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JP6877104B2 - Repair drainage drain - Google Patents
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JP6877104B2 - Repair drainage drain - Google Patents

Repair drainage drain Download PDF

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JP6877104B2
JP6877104B2 JP2016149990A JP2016149990A JP6877104B2 JP 6877104 B2 JP6877104 B2 JP 6877104B2 JP 2016149990 A JP2016149990 A JP 2016149990A JP 2016149990 A JP2016149990 A JP 2016149990A JP 6877104 B2 JP6877104 B2 JP 6877104B2
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drainage drain
aluminum
plate
mass
repair
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JP2018017073A (en
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星河 浩介
浩介 星河
章 永田
章 永田
雄輝 久保
雄輝 久保
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
    • E04D13/04Roof drainage; Drainage fittings in flat roofs, balconies or the like
    • E04D13/0404Drainage on the roof surface
    • E04D13/0445Drainage channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, rods, wire, tubes, profiles or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/02Manufacture of metal sheets, rods, wire, tubes, profiles or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of sheets
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Roof Covering Using Slabs Or Stiff Sheets (AREA)

Description

本発明は、改修排水ドレン用アルミニウム材、それからなる改修排水ドレン用板状構造体およびその製造方法に関する。 The present invention relates to an aluminum material for repair drainage drainage, a plate-like structure for repair drainage drainage made of the aluminum material, and a method for manufacturing the same.

屋上、陸屋根、廊下、バルコニー等(以下、「屋上等」と称することがある)の建物平坦部に降った雨水を集めて竪樋等に流すために、屋上等には通常、排水ドレンが設けられている。 Drainage drains are usually provided on rooftops, flat roofs, corridors, balconies, etc. (hereinafter sometimes referred to as "rooftops, etc.") in order to collect rainwater that has fallen on the flat parts of buildings and drain it into gutters, etc. Has been done.

排水ドレンには、屋上等の下に設けられた竪樋等に雨水を流す縦引き排水用の排水ドレンと、屋上等の横に設けられた竪樋等に雨水を引込む横引き排水用の排水ドレンとがある。 The drainage drain includes a drainage drain for vertical drainage that allows rainwater to flow into a gutter or the like provided under the rooftop, and a drainage for horizontal drainage that draws rainwater into a gutter or the like provided next to the rooftop or the like. There is a drain.

排水ドレンは通常、鋳鉄、ステンレスまたはアルミニウム等の材質でできており、焼き付け塗装等の塗装が施されているものもあり、屋上等に種々の方法で固定されている。 The drainage drain is usually made of a material such as cast iron, stainless steel or aluminum, and some of them are painted by baking finish or the like, and are fixed to the rooftop or the like by various methods.

しかしながら、時間の経過とともに、排水ドレン自体が劣化したり、排水ドレンを屋上等に固定してある接触場所等が浸食を受けたりして、雨水が正常に竪桶等に流れなくなったり、排水ドレンの周辺が汚くなったり、また排水ドレンの腐食部等から漏水したりすることがある。 However, with the passage of time, the drainage drain itself deteriorates, the contact area where the drainage drain is fixed to the rooftop, etc. is eroded, and rainwater does not flow normally to the tub, etc., or the drainage drain The area around the drain may become dirty, or water may leak from the corroded part of the drainage drain.

このような劣化した排水ドレンや排水ドレン周辺を補修するために、例えば、特許文献1に開示されているように、改修排水ドレンが広く用いられている。図4に、改修排水ドレンの一例を示す。図4に示すように、改修排水ドレン40は、板状構造体42の略中央部に穴が開けられており、その穴から板状構造体42の片面側に中空管44が伸びている。改修排水ドレン設置前の排水ドレン下地の概略断面図を図3に、改修排水ドレンを設置した排水ドレン下地の概略断面図を図5に示した。図5に示すように、当該中空管44を、補修しようとする排水ドレンの既設ドレン管50に差し込み、板状構造体42を既設の排水ドレン下地34の形状になじませ、密着させることで排水ドレンを補修できるようになっている。改修排水ドレン設置前の排水ドレン下地は、平坦部36と窪み部38があるため、排水ドレン下地34の形状に合うように容易に変形し、かつ密着する(すなわち、下地追従性が高い)板状構造体が必要である。 In order to repair such a deteriorated drainage drain and the vicinity of the drainage drain, for example, as disclosed in Patent Document 1, a repair drainage drain is widely used. FIG. 4 shows an example of the repair drainage drain. As shown in FIG. 4, the repair drainage drain 40 has a hole in the substantially central portion of the plate-shaped structure 42, and a hollow pipe 44 extends from the hole to one side of the plate-shaped structure 42. .. FIG. 3 shows a schematic cross-sectional view of the drainage drain base before the repair drainage drain is installed, and FIG. 5 shows a schematic cross-sectional view of the drainage drain base on which the repair drainage drain is installed. As shown in FIG. 5, the hollow pipe 44 is inserted into the existing drain pipe 50 of the drainage drain to be repaired, and the plate-shaped structure 42 is adapted to the shape of the existing drainage drain base 34 and brought into close contact with each other. The drainage drain can be repaired. Since the drainage drain base before the repair drain drain is installed has a flat portion 36 and a recessed portion 38, it is easily deformed to match the shape of the drain drain base 34 and adheres to the drainage drain base 34 (that is, the base followability is high). A shaped structure is required.

かかる改修排水ドレンの板状構造体の材質としては、排水ドレンおよびその周辺の形状に隙間なく密接するように、低強度かつ塑性変形しやすいものが好ましい。このような改修排水ドレンの材質として、鉛が用いられている。鉛はハンマー等で押叩くことで容易に排水ドレン下地に追従するので、施工性が高い。 As the material of the plate-like structure of the repaired drainage drain, a material having low strength and easily plastically deformed so as to be in close contact with the shape of the drainage drain and its surroundings without a gap is preferable. Lead is used as the material for such repair drainage drains. Lead easily follows the drainage drain base by hitting it with a hammer or the like, so it is highly workable.

しかし、鉛は毒性を有する金属であり、板状構造体の材料として鉛を用いた場合、鉛に接触した雨水に毒性の持つ鉛イオンが溶け込み、環境に影響を及ぼす恐れがあった。また、改修排水ドレンの施工時に、作業者が鉛に直接触れることもあり、人体に危険性を及ぼす恐れがあるといった問題があった。 However, lead is a toxic metal, and when lead is used as a material for a plate-like structure, toxic lead ions may dissolve in rainwater in contact with lead, which may affect the environment. In addition, there is a problem that the worker may come into direct contact with lead during the construction of the repair drainage drain, which may pose a danger to the human body.

このような事情から、改修排水ドレンの板状構造体に用いる素材として、鉛に代わる新たな素材が求められており、これまで種々の素材が提案されている。 Under these circumstances, a new material that replaces lead is required as a material used for the plate-like structure of the repair drainage drain, and various materials have been proposed so far.

