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JP6885121B2 - Secondary battery and its manufacturing method - Google Patents
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JP6885121B2 - Secondary battery and its manufacturing method - Google Patents

Secondary battery and its manufacturing method Download PDF

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JP6885121B2
JP6885121B2 JP2017048305A JP2017048305A JP6885121B2 JP 6885121 B2 JP6885121 B2 JP 6885121B2 JP 2017048305 A JP2017048305 A JP 2017048305A JP 2017048305 A JP2017048305 A JP 2017048305A JP 6885121 B2 JP6885121 B2 JP 6885121B2
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current collecting
extending portion
extending
terminal
connecting portion
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JP2018129280A (en
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聡美 山本
聡美 山本
瑞穂 松本
瑞穂 松本
寛史 高松
寛史 高松
裕明 今西
裕明 今西
一郎 村田
一郎 村田
きよみ 神月
きよみ 神月
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Description

本開示は、二次電池およびその製造方法に関する。 The present disclosure relates to a secondary battery and a method for manufacturing the secondary battery.

二次電池においては、高効率での放電および高容量を実現可能とするために、複数枚の電極箔を積層あるいは巻回して電極体を構成している。電極体は、集電端子(集電体ともいう)とともにケース体の内部に収容され、外部端子がケース体の外部(蓋の上)に配置される。電極体に取り付けられた集電端子は、電極体と外部端子とを電気的に接続する。 In a secondary battery, in order to realize high-efficiency discharge and high capacity, a plurality of electrode foils are laminated or wound to form an electrode body. The electrode body is housed inside the case body together with the current collector terminal (also referred to as a current collector), and the external terminal is arranged outside the case body (on the lid). The current collecting terminal attached to the electrode body electrically connects the electrode body and the external terminal.

特開平10−106536号公報(特許文献1)に開示されているように、電極体を構成している複数枚の集電箔の端部は、集電端子に設けられたスリットの内側に束ねた状態で挿入され、レーザー溶接によって両者は溶接される。これと同様な技術は、特開2013−179015号公報(特許文献2)等にも開示されている。 As disclosed in Japanese Patent Application Laid-Open No. 10-106536 (Patent Document 1), the ends of a plurality of current collector foils constituting the electrode body are bundled inside a slit provided in the current collector terminal. It is inserted in a state of being inserted, and both are welded by laser welding. A technique similar to this is also disclosed in Japanese Patent Application Laid-Open No. 2013-179015 (Patent Document 2) and the like.

特開平10−106536号公報Japanese Unexamined Patent Publication No. 10-106536 特開2013−179015号公報Japanese Unexamined Patent Publication No. 2013-179015

従来の二次電池およびその製造方法に用いられる集電端子は、複数の延在部を有しており、隣り合う2つの延在部の間にスリットが形成される(特許文献1,2参照)。 The current collecting terminal used in the conventional secondary battery and its manufacturing method has a plurality of extending portions, and a slit is formed between two adjacent extending portions (see Patent Documents 1 and 2). ).

しかしながら、複数枚の集電箔の端部を束ねた状態でスリットに挿入するに際して、スリット幅が狭いと、複数の集電箔の端部をスリットに挿入しにくく、結果として集電端子を電極体に組み付けることが困難となる場合がある。一方、複数枚の集電箔の端部を束ねた状態で集電端子にレーザー溶接にて接合するに際して、スリット幅が広いと、すなわち2つの延在部間の間隔が広いと、複数枚の集電箔の端部と集電端子の延在部とを相互に接触させることが困難となったり、溶接用のレーザーがスリットを通過して集電端子の内側に位置する集電箔やセパレータに到達し(いわゆるレーザー抜け)、結果として適切な溶接を行なうことが困難となったりする場合がある。 However, when inserting the ends of a plurality of current collector foils into the slit in a bundled state, if the slit width is narrow, it is difficult to insert the ends of the plurality of current collector foils into the slit, and as a result, the current collector terminals are electrodeed. It may be difficult to attach it to the body. On the other hand, when the ends of a plurality of current collector foils are bundled and joined to the current collector terminals by laser welding, if the slit width is wide, that is, if the distance between the two extending portions is wide, the plurality of sheets are present. It becomes difficult to make the end of the current collector foil and the extending part of the current collector terminal contact each other, or the laser for welding passes through the slit and is located inside the current collector terminal. (So-called laser omission) may be reached, and as a result, it may be difficult to perform proper welding.

