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JP6842404B2 - Manufacturing method of adhesive base material - Google Patents
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JP6842404B2 - Manufacturing method of adhesive base material - Google Patents

Manufacturing method of adhesive base material Download PDF

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JP6842404B2
JP6842404B2 JP2017236434A JP2017236434A JP6842404B2 JP 6842404 B2 JP6842404 B2 JP 6842404B2 JP 2017236434 A JP2017236434 A JP 2017236434A JP 2017236434 A JP2017236434 A JP 2017236434A JP 6842404 B2 JP6842404 B2 JP 6842404B2
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base material
adhesive
adhesive layer
convex portion
convex
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JP2019104785A (en
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洋之 井口
洋之 井口
塩原 利夫
利夫 塩原
柏木 努
努 柏木
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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Priority to JP2017236434A priority Critical patent/JP6842404B2/en
Priority to TW107136894A priority patent/TWI791644B/en
Priority to KR1020180142405A priority patent/KR102593231B1/en
Publication of JP2019104785A publication Critical patent/JP2019104785A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/204Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/206Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer comprising non-adhesive protrusions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Led Device Packages (AREA)
  • Adhesive Tapes (AREA)
  • Die Bonding (AREA)

Description

本発明は、粘着性基材及び粘着性基材の製造方法に関する。 The present invention relates to an adhesive base material and a method for producing an adhesive base material.

近年、時計や携帯電話などの携帯機器を中心に、電子機器の小型軽量化が進んでいる。これに伴い、これら電子機器に内蔵される半導体チップに関しても小型化が一層進んでいる。 In recent years, electronic devices have become smaller and lighter, mainly in portable devices such as watches and mobile phones. Along with this, the semiconductor chips built into these electronic devices are also becoming smaller and smaller.

半導体チップの電極にリード線を繋げる方法として、従来からワイヤボンディングが知られているが、ワイヤーの占めるスペースが大きいため、半導体チップの小型化には不向きである。 Wire bonding has been conventionally known as a method of connecting a lead wire to an electrode of a semiconductor chip, but it is not suitable for miniaturization of a semiconductor chip because the space occupied by the wire is large.

そこで、電極がある上面を反転して直接電極基板と接続するフリップチップボンディングが行われている(特許文献1,2)。この方法ではワイヤーがないぶん、小型化が可能となる。しかし従来の方法ではチップを1つ1つピックアップするので、マイクロLEDなど非常に小さなチップを大量にダイボンドする際には非常に時間がかかってしまう。 Therefore, flip-chip bonding is performed in which the upper surface of the electrode is inverted and directly connected to the electrode substrate (Patent Documents 1 and 2). With this method, it is possible to reduce the size because there is no wire. However, since the conventional method picks up the chips one by one, it takes a very long time to die bond a large number of very small chips such as micro LEDs.

特許文献3に記載されている転写用の部材では、凹凸パターンの凸部に粘着層が平面に付着しているが、このような転写用の部材は、チップと接触させた際に、平面粘着層とチップの接している面積が大きいため、チップをピックアップして別の粘着性基板に配置する際、全てのチップがきちんと別の粘着性基板に移行することが困難であった。また、平面粘着層とチップの接している面積が大きいために、チップのピックアップ速度と別の粘着性基板へ転写する速度が異なるなど、工程が煩雑となる。 In the transfer member described in Patent Document 3, an adhesive layer is attached to a flat surface on the convex portion of the uneven pattern, but such a transfer member is surface-adhesive when brought into contact with the chip. Since the area of contact between the layer and the chip is large, it is difficult for all the chips to be properly transferred to another adhesive substrate when the chip is picked up and placed on another adhesive substrate. Further, since the area in contact between the flat adhesive layer and the chip is large, the pick-up speed of the chip and the transfer speed to another adhesive substrate are different, and the process becomes complicated.

特開2016−001752号公報Japanese Unexamined Patent Publication No. 2016-001752 国際公開WO2014/098174号公報International Publication WO2014 / 098174 国際公開WO2016/012409号公報International Publication WO 2016/012409

本発明は上記事情に鑑みなされたもので、大量の微細なチップを短時間でダイボンドすることが可能な粘着性基材及び粘着性基材の製造方法を提供することを目的とする。 The present invention has been made in view of the above circumstances, and an object of the present invention is to provide an adhesive substrate and a method for producing an adhesive substrate capable of die-bonding a large amount of fine chips in a short time.

上記課題を解決するために、本発明によれば、支持基材と、該支持基材に設けられた粘着層とを有する粘着性基材であって、前記支持基材は、片面又は両面に2個以上の凸部を有する凹凸パターンを有し、前記粘着層は、少なくとも、前記支持基材の前記凹凸パターンの前記凸部の上面に設けられ、前記凸部の上面の前記粘着層表面が曲面を有するものであることを特徴とする粘着性基材を提供する。 In order to solve the above problems, according to the present invention, the adhesive base material has a support base material and an adhesive layer provided on the support base material, and the support base material is provided on one side or both sides. It has a concavo-convex pattern having two or more convex portions, and the adhesive layer is provided on at least the upper surface of the convex portion of the concavo-convex pattern of the supporting base material, and the surface of the adhesive layer on the upper surface of the convex portion is provided. Provided is an adhesive base material having a curved surface.

本発明の粘着性基材によれば、微細なチップを大量に短時間でダイボンドすることが可能となる。 According to the adhesive substrate of the present invention, it is possible to die bond a large amount of fine chips in a short time.

またこの場合、前記粘着層は、前記支持基材の前記凹凸パターンの前記凸部の上面のみに設けられたものすることが好ましい。 Further, in this case, it is preferable that the adhesive layer is provided only on the upper surface of the convex portion of the uneven pattern of the supporting base material.

また、前記粘着層は、前記支持基材の前記凹凸パターンの凹部にも設けられたものであり、かつ、前記凹凸パターンの凹部に設けられた前記粘着層の表面高さが、前記凸部の上面に設けられた前記粘着層の表面高さよりも低い位置となるように設けられたものとすることが好ましい。 Further, the adhesive layer is also provided in the concave portion of the concave-convex pattern of the supporting base material, and the surface height of the adhesive layer provided in the concave portion of the concave-convex pattern is the height of the convex portion. It is preferable that the adhesive layer is provided at a position lower than the surface height of the adhesive layer provided on the upper surface.

本発明の粘着性基材としては、これらの具体的態様が挙げられる。このような粘着性基材であれは、微細なチップを大量に選択的にピックアップすることができ、短時間で大量のチップをダイボンドすることができる。 Specific aspects of the adhesive substrate of the present invention can be mentioned. With such an adhesive base material, a large number of fine chips can be selectively picked up, and a large number of chips can be die-bonded in a short time.