特許文献2には、改修排水ドレンの板状構造体として、アルミニウム金属メッシュを含み、当該アルミニウム金属メッシュをゴムで被覆したものが開示されている。しかし、アルミニウム金属メッシュを含み、当該アルミニウム金属メッシュをゴムで被覆した改修ドレンは、金属板を用いた場合と比較すると塑性変形が生じにくく、また、金属メッシュは形状が複雑なため、製造工程が複雑になるという課題がある。 Patent Document 2 discloses a plate-like structure of a repair drainage drain containing an aluminum metal mesh and the aluminum metal mesh coated with rubber. However, the repair drain containing the aluminum metal mesh and the aluminum metal mesh coated with rubber is less likely to undergo plastic deformation as compared with the case where a metal plate is used, and the metal mesh has a complicated shape, so that the manufacturing process is complicated. There is the problem of complexity.

特許文献3には、改修排水ドレンの板状構造体として銅を用いたものが開示されている。しかし、銅は鉛よりも強度(例えば引張強度)が相当に大きいため、柔軟性が不足し、施工時に排水ドレンの補修部位に密着させることが困難という問題がある。 Patent Document 3 discloses a plate-like structure of a repair drainage drain using copper. However, since copper has a considerably higher strength (for example, tensile strength) than lead, there is a problem that it lacks flexibility and it is difficult to bring it into close contact with the repaired part of the drainage drain during construction.

特許文献4には、改修排水ドレンの板状構造体として工業用純アルミニウムを用いるものが開示されている。しかし、工業用純アルミニウムは鉛よりも強度が相当に大きいため、柔軟性が不十分であり、施工時に排水ドレン周辺の形状に密着させることが困難という問題がある。 Patent Document 4 discloses a structure in which industrial pure aluminum is used as the plate-like structure of the repair drainage drain. However, since industrial pure aluminum has considerably higher strength than lead, it has insufficient flexibility, and there is a problem that it is difficult to make it adhere to the shape around the drainage drain during construction.

特開2014−101643号公報Japanese Unexamined Patent Publication No. 2014-101634 特開2012−202048号公報Japanese Unexamined Patent Publication No. 2012-202048 実用新案登録第3090951号公報Utility Model Registration No. 3090951 特開2015−59333号公報Japanese Unexamined Patent Publication No. 2015-559333

このように、改修排水ドレンの板状構造体に用いられる素材として種々のものが提案されている。しかし、いずれの素材も、従来用いられている鉛と比較して柔軟性(靱性、延性など)が大幅に劣るので、下地追従性(すなわち、施工性)が大幅に劣り、改修排水ドレンの板状構造体として用いられる鉛の代替素材としては不十分であった。 As described above, various materials have been proposed as materials used for the plate-like structure of the repair drainage drain. However, since all the materials are significantly inferior in flexibility (toughness, ductility, etc.) to the conventionally used lead, the base followability (that is, workability) is significantly inferior, and the repair drainage drain plate It was insufficient as a substitute material for lead used as a structure.

そこで、本発明は、改修排水ドレンの板状構造体の素材として好適に用いることができる、十分に優れた柔軟性を有し、施工性に優れた、鉛の代替素材を提供することを目的とする。 Therefore, an object of the present invention is to provide a lead alternative material which can be suitably used as a material for a plate-like structure of a repair drainage drain, has sufficiently excellent flexibility, and is excellent in workability. And.

本発明の態様1は、Fe、SiおよびCuの合計の含有量が0.01質量%以下であり、残部がAlおよび不可避不純物元素である、改修排水ドレン用アルミニウム材である。 Aspect 1 of the present invention is an aluminum material for repair drainage drainage in which the total content of Fe, Si and Cu is 0.01% by mass or less, and the balance is Al and unavoidable impurity elements.

本発明の態様2は、O材に調質された調質処理材である、態様1に記載のアルミニウム材である。 Aspect 2 of the present invention is the aluminum material according to Aspect 1, which is a tempering treatment material tempered into an O material.

本発明の態様3は、態様1または2に記載のアルミニウム材からなる改修排水ドレン用板状構造体である。 Aspect 3 of the present invention is a plate-like structure for repair drainage drain made of the aluminum material according to Aspect 1 or 2.

本発明の態様4は、板厚が0.3〜2mmである、態様3に記載の板状構造体である。 Aspect 4 of the present invention is the plate-like structure according to Aspect 3, which has a plate thickness of 0.3 to 2 mm.

本発明の態様5は、Fe、SiおよびCuの合計の含有量が0.01質量%以下であり、残部がAlおよび不可避不純物元素であるアルミニウム材からなる圧延素材を作製する工程と、前記圧延素材を圧延する圧延工程と、を含む、改修排水ドレン用板状構造体の製造方法である。 Aspect 5 of the present invention comprises a step of producing a rolled material in which the total content of Fe, Si and Cu is 0.01% by mass or less, and the balance is Al and an aluminum material which is an unavoidable impurity element, and the rolling. It is a method for manufacturing a plate-like structure for repair drainage drainage, which includes a rolling process for rolling a material.

本発明の態様6は、前記圧延工程後、300〜600℃の温度で保持する焼鈍工程をさらに含む、態様5に記載の板状構造体の製造方法である。 Aspect 6 of the present invention is the method for producing a plate-like structure according to Aspect 5, further comprising an annealing step of holding at a temperature of 300 to 600 ° C. after the rolling step.

本発明によれば、改修排水ドレンの板状構造体の素材として好適に用いることができる、十分に優れた柔軟性を有し、施工性に優れた、鉛の代替素材を提供することができる。
また、本発明によれば、十分に優れた柔軟性を有し、施工性に優れた、改修排水ドレン用板状構造体およびその製造方法を提供することができる。
According to the present invention, it is possible to provide a lead alternative material which can be suitably used as a material for a plate-like structure of a repair drainage drain, has sufficiently excellent flexibility, and is excellent in workability. ..
Further, according to the present invention, it is possible to provide a plate-shaped structure for repair drainage drain, which has sufficiently excellent flexibility and excellent workability, and a method for manufacturing the same.

図1は、実施例で用いた模擬治具および試験片を示す概略図である。FIG. 1 is a schematic view showing a simulated jig and a test piece used in the examples. 図2は、図1のAの箇所を示す図である。FIG. 2 is a diagram showing a portion A in FIG. 図3は、排水ドレン下地の一例を示す概略断面図である。FIG. 3 is a schematic cross-sectional view showing an example of a drainage drain base. 図4は、改修排水ドレンの一例を示す概略斜視図である。FIG. 4 is a schematic perspective view showing an example of the repair drainage drain. 図5は、改修排水ドレンの中空管が、排水ドレン管の内部まで差し込まれた状態の一例を示す概略断面図である。FIG. 5 is a schematic cross-sectional view showing an example of a state in which the hollow pipe of the repair drainage drain is inserted into the inside of the drainage drain pipe.

本発明は、高純度アルミニウムの柔軟性に着眼したものである。 The present invention focuses on the flexibility of high-purity aluminum.