本開示は、集電端子を電極体に容易に組み付けることができ、かつ集電端子を電極体に容易にかつ安定して接合することが可能な構成を備えた二次電池およびその製造方法を提供することを目的とする。 The present disclosure describes a secondary battery having a configuration in which the current collecting terminal can be easily assembled to the electrode body and the current collecting terminal can be easily and stably bonded to the electrode body, and a method for manufacturing the secondary battery. The purpose is to provide.

本開示に基づく二次電池は、正極用および負極用の集電箔がセパレータを介して積層されてなる電極本体部と、正極用および負極用の上記集電箔がそれぞれ上記電極本体部に対してその外側に延出してなる集電箔延出部と、上記集電箔延出部を構成している複数枚の上記集電箔によって上記集電箔延出部の外側先端に形成された集電箔接続部とを含む、電極体と、上記集電箔接続部の長手方向に沿って延びる形状を有する第1延在部を含み、上記第1延在部が上記集電箔接続部に溶接された第1集電端子と、上記長手方向に沿って延びる形状を有する第2延在部を含み、上記第2延在部が上記集電箔接続部に溶接された、上記第1集電端子と互いに別部材である第2集電端子と、を備え、上記第1延在部と上記第2延在部とは上記集電箔接続部に対して互いに反対側に位置し、上記第1延在部および上記第2延在部の双方が上記集電箔接続部に溶接されることで、上記第1延在部、上記第2延在部および上記集電箔接続部を一体化する溶接部が形成されており、上記第1集電端子と上記第2集電端子とは上記溶接部を介して一体化されている。 In the secondary battery based on the present disclosure, the electrode main body portion in which the current collector foils for the positive electrode and the negative electrode are laminated via the separator, and the current collector foils for the positive electrode and the negative electrode are respectively attached to the electrode main body portion. A current collecting foil extending portion extending to the outside of the current collecting foil and a plurality of the current collecting foils constituting the current collecting foil extending portion are formed at the outer tip of the current collecting foil extending portion. The electrode body including the current collecting foil connecting portion and the first extending portion having a shape extending along the longitudinal direction of the collecting foil connecting portion are included, and the first extending portion is the collecting foil connecting portion. A first current collecting terminal welded to the above, and a second extending portion having a shape extending along the longitudinal direction are included, and the second extending portion is welded to the current collecting foil connecting portion. The current collecting terminal and the second current collecting terminal which are separate members are provided, and the first extending portion and the second extending portion are located on opposite sides of the current collecting foil connecting portion. By welding both the first extending portion and the second extending portion to the current collecting foil connecting portion, the first extending portion, the second extending portion, and the current collecting foil connecting portion can be formed. A welded portion to be integrated is formed, and the first current collecting terminal and the second current collecting terminal are integrated via the welded portion.

上記のように構成された二次電池は、第1集電端子と第2集電端子とが互いに別部材として構成されているため、その製造過程において第1集電端子と第2集電端子とを相対移動させることによって、集電箔接続部が挿入される部分であるスリットの幅を変化させることができる。たとえば集電箔接続部をスリットに挿入するに際しては、スリット幅が可動範囲の中で最大限広くなるように第1集電端子および第2集電端子を配置した状態で、集電箔接続部をスリットに挿入することができ、第1集電端子および第2集電端子を電極体に容易に組み付けることが可能となる。またレーザー溶接を行なう際には、スリット幅が狭くなるように第1集電端子および第2集電端子を配置することができるため、集電箔接続部と第1集電端子および第2集電端子とを相互に容易に接触させることができ、レーザー溶接を実施したとしてもいわゆるレーザー抜けが発生することもなく、適切な溶接を行なうことができ、高品質の二次電池とすることができる。 In the secondary battery configured as described above, since the first current collecting terminal and the second current collecting terminal are configured as separate members from each other, the first current collecting terminal and the second current collecting terminal are formed in the manufacturing process. By moving and relative to each other, the width of the slit, which is the portion where the current collector foil connecting portion is inserted, can be changed. For example, when inserting the current collector foil connection portion into the slit, the current collector foil connection portion is arranged with the first current collector terminal and the second current collector terminal arranged so that the slit width is as wide as possible within the movable range. Can be inserted into the slit, and the first current collecting terminal and the second current collecting terminal can be easily assembled to the electrode body. Further, when performing laser welding, the first current collector terminal and the second current collector terminal can be arranged so that the slit width becomes narrower, so that the current collector foil connection portion, the first current collector terminal, and the second current collector terminal can be arranged. The electric terminals can be easily brought into contact with each other, and even if laser welding is performed, so-called laser omission does not occur, appropriate welding can be performed, and a high-quality secondary battery can be obtained. it can.

