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JP6829028B2 - Rolling device - Google Patents
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JP6829028B2 - Rolling device - Google Patents

Rolling device Download PDF

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JP6829028B2
JP6829028B2 JP2016167160A JP2016167160A JP6829028B2 JP 6829028 B2 JP6829028 B2 JP 6829028B2 JP 2016167160 A JP2016167160 A JP 2016167160A JP 2016167160 A JP2016167160 A JP 2016167160A JP 6829028 B2 JP6829028 B2 JP 6829028B2
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plating film
low
film
base layer
diameter surface
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JP2018035822A (en
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圭祐 武藤
圭祐 武藤
豊 永井
豊 永井
和史 山本
和史 山本
佐藤 努
努 佐藤
奥畑 充宏
充宏 奥畑
崇 津村
崇 津村
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NSK Ltd
Japan Kanigen Co Ltd
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Japan Kanigen Co Ltd
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Description

本発明は、ボールねじ装置やリニアガイド装置、転がり軸受等の各種転動装置に関する。 The present invention relates to various rolling devices such as a ball screw device, a linear guide device, and a rolling bearing.

例えば図1及び図2(図1のAA断面図)に示すように、ボールねじ装置1は、ねじ溝3aがその外周に螺旋状に形成されたねじ軸3と、ねじ溝3aと対向するねじ溝5がその内周に螺旋状に形成された円筒形状のナット7と、両ねじ溝3a,5により形成される空間に配置される多数のボール9とを主要構成部材としている。ナット7には、一端に図示しないテーブル等に固定するためのフランジ11が形成されるとともに、外周面の一部(図2中の上方)に平面(切欠面)13が切削加工されている。また、ナット7には、ボール9の循環経路として前後一対の鋼管製のチューブ15が固着されており、両ねじ溝3a,5間を所定回数回転したボール9がこれらチューブ15を介して循環する構造となっている。尚、図中、符号17はナット7の平面13上にチューブ15を固定するためのチューブ押えを示し、符号19はナット7の両端に取り付けられた防塵用のプラスチックシールを示している。また、ボール9同士の衝突防止のために、ボール9間にスペーサ21を介在させる場合もある。 For example, as shown in FIGS. 1 and 2 (AA cross-sectional view of FIG. 1), in the ball screw device 1, a screw shaft 3 in which a screw groove 3a is spirally formed on the outer periphery thereof and a screw facing the screw groove 3a A cylindrical nut 7 having a groove 5 spirally formed on the inner circumference thereof and a large number of balls 9 arranged in a space formed by the double-threaded grooves 3a and 5 are main constituent members. The nut 7 is formed with a flange 11 at one end for fixing to a table or the like (not shown), and a flat surface (notch surface) 13 is machined on a part of the outer peripheral surface (upper side in FIG. 2). A pair of front and rear steel pipe tubes 15 are fixed to the nut 7 as a circulation path for the balls 9, and the balls 9 rotated between the screw grooves 3a and 5 a predetermined number of times circulate through the tubes 15. It has a structure. In the figure, reference numeral 17 indicates a tube retainer for fixing the tube 15 on the flat surface 13 of the nut 7, and reference numeral 19 indicates dust-proof plastic seals attached to both ends of the nut 7. Further, in order to prevent collisions between the balls 9, a spacer 21 may be interposed between the balls 9.

しかし、ボールねじ装置1では、振動等によりボール9とねじ溝3a,5とが接触してねじ溝3a,5の表面が損傷し、寿命が低下する大きな原因になっている。そこで、ねじ軸3の外径面やナット7の内径面に各種被膜を形成して耐摩耗性等を改善して耐久性を向上することも行われている。 However, in the ball screw device 1, the ball 9 and the screw grooves 3a and 5 come into contact with each other due to vibration or the like, and the surface of the screw grooves 3a and 5 is damaged, which is a major cause of shortening the life. Therefore, various coatings are formed on the outer diameter surface of the screw shaft 3 and the inner diameter surface of the nut 7 to improve wear resistance and the like to improve durability.

例えば、特許文献1には、摺動部分をカニゼン処理して無電解ニッケルめっき被膜で被覆した機械部品が記載されている。このカニゼン処理による無電解ニッケルめっき被膜は、衝撃強度が高く(高靱性である)、高い硬度を有し、摺動特性のような潤滑性に優れ、しかも高速で形成できるという利点を有するものの、耐摩耗性については十分とは言えない。 For example, Patent Document 1 describes a mechanical part in which a sliding portion is treated with Kanigen and coated with an electroless nickel plating film. Although the electroless nickel plating film by this Kanigen treatment has the advantages of high impact strength (high toughness), high hardness, excellent lubricity such as sliding characteristics, and high speed formation. Abrasion resistance is not sufficient.