またこの場合、前記支持基材の前記凸部の上面に設けられた前記粘着層の表面のみが、曲面を有するものとすることが好ましい。 Further, in this case, it is preferable that only the surface of the adhesive layer provided on the upper surface of the convex portion of the supporting base material has a curved surface.

このような粘着性基材であれば、より確実に、微細なチップを大量に選択的にピックアップでき、短時間で大量のチップをダイボンドすることができるものとなる。 With such an adhesive base material, a large amount of fine chips can be selectively picked up more reliably, and a large number of chips can be die-bonded in a short time.

また、前記支持基材の前記凸部の上面に設けられた前記粘着層の表面高さと、前記支持基材の前記凹凸パターンの凹部の表面高さとの差が最長1μm〜100μmであることが好ましい。 Further, it is preferable that the difference between the surface height of the adhesive layer provided on the upper surface of the convex portion of the support base material and the surface height of the concave portion of the uneven pattern of the support base material is 1 μm to 100 μm at the longest. ..

また、前記支持基材の前記凸部の上面に設けられた粘着層の表面高さと、前記支持基材の前記凹部に設けられた粘着層の表面高さとの差が最長1μm〜100μmであることが好ましい。 Further, the difference between the surface height of the adhesive layer provided on the upper surface of the convex portion of the supporting base material and the surface height of the adhesive layer provided on the concave portion of the supporting base material shall be a maximum of 1 μm to 100 μm. Is preferable.

このような支持基材の凸部の上面に設けられた粘着層の表面と、支持基材の凹部の表面又は凹部に設けられた粘着層の表面との距離であれば、より確実に、微細なチップを大量に選択的にピックアップでき、短時間で大量のチップをダイボンドすることができるものとなる。 The distance between the surface of the adhesive layer provided on the upper surface of the convex portion of the support base material and the surface of the concave portion of the support base material or the surface of the adhesive layer provided in the concave portion is more reliable and fine. A large number of chips can be selectively picked up, and a large number of chips can be die-bonded in a short time.

また、前記粘着層の最大厚みが0.01μm〜100μmであることが好ましい。 Further, the maximum thickness of the adhesive layer is preferably 0.01 μm to 100 μm.

このような最大厚み(高さ)を有する粘着層であれば、粘着性基材をチップに押し付けた際に、変形量が小さくすむために好ましい。 An adhesive layer having such a maximum thickness (height) is preferable because the amount of deformation can be reduced when the adhesive base material is pressed against the chip.

また、前記支持基材の前記凹凸パターンの隣接する前記凸部の間隔が1μm〜100μmであることが好ましい。 Further, it is preferable that the distance between the convex portions adjacent to the uneven pattern of the supporting base material is 1 μm to 100 μm.

また、前記支持基材の前記凹凸パターンの前記凸部の幅が1μm〜100μmであることが好ましい。 Further, it is preferable that the width of the convex portion of the uneven pattern of the supporting base material is 1 μm to 100 μm.

このような支持基材の隣接する凸部の間隔や凸部の幅であれば、確実に、微細なチップをピックアップすることができるために好ましい。 Such an interval between adjacent convex portions of the supporting base material and the width of the convex portions are preferable because fine chips can be reliably picked up.

また、前記粘着層の粘着力が、JIS Z 0237:2009に準拠した、23℃、引きはがし角度180°、及び剥離速度300mm/min.の条件での剥離時の粘着力が、0.05〜50(N/25mm幅)であることが好ましい。 Further, the adhesive strength of the adhesive layer is 23 ° C., a peeling angle of 180 °, and a peeling speed of 300 mm / min. The adhesive strength at the time of peeling under the above conditions is preferably 0.05 to 50 (N / 25 mm width).

本発明における粘着層の粘着力がこの範囲であれば、マイクロチップをピックアップするのに十分な粘着性を有するために好ましい。 When the adhesive strength of the adhesive layer in the present invention is within this range, it is preferable because it has sufficient adhesiveness to pick up the microchip.

また、前記粘着性基材が、マイクロLED転写用であることが好ましい。 Further, it is preferable that the adhesive base material is for micro LED transfer.

本発明の粘着性基材は、微細なチップを大量に選択的にピックアップでき、短時間で大量のチップをダイボンドすることが可能であるため、マイクロLED転写用として有用である。 The adhesive substrate of the present invention is useful for micro LED transfer because it can selectively pick up a large number of fine chips and die bond a large number of chips in a short time.

また、本発明では、前記粘着性基材の製造方法であって、静電気力でノズルから粘着剤を塗布することによって、前記支持基材の、少なくとも前記凸部の上面に、表面に曲面を有する粘着層を形成することを特徴とする粘着性基材の製造方法を提供する。 Further, in the present invention, the method for producing an adhesive base material has a curved surface on the surface of at least the upper surface of the convex portion of the support base material by applying an adhesive from a nozzle by electrostatic force. Provided is a method for producing an adhesive base material, which comprises forming an adhesive layer.

このように静電気力で粘着剤を塗布することにより、支持基材の凸部の上面に、表面に曲面を有する粘着層が設けられた本発明の粘着性基材を短時間で製造することができる。 By applying the adhesive by electrostatic force in this way, the adhesive base material of the present invention in which the pressure-sensitive adhesive layer having a curved surface is provided on the upper surface of the convex portion of the support base material can be produced in a short time. it can.

本発明の粘着性基材は、支持基材の表面に凹凸パターンが配列されており、少なくとも、支持基材の凹凸パターンの凸部の上面に粘着層が設けられ、この凸部の上面の粘着層表面が曲面を有するものであることにより、微細なチップを大量に選択的にピックアップでき、短時間で大量のチップをダイボンドすることができる。そのため、チップトランスファー用基材として有用である。 In the adhesive base material of the present invention, a concavo-convex pattern is arranged on the surface of the support base material, and at least an adhesive layer is provided on the upper surface of the convex portion of the concavo-convex pattern of the support base material, and the adhesive layer on the upper surface of the convex portion is provided. Since the layer surface has a curved surface, a large number of fine chips can be selectively picked up, and a large number of chips can be die-bonded in a short time. Therefore, it is useful as a base material for chip transfer.

