような工程により、本実施形態の保温具100または保冷具100が製造される。なお、本発明の技術範囲は上記実施形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲において種々の変更を加えることが可能である。 Finally, when used as the heat insulating device 100, the heat insulating device is allowed to stand at an environmental temperature equal to or higher than the melting start temperature of the latent heat storage material 150 to keep it in a melted state. On the other hand, when used as the cold insulation tool 100, the cold insulation tool 100 is allowed to stand in a temperature environment equal to or lower than the solidification temperature of the latent heat storage material 150 to solidify the latent heat storage material 150. By such a step, the heat insulating tool 100 or the cold insulating tool 100 of this embodiment is manufactured. The technical scope of the present invention is not limited to the above embodiment, and various modifications can be made without departing from the spirit of the present invention.

[実施例1]
実施例1は、第1の実施形態に係る保温具を用いた物流システムの実施例である。実施例1は、荷送人である食品製造業者が荷受人である店舗に、保持されるべき温度範囲が20〜25℃の米飯類を気温10℃の環境下で輸送する物流システムを想定している。まず、荷送人が、潜熱蓄熱材としてヘプタデカンを主成分とするものを用いた保温具を液体の状態で、米飯類と共に、図3Aおよび図3Bに示す物流梱包容器に25℃の環境温度の食品製造工場内で梱包した。なお、保温具は、図6Aに示すようなブロー成型容器(材質:ポリエチレン、外形:180*280*29mm/t(保冷具本体)を準備し、ブロー成型容器に図6Bに示すようなシリンダーポンプを備えた液体充填機を用いて、潜熱蓄熱材を800g注液し、超音波溶着機を用いて、注入口をキャップし、溶着により密栓することで作製した。
[Example 1]
The first embodiment is an example of a physical distribution system using the heat insulating device according to the first embodiment. The first embodiment assumes a distribution system in which a food manufacturer, which is a shipper, transports cooked rice with a temperature range of 20 to 25 ° C. to a store, which is a consignee, in an environment of 10 ° C. ing. First, the shipper puts a heat insulator using a latent heat storage material containing heptadecane as a main component in a liquid state together with cooked rice in a distribution packing container shown in FIGS. 3A and 3B at an environmental temperature of 25 ° C. Packed in a food manufacturing plant. As the heat insulating device, a blow molded container (material: polyethylene, outer shape: 180 * 280 * 29 mm / t (cooling device main body)) as shown in FIG. 6A is prepared, and a cylinder pump as shown in FIG. 6B is prepared in the blow molded container. 800 g of the latent heat storage material was injected using a liquid filling machine equipped with the above, and the injection port was capped and sealed by welding using an ultrasonic welding machine.

このときの潜熱蓄熱材の凝固温度は21℃、融解開始温度が21℃、主な融解温度は22℃であり、凝固温度と融解開始温度の差は1℃未満であり、凝固温度が保持されるべき温度範囲内であった。なお、この潜熱蓄熱材の凝固温度は、50mlの潜熱蓄熱材をポリ瓶に入れた状態で、プログラマブル恒温槽に配置し、−20℃まで降下させた時に、結晶核を生じ始める温度とした。また、融解開始温度、および主たる融解温度は示差走査熱量測定(使用装置:Rigaku社製DSC8213、測定温度範囲:−30〜30℃、降温速度:−5℃/min、昇温速度:5℃/min)から評価した。 At this time, the solidification temperature of the latent heat storage material is 21 ° C., the melting start temperature is 21 ° C., the main melting temperature is 22 ° C., the difference between the solidification temperature and the melting start temperature is less than 1 ° C., and the solidification temperature is maintained. It was within the expected temperature range. The solidification temperature of the latent heat storage material was set to a temperature at which crystal nuclei began to be formed when 50 ml of the latent heat storage material was placed in a programmable constant temperature bath in a plastic bottle and lowered to −20 ° C. The melting start temperature and the main melting temperature are measured by differential scanning calorimetry (device used: DSC8213 manufactured by Rigaku Co., Ltd., measurement temperature range: -30 to 30 ° C., temperature lowering rate: -5 ° C./min, temperature rising rate: 5 ° C./ It was evaluated from min).