また、特許文献2では、電動アクチュエータのフレームの表面にレイデント処理やクロムめっき、カニゼンめっき等を施し、更にフレームの内壁面の転動溝やガイドブロックの転動溝にカニゼンめっきによる表面処理を施している。しかし、転動溝の表面はカニゼン処理による無電解ニッケルめっき被膜が形成されており、特許文献1と同様、耐摩耗性が十分とは言えない。 Further, in Patent Document 2, the surface of the frame of the electric actuator is subjected to raident treatment, chrome plating, kanizen plating, etc., and the rolling groove of the inner wall surface of the frame and the rolling groove of the guide block are surface-treated by kanizen plating. ing. However, an electroless nickel plating film is formed on the surface of the rolling groove by a Kanigen treatment, and it cannot be said that the wear resistance is sufficient as in Patent Document 1.

また、ボールねじ装置1は、各種薬品と接触する用途に使用され、耐食性が要求されることもあるが、ねじ軸3やナット7は一般的には鋼材製であり、腐食性が十分とは言えない。 Further, the ball screw device 1 is used for applications in which it comes into contact with various chemicals, and corrosion resistance may be required. However, the screw shaft 3 and the nut 7 are generally made of steel, and have sufficient corrosiveness. I can not say.

尚、上記はボールねじ装置1に限ったことではなく、リニアガイド装置や転がり軸受等の各種転動装置にも同様のことがいえる。 The above is not limited to the ball screw device 1, but the same can be said for various rolling devices such as linear guide devices and rolling bearings.

特許第3027515号公報Japanese Patent No. 3027515 特開2000−88071号公報Japanese Unexamined Patent Publication No. 2000-88071

本発明はこのような状況に鑑みてなされたものであり、ナット7のねじ溝5のような外方部材の軌道溝や、ねじ軸3のねじ溝3aのような内方部材の軌道溝の耐摩耗性、耐衝撃性及び耐食性を更に向上させることを目的とする。 The present invention has been made in view of such a situation, and the track groove of the outer member such as the thread groove 5 of the nut 7 and the track groove of the inner member such as the thread groove 3a of the screw shaft 3 The purpose is to further improve wear resistance, impact resistance and corrosion resistance.

上記課題を解決するために本発明は、下記の転動装置を提供する。
(1)内径面に軌道溝を有する外方部材と、外径面に軌道溝を有する内方部材と、前記外方部材及び前記内方部材の両軌道溝の間に転動自在に配置された複数の転動体とを備える転動装置において、
前記外方部材の前記内径面及び前記内方部材の前記外径面の少なくとも一方が、
無電解ニッケルめっき被膜、または前記外方部材及び前記内方部材を形成する母材よりもイオン化傾向が小さい金属のめっき被膜からなる下地層を介して、多孔質の低温クロムめっき被膜を有することを特徴とする転動装置。
(2)前記低温クロムめっき被膜の、少なくとも前記軌道溝の表面粗さが1μmRa以下であることを特徴とする上記(1)記載の転動装置。
In order to solve the above problems, the present invention provides the following rolling devices.
(1) an outer member having a raceway groove on the inner diameter surface, an inner member having a raceway groove in the outer diameter surface, rolling is rotatably disposed between both raceway grooves of the outer member and the inner member In a rolling device including a plurality of rolling elements,
At least one of the inner diameter surface of the outer member and the outer diameter surface of the inner member
Having a porous low-temperature chrome plating film via an electroless nickel plating film or a base layer composed of a metal plating film having a lower ionization tendency than the outer member and the base material forming the inner member. A featured rolling device.
(2) The rolling apparatus according to (1) above, wherein the surface roughness of the track groove of the low temperature chrome plating film is at least 1 μmRa or less.

本発明によれば、軌道溝の耐摩耗性及び耐衝撃性、耐食性が向上し、転動装置の耐久性を大幅に向上させることができる。 According to the present invention, the wear resistance, impact resistance, and corrosion resistance of the track groove can be improved, and the durability of the rolling element can be significantly improved.

ボールねじ装置の一例を示す上面図である。It is a top view which shows an example of the ball screw device. 図1のAA断面図である。It is a cross-sectional view of AA of FIG. 図2の部分Xの拡大図である。It is an enlarged view of the part X of FIG.