本発明の粘着性基材の一実施形態を示す概略断面図(A)、本発明の粘着性基材の別の一実施形態を示す概略断面図(B)である。FIG. 5A is a schematic cross-sectional view showing one embodiment of the adhesive base material of the present invention, and FIG. 3B is a schematic cross-sectional view showing another embodiment of the adhesive base material of the present invention. リソグラフィーによる凹凸パターンを有する支持基材の作製工程を説明するフロー図である。It is a flow figure explaining the manufacturing process of the support base material which has a concavo-convex pattern by lithography. 凸部の幅10μm、高さ10μm、間隔10μmである支持基材の写真である。It is a photograph of a supporting base material having a width of 10 μm, a height of 10 μm, and an interval of 10 μm of the convex portions. 図3の支持基材に粘着層を形成した、実施例1の粘着性基材の写真である。It is a photograph of the adhesive base material of Example 1 in which an adhesive layer was formed on the support base material of FIG. 凸部の幅5μm、高さ10μm、間隔5μmである支持基材の写真である。It is a photograph of a supporting base material having a width of 5 μm, a height of 10 μm, and an interval of 5 μm of the convex portions. 図5の支持基材に粘着層を形成した、実施例2の粘着性基材の写真である。It is a photograph of the adhesive base material of Example 2 in which an adhesive layer was formed on the support base material of FIG. 凸部の幅30μm、高さ50μm、間隔30μmである支持基材の写真である。It is a photograph of a supporting base material having a width of 30 μm, a height of 50 μm, and an interval of 30 μm of the convex portions. 図7の支持基材に粘着層を形成した、実施例3の粘着性基材の写真である。It is a photograph of the adhesive base material of Example 3 in which an adhesive layer was formed on the support base material of FIG. 7. 比較例1の粘着性基材の概略断面図である。It is the schematic sectional drawing of the adhesive base material of the comparative example 1. FIG. 比較例2の粘着性基材の概略断面図である。It is the schematic sectional drawing of the adhesive base material of the comparative example 2. FIG. 比較例3の粘着性基材の概略断面図である。It is the schematic sectional drawing of the adhesive base material of the comparative example 3. FIG. 実施例及び比較例の粘着試験において、赤、緑、青のマイクロLEDを選択的にピックアンドプレイスする工程のイメージ図である。It is an image diagram of the process of selectively picking and placing red, green, and blue micro LEDs in the adhesion test of Examples and Comparative Examples.

本発明者は、上記目的を達成するため鋭意検討を行った結果、支持基材と、該支持基材に設けられた粘着層とを有する粘着性基材であって、前記支持基材は、片面又は両面に2個以上の凸部を有する凹凸パターンを有し、前記粘着層は、少なくとも、前記支持基材の前記凹凸パターンの前記凸部の上面に設けられ、前記凸部の上面の前記粘着層表面が曲面を有するものである粘着性基材であれば、微細なチップを大量に選択的にピックアップすることができ、基板の回路電極にプレスすることにより、短時間で大量のチップを電気的に接続することができることを見出し、本発明を成すに至った。以下、本発明の粘着性基材、及び粘着性基材の製造方法について詳細に説明する。 As a result of diligent studies to achieve the above object, the present inventor is an adhesive base material having a support base material and an adhesive layer provided on the support base material, and the support base material is a support base material. It has a concavo-convex pattern having two or more convex portions on one side or both sides, and the adhesive layer is provided on at least the upper surface of the convex portion of the concavo-convex pattern of the supporting base material, and the upper surface of the convex portion. If the surface of the adhesive layer is an adhesive substrate having a curved surface, a large number of fine chips can be selectively picked up, and by pressing the circuit electrodes of the substrate, a large number of chips can be picked up in a short time. They have found that they can be electrically connected, and have come up with the present invention. Hereinafter, the adhesive base material of the present invention and the method for producing the adhesive base material will be described in detail.

即ち、本発明は、支持基材と、該支持基材に設けられた粘着層とを有する粘着性基材であって、前記支持基材は、片面又は両面に2個以上の凸部を有する凹凸パターンを有し、前記粘着層は、少なくとも、前記支持基材の前記凹凸パターンの前記凸部の上面に設けられ、前記凸部の上面の前記粘着層表面が曲面を有するものであることを特徴とする粘着性基材を提供する。 That is, the present invention is an adhesive base material having a support base material and an adhesive layer provided on the support base material, and the support base material has two or more convex portions on one side or both sides. It has a concavo-convex pattern, and the adhesive layer is provided at least on the upper surface of the convex portion of the concavo-convex pattern of the supporting base material, and the surface of the adhesive layer on the upper surface of the convex portion has a curved surface. Provided is a characteristic adhesive base material.

このような本発明の粘着性基材の具体的態様としては、図1(A)に示されるような、片面又は両面に2個以上の凸部を有する凹凸パターンを有する支持基材1の凸部の上面1’のみに粘着層2aが設けられ、この凸部の上面1’の粘着層2aの表面が曲面を有する粘着性基材100Aが挙げられる。また、別の態様としては、図1(B)に示されるような、支持基材1の凸部の上面1’に粘着層2aが設けられ、粘着層2a以外に、支持基材1の凹凸パターンの凹部にも粘着層2bが設けられたものであり、かつ、凹凸パターンの凹部に設けられた粘着層2bの表面高さが、凸部の上面1’に設けられた粘着層2aの表面高さよりも低い位置となるように設けられた粘着性基材100Bが挙げられる。以下、本発明における支持基材、粘着層について詳述する。 As a specific embodiment of such an adhesive base material of the present invention, as shown in FIG. 1 (A), the convex surface of the support base material 1 having a concavo-convex pattern having two or more convex portions on one side or both sides. An adhesive base material 100A in which the adhesive layer 2a is provided only on the upper surface 1'of the portion and the surface of the adhesive layer 2a on the upper surface 1'of the convex portion has a curved surface can be mentioned. As another aspect, as shown in FIG. 1B, the adhesive layer 2a is provided on the upper surface 1'of the convex portion of the supporting base material 1, and the unevenness of the supporting base material 1 is provided in addition to the adhesive layer 2a. The adhesive layer 2b is also provided in the concave portion of the pattern, and the surface height of the adhesive layer 2b provided in the concave portion of the concave-convex pattern is the surface of the adhesive layer 2a provided on the upper surface 1'of the convex portion. Examples thereof include an adhesive base material 100B provided so as to be located at a position lower than the height. Hereinafter, the supporting base material and the adhesive layer in the present invention will be described in detail.

[支持基材]
本発明に使用される支持基材1としては、片面又は両面に2個以上の凸部を有する凹凸パターン、特には、規則的な凹凸パターンを有しているものであれば、特に制限はない。このような支持基材1は、例えば、ガラス、セラミックス基板、シリコンウエハー、ガラスエポキシ積層基板、ポリイミド積層基板、紙フェノール基板、シリコーン樹脂基板、フッ素樹脂基板、ポリエステル基板などを用いて作製することができる。
[Supporting base material]
The supporting base material 1 used in the present invention is not particularly limited as long as it has a concavo-convex pattern having two or more convex portions on one side or both sides, particularly a regular concavo-convex pattern. .. Such a supporting base material 1 can be produced by using, for example, glass, a ceramics substrate, a silicon wafer, a glass epoxy laminated substrate, a polyimide laminated substrate, a paper phenol substrate, a silicone resin substrate, a fluororesin substrate, a polyester substrate, or the like. it can.

凹凸パターンの設け方は特に制限はないが、例えば、フォトリソグラフィーにより被加工体に直接凹凸パターンを形成したものを支持基材1とすることができる。 The method of providing the concavo-convex pattern is not particularly limited, and for example, a support base material 1 in which the concavo-convex pattern is directly formed on the workpiece by photolithography can be used.

