JP6765496B2 - Bainite steel wheels for high toughness railway transportation and their manufacturing methods - Google Patents
Bainite steel wheels for high toughness railway transportation and their manufacturing methods Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/28—Normalising
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/001—Heat treatment of ferrous alloys containing Ni
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/34—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tyres; for rims
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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Description
本発明は、鋼の化学組成設計及び車輪製造の分野に関し、具体的には、高靭性鉄道輸送用ベイナイト鋼車輪及びその製造方法、並びに鉄道輸送の他の部品及び類似の部品の鋼の設計と製造方法に関する。 The present invention relates to the fields of steel chemical composition design and wheel manufacturing, specifically, the design of bainite steel wheels for high toughness rail transport and its manufacturing method, and the design of steel for other parts and similar parts for rail transport. Regarding the manufacturing method.
「高速、高荷重及び低騒音」は、世界鉄道輸送の主要な発展方向である。車輪は鉄道輸送の「靴」であり、最も重要な走行部品の1つであり、運行の安全性に直接影響を与える。列車の通常運行中に、車輪は車両の全部の荷重を負い、摩耗及び転がり接触疲労(RCF)によって損傷され、同時に、それは線路、制輪子、車軸、及び周囲の媒体と非常に複雑な作用関係を有し、動的な交互に変化するストレス状態にある。特に車輪と線路、及び車輪と制輪子(ディスクブレーキを除く)は、2対の、常に存在する、無視できない摩擦ペアである。緊急状況又は特殊道路での運行中に、ブレーキの熱的損傷や擦り傷が非常に著しく、熱疲労が生じ、車輪の安全性や使用寿命にも影響を及ぼす。 "High speed, high load and low noise" are the major development directions of world rail transportation. Wheels are the "shoes" of rail transport, one of the most important traveling parts, and have a direct impact on operational safety. During normal operation of the train, the wheels bear the full load of the vehicle and are damaged by wear and rolling contact fatigue (RCF), which at the same time it has a very complex working relationship with railroad tracks, brake shoes, axles and surrounding media. And is in a dynamic, alternating stress state. In particular, wheels and railroad tracks, and wheels and brake shoes (excluding disc brakes) are two pairs of always-existing, non-negligible friction pairs. During emergencies or operation on special roads, the brakes are extremely severely damaged or scratched, causing thermal fatigue and affecting wheel safety and service life.
鉄道輸送では、車輪が基本的な強度を満たす場合、安全性や信頼性を確保するために、特に車輪の靭性指数に注意を払う。貨物輸送用車輪の摩耗や転がり接触疲労(RCF)による損傷が大きく、踏面ブレーキのため、熱疲労損傷も大きく、剥離、剥落、リム割れなどの欠陥が生じる。旅客輸送用車輪については、車輪の靭性及び低温靭性によりいっそう注意を払う。旅客輸送は、ディスクブレーキを使用するため、ブレーキ熱疲労が減少する。 In rail transport, if the wheels meet basic strength, pay particular attention to the toughness index of the wheels to ensure safety and reliability. Freight transport wheels are heavily damaged by wear and rolling contact fatigue (RCF), and because of the tread brake, thermal fatigue damage is also large, causing defects such as peeling, peeling, and rim cracking. For passenger transport wheels, pay more attention to the toughness and low temperature toughness of the wheels. Since passenger transportation uses disc brakes, brake thermal fatigue is reduced.
現在、中国の国内外での鉄道輸送用車輪鋼は、例えば、中国車輪規格GB/T8601、TB/T2817、欧州車輪規格EN13262、日本車輪規格JRSとJIS B5402、及び北米車輪規格AAR M107などにより、中高炭素鋼又は中高炭素マイクロ合金化鋼であり、その金属組織はパーライト−フェライト組織である。 Currently, steel wheels for railway transportation in China and abroad are based on, for example, Chinese wheel standards GB / T8601, TB / T2817, European wheel standards EN13262, Japanese wheel standards JRS and JIS B5402, and North American wheel standards AAR M107. It is a medium-high carbon steel or a medium-high carbon microalloyed steel, and its metal structure is a pearlite-ferrite structure.
CL60鋼車輪は、中国の現在の鉄道輸送車両(旅客輸送及び貨物輸送)に主に使用されている圧延鋼の車輪鋼である。BZ−Lは、中国の現在の鉄道輸送車両(貨物輸送)に主に使用されている鋳鋼の車輪鋼である。両者の金属組織はパーライト−フェライト組織である。 CL60 steel wheels are rolled steel wheel steels that are mainly used in China's current rail transport vehicles (passenger transport and freight transport). BZ-L is a cast steel wheel steel mainly used in the current railway transportation vehicles (freight transportation) in China. Both metal structures are pearlite-ferrite structures.
車輪の各部分の名称を図1に示す。CL60鋼の主な技術的指標の要求を表1に示す。
The names of each part of the wheel are shown in FIG. Table 1 shows the requirements for the main technical indicators of CL60 steel.
製造中は、車輪材料に優れ、鋼中の有害ガス及び有害な残留元素の含有量が低いことを保証することが必要である。車輪が高温にある状態で、リムの踏面は水の噴射で強化冷却されて、リムの強度及び硬度が向上する。スポーク板部及び車輪ハブは、焼ならし熱処理と同等であり、リムの強度と靭性の整合性が高く、スポーク板部に高靭性がある。最終的に、車輪は優れた総合的な機械的特性とサービス性能を有する。 During production, it is necessary to ensure that the wheel material is excellent and the content of harmful gases and harmful residual elements in the steel is low. When the wheels are hot, the treads of the rim are reinforced and cooled by a jet of water, improving the strength and hardness of the rim. The spoke plate portion and the wheel hub are equivalent to the normalizing heat treatment, the strength and toughness of the rim are highly consistent, and the spoke plate portion has high toughness. Ultimately, the wheels have excellent overall mechanical properties and service performance.