従来にも、改修排水ドレンの板状構造体として工業用純アルミニウムを適用しているものが提案されている。しかし、このような工業用純アルミニウムは、ホール・エルー法等の電気分解法により製造されるため、通常は純度が99質量%程度であり、すなわち1質量%に近い不純物元素を含む。例えばJIS規格の合金番号A1100の純度は99質量%程度、A1050の純度は99.5質量%程度である。
なお、純度を示す質量パーセント表記における先頭から連続する9の数の後にナインの頭文字であるNを付して、例えば純度99.99質量%を「4N」と記載し、「フォーナイン」と呼ぶことがある。純度4Nのアルミニウムを「4N−Al」と標記する場合がある。
Conventionally, it has been proposed that industrial pure aluminum is applied as a plate-like structure of a repair drainage drain. However, since such industrial pure aluminum is produced by an electrolysis method such as the Hall-Héroult method, the purity is usually about 99% by mass, that is, it contains an impurity element close to 1% by mass. For example, the purity of the JIS standard alloy number A1100 is about 99% by mass, and the purity of A1050 is about 99.5% by mass.
In addition, in the mass percent notation indicating purity, N, which is an acronym for nine, is added after the number of 9s consecutive from the beginning, for example, 99.99 mass% of purity is described as "4N", and is referred to as "four nines". I may call it. Aluminum with a purity of 4N may be labeled as "4N-Al".

99質量%程度の純度の純アルミニウムでは、通常0.1質量%程度またはそれ以上のFeと0.05質量%程度またはそれ以上のSiを不純物として含んでいる。 Pure aluminum having a purity of about 99% by mass usually contains about 0.1% by mass or more of Fe and about 0.05% by mass or more of Si as impurities.

上述したように、劣化した排水ドレンを補修する際には、改修排水ドレンが排水ドレンおよびその周辺の形状に隙間なく密接するように、改修排水ドレンを変形加工させて使用する。99質量%程度の純度の工業用純アルミニウムは、不純物元素を多く含有するため強度が高く、改修排水ドレンに必要とされる厚さ0.3mm以上の板材の場合にハンマー等での押叩きにて下地に追従させることが困難である。さらに工業用純アルミニウムの中では強度が低いO材(焼鈍材)を用いた場合でも、鉛に比較すると強度が高いために変形させにくく、また加工硬化により強度が上昇しやすいために、十分に塑性変形させてドレン下地に追従させることが困難であった。そこで、低強度であり、塑性変形性が高く、かつ加工硬化しにくい素材が必要となることに着眼した。 As described above, when repairing the deteriorated drainage drain, the repair drainage drain is deformed and used so that the repair drainage drain is in close contact with the shape of the drainage drain and its surroundings without any gap. Industrial pure aluminum with a purity of about 99% by mass has high strength because it contains a large amount of impurity elements, and can be used for tapping with a hammer, etc. in the case of a plate material with a thickness of 0.3 mm or more required for repair drainage drainage. It is difficult to follow the groundwork. Furthermore, even when O material (annealed material), which has low strength among industrial pure aluminum, is used, it is difficult to deform because it has higher strength than lead, and the strength tends to increase due to work hardening. It was difficult to plastically deform it to follow the drain base. Therefore, we focused on the need for a material that has low strength, high plastic deformability, and is difficult to work harden.

本発明者らは、鋭意検討した結果、99.99質量%以上の純度(4N以上)の高純度のアルミニウム材を改修排水ドレンの板状構造体の素材として用いることで上記課題を解決できることを見出した。
すなわち、アルミニウム材に含まれるFe、SiおよびCuの合計の含有量を0.01質量%以下に制御することにより、アルミニウム材の強度を抑制し、塑性変形を容易にし、かつ加工硬化による強度上昇を生じにくくすることができる。そのため、このような高純度のアルミニウム材を改修排水ドレンの板状構造体の素材として用いた場合、補修部位の形状に合わせて板状構造体を変形加工すると、十分に塑性変形させることができ、補修部位の形状に合わせて容易に密着させることができ施工性に優れた改修排水ドレンを提供できることを見出したのである。
As a result of diligent studies, the present inventors have found that the above problems can be solved by using a high-purity aluminum material having a purity of 99.99% by mass or more (4N or more) as a material for the plate-like structure of the repair drainage drain. I found it.
That is, by controlling the total content of Fe, Si and Cu contained in the aluminum material to 0.01% by mass or less, the strength of the aluminum material is suppressed, plastic deformation is facilitated, and the strength is increased by work hardening. Can be less likely to occur. Therefore, when such a high-purity aluminum material is used as a material for the plate-shaped structure of the repair drainage drain, if the plate-shaped structure is deformed according to the shape of the repaired part, it can be sufficiently plastically deformed. They have found that it is possible to provide a repair drainage drain that can be easily adhered to the shape of the repaired part and has excellent workability.

以下、本発明の実施形態に係る改修排水ドレン用アルミニウム材、それからなる改修排水ドレン用板状構造体およびその製造方法について説明する。 Hereinafter, an aluminum material for repair drainage drain according to an embodiment of the present invention, a plate-like structure for repair drainage drain made of the aluminum material, and a method for manufacturing the same will be described.

1.改修排水ドレン用アルミニウム材
本発明の実施形態に係る改修排水ドレン用アルミニウム材は、Fe、SiおよびCuの合計の含有量が0.01質量%以下であり、残部がAlおよび不可避不純物元素である。Fe、SiおよびCuの合計の含有量を0.01質量%以下に制限することにより、アルミニウム材の強度を低く抑え、塑性変形を容易にし、また加工硬化による強度向上を抑制することができる。そのため、本発明の実施形態に係るアルミニウム材を改修排水ドレンの板状構造体の材料として用いた場合、板状構造体の加工硬化による柔軟性の低下を抑制することができるので、当該板状構造体を排水ドレンの補修部位の形状に合わせて密接するように容易に施工することができる。
1. 1. Aluminum material for repair drainage drain The aluminum material for repair drainage according to the embodiment of the present invention has a total content of Fe, Si and Cu of 0.01% by mass or less, and the balance is Al and unavoidable impurity elements. .. By limiting the total content of Fe, Si and Cu to 0.01% by mass or less, the strength of the aluminum material can be suppressed to a low level, plastic deformation can be facilitated, and strength improvement due to work hardening can be suppressed. Therefore, when the aluminum material according to the embodiment of the present invention is used as the material for the plate-shaped structure of the repair drainage drain, it is possible to suppress a decrease in flexibility due to work hardening of the plate-shaped structure. The structure can be easily constructed so as to be in close contact with the shape of the repaired part of the drainage drain.

本発明の実施形態に係る改修排水ドレン用アルミニウム材は、Fe、SiおよびCuの合計の含有量が0.001質量%以下であることが好ましい。より好ましくは、本発明の実施形態に係る改修排水ドレン用アルミニウム材では、Fe、SiおよびCuの合計の含有量が0.0001質量%以下である。
不純物元素であるFe、SiおよびCuの合計の含有量をより制限することにより、アルミニウム材の強度をより小さくし、塑性変形をより容易にし、加工硬化をより抑制することができるので、本発明に係るアルミニウム材を改修排水ドレンの板状構造体の材料として用いた場合、改修排水ドレンの施工性をより向上することができる。
The aluminum material for repair drainage drain according to the embodiment of the present invention preferably has a total content of Fe, Si and Cu of 0.001% by mass or less. More preferably, in the aluminum material for repair drainage drain according to the embodiment of the present invention, the total content of Fe, Si and Cu is 0.0001% by mass or less.
By further limiting the total content of the impurity elements Fe, Si and Cu, the strength of the aluminum material can be made smaller, plastic deformation can be made easier, and work hardening can be further suppressed. When the aluminum material according to the above is used as a material for the plate-like structure of the repair drainage drain, the workability of the repair drainage drain can be further improved.