フォトリソグラフィーにより凹凸パターンを有する支持基材1を作製する方法は、従来公知の方法に従えばよく、図2に示されるように、被加工体3にフォトレジスト4を塗布し、次いで露光、次いで現像、次いでエッチング、その後余ったレジストを洗浄することで、凹凸パターンを有する支持基材1を得ることができる。 The method for producing the supporting base material 1 having an uneven pattern by photolithography may follow a conventionally known method, and as shown in FIG. 2, the photoresist 4 is applied to the workpiece 3, then exposed, and then exposed. The supporting substrate 1 having an uneven pattern can be obtained by developing, then etching, and then cleaning the excess resist.

更には、このような方法で作製した凹凸パターンに型取り材料を押し当てて型取りし、その型に熱硬化性樹脂、熱可塑性樹脂などを流し込んで、凹凸パターンを有する支持基材1としても良い。 Further, a molding material is pressed against the uneven pattern produced by such a method to form a mold, and a thermosetting resin, a thermoplastic resin, or the like is poured into the mold to obtain a supporting base material 1 having the uneven pattern. good.

また、本発明における凹凸パターンを有する支持基材1は、他の基板の上に粘着剤を塗布し、その上に配置しても良い。この場合の粘着剤は、本発明において支持基材1の凸部の上面に設ける粘着層を形成するための粘着剤と同じであっても良いし、異なっても良い。他の基板としては、上記支持基材の作製に用いられる基板と同様の基板が挙げられる。 Further, the supporting base material 1 having the uneven pattern in the present invention may be arranged by applying an adhesive on another substrate. The pressure-sensitive adhesive in this case may be the same as or different from the pressure-sensitive adhesive for forming the pressure-sensitive adhesive layer provided on the upper surface of the convex portion of the support base material 1 in the present invention. Examples of other substrates include substrates similar to those used for producing the support base material.

支持基材1の凹凸パターンの大きさ、間隔としては特に制限はなく、ピックアップしようとするチップサイズに合わせて適宜選択することができるが、微細なチップをピックアップするためには、図1に示される凸部の幅101は1μm〜100μmとすることができ、好ましくは1μm〜20μm、より好ましくは1μm〜10μmである。 The size and spacing of the uneven pattern of the support base material 1 are not particularly limited and can be appropriately selected according to the chip size to be picked up. However, in order to pick up fine chips, FIG. 1 is shown. The width 101 of the convex portion can be 1 μm to 100 μm, preferably 1 μm to 20 μm, and more preferably 1 μm to 10 μm.

さらに幅101に合わせて、高さ103a、103bが1μm〜100μm、好ましくは1μm〜20μm、より好ましくは1μm〜10μmであると良い。ここでいう高さ103aとは、図1(A)に示されるように、支持基材の凸部の上面に設けられた粘着層2aの表面高さと、支持基材の凹部の表面高さとの差の最長距離であり、また、高さ103bとは、図1(B)に示されるように、支持基材の凸部の上面に設けられた粘着層の表面高さと、支持基材の凹部に設けられた粘着層の表面高さとの差の最長距離である。 Further, the heights 103a and 103b are preferably 1 μm to 100 μm, preferably 1 μm to 20 μm, and more preferably 1 μm to 10 μm according to the width 101. As shown in FIG. 1A, the height 103a referred to here is the surface height of the adhesive layer 2a provided on the upper surface of the convex portion of the supporting base material and the surface height of the concave portion of the supporting base material. The longest distance of the difference, and the height 103b, is the surface height of the adhesive layer provided on the upper surface of the convex portion of the supporting base material and the concave portion of the supporting base material, as shown in FIG. 1 (B). It is the longest distance of the difference from the surface height of the adhesive layer provided in.

また、隣接する凸部の間隔102としては1μm〜100μm、好ましくは1μm〜50μm、より好ましくは1μm〜20μmであると良い。なお、本発明において凸部の幅、高さ、間隔とは走査型電子顕微鏡によって測定された値を指す。 The distance 102 between adjacent convex portions is preferably 1 μm to 100 μm, preferably 1 μm to 50 μm, and more preferably 1 μm to 20 μm. In the present invention, the width, height, and spacing of the convex portions refer to the values measured by the scanning electron microscope.

[粘着層]
本発明の粘着性基材100A、100Bは、少なくとも、支持基材1の凹凸パターンの凸部の上面1’に粘着層2aが設けられ、この粘着層2a表面が曲面を有することを特徴とする。このような形状の粘着層2aを有する粘着性基材であれば、マイクロチップピックアップ時の押し付け圧力を分散させチップに掛かる圧力を低減することができ、また密着面積の低減により低応力で剥離することができる。そのため、微細なチップを大量に短時間でダイボンドすることが可能となる。また、本発明における粘着層は、支持基材1の凹凸パターンの凹部にも形成されていても良いが、支持基材の凸部上面の粘着層2aの表面のみが曲面を有することが好ましい。
[Adhesive layer]
The adhesive base materials 100A and 100B of the present invention are characterized in that, at least, the adhesive layer 2a is provided on the upper surface 1'of the convex portion of the concave-convex pattern of the supporting base material 1, and the surface of the adhesive layer 2a has a curved surface. .. An adhesive base material having an adhesive layer 2a having such a shape can disperse the pressing pressure at the time of picking up the microchip and reduce the pressure applied to the chip, and can be peeled off with low stress by reducing the adhesion area. be able to. Therefore, it is possible to die bond a large number of fine chips in a short time. Further, the adhesive layer in the present invention may be formed in the concave portion of the concave-convex pattern of the support base material 1, but it is preferable that only the surface of the adhesive layer 2a on the upper surface of the convex portion of the support base material has a curved surface.

粘着層の粘着力としては特に制限はないが、180度剥離強度が0.05〜50(N/25mm幅)が好ましく、0.1〜40(N/25mm幅)がより好ましく、0.15〜30(N/25mm幅)が更に好ましい。この範囲であればマイクロチップをピックアップするのに十分な粘着性を有する。 The adhesive strength of the adhesive layer is not particularly limited, but the 180-degree peel strength is preferably 0.05 to 50 (N / 25 mm width), more preferably 0.1 to 40 (N / 25 mm width), and 0.15. ~ 30 (N / 25 mm width) is more preferable. Within this range, it has sufficient adhesiveness to pick up a microchip.

なお、本発明における粘着力とは、JIS Z 0237:2009記載の方法で測定した、温度:23℃、剥離速度:300mm/min.、引きはがし角度:180°の条件で剥離した際の剥離強度を指す。 The adhesive strength in the present invention is measured by the method described in JIS Z 0237: 2009, and has a temperature of 23 ° C. and a peeling speed of 300 mm / min. , Peeling angle: Refers to the peeling strength when peeling under the condition of 180 °.