以下、本発明に関して図面を参照して詳細に説明する。尚、本実施形態では、ボールねじ装置を例にして説明するが、リニアガイド装置や転がり軸受等の転動装置一般に応用することができる。 Hereinafter, the present invention will be described in detail with reference to the drawings. In this embodiment, the ball screw device will be described as an example, but it can be generally applied to rolling devices such as linear guide devices and rolling bearings.

本発明において、ボールねじ装置の種類には制限はなく、図1、2に示したボールねじ装置1を始めとして、種々のボールねじ装置が対象になる。図3は図2の部分Xの拡大図であるが、本発明ではねじ軸3の外径面及びナット7の内径面の少なくとも一方、好ましくは両方に、無電解ニッケルめっき被膜、またはねじ軸3及びナット7を形成する母材よりもイオン化傾向が小さい金属のめっき被膜からなる下地層20を介して、低温クロムめっき被膜30を形成している。 In the present invention, the type of the ball screw device is not limited, and various ball screw devices including the ball screw device 1 shown in FIGS. 1 and 2 are targeted. FIG. 3 is an enlarged view of a portion X of FIG. 2, but in the present invention, at least one of the outer diameter surface of the screw shaft 3 and the inner diameter surface of the nut 7, preferably both, is an electroless nickel-plated coating or the screw shaft 3. The low-temperature chrome plating film 30 is formed via the base layer 20 made of a metal plating film having a lower ionization tendency than the base material forming the nut 7.

下地層20となるニッケルめっき被膜は耐衝撃性に優れており、ボールねじ装置においては、振動によるボール9との衝突に対する耐久性が高まる。また、ねじ軸3やナット7は一般にSCM材やSAE材等の鋼材製であり、鉄よりもニッケルはイオン化傾向が小さい金属であるため、無電解ニッケル被膜を形成しない場合よりも耐食性に優れるようになる。 The nickel-plated coating as the base layer 20 has excellent impact resistance, and in the ball screw device, the durability against collision with the ball 9 due to vibration is enhanced. Further, the screw shaft 3 and the nut 7 are generally made of steel materials such as SCM material and SAE material, and nickel is a metal having a lower ionization tendency than iron, so that it has better corrosion resistance than the case where an electroless nickel film is not formed. become.

また、下地層20として、ねじ軸3やナット7を形成する母材よりもイオン化傾向が小さい金属のめっき被膜にしても、同様に耐食性の向上を図ることができる。中でも、比較的軟質であり、耐衝撃性も兼備することから、金属種としてスズや銅、銀、金等が好ましい。 Further, even if the base layer 20 is a metal plating film having a lower ionization tendency than the base material forming the screw shaft 3 and the nut 7, the corrosion resistance can be similarly improved. Among them, tin, copper, silver, gold and the like are preferable as the metal species because they are relatively soft and also have impact resistance.

一方、低温クロムめっき被膜30は、耐摩耗性に優れるため、ボール9との接触による摩耗を抑制する。また、低温クロムめっき被膜30は多孔質であり、変形しやすい性質がある。これに対し下地層20である無電解ニッケルめっき被膜やイオン化傾向が小さい金属は変形しにくく、ボール9を介して荷重が負荷されるとクラックを発生しやすい。しかし、下地層20の上に低温クロムめっき被膜30があると、変形しやすい低温クロムめっき被膜30が荷重を緩和して下地層20のクラック発生を抑制する。このように、下地層20と低温クロムめっき被膜30とを積層することにより、膜全体としての耐久性が向上する。 On the other hand, since the low-temperature chrome plating film 30 has excellent wear resistance, it suppresses wear due to contact with the balls 9. Further, the low-temperature chrome plating film 30 is porous and has a property of being easily deformed. On the other hand, the electroless nickel plating film which is the base layer 20 and the metal having a low ionization tendency are not easily deformed, and cracks are likely to occur when a load is applied through the balls 9. However, when the low-temperature chrome plating film 30 is placed on the base layer 20, the easily deformable low-temperature chrome plating film 30 relaxes the load and suppresses the generation of cracks in the base layer 20. By laminating the base layer 20 and the low-temperature chrome plating film 30 in this way, the durability of the film as a whole is improved.

これらの効果を十分に発現するために、下地層20の膜厚を3〜100μmにすることが好ましい。下地層20が3μmよりも薄くなると耐食性及び耐摩耗性の向上効果が十分に得られない。 In order to fully exhibit these effects, it is preferable that the film thickness of the base layer 20 is 3 to 100 μm. If the base layer 20 is thinner than 3 μm, the effect of improving corrosion resistance and wear resistance cannot be sufficiently obtained.