アルミニウムの純度が高いほど、加工硬化による強度向上を抑制できるメカニズムは、明確ではないが、以下のように推測している。つまり、不純物濃度が高い一般的な金属の場合には、加工とともに転位と呼ばれる結晶欠陥が導入された際に、転位の移動が不純物元素で抑制され(すなわち、ピン止めされ)て蓄積し、転位が移動しにくくなる、つまり加工硬化していく。それに対し、アルミニウムの純度が99.99質量%以上になると、一般的な金属と比べて不純物元素が大幅に少ないため、転位の移動が不純物元素によって抑制される(ピン止めされる)効果が小さくなり、したがって加工硬化が生じにくいと考えられる。 The mechanism by which the higher the purity of aluminum is, the more the strength improvement due to work hardening can be suppressed is not clear, but it is speculated as follows. That is, in the case of a general metal having a high impurity concentration, when crystal defects called dislocations are introduced during processing, the movement of dislocations is suppressed (that is, pinned) by the impurity element and accumulated, and dislocations occur. Becomes difficult to move, that is, work hardening. On the other hand, when the purity of aluminum is 99.99% by mass or more, the amount of impurity elements is significantly smaller than that of general metals, so that the effect of suppressing (pinning) the movement of dislocations by the impurity elements is small. Therefore, it is considered that work hardening is unlikely to occur.

また、本発明の実施形態に係る改修排水ドレン用アルミニウム材は、不純物元素であるFe、SiおよびCuの合計の含有量が0.01質量%以下まで制限されているため、加工硬化による柔軟性の低下を抑制できることに加えて、優れた耐食性を有することができる。そのため、本発明の実施形態に係る改修排水ドレン用アルミニウム材を改修排水ドレンの板状構造体の素材として用いた場合、長時間雨水に曝されても劣化しにくくなる。このような耐食性向上の効果は、不純物元素であるFe、SiおよびCuの合計の含有量をより制限することによって、より顕著に発揮できる。したがって、耐食性の効果を得るためには、Fe、SiおよびCuの合計の含有量は、0.001質量%以下がより好ましく、0.0001質量%以下がさらに好ましい。 Further, the aluminum material for repair drainage drain according to the embodiment of the present invention has flexibility due to work hardening because the total content of the impurity elements Fe, Si and Cu is limited to 0.01% by mass or less. In addition to being able to suppress the decrease in corrosion resistance, it is possible to have excellent corrosion resistance. Therefore, when the aluminum material for the repair drainage drain according to the embodiment of the present invention is used as the material of the plate-like structure of the repair drainage drain, it is less likely to deteriorate even when exposed to rainwater for a long time. Such an effect of improving corrosion resistance can be more remarkablely exhibited by further limiting the total content of the impurity elements Fe, Si and Cu. Therefore, in order to obtain the effect of corrosion resistance, the total content of Fe, Si and Cu is more preferably 0.001% by mass or less, further preferably 0.0001% by mass or less.

好ましい1つの実施形態では、残部は、Alおよび不可避不純物元素である。不可避不純物元素としては、原料、資材、製造設備等の状況によって持ち込まれる微量元素(例えば、Mn、Mg、Ti、B、Cr、Ga、Ni、V、Zn、Zrなど)が挙げられる。本発明に係るアルミニウム材は、不可避不純物元素の合計含有量が、0.01質量%以下であることが好ましい。より好ましくは0.001質量%以下、さらに好ましくは0.0001質量%以下である。 In one preferred embodiment, the balance is Al and unavoidable impurity elements. Examples of the unavoidable impurity element include trace elements (for example, Mn, Mg, Ti, B, Cr, Ga, Ni, V, Zn, Zr, etc.) brought in depending on the conditions of raw materials, materials, manufacturing equipment, and the like. The aluminum material according to the present invention preferably has a total content of unavoidable impurity elements of 0.01% by mass or less. It is more preferably 0.001% by mass or less, still more preferably 0.0001% by mass or less.

なお、Fe、SiおよびCuを含むアルミニウム中の不純物元素の濃度の測定は、例えば固体発光分光分析により行うことができる。また、例えばグロー放電質量分析(GD−MS)のような質量分析により測定することもできる。 The concentration of impurity elements in aluminum containing Fe, Si and Cu can be measured, for example, by solid-state emission spectrum analysis. It can also be measured by mass spectrometry such as glow discharge mass spectrometry (GD-MS).

本発明の実施形態に係る改修排水ドレン用アルミニウム材は、O材に調質された調質処理材であることが好ましい。「O材に調質された」とは、JIS H 0001:1998で規定されるように、最も柔らかい状態を得るように焼き鈍しされた状態を意味する。このような形態であれば、製造時の圧延工程で導入された加工ひずみが緩和され柔軟性が向上するため、アルミニウム材を改修排水ドレンの板状構造体の素材として用いた場合、板状構造体が排水ドレンの補修部位の形状に合わせてより密着しやすくなり、改修排水ドレンの施工性をより向上することができる。 The aluminum material for repair drainage drain according to the embodiment of the present invention is preferably a tempering treatment material tempered to an O material. "Trained to O material" means annealed state to obtain the softest state as specified in JIS H 0001: 1998. In such a form, the processing strain introduced in the rolling process at the time of manufacturing is alleviated and the flexibility is improved. Therefore, when the aluminum material is used as the material of the plate-like structure of the repair drainage drain, the plate-like structure is used. It becomes easier for the body to adhere to the shape of the repaired part of the drainage drain, and the workability of the repaired drainage drain can be further improved.

2.改修排水ドレン用板状構造体
本発明の別の好ましい実施形態は、上述した組成を有するアルミニウム材からなる改修排水ドレン用板状構造体である。このような改修排水ドレン用板状構造体であれば、補修部位の形状に合わせて板状構造体を変形加工すると、十分に塑性変形させることができ、補修部位の形状に合わせて容易に密着させることができ施工性に優れた改修排水ドレンを提供できる。
2. Plate-shaped structure for repaired drainage drain Another preferred embodiment of the present invention is a plate-shaped structure for repaired drainage drain made of an aluminum material having the above-mentioned composition. In the case of such a plate-shaped structure for repair drainage drainage, if the plate-shaped structure is deformed according to the shape of the repaired part, it can be sufficiently plastically deformed and easily adhered to the shape of the repaired part. It is possible to provide a repair drainage drain that can be made to work and has excellent workability.