粘着層の最大厚さ(高さ)としては特に制限はないが、チップトランスファー用基材をチップに押し付けた際に、変形量が小さい方がよく、0.01μm〜100μm、好ましくは0.01μm〜50μm、より好ましくは0.05μm〜30μmが良い。 The maximum thickness (height) of the adhesive layer is not particularly limited, but it is preferable that the amount of deformation is small when the substrate for chip transfer is pressed against the chip, and the amount of deformation is preferably 0.01 μm to 100 μm, preferably 0.01 μm. It is preferably ~ 50 μm, more preferably 0.05 μm to 30 μm.

本発明における粘着層を形成する粘着剤としては、特に制限はなく、塗布後に硬化するもの、例えばアクリル粘着剤、シリコーン粘着剤、ウレタン粘着剤、ラテックス粘着剤、エポキシ粘着剤等が挙げられる。 The pressure-sensitive adhesive forming the pressure-sensitive adhesive layer in the present invention is not particularly limited, and examples thereof include those that cure after application, such as acrylic pressure-sensitive adhesive, silicone pressure-sensitive adhesive, urethane pressure-sensitive adhesive, latex pressure-sensitive adhesive, and epoxy pressure-sensitive adhesive.

粘着層の形成方法は特に制限はないが、支持基材の凸部の上面の粘着層表面が曲面を有するものとなる必要がある。特には、図1(A)のように、支持基材1の凸部の上面のみに表面が曲面を有する粘着層2aを形成することが好ましい。または、図1(B)のように、支持基材1の凸部の上面1’に表面が曲面を有する粘着層2aを、支持基材1の凹凸パターンの凹部にも粘着層2bを、凹凸パターンの凹部に設けられた粘着層2bの表面高さが、凸部の上面に設けられた粘着層2aの表面高さよりも低い位置となるように形成することが好ましい。 The method for forming the adhesive layer is not particularly limited, but the surface of the adhesive layer on the upper surface of the convex portion of the supporting base material needs to have a curved surface. In particular, as shown in FIG. 1A, it is preferable to form the adhesive layer 2a having a curved surface only on the upper surface of the convex portion of the support base material 1. Alternatively, as shown in FIG. 1B, an adhesive layer 2a having a curved surface on the upper surface 1'of the convex portion of the support base material 1 is provided, and an adhesive layer 2b is also provided on the concave portion of the concave-convex pattern of the support base material 1. It is preferable to form the adhesive layer 2b provided in the concave portion of the pattern so that the surface height is lower than the surface height of the adhesive layer 2a provided on the upper surface of the convex portion.

そのため、スピンコーターや通常の加圧スプレーで接着剤を塗布するだけでは、支持基材の凸部に塗布された粘着剤が流れてしまい、凸部上面に粘着層が形成されない、または凹部の粘着層の高さと凸部の粘着層の高さが同じになってしまい、微細なフリップチップを選択的にピックアップすることができなくなってしまう。 Therefore, if the adhesive is simply applied with a spin coater or a normal pressure spray, the adhesive applied to the convex portion of the supporting base material will flow, and the adhesive layer will not be formed on the upper surface of the convex portion, or the adhesive of the concave portion will be adhered. The height of the layer and the height of the adhesive layer on the convex portion become the same, and it becomes impossible to selectively pick up fine flip chips.

支持基材1の凸部の上面1’のみに表面が曲面を有する粘着層2aを形成する(図1(A))、または、支持基材1の凹凸パターンの凹部にも粘着層2bが形成されており、凹凸パターンの凹部に設けられた粘着層2bの表面高さが、凸部の上面に設けられた表面が曲面を有する粘着層2aの表面高さよりも低い位置となるように形成する(図1(B))ための具体的方法としては、例えば微細なノズルを用いて凸部の上から粘着剤を塗布する、または静電塗布(エレクトロスプレー)などが挙げられる。 An adhesive layer 2a having a curved surface is formed only on the upper surface 1'of the convex portion of the support base material 1 (FIG. 1 (A)), or the adhesive layer 2b is also formed on the concave portion of the uneven pattern of the support base material 1. The surface height of the adhesive layer 2b provided in the concave portion of the concave-convex pattern is formed so that the surface provided on the upper surface of the convex portion is lower than the surface height of the adhesive layer 2a having a curved surface. Specific methods for (FIG. 1B) include, for example, applying an adhesive from above the convex portion using a fine nozzle, or electrostatically applying (electrospray).

特に、静電塗布は、正または負に帯電した粘着剤が、静電気の引力によって基材に塗布されるため、ノズルと基材の距離が近い箇所に多く塗布され、細かく制御しなくとも短時間で、支持基材1の凸部の上面1’のみに表面が曲面を有する粘着層2aを形成するように、または、凹凸パターンの凹部に設けられた粘着層2bの表面高さが、凸部の上面に設けられた表面が曲面を有する粘着層2aの表面高さよりも低い位置となるような粘着層2a,2bを形成するように、粘着剤を塗布することが可能であるため好ましい。 In particular, in electrostatic coating, a positively or negatively charged adhesive is applied to the base material by the attractive force of static electricity, so that it is often applied to places where the distance between the nozzle and the base material is short, and it takes a short time without fine control. The surface height of the adhesive layer 2b provided in the concave portion of the concave-convex pattern is such that the adhesive layer 2a having a curved surface is formed only on the upper surface 1'of the convex portion of the support base material 1. It is preferable because the pressure-sensitive adhesive can be applied so as to form the pressure-sensitive adhesive layers 2a and 2b such that the surface provided on the upper surface of the surface is lower than the surface height of the pressure-sensitive adhesive layer 2a having a curved surface.

ノズルの形状としては、特に制限はないが、分散液に均一に電圧を印加するために円形状が望ましい。ノズルの径としては、特に制限はなく、パターンの幅、間隔に合わせて適宜選択することができるが、例えば幅10μm、高さ10μm、間隔10μmの凸パターンに粘着層を形成するためには、5μm〜500μm、好ましくは10μm〜300μm、より好ましくは20μm〜100μmが良い。 The shape of the nozzle is not particularly limited, but a circular shape is desirable in order to apply a voltage uniformly to the dispersion liquid. The diameter of the nozzle is not particularly limited and can be appropriately selected according to the width and spacing of the pattern. For example, in order to form an adhesive layer in a convex pattern having a width of 10 μm, a height of 10 μm, and a spacing of 10 μm, It is preferably 5 μm to 500 μm, preferably 10 μm to 300 μm, and more preferably 20 μm to 100 μm.