この物流梱包容器を気温10℃の環境下で常温トラックにて2時間かけて、配送センターに運搬した。配送センター内は25℃の環境であり、開梱し1時間かけて荷分けを行なった。なお、物流梱包容器内の潜熱蓄熱材は、配送センターに到着時は一部、凝固が確認されたが、荷分け終了時の1時間後には液体に戻っており、固体から液体への再生が確認された。次に、再生された保温具と荷分けされた米飯類を物流梱包容器に梱包し、2時間かけて店舗に運送した。開梱したところ、米飯類の品質が保持されていることが確認され、保温具の潜熱蓄熱材は一部固体になっていた。このことから、本発明の物流システムであれば、配送センターでの滞在期間で再生されるため、配送センターでの保温具の交換が不要であり、長時間の輸送が可能となる。また、本発明の物流システムであれば、配送センターでの滞在期間で再生されるため、搭載する潜熱蓄熱材の重量を減らすことができる。 This distribution packing container was transported to a distribution center in an environment of a temperature of 10 ° C. by a normal temperature truck for 2 hours. The inside of the distribution center was in an environment of 25 ° C, and the unpacking was carried out for 1 hour. The latent heat storage material in the distribution packing container was partially solidified when it arrived at the distribution center, but it returned to liquid one hour after the end of sorting, and it was regenerated from solid to liquid. confirmed. Next, the regenerated heat insulating device and the separated cooked rice were packed in a distribution packing container and transported to the store over 2 hours. When unpacked, it was confirmed that the quality of cooked rice was maintained, and the latent heat storage material of the heat insulator was partially solid. From this, the distribution system of the present invention is regenerated during the period of stay at the distribution center, so that it is not necessary to replace the heat insulating device at the distribution center, and long-term transportation is possible. Further, in the distribution system of the present invention, the weight of the latent heat storage material to be mounted can be reduced because the distribution system is regenerated during the period of stay at the distribution center.

[実施例2および3]
図7に、実施例2、3に係る保冷具の潜熱蓄熱材の例とその蓄熱材を用いて輸送されることが想定される物品例を示す。なお、再生期の温度範囲は、保冷具として使用した場合の範囲を示している。この表に示される例のような様々な主たる融解温度を有する潜熱蓄熱材から適切なものを選択することで、様々な物品をその保持されるべき温度範囲の温度に保持したまま、物流過程で潜熱蓄熱材を入れ替えたりすることなく、輸送することができる。また、凝固温度と融解開始温度の差が1℃未満と小さいため、医薬品やチョコレートのような保持すべき温度範囲が狭い物品に対しても、保持すべき温度範囲と再生期とが重複する範囲を設けることができ、保冷具を長時間使用することができる。
[Examples 2 and 3]
FIG. 7 shows an example of the latent heat storage material of the cold insulation tool according to Examples 2 and 3 and an example of an article that is expected to be transported using the heat storage material. The temperature range during the regeneration period indicates the range when used as a cold insulator. By selecting the appropriate latent heat storage material with various main melting temperatures, such as the examples shown in this table, various articles can be kept at temperatures in the temperature range to be held during the logistics process. It can be transported without replacing the latent heat storage material. In addition, since the difference between the solidification temperature and the melting start temperature is as small as less than 1 ° C., the temperature range to be maintained and the regeneration period overlap even for articles with a narrow temperature range to be maintained, such as pharmaceuticals and chocolate. Can be provided, and the cold insulation device can be used for a long time.

本発明の一実施形態は、以下のような構成を採ることができる。即ち(1)本発明の一実施形態の保温具は、物流梱包容器に用いられ、保温対象物の温度調節を行なう保温具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備え、前記潜熱蓄熱材は、保温対象物の保持されるべき温度範囲に応じて、凝固温度が前記保温対象物の保持されるべき温度範囲に含まれ、前記融解開始温度が前記保温対象物の保持されるべき温度範囲の上限より低くなるよう選択されたものである。 One embodiment of the present invention can adopt the following configuration. That is, (1) the heat insulating device of the embodiment of the present invention is a heat insulating device used for a distribution packing container and controls the temperature of a heat insulating object, and has a solidification temperature and a solid state at which the phase changes from a liquid phase to a solid phase. The latent heat storage material is provided with a latent heat storage material having a difference of less than 1 ° C. from the melting start temperature at which the phase changes from the phase to the liquid phase, and an accommodating portion for accommodating the latent heat storage material. Depending on the temperature range to be retained, the solidification temperature is included in the temperature range to be retained of the heat-retaining object, and the melting start temperature is lower than the upper limit of the temperature range to be retained of the heat-retaining object. It is the one selected.