本発明の実施形態に係る改修排水ドレン用板状構造体は、板厚が小さすぎると、施工時に板状構造体が破損するおそれがあり、また雨水等による腐食による漏水が生じやすい。そのため、板厚は0.3mm以上であることが好ましく、より好ましくは0.5mm以上、さらに好ましくは0.7mm以上である。一方、板厚が大きすぎると柔軟性が低下し施工性が悪くなるおそれがある。そのため、板厚は2mm以下であることが好ましく、より好ましくは1.2mm以下、さらに好ましくは1.0mm以下である。 If the plate-like structure for repair drainage drain according to the embodiment of the present invention is too small in thickness, the plate-like structure may be damaged during construction, and water leakage due to corrosion due to rainwater or the like is likely to occur. Therefore, the plate thickness is preferably 0.3 mm or more, more preferably 0.5 mm or more, still more preferably 0.7 mm or more. On the other hand, if the plate thickness is too large, the flexibility may decrease and the workability may deteriorate. Therefore, the plate thickness is preferably 2 mm or less, more preferably 1.2 mm or less, still more preferably 1.0 mm or less.

3.改修排水ドレン用板状構造体の製造方法 3. 3. Manufacturing method of plate-shaped structure for repair drainage drain

本発明に係る改修排水ドレン用板状構造体の製造方法は、例えば、圧延素材作製工程および圧延工程を含む。以下、これらの各工程について説明する。 The method for producing a plate-shaped structure for repair drainage drain according to the present invention includes, for example, a rolling material manufacturing step and a rolling step. Hereinafter, each of these steps will be described.

(圧延素材作製工程)
圧延素材作製工程は、Fe、SiおよびCuの合計の含有量が0.01質量%以下であり、残部がAlおよび不可避不純物元素であるアルミニウム材からなる圧延素材を得る工程である。
(Rolling material manufacturing process)
The rolling material manufacturing step is a step of obtaining a rolled material in which the total content of Fe, Si and Cu is 0.01% by mass or less, and the balance is Al and an aluminum material which is an unavoidable impurity element.

上述した組成を有するアルミニウム材からなる圧延素材は、例えば以下のような方法で得ることができる。すなわち、後述する精製方法により得られる高純度アルミニウムに対して、不純物の侵入を抑制しつつ溶解した溶湯から所定形状の鋳塊を作製する。その後、鋳塊を所定形状に切削加工することで圧延素材を得ることができる。なお、圧延素材の作成方法は上述の方法に限定されるものではなく、従来公知の方法(例えばダイキャスティング、押出など)を用いてもよい。また、圧延素材に熱処理を施す工程(均質化熱処理工程)が含まれていてもよい。 A rolled material made of an aluminum material having the above-mentioned composition can be obtained by, for example, the following method. That is, an ingot having a predetermined shape is produced from the molten metal dissolved in the high-purity aluminum obtained by the refining method described later while suppressing the invasion of impurities. After that, a rolled material can be obtained by cutting the ingot into a predetermined shape. The method for producing the rolled material is not limited to the above-mentioned method, and conventionally known methods (for example, die casting, extrusion, etc.) may be used. Further, a step of heat-treating the rolled material (homogenization heat treatment step) may be included.

高純度アルミニウムの精製方法として、例えば偏析法および三層電解法を例示できる。 Examples of the method for purifying high-purity aluminum include a segregation method and a three-layer electrolysis method.

偏析法は、アルミニウム溶湯の凝固の際の偏析現象を利用した純化法であり、複数の手法が実用化されている。偏析法の一つの形態としては、容器の中に溶湯アルミニウムを注ぎ、容器を回転させながら上部の溶融アルミニウムを加熱、撹拌しつつ底部より精製アルミニウムを凝固させる。偏析法により、純度99.99質量%以上の高純度アルミニウムを得ることができる。 The segregation method is a purification method that utilizes the segregation phenomenon during solidification of molten aluminum, and a plurality of methods have been put into practical use. One form of the segregation method is to pour molten aluminum into the container, heat the molten aluminum at the top while rotating the container, and solidify the purified aluminum from the bottom while stirring. High-purity aluminum having a purity of 99.99% by mass or more can be obtained by the segregation method.

三層電解法は、Al−Cu合金層に比較的純度の低い純アルミニウム等(例えば純度99.9質量%のJIS−H2102の特1種程度のグレード)を投入し、溶融状態で陽極とし、その上に例えばフッ化アルミニウムおよびフッ化バリウム等を含む電解浴を配置し、陰極に高純度のアルミニウムを析出させる方法である。
三層電解法では純度99.999質量%以上の高純度アルミニウムを得ることができる。またアルミニウム中のFeの濃度を比較的容易に10質量ppm(0.001質量%)以下に抑制することができる。
In the three-layer electrolysis method, pure aluminum or the like having a relatively low purity (for example, a grade of JIS-H2102 having a purity of 99.9% by mass) is added to the Al—Cu alloy layer to form an anode in a molten state. This is a method in which an electrolytic bath containing, for example, aluminum fluoride and barium fluoride is placed on the electrolytic bath to deposit high-purity aluminum on the anode.
By the three-layer electrolysis method, high-purity aluminum having a purity of 99.999% by mass or more can be obtained. Further, the concentration of Fe in aluminum can be relatively easily suppressed to 10 mass ppm (0.001 mass%) or less.

高純度アルミニウムの製造方法は、偏析法、三層電解法に限定されるものではなく、帯溶融精製法、超高真空溶解精製法など、既に知られている他の方法でもよい。 The method for producing high-purity aluminum is not limited to the segregation method and the three-layer electrolysis method, and other methods already known such as a band melt purification method and an ultra-high vacuum dissolution purification method may be used.

(圧延工程)
圧延工程は、得られた圧延素材を圧延する工程であり、例えば、圧延加工率90%以上の圧延を施す工程である。ここでいう圧延加工率は、圧延素材の厚さ(つまり、圧延前の厚さ)から圧延により得られた最終板材の厚さを差し引いた値(つまり、圧延により減少した厚さ)を、圧延素材の厚さで除した値の百分率であって、次式:
圧延加工率(%)=[(圧延前の厚さ−圧延後の厚さ)÷圧延前の厚さ]×100
により算出される。例えば、厚さ10mmの圧延素材を圧延して厚さ1mmの板材とすれば、圧延加工率は90%となる。
(Rolling process)
The rolling step is a step of rolling the obtained rolled material, for example, a step of rolling with a rolling processing rate of 90% or more. The rolling processing ratio referred to here is the value obtained by subtracting the thickness of the final plate obtained by rolling from the thickness of the rolled material (that is, the thickness before rolling) (that is, the thickness reduced by rolling). It is the percentage of the value divided by the thickness of the material, and is based on the following equation:
Rolling rate (%) = [(Thickness before rolling-Thickness after rolling) ÷ Thickness before rolling] x 100
Is calculated by. For example, if a rolled material having a thickness of 10 mm is rolled into a plate material having a thickness of 1 mm, the rolling processing rate is 90%.

圧延素材に圧延加工を複数回行って最終板厚とすることが好ましい。圧延加工率が大きいほど生産効率を高められる場合が多いため、圧延加工率は90%以上が望ましい。なお、圧延加工率は高いほど好ましいため、上限は特に設けない。 It is preferable that the rolled material is rolled a plurality of times to obtain the final plate thickness. The higher the rolling process rate, the higher the production efficiency in many cases. Therefore, the rolling process rate is preferably 90% or more. Since the higher the rolling rate is, the more preferable it is, no upper limit is set.