また、下地層20や低温クロムめっき被膜30が形成されたねじ軸3のねじ溝3aやナット7のねじ溝5と、ボール9との間には隙間が形成され、荷重が加わるほど隙間が狭くなる。その際、荷重に抗して適切な隙間を形成するためには、下地層20をある膜厚以上にすることが必要であり、上記のように3μm以上にする。但し、下地層20が厚くなると膜厚の管理が難しくなるため、上記したように100μm以下にすることが好ましい。 Further, a gap is formed between the thread groove 3a of the screw shaft 3 on which the base layer 20 and the low-temperature chrome plating film 30 are formed, the thread groove 5 of the nut 7, and the ball 9, and the gap becomes narrower as a load is applied. Become. At that time, in order to form an appropriate gap against the load, it is necessary to make the base layer 20 a certain film thickness or more, and make it 3 μm or more as described above. However, if the base layer 20 becomes thick, it becomes difficult to control the film thickness, so it is preferable that the film thickness is 100 μm or less as described above.

また、低温クロムめっき被膜30の膜厚は0.1〜3μmにすることが好ましく、0.5〜2μmにすることがより好ましい。低温クロムめっき被膜30が0.1μmよりも薄いと耐摩耗性の向上効果が十分に得られず、3μmより厚いと圧縮応力が低くなり、下地層20への密着性が低くなる。 The film thickness of the low-temperature chrome plating film 30 is preferably 0.1 to 3 μm, more preferably 0.5 to 2 μm. If the low-temperature chrome plating film 30 is thinner than 0.1 μm, the effect of improving wear resistance cannot be sufficiently obtained, and if it is thicker than 3 μm, the compressive stress becomes low and the adhesion to the base layer 20 becomes low.

下地層20となる無電解ニッケルめっき被膜は、Ni−Pの他、Ni−B、Ni−P−B等のように、他の元素を含んでいてもよい。また、無電解ニッケルめっき被膜は、一般的な無電解めっき法により形成することができるが、カニゼン処理により形成することが好ましい。 The electroless nickel plating film to be the base layer 20 may contain other elements such as Ni-B and Ni-P-B in addition to Ni-P. The electroless nickel plating film can be formed by a general electroless plating method, but is preferably formed by a Kanigen treatment.

カニゼン処理の一例として、ニッケル塩に、還元剤としてリン化合物及びホウ素化合物を含むめっき浴を用いてNi−P−B被膜を形成することができる。ニッケル塩としては、塩化ニッケル、硫酸ニッケル、酢酸ニッケル、炭酸ニッケル等を用いることができる。リン化合物としては次亜リン酸ナトリウム、次亜リン酸カリウム、次亜リン酸ニッケル等を用いることができ、ホウ素化合物としてはジメチルアミノホウ素、ジエチルアミノホウ素、水素化ホウ素ナトリウム等を用いることができる。めっき浴におけるニッケル塩、リン化合物及びホウ素化合物の比率は、得られる被膜の組成に応じて適宜調整することができる。また、各成分の濃度は、めっき浴の安定性や析出速度等を考慮して決めることができ、例えばニッケル塩濃度が15〜30g/Lの範囲にすることが適当である。 As an example of the Kanigen treatment, a Ni-P-B film can be formed on a nickel salt by using a plating bath containing a phosphorus compound and a boron compound as a reducing agent. As the nickel salt, nickel chloride, nickel sulfate, nickel acetate, nickel carbonate and the like can be used. As the phosphorus compound, sodium hypophosphite, potassium hypophosphite, nickel hypophosphate and the like can be used, and as the boron compound, dimethylaminoboron, diethylaminoboron, sodium borohydride and the like can be used. The ratio of the nickel salt, the phosphorus compound and the boron compound in the plating bath can be appropriately adjusted according to the composition of the obtained coating film. Further, the concentration of each component can be determined in consideration of the stability of the plating bath, the precipitation rate, etc. For example, it is appropriate that the nickel salt concentration is in the range of 15 to 30 g / L.

また、めっき浴には、安定性やpH緩衝作用を考慮して、酢酸やリンゴ酸、クエン酸等の有機酸やエチレンジアミン四酢酸等のキレート剤を添加することもできる。また、安定化剤として、微量の硝酸鉛や硝酸ビスマス、アンチモン塩、イオウ化合物等を添加することができる。更に、めっき浴は、安定性や析出速度等を考慮して、pHを6〜7の範囲に調整することが好ましい。 Further, an organic acid such as acetic acid, malic acid and citric acid and a chelating agent such as ethylenediaminetetraacetic acid can be added to the plating bath in consideration of stability and pH buffering action. Further, as a stabilizer, a trace amount of lead nitrate, bismuth nitrate, antimony salt, sulfur compound and the like can be added. Further, in the plating bath, the pH is preferably adjusted to the range of 6 to 7 in consideration of stability, precipitation rate and the like.