これにより、温度を制御しない時間帯は、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を用いて、潜熱蓄熱材の潜熱により凝固温度の近傍で温度変化が小さい状態で保温対象物を保温できる。また、保温対象物が保持されるべき温度の上限が、融解開始温度より高いため、温度を制御する時間帯において、制御する温度を、融解開始温度よりも高く、かつ前記上限よりも低い温度で加熱することによって、潜熱蓄熱材を固相から液相に相変化させ、再生させることができ、保温機能の延長ができる。 As a result, during the time when the temperature is not controlled, the temperature change is small near the solidification temperature due to the latent heat of the latent heat storage material, using the high temperature stability in the process of phase change of the latent heat storage material from the liquid phase to the solid phase. The object to be kept warm can be kept warm in the state. Further, since the upper limit of the temperature at which the heat-retaining object should be held is higher than the melting start temperature, the temperature to be controlled is set to be higher than the melting start temperature and lower than the upper limit in the time zone for controlling the temperature. By heating, the latent heat storage material can be phase-changed from a solid phase to a liquid phase and regenerated, and the heat retention function can be extended.

(2)また、本発明の一実施形態の保温具において、前記潜熱蓄熱材は、炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含む。 (2) Further, in the heat insulating device according to the embodiment of the present invention, the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms.

このような潜熱蓄熱材を用いることで、熱伝導率が低く、液相から固相への相転移する速度が遅いため、凝固温度近傍を長時間保持することができる。また、厳密な温度管理が可能となる。 By using such a latent heat storage material, the thermal conductivity is low and the rate of phase transition from the liquid phase to the solid phase is slow, so that the vicinity of the solidification temperature can be maintained for a long time. In addition, strict temperature control becomes possible.

(3)また、本発明の一実施形態の保温具において、前記潜熱蓄熱材が炭素数15から24の直鎖アルカンを含む。 (3) Further, in the heat insulating device according to the embodiment of the present invention, the latent heat storage material contains a linear alkane having 15 to 24 carbon atoms.

このような潜熱蓄熱材を用いることで、熱伝導率が低く、液相から固相への相転移する速度が遅いため、凝固温度近傍を長時間保持することができる。また、チョコレートや、米飯類、精密機器・部品や美術品、血液や臓器などの保温が可能であり、厳密な温度管理が可能となる。 By using such a latent heat storage material, the thermal conductivity is low and the rate of phase transition from the liquid phase to the solid phase is slow, so that the vicinity of the solidification temperature can be maintained for a long time. In addition, it is possible to keep warm chocolate, cooked rice, precision equipment / parts, fine arts, blood and organs, etc., and strict temperature control is possible.

(4)また、本発明の一実施形態の物流梱包容器は、物品を梱包する物流梱包容器であって、物流梱包容器本体と、梱包される物品の保持されるべき温度範囲に応じて選択された、上記(1)から(3)のいずれかに記載の保温具と、前記物流梱包容器本体内部に設けられ、前記保温具を保持する保温具保持部と、前記物流梱包容器本体内部に設けられ、物品を収容する物品収容部と、を備える。 (4) Further, the distribution packing container according to the embodiment of the present invention is a distribution packing container for packing goods, and is selected according to the main body of the distribution packing container and the temperature range in which the goods to be packed should be held. Further, the heat insulating device according to any one of (1) to (3) above, a heat insulating device holding portion provided inside the distribution packing container main body and holding the heat insulating tool, and a heat insulating device holding portion provided inside the distribution packing container main body. It is provided with an article storage unit for accommodating articles.

これにより、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を有する潜熱蓄熱材を用いた保温具を、物流に使用することができる。 As a result, a heat insulating device using the latent heat storage material having high temperature stability in the process of changing the phase of the latent heat storage material from the liquid phase to the solid phase can be used for physical distribution.

(5)また、本発明の一実施形態の物流システムは、保持されるべき温度範囲が定められた物品が、上記(4)記載の物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、温度が制御されない時間帯の前後の少なくとも一方で、前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御する加熱装置を備え、前記加熱装置が、前記潜熱蓄熱材の融解開始温度よりも高く、前記物品の保持されるべき温度範囲の上限よりも低い温度で前記物流梱包容器を加熱することによって、前記潜熱蓄熱材が固相から液相に相変化する。 (5) Further, in the distribution system according to the embodiment of the present invention, an article having a temperature range to be held is packed in the distribution packing container described in (4) above, and is received by the carrier from the shipper. A distribution system delivered to a person, comprising a heating device that controls the temperature outside the distribution packing container to a temperature range in which the article should be held, at least before and after a time when the temperature is not controlled. The latent heat storage material is removed from the solid phase by heating the distribution packing container at a temperature higher than the melting start temperature of the latent heat storage material and lower than the upper limit of the temperature range in which the article should be held. The phase changes to a liquid phase.

これにより、潜熱蓄熱材を用いた物流梱包容器を使用した物流システムにおいて、凝固温度近傍で物品を保温できる。また、潜熱蓄熱材を再生させることができ、保温機能を延長させることができる。 As a result, in a distribution system using a distribution packing container using a latent heat storage material, the article can be kept warm near the solidification temperature. In addition, the latent heat storage material can be regenerated, and the heat retention function can be extended.