パーライト−少量フェライト車輪鋼では、フェライトは、材料の軟質相であり、良好な靭性と低い降伏強度を有する。その柔らかさのために、転がり接触疲労(RCF)に対する耐性が低い。一般に、フェライト含有量が高いほど、鋼の衝撃靱性は良好である。フェライトと比較して、パーライトは、強度が高く、靭性が低いため、衝撃性能が劣る。鉄道輸送の発展方向は高速かつ高荷重であり、運行中に車輪への負荷は大幅に増加する。既存のパーライト−少量フェライト材料の車輪は、運行とサービス中にますます多くの問題が表れ、主に以下の欠点が存在している。
(1)リム降伏強度は低く、一般的には600MPaを超えない。車輪の走行中に車輪と軌道との転がり接触応力が大きく、時には車輪鋼の降伏強度を超えるので、走行過程で塑性変形が発生して、踏面の副表面の塑性変形を生じる。また、介在物やセメンタイトなどの脆い相が鋼中に存在するため、リムにはマイクロクラックが発生しやすい。これらのマイクロクラックは、車輪の走行中に転がり接触疲労により、剥離やリム割れなどの欠陥を引き起こす。
(2)鋼は炭素含有量が高く、耐熱損傷性が低い。踏面ブレーキが使用されるときに又は車輪がスライドするときに擦り傷が発生した場合、車輪は局部的に鋼のオーステナイト化温度に昇温し、その後急冷してマルテンサイトを生成する。このように熱疲労が繰り返されて、ブレーキ熱クラックが形成され、剥落や大割れなどの欠陥が発生する。
(3)車輪鋼の焼入性が悪い。車輪リムは、一定の硬度勾配を有し、不均一な硬度により、輪縁の摩耗や円周のひずみなどの欠陥が発生しやすい。
In pearlite-low volume ferrite wheel steel, ferrite is the soft phase of the material and has good toughness and low yield strength. Due to its softness, it has low resistance to rolling contact fatigue (RCF). In general, the higher the ferrite content, the better the impact toughness of the steel. Compared to ferrite, pearlite is inferior in impact performance due to its high strength and low toughness. The direction of development of railway transportation is high speed and high load, and the load on the wheels increases significantly during operation. Existing perlite-small amount ferrite material wheels present more and more problems during operation and service, with the following main drawbacks:
(1) The rim yield strength is low and generally does not exceed 600 MPa. Since the rolling contact stress between the wheel and the track is large during the running of the wheel and sometimes exceeds the yield strength of the wheel steel, plastic deformation occurs during the running process, causing plastic deformation of the secondary surface of the tread surface. In addition, since brittle phases such as inclusions and cementite are present in the steel, microcracks are likely to occur in the rim. These microcracks cause defects such as peeling and rim cracking due to rolling contact fatigue while the wheel is running.
(2) Steel has a high carbon content and low heat damage resistance. If scratches occur when the tread brakes are used or when the wheels slide, the wheels locally heat up to the austenitizing temperature of the steel and then quench to produce martensite. In this way, thermal fatigue is repeated, brake thermal cracks are formed, and defects such as peeling and large cracks occur.
(3) Poor hardenability of wheel steel. The wheel rim has a constant hardness gradient, and due to the non-uniform hardness, defects such as wear of the wheel edge and distortion of the circumference are likely to occur.
ベイナイト鋼の相変態に関する研究の発展とブレークスルーに伴い、特に炭化物フリーベイナイト鋼の理論と応用研究により、高強度と高靭性の良好な整合が達成される。炭化物フリーベイナイト鋼は、理想的な微細組織構造を有し、優れた機械的性質を有する。その微細組織構造は、炭化物フリーベイナイトであり、即ち、ナノスケールのラス状の過飽和フェライトである。中間は、ナノスケールの薄膜状炭素リッチ残留オーステナイトである。それにより、鋼の強度と靭性が向上し、特に、鋼の降伏強度、衝撃靭性及び破壊靱性が向上し、鋼の切欠き感受性が低下する。従って、ベイナイト鋼車輪は、車輪の転がり接触疲労(RCF)に対する耐性が効果的に向上し、車輪の剥離や剥落などの現象が低減され、車輪の安全性及び使用性能が向上する。ベイナイト鋼車輪の炭素含有量が低いため、車輪の熱疲労性能が向上し、リムのヒートクラックが防止され、車輪の旋盤加工回数及び旋盤加工量が減少し、リム金属の使用効率が向上し、車輪の使用寿命が延びる。 With the development and breakthrough of research on phase transformation of bainite steel, good matching of high strength and high toughness is achieved, especially by theoretical and applied research of carbide-free bainite steel. Carbide-free bainite steel has an ideal microstructure and excellent mechanical properties. Its microstructure is carbide free bainite, i.e., nanoscale lath-like supersaturated ferrite. In the middle is nanoscale thin-film carbon-rich retained austenite. As a result, the strength and toughness of the steel are improved, and in particular, the yield strength, impact toughness and fracture toughness of the steel are improved, and the notch sensitivity of the steel is reduced. Therefore, the bainite steel wheel effectively improves the resistance to rolling contact fatigue (RCF) of the wheel, reduces phenomena such as peeling and peeling of the wheel, and improves the safety and use performance of the wheel. Due to the low carbon content of baynite steel wheels, the thermal fatigue performance of the wheels is improved, heat cracks in the rim are prevented, the number of lathes and the amount of lathes are reduced, and the efficiency of rim metal use is improved. The service life of the wheel is extended.
2006年7月12日に公開されたCN1800427A号(公開番号)の中国特許「鉄道車両車輪用ベイナイト鋼」に開示された鋼の化学組成範囲(wt%)は、炭素C:0.08〜0.45%、ケイ素Si:0.60〜2.10%、マンガンMn:0.60〜2.10%、モリブデンMo:0.08〜0.60%、ニッケルNi:0.00〜2.10%、クロムCr:<0.25%、バナジウムV:0.00〜0.20%、銅Cu:0.00〜1.00%である。そのベイナイト鋼の典型的な組織は、炭化物フリーベイナイトであり、優れた靭性、低い切欠き感受性、良好な耐ヒートクラック性を有する。Mo元素の添加により、鋼の焼入性を高めることができるが、大断面の車輪の場合、生産管理が困難でコストが高い。 The chemical composition range (wt%) of the steel disclosed in the Chinese patent "Baynite Steel for Railroad Vehicle Wheels" of CN1800247A (publication number) published on July 12, 2006 is carbon C: 0.08 to 0. .45%, Silicon Si: 0.60 to 2.10%, Manganese Mn: 0.60 to 2.10%, Molybdenum Mo: 0.08 to 0.60%, Nickel Ni: 0.00 to 2.10 %, Chromium Cr: <0.25%, Vanadium V: 0.00 to 0.20%, Copper Cu: 0.00 to 1.00%. The typical structure of the bainite steel is carbide-free bainite, which has excellent toughness, low notch sensitivity and good heat crack resistance. By adding the Mo element, the hardenability of steel can be improved, but in the case of a wheel having a large cross section, production control is difficult and the cost is high.
ブリティッシュ・スチールの特許CN1059239Cには、ベイナイト鋼及びその生産プロセスが開示されている。その鋼の化学組成範囲(wt%)は、炭素C:0.05〜0.50%、ケイ素Si及び/又はアルミニウムAl:1.00〜3.00%、マンガンMn:0.50〜2.50%、クロムCr:0.25〜2.50%である。そのベイナイト鋼の典型的な組織は、炭化物フリーベイナイトであり、高い耐摩耗性及び転がり接触疲労耐性を有する。そのタイプの鋼は、良好な靭性を有するが、鋼レールの断面が比較的簡単であり、20℃での衝撃靭性が高くなく、鋼のコストが高い。 British Steel's patent CN1059239C discloses bainite steel and its production process. The chemical composition range (wt%) of the steel is carbon C: 0.05 to 0.50%, silicon Si and / or aluminum Al: 1.00 to 3.00%, manganese Mn: 0.50 to 2. 50%, chromium Cr: 0.25 to 2.50%. The typical structure of the bainite steel is carbide-free bainite, which has high wear resistance and rolling contact fatigue resistance. That type of steel has good toughness, but the cross section of the steel rail is relatively simple, the impact toughness at 20 ° C. is not high, and the cost of steel is high.