そして、上記のめっき浴に、ねじ軸3やナット7を一定時間浸漬することで、ねじ軸3の外径面やナット7の内径面にめっき被膜を形成する。めっき浴の温度は、浴の安定性や析出速度等を考慮して決められるが、例えば60〜95℃、好ましくは70〜90℃にする。また、めっき浴への浸漬時間を調整することで、めっき被膜の膜厚を調整することができる。 Then, by immersing the screw shaft 3 and the nut 7 in the above plating bath for a certain period of time, a plating film is formed on the outer diameter surface of the screw shaft 3 and the inner diameter surface of the nut 7. The temperature of the plating bath is determined in consideration of the stability of the bath, the precipitation rate, etc., and is, for example, 60 to 95 ° C, preferably 70 to 90 ° C. Further, the film thickness of the plating film can be adjusted by adjusting the immersion time in the plating bath.

尚、ねじ軸3の外径面やナット7の内径面に、めっき被膜との付着性を良好にするために、通常のめっき工程で行われる前処理を施すことが好ましい。前処理としては、例えば、溶剤又はアルカリ溶液を用いた脱脂、亜鉛置換処理、酸浸漬処理等を挙げることができる。 It is preferable that the outer diameter surface of the screw shaft 3 and the inner diameter surface of the nut 7 are subjected to pretreatment performed in a normal plating step in order to improve the adhesion to the plating film. Examples of the pretreatment include degreasing using a solvent or an alkaline solution, zinc substitution treatment, acid immersion treatment and the like.

更に、めっき被膜を熱処理することにより膜硬度を高めることができる。熱処理条件は、めっき被膜に要求される硬度等に応じて決めることができるが、熱処理温度は150〜400℃にすることができ、200〜350℃の範囲がより好ましい。また、熱処理時間は、30〜120分間が適当である。尚、熱処理の雰囲気は、空気、不活性ガス、還元性のガス等を用いることができ、作業性やコスト等を考慮して適宜選択することができる。 Further, the film hardness can be increased by heat-treating the plating film. The heat treatment conditions can be determined according to the hardness and the like required for the plating film, but the heat treatment temperature can be 150 to 400 ° C., more preferably 200 to 350 ° C. The heat treatment time is appropriately 30 to 120 minutes. The atmosphere of the heat treatment can be air, an inert gas, a reducing gas, or the like, and can be appropriately selected in consideration of workability, cost, and the like.

一方、低温クロムめっき被膜30は、レイデント処理とも呼ばれる低温でのめっき処理により形成することができる。この低温クロムめっき処理では、クロム酸水溶液に適宜触媒成分を添加し、−5〜−10℃の低温下において直流電解を行い、クロム微粒子群の多孔質黒色被膜を形成する方法である。電圧や処理時間は、膜厚等に応じて適宜調製することができ、例えば6V〜12Vで、5分〜60分行なうことが適当である。低温クロムめっき処理では、多孔質の被膜の一部が下地層20の内部に拡散して拡散層(合金層)を形成し、優れた密着力を発揮して長期間に亘って耐摩耗性を維持できる。 On the other hand, the low temperature chrome plating film 30 can be formed by a low temperature plating treatment, which is also called a raydent treatment. This low-temperature chromium plating treatment is a method in which a catalyst component is appropriately added to an aqueous solution of chromic acid and DC electrolysis is performed at a low temperature of −5 to −10 ° C. to form a porous black film of chromium fine particles. The voltage and processing time can be appropriately adjusted according to the film thickness and the like, and it is appropriate to carry out the voltage and processing time at 6 V to 12 V for 5 minutes to 60 minutes, for example. In the low-temperature chrome plating treatment, a part of the porous film diffuses inside the base layer 20 to form a diffusion layer (alloy layer), which exerts excellent adhesion and provides abrasion resistance for a long period of time. Can be maintained.

このように、本発明によれば、下地層20及び低温クロムめっき被膜30により耐衝撃性、耐摩耗性及び耐食性に優れるようになり、ボールねじ装置1の耐久性を向上させることができる。 As described above, according to the present invention, the base layer 20 and the low-temperature chrome plating film 30 are excellent in impact resistance, wear resistance, and corrosion resistance, and the durability of the ball screw device 1 can be improved.