(6)また、本発明の一実施形態の物流方法は、保持されるべき温度範囲が定められた物品が、上記(4)記載の物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流方法であって、温度が制御されない時間帯の前後の少なくとも一方で、加熱装置を用いて前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御するステップと、を有し、前記加熱装置が、前記潜熱蓄熱材の融解開始温度よりも高く、前記物品の保持されるべき温度範囲の上限よりも低い温度で前記物流梱包容器を加熱することによって、前記潜熱蓄熱材が固相から液相に相変化する。 (6) Further, in the distribution method according to the embodiment of the present invention, an article having a temperature range to be held is packed in the distribution packing container described in (4) above, and is received by the carrier from the shipper. A distribution method delivered to a person, at least before and after a time when the temperature is not controlled, a step of controlling the temperature outside the distribution packing container to a temperature range in which the article should be held by using a heating device. By heating the distribution packing container at a temperature higher than the melting start temperature of the latent heat storage material and lower than the upper limit of the temperature range in which the article should be held. The latent heat storage material undergoes a phase change from a solid phase to a liquid phase.

これにより、潜熱蓄熱材を用いた物流梱包容器を使用した物流方法において、凝固温度近傍で物品を保温できる。また、潜熱蓄熱材を再生させることができ、保温機能を延長させることができる。 As a result, in the distribution method using the distribution packing container using the latent heat storage material, the article can be kept warm in the vicinity of the solidification temperature. In addition, the latent heat storage material can be regenerated, and the heat retention function can be extended.

(7)また、本発明の一実施形態の保冷具は、物流梱包容器に用いられ、保冷対象物の温度調節を行なう保冷具であって、液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、前記潜熱蓄熱材を収容する収容部と、を備え、前記潜熱蓄熱材は、保冷対象物の保持されるべき温度範囲に応じて、主たる融解温度が前記保冷対象物の保持されるべき温度範囲に含まれ、前記凝固温度が前記保冷対象物の保持されるべき温度範囲の下限より高くなるよう選択されたものである。 (7) Further, the cold storage device according to the embodiment of the present invention is a cold storage device used for a distribution packing container and controls the temperature of a cold storage object, and has a solidification temperature at which a phase change from a liquid phase to a solid phase begins. The latent heat storage material is provided with a latent heat storage material having a difference of less than 1 ° C. from the melting start temperature at which the phase changes from the solid phase to the liquid phase, and an accommodating portion for accommodating the latent heat storage material. Depending on the temperature range to be retained, the main melting temperature is included in the temperature range to be retained of the object to be cooled, and the solidification temperature is higher than the lower limit of the temperature range to be retained of the object to be cooled. Was chosen to be.

これにより、温度を制御しない時間帯は、潜熱蓄熱材の潜熱により主たる融解温度の近傍で保冷対象物を保冷できる。また、保冷対象物が保持されるべき温度の下限が、凝固温度より低いため、温度を制御する時間帯において、制御する温度を潜熱蓄熱材の凝固温度よりも低く、保冷対象物の保持されるべき温度範囲の下限よりも高い温度にすることによって、潜熱蓄熱材を液相から固相に相変化させ、再生させることができ、保冷機能の延長ができる。また、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を用いて、保冷時に潜熱をすべて使い果たし、液体状態になったとしても、潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷できる。 As a result, the object to be kept cold can be kept cold in the vicinity of the main melting temperature by the latent heat of the latent heat storage material during the time period when the temperature is not controlled. Further, since the lower limit of the temperature at which the object to be cooled should be retained is lower than the solidification temperature, the temperature to be controlled is lower than the solidification temperature of the latent heat storage material in the time zone for controlling the temperature, and the object to be cooled is retained. By setting the temperature higher than the lower limit of the power temperature range, the latent heat storage material can be phase-changed from the liquid phase to the solid phase and regenerated, and the cold insulation function can be extended. In addition, by using the high temperature stability in the process of phase change of the latent heat storage material from the liquid phase to the solid phase, even if all the latent heat is exhausted during cold storage and the latent heat storage material becomes liquid, when the latent heat storage material is regenerated, The object to be kept cold can be kept cold with a small temperature change.

(8)また、本発明の一実施形態の保冷具において、前記潜熱蓄熱材は、炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含む。 (8) Further, in the cold insulation device according to the embodiment of the present invention, the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms.

このような潜熱蓄熱材を用いることで、潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷できる。また、厳密な温度管理が可能となる。 By using such a latent heat storage material, when the latent heat storage material is regenerated, the object to be cooled can be kept cold in a state where the temperature change is small. In addition, strict temperature control becomes possible.