本発明の目的は、Mo、V、Cr及びBなどの合金元素を添加することなく、リムの典型的な組織が炭化物フリーベイナイトであり、優れた強度と靭性及び低い切欠き感受性などの特徴を有するC−Si−Mn−Ni−RE系の高靭性鉄道輸送用ベイナイト鋼車輪を提供することである。 An object of the present invention is that the typical structure of the rim is carbide free bainite without the addition of alloying elements such as Mo, V, Cr and B, and features such as excellent strength and toughness and low notch sensitivity. The purpose of the present invention is to provide a C-Si-Mn-Ni-RE-based high toughness bainite steel wheel for railway transportation.
本発明は、熱処理プロセス及び技術により、車輪に良好な総合的な機械的特性を与え、生産を制御しやすい高靭性鉄道輸送用ベイナイト鋼車輪の製造方法をさらに提供する。 The present invention further provides a method for producing a toughness bainite steel wheel for rail transport, which provides the wheel with good overall mechanical properties and is easy to control production by means of a heat treatment process and technique.
本発明による高靭性鉄道輸送用ベイナイト鋼車輪は、重量パーセントで、
炭素C:0.10〜0.40%、ケイ素Si:1.00〜2.00%、マンガンMn:1.00〜2.50%、
ニッケルNi:0.20〜1.00%、希土類RE:0.001 〜0.040%、
リンP≦0.020%、硫黄S≦0.020%を含み、
残部は鉄及び不可避的残留元素であり、
且つ、1.50%≦Si+Ni≦2.50%、2.00%≦Si+Mn≦4.00%である。
The toughness rail transport bainite steel wheels according to the present invention are, by weight percent,
Carbon C: 0.10 to 0.40%, Silicon Si: 1.00 to 2.00%, Manganese Mn: 1.00 to 2.50%,
Nickel Ni: 0.25 to 1.00%, rare earth RE: 0.001 to 0.040%,
Containing phosphorus P ≤ 0.020% and sulfur S ≤ 0.020%
The rest is iron and unavoidable residual elements
Moreover, 1.50% ≦ Si + Ni ≦ 2.50% and 2.00% ≦ Si + Mn ≦ 4.00%.
好ましくは、前記高靭性鉄道輸送用ベイナイト鋼車輪は、重量パーセントで、
炭素C:0.15〜0.25%、ケイ素Si:1.20〜1.80%、マンガンMn:1.60〜2.10%、
ニッケルNi:0.20〜0.80%、希土類RE:0.010 〜0.040%、リンP≦0.020%、硫黄S≦0.020%を含み、残部は鉄及び不可避的残留元素であり、且つ、1.50%≦Si+Ni≦2.50%、2.00%≦Si+Mn≦4.00%である。
Preferably, the toughness rail transport bainite steel wheels are in percent by weight.
Carbon C: 0.15-0.25%, Silicon Si: 1.20 to 1.80%, Manganese Mn: 1.60 to 2.10%,
Nickel Ni: 0.25 to 0.80%, rare earth RE: 0.010 to 0.040%, phosphorus P ≤ 0.020%, sulfur S ≤ 0.020%, the balance is iron and unavoidable residual elements And 1.50% ≦ Si + Ni ≦ 2.50%, 2.00% ≦ Si + Mn ≦ 4.00%.
好ましくは、前記高靭性鉄道輸送用ベイナイト鋼車輪は、重量パーセントで、
炭素C:0.20%、ケイ素Si:1.45%、マンガンMn:1.92%、
ニッケルNi:0.35%、希土類RE:0.018%、リンP:0.013%、硫黄S:0.008%を含み、残部は鉄及び不可避的不純物元素である。
Preferably, the toughness rail transport bainite steel wheels are in percent by weight.
Carbon C: 0.20%, Silicon Si: 1.45%, Manganese Mn: 1.92%,
It contains nickel Ni: 0.35%, rare earth RE: 0.018%, phosphorus P: 0.013%, sulfur S: 0.008%, and the balance is iron and unavoidable impurity elements.
SiとMnの合計含有量が2%未満である場合、鋼の焼入性が低下し、炭化物が生成しやすくなり、強度と靭性に優れた炭化物フリーベイナイト組織を得るためには不利となる。SiとMnの合計含有量が4%を超えると、鋼の焼入性が高すぎ、マルテンサイトなどの望ましくない組織を形成しやすくなり、生産制御が困難となる。 When the total content of Si and Mn is less than 2%, the hardenability of the steel is lowered, carbides are easily formed, which is disadvantageous for obtaining a carbide-free bainite structure having excellent strength and toughness. If the total content of Si and Mn exceeds 4%, the hardenability of the steel is too high, and it becomes easy to form an undesired structure such as martensite, which makes production control difficult.
SiとNiの合計含有量が1.5%未満である場合、鋼に炭化物が生成しやすくなり、強度と靭性に優れた炭化物フリーベイナイト組織を得るためには不利となる。SiとNiの合計含有量が2.5%を超えた場合、元素の作用を効果的に発揮することができず、コストも上昇する。 When the total content of Si and Ni is less than 1.5%, carbides are likely to be formed in the steel, which is disadvantageous for obtaining a carbide-free bainite structure having excellent strength and toughness. If the total content of Si and Ni exceeds 2.5%, the action of the element cannot be effectively exerted and the cost increases.
得られた車輪の微細組織については、車輪リム踏面下から40mm以内の金属組織は炭化物フリーベイナイト組織であり、即ち、ナノスケールのラス状の過飽和フェライトであり、ラス状の過飽和フェライトの中間にはナノスケールの薄膜状の炭素リッチ残留オーステナイトがあり、残留オーステナイトの体積パーセントは4%〜15%である。リムの微細構造は、過飽和フェライト及び炭素リッチ残留オーステナイトにより構成された複相構造であり、そのサイズはナノスケールであり、前記ナノスケールは1nm〜999nmの長さを意味する。 Regarding the obtained fine structure of the wheel, the metal structure within 40 mm from the bottom of the wheel rim tread is a carbide free bainite structure, that is, a nanoscale lath-shaped hypersaturated ferrite, and in the middle of the lath-shaped supersaturated ferrite. There are nanoscale thin carbon-rich retained austenite, with a volume percent of retained austenite ranging from 4% to 15%. The microstructure of the rim is a multiphase structure composed of supersaturated ferrite and carbon-rich retained austenite, the size of which is nanoscale, which means a length of 1 nm to 999 nm.
本発明による車輪は、貨車の車輪及び客車の車輪、並びに鉄道輸送の他の部品及び類似の部品の生産に適用できる。 The wheels according to the invention can be applied to the production of freight car wheels and passenger car wheels, as well as other and similar parts of rail transport.