圧延方法は、冷間圧延、熱間圧延のどちらでもよい。熱間圧延と冷間圧延を組み合わせることもでき、例えば、複数回行われる圧延加工のうち、初期は熱間圧延とし、後半を冷間圧延とするような形態をとることもできる。 The rolling method may be either cold rolling or hot rolling. Hot rolling and cold rolling can be combined. For example, among the rolling processes performed a plurality of times, the initial stage may be hot rolling and the latter half may be cold rolling.

(焼鈍工程)
好ましい実施形態において、前記圧延工程で得られた圧延材に対して、さらに焼鈍工程を行ってもよい。焼鈍工程は、前記圧延工程後に、300〜600℃の温度で1〜24時間保持する仕上げ焼鈍を施す工程である。最終焼鈍温度を300℃以上とすることで、より優れた柔軟性を有する改修排水ドレン用板状構造体を得ることができる。一方、その温度を600℃以下とすることで、焼鈍時の圧延材同士の貼り付きを抑制でき、外観品質の良好な改修排水ドレン用板状構造体が得られる。したがって焼鈍温度は300〜600℃が好ましい。また、焼鈍時間を1時間以上とすることで、より柔軟性に優れた改修排水ドレン用板状構造体が得られる。焼鈍時間は長くしても特性上の問題は生じないが、コスト上の観点から24時間程度までで充分である。したがって焼鈍時間は1〜24時間が望ましい。
(Annealing process)
In a preferred embodiment, the rolled material obtained in the rolling step may be further annealed. The annealing step is a step of performing finish annealing at a temperature of 300 to 600 ° C. for 1 to 24 hours after the rolling step. By setting the final annealing temperature to 300 ° C. or higher, a plate-like structure for repair drainage drain having more excellent flexibility can be obtained. On the other hand, by setting the temperature to 600 ° C. or lower, sticking of the rolled materials to each other during annealing can be suppressed, and a plate-like structure for repair drainage drain with good appearance quality can be obtained. Therefore, the annealing temperature is preferably 300 to 600 ° C. Further, by setting the annealing time to 1 hour or more, a plate-like structure for repair drainage drain having more excellent flexibility can be obtained. Even if the annealing time is lengthened, there is no problem in characteristics, but from the viewpoint of cost, up to about 24 hours is sufficient. Therefore, the annealing time is preferably 1 to 24 hours.

以下、実施例を用いて本発明をより詳細に説明するが、本発明は実施例により何ら制限されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the Examples.

1.下地追従性試験
(1)試験片作製
実施例の試験用に、高純度アルミニウム(4N−Al、5N−Al、6N−Al)からなる圧延素材を準備し、圧延により得られた圧延材から板材を切り出した。比較例の試験用に、純度が99.9質量%程度の純アルミニウムからなる圧延素材を準備し、圧延により得られた圧延材から板材を切り出した。それぞれ、430℃にて7時間の熱処理を施しO材とした板材と、圧延後に熱処理を施さないH材の板材、の2種類を作製した。比較例の試験用に、市販の純アルミニウム(広く入手可能なアルミニウム)として、A1100(純度99質量%程度)の質別H14の板材、およびA1050(純度99.5%程度)の質別H24の板材を準備した。上述の板材の一部を350℃にて3時間の熱処理を施し、O材の板材を作製した。比較材として、市販の高純度銅(銅純度99.96%程度)の板材を準備した。参考例の試験片として、市販の高純度鉛(鉛純度99.99質量%程度)の板材を準備した。表1に、準備した試験片の一覧を示した。純度6N以外の高純度アルミニウム材については、Fe、SiおよびCuの含有量を固体発光分光分析法で測定した。このようにして得られたFe、SiおよびCuの含有量、ならびにこれら3元素の合計値を、表1に示した。純度6Nのアルミニウムについては固体発光分光分析では定量下限以下となる元素があったため、グロー放電質量分析(GD−MS)で測定した結果を示した。なお、使用した高純度アルミニウム材が含有する不可避不純物(Mn、Mg、Ti、B、Cr、Ga、Ni、V、Zn、Zr)の量は、4N−Alは0.003質量%以下、5N−Alは0.0003質量%以下、6N−Alは0.00002質量%以下である。
1. 1. Base followability test (1) Preparation of test piece A rolled material made of high-purity aluminum (4N-Al, 5N-Al, 6N-Al) was prepared for the test of the example, and a plate material was prepared from the rolled material obtained by rolling. Was cut out. For the test of the comparative example, a rolled material made of pure aluminum having a purity of about 99.9% by mass was prepared, and a plate material was cut out from the rolled material obtained by rolling. Two types were prepared, one was a plate material that was heat-treated at 430 ° C. for 7 hours to form an O material, and the other was a plate material that was not heat-treated after rolling. For the test of the comparative example, as commercially available pure aluminum (aluminum widely available), a plate material of A1100 (purity of about 99% by mass) of quality H14 and A1050 (purity of about 99.5%) of quality H24. The board material was prepared. A part of the above-mentioned plate material was heat-treated at 350 ° C. for 3 hours to prepare an O material plate material. As a comparative material, a commercially available high-purity copper (copper purity of about 99.96%) plate material was prepared. As a test piece of a reference example, a commercially available high-purity lead (lead purity of about 99.99% by mass) plate material was prepared. Table 1 shows a list of prepared test pieces. For high-purity aluminum materials having a purity other than 6N, the contents of Fe, Si and Cu were measured by solid-state emission spectroscopy. The contents of Fe, Si and Cu thus obtained and the total value of these three elements are shown in Table 1. For aluminum with a purity of 6N, some elements were below the lower limit of quantification in solid-state emission spectroscopic analysis, so the results measured by glow discharge mass spectrometry (GD-MS) are shown. The amount of unavoidable impurities (Mn, Mg, Ti, B, Cr, Ga, Ni, V, Zn, Zr) contained in the high-purity aluminum material used is 0.003% by mass or less for 4N-Al and 5N. -Al is 0.0003% by mass or less, and 6N-Al is 0.00002% by mass or less.

実施例1〜18の試験片は、上述の高純度アルミニウム材を圧延し、得られた圧延材から板材を切り出し、大きさが、幅50mm×長さ300mm、厚さが0.5mm、0.8mmまたは1.0mmとなるようにした。
比較例1〜6および13〜15、ならびに参考例1〜2の試験片の大きさは、幅50mm×長さ300mm、厚さが0.5mm、0.8mmまたは1.0mmとした。
比較例7〜12の試験片は、上述の純度99.9質量%程度の純アルミニウムからなる圧延素材を圧延し、得られた圧延材から板材を切り出し、大きさが、幅50mm×長さ300mm、厚さが0.5mm、0.8mmまたは1.0mmとなるようにした。
In the test pieces of Examples 1 to 18, the above-mentioned high-purity aluminum material was rolled, and a plate material was cut out from the obtained rolled material, and the size was 50 mm in width × 300 mm in length and 0.5 mm in thickness. It was set to 8 mm or 1.0 mm.
The size of the test pieces of Comparative Examples 1 to 6 and 13 to 15 and Reference Examples 1 to 2 was 50 mm in width × 300 mm in length and 0.5 mm, 0.8 mm or 1.0 mm in thickness.
The test pieces of Comparative Examples 7 to 12 were obtained by rolling a rolled material made of pure aluminum having a purity of about 99.9% by mass, cutting out a plate material from the obtained rolled material, and measuring 50 mm in width × 300 mm in length. The thickness was adjusted to 0.5 mm, 0.8 mm or 1.0 mm.