(9)また、本発明の一実施形態の保冷具は、前記潜熱蓄熱材が炭素数14から16の直鎖アルカンを含む。 (9) Further, the cold insulation device according to the embodiment of the present invention contains a linear alkane whose latent heat storage material has 14 to 16 carbon atoms.

このような潜熱蓄熱材を用いることで、有用性の高いチルド温度帯(2〜8℃)、青果品の保存に適した温度帯(8〜15℃)での保冷が可能となる。また、厳密な温度管理が可能となる。 By using such a latent heat storage material, it is possible to keep cold in a highly useful chilled temperature range (2 to 8 ° C.) and a temperature range suitable for storing fruits and vegetables (8 to 15 ° C.). In addition, strict temperature control becomes possible.

(10)また、本発明の一実施形態の物流梱包容器は、物品を梱包する物流梱包容器であって、物流梱包容器本体と、梱包される物品の保持されるべき温度範囲に応じて選択された、上記(7)から(9)のいずれかに記載の保冷具と、前記物流梱包容器本体内部に設けられ、前記保冷具を保持する保冷具保持部と、前記物流梱包容器本体内部に設けられ、物品を収容する物品収容部と、を備える。 (10) Further, the distribution packing container according to the embodiment of the present invention is a distribution packing container for packing articles, and is selected according to the main body of the distribution packing container and the temperature range in which the goods to be packed should be held. Further, the cold storage device according to any one of (7) to (9) above, a cold storage device holding portion provided inside the distribution packing container main body and holding the cold storage device, and a cold storage device holding portion provided inside the distribution packing container main body. It is provided with an article storage unit for accommodating articles.

これにより、潜熱蓄熱材が液相から固相に相変化する過程での高い温度安定性を有する潜熱蓄熱材を用いた保冷具を、物流に使用することができる。 As a result, a cooler using the latent heat storage material having high temperature stability in the process of changing the phase of the latent heat storage material from the liquid phase to the solid phase can be used for physical distribution.

(11)また、本発明の一実施形態の物流システムは、保持されるべき温度範囲が定められた物品が、上記(10)記載の物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、温度が制御されない時間帯の前後の少なくとも一方で、前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御する冷却装置を備え、前記冷却装置が、前記潜熱蓄熱材の凝固温度よりも低く、前記物品の保持されるべき温度範囲の下限よりも高い温度で前記物流梱包容器を冷却することによって、前記潜熱蓄熱材が液相から固相に相変化する。 (11) Further, in the distribution system of the embodiment of the present invention, the article in which the temperature range to be held is defined is packed in the distribution packing container described in (10) above, and is received by the carrier from the shipper. A distribution system delivered to a person, comprising a cooling device that controls the temperature outside the distribution packaging container to a temperature range in which the article should be held, at least before and after a time when the temperature is not controlled. When the cooling device cools the distribution packing container at a temperature lower than the solidification temperature of the latent heat storage material and higher than the lower limit of the temperature range in which the article should be held, the latent heat storage material is solidified from the liquid phase. Phase change.

これにより、潜熱蓄熱材を用いた物流梱包容器を使用した物流システムにおいて、潜熱蓄熱材を再生させることができ、保冷機能を延長させることができる。また、保冷時に潜熱を使い果たし、液体状態になったとしても、潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷できる。 As a result, in the distribution system using the distribution packing container using the latent heat storage material, the latent heat storage material can be regenerated and the cold insulation function can be extended. Further, even if the latent heat is exhausted during cold storage and the latent heat storage material is regenerated, the cold storage object can be kept cold with a small temperature change.

(12)また、本発明の一実施形態の物流方法は、保持されるべき温度範囲が定められた物品が、上記(10)記載の物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流方法であって、温度が制御されない時間帯の前後の少なくとも一方で、冷却装置を用いて前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御するステップと、を有し、前記冷却装置が、前記潜熱蓄熱材の凝固温度よりも低く、前記物品の保持されるべき温度範囲の下限よりも高い温度で前記物流梱包容器を冷却することによって、前記潜熱蓄熱材が液相から固相に相変化する。 (12) Further, in the distribution method of the embodiment of the present invention, an article in which a temperature range to be held is defined is packed in the distribution packing container described in (10) above, and is received by the carrier from the shipper. A distribution method delivered to a person, at least before and after a temperature uncontrolled time period, in which a cooling device is used to control the temperature outside the distribution packaging container to a temperature range in which the article should be held. The latent heat is generated by cooling the distribution packing container at a temperature lower than the solidification temperature of the latent heat storage material and higher than the lower limit of the temperature range in which the article should be held. The heat storage material undergoes a phase change from a liquid phase to a solid phase.