この範囲であれば、支持基材1の凸部の上面のみに表面が曲面を有する粘着層2aが形成され、または、支持基材1の凹部に設けられた粘着層2bの表面高さが、凸部の上面に設けられた表面が曲面を有する粘着層2aの表面高さよりも低い位置となるよう粘着層2a、2bが形成されるように、粘着剤を塗布することが可能である。 Within this range, the adhesive layer 2a having a curved surface is formed only on the upper surface of the convex portion of the support base material 1, or the surface height of the adhesive layer 2b provided in the concave portion of the support base material 1 is increased. The adhesive can be applied so that the adhesive layers 2a and 2b are formed so that the surface provided on the upper surface of the convex portion is lower than the surface height of the adhesive layer 2a having a curved surface.

印加する電圧は、特に制限はないが、例えば1,000V〜10,000V、好ましくは1,000V〜8,000V、より好ましくは1,000V〜5,000Vである。またノズルの先端部と支持基材との距離は例えば10μm〜3,000μm、好ましくは10μm〜2,000μmである。 The voltage to be applied is not particularly limited, but is, for example, 1,000 V to 10,000 V, preferably 1,000 V to 8,000 V, and more preferably 1,000 V to 5,000 V. The distance between the tip of the nozzle and the supporting base material is, for example, 10 μm to 3,000 μm, preferably 10 μm to 2,000 μm.

粘着層の硬化方法は、樹脂の種類によって異なるが、特に限定はなく、例えば熱硬化、光硬化、湿気硬化などが挙げられる。 The method for curing the adhesive layer varies depending on the type of resin, but is not particularly limited, and examples thereof include thermosetting, photocuring, and moisture curing.

本発明における粘着性基材は、微細なチップを大量に選択的にピックアップでき、短時間で大量のチップをダイボンドすることが可能であるため、マイクロLED転写用として、ボンディングヘッドに好適に利用される。 Since the adhesive substrate in the present invention can selectively pick up a large amount of fine chips and die bond a large number of chips in a short time, it is suitably used for a bonding head for micro LED transfer. To.

以下、実施例、比較例を示し、本発明をより詳細に説明するが、本発明は下記の実施例に制限されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples.

(実施例1)
酸化膜が形成されたシリコンウエハー(被加工体3)に、フォトレジスト膜4を形成し、公知のフォトリソグラフィー法を用いて凸部の幅10μm、高さ10μm、間隔10μmの凹凸パターンを形成し、凹凸パターンを有する支持基材を作製した(図2、図3)。次いで、メチルエチルケトン(MEK)を用いて、付加硬化型シリコーン粘着剤KR−3700(信越化学工業(株)社製、粘着力:8.7N/25mm)を固形分濃度1.25質量%に希釈し、前記粘着剤を静電噴霧/塗布実験機(アピックヤマダ(株)社製)を用いて前記凹凸パターンの凸部上面に塗布し、曲面を有する粘着層を凸部にのみ有する粘着性基材を製造した(図4)。
(Example 1)
A photoresist film 4 is formed on a silicon wafer (workpiece 3) on which an oxide film is formed, and a concavo-convex pattern having a convex portion width of 10 μm, a height of 10 μm, and an interval of 10 μm is formed by using a known photolithography method. , A supporting base material having a concavo-convex pattern was produced (FIGS. 2 and 3). Next, using methyl ethyl ketone (MEK), the addition-curing silicone pressure-sensitive adhesive KR-3700 (manufactured by Shin-Etsu Chemical Industry Co., Ltd., adhesive strength: 8.7 N / 25 mm) was diluted to a solid content concentration of 1.25% by mass. , The adhesive is applied to the upper surface of the convex portion of the uneven pattern using an electrostatic spray / coating experimental machine (manufactured by Apic Yamada Co., Ltd.) to obtain an adhesive base material having an adhesive layer having a curved surface only on the convex portion. Manufactured (Fig. 4).

(実施例2)
実施例1と同様の方法で、酸化膜が形成されたシリコンウエハー(被加工体3)に、凸部の幅5μm、高さ10μm、間隔5μmの凹凸パターンを形成し、凹凸パターンを有する支持基材を作製した(図5)。次いで、メチルエチルケトン(MEK)を用いて、付加硬化型シリコーン粘着剤X−40−3270−1(信越化学工業(株)社製、粘着力:0.15N/25mm)を固形分濃度1.25質量%に希釈し、前記粘着剤を静電噴霧/塗布実験機(アピックヤマダ(株)社製)を用いて前記凹凸パターンの凸部上面に塗布し、曲面を有する粘着層を凸部にのみ有する粘着性基材を製造した(図6)。
(Example 2)
By the same method as in Example 1, a concavo-convex pattern having a convex portion width of 5 μm, a height of 10 μm, and an interval of 5 μm is formed on a silicon wafer (workpiece 3) on which an oxide film is formed, and a support group having the concavo-convex pattern is formed. A material was prepared (Fig. 5). Next, using methyl ethyl ketone (MEK), an addition-curing silicone pressure-sensitive adhesive X-40-3270-1 (manufactured by Shin-Etsu Chemical Industry Co., Ltd., adhesive strength: 0.15 N / 25 mm) was added to a solid content concentration of 1.25 mass. %, And the adhesive is applied to the upper surface of the convex portion of the uneven pattern using an electrostatic spray / coating experimental machine (manufactured by Apic Yamada Co., Ltd.), and the adhesive layer having a curved surface is provided only on the convex portion. A sex substrate was produced (Fig. 6).

(実施例3)
実施例1と同様の方法で、酸化膜が形成されたシリコンウエハー(被加工体3)に、凸部の幅30μm、高さ50μm、間隔30μmの凹凸パターンを形成して型を作製した。その型に付加硬化型ジメチルシリコーン樹脂を流し込み、150℃×4時間加熱して硬化させ、剥がすことで凹凸パターンがシリコンウエハーの逆になったシリコーン樹脂型を作製した。作製した型に付加硬化型メチルフェニルシリコーン樹脂を流し込み、150℃×4時間加熱して硬化させ、剥がすことで凹凸パターンを有するシリコーン樹脂製支持基材を作製した(図7)。次いで粘着層として、メチルエチルケトン(MEK)を用いて、アクリル樹脂系粘着剤オリバインBPW6570(トーヨーケム(株)社製、粘着力:25.6N/25mm)を固形分濃度10質量%に希釈し、前記粘着剤を静電噴霧/塗布実験機(アピックヤマダ(株)社製)を用いて前記凹凸パターンの凸部上面に塗布し、曲面を有する粘着層を凸部にのみ有する粘着性基材を製造した(図8)。
(Example 3)
In the same manner as in Example 1, a concavo-convex pattern having a convex portion width of 30 μm, a height of 50 μm, and an interval of 30 μm was formed on a silicon wafer (workpiece 3) on which an oxide film was formed to prepare a mold. An addition-curable dimethyl silicone resin was poured into the mold, heated at 150 ° C. for 4 hours to cure, and peeled off to prepare a silicone resin mold in which the uneven pattern was the reverse of that of a silicon wafer. An addition-curable methylphenyl silicone resin was poured into the prepared mold, heated at 150 ° C. for 4 hours to cure, and peeled off to prepare a silicone resin supporting base material having an uneven pattern (FIG. 7). Next, as the adhesive layer, methyl ethyl ketone (MEK) was used to dilute the acrylic resin-based adhesive Oliveine BPW6570 (manufactured by Toyochem Co., Ltd., adhesive strength: 25.6 N / 25 mm) to a solid content concentration of 10% by mass, and the adhesive The agent was applied to the upper surface of the convex portion of the uneven pattern using an electrostatic spray / coating experimental machine (manufactured by Apic Yamada Co., Ltd.) to produce an adhesive base material having an adhesive layer having a curved surface only on the convex portion (). FIG. 8).