(2)評価用模擬冶具の作製
図1に示すように、縦250mm×横250mm×高さ50mmの硬質金属ブロック(材料名A5052合金)を準備し、上面の略中心φ200mmの範囲に最大深さ10mmの窪み12を設け、排水ドレン下地を模した評価用模擬治具10を作製した。なお、評価用模擬治具10に設けた窪み12は、曲率半径が約505mmである球面の一部となるようにした。
(2) Preparation of simulated jig for evaluation As shown in FIG. 1, a hard metal block (material name A5052 alloy) having a length of 250 mm, a width of 250 mm, and a height of 50 mm is prepared, and the maximum depth is within a range of approximately φ200 mm at the center of the upper surface. A 10 mm recess 12 was provided, and an evaluation simulation jig 10 imitating a drainage drain base was produced. The recess 12 provided in the evaluation simulation jig 10 is made to be a part of a spherical surface having a radius of curvature of about 505 mm.

(3)変形性および反発高さの評価
評価用模擬治具の上面の端部に試験片留め具14を設け、(1)で準備した試験片20が評価用模擬治具10の上面16に平行になるように、試験片20の一端を留め具14に固定して設置した。
続いて、設置した試験片20に対して、上方から見て窪み12の領域を、上方からハンマー(ヘッド径:32mm、ヘッド重さ:約700g、全長:370mm)で毎分120回×2分間(計240回)叩き、試験片20が評価用模擬治具10の窪み12の表面に追従させるようにした。なお、ハンマーのヘッドを振り上げる際には、ハンマーのヘッドの高さが、模擬治具10の上面16から10〜20cm以内の範囲となるようにし、ハンマーのヘッドの振り下ろしはヘッドの自重を利用して行い、また留め具14で固定されていない側の試験片の一端を、ハンマーを持たない手で軽く下方に押さえながらハンマーで叩いた。
(3) Evaluation of Deformability and Repulsion Height A test piece fastener 14 is provided at the end of the upper surface of the evaluation simulation jig, and the test piece 20 prepared in (1) is placed on the upper surface 16 of the evaluation simulation jig 10. One end of the test piece 20 was fixed to the fastener 14 so as to be parallel to each other.
Subsequently, with respect to the installed test piece 20, the area of the recess 12 when viewed from above is squeezed from above with a hammer (head diameter: 32 mm, head weight: about 700 g, total length: 370 mm) 120 times per minute for 2 minutes. By tapping (240 times in total), the test piece 20 was made to follow the surface of the recess 12 of the evaluation simulation jig 10. When swinging up the hammer head, the height of the hammer head should be within a range of 10 to 20 cm from the upper surface 16 of the simulated jig 10, and the hammer head should be swung down by its own weight. It was performed by using it, and one end of the test piece on the side not fixed by the fastener 14 was hit with a hammer while being lightly pressed downward by a hand without a hammer.

変形性の評価としては、240回叩き終えた後に、留め具14で固定されていない側の試験片の一端を軽く下方に押さえた状態で、試験片が窪みに良好に追従していると目視で認められるものを良好(○)、試験片が窪みに完全には追従していないが部分的に追従していると目視で認められるものを課題有(△)、試験片が窪みに全く追従しないものを不良(×)として評価した。
反発高さの評価としては、240回叩き終えた後、試験片の他端(すなわち、留め具が設置されている側とは反対側)の評価用模擬治具10の上面16からの跳ね上がり距離(図2に示す高さh)を測定して、反発高さとして評価した。反発高さが小さいほど、試験片が塑性変形をしやすい、あるいは下地へ追従しやすいと考えられる。
変形性が○であり、かつ反発高さが小さい場合、下地追従性がよく施工性が良好であると評価することができる。
As an evaluation of the deformability, after hitting 240 times, it is visually observed that the test piece follows the dent well with one end of the test piece on the side not fixed by the fastener 14 being lightly pressed downward. Good (○), the test piece does not completely follow the dent, but there is a problem that it is visually recognized that it partially follows (△), and the test piece completely follows the dent. Those that did not were evaluated as defective (x).
As an evaluation of the repulsion height, after hitting 240 times, the jumping distance from the upper surface 16 of the evaluation simulation jig 10 at the other end of the test piece (that is, the side opposite to the side where the fastener is installed). (Height h shown in FIG. 2) was measured and evaluated as the repulsion height. It is considered that the smaller the repulsion height, the easier it is for the test piece to undergo plastic deformation or to follow the substrate.
When the deformability is ◯ and the repulsion height is small, it can be evaluated that the base followability is good and the workability is good.

変形性が良好(○)であり、かつ反発高さが26mm以内である試験片について、総合良否を○(すなわち、下地追従性が良好)とした。それ以外の試験片については、総合良否を×(すなわち、下地追従性が不良)とした。結果を表1に示す。 For the test pieces having good deformability (◯) and a repulsion height of 26 mm or less, the overall quality was evaluated as ○ (that is, good ground followability). For the other test pieces, the overall quality was marked with x (that is, the ground followability was poor). The results are shown in Table 1.

変形性が不良(×)である試験片では、板材がほとんど変形しない場合には反発高さが小さな値になり、またある程度変形したときには反発高さが大きくなった。これより、変形性が不良(×)である試験片では反発高さの測定値は下地追従性(施工性)を反映せず、むしろ逆の傾向を示すことがわかった。したがって、変形性が不良(×)である試験片では反発高さは下地追従性(施工性)の評価として適切ではないと考えられ、表1に有効データ無(−)として記した。
変形性が課題有(△)である試験片では、変形性が不良(×)のときと同様の理由により、反発高さの測定値が下地追従性(施工性)を反映しない場合があると考えられたため、表1に括弧書きで参考値として記した。
In the test piece having poor deformability (x), the repulsion height became a small value when the plate material was hardly deformed, and the repulsion height became large when the plate material was deformed to some extent. From this, it was found that the measured value of the repulsion height did not reflect the groundwork followability (workability) in the test piece having poor deformability (x), but rather showed the opposite tendency. Therefore, it is considered that the repulsion height is not appropriate for the evaluation of the base followability (workability) in the test piece having poor deformability (x), and it is described as no valid data (-) in Table 1.
For a test piece whose deformability is problematic (Δ), the measured value of the repulsion height may not reflect the ground followability (workability) for the same reason as when the deformability is poor (×). Since it was considered, it is shown in parentheses in Table 1 as a reference value.