これにより、潜熱蓄熱材を用いた物流梱包容器を使用した物流方法において、潜熱蓄熱材を再生させることができ、保冷機能を延長させることができる。また、保冷時に潜熱を使い果たし、液体状態になったとしても、潜熱蓄熱材を再生させる際に、保冷対象物を温度変化が小さい状態で保冷できる。 As a result, in the distribution method using the distribution packing container using the latent heat storage material, the latent heat storage material can be regenerated and the cold insulation function can be extended. Further, even if the latent heat is exhausted during cold storage and the latent heat storage material is regenerated, the cold storage object can be kept cold with a small temperature change.

なお、本国際出願は、2017年3月28に出願した日本国特許出願第2017−063250号に基づく優先権を主張するものであり、日本国特許出願第2017−063250号の全内容を本国際出願に援用する。 This international application claims priority based on Japanese Patent Application No. 2017-063250 filed on March 28, 2017, and the entire contents of Japanese Patent Application No. 2017-063250 are included in this international application. Incorporate for application.

100 保温具、保冷具
110 保温具本体、保冷具本体
120 収容部
130 蓄熱層
150 潜熱蓄熱材
170 注入口
190 栓
200 物流梱包容器
210 物流梱包容器本体
220 保温具保持部、保冷具保持部
230 物品収容部
240 収容部
250 蓋部
100 Insulation device, cold insulation device 110 Insulation device main body, cold insulation device main body 120 Storage part 130 Heat storage layer 150 Latent heat storage material 170 Injection port 190 Plug 200 Logistics packing container 210 Logistics packing container main body 220 Heat insulation device holding part, cold storage device holding part 230 Articles Storage part 240 Storage part 250 Lid part

Claims (12)