上記の構成において、上記第1集電端子は、間隙を隔てて相互に隣り合うように形成され、上記間隙を内側から外側に向けて通過するように上記集電箔接続部が配置される第1の上記第1延在部と第2の上記第1延在部とを含み、第1の上記第1延在部は、上記長手方向に沿って延びる平板部と、上記平板部のうちの上記集電箔接続部が配置される側の端部から外側に向けて突出する形状を有する凸部とを有し、上記第2集電端子の上記第2延在部は、第2の上記第1延在部の外側表面に重なり合うように配置され、上記溶接部は、上記第2延在部のうちの上記集電箔接続部が位置する側の端部と、上記集電箔接続部と、第1の上記第1延在部に設けられた上記凸部とを一体化していてもよい。 In the above configuration, the first current collector terminals are formed so as to be adjacent to each other with a gap between them, and the current collector foil connection portion is arranged so as to pass through the gap from the inside to the outside. 1. The first extending portion and the second extending portion of the first extending portion are included, and the first extending portion of the first extending portion includes a flat plate portion extending along the longitudinal direction and a flat plate portion of the flat plate portion. The second extending portion of the second current collecting terminal has a convex portion having a shape protruding outward from the end portion on the side where the current collecting foil connecting portion is arranged, and the second extending portion of the second current collecting terminal is the second one. The welded portion is arranged so as to overlap the outer surface of the first extending portion, and the welded portion is the end portion of the second extending portion on the side where the current collecting foil connecting portion is located and the current collecting foil connecting portion. And the convex portion provided in the first extending portion may be integrated.

上記の構成によれば、第1の第1延在部と第2の第1延在部との間に第2延在部が配置される場合に比べて、第1の第1延在部と第2の第1延在部との間に形成される隙間を小さくすることができ、第1集電端子や第2集電端子の小型化を図ることができ、ひいては二次電池の全体としての小型化を図ることも可能となる。 According to the above configuration, the first extending portion is compared with the case where the second extending portion is arranged between the first extending portion and the second first extending portion. The gap formed between the first and the second extending portion can be reduced, the first current collecting terminal and the second current collecting terminal can be miniaturized, and the entire secondary battery can be reduced in size. It is also possible to reduce the size of the battery.

上記の構成において、上記第2延在部のうちの上記集電箔接続部が位置する側の上記端部と、第1の上記第1延在部に設けられた上記凸部とは、各々の外側表面が略面一となる関係を有していてもよい。 In the above configuration, the end portion of the second extending portion on the side where the current collecting foil connecting portion is located and the convex portion provided on the first extending portion are respectively. The outer surface of the surface may be substantially flush with each other.

上記の構成によれば、第1集電端子および第2集電端子が溶接時において集電箔接続部に対して両側から均等に接触ないし圧接されるため、集電箔接続部が湾曲したり屈曲したりすることがなく、第1集電端子および第2集電端子を集電箔接続部に対して安定して容易に溶接することが可能となる。 According to the above configuration, since the first current collecting terminal and the second current collecting terminal are evenly contacted or pressed against the current collecting foil connecting portion from both sides at the time of welding, the current collecting foil connecting portion may be curved. The first current collector terminal and the second current collector terminal can be stably and easily welded to the current collector foil connection portion without bending.

上記の構成において、上記溶接部は、上記凸部のうちの上記長手方向における両端以外の部分と、上記集電箔接続部と、上記第2延在部のうちの上記集電箔接続部が位置する側の上記端部とを溶接するように設けられていてもよい。 In the above configuration, the welded portion includes a portion of the convex portion other than both ends in the longitudinal direction, the current collector foil connecting portion, and the current collecting foil connecting portion of the second extending portion. It may be provided so as to weld the end portion on the side to be located.