本発明による高靭性鉄道輸送用ベイナイト鋼車輪の製造方法は、製錬、精錬、成形及び熱処理プロセスを含む。製錬及び成形のプロセスでは、従来技術を使用する。熱処理プロセスでは、
成形された車輪をオーステナイト化温度に加熱し、リム踏面を水噴射で400℃以下に強化冷却し、焼き戻し処理する。前記オーステナイト化温度への加熱は、具体的には、860〜930℃に加熱し、2.0〜2.5時間保温する。前記焼き戻し処理では、車輪を400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷し、又は、リム踏面を水噴射で400℃以下に強化冷却し、室温に空冷し、その間、スポーク板部、車輪ハブの残留熱によって自己焼き戻しを行う。
The method for producing a bainite steel wheel for high toughness railway transportation according to the present invention includes a smelting, refining, forming and heat treatment process. Conventional techniques are used in the smelting and molding process. In the heat treatment process
The molded wheel is heated to an austenitizing temperature, the rim tread is reinforced and cooled to 400 ° C. or lower by water injection, and tempered. Specifically, the heating to the austenitizing temperature is carried out at 860 to 930 ° C. and kept warm for 2.0 to 2.5 hours. In the tempering process, the wheels are tempered at a medium / low temperature of less than 400 ° C. for 30 minutes or more, and then air-cooled to room temperature, or the rim tread is reinforced and cooled to 400 ° C. or lower by water injection and air-cooled to room temperature. During that time, self-cooling is performed by the residual heat of the spoke plate and the wheel hub.
熱処理プロセスでは、成形後の高温の残留熱により、成形された車輪のリム踏面を直接水の噴射で400℃以下に強化冷却し、焼き戻しで処理することもできる。前記焼き戻し処理では、車輪を400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷し、又は、リム踏面を水噴射で400℃以下に強化冷却し、室温に空冷し、その間、スポーク板部、車輪ハブの残留熱によって自己焼き戻しを行う。 In the heat treatment process, the rim tread surface of the molded wheel can be reinforced and cooled to 400 ° C. or lower by direct water injection by the high temperature residual heat after molding, and can be treated by tempering. In the tempering process, the wheels are tempered at a medium / low temperature of less than 400 ° C. for 30 minutes or more, and then air-cooled to room temperature, or the rim tread is reinforced and cooled to 400 ° C. or lower by water injection and air-cooled to room temperature. During that time, self-cooling is performed by the residual heat of the spoke plate and the wheel hub.
熱処理プロセスでは、車輪を成形した後、車輪を400℃以下に空冷し、焼き戻しで処理することもできる。焼き戻し処理では、車輪を400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷し、又は、400℃以下に空冷し、室温に空冷し、その間、スポーク板部、車輪ハブの残留熱によって自己焼き戻しを行う。 In the heat treatment process, after the wheels are molded, the wheels can be air-cooled to 400 ° C. or lower and then tempered. In the tempering process, the wheels are tempered at a medium / low temperature of less than 400 ° C. for 30 minutes or more, and then air-cooled to room temperature after tempering, or air-cooled to 400 ° C. or lower and air-cooled to room temperature, during which the spoke plate portion, Self-burning is performed by the residual heat of the wheel hub.
具体的には、前記熱処理工程は、以下のいずれかの方法である。
車輪をオーステナイト化温度に加熱し、リム踏面を水噴射で400℃以下に強化冷却し、室温に空冷し、その間、残留熱によって自己焼き戻しを行う。
または、車輪をオーステナイト化温度に加熱し、リム踏面を噴水で400℃以下に強化冷却し、400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷する。
Specifically, the heat treatment step is any of the following methods.
The wheels are heated to austenitizing temperature, the rim tread is reinforced and cooled to 400 ° C. or lower by water injection, air-cooled to room temperature, and self-tempering is performed by residual heat during that time.
Alternatively, the wheels are heated to an austenitizing temperature, the rim tread is reinforced and cooled to 400 ° C. or lower with a fountain, tempered at a medium or low temperature of less than 400 ° C. for 30 minutes or more, and then air-cooled to room temperature after tempering.
前記オーステナイト化温度への加熱は、具体的には、860〜930℃に加熱し、2.0〜2.5時間保温する。 Specifically, the heating to the austenitizing temperature is carried out at 860 to 930 ° C. and kept warm for 2.0 to 2.5 hours.
または、車輪成形後の高温の残留熱を用いて、リム踏面を水噴射で400℃以下に強化冷却し、室温に空冷し、その間、スポーク板部、車輪ハブの残留熱によって自己焼き戻しを行う。 Alternatively, using the high-temperature residual heat after wheel molding, the rim tread is reinforced and cooled to 400 ° C or lower by water injection, air-cooled to room temperature, and during that time, self-tempering is performed by the residual heat of the spoke plate and wheel hub. ..
または、車輪成形後の高温の残留熱を用いて、リム踏面を水噴射で400℃以下に強化冷却し、400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷する。
または、車輪を成形した後、車輪を400℃以下に空冷し、その間、スポーク板部、車輪ハブの残留熱によって自己焼き戻しを行う。
Alternatively, using the high-temperature residual heat after wheel molding, the rim tread is reinforced and cooled to 400 ° C or lower by water injection, tempered at a medium or low temperature of less than 400 ° C for 30 minutes or more, and air-cooled to room temperature after tempering. ..
Alternatively, after molding the wheel, the wheel is air-cooled to 400 ° C. or lower, and during that time, self-tempering is performed by the residual heat of the spoke plate portion and the wheel hub.
または、車輪を成形した後、車輪を400℃以下に空冷してから、400℃未満の中低温で30分以上焼き戻しして、焼き戻し後に室温に空冷する。 Alternatively, after molding the wheel, the wheel is air-cooled to 400 ° C. or lower, then tempered at a medium / low temperature of less than 400 ° C. for 30 minutes or more, and after tempering, air-cooled to room temperature.
本発明における各元素の作用は以下のとおりである。
C含有量については、次のとおりである。Cは、鋼中の基本元素であり、隙間固溶硬化及び析出強化の効果が高い。炭素含有量の増加に伴い、鋼の強度が向上し、靭性が低下する。炭素は、フェライトよりもオーステナイト中の溶解度がはるかに大きく、有効なオーステナイト安定化元素である。鋼中の炭化物の体積分率は炭素含有量に正比例する。炭化物フリーベイナイト組織を得るために、材料の硬度がさらに向上し、特に、材料の降伏強度が向上するように、過冷却オーステナイト及び過飽和フェライトに固溶された一定のC含有量を確保する必要がある。C含有量が0.40%を超えると、セメンタイトの析出が起こり、鋼の靭性が低下し、C含有量が0.10%未満である場合、フェライトの過飽和度が低下し、鋼の強度が低下するため、炭素含有量の合理的な範囲は0.10〜0.40%であることが好ましい。
The action of each element in the present invention is as follows.
The C content is as follows. C is a basic element in steel and has a high effect of crevice solid solution hardening and precipitation strengthening. As the carbon content increases, the strength of the steel increases and the toughness decreases. Carbon is an effective austenite stabilizing element with a much higher solubility in austenite than ferrite. The volume fraction of carbides in steel is directly proportional to the carbon content. In order to obtain a carbide-free bainite structure, it is necessary to secure a constant C content dissolved in supercooled austenite and supersaturated ferrite so that the hardness of the material is further improved, and in particular, the yield strength of the material is improved. is there. If the C content exceeds 0.40%, cementite precipitation will occur and the toughness of the steel will decrease. If the C content is less than 0.10%, the supersaturation of ferrite will decrease and the strength of the steel will increase. The rational range of carbon content is preferably 0.10 to 0.40% because it decreases.