保持されるべき温度範囲が定められた物品が、物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、
温度が制御されない時間帯の前後の少なくとも一方で、前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御する加熱装置を備え、
前記物流梱包容器は、
物流梱包容器本体と、
前記物品の保持されるべき温度範囲に応じて選択された保温具と、
前記物流梱包容器本体内部に設けられ、前記保温具を保持する保温具保持部と、
前記物流梱包容器本体内部に設けられ、前記物品を収容する物品収容部と、
を備え、
前記保温具は、
前記物品の温度調節を行ない、
液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、
前記潜熱蓄熱材を収容する収容部と、
を備え、
前記潜熱蓄熱材は、前記物品の保持されるべき温度範囲に応じて、前記凝固温度が前記保温対象物の保持されるべき温度範囲に含まれ、前記融解開始温度が前記物品の保持されるべき温度範囲の上限より低くなるよう選択されたものであり、
前記加熱装置が、前記保温具の交換を行わずに、前記潜熱蓄熱材の融解開始温度よりも高く、前記物品の保持されるべき温度範囲の上限よりも低い温度で前記物流梱包容器を加熱することによって、前記潜熱蓄熱材が固相から液相に相変化する物流システム。
A logistics system in which goods with a defined temperature range to be held are packed in a logistics packing container and delivered from the shipper to the consignee by the carrier.
A heating device is provided that controls the temperature outside the distribution packing container to a temperature range in which the article should be held, at least before and after the time when the temperature is not controlled.
The distribution packing container is
Logistics packing container body and
A warming device selected according to the temperature range in which the article should be held, and
A heat insulating device holding portion provided inside the distribution packing container body and holding the heat insulating device,
An article storage unit provided inside the distribution packing container body and accommodating the article,
With
The heat insulator
Adjust the temperature of the article,
A latent heat storage material in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase is less than 1 ° C.
A housing unit for accommodating the latent heat storage material and
With
In the latent heat storage material, the solidification temperature should be included in the temperature range in which the heat retaining object should be held, and the melting start temperature should be held in the article, depending on the temperature range in which the article should be held. It was chosen to be below the upper limit of the temperature range and
The heating device heats the distribution packing container at a temperature higher than the melting start temperature of the latent heat storage material and lower than the upper limit of the temperature range in which the article should be held, without replacing the heat insulating device. A distribution system in which the latent heat storage material undergoes a phase change from a solid phase to a liquid phase.
前記潜熱蓄熱材が炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含むことを特徴とする請求項1記載の物流システム。 The distribution system according to claim 1, wherein the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms . 前記潜熱蓄熱材が炭素数15から24の直鎖アルカンを含むことを特徴とする請求項1記載の物流システム。 The distribution system according to claim 1, wherein the latent heat storage material contains a linear alkane having 15 to 24 carbon atoms . 保持されるべき温度範囲が定められた物品が、物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流方法であって、
温度が制御されない時間帯の前後の少なくとも一方で、加熱装置を用いて前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御するステップと、を有し、
前記物流梱包容器は、
物流梱包容器本体と、
前記物品の保持されるべき温度範囲に応じて選択された保温具と、
前記物流梱包容器本体内部に設けられ、前記保温具を保持する保温具保持部と、
前記物流梱包容器本体内部に設けられ、前記物品を収容する物品収容部と、
を備え、
前記保温具は、
前記物品の温度調節を行ない、
液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、
前記潜熱蓄熱材を収容する収容部と、
を備え、
前記潜熱蓄熱材は、前記物品の保持されるべき温度範囲に応じて、前記凝固温度が前記保温対象物の保持されるべき温度範囲に含まれ、前記融解開始温度が前記物品の保持されるべき温度範囲の上限より低くなるよう選択されたものであり、
前記加熱装置が、前記保温具の交換を行わずに、前記潜熱蓄熱材の融解開始温度よりも高く、前記物品の保持されるべき温度範囲の上限よりも低い温度で前記物流梱包容器を加熱することによって、前記潜熱蓄熱材が固相から液相に相変化する物流方法。
A distribution method in which goods with a defined temperature range to be held are packed in a distribution packing container and delivered from the shipper to the consignee by the carrier.
At least before and after the time when the temperature is not controlled, there is a step of controlling the temperature outside the distribution packing container to the temperature range in which the article should be held by using a heating device.
The distribution packing container is
Logistics packing container body and
A warming device selected according to the temperature range in which the article should be held, and
A heat insulating device holding portion provided inside the distribution packing container body and holding the heat insulating device,
An article storage unit provided inside the distribution packing container body and accommodating the article,
With
The heat insulator
Adjust the temperature of the article,
A latent heat storage material in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase is less than 1 ° C.
A housing unit for accommodating the latent heat storage material and
With
In the latent heat storage material, the solidification temperature should be included in the temperature range in which the heat retaining object should be held, and the melting start temperature should be held in the article, depending on the temperature range in which the article should be held. It was chosen to be below the upper limit of the temperature range and
The heating device heats the distribution packing container at a temperature higher than the melting start temperature of the latent heat storage material and lower than the upper limit of the temperature range in which the article should be held, without replacing the heat insulating device. A distribution method in which the latent heat storage material undergoes a phase change from a solid phase to a liquid phase.
前記潜熱蓄熱材が炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含むことを特徴とする請求項4記載の物流方法。 The distribution method according to claim 4, wherein the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms . 前記潜熱蓄熱材が炭素数15から24の直鎖アルカンを含むことを特徴とする請求項4記載の物流方法。 The distribution method according to claim 4, wherein the latent heat storage material contains a linear alkane having 15 to 24 carbon atoms . 保持されるべき温度範囲が定められた物品が、物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流システムであって、
温度が制御されない時間帯の前後の少なくとも一方で、前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御する冷却装置を備え、