Figure 0006877104
Figure 0006877104

表1から分かるように、Fe、SiおよびCuの合計含有量が0.01質量%以下である高純度アルミニウムからなる試験片を用いた実施例1〜18は、いずれも、変形性が良好であり、かつ反発高さが26mm以内であり、総合良否が良好であった。
Fe、SiおよびCuの合計含有量が0.01質量%以下である、純度が4Nクラスの高純度アルミニウムからなる試験片を用いた実施例1と実施例2とを比べると、O材に調質(完全焼き鈍し処理)された調質処理材を用いた実施例2は、完全焼き鈍し処理をしていない実施例1よりも、反発高さが低く、下地追従性が向上していた。
Fe、SiおよびCuの合計含有量が0.001質量%以下である5Nクラス、および0.0001質量%以下である6Nクラスの高純度アルミニウムからなる試験片を用いた場合、4Nクラスの場合よりもさらに反発高さが小さくなり、下地追従性(施工性)がさらに向上していた。
As can be seen from Table 1, all of Examples 1 to 18 using the test piece made of high-purity aluminum having a total content of Fe, Si and Cu of 0.01% by mass or less have good deformability. Yes, and the repulsion height was within 26 mm, and the overall quality was good.
Comparing Example 1 and Example 2 using a test piece made of high-purity aluminum having a purity of 4N class and having a total content of Fe, Si and Cu of 0.01% by mass or less, it is adjusted to O material. In Example 2 using the quality (completely annealed) tempered material, the repulsion height was lower and the substrate followability was improved as compared with Example 1 in which the complete annealing treatment was not performed.
When using a test piece made of high-purity aluminum of 5N class in which the total content of Fe, Si and Cu is 0.001% by mass or less and 6N class in which the total content is 0.0001% by mass or less, compared to the case of 4N class. However, the repulsion height was further reduced, and the ground followability (workability) was further improved.

一方、Fe、SiおよびCuの合計含有量が0.01質量%超である、純度が99質量%程度の純アルミニウム(質別H14またはH24)からなる試験片を用いた比較例1および3は、変形性が不良(×)であった。このような純アルミニウムをO材に調質した調質処理材である試験片を用いた比較例2および4は、変形性の改善が見られたものの課題有(△)であった。
Fe、SiおよびCuの合計含有量が0.01質量%超である、純度が99.9質量%程度の純アルミニウムからなる試験を用いた比較例7〜12は、H材の場合(比較例7、9および11)には変形性が不良(×)、O材の場合(比較例8、10および12)には変形性が課題有(△)であった。
On the other hand, Comparative Examples 1 and 3 using a test piece made of pure aluminum (classification H14 or H24) having a total content of Fe, Si and Cu of more than 0.01% by mass and a purity of about 99% by mass are shown. , Deformability was poor (x). Comparative Examples 2 and 4 using the test piece, which is a tempered material obtained by tempering pure aluminum into an O material, showed improvement in deformability, but had a problem (Δ).
Comparative Examples 7 to 12 using the test made of pure aluminum having a total content of Fe, Si and Cu of more than 0.01% by mass and a purity of about 99.9% by mass are for H material (Comparative Example). In the case of 7, 9 and 11), the deformability was poor (x), and in the case of the O material (Comparative Examples 8, 10 and 12), the deformability was problematic (Δ).

2.耐食性試験
耐食性試験として、素材が高純度鉛(鉛純度99.99%程度)、高純度銅(JIS規格の番号C1020、銅純度99.96%程度)、アルミニウム合金(JIS規格の合金番号A5052(H材))および高純度アルミニウム(5N−Al、H材)からそれぞれ構成される4つのサンプルを準備して、それぞれのサンプルに対して浸漬溶解試験を行った。改修排水ドレンの実使用環境は施工地域、施工場所(周辺環境)、季節等の種々の要因の影響を受けると考えられ、耐食性評価条件も複数考えられるため、今回は下記条件で評価した。酢酸にてpH3に調整した30℃の3.5質量%NaCl水溶液に72時間浸漬する条件で実施した。試験後、腐食生成物を除去した後の腐食減量を測定し、その値から全面均一腐食を仮定して浸食速度を算出した。耐食性試験の結果を表2に示す。
2. Corrosion resistance test As a corrosion resistance test, the material is high-purity lead (lead purity about 99.99%), high-purity copper (JIS standard number C1020, copper purity about 99.96%), aluminum alloy (JIS standard alloy number A5052). Four samples each composed of H material)) and high-purity aluminum (5N-Al, H material) were prepared, and a immersion dissolution test was performed on each sample. The actual usage environment of the repaired drainage drain is considered to be affected by various factors such as the construction area, construction site (surrounding environment), and season, and there are multiple possible corrosion resistance evaluation conditions. Therefore, this time, the evaluation was made under the following conditions. The procedure was carried out under the condition of immersing in a 3.5 mass% NaCl aqueous solution at 30 ° C. adjusted to pH 3 with acetic acid for 72 hours. After the test, the corrosion weight loss after removing the corrosion products was measured, and the erosion rate was calculated from the value assuming uniform corrosion over the entire surface. The results of the corrosion resistance test are shown in Table 2.

Figure 0006877104
Figure 0006877104

表2の結果から分かるように、従来、改修排水ドレンの板状構造体の材料として用いられている鉛に比べて、高純度アルミニウムは、浸食速度が約4分の1であり、高純度アルミニウムは、鉛よりも優れた耐食性を有すると考えられる。 As can be seen from the results in Table 2, high-purity aluminum has an erosion rate of about one-fourth that of lead, which has been conventionally used as a material for the plate-like structure of the repair drainage drain, and is high-purity aluminum. Is considered to have better corrosion resistance than lead.

10:評価用模擬治具
12:窪み
14:試験片留め具
16:上面
20:試験片
32:排水口
34:排水ドレン下地
36:排水ドレン下地平坦部
38:排水ドレン下地窪み部
40:改修排水ドレン
42:板状構造体
44:中空管
50:既設ドレン管
10: Simulation jig for evaluation 12: Depression 14: Test piece Fastener 16: Top surface 20: Test piece 32: Drainage port 34: Drainage drain base 36: Drainage drain base flat part 38: Drainage drain base dent part 40: Repair drainage Drain 42: Plate-like structure 44: Hollow pipe 50: Existing drain pipe

Claims (3)

Fe、SiおよびCuの合計の含有量が0.01質量%以下であり、残部がAlおよび不可避不純物元素であるアルミニウム材からなる板状構造体を含む改修排水ドレン A repair drainage drain containing a plate-like structure in which the total content of Fe, Si and Cu is 0.01 % by mass or less, and the balance is made of an aluminum material which is Al and an unavoidable impurity element. 前記アルミニウム材がO材に調質された調質処理材である、請求項1に記載の改修排水ドレン The repair drainage drain according to claim 1, wherein the aluminum material is a heat-treated material prepared into an O material. 前記板状構造体の板厚が0.3〜2mmである、請求項1または2に記載の改修排水ドレンThe repair drainage drain according to claim 1 or 2 , wherein the plate-like structure has a plate thickness of 0.3 to 2 mm.
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