Si含有量については、以下のとおりである。Siは、鋼中の基本合金元素であり、一般的に使用される脱酸剤であり、その原子半径は鉄原子の半径より小さく、オーステナイトとフェライトに対する固溶強化の効果が高く、オーステナイトの剪断強度が向上する。Siは、非炭化物形成元素であり、セメンタイトの析出を阻止し、ベイナイト−フェライトの間に炭素リッチオーステナイト薄膜及び(M−A)島状組織の形成を促進し、炭化物フリーベイナイト鋼を得るための主要元素である。Siはまた、セメンタイトの析出を阻止し、過冷オーステナイトの分解による炭化物の析出を防止することもできる。300℃〜400℃での焼き戻し中に、セメンタイトの析出は完全に抑制され、オーステナイトの熱安定性及び機械的安定性が向上する。鋼中のSi含有量が2.00%を超えると、初析フェライトの析出傾向が増加し、残留オーステナイトの量が増加し、鋼の強度と靭性が低下し、Si含有量が1.00%未満である場合、鋼中にセメンタイトが析出しやすく、炭化物フリーベイナイト組織が得られにくいため、Si含有量を1.00〜2.00%に制御する必要がある。 The Si content is as follows. Si is a basic alloy element in steel and is a commonly used deoxidizer. Its atomic radius is smaller than the radius of iron atom, and it has a high effect of solid solution strengthening on austenite and ferrite, and austenite shearing. Strength is improved. Si is a non-carbide forming element for preventing the precipitation of cementite, promoting the formation of a carbon-rich austenite thin film and (MA) island-like structure between bainite and ferrite, and obtaining a carbide-free bainite steel. It is a major element. Si can also prevent the precipitation of cementite and prevent the precipitation of carbides due to the decomposition of supercooled austenite. During tempering at 300 ° C to 400 ° C, the precipitation of cementite is completely suppressed, and the thermal stability and mechanical stability of austenite are improved. When the Si content in the steel exceeds 2.00%, the precipitation tendency of proeutectoid ferrite increases, the amount of retained austenite increases, the strength and toughness of the steel decrease, and the Si content is 1.00%. If it is less than, cementite is likely to be precipitated in the steel, and it is difficult to obtain a carbide-free bainite structure. Therefore, it is necessary to control the Si content to 1.00 to 2.00%.
Ni含有量については、以下のとおりである。Niは、非炭化物形成元素であり、ベイナイト変態中の炭化物の析出を抑制することができるので、ベイナイトフェライトのラス間に安定したオーステナイト薄膜が形成され、炭化物フリーベイナイト組織の形成に有利である。Niは、鋼の強度及び靭性を向上させることができ、高い衝撃靭性を得るために不可欠な合金元素であり、衝撃靭性転移温度を低下させる。Ni含有量が0.20%未満である場合、炭化物フリーベイナイトの形成に不利となり、Ni含有量が1.00%を超えると、鋼の強度と靭性への寄与率が大きく低下し、生産コストが上昇するため、Ni含有量を0.20〜1.00%に制御する必要がある。 The Ni content is as follows. Since Ni is a non-carbide forming element and can suppress the precipitation of carbides during bainite transformation, a stable austenite thin film is formed between bainite ferrite laths, which is advantageous for forming a carbide-free bainite structure. Ni is an alloying element that can improve the strength and toughness of steel and is indispensable for obtaining high impact toughness, and lowers the impact toughness transition temperature. If the Ni content is less than 0.20%, it is disadvantageous for the formation of carbide free bainite, and if the Ni content exceeds 1.00%, the contribution rate to the strength and toughness of the steel is greatly reduced, and the production cost is reduced. Therefore, it is necessary to control the Ni content to 0.25 to 1.00%.
Mn含有量については、以下のとおりである。Mnは鋼中のオーステナイト安定化元素であり、鋼の焼入性を増加させ、鋼の機械的性質を向上させる。SiとMnの合金量を適切に調整することにより、炭化物析出のない、ベイナイトフェライトラスの間に間隔分布する薄膜状オーステナイト組織、即ち、炭化物フリーベイナイトが得られる。Mnはまた、Pの拡散係数を増大させ、鋼の脆性を増大させることもできる。Mn含有量が1.00%未満である場合、鋼の焼入性が悪く、炭化物フリーベイナイトの取得に不利となり、Mn含有量が2.50%を超えると、鋼の焼入性が著しく向上するが、Pの拡散傾向が著しく増大し、鋼の靭性が低下するため、Mn含有量を1.00〜2.50%に制御する必要がある。 The Mn content is as follows. Mn is an austenite stabilizing element in steel, which increases the hardenability of steel and improves the mechanical properties of steel. By appropriately adjusting the amount of alloy of Si and Mn, a thin-film austenite structure having no carbide precipitation and distributed between bainite ferrite laths, that is, carbide-free bainite can be obtained. Mn can also increase the diffusion coefficient of P and increase the brittleness of steel. If the Mn content is less than 1.00%, the hardenability of the steel is poor, which is disadvantageous for obtaining carbide-free bainite. If the Mn content exceeds 2.50%, the hardenability of the steel is significantly improved. However, since the diffusion tendency of P is remarkably increased and the toughness of steel is lowered, it is necessary to control the Mn content to 1.00 to 2.50%.
RE含有量については、以下のとおりである。鋼中のRE元素の添加は、オーステナイト結晶粒を微細化し、浄化及び変質の作用を有し、粒界での有害不純物の偏析を低減し、粒界を改善し強化し、それによって鋼の強度と靭性を向上させることができる。同時に、REは、介在物の球状化を促進し、鋼の靭性をさらに改善し、材料の切欠き感受性を低下させることができる。RE含有量が多すぎると、その有益な効果が弱まり、同時に鋼の製造コストが上がる。RE含有量が0.001%未満である場合、有害な元素を完全に除去して靭性希土類介在物を形成することができず、RE含有量が0.040%を超えると、RE元素が過剰になり、その効果が発揮できなくなるため、RE含有量が0.001〜0.040%に制御される。 The RE content is as follows. The addition of the RE element in the steel refines the austenite grains, has purifying and altering effects, reduces segregation of harmful impurities at the grain boundaries, improves and strengthens the grain boundaries, thereby strengthening the steel. And toughness can be improved. At the same time, RE can promote spheroidization of inclusions, further improve the toughness of the steel and reduce the notch sensitivity of the material. If the RE content is too high, its beneficial effects are diminished and at the same time the steel manufacturing cost is increased. If the RE content is less than 0.001%, the harmful elements cannot be completely removed to form toughness rare earth inclusions, and if the RE content exceeds 0.040%, the RE element is excessive. The RE content is controlled to 0.001 to 0.040% because the effect cannot be exhibited.
P含有量については、以下のとおりである。中高炭素鋼では、Pが粒界に偏析しやすいので、粒界が弱くなり、鋼の強度及び靭性が低下する。有害な元素として、P≦0.020%の場合、性能に対する大きな悪影響がない。 The P content is as follows. In medium- and high-carbon steels, P is likely to segregate at the grain boundaries, so that the grain boundaries are weakened and the strength and toughness of the steel are lowered. When P ≦ 0.020% as a harmful element, there is no significant adverse effect on performance.