前記物流梱包容器は、
物流梱包容器本体と、
前記物品の保持されるべき温度範囲に応じて選択された保冷具と、
前記物流梱包容器本体内部に設けられ、前記保冷具を保持する保冷具保持部と、
前記物流梱包容器本体内部に設けられ、前記物品を収容する物品収容部と、
を備え、
前記保冷具は、
前記物品の温度調節を行い、
液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、
前記潜熱蓄熱材を収容する収容部と、
を備え、
前記潜熱蓄熱材は、前記物品の保持されるべき温度範囲に応じて、主たる融解温度が前記物品の保持されるべき温度範囲に含まれ、前記凝固温度が前記物品の保持されるべき温度範囲の下限より高くなるよう選択されたものであり、
前記冷却装置が、前記保冷具の交換を行わずに、前記潜熱蓄熱材の凝固温度よりも低く、前記物品の保持されるべき温度範囲の下限よりも高い温度で前記物流梱包容器を冷却することによって、前記潜熱蓄熱材が液相から固相に相変化する物流システム。
A logistics system in which goods with a defined temperature range to be held are packed in a logistics packing container and delivered from the shipper to the consignee by the carrier.
A cooling device for controlling the temperature outside the distribution packing container to a temperature range in which the article should be held is provided, at least before and after the time when the temperature is not controlled.
The distribution packing container is
Logistics packing container body and
A cold insulator selected according to the temperature range in which the article should be held, and
A cold storage device holding unit provided inside the distribution packing container body and holding the cold storage device,
An article storage unit provided inside the distribution packing container body and accommodating the article,
With
The cold storage device
Adjust the temperature of the article
A latent heat storage material in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase is less than 1 ° C.
A housing unit for accommodating the latent heat storage material and
With
In the latent heat storage material, the main melting temperature is included in the temperature range in which the article should be held, and the solidification temperature is in the temperature range in which the article should be held, depending on the temperature range in which the article should be held. It was chosen to be higher than the lower limit and
The cooling device cools the distribution packing container at a temperature lower than the solidification temperature of the latent heat storage material and higher than the lower limit of the temperature range in which the article should be held, without replacing the cold insulator. A distribution system in which the latent heat storage material undergoes a phase change from a liquid phase to a solid phase.
前記潜熱蓄熱材が炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含むことを特徴とする請求項7記載の物流システム。 The distribution system according to claim 7, wherein the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms . 前記潜熱蓄熱材が炭素数15から24の直鎖アルカンを含むことを特徴とする請求項7記載の物流システム。 The distribution system according to claim 7, wherein the latent heat storage material contains a linear alkane having 15 to 24 carbon atoms . 保持されるべき温度範囲が定められた物品が、物流梱包容器に梱包され、荷送人から運送人によって荷受人に引き渡される物流方法であって、
温度が制御されない時間帯の前後の少なくとも一方で、冷却装置を用いて前記物流梱包容器の外部の温度を前記物品の保持されるべき温度範囲に制御するステップと、を有し、
前記物流梱包容器は、
物流梱包容器本体と、
前記物品の保持されるべき温度範囲に応じて選択された保冷具と、
前記物流梱包容器本体内部に設けられ、前記保冷具を保持する保冷具保持部と、
前記物流梱包容器本体内部に設けられ、前記物品を収容する物品収容部と、
を備え、
前記保冷具は、
前記物流梱包容器に用いられ、前記物品の温度調節を行い、
液相から固相に相変化し始める凝固温度と固相から液相に相変化し始める融解開始温度との差が1℃未満である潜熱蓄熱材と、
前記潜熱蓄熱材を収容する収容部と、
を備え、
前記潜熱蓄熱材は、前記物品の保持されるべき温度範囲に応じて、主たる融解温度が前記物品の保持されるべき温度範囲に含まれ、前記凝固温度が前記物品の保持されるべき温度範囲の下限より高くなるよう選択されたものであり、
前記冷却装置が、前記保冷具の交換を行わずに、前記潜熱蓄熱材の凝固温度よりも低く、前記物品の保持されるべき温度範囲の下限よりも高い温度で前記物流梱包容器を冷却することによって、前記潜熱蓄熱材が液相から固相に相変化する物流方法。
A distribution method in which goods with a defined temperature range to be held are packed in a distribution packing container and delivered from the shipper to the consignee by the carrier.
At least before and after the time when the temperature is not controlled, there is a step of controlling the temperature outside the distribution packing container to the temperature range in which the article should be held by using a cooling device.
The distribution packing container is
Logistics packing container body and
A cold insulator selected according to the temperature range in which the article should be held, and
A cold storage device holding unit provided inside the distribution packing container body and holding the cold storage device,
An article storage unit provided inside the distribution packing container body and accommodating the article,
With
The cold storage device
Used for the distribution packing container, the temperature of the article is controlled,
A latent heat storage material in which the difference between the solidification temperature at which the phase changes from the liquid phase to the solid phase and the melting start temperature at which the phase changes from the solid phase to the liquid phase is less than 1 ° C.
A housing unit for accommodating the latent heat storage material and
With
In the latent heat storage material, the main melting temperature is included in the temperature range in which the article should be held, and the solidification temperature is in the temperature range in which the article should be held, depending on the temperature range in which the article should be held. It was chosen to be higher than the lower limit and
The cooling device cools the distribution packing container at a temperature lower than the solidification temperature of the latent heat storage material and higher than the lower limit of the temperature range in which the article should be held, without replacing the cold insulator. A distribution method in which the latent heat storage material undergoes a phase change from a liquid phase to a solid phase.
前記潜熱蓄熱材が炭素数13から30の直鎖アルカンまたは炭素数13から20の直鎖アルキルアルコールのいずれかを含むことを特徴とする請求項10記載の物流方法。 The distribution method according to claim 10, wherein the latent heat storage material contains either a linear alkane having 13 to 30 carbon atoms or a linear alkyl alcohol having 13 to 20 carbon atoms . 前記潜熱蓄熱材が炭素数15から24の直鎖アルカンを含むことを特徴とする請求項10記載の物流方法。 The distribution method according to claim 10, wherein the latent heat storage material contains a linear alkane having 15 to 24 carbon atoms .
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