上記の構成に関して、溶接の過程では、溶接対象である集電箔接続部などが固体から液体へと変化し再び固体へと戻るという状態遷移が行なわれるため、集電箔接続部が挿入される部分である上記の隙間の幅も溶接の過程で変化することとなる。上記の構成によれば、隙間の幅の変化量を小さくすることができ、溶接後の溶接部の状態におよぶ影響を小さくすることが可能となる。また溶接箇所の近くに存在するセパレータは熱に弱いところ、溶接部の溶接長を短くすることによってセパレータにおよぶ熱影響を小さくすることも可能となる。 Regarding the above configuration, in the welding process, a state transition is performed in which the current collector foil connection portion to be welded changes from a solid to a liquid and then returns to a solid state, so that the current collector foil connection portion is inserted. The width of the above-mentioned gap, which is a portion, also changes during the welding process. According to the above configuration, the amount of change in the width of the gap can be reduced, and the influence on the state of the welded portion after welding can be reduced. Further, since the separator existing near the welded portion is vulnerable to heat, it is possible to reduce the influence of heat on the separator by shortening the welding length of the welded portion.

本開示に基づく二次電池の製造方法は、正極用および負極用の集電箔がセパレータを介して積層されてなる電極本体部と、正極用および負極用の上記集電箔がそれぞれ上記電極本体部に対してその外側に延出してなる集電箔延出部と、上記集電箔延出部を構成している複数枚の上記集電箔によって上記集電箔延出部の外側先端に形成された集電箔接続部とを含む、電極体を準備する工程と、第1延在部を含み、上記第1延在部が上記集電箔接続部の長手方向に沿って延びる形状を有する第1集電端子と、第2延在部を含み、上記第2延在部が上記長手方向に沿って延びる形状を有する、上記第1集電端子と互いに別部材である第2集電端子とを準備する工程と、上記第1延在部と上記第2延在部とが上記集電箔接続部に対して互いに反対側に位置するように、上記第1集電端子および上記第2集電端子を配置する配置工程と、上記第1延在部と上記第2延在部とが相互に近づくように上記第1集電端子と上記第2集電端子とを相対移動させることによって、上記第1延在部および上記第2延在部の双方を上記集電箔接続部に接触させる工程と、上記第1延在部および上記第2延在部の双方が上記集電箔接続部に接触している状態でレーザー溶接を実施して上記第1延在部、上記第2延在部および上記集電箔接続部を一体化する溶接部を形成することで、上記第1集電端子と上記第2集電端子とを上記溶接部を介して一体化させる溶接工程と、を備える。 In the method for manufacturing a secondary battery based on the present disclosure, an electrode main body portion in which current collector foils for a positive electrode and a negative electrode are laminated via a separator, and the current collector foils for a positive electrode and a negative electrode are the electrode main bodies, respectively. The current collecting foil extending portion extending to the outside of the portion and the plurality of current collecting foils constituting the current collecting foil extending portion are attached to the outer tip of the current collecting foil extending portion. A step of preparing the electrode body including the formed current collector foil connecting portion and a shape including the first extending portion and the first extending portion extending along the longitudinal direction of the current collecting foil connecting portion. A second current collector that includes a first current collector terminal and a second extending portion, and has a shape in which the second extending portion extends along the longitudinal direction, and is a separate member from the first current collecting terminal. The first current collecting terminal and the first current collecting terminal so that the step of preparing the terminal and the first extending portion and the second extending portion are located on opposite sides of the current collecting foil connecting portion. (2) The first current collecting terminal and the second current collecting terminal are relatively moved so that the first extending portion and the second extending portion are close to each other in the arrangement step of arranging the current collecting terminals. As a result, both the first extending portion and the second extending portion are brought into contact with the current collecting foil connecting portion, and both the first extending portion and the second extending portion are made of the current collecting foil. By performing laser welding in contact with the connecting portion to form a welded portion that integrates the first extending portion, the second extending portion, and the current collecting foil connecting portion, the first extending portion is formed. A welding step of integrating the current collecting terminal and the second current collecting terminal via the welded portion is provided.