S含有量については、以下のとおりである。Sは粒界に偏析しやすく、他の元素と介在物を形成しやすく、鋼の強度及び靭性が低下する。有害な元素として、S≦0.020%の場合、性能に対する大きな悪影響がない。 The S content is as follows. S tends to segregate at grain boundaries, easily forms inclusions with other elements, and reduces the strength and toughness of steel. When S ≦ 0.020% as a harmful element, there is no significant adverse effect on performance.
鋼の元素設計において、本発明はC−Si−Mn−Ni−RE系を採用し、Mo、V、Cr及びBなどの合金元素を特別に添加しないで、熱処理プロセスを組み合わせて、リムの典型的な組織を炭化物フリーベイナイト、即ち、ナノスケールのラス状の過飽和フェライトにする。中間はナノスケールの薄膜状炭素リッチ残余オーステナイトである。残余オーステナイトは4%〜15%ある。車輪は、優れた強度と靭性、及び低い切欠き感受性などの特徴を有する。このタイプの鋼は、中等焼入性を有し、生産制御が比較的容易であり、コストが低い。希土類元素は、鋼中の介在物を球状化し、粒界を強化することができるので、このタイプの鋼は、20℃の衝撃靭性が高い。Niの添加により、得られたベイナイト鋼はより高い20℃衝撃靭性を有する。 In the elemental design of steel, the present invention adopts the C-Si-Mn-Ni-RE system, which is typical of rims by combining heat treatment processes without adding special alloying elements such as Mo, V, Cr and B. The structure is made into carbide free bainite, that is, nanoscale lath-like supersaturated ferrite. In the middle is nanoscale thin-film carbon-rich residual austenite. Residual austenite is 4% to 15%. Wheels have features such as excellent strength and toughness, and low notch sensitivity. This type of steel has moderate hardenability, is relatively easy to control production, and is low cost. Rare earth elements can spheroidize inclusions in steel and strengthen grain boundaries, so this type of steel has high impact toughness at 20 ° C. With the addition of Ni, the resulting bainite steel has higher 20 ° C impact toughness.
本発明では、組成及び製造プロセスを設計することにより、車輪の高強度と高靭性の整合性を実現し、車輪の総合的な機械的性質を提供し、車輪のサービス性能を向上させる目的を達成し、鉄道輸送の他の主要部品及び類似の部品の製造にも使用できる。 In the present invention, by designing the composition and manufacturing process, the objectives of achieving high strength and high toughness consistency of the wheel, providing the overall mechanical properties of the wheel, and improving the service performance of the wheel are achieved. It can also be used to manufacture other major parts of rail transport and similar parts.
本発明は、主にSi及びNi非炭化物形成元素を利用して、フェライト中の炭素の活性を改善し、炭化物の析出を遅延及び抑制し、適切な成形プロセス(鍛造圧延又はモデル鋳造などを含む)、特に熱処理プロセスにより、鋼の調合に応じて、リム踏面を水噴射で強化冷却することによって、車輪リムに炭化物フリーベイナイト組織を与え、残留熱を利用して自己焼き戻しするか又は中低温で焼き戻しして、車輪の組織安定性及び車輪の総合的な機械的性質をさらに改善する。同時に、Mn元素の優れたオーステナイト安定化効果により、鋼の焼入性が増加し、鋼の強度が向上する。希土類元素は、鋼中の水素などの有害ガスを吸着する機能を有し、鋼中の不可避的介在物を球状化し、鋼の靭性をさらに向上させる。Si、Ni、Mn、及びREの含有量を適切に調整することにより、リムは炭化物析出のない炭化物フリーベイナイト組織を得て、車輪の強度及び靭性がさらに向上する。Ni元素の優れた固溶強化の特徴により、靭性指数が低下せずに、強度と靭性がさらに向上する。また、Ni元素の耐食性により、車輪の大気腐食耐性が実現され、車輪の使用寿命が延び、高靭性ベイナイト鋼車輪が実現し、鉄道輸送運行条件の厳しい要求が満たされる。 The present invention mainly utilizes Si and Ni non-carbide forming elements to improve the activity of carbon in ferrite, delay and suppress the precipitation of carbides, and include an appropriate forming process (forging rolling or model casting, etc.). ), Especially by heat treatment process, depending on the steel formulation, the rim tread is reinforced and cooled by water injection to give the wheel rim a carbide-free bainite structure and self-tempered using residual heat or at medium and low temperatures. Tempered with to further improve the structural stability of the wheel and the overall mechanical properties of the wheel. At the same time, the excellent austenite stabilizing effect of the Mn element increases the hardenability of the steel and improves the strength of the steel. Rare earth elements have the function of adsorbing harmful gases such as hydrogen in steel, spheroidizing unavoidable inclusions in steel, and further improving the toughness of steel. By appropriately adjusting the contents of Si, Ni, Mn, and RE, the rim obtains a carbide-free bainite structure without carbide precipitation, and the strength and toughness of the wheel are further improved. Due to the excellent solid solution strengthening characteristics of the Ni element, the strength and toughness are further improved without lowering the toughness index. In addition, the corrosion resistance of the Ni element realizes resistance to atmospheric corrosion of the wheel, extends the service life of the wheel, realizes high toughness bainite steel wheel, and meets the strict requirements of railway transportation operating conditions.
従来技術と比較して、本発明により製造されたベイナイト鋼車輪は、CL60車輪と比較して、リムの強度と靭性の整合性が著しく向上する。それにより、安全性が保証される前提で、車輪の降伏強度、靭性及び低温靭性が効果的に向上し、車輪の転がり接触疲労(RCF)耐性が向上し、車輪の耐ヒートクラック性が向上し、車輪の耐食性が向上し、車輪の切欠き感受性が低下し、車輪の使用中の剥離や剥落の可能性が低減され、車輪踏面の均一な摩耗及び少ない旋盤加工が実現され、車輪リム金属の仕様効率が向上し、車輪の使用寿命及び総合的な利益が改善され、一定の経済的及び社会的利益がある。 Compared with the prior art, the bainite steel wheels manufactured according to the present invention have significantly improved rim strength and toughness consistency as compared to CL60 wheels. As a result, on the premise that safety is guaranteed, the yield strength, toughness and low temperature toughness of the wheel are effectively improved, the rolling contact fatigue (RCF) resistance of the wheel is improved, and the heat crack resistance of the wheel is improved. Improves wheel corrosion resistance, reduces wheel notch sensitivity, reduces the possibility of peeling and peeling during use of the wheel, achieves uniform wear of the wheel tread and less laminating, wheel rim metal Specification efficiency is improved, wheel life and overall benefits are improved, and there are certain economic and social benefits.