(比較例1)
実施例1と同様の方法で、酸化膜が形成されたシリコンウエハー(被加工体3)に、凸部の幅10μm、高さ10μm、間隔10μmの凹凸パターンを形成し、凹凸パターンを有する支持基材を作製した。次いで粘着層として、メチルエチルケトン(MEK)を用いて、付加硬化型シリコーン粘着剤KR−3700(信越化学工業(株)社製、粘着力:8.7N/25mm)を固形分濃度1.25質量%に希釈し、前記粘着剤をスピンコーター(株式会社アクティブ社製)を用いて前記凹凸パターンに塗布し、図9に示されるような、支持基材10の凹部にのみ粘着層20を持ち、凸部に粘着層を持たない粘着性基材を作製した。
(Comparative Example 1)
By the same method as in Example 1, a concavo-convex pattern having a convex portion width of 10 μm, a height of 10 μm, and an interval of 10 μm is formed on a silicon wafer (workpiece 3) on which an oxide film is formed, and a support group having the concavo-convex pattern is formed. The material was prepared. Next, as an adhesive layer, methyl ethyl ketone (MEK) was used to add a curable silicone adhesive KR-3700 (manufactured by Shinetsu Chemical Industry Co., Ltd., adhesive strength: 8.7 N / 25 mm) with a solid content concentration of 1.25 mass%. The adhesive is applied to the uneven pattern using a spin coater (manufactured by Active Co., Ltd.), and the adhesive layer 20 is provided only in the concave portion of the supporting base material 10 as shown in FIG. An adhesive base material having no adhesive layer in the portion was prepared.

(比較例2)
凸部の幅10μm、高さ10μm、間隔10μmに変更した以外は、実施例3と同様の方法で凹凸パターンを有するシリコーン樹脂製支持基材を作製した。次いで粘着層として、メチルエチルケトン(MEK)を用いて、付加硬化型シリコーン粘着剤KR−3700(信越化学工業(株)社製、粘着力:8.7N/25mm)を固形分濃度1.25質量%に希釈し、前記粘着剤をハンドスプレーガンを用いて前記凹凸パターンに塗布し、図10に示されるような、支持基材10の凹部が粘着層20で埋まり、凹凸パターンを持たない、即ち、凸部の上面及び凹部に形成された粘着層20の表面が平坦である粘着性基材を作製した。
(Comparative Example 2)
A silicone resin supporting base material having an uneven pattern was produced in the same manner as in Example 3 except that the width of the convex portion was changed to 10 μm, the height was changed to 10 μm, and the interval was changed to 10 μm. Next, as an adhesive layer, methyl ethyl ketone (MEK) was used to add a curable silicone adhesive KR-3700 (manufactured by Shinetsu Chemical Industry Co., Ltd., adhesive strength: 8.7 N / 25 mm) with a solid content concentration of 1.25 mass%. The pressure-sensitive adhesive is applied to the uneven pattern using a hand spray gun, and the concave portion of the support base material 10 is filled with the adhesive layer 20 as shown in FIG. 10, and has no uneven pattern, that is, An adhesive base material having a flat surface of the adhesive layer 20 formed on the upper surface and the concave portion of the convex portion was produced.

(比較例3)
凸部の幅20μm、高さ50μm、間隔20μmに変更した以外は、実施例3と同様の方法で凹凸パターンを有するシリコーン樹脂製支持基材を作製した。次いで粘着層として、付加硬化型シリコーン粘着剤KR−3700(信越化学工業(株)社製、粘着力:8.7N/25mm)をスクリーン印刷し、図11に示されるような、支持基材10の凸部に矩形の粘着層20を持つ粘着性基材を作製した。
(Comparative Example 3)
A silicone resin supporting base material having an uneven pattern was produced in the same manner as in Example 3 except that the width of the convex portion was changed to 20 μm, the height was changed to 50 μm, and the interval was changed to 20 μm. Next, as an adhesive layer, an addition-curable silicone adhesive KR-3700 (manufactured by Shin-Etsu Chemical Co., Ltd., adhesive strength: 8.7 N / 25 mm) was screen-printed, and the supporting base material 10 as shown in FIG. An adhesive base material having a rectangular adhesive layer 20 on the convex portion of the surface was prepared.

[粘着試験]
実施例1〜3、比較例1〜3で得られた粘着性基材を用いて、図12のように並べられた赤、緑、青のマイクロLEDを選択的にピックアンドプレイスで転写した。選択的に転写したものを○、転写できなかったものを×とした。結果を表1に示す。
[Adhesion test]
Using the adhesive substrates obtained in Examples 1 to 3 and Comparative Examples 1 to 3, the red, green, and blue micro LEDs arranged as shown in FIG. 12 were selectively transferred by pick and place. Those that were selectively transcribed were marked with ◯, and those that could not be transcribed were marked with x. The results are shown in Table 1.

表1に示す通り、本発明の粘着性基材(実施例1〜3)を用いれば、一度に多くのマイクロLEDを選択的にピックアンドプレイスできるため、マイクロLEDの転写用として好適に用いることができる。 As shown in Table 1, if the adhesive substrate of the present invention (Examples 1 to 3) is used, many micro LEDs can be selectively picked and placed at one time, and therefore, it is suitably used for transfer of micro LEDs. Can be done.

一方、比較例1では、実施例のように支持基材の凸部に粘着層を有していなかったため、LEDをピックアップすることができなかった。また、比較例2では、凹部と凸部の全てに粘着層を有していたため、選択的にLEDをピックアップできなかった。また、ピックアップしたLEDも転写することができなかった。比較例3では選択的にLEDをピックアップできたが、チップと粘着層の密着面積が大きいため、別の粘着性基板に転写できなかった。 On the other hand, in Comparative Example 1, the LED could not be picked up because the adhesive layer was not provided on the convex portion of the supporting base material as in the example. Further, in Comparative Example 2, since the adhesive layer was provided in all of the concave portion and the convex portion, the LED could not be selectively picked up. Also, the picked up LED could not be transferred. In Comparative Example 3, the LED could be selectively picked up, but it could not be transferred to another adhesive substrate because the contact area between the chip and the adhesive layer was large.