上記の構成によれば、第1集電端子と第2集電端子とが互いに別部材として構成されているため、その製造過程において第1集電端子と第2集電端子とを相対移動させることによって、集電箔接続部が挿入される部分であるスリットの幅を変化させることができる。たとえば集電箔接続部をスリットに挿入するに際しては、スリット幅が可動範囲の中で最大限広くなるように第1集電端子および第2集電端子を配置した状態で、集電箔接続部をスリットに挿入することができ、第1集電端子および第2集電端子を電極体に容易に組み付けることが可能となる。またレーザー溶接を行なう際には、スリット幅が狭くなるように第1集電端子および第2集電端子を配置することができるため、集電箔接続部と第1集電端子および第2集電端子とを相互に容易に接触させることができ、レーザー溶接を実施したとしてもいわゆるレーザー抜けが発生することもなく、適切な溶接を行なうことができ、高品質の二次電池を作製することが可能となる。 According to the above configuration, since the first current collecting terminal and the second current collecting terminal are configured as separate members from each other, the first current collecting terminal and the second current collecting terminal are relatively moved in the manufacturing process. Thereby, the width of the slit, which is the portion where the current collecting foil connecting portion is inserted, can be changed. For example, when inserting the current collector foil connection portion into the slit, the current collector foil connection portion is arranged with the first current collector terminal and the second current collector terminal arranged so that the slit width is as wide as possible within the movable range. Can be inserted into the slit, and the first current collecting terminal and the second current collecting terminal can be easily assembled to the electrode body. Further, when performing laser welding, the first current collector terminal and the second current collector terminal can be arranged so that the slit width becomes narrower, so that the current collector foil connection portion, the first current collector terminal, and the second current collector terminal can be arranged. It is possible to easily bring the electric terminals into contact with each other, and even if laser welding is performed, so-called laser omission does not occur, appropriate welding can be performed, and a high-quality secondary battery can be manufactured. Is possible.

上記の構成において、上記第1集電端子は、間隙を隔てて相互に隣り合うように形成され、上記間隙を内側から外側に向けて通過するように上記集電箔接続部が配置される第1の上記第1延在部と第2の上記第1延在部とを含み、第1の上記第1延在部は、上記長手方向に沿って延びる平板部と、上記平板部のうちの上記集電箔接続部が配置される側の端部から外側に向けて突出する形状を有する凸部とを有し、上記配置工程は、上記第2集電端子の上記第2延在部を第2の上記第1延在部の外側表面に重なり合うように配置することで、上記第2延在部と上記凸部との間にスリットを形成する工程と、上記集電箔接続部が上記スリットを内側から外側に向けて通過するように、上記第1集電端子および上記第2集電端子を配置する工程と、を含み、上記溶接工程においては、上記第2延在部のうちの上記集電箔接続部が位置する側の端部と第1の上記第1延在部に設けられた上記凸部との双方が上記集電箔接続部に接触している状態で上記レーザー溶接が実施され、上記溶接部の形成によって、上記第2延在部のうちの上記集電箔接続部が位置する側の上記端部と、上記集電箔接続部と、第1の上記第1延在部に設けられた上記凸部とが一体化されてもよい。 In the above configuration, the first current collector terminals are formed so as to be adjacent to each other with a gap between them, and the current collector foil connecting portion is arranged so as to pass through the gap from the inside to the outside. 1. The first extending portion and the second extending portion of the first extending portion are included, and the first extending portion of the first extending portion includes a flat plate portion extending along the longitudinal direction and a flat plate portion of the flat plate portion. It has a convex portion having a shape protruding outward from the end portion on the side where the current collector foil connection portion is arranged, and the arrangement step involves the second extending portion of the second current collector terminal. The step of forming a slit between the second extending portion and the convex portion by arranging the second extending portion so as to overlap the outer surface of the first extending portion, and the current collecting foil connecting portion are described above. The step of arranging the first current collecting terminal and the second current collecting terminal so as to pass through the slit from the inside to the outside is included, and in the welding step, of the second extending portion. Laser welding in a state where both the end portion on the side where the current collector foil connection portion is located and the convex portion provided on the first first extension portion are in contact with the current collector foil connection portion. Is carried out, and by forming the welded portion, the end portion of the second extending portion on the side where the current collecting foil connecting portion is located, the current collecting foil connecting portion, and the first first The convex portion provided on the extending portion may be integrated with the convex portion.