実施例1、2、3における車輪鋼の化学組成の重量パーセントを表2に示す。実施例1、2、3はいずれも、電気炉製錬を用い、LF+RH精錬真空脱ガス後に直接φ380mmの丸ビレットを連続鋳造し、鋼塊切断、加熱及び輾圧圧延、熱処理、仕上げ加工を行った後に、直径が915mmの車輪を形成した。 Table 2 shows the weight percent of the chemical composition of the wheel steel in Examples 1, 2 and 3. In all of Examples 1, 2 and 3, electric furnace smelting is used, and after LF + RH refining vacuum degassing, a round billet having a diameter of 380 mm is continuously cast, and steel ingot cutting, heating and pressure rolling, heat treatment, and finishing are performed. After that, a wheel having a diameter of 915 mm was formed.
<実施例1>
高靭性鉄道輸送用ベイナイト鋼車輪は、下記の表2に示す重量パーセントの元素を含有する。
<Example 1>
Bainite steel wheels for high toughness rail transport contain the weight percent elements shown in Table 2 below.
高靭性鉄道輸送用ベイナイト鋼車輪の製造方法は、以下のステップを含む:表2の実施例1のような化学組成を有する溶鋼を、電気炉製鋼工程、LF炉精錬工程、RH真空処理工程、丸ビレット連続鋳造工程、鋼塊切断圧延工程、熱処理工程、加工、完成品検査工程を経て、車輪を形成した。前記熱処理工程では、860〜930℃に加熱し2.0〜2.5時間保温し、リムを噴水で400℃以下に冷却し、280℃で4.5〜5.0時間焼き戻し処理した。 A method for producing a tough rail transport baynite steel wheel includes the following steps: a molten steel having a chemical composition as shown in Example 1 of Table 2 is subjected to an electric furnace steelmaking process, an LF furnace refining process, an RH vacuum processing process, and the like. The wheels were formed through a round billet continuous casting process, a steel ingot cutting and rolling process, a heat treatment process, processing, and a finished product inspection process. In the heat treatment step, the mixture was heated to 860 to 930 ° C. and kept warm for 2.0 to 2.5 hours, the rim was cooled to 400 ° C. or lower with a fountain, and tempered at 280 ° C. for 4.5 to 5.0 hours.
図2a、図2bに示すように、本実施例で製造された車輪リムの金属組織は主に炭化物フリーベイナイト組織である。本実施例の車輪の機械的性能を表3に示す。車輪実物の強度と靭性の整合性はCL60車輪よりも優れている。 As shown in FIGS. 2a and 2b, the metal structure of the wheel rim manufactured in this embodiment is mainly a carbide free bainite structure. Table 3 shows the mechanical performance of the wheels of this embodiment. The consistency between the strength and toughness of the actual wheel is superior to that of the CL60 wheel.
<実施例2>
高靭性鉄道輸送用ベイナイト鋼車輪は、下記の表2に示す重量パーセントの元素を含有する。
<Example 2>
Bainite steel wheels for high toughness rail transport contain the weight percent elements shown in Table 2 below.
高靭性鉄道輸送用ベイナイト鋼車輪の製造方法は、以下のステップを含む:表2の実施例2のような化学組成を有する溶鋼を、電気炉製鋼工程、LF炉精錬工程、RH真空処理工程、丸ビレット連続鋳造工程、鋼塊切断圧延工程、熱処理工程、加工、完成品検査工程を経て、車輪を形成した。前記熱処理工程では、860〜930℃に加熱し2.0〜2.5時間保温し、リムを噴水で400℃以下に冷却し、240℃で4.5〜5.0時間焼き戻し処理した。 A method for producing a tough rail transport baynite steel wheel includes the following steps: a molten steel having a chemical composition as shown in Example 2 of Table 2 is subjected to an electric furnace steelmaking process, an LF furnace refining process, an RH vacuum processing process, and the like. The wheels were formed through a round billet continuous casting process, a steel ingot cutting and rolling process, a heat treatment process, processing, and a finished product inspection process. In the heat treatment step, the mixture was heated to 860 to 930 ° C. and kept warm for 2.0 to 2.5 hours, the rim was cooled to 400 ° C. or lower with a fountain, and tempered at 240 ° C. for 4.5 to 5.0 hours.
図3a、3b、3c、3dに示すように、本実施例で製造された車輪リムの金属組織は主に炭化物フリーベイナイトである。本実施例の車輪の機械的性能を表3に示す。車輪実物の強度と靭性の整合性はCL60車輪よりも優れている。 As shown in FIGS. 3a, 3b, 3c and 3d, the metal structure of the wheel rim manufactured in this embodiment is mainly carbide free bainite. Table 3 shows the mechanical performance of the wheels of this embodiment. The consistency between the strength and toughness of the actual wheel is superior to that of the CL60 wheel.
<実施例3>
高靭性鉄道輸送用ベイナイト鋼車輪は、下記の表2に示す重量パーセントの元素を含有する。
<Example 3>
Bainite steel wheels for high toughness rail transport contain the weight percent elements shown in Table 2 below.
高靭性鉄道輸送用ベイナイト鋼車輪の製造方法は、以下のステップを含む:表2の実施例3のような化学組成を有する溶鋼を、電気炉製鋼工程、LF炉精錬工程、RH真空処理工程、丸ビレット連続鋳造工程、鋼塊切断圧延工程、熱処理工程、加工、完成品検査工程を経て、車輪を形成した。前記熱処理工程では、860〜930℃に加熱し2.0〜2.5時間保温し、リムを噴水で400℃以下に冷却し、200℃で4.5〜5.0時間焼き戻し処理した。 A method for producing a tough rail transport baynite steel wheel includes the following steps: a molten steel having a chemical composition as shown in Example 3 of Table 2 is subjected to an electric furnace steelmaking process, an LF furnace refining process, an RH vacuum processing process, and the like. The wheels were formed through a round billet continuous casting process, a steel ingot cutting and rolling process, a heat treatment process, processing, and a finished product inspection process. In the heat treatment step, the mixture was heated to 860 to 930 ° C. and kept warm for 2.0 to 2.5 hours, the rim was cooled to 400 ° C. or lower with a fountain, and tempered at 200 ° C. for 4.5 to 5.0 hours.
図4a、4bに示すように、本実施例で製造された車輪リムの金属組織は主に炭化物フリーベイナイトである。本実施例の車輪の機械的性能を表3に示す。車輪実物の強度と靭性の整合性はCL60車輪よりも優れている。 As shown in FIGS. 4a and 4b, the metal structure of the wheel rim manufactured in this example is mainly carbide free bainite. Table 3 shows the mechanical performance of the wheels of this embodiment. The consistency between the strength and toughness of the actual wheel is superior to that of the CL60 wheel.
Claims (8)
炭素C:0.10〜0.40%、ケイ素Si:1.00〜2.00%、マンガンMn:1.00〜2.50%、
ニッケルNi:0.20〜1.00%、希土類RE:0.001 〜0.040%、
リンP≦0.020%、硫黄S≦0.020%を含み、
残部は鉄及び不可避的残留元素であり、
且つ、1.50%≦Si+Ni≦2.50%、2.00%≦Si+Mn≦4.00%である、ことを特徴とする高靭性鉄道輸送用ベイナイト鋼車輪。 Bainite steel wheels for high toughness rail transport, by weight percent,
Carbon C: 0.10 to 0.40%, Silicon Si: 1.00 to 2.00%, Manganese Mn: 1.00 to 2.50%,
Nickel Ni: 0.25 to 1.00%, rare earth RE: 0.001 to 0.040%,
Containing phosphorus P ≤ 0.020% and sulfur S ≤ 0.020%
The rest is iron and unavoidable residual elements
A bainite steel wheel for rail transportation with high toughness, characterized in that 1.50% ≤ Si + Ni ≤ 2.50% and 2.00% ≤ Si + Mn ≤ 4.00%.
炭素C:0.15〜0.25%、ケイ素Si:1.20〜1.80%、マンガンMn:1.60〜2.10%、
ニッケルNi:0.20〜0.80%、希土類RE:0.010 〜0.040%、リンP≦0.020%、硫黄S≦0.020%を含み、
残部は鉄及び不可避的残留元素であり、且つ、1.50%≦Si+Ni≦2.50%、2.00%≦Si+Mn≦4.00%である、ことを特徴とする請求項1に記載の高靭性鉄道輸送用ベイナイト鋼車輪。 The toughness rail transport bainite steel wheels are, by weight percent,
Carbon C: 0.15-0.25%, Silicon Si: 1.20 to 1.80%, Manganese Mn: 1.60 to 2.10%,
Nickel Ni: 0.25 to 0.80%, rare earth RE: 0.010 to 0.040%, phosphorus P ≤ 0.020%, sulfur S ≤ 0.020%.
The first aspect of claim 1, wherein the balance is iron and an unavoidable residual element, and 1.50% ≤ Si + Ni ≤ 2.50% and 2.00% ≤ Si + Mn ≤ 4.00%. Bainite steel wheels for high toughness rail transport.
炭素C:0.20%、ケイ素Si:1.45%、マンガンMn:1.92%、ニッケルNi:0.35%、希土類RE:0.018%、リンンP:0.013%、硫黄S:0.008%を含み、残部は鉄及び不可避的残留元素である、ことを特徴とする請求項1又は2に記載の高靭性鉄道輸送用ベイナイト鋼車輪。 The toughness rail transport bainite steel wheels are, by weight percent,
Carbon C: 0.20%, Silicon Si: 1.45%, Manganese Mn: 1.92%, Nickel Ni: 0.35%, Rare Earth RE: 0.018%, Linn P: 0.013%, Sulfur S The bainite steel wheel for high toughness rail transport according to claim 1 or 2, wherein it contains 0.008% and the balance is iron and unavoidable residual elements.
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| PCT/CN2017/091930 WO2018006845A1 (en) | 2016-07-06 | 2017-07-06 | High toughness bainitic steel wheel for rail transit, and manufacturing method therefor |
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| CN106435367B (en) * | 2016-11-23 | 2018-07-10 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of bainite rail and preparation method thereof |
| AT519669B1 (en) * | 2017-06-07 | 2018-09-15 | Voestalpine Schienen Gmbh | Rail part and method for producing a rail part |
| CN109182920A (en) * | 2018-06-20 | 2019-01-11 | 马钢(集团)控股有限公司 | A kind of rail traffic bainitic steel wheel and its manufacturing method of heat resistance and corrosive environment |
| CN118945216A (en) * | 2019-03-13 | 2024-11-12 | 交互数字专利控股公司 | Dynamic network capability configuration |
| CN114107821B (en) * | 2021-11-26 | 2022-07-08 | 钢铁研究总院 | High-toughness ultrahigh-strength steel and manufacturing method thereof |
| CN114058965B (en) * | 2021-11-30 | 2022-05-13 | 宝武集团马钢轨交材料科技有限公司 | High-contact-fatigue-resistance microalloyed steel wheel and production method thereof |
| CN114908291B (en) * | 2022-04-27 | 2023-04-14 | 鞍钢股份有限公司 | A kind of 850MPa level precipitation strengthening type hot-rolled bainite steel and its production method |
| CN115058666B (en) * | 2022-06-30 | 2023-08-11 | 马鞍山钢铁股份有限公司 | Wheel rim for high corrosion resistance elastic wheel and heat treatment process thereof |
| CN115216612B (en) * | 2022-07-22 | 2024-04-05 | 攀钢集团攀枝花钢铁研究院有限公司 | A heat treatment process for high-strength and high-toughness bainite rail |
| CN115558765B (en) * | 2022-09-27 | 2025-01-10 | 马鞍山钢铁股份有限公司 | Wheel capable of reducing hardness of near surface layer of tread and production method thereof |
| CN118756040A (en) * | 2024-06-12 | 2024-10-11 | 包头钢铁(集团)有限责任公司 | A method for reducing the cracking rate of flash welding of wheel steel for 380MPa grade rim |
| CN118531320B (en) * | 2024-07-29 | 2024-10-18 | 宝武集团马钢轨交材料科技有限公司 | Steel for high-fatigue-resistance high-speed wheel, wheel and manufacturing method of wheel |
| CN118854029B (en) * | 2024-08-12 | 2026-03-13 | 攀钢集团攀枝花钢铁研究院有限公司 | A high-strength, high-toughness, ultra-fine bainitic railway steel and its production method |
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| JP4068950B2 (en) * | 2002-12-06 | 2008-03-26 | 株式会社神戸製鋼所 | High-strength steel sheet, warm-working method, and warm-worked high-strength member or parts |
| ITMI20032370A1 (en) * | 2003-12-03 | 2005-06-04 | Lucchini Sidermeccanica S P A | HIGH BAINITH MICROLEGATE STEEL FOR FATIGUE RESISTANCE |
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| CN100395366C (en) * | 2004-12-31 | 2008-06-18 | 马鞍山钢铁股份有限公司 | A kind of bainite steel for railway vehicle wheel |
| CN101220441A (en) * | 2005-04-18 | 2008-07-16 | 河南省强力机械有限公司 | Meta-bainite steel and application of the same in railway industry |
| CN101326298A (en) * | 2005-12-19 | 2008-12-17 | 株式会社神户制钢所 | Steel plate excellent in suppressing fatigue crack growth |
| CN100567549C (en) * | 2008-08-14 | 2009-12-09 | 南京钢铁股份有限公司 | A kind of carbides-free bainite wear resistant steel plate and production technique thereof |
| KR101185232B1 (en) * | 2010-08-30 | 2012-09-21 | 현대제철 주식회사 | Api hot-rolled steel with high strength and high toughness and method for manufacturing the api hot-rolled steel |
| US20130192726A1 (en) * | 2010-10-12 | 2013-08-01 | Tata Steel Ijmuiden B.V. | Method of hot forming a steel blank and the hot formed part |
| CN103409689A (en) * | 2013-07-31 | 2013-11-27 | 内蒙古包钢钢联股份有限公司 | Bainitic/martensitic steel treated by rare earth and special for railway frog |
| CN103397275B (en) * | 2013-08-09 | 2016-04-27 | 钢铁研究总院 | A kind of martensite series wear resisting steel and preparation method thereof |
| CN105671429A (en) * | 2016-03-30 | 2016-06-15 | 内蒙古第一机械集团有限公司 | High-performance E+ steel containing rare earth |
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