なお、本発明は、上記実施形態に限定されるものではない。上記実施形態は例示であり、本発明の特許請求の範囲に記載された技術的思想と実質的に同一な構成を有し、同様な作用効果を奏するものは、いかなるものであっても本発明の技術的範囲に含有される。 The present invention is not limited to the above embodiment. The above-described embodiment is an example, and any object having substantially the same configuration as the technical idea described in the claims of the present invention and exhibiting the same effect and effect is the present invention. Included in the technical scope of.

1、10…支持基材、 1’ …支持基材の凸部の上面、 2a、2b、20…粘着層、 3…被加工体、 4…フォトレジスト、 100A、100B…粘着性基材、 101…凸部の幅、 102…隣接する凸部の間隔、 103a、103b…高さ。
1, 10 ... Supporting base material, 1'... Upper surface of the convex portion of the supporting base material, 2a, 2b, 20 ... Adhesive layer, 3 ... Work piece, 4 ... Photoresist, 100A, 100B ... Adhesive base material, 101 ... Width of the convex portion, 102 ... Spacing of adjacent convex portions, 103a, 103b ... Height.

Claims (11)

支持基材と、該支持基材に設けられた粘着層とを有する粘着性基材の製造方法であって、
前記支持基材は、片面又は両面に2個以上の凸部を有する凹凸パターンを有し、
前記粘着層は、少なくとも、前記支持基材の前記凹凸パターンの前記凸部の上面に設けられ、前記凸部の上面の前記粘着層表面が曲面を有する粘着性基材の製造方法であり、静電気力でノズルから粘着剤を塗布することによって、前記支持基材の、少なくとも前記凸部の上面に、表面に曲面を有する粘着層を形成することを特徴とする粘着性基材の製造方法
A method for producing an adhesive base material having a support base material and an adhesive layer provided on the support base material.
The supporting base material has an uneven pattern having two or more convex portions on one side or both sides.
The adhesive layer is at least provided on the upper surface of the convex portion of the concavo-convex pattern of the supporting substrate, Ri manufacturing method der adhesive base material which the adhesive layer surface of the upper surface of the convex portion has a curved surface, A method for producing an adhesive base material , which comprises applying an adhesive from a nozzle by electrostatic force to form an adhesive layer having a curved surface on at least the upper surface of the convex portion of the support base material .
前記粘着層は、前記支持基材の前記凹凸パターンの前記凸部の上面のみに設けられていることを特徴とする請求項1に記載の粘着性基材の製造方法The adhesive layer is, the production method of the adhesive base material according to claim 1, characterized in Tei Rukoto provided only on the upper surface of the convex portion of the concavo-convex pattern of the supporting substrate. 前記粘着層は、前記支持基材の前記凹凸パターンの凹部にも設けられており、かつ、前記凹凸パターンの凹部に設けられた前記粘着層の表面高さが、前記凸部の上面に設けられた前記粘着層の表面高さよりも低い位置となるように設けられていることを特徴とする請求項1に記載の粘着性基材の製造方法The adhesive layer, the well is provided in the recess of the uneven pattern of the supporting substrate in contact it is, and the surface height of the adhesive layer provided on the concave portion of the concavo-convex pattern is provided on the upper surface of the convex portion method for producing adhesive base material according to claim 1 above, wherein the Tei Rukoto provided so as to be lower than the surface height of the adhesive layer which is. 前記支持基材の前記凸部の上面に設けられた前記粘着層の表面のみが、曲面を有していることを特徴とする請求項3に記載の粘着性基材の製造方法Wherein only the surface of the supporting substrate the adhesive layer provided on the upper surface of the convex portion of the method for producing an adhesive base material according to claim 3, characterized that you have to have a curved surface. 前記支持基材の前記凸部の上面に設けられた前記粘着層の表面高さと、前記支持基材の前記凹凸パターンの凹部の表面高さとの差最長1μm〜100μmとすることを特徴とする請求項2に記載の粘着性基材の製造方法And the surface height of the adhesive layer provided on the upper surface of the convex portion of the supporting substrate, and wherein the longest 1μm~100μm and to Rukoto the difference between the surface height of the concave portion of the concavo-convex pattern of the supporting substrate The method for producing an adhesive base material according to claim 2. 前記支持基材の前記凸部の上面に設けられた前記粘着層の表面高さと、前記支持基材の前記凹部に設けられた粘着層の表面高さとの差最長1μm〜100μmとすることを特徴とする請求項3又は請求項4に記載の粘着性基材の製造方法Wherein the surface height of the support the adhesive layer provided on the upper surface of the convex portion of the substrate, the longest 1μm~100μm and to Rukoto the difference between the surface height of the pressure-sensitive adhesive layer provided on the concave portion of the supporting substrate The method for producing an adhesive base material according to claim 3 or 4, wherein the adhesive base material is produced. 前記粘着層の最大厚み0.01μm〜100μmとすることを特徴とする請求項1から請求項6のいずれか1項に記載の粘着性基材の製造方法 Production method of the adhesive base material as claimed in any one of claims 6, wherein to Rukoto and 0.01μm~100μm the maximum thickness of the adhesive layer. 前記支持基材の前記凹凸パターンの隣接する前記凸部の間隔1μm〜100μmとすることを特徴とする請求項1から請求項7のいずれか1項に記載の粘着性基材の製造方法 Production method of the adhesive base material as claimed in any one of claims 7 to the uneven pattern, wherein 1μm~100μm and to Rukoto an interval between the convex portions adjacent in the supporting substrate .. 前記支持基材の前記凹凸パターンの前記凸部の幅1μm〜100μmとすることを特徴とする請求項1から請求項8のいずれか1項に記載の粘着性基材の製造方法 Production method of the adhesive base material as claimed in any one of claims 8, wherein the width 1μm~100μm and to Rukoto of the convex portion of the concavo-convex pattern of the supporting substrate. 前記粘着層の粘着力、JIS Z 0237:2009に準拠した、23℃、引きはがし角度180°、及び剥離速度300mm/min.の条件での剥離時の粘着力、0.05〜50(N/25mm幅)とすることを特徴とする請求項1から請求項9のいずれか1項に記載の粘着性基材の製造方法The adhesive strength of the adhesive layer was adjusted to 23 ° C., a peeling angle of 180 °, and a peeling speed of 300 mm / min, in accordance with JIS Z 0237: 2009. In adhesive strength at the peeling of the condition, 0.05~50 (N / 25mm width) and to the claim 1, characterized in Rukoto according to any one of claims 9 tacky substrate Manufacturing method . 前記粘着性基材、マイクロLED転写に用いることを特徴とする請求項1から請求項10のいずれか1項に記載の粘着性基材の製造方法 It said adhesive base material, the production method of the adhesive base material according to claims 1, characterized in be used in actual micro LED transfer to any one of claims 10.
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