上記の構成によれば、第1の第1延在部と第2の第1延在部との間に第2延在部が配置される場合に比べて、第1の第1延在部と第2の第1延在部との間に形成される隙間を小さくすることができ、第1集電端子や第2集電端子の小型化を図ることができ、ひいては二次電池の全体としての小型化を図ることも可能となる。 According to the above configuration, the first extending portion is compared with the case where the second extending portion is arranged between the first extending portion and the second first extending portion. The gap formed between the first and the second extending portion can be reduced, the first current collecting terminal and the second current collecting terminal can be miniaturized, and the entire secondary battery can be reduced in size. It is also possible to reduce the size of the battery.

上記の構成において、上記レーザー溶接が実施される際、上記第2延在部のうちの上記集電箔接続部が位置する側の上記端部と、第1の上記第1延在部に設けられた上記凸部とは、各々の外側表面が略面一となる関係を有している。 In the above configuration, when the laser welding is performed, the end portion of the second extending portion on the side where the current collecting foil connecting portion is located and the first extending portion are provided. The convex portions have a relationship in which their outer surfaces are substantially flush with each other.

上記の構成によれば、第1集電端子および第2集電端子が溶接時において集電箔接続部に対して両側から均等に接触ないし圧接されるため、集電箔接続部が湾曲したり屈曲したりすることがなく、第1集電端子および第2集電端子を集電箔接続部に対して安定して容易に溶接することが可能となる。 According to the above configuration, since the first current collecting terminal and the second current collecting terminal are evenly contacted or pressed against the current collecting foil connecting portion from both sides at the time of welding, the current collecting foil connecting portion may be curved. The first current collector terminal and the second current collector terminal can be stably and easily welded to the current collector foil connection portion without bending.

上記の構成において、上記溶接部は、上記凸部のうちの上記長手方向における両端以外の部分と、上記集電箔接続部と、上記第2延在部のうちの上記集電箔接続部が位置する側の上記端部とを溶接するように設けられていてもよい。 In the above configuration, the welded portion includes a portion of the convex portion other than both ends in the longitudinal direction, the current collector foil connecting portion, and the current collecting foil connecting portion of the second extending portion. It may be provided so as to weld the end portion on the side to be located.

上記の構成に関して、溶接の過程では、溶接対象である集電箔接続部などが固体から液体へと変化し再び固体へと戻るという状態遷移が行なわれるため、集電箔接続部が挿入される部分である上記の隙間の幅も溶接の過程で変化することとなる。上記の構成によれば、隙間の幅の変化量を小さくすることができ、溶接後の溶接部の状態におよぶ影響を小さくすることが可能となる。また溶接箇所の近くに存在するセパレータは熱に弱いところ、溶接部の溶接長を短くすることによってセパレータにおよぶ熱影響を小さくすることも可能となる。 Regarding the above configuration, in the welding process, a state transition is performed in which the current collector foil connection portion to be welded changes from a solid to a liquid and then returns to a solid state, so that the current collector foil connection portion is inserted. The width of the above-mentioned gap, which is a portion, also changes during the welding process. According to the above configuration, the amount of change in the width of the gap can be reduced, and the influence on the state of the welded portion after welding can be reduced. Further, since the separator existing near the welded portion is vulnerable to heat, it is possible to reduce the influence of heat on the separator by shortening the welding length of the welded portion.

本開示によれば、集電端子を電極体に容易に組み付けることができ、かつ集電端子を電極体に容易にかつ安定して接合することが可能な構成を備えた二次電池およびその製造方法を得ることができる。 According to the present disclosure, a secondary battery and its manufacture having a configuration in which a current collecting terminal can be easily assembled to an electrode body and the current collecting terminal can be easily and stably bonded to the electrode body. You can get the method.