また、ボール9の転動性を考慮すると、低温クロムめっき被膜30の表面粗さは小さいほど好ましく、少なくとも両ねじ溝3a、5の低温クロムめっき被膜30の表面粗さを1μmRa以下にすることが好ましく、0.8μmRa以下にすることがより好ましい。このような表面粗さは、低温クロムめっき被膜30を形成した後、機械的に研磨加工すればよい。尚、両ねじ溝3a、5を含めてねじ軸3の外径面の全面及びナット7の内径面の全面をこのような表面粗さにしてもよい。 Further, considering the rolling property of the ball 9, it is preferable that the surface roughness of the low temperature chrome plating film 30 is small, and at least the surface roughness of the low temperature chrome plating film 30 of both screw grooves 3a and 5 is set to 1 μmRa or less. It is preferably 0.8 μmRa or less, and more preferably 0.8 μmRa or less. Such surface roughness may be mechanically polished after the low-temperature chrome plating film 30 is formed. The entire outer diameter surface of the screw shaft 3 and the entire inner diameter surface of the nut 7 including both screw grooves 3a and 5 may have such surface roughness.

更に、ねじ軸3やナット7(以下「母材」ともいう)はステンレス等の鉄基合金製であり、その上の下地層20の形成材料であるニッケル合金や、母材よりもイオン化傾向の小さい金属との間の電位差が大きいため、母材と下地層20との密着性が低くなるおそれがある。また、母材の表面状態によっては、あるいは下地層20が薄い場合には、下地層20が形成されずに母材の一部が露出することがあり、同様に母材と下地層20との密着性が低下するおそれもある。そこで、ねじ軸3やナット7と下地層20との間に、電気ニッケルめっき被膜(ストライクニッケルめっき)を介在させることが好ましい。 Further, the screw shaft 3 and the nut 7 (hereinafter, also referred to as “base material”) are made of an iron-based alloy such as stainless steel, and have a higher ionization tendency than the nickel alloy which is the material for forming the base layer 20 on the base material and the base material. Since the potential difference between the small metal and the metal is large, the adhesion between the base material and the base layer 20 may be low. Further, depending on the surface condition of the base material, or when the base layer 20 is thin, a part of the base material may be exposed without forming the base layer 20, and similarly, the base material and the base layer 20 may be exposed. Adhesion may decrease. Therefore, it is preferable to interpose an electrolytic nickel plating film (strike nickel plating) between the screw shaft 3 or the nut 7 and the base layer 20.

また、低温クロムめっき被膜30の表面をフッ素樹脂でコーティングすることが好ましい。フッ素コーティング被膜が低温クロムめっき被膜30の保護膜となり、またフッ素樹脂は潤滑性も備えることから、耐久性が向上する。更に、無電解ニッケルめっき被膜は母材の凹部を埋めることができない。低温クロムめっき被膜30にはこの凹部を埋める効果や、これにより無電解ニッケルめっき被膜と低温クロムめっき被膜30との密着性を高める効果が考えられる。そして、低温クロムめっき被膜30の上にフッ素コーティング被膜が形成されると、フッ素コーティング被膜が重石として作用して無電解ニッケルめっき被膜と低温クロムめっき被膜30とが密着するため、耐久性が更に高まる。尚、フッ素樹脂としては、ポリテトラフルオロエチレン(PTFE)等が好適である。 Further, it is preferable to coat the surface of the low temperature chrome plating film 30 with a fluororesin. Since the fluorine coating film serves as a protective film for the low temperature chrome plating film 30, and the fluororesin also has lubricity, durability is improved. Further, the electroless nickel plating film cannot fill the recesses of the base material. The low-temperature chrome plating film 30 is considered to have an effect of filling the recesses and an effect of enhancing the adhesion between the electroless nickel plating film and the low-temperature chrome plating film 30. When the fluorine coating film is formed on the low temperature chrome plating film 30, the fluorine coating film acts as a weight stone and the electroless nickel plating film and the low temperature chrome plating film 30 are in close contact with each other, so that the durability is further improved. .. As the fluororesin, polytetrafluoroethylene (PTFE) or the like is suitable.

以下に実施例及び比較例を挙げて本発明を更に説明するが、本発明はこれにより何ら制限されるものではない。 The present invention will be further described below with reference to Examples and Comparative Examples, but the present invention is not limited thereto.

(実施例1)
SCM材製の上レース及び下レースと、SUJ材製のボールとを備えるスラスト玉軸受(呼び番号「51305」)を用意した。そして、日本カニゼン(株)製S−780またはSK−100等を5倍に純水で希釈し、安定剤を微量添加し、次にジメチルアミノホウ素を適量加え、苛性ソーダでpH6.2に調整し、液温を80〜82℃に加温しためっき浴を準備し、そこへ上レース及び下レースの各軌道面を浸漬した、このカニゼン処理により、上レース及び下レースの各軌道面に無電解Ni−Pめっき被膜を形成した。次いで、低温クロムめっき処理により、無電解Ni−Pめっき被膜の上に低温クロムめっき被膜を形成して試験体とした。尚、無電解Ni−Pめっき被膜の膜厚は10μmであり、低温クロムめっき被膜の膜厚は1μmである。
(Example 1)
Thrust ball bearings (nominal number "51305") including upper and lower races made of SCM material and balls made of SUJ material were prepared. Then, S-780 or SK-100 manufactured by Japan Kanigen Co., Ltd. is diluted 5 times with pure water, a small amount of stabilizer is added, then an appropriate amount of dimethylaminoboron is added, and the pH is adjusted to 6.2 with caustic soda. , A plating bath in which the liquid temperature was heated to 80 to 82 ° C. was prepared, and each raceway surface of the upper race and the lower race was immersed therein. By this Kanigen treatment, electroless electrolessness was applied to each raceway surface of the upper race and the lower race. A Ni-P plating film was formed. Next, a low-temperature chrome plating film was formed on the electroless Ni-P plating film by low-temperature chrome plating treatment to prepare a test piece. The film thickness of the electroless Ni-P plating film is 10 μm, and the film thickness of the low temperature chrome plating film is 1 μm.

(比較例1)
実施例1と同一の上レース及び下レースの各軌道面に、実施例1と同様の低温クロムめっき被膜のみ形成して試験体とした。尚、低温クロムめっき被膜の膜厚は、実施例1のクロムめっき被膜と同じにした。
(Comparative Example 1)
Only the same low-temperature chrome plating film as in Example 1 was formed on each raceway surface of the same upper race and lower race as in Example 1 to prepare a test body. The film thickness of the low-temperature chrome plating film was the same as that of the chrome plating film of Example 1.

(比較例2)
実施例1と同一の上レース及び下レースの各軌道面に、実施例1と同様の低温クロムめっき被膜を形成し、その上にフッ素コーティング被膜を形成して試験体とした。尚、低温クロムめっき被膜の膜厚は、実施例1のクロムめっき被膜と同じにした。
(Comparative Example 2)
The same low-temperature chrome plating film as in Example 1 was formed on each raceway surface of the same upper race and lower race as in Example 1, and a fluorine coating film was formed on the low temperature chrome plating film to prepare a test piece. The film thickness of the low-temperature chrome plating film was the same as that of the chrome plating film of Example 1.

(比較例3)
実施例1と同一の上レース及び下レースの各軌道面に、実施例1と同様のカニゼン処理により無電解Ni−Pめっき被膜のみ形成して試験体とした。
(Comparative Example 3)
Only the electroless Ni-P plating film was formed on each raceway surface of the same upper race and lower race as in Example 1 by the same Kanigen treatment as in Example 1 to prepare a test piece.

(比較例4)
実施例1と同一の上レース及び下レースの各軌道面に、実施例1と同様のカニゼン処理により無電解Ni−Pめっき被膜を形成し、その上にカニボロンめっき処理によりホウ素被膜を形成して試験体とした。尚、無電解Ni−Pめっき膜厚は、実施例1の無電解Ni−Pめっき被膜と同じにした。
(Comparative Example 4)
An electroless Ni-P plating film was formed on each raceway surface of the same upper race and lower race as in Example 1 by the same Kanigen treatment as in Example 1, and a boron coating was formed on the electroless Ni-P plating film by the canivoron plating treatment. It was used as a test body. The electroless Ni-P plating film thickness was the same as that of the electroless Ni-P plating film of Example 1.

そして、各試験体ついて、下記に示す(1)耐食性試験、(2)高面圧試験を行った。結果を表1に示す。 Then, each test piece was subjected to (1) corrosion resistance test and (2) high surface pressure test shown below. The results are shown in Table 1.

(1)耐食性試験
JIS Z 2371に基づき、塩化ナトリウム水溶液(濃度5±0.5%)に、試験体の上レースまたは下レースをそれぞれ120時間浸漬し、浸漬後、軌道面について目視により腐食の程度を確認した。評価は、腐食が見られないものを「○」、腐食がやや見られるものを「△」、腐食が見られるものを「×」と判断した。
(1) Corrosion resistance test Based on JIS Z 2371, the upper race and lower race of the test piece were immersed in an aqueous solution of sodium chloride (concentration 5 ± 0.5%) for 120 hours each, and after immersion, the raceway surface was visually corroded. I confirmed the degree. In the evaluation, those without corrosion were judged as "○", those with slight corrosion were judged as "Δ", and those with corrosion were judged as "×".

(2)高面圧試験
試験体を用い、下記条件にて、軌道面に形成した各被膜のはく離状況を確認した。また、高面圧をかけているため、耐衝撃性も同時に評価することができる。評価は、はく離が切られないものを「○」、はく離がやや見られるものを「△」、はく離が見られるものを「×」とした。
<試験条件>
・試験体:スラスト玉軸受(呼び番号「51305」)
・球数:3球
・回転数:1000min−1
・荷重:620kg(純アキシアル荷重)
・面圧:3.0GPa
・サイクル数(回転量×玉数):120000rev.
・潤滑油:油(FBK R068)
・潤滑方式:油浴
(2) High surface pressure test Using the test piece, the peeling condition of each coating film formed on the raceway surface was confirmed under the following conditions. Moreover, since a high surface pressure is applied, the impact resistance can be evaluated at the same time. The evaluation was "○" for those with inseparable peeling, "△" for those with slight peeling, and "×" for those with slight peeling.
<Test conditions>
-Test piece: Thrust ball bearing (nominal number "51305")
・ Number of balls: 3 balls ・ Number of rotations: 1000min -1
-Load: 620 kg (pure axial load)
・ Surface pressure: 3.0 GPa
-Number of cycles (rotation amount x number of balls): 120,000 rev.
-Lubricating oil: Oil (FBK R068)
・ Lubrication method: Oil bath

Figure 0006829028
Figure 0006829028

表1に示すように、無電解ニッケルめっき被膜を下地層とし、その上に低温クロムめっき被膜を形成することにより、それぞれの単独被膜に比べて、耐食性、耐摩耗性及び耐衝撃性の全てにおいて優れることがわかる。 As shown in Table 1, by using an electroless nickel plating film as a base layer and forming a low-temperature chrome plating film on it, all of the corrosion resistance, abrasion resistance, and impact resistance are improved as compared with each single film. It turns out to be excellent.

以上、本発明に関してボールねじ装置やスラスト玉軸受を例示して説明したが、例えばリニアガイド装置の案内軸(内方部材)の外径面やスライダ(外方部材)の内径面、転がり軸受の内輪(内方部材)の内輪軌道面や外輪(外方部材)の外輪軌道面に、上記したように、下地層20を介してクロムめっき被膜30を形成しても、同様の耐食性、耐摩耗性及び耐衝撃性が得られる。 The ball screw device and the thrust ball bearing have been described above with reference to the present invention. For example, the outer diameter surface of the guide shaft (inner member) of the linear guide device, the inner diameter surface of the slider (outer member), and the rolling bearing. Even if the chrome plating film 30 is formed on the inner ring raceway surface of the inner ring (inner member) and the outer ring raceway surface of the outer ring (outer member) via the base layer 20 as described above, the same corrosion resistance and wear resistance are obtained. Properties and impact resistance can be obtained.

1 ボールねじ装置
3 ねじ軸
3a、5 ねじ溝
7 ナット
9 ボール
20 下地層
30 クロムめっき被膜
1 Ball screw device 3 Screw shaft 3a, 5 Thread groove 7 Nut 9 Ball 20 Base layer 30 Chrome plating film

Claims (2)

内径面に軌道溝を有する外方部材と、外径面に軌道溝を有する内方部材と、前記外方部材及び前記内方部材の両軌道溝の間に転動自在に配置された複数の転動体とを備える転動装置において、
前記外方部材の前記内径面及び前記内方部材の前記外径面の少なくとも一方が、
無電解ニッケルめっき被膜、または前記外方部材及び前記内方部材を形成する母材よりもイオン化傾向が小さい金属のめっき被膜からなる下地層を介して、多孔質の低温クロムめっき被膜を有することを特徴とする転動装置。
An outer member having a raceway groove on the inner diameter surface, an inner member having a raceway groove on the outer diameter surface, and a plurality of rollable arrangements between the outer member and both raceway grooves of the inner member. In a rolling device provided with a rolling element,
At least one of the inner diameter surface of the outer member and the outer diameter surface of the inner member
Having a porous low-temperature chrome plating film via an electroless nickel plating film or a base layer composed of a metal plating film having a lower ionization tendency than the outer member and the base material forming the inner member. A featured rolling device.
前記低温クロムめっき被膜の、少なくとも前記軌道溝の表面粗さが1μmRa以下であることを特徴とする請求項1記載の転動装置。 The rolling apparatus according to claim 1, wherein the surface roughness of the track groove of the low-temperature chrome-plated coating film is at least 1 μmRa or less.
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