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JP6779575B2 - Wash-free rice and manufacturing method of wash-free rice - Google Patents
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JP6779575B2 - Wash-free rice and manufacturing method of wash-free rice - Google Patents

Wash-free rice and manufacturing method of wash-free rice Download PDF

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JP6779575B2
JP6779575B2 JP2016244880A JP2016244880A JP6779575B2 JP 6779575 B2 JP6779575 B2 JP 6779575B2 JP 2016244880 A JP2016244880 A JP 2016244880A JP 2016244880 A JP2016244880 A JP 2016244880A JP 6779575 B2 JP6779575 B2 JP 6779575B2
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rice
fat
oil
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wash
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JP2018093842A (en
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鈴木 順子
順子 鈴木
生稲 淳一
淳一 生稲
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Nisshin Oillio Group Ltd
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Description

本発明は、ご飯のほぐれ性や艶、食感を向上させ、風味に優れた炊飯が得られる無洗米、およびその製造方法に関する。 The present invention relates to non-washed rice that improves the looseness, luster, and texture of cooked rice and can obtain cooked rice with excellent flavor, and a method for producing the same.

従来、ご飯のほぐれ性や艶、風味等を改善するために炊飯時に、水につけた生米に食用油を添加されることが行われている。これらの十分な効果を得るために、水との親和性が悪い食用油を均一に分散させる必要があり、食用油に乳化剤を添加する方法(特許文献1)、食用油中に中鎖脂肪酸トリグリセリドを含む方法(特許文献2)が提案されている。しかし、食用油の分散性は、炊飯スケールや炊飯釜の形状にも影響されるため、添加する油脂量や乳化剤含有量等を微調整する必要があった。
特開2002−153209号公報 特開2015−198590号公報
Conventionally, cooking oil has been added to raw rice soaked in water at the time of cooking rice in order to improve the looseness, luster, flavor and the like of the rice. In order to obtain these sufficient effects, it is necessary to uniformly disperse edible oil having poor affinity with water, a method of adding an emulsifier to edible oil (Patent Document 1), medium-chain fatty acid triglyceride in edible oil. (Patent Document 2) has been proposed. However, since the dispersibility of cooking oil is affected by the shape of the rice cooking scale and the rice cooking pot, it is necessary to finely adjust the amount of oil and fat to be added, the content of emulsifier, and the like.
Japanese Unexamined Patent Publication No. 2002-153209 Japanese Unexamined Patent Publication No. 2015-198590

本発明の課題は、炊飯時に食用油を添加することなく、ほぐれ性や艶、風味等が均一な炊飯を得ることができる無洗米を提供することである。 An object of the present invention is to provide non-washed rice capable of obtaining cooked rice having uniform loosening property, luster, flavor and the like without adding cooking oil at the time of cooking rice.

本発明者らは、鋭意検討を行った結果、特定の条件を満たす固形状の油脂組成物を、生米の表面に付着させることによって、炊飯時に食用油を添加することもなく、さらに、炊飯後の均一な、ほぐれ性や艶、風味等が得られることを見出し、本発明を完成させた。 As a result of diligent studies, the present inventors have adhered a solid oil / fat composition satisfying a specific condition to the surface of raw rice, so that cooking oil is not added at the time of cooking rice, and further, rice is cooked. The present invention was completed by finding that a uniform looseness, luster, flavor, etc. can be obtained later.

すなわち、本発明は、下記の[1]〜[9]を提供する。
[1] 油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物が、生米の表面に付着している、無洗米。
[2] 前記15℃で固形状の油脂組成物が粉末である、[1]に記載の無洗米。
[3] 前記粉末のゆるめ嵩密度が0.1〜0.6g/cm3である、[2]の無洗米。
[4] 前記固形状の油脂組成物に含まれる全トリグリセリドの全量を100質量%とした場合、1位〜3位に炭素数xの直鎖飽和脂肪酸残基Xを有するXXX型トリグリセリドを65〜99質量%と、前記XXX型トリグリセリドの直鎖飽和脂肪酸残基Xの1つを炭素数yの直鎖飽和脂肪酸残基Yに置換した1種以上のX2Y型トリグリセリドを35〜1質量%とを含有する油脂組成物であって、前記炭素数xは10〜12から選択される整数であり、前記炭素数yは、それぞれ独立して、x+2〜x+12から選択される整数でありかつy≦22である、[1]〜[4]のいずれかの無洗米。
[5] 前記XXX型トリグリセリドが80〜99質量%、前記1種以上のX2Y型トリグリセリドの合計が20〜1質量%である[1]〜[4]のいずれかの無洗米。
[6] 前記yが、それぞれ独立して、x+2〜x+10から選択される整数でありかつy≦22である、[1]〜[5]のいずれかの無洗米。
[7] 前記yが、それぞれ独立して、x+4〜x+8から選択される整数でありかつy≦22である、[1]〜[6]のいずれかに記載の無洗米。
[8] 前記15℃で固形状の油脂組成物が、生米100質量部に対して0.3〜15質量部の割合で生米に付着されている、[1]〜[7]のいずれかに記載の無洗米。
[9] 油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物を溶解し、無洗米にスプレーし、その後冷却する、無洗米の製造方法。
[10] 油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有し、15℃で固形状である油脂組成物の粉末を、無洗米に混合する、無洗米の製造方法。
That is, the present invention provides the following [1] to [9].
[1] Non-washed rice in which a solid fat composition at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil adheres to the surface of raw rice. ..
[2] The non-washed rice according to [1], wherein the fat and oil composition solidified at 15 ° C. is a powder.
[3] The wash-free rice according to [2], wherein the loosening bulk density of the powder is 0.1 to 0.6 g / cm 3 .
[4] When the total amount of all triglycerides contained in the solid oil / fat composition is 100% by mass, XXX-type triglycerides having a linear saturated fatty acid residue X having a carbon number x at the 1st to 3rd positions are 65 to 5 99% by mass and 35 to 1% by mass of one or more X2Y type triglycerides in which one of the linear saturated fatty acid residues X of the XXX type triglyceride is replaced with the linear saturated fatty acid residue Y having the number of carbon atoms y. In the fat and oil composition contained, the carbon number x is an integer selected from 10 to 12, and the carbon number y is an integer selected independently from x + 2 to x + 12 and y ≦ 22. The non-washed rice according to any one of [1] to [4].
[5] The non-washed rice according to any one of [1] to [4], wherein the XXX-type triglyceride is 80 to 99% by mass, and the total of the one or more X2Y-type triglycerides is 20 to 1% by mass.
[6] The non-washed rice according to any one of [1] to [5], wherein y is an integer selected independently from x + 2 to x + 10 and y ≦ 22.
[7] The wash-free rice according to any one of [1] to [6], wherein y is an integer selected independently from x + 4 to x + 8 and y ≦ 22.
[8] Any of [1] to [7], wherein the fat and oil composition solid at 15 ° C. is attached to the raw rice at a ratio of 0.3 to 15 parts by mass with respect to 100 parts by mass of the raw rice. Wash-free rice described in Crab.
[9] A solid fat or oil composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat or oil is dissolved at 15 ° C., sprayed on unwashed rice, and then cooled. How to make non-washed rice.
[10] Non-washed rice in which a powder of a fat and oil composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms and being solid at 15 ° C. is mixed with the non-washed rice. Manufacturing method.

本発明によれば、特定の条件を満たす固形状の油脂組成物を、生米の表面に付着させることによって、炊飯時に食用油を添加することもなく、さらに、炊飯後の均一な、ほぐれ性や艶、風味等を有する炊飯が得られる無洗米、および無洗米の製造方法を提供することができる。 According to the present invention, by adhering a solid oil / fat composition satisfying a specific condition to the surface of raw rice, cooking oil is not added at the time of cooking rice, and moreover, uniform loosening property after cooking rice. It is possible to provide a wash-free rice that can be used to cook rice having a gloss, flavor, etc., and a method for producing the wash-free rice.

以下、本発明の「無洗米」について詳細に例示説明する。なお、本発明の実施の形態において、A(数値)〜B(数値)は、A以上B以下を意味する。
<無洗米>
本発明では、後述する固形状の油脂組成物が生米の表面に付着している状態である無洗米である。本発明において、無洗米とは、研ぎ洗いすることなく水を加えて炊くだけで食べられるように加工された米のことであり、精白で少し残ってしまう肌糠(ぬか)をあらかじめ取り去ってあるために、この糠を洗い落とすための研ぎ洗い作業の必要がない米である。肌糠をあらかじめ取り去る方法としては、特に限定するものではないが、水洗い乾燥法・湿式法、乾式法、BG製法、NTWP製法などが挙げられる。なお、無洗米に使用される米は、ジャポニカ種、インディカ種、ジャパニカ種及びそれらの交配によって生じた品種を用いることができる。
Hereinafter, the "wash-free rice" of the present invention will be described in detail. In the embodiment of the present invention, A (numerical value) to B (numerical value) mean A or more and B or less.
<Musenmai>
In the present invention, the non-washed rice is in a state where the solid oil / fat composition described later is attached to the surface of the raw rice. In the present invention, the non-washed rice is rice that has been processed so that it can be eaten simply by adding water and cooking without polishing, and the skin bran that remains a little after polishing has been removed in advance. Therefore, it is rice that does not need to be sharpened to wash off this bran. The method for removing the skin bran in advance is not particularly limited, and examples thereof include a washing / drying method / wet method, a dry method, a BG manufacturing method, and an NTWP manufacturing method. As the rice used for non-washed rice, Japonica rice, Indica rice, Japanica rice and varieties produced by crossing them can be used.

<固形状の油脂組成物>
本発明は、生米の表面に付着している固形状の油脂組成物として、油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物を用いる。生米に付着させる油脂組成物は、長期間、空気(酸素)と接触するので、酸化を防止するために飽和脂肪酸であることが好ましく、また、保存時に生米に付着した油脂組成物が流れ落ちることを防ぐため、作業時のベトツキなどのハンドリングをよくするために油脂組成物は固形状であることが好ましい。そのため、15℃で固形状の油脂組成物を用いることが好ましい。
一方、融点が高すぎる油脂組成物を用いると、炊飯時には、加熱により固形状の油脂組成物は溶解するが、食事時には、冷却し固化することにより、ご飯粒が造粒してしまう可能性がある。そのため、適度な融点を示す炭素数10〜12の直鎖飽和脂肪酸を油脂の構成脂肪酸中に10〜100質量%含有する油脂組成物を用いる。油脂組成物の融点が40℃以下であれば、食事時に直ちに固化することなく好ましく、融点が15〜35℃であることがより好ましく、融点が25〜35℃であることがさらに好ましい。炭素数10〜12の直鎖飽和脂肪酸は、より好ましくはカプリン酸である。炭素数10〜12の直鎖飽和脂肪酸の油脂の構成脂肪酸中の含有量は50〜100質量%がより好ましく、60〜100質量%がさらに好ましい。
<Solid oil and fat composition>
In the present invention, as a solid fat / oil composition adhering to the surface of raw rice, a solid state at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat or oil. Use the oil and fat composition of. Since the fat and oil composition to be attached to the raw rice is in contact with air (oxygen) for a long period of time, it is preferably a saturated fatty acid in order to prevent oxidation, and the fat and oil composition attached to the raw rice runs off during storage. In order to prevent this from happening, it is preferable that the fat and oil composition is in a solid state in order to improve handling such as stickiness during work. Therefore, it is preferable to use an oil / fat composition that is solid at 15 ° C.
On the other hand, if an oil / fat composition having an excessively high melting point is used, the solid oil / fat composition is melted by heating during rice cooking, but there is a possibility that rice grains may be granulated by cooling and solidifying during meals. is there. Therefore, an oil / fat composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms showing an appropriate melting point in the constituent fatty acids of the oil / fat is used. When the melting point of the oil / fat composition is 40 ° C. or lower, it is preferable that it does not solidify immediately at meal time, the melting point is more preferably 15 to 35 ° C., and the melting point is further preferably 25 to 35 ° C. The linear saturated fatty acid having 10 to 12 carbon atoms is more preferably capric acid. The content of the linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids is more preferably 50 to 100% by mass, further preferably 60 to 100% by mass.

本発明で用いる固形状の油脂組成物は、生米の表面に付着している固形状の油脂組成物は、生米に付着させるとき、あるいは付着させた後に粉末状であることが、生米が造粒しない点で好ましい。
本発明で用いる固形状の油脂組成物の粉末時のゆるめ嵩密度は、例えば実質的に油脂のみからなる場合、0.1〜0.6g/cm3、好ましくは0.15〜0.5g/cm3であり、より好ましくは0.2〜0.4g/cm3である。ここで「ゆるめ嵩密度」とは、粉体を自然落下させた状態の充填密度である。ゆるめ嵩密度(g/cm3)の測定は、例えば、内径15mm×25mLのメスシリンダーに、当該メスシリンダーの上部開口端から2cm程度上方からコーティング用粉末油脂組成物の適量を落下させて疎充填し、充填された質量(g)の測定と容量(cm3)の読み取りを行い、cm3当たりの当該コーティング用粉末油脂組成物の質量(g)を算出することで求めることができる。また、ゆるめ嵩密度は、(株)蔵持科学器械製作所のカサ比重測定器を使用し、JIS K−6720(又はISO 1060−1及び2)に基づいて測定したカサ比重から算出することもできる。具体的には、試料120cm3を、受器(内径40mm×高さ85mmの100cm3円柱形容器)の上部開口部から38mmの高さの位置から、該受器に落とす。受器から盛り上がった試料はすり落とし、受器の内容積(100cm3)分の試料の質量(Ag)を秤量し、以下の式からゆるめ嵩密度を求めることができる。
ゆるめ嵩密度(g/cm3)=A(g)/100(cm3
測定は3回行ってその平均値を取ることが好ましい。
The solid oil / fat composition used in the present invention is that the solid oil / fat composition adhering to the surface of the raw rice is in the form of powder when or after adhering to the raw rice. Is preferable in that it does not granulate.
The loose bulk density of the solid oil / fat composition used in the present invention when powdered is, for example, 0.1 to 0.6 g / cm 3 , preferably 0.15 to 0.5 g / cm when it is substantially composed of only oil and fat. It is cm 3 , more preferably 0.2 to 0.4 g / cm 3 . Here, the "loose bulk density" is the packing density in a state where the powder is naturally dropped. The loose bulk density (g / cm 3 ) is measured, for example, by dropping an appropriate amount of the powdered oil / fat composition for coating onto a graduated cylinder having an inner diameter of 15 mm × 25 mL from about 2 cm above the upper opening end of the graduated cylinder. Then, the filled mass (g) is measured and the volume (cm 3 ) is read, and the mass (g) of the powdered oil / fat composition for coating per cm 3 can be calculated. The loose bulk density can also be calculated from the bulk specific gravity measured based on JIS K-6720 (or ISO 1060-1 and 2) using a bulk specific gravity measuring instrument manufactured by Kuramochi Kagaku Kikai Seisakusho Co., Ltd. Specifically, the sample 120 cm 3 is dropped onto the receiver from a position 38 mm above the upper opening of the receiver (100 cm 3 cylindrical container having an inner diameter of 40 mm and a height of 85 mm). The sample raised from the receiver is scraped off, the mass (Ag) of the sample for the internal volume (100 cm 3 ) of the receiver is weighed, and the loose bulk density can be obtained from the following formula.
Loose bulk density (g / cm 3 ) = A (g) / 100 (cm 3 )
It is preferable to perform the measurement three times and take the average value.

油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物として、トリカプリン、トリラウリンのほか、これらのトリグリセリド中に他の脂肪酸を含む合成油、あるいはヤシ油、パーム核油、ヤシ油分別油、パーム核油分別油の硬化油を用いることができる。なお、本発明で用いる固形状の油脂組成物は、本発明の効果を損なわない限り、その他のトリグリセリドを含んでいてもよい。その他のトリグリセリドは、複数の種類のトリグリセリドであってもよく、合成油脂であっても天然油脂であってもよい。合成油脂としては、ジカプリル酸モノカプリン酸グリセリル等が挙げられる。天然油脂としては、例えば、菜種油、大豆油、ひまわり油、コーン油、ゴマ油、綿実油、紅花油、パーム油、パーム核油、パーム油又はパーム核油の分別油、ココアバター等が挙げられる。本発明の油脂組成物中の全トリグリセリドを100質量%とした場合、その他のトリグリセリドは、1質量%以上、例えば、5〜50質量%程度含まれていても問題はない。その他のトリグリセリドの含有量は、例えば、0〜50質量%、好ましくは0〜30質量%、より好ましくは0〜18質量%、更に好ましくは0〜15質量%、最も好ましくは0〜8質量%である。 As a fat and oil composition solid at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil, tricaprin, trilaurin, and other fatty acids are added to these triglycerides. Synthetic oils containing coconut oil, coconut oil, palm oil fractionated oil, and hydrogenated palm oil fractionated oil can be used. The solid oil / fat composition used in the present invention may contain other triglycerides as long as the effects of the present invention are not impaired. The other triglyceride may be a plurality of types of triglycerides, and may be synthetic fats and oils or natural fats and oils. Examples of synthetic fats and oils include glyceryl dicaprylate monocaprate. Examples of natural fats and oils include rapeseed oil, soybean oil, sunflower oil, corn oil, sesame oil, cottonseed oil, red flower oil, palm oil, palm kernel oil, palm oil or palm kernel oil fractionated oil, and cocoa butter. When the total triglyceride in the fat and oil composition of the present invention is 100% by mass, there is no problem even if other triglycerides are contained in an amount of 1% by mass or more, for example, about 5 to 50% by mass. The content of other triglycerides is, for example, 0 to 50% by mass, preferably 0 to 30% by mass, more preferably 0 to 18% by mass, still more preferably 0 to 15% by mass, and most preferably 0 to 8% by mass. Is.

油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物として、以下の油脂組成物を用いると、油脂組成物を冷却することにより、機械粉砕等特別の加工手段を採らなくても、粉末状になるので好ましい。これらの効果により、無洗米に付着した油脂組成物が、作業時の摩擦や保管時の加熱等で仮に溶解して、再固化しても、無洗米と無洗米を接着する油脂組成物が、粉末になり崩壊するので、無洗米の造粒防止になり、好ましい。
上記油脂組成物は、油脂組成物に含まれるトリグリセリドの全量を100質量%とした場合、1位〜3位に炭素数xの直鎖飽和脂肪酸残基Xを有する1種類又はそれ以上のXXX型トリグリセリドを65〜99質量%と、前記XXX型トリグリセリドの直鎖飽和脂肪酸残基Xの1つを炭素数yの直鎖飽和脂肪酸残基Yに置換した1種以上のX2Y型トリグリセリドを35〜1質量%とを含有する油脂組成物であって、前記炭素数xは8〜20から選択される整数であり、前記炭素数yは、それぞれ独立して、x+2〜x+12から選択される整数でありかつy≦22である条件から選ばれる、油脂組成物である。上記2種類のトリグリセリドを上記質量%にて含む当該油脂組成物は、乳化剤、賦形剤等の添加剤を含めることなく、容易に粉末状となる。当該油脂組成物については、先に出願したPCT/JP2015/070850(特願2014−149168号)において、油脂組成物及び粉末油脂組成物として詳しく説明されているので、ここでは詳細を割愛する。
When the following fat and oil composition is used as a fat and oil composition solid at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil, the fat and oil composition is cooled. This is preferable because it becomes a powder without using special processing means such as mechanical crushing. Due to these effects, even if the oil / fat composition adhered to the non-washed rice is temporarily melted by friction during work or heating during storage and resolidified, the oil / fat composition that adheres the non-washed rice to the non-washed rice Since it becomes a powder and disintegrates, it prevents granulation of non-washed rice, which is preferable.
The above-mentioned fat and oil composition is one kind or more XXX type having a linear saturated fatty acid residue X having a carbon number x at the 1st to 3rd positions when the total amount of triglyceride contained in the fat and oil composition is 100% by mass. One or more X2Y-type triglycerides in which triglyceride is 65 to 99% by mass and one of the linear saturated fatty acid residues X of the XXX-type triglyceride is replaced with a linear saturated fatty acid residue Y having y carbon atoms are 35 to 1 In the fat and oil composition containing mass%, the carbon number x is an integer selected from 8 to 20, and the carbon number y is an integer selected independently from x + 2 to x + 12. It is an oil / fat composition selected from the conditions that y ≦ 22. The fat and oil composition containing the above two types of triglycerides in the above mass% can be easily powdered without containing additives such as emulsifiers and excipients. The fat and oil composition is described in detail as the fat and oil composition and the powdered fat and oil composition in PCT / JP2015 / 070850 (Japanese Patent Application No. 2014-149168), which was previously applied for, and therefore the details are omitted here.

前述のXXX型トリグリセリドは、単一種又は複数種、好ましくは単一種(1種類)のXXX型トリグリセリドである。当該XXX型トリグリセリドは、1位〜3位に炭素数xの直鎖飽和脂肪酸残基Xを有するトリグリセリドであり、各脂肪酸残基Xは互いに同一である。ここで、当該炭素数xは10〜12から選択される整数であり、好ましくは、カプリン酸及び/又はラウリル酸であり、より好ましくはカプリン酸である。
XXX型トリグリセリドは、油脂組成物中の全トリグリセリドを100質量%とした場合、65〜99質量%含まれる。XXX型トリグリセリドの含有量として好ましくは、75〜99質量%であり、より好ましくは80〜99質量%であり、更に好ましくは83〜98質量%であり、特に好ましくは85〜98質量%であり、殊更好ましくは90〜98質量%である。
The above-mentioned XXX type triglyceride is a single type or a plurality of types, preferably a single type (one type) of the XXX type triglyceride. The XXX type triglyceride is a triglyceride having a linear saturated fatty acid residue X having a carbon number x at the 1st to 3rd positions, and each fatty acid residue X is the same as each other. Here, the number of carbon atoms x is an integer selected from 10 to 12, preferably capric acid and / or lauryl acid, and more preferably capric acid.
The XXX type triglyceride is contained in an amount of 65 to 99% by mass when the total amount of triglyceride in the oil / fat composition is 100% by mass. The content of the XXX-type triglyceride is preferably 75 to 99% by mass, more preferably 80 to 99% by mass, further preferably 83 to 98% by mass, and particularly preferably 85 to 98% by mass. , Especially preferably 90 to 98% by mass.

前述X2Y型トリグリセリドは、上記XXX型トリグリセリドの脂肪酸残基Xの1つを炭素数yの脂肪酸残基Yに置換したX2Y型トリグリセリドを1種以上含む。ここで、1つのX2Y型トリグリセリドに含まれる各脂肪酸残基Xは互いに同一であり、かつXXX型トリグリセリドの脂肪酸残基Xとも同一である。当該1つのX2Y型トリグリセリドに含まれる脂肪酸残基Yの炭素数yはx+2〜x+12でありかつy≦22である条件から選ばれる整数である。炭素数yは、好ましくはy=x+2〜x+10を満たし、より好ましくはy=x+4〜x+8を満たす条件から選ばれる整数である。また、炭素数yの上限値は、好ましくはy≦20であり、より好ましくはy≦18である。本発明の油脂組成物は複数、例えば、2種類〜5種類、好ましくは3〜4種類のX2Y型トリグリセリドを含んでいてもよく、その場合の各X2Y型トリグリセリドの定義は上述の通りである。各X2Y型トリグリセリドの脂肪酸残基Yの炭素数yは、上述の範囲内から、各X2Y型トリグリセリドごとにそれぞれ独立して選択される。例えば、本発明の油脂組成物を、トリカプリンとパーム核ステアリン極度硬化油とをエステル交換して製造する場合は、xは共通してx=10であるが、yはそれぞれy=12、14、16及び18である4種類のX2Y型トリグリセリドを含む。
脂肪酸残基Yは、飽和あるいは不飽和の脂肪酸残基であってもよい。具体的な脂肪酸残基Yとしては、例えば、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、アラキジン酸及びベヘン酸等の残基が挙げられるがこれに限定するものではない。脂肪酸としてより好ましくは、ミリスチン酸、パルミチン酸、ステアリン酸、アラキジン酸及びベヘン酸であり、さらに好ましくは、ミリスチン酸、パルミチン酸及びステアリン酸である。
このX2Y型トリグリセリドの脂肪酸残基Yは、1位〜3位の何れに配置していてもよい。
X2Y型トリグリセリドは、油脂組成物中の全トリグリセリドを100質量%とした場合、35〜1質量%含まれる。X2Y型トリグリセリドの含有量としては、例えば、25〜1質量%であり、好ましくは20〜1質量%であり、より好ましくは17〜1質量%であり、更に好ましくは15〜2質量%であり、殊更好ましくは10〜2質量%である。本発明の油脂組成物に複数のX2Y型トリグリセリドが含まれる場合、上記X2Y型トリグリセリドの量は、含まれるX2Y型トリグリセリドの合計量である。
The X2Y-type triglyceride contains one or more X2Y-type triglycerides in which one of the fatty acid residues X of the XXX-type triglyceride is replaced with a fatty acid residue Y having a carbon number of y. Here, each fatty acid residue X contained in one X2Y type triglyceride is the same as each other, and is also the same as the fatty acid residue X of the XXX type triglyceride. The carbon number y of the fatty acid residue Y contained in the one X2Y type triglyceride is an integer selected from the conditions of x + 2 to x + 12 and y ≦ 22. The number of carbon atoms y is an integer selected from the conditions that preferably satisfy y = x + 2 to x + 10, and more preferably y = x + 4 to x + 8. Further, the upper limit of the number of carbon atoms y is preferably y ≦ 20, more preferably y ≦ 18. The oil and fat composition of the present invention may contain a plurality of, for example, 2 to 5 types, preferably 3 to 4 types of X2Y type triglycerides, and the definition of each X2Y type triglyceride in that case is as described above. The carbon number y of the fatty acid residue Y of each X2Y type triglyceride is independently selected for each X2Y type triglyceride from the above range. For example, when the oil and fat composition of the present invention is produced by transesterifying tricaprin and palm kernel stearin extremely hardened oil, x is common x = 10, but y is y = 12, 14, respectively. Contains four types of X2Y-type triglycerides, 16 and 18.
The fatty acid residue Y may be a saturated or unsaturated fatty acid residue. Specific examples of the fatty acid residue Y include, but are not limited to, residues such as lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, and behenic acid. The fatty acids are more preferably myristic acid, palmitic acid, stearic acid, arachidic acid and behenic acid, and even more preferably myristic acid, palmitic acid and stearic acid.
The fatty acid residue Y of this X2Y type triglyceride may be arranged at any of the 1st to 3rd positions.
The X2Y type triglyceride is contained in an amount of 35 to 1% by mass when the total amount of triglyceride in the oil / fat composition is 100% by mass. The content of the X2Y type triglyceride is, for example, 25 to 1% by mass, preferably 20 to 1% by mass, more preferably 17 to 1% by mass, and further preferably 15 to 2% by mass. , Especially preferably 10 to 2% by mass. When the oil / fat composition of the present invention contains a plurality of X2Y-type triglycerides, the amount of the X2Y-type triglyceride is the total amount of the contained X2Y-type triglyceride.

上記XXX型トリグリセリドと上記X2Y型トリグリセリドを含有する油脂組成物を任意に加熱・融解して溶融状態の油脂組成物を得、その後冷却すると溶融状態の油脂組成物よりも体積が増加した空隙を有する固形物が形成される。得られた該固形物を外部より軽く衝撃を加えて粉砕する(ほぐす)ことで容易に固形状の油脂組成物が粉末化する。なお、粉末の油脂組成物の粒径は特に制限されないが、JIS標準篩で100メッシュ以上、好ましくは120メッシュ以上、より好ましくは170メッシュ以上のメッシュをパスするような範囲を例示することができる。 The fat and oil composition containing the XXX-type triglyceride and the X2Y-type triglyceride is arbitrarily heated and melted to obtain a melted fat and oil composition, and when cooled thereafter, it has voids having an increased volume as compared with the melted fat and oil composition. A solid is formed. The solid oil / fat composition is easily pulverized by pulverizing (relaxing) the obtained solid by applying a light impact from the outside. The particle size of the powdered oil / fat composition is not particularly limited, but a range in which a JIS standard sieve passes 100 mesh or more, preferably 120 mesh or more, more preferably 170 mesh or more can be exemplified. ..

本発明で用いる固形状の油脂組成物は、上記トリグリセリドの他、任意乳化剤、酸化防止剤、香料、デキストリン等のその他の成分を含んでいてもよい。これらその他の成分の量は、本発明の効果を損なわない限り任意の量とすることができるが、例えば、油脂組成物の全質量を100質量%とした場合、0〜70質量%、好ましくは0〜20質量%、より好ましくは0〜5質量%である。 The solid oil / fat composition used in the present invention may contain other components such as an optional emulsifier, an antioxidant, a fragrance, and dextrin in addition to the above triglyceride. The amount of these other components can be any amount as long as the effects of the present invention are not impaired. For example, when the total mass of the fat and oil composition is 100% by mass, 0 to 70% by mass is preferable. It is 0 to 20% by mass, more preferably 0 to 5% by mass.

本発明で用いる固形状の油脂組成物は、生米100質量部に対して0.3〜15質量部付着していることが好ましく、より好ましくは0.3〜3質量%であり、さらに好ましくは0.5〜1質量%である。 The solid oil / fat composition used in the present invention preferably adheres to 100 parts by mass of raw rice in an amount of 0.3 to 15 parts by mass, more preferably 0.3 to 3% by mass, and even more preferably. Is 0.5 to 1% by mass.

<無洗米の製造方法>
本発明の無洗米の製造方法は、油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物を溶解し、無洗米に溶解した油脂組成物をスプレーし、その後冷却する工程、を含む製造方法(A)である。または、油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有し、15℃で固形状である油脂組成物の粉末を、無洗米に混合する工程、を含む製造方法(B)である。
<Manufacturing method of wash-free rice>
In the method for producing wash-free rice of the present invention, a solid fat-and-fat composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil is dissolved at 15 ° C. to obtain wash-free rice. The production method (A) includes a step of spraying the dissolved fat and oil composition and then cooling the composition. Alternatively, it comprises a step of mixing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil and a powder of the fat and oil composition which is solid at 15 ° C. with unwashed rice. This is the manufacturing method (B).

本発明の無洗米の製造方法では、肌糠(ぬか)をあらかじめ取り去った生米を用いるが、前記<無洗米>に記載のものを用いることができる。また、油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物、あるいは粉末油脂組成物は、前述の<固形状の油脂組成物>に記載のものを用いることができる。 In the method for producing non-washed rice of the present invention, raw rice from which the bran has been removed in advance is used, but the one described in <Wash-free rice> can be used. Further, the fat and oil composition solid at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil, or the powdered fat and oil composition is described in the above-mentioned <solid fat and oil. The composition described in> can be used.

製造方法(A)における、固形状の油脂組成物の溶解は油脂の融点以上である必要があり、好ましくは40℃以上、より好ましくは50℃以上、さらに好ましくは60℃以上に加熱する。また、油脂組成物の熱劣化を防止する点から、加熱は150℃以下が好ましく、より好ましくは120℃以下、さらに好ましくは100℃以下である。最も好ましい範囲は、60〜80℃で加熱することが好ましい。
スプレーは、均一に生米に付着するように、生米を回転させながら、溶解した油脂組成物をスプレーすることが好ましい。例えば、タンクの中で生米を混ぜながら、あるいは、生米を転がらせながら、スプレーする方法などが挙げられる。
スプレー後に冷却するが、冷却温度は、油脂組成物の融点以下であればよいが、効率的に油脂組成物を固化するために、油脂組成物の融点より10℃以上低い冷却温度が好ましい。例えば、融点が40〜60℃の油脂組成物の場合、冷却温度は0〜25℃が好ましい。
なお、スプレー時に予め生米を冷やしておくと、油脂組成物の固化が促進され、好ましい。
The dissolution of the solid fat and oil composition in the production method (A) needs to be at least the melting point of the fat and oil, and is preferably heated to 40 ° C. or higher, more preferably 50 ° C. or higher, and even more preferably 60 ° C. or higher. Further, from the viewpoint of preventing thermal deterioration of the oil / fat composition, heating is preferably 150 ° C. or lower, more preferably 120 ° C. or lower, still more preferably 100 ° C. or lower. The most preferable range is preferably heating at 60 to 80 ° C.
As for the spray, it is preferable to spray the dissolved fat and oil composition while rotating the raw rice so that the raw rice adheres uniformly to the raw rice. For example, a method of spraying while mixing raw rice in a tank or while rolling raw rice can be mentioned.
Although it is cooled after spraying, the cooling temperature may be equal to or lower than the melting point of the fat or oil composition, but in order to efficiently solidify the fat or oil composition, a cooling temperature lower than the melting point of the fat or oil composition by 10 ° C. or more is preferable. For example, in the case of an oil / fat composition having a melting point of 40 to 60 ° C., the cooling temperature is preferably 0 to 25 ° C.
It is preferable to cool the raw rice in advance at the time of spraying because the solidification of the fat and oil composition is promoted.

製造方法(B)において、15℃で固形状である油脂組成物の粉末を用いるが、油脂組成物の粉末化は、油脂を液体窒素中で凍結粉砕する方法等や、極度硬化油等の常温で固体脂含量が高い油脂を粉砕機で粉砕後、篩で粒度を揃える方法や、極度硬化油等の常温で固体脂含量が高い油脂を融解し、直接噴霧する方法のほか、前述の<固形状の油脂組成物>で記載した粉末を用いてもよい。
15℃で固形状である油脂組成物の粉末と無洗米を混合する工程における混合は、摩擦熱等により、粉末状の油脂組成物が融解しないことが好ましく、40℃以下、あるいは融点以下に冷却しながら撹拌することが好ましい。
In the production method (B), a powder of an oil / fat composition which is solid at 15 ° C. is used, but the oil / fat composition is pulverized by a method of pulverizing the oil / fat in liquid nitrogen or the like, or at room temperature of extremely hydrogenated oil or the like. In addition to the method of crushing fats and oils with a high solid fat content with a crusher and then aligning the particle size with a sieve, the method of melting fats and oils with a high solid fat content at room temperature such as extremely hydrogenated oil and spraying directly, the above-mentioned <solid fats and oils The powder described in the oil / fat composition of the shape> may be used.
In the step of mixing the powder of the fat and oil composition which is solid at 15 ° C. and the non-washed rice, it is preferable that the powdery fat and oil composition does not melt due to frictional heat or the like, and it is cooled to 40 ° C. or lower or the melting point or lower. It is preferable to stir while stirring.

次に、実施例、比較例及び参考例を挙げ、本発明を更に詳しく説明するが、本発明はこれらに何ら制限されるものではない。また。以下において「%」とは、特別な記載がない場合、質量%を示す。 Next, the present invention will be described in more detail with reference to Examples, Comparative Examples and Reference Examples, but the present invention is not limited thereto. Also. In the following, "%" means mass% unless otherwise specified.

<原料油脂>
原料油脂1:トリカプリン
原料油脂2:パーム油硬化油
原料油脂3:MCT(カプリル酸:カプリン酸=75:25のトリグリセリド
原料油脂4:菜種サラダ油
原料油脂5:粉末油脂

〔原料油脂5の製造 :x=10、y=14〕
攪拌機、温度計、窒素ガス吹込管及び水分分離機を備えた500mLの四つ口フラスコに、グリセリン(阪本薬品工業社製)44.4g(0.482mol)と、ミリスチン酸(Palmac98−14(アシッドケム社製))25.6g(0.112mol)とカプリン酸(Palmac99−10(アシッドケム社製))265.6g(1.541mol)を仕込み、窒素気流下、250℃の温度で15時間反応させた。過剰のカプリン酸を190℃、減圧下にて留去した後、脱色・濾過、脱臭を行い、50℃において淡黄色液状の反応物を186g得た(XXX型:80.6質量%、X2Y型:17.0質量%)。得られた反応物80gとトリカプリン(日清オイリオグループ株式会社製)120gを混合し原料油脂とした(XXX型:91.9質量%、X2Y型:6.8質量%)。原料油脂を27恒温槽にて品温が27℃になるまで冷却した後、上記トリカプリン(日清オイリオグループ株式会社製)を液体窒素で冷却固化させ、凍結粉砕機(アズワン株式会社製)で粉砕した油脂粉末を原料油脂に対して0.1質量%添加し、20℃恒温槽にて6時間静置し、体積が増加した空隙を有する固形物を形成させた後、ほぐすことで粉末状の結晶組成物を得た(ゆるめ嵩密度:0.2g/cm3、平均粒径75μm)。
ここで、ゆるめ嵩密度は、(株)蔵持科学器械製作所のカサ比重測定器を使用し、JIS K-6720(又はISO 1060-1及び2)に基づいて測定したカサ比重から算出した。具体的には、試料120mLを、受器(内径40mm×高さ85mmの100mL円柱形容器)の上部開口部から38mmの高さの位置から、該受器に落とした。続いて、受器から盛り上がった試料をすり落とし、受器の内容積(100mL)分の試料の質量(Ag)を秤量し、以下の式からゆるめ嵩密度を求めた。
ゆるめ嵩密度(g/mL)=A(g)/100(mL)
測定は3回行って、その平均値を測定値とした。
ここで、平均粒径は、日機装株式会社製 Microtrac MT3300ExII)でレーザー回折散乱法(ISO133201、ISO9276−1)に基づいて測定した。
<Ingredient oils and fats>
Raw material fat 1: Tricaprine raw material fat 2: Palm oil Hydrogenated oil Raw material fat 3: MCT (caprylic acid: capric acid = 75: 25 triglyceride raw material fat 4: Rapeseed salad oil raw fat 5: Powdered fat

[Manufacturing of raw material fats and oils 5: x = 10, y = 14]
44.4 g (0.482 mol) of glycerin (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and myristic acid (Palmac98-14 (acidchem)) in a 500 mL four-necked flask equipped with a stirrer, a thermometer, a nitrogen gas blow tube and a water separator. 25.6 g (0.112 mol) and capric acid (Palmac99-10 (manufactured by Acid Chem)) 265.6 g (1.541 mol) were charged and reacted at a temperature of 250 ° C. for 15 hours under a nitrogen stream. .. Excess capric acid was distilled off at 190 ° C. under reduced pressure, and then decolorization, filtration and deodorization were performed to obtain 186 g of a pale yellow liquid reaction product at 50 ° C. (XXX type: 80.6% by mass, X2Y type). : 17.0% by mass). 80 g of the obtained reaction product and 120 g of tricaprin (manufactured by Nisshin Oillio Group Co., Ltd.) were mixed to obtain a raw material fat (XXX type: 91.9% by mass, X2Y type: 6.8% by mass). After cooling the raw material fats and oils in a constant temperature bath of 27 until the product temperature reaches 27 ° C, the above tricaprin (manufactured by Nisshin Oillio Group Co., Ltd.) is cooled and solidified in liquid nitrogen and crushed by a freeze crusher (manufactured by AS ONE Co., Ltd.). 0.1% by mass of the obtained fat and oil powder was added to the raw material fat and oil, and the mixture was allowed to stand in a constant temperature bath at 20 ° C. for 6 hours to form a solid substance having voids with an increased volume. A crystal composition was obtained (loose bulk density: 0.2 g / cm 3 , average particle size 75 μm).
Here, the loose bulk density was calculated from the bulk specific gravity measured based on JIS K-6720 (or ISO 1060-1 and 2) using a bulk specific gravity measuring instrument manufactured by Kuramochi Kagaku Kikai Seisakusho Co., Ltd. Specifically, 120 mL of the sample was dropped into the receiver from a position 38 mm above the upper opening of the receiver (100 mL cylindrical container having an inner diameter of 40 mm and a height of 85 mm). Subsequently, the raised sample was scraped off from the receiver, the mass (Ag) of the sample for the internal volume (100 mL) of the receiver was weighed, and the bulk density was obtained by loosening from the following formula.
Loose bulk density (g / mL) = A (g) / 100 (mL)
The measurement was performed three times, and the average value was used as the measured value.
Here, the average particle size was measured by the Microtrac MT3300ExII manufactured by Nikkiso Co., Ltd. based on the laser diffraction / scattering method (ISO133201, ISO9276-1).

Figure 0006779575
Figure 0006779575

<無洗米1>
「秋田県産無洗米あきたこまち」を無洗米1とした。
<無洗米2:実施例1>
原料油脂1を60℃で溶解した。無洗米1(5kg)を撹拌しながら、溶解した原料油脂1(25g)をスプレーした。スプレー後、5℃で2時間冷却して無洗米2を得た。
<無洗米3:実施例2>
原料油脂1(100g)と原料油脂2(各100g)を60℃で溶解しながら混合し、混合油脂を得た。無洗米1(5kg)を撹拌しながら、溶解した混合油脂(50g)をスプレーした。スプレー後、5℃で2時間冷却して無洗米3を得た。
<無洗米4:実施例3>
原料油脂1を60℃で溶解した。無洗米1(5kg)を撹拌しながら、溶解した原料油脂1(500g)をスプレーした。スプレー後、5℃で2時間冷却して無洗米4を得た。
<無洗米5:比較例1>
無洗米1(5kg)を撹拌しながら、60℃に加温した原料油脂3(25g)をスプレーした。スプレー後、5℃で2時間冷却して無洗米5を得た。
<無洗米6:比較例2>
無洗米1(5kg)を撹拌しながら、60℃に加温した原料油脂4(25g)をスプレーした。スプレー後、5℃で2時間冷却して無洗米6を得た。
<無洗米7:実施例4>
原料油脂5(粉末 100g)と5kgの無洗米1(5kg)を撹拌しながら混合して無洗米7を得た。
<実施例5〜8、比較例3〜5の無洗米の炊飯>
無洗米1〜7を20℃で2ヶ月間、タンクにて保管した。その後、家庭用炊飯ジャーで無洗米を450g(3合)、又は業務用IH炊飯ジャーで無洗米を4.5kg(3升)炊飯した。炊き上がった米飯をパットに移して15℃で1時間放置し、米飯のほぐれ性、艶、食感、風味を官能評価した。結果を表2に示す。
<Musenmai 1>
"Wash-free rice Akitakomachi from Akita Prefecture" was designated as wash-free rice 1.
<Wash-free rice 2: Example 1>
The raw material fat 1 was dissolved at 60 ° C. The dissolved raw material fat 1 (25 g) was sprayed while stirring the unwashed rice 1 (5 kg). After spraying, it was cooled at 5 ° C. for 2 hours to obtain wash-free rice 2.
<Wash-free rice 3: Example 2>
Raw material fat 1 (100 g) and raw material fat 2 (100 g each) were mixed while being dissolved at 60 ° C. to obtain a mixed fat. The dissolved mixed fat (50 g) was sprayed while stirring the unwashed rice 1 (5 kg). After spraying, it was cooled at 5 ° C. for 2 hours to obtain wash-free rice 3.
<Wash-free rice 4: Example 3>
The raw material fat 1 was dissolved at 60 ° C. The dissolved raw material fat 1 (500 g) was sprayed while stirring the wash-free rice 1 (5 kg). After spraying, it was cooled at 5 ° C. for 2 hours to obtain wash-free rice 4.
<Wash-free rice 5: Comparative example 1>
The raw material fat and oil 3 (25 g) heated to 60 ° C. was sprayed while stirring the wash-free rice 1 (5 kg). After spraying, it was cooled at 5 ° C. for 2 hours to obtain wash-free rice 5.
<Wash-free rice 6: Comparative example 2>
While stirring 1 (5 kg) of unwashed rice, 4 (25 g) of raw material fat and oil heated to 60 ° C. was sprayed. After spraying, it was cooled at 5 ° C. for 2 hours to obtain wash-free rice 6.
<Wash-free rice 7: Example 4>
Raw material oil 5 (powder 100 g) and 5 kg of wash-free rice 1 (5 kg) were mixed with stirring to obtain wash-free rice 7.
<Rice cooking without washing rice in Examples 5 to 8 and Comparative Examples 3 to 5>
Wash-free rice 1 to 7 was stored in a tank at 20 ° C. for 2 months. Then, 450 g (3 go) of unwashed rice was cooked in a household rice cooker, or 4.5 kg (3 squares) of unwashed rice was cooked in a commercial IH rice cooker. The cooked cooked rice was transferred to a pad and left at 15 ° C. for 1 hour to sensoryly evaluate the looseness, luster, texture and flavor of the cooked rice. The results are shown in Table 2.

<参考例1の無洗米の炊飯>
無洗米1を、20℃で2ヶ月間、タンクにて保管した。その後、家庭用炊飯ジャーで無洗米1を450g(3合)水とともに仕込み、原料油脂1を3.5g添加し、炊飯した。炊き上がった米飯をパットに移して15℃で1時間放置し、米飯のほぐれ性、艶、食感、風味を官能評価した。また、炊飯条件のスケールを大きく(業務用IH炊飯ジャー 無洗米4.5kg(3升)、原料油脂1 22.5g)して同様に評価を行った。結果を表2に示す。
<Rice cooking without washing rice in Reference Example 1>
Wash-free rice 1 was stored in a tank at 20 ° C. for 2 months. Then, unwashed rice 1 was charged with 450 g (3 go) of water in a household rice cooker, 3.5 g of raw material fat and oil 1 was added, and the rice was cooked. The cooked cooked rice was transferred to a pad and left at 15 ° C. for 1 hour to evaluate the looseness, luster, texture and flavor of the cooked rice. In addition, the scale of rice cooking conditions was increased (commercial IH rice cooker 4.5 kg (3 squares) of unwashed rice, 122.5 g of raw material fat and oil), and the same evaluation was performed. The results are shown in Table 2.

[官能評価]
上記のように得られた米飯について、5名の専門パネラーによる官能評価を行った。官
能評価の観点は以下のとおりである。
<ご飯のほぐれ性評価>
◎:ご飯1粒ずつがそれぞれくっつかず、ほぐれている
○:ご飯どうしがさほどくっつかず、ほぐれている
△:ご飯の塊がところどころにみとめられる
×:ご飯全体がねばついていて塊となり、ほぐれていない
<ご飯の艶評価>
◎:光沢があり、つやつやしている
○:やや光沢がある
△:光沢がない
×:くすんでいる
<ご飯の食感評価>
◎:ご飯粒それぞれに粘りがあり、油脂などを添加していないご飯本来の食感が感じられ

○:ご飯粒に粘りが残っており、油脂を添加してないご飯本来の食感に近い
△:ご飯粒に粘りが少なく、ご飯本来の食感を感じない
×:ご飯粒に粘りがなく、かつ、ご飯本来の味がなく、まずい
<ご飯の臭い>
◎:ご飯本来の風味が残っており、異臭を感じない
○:ご飯本来の風味が残っており、異臭をさほど感じない
△:ご飯本来の風味が感じられず、異臭を少し感じる
×:ご飯本来の風味がなく、異味異臭を感じる
<ご飯の雑味>
◎:ご飯本来の味を有し、雑味を感じない
○:ご飯本来の味を有し、雑味をさほど感じない
△:ご飯本来の味がやや損なわれている
×:ご飯本来の風味がなく、異味を感じる
[sensory evaluation]
The cooked rice obtained as described above was subjected to sensory evaluation by five specialized panelists. The viewpoint of sensory evaluation is as follows.
<Rice loosening evaluation>
◎: Each grain of rice does not stick to each other and is loosened ○: Rice does not stick to each other and is loosened △: A lump of rice is found here and there ×: The whole rice is sticky and becomes a lump and is not loosened <Rice gloss evaluation>
◎: Glossy and glossy ○: Slightly glossy △: Not glossy ×: Dull <Rice texture evaluation>
◎: Each rice grain is sticky and you can feel the original texture of rice without adding oils and fats ○: The stickiness remains in the rice grains and it is close to the original texture of rice without oils and fats added △ : Rice grains are less sticky and do not feel the original texture of rice ×: Rice grains are not sticky and have no original taste of rice, which is bad <smell of rice>
◎: The original flavor of the rice remains and no offensive odor is felt ○: The original flavor of the rice remains and the offensive odor is not felt so much △: The original flavor of the rice is not felt and the offensive odor is slightly felt ×: The original rice There is no flavor of rice, and you can feel a strange odor <Rice miscellaneous taste>
◎: Has the original taste of rice and does not feel the unpleasant taste ○: Has the original taste of rice and does not feel the unpleasant taste so much △: The original taste of rice is slightly impaired ×: The original flavor of rice I feel strange

Figure 0006779575
Figure 0006779575

表2の結果から明らかであるように、本発明の無洗米2〜4,及び7は、無洗米1,5,6に比べて、ほぐれ性や艶、風味等が良好な炊飯を得ることができた。さらに、炊飯時に油脂を添加する参考例に比べて、均一で良好な炊飯を得ることができた。 As is clear from the results in Table 2, the washing-free rice 2 to 4 and 7 of the present invention can obtain cooked rice having better loosening property, luster, flavor and the like as compared with the washing-free rice 1, 5 and 6. did it. Furthermore, compared to the reference example in which fats and oils were added during rice cooking, uniform and good rice cooking could be obtained.

<実施例9:無洗米の炊飯>
無洗米6,7を各200、紙袋に入れ、40℃で3時間保管し、15℃で24時間保管した。無洗米6の一部は、造粒がみられたが、無洗米7は造粒がみられなかった。
<Example 9: Cooking rice without washing>
200 unwashed rice 6 and 7 were placed in a paper bag, stored at 40 ° C. for 3 hours, and stored at 15 ° C. for 24 hours. Granulation was observed in a part of the unwashed rice 6, but no granulation was observed in the unwashed rice 7.

Claims (10)

油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物が、生米の表面に付着している、無洗米。 Non-washed rice in which a solid fat composition at 15 ° C. containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat and oil adheres to the surface of the raw rice. 前記15℃で固形状の油脂組成物が粉末である、請求項1に記載の無洗米。 The wash-free rice according to claim 1, wherein the fat and oil composition solid at 15 ° C. is a powder. 前記粉末のゆるめ嵩密度が0.1〜0.6g/cm3である、請求項2に記載の無洗米。 The wash-free rice according to claim 2, wherein the loosening bulk density of the powder is 0.1 to 0.6 g / cm 3 . 前記固形状の油脂組成物に含まれる全トリグリセリドの全量を100質量%とした場合、1位〜3位に炭素数xの直鎖飽和脂肪酸残基Xを有するXXX型トリグリセリドを65〜99質量%と、前記XXX型トリグリセリドの直鎖飽和脂肪酸残基Xの1つを炭素数yの直鎖飽和脂肪酸残基Yに置換した1種以上のX2Y型トリグリセリドを35〜1質量%とを含有する油脂組成物であって、前記炭素数xは10〜12から選択される整数であり、前記炭素数yは、それぞれ独立して、x+2〜x+12から選択される整数でありかつy≦22である、請求項1〜3のいずれか1項に記載の無洗米。 When the total amount of all triglycerides contained in the solid fat and oil composition is 100% by mass, 65 to 99% by mass of XXX-type triglyceride having a linear saturated fatty acid residue X having a carbon number x at the 1st to 3rd positions. An oil and fat containing 35 to 1% by mass of one or more X2Y-type triglycerides in which one of the linear saturated fatty acid residues X of the XXX-type triglyceride is replaced with a linear saturated fatty acid residue Y having y carbon atoms. In the composition, the carbon number x is an integer selected from 10 to 12, and the carbon number y is an integer selected independently from x + 2 to x + 12 and y ≦ 22. The wash-free rice according to any one of claims 1 to 3. 前記XXX型トリグリセリドが80〜99質量%、前記1種以上のX2Y型トリグリセリドの合計が20〜1質量%である、請求項4に記載の無洗米。 The wash-free rice according to claim 4, wherein the XXX-type triglyceride is 80 to 99% by mass, and the total of the one or more types of X2Y-type triglyceride is 20 to 1 % by mass. 前記yが、それぞれ独立して、x+2〜x+10から選択される整数でありかつy≦22である、請求項4又は5に記載の無洗米。 The wash-free rice according to claim 4 or 5, wherein y is an integer independently selected from x + 2 to x + 10 and y ≦ 22. 前記yが、それぞれ独立して、x+4〜x+8から選択される整数でありかつy≦22である、請求項〜6のいずれか1項に記載の無洗米。 The wash-free rice according to any one of claims 4 to 6, wherein y is an integer selected independently from x + 4 to x + 8 and y ≦ 22. 前記15℃で固形状の油脂組成物が、生米100質量部に対して0.3〜15質量部の割合で生米に付着されている、請求項1〜7のいずれか1項に記載の無洗米。 The method according to any one of claims 1 to 7, wherein the fat and oil composition solid at 15 ° C. is attached to the raw rice at a ratio of 0.3 to 15 parts by mass with respect to 100 parts by mass of the raw rice. Wash-free rice. 油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有する15℃で固形状の油脂組成物を溶解し、無洗米にスプレーし、その後冷却する、無洗米の製造方法。 A solid fat or oil composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms in the constituent fatty acids of the fat or oil is dissolved in the fat or oil composition at 15 ° C., sprayed on the non-washed rice, and then cooled. Production method. 油脂の構成脂肪酸中に炭素数10〜12の直鎖飽和脂肪酸を10〜100質量%含有し、15℃で固形状である油脂組成物の粉末を、無洗米に混合する、無洗米の製造方法。 A method for producing non-washed rice, in which powder of a fat and oil composition containing 10 to 100% by mass of a linear saturated fatty acid having 10 to 12 carbon atoms and being solid at 15 ° C. is mixed with non-washed rice. ..
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