実施の形態1における二次電池100を示す断面図である。It is sectional drawing which shows the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100に備えられる電極体30、第1集電端子10および第2集電端子20を示す斜視図である。It is a perspective view which shows the electrode body 30, the 1st current collecting terminal 10 and the 2nd current collecting terminal 20 provided in the secondary battery 100 in Embodiment 1. FIG. 図2中の矢印III線に沿って第1集電端子10および第2集電端子20などを見た際の様子を示す図(側面図)である。It is a figure (side view) which shows the state when the 1st current collector terminal 10 and the 2nd current collector terminal 20 are seen along the arrow III line in FIG. 図2中の矢印IV線に沿って第1集電端子10および第2集電端子20などを見た際の様子を示す図(平面図)である。It is a figure (plan view) which shows the state when the 1st current collecting terminal 10 and the 2nd current collecting terminal 20 and the like are seen along the arrow IV line in FIG. 図2中のV−V線に沿った矢視断面図である。It is a cross-sectional view taken along the line VV in FIG. 実施の形態1における二次電池100に備えられる第1集電端子10および第2集電端子20などの分解した様子を示す斜視図である。It is a perspective view which shows the disassembled state of the 1st current collecting terminal 10 and the 2nd current collecting terminal 20 provided in the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100の製造方法の準備工程を説明するための図である。It is a figure for demonstrating the preparation process of the manufacturing method of the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100の製造方法の配置工程(第1段階)を説明するための図である。It is a figure for demonstrating the arrangement process (first stage) of the manufacturing method of the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100の製造方法の配置工程(第2段階)を説明するための図である。It is a figure for demonstrating the arrangement process (second stage) of the manufacturing method of the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100の製造方法の配置工程(第3段階)を説明するための図である。It is a figure for demonstrating the arrangement process (third stage) of the manufacturing method of the secondary battery 100 in Embodiment 1. FIG. 実施の形態1における二次電池100の製造方法の溶接工程を説明するための図である。It is a figure for demonstrating the welding process of the manufacturing method of the secondary battery 100 in Embodiment 1. FIG. 比較例における二次電池およびその製造方法に用いられる集電端子50などを示す斜視図である。It is a perspective view which shows the secondary battery in the comparative example, the current collector terminal 50 used in the manufacturing method thereof, and the like. 比較例における二次電池の製造方法の配置工程を説明するための図である。It is a figure for demonstrating the arrangement process of the manufacturing method of the secondary battery in the comparative example. 比較例における二次電池の製造方法の溶接工程を説明するための図である。It is a figure for demonstrating the welding process of the manufacturing method of the secondary battery in the comparative example. 比較例に基づく比較例1,2と、実施の形態1に基づく実施例とに関する実験およびその結果を説明するための図である。It is a figure for demonstrating the experiment and the result about the comparative example 1 and 2 based on the comparative example, and the example based on Embodiment 1. FIG. 実施の形態2における二次電池の製造方法を説明するための断面図である。It is sectional drawing for demonstrating the manufacturing method of the secondary battery in Embodiment 2. FIG. 実施の形態3における二次電池およびその製造方法に用いられる第1集電端子10および第2集電端子20Aを示す斜視図である。It is a perspective view which shows the 1st current collector terminal 10 and the 2nd current collector terminal 20A used for the secondary battery in Embodiment 3 and the manufacturing method thereof. 実施の形態3における二次電池およびその製造方法に用いられる第1集電端子10および第2集電端子20Aを示す断面図である。It is sectional drawing which shows the 1st current collector terminal 10 and the 2nd current collector terminal 20A used for the secondary battery in Embodiment 3 and the manufacturing method thereof. 実施の形態4における二次電池およびその製造方法に用いられる第1集電端子10Bおよび第2集電端子20Bを示す斜視図である。It is a perspective view which shows the 1st current collector terminal 10B and the 2nd current collector terminal 20B used for the secondary battery in Embodiment 4 and the manufacturing method thereof. 実施の形態4における二次電池およびその製造方法に用いられる第1集電端子10Bおよび第2集電端子20Bを示す断面図である。It is sectional drawing which shows the 1st current collector terminal 10B and the 2nd current collector terminal 20B used for the secondary battery in Embodiment 4 and the manufacturing method thereof.

実施の形態について、以下、図面を参照しながら説明する。同一の部品および相当部品には同一の参照番号を付し、重複する説明は繰り返さない場合がある。 The embodiment will be described below with reference to the drawings. The same parts and equivalent parts may be given the same reference number and duplicate explanations may not be repeated.

[実施の形態1]
(二次電池100)
図1は、実施の形態1における二次電池100を示す断面図である。二次電池100は、非水電解質二次電池であり、たとえばリチウムイオン電池として利用できる。二次電池100は、たとえば車両を駆動するために利用され、ガソリンエンジンやディーゼルエンジン等の内燃機関と、充放電可能なバッテリから電力供給されるモータとを動力源とするハイブリッド自動車や、外部充電が可能なプラグインハイブリッド自動車、および電気自動車などに搭載される。
[Embodiment 1]
(Secondary battery 100)
FIG. 1 is a cross-sectional view showing the secondary battery 100 according to the first embodiment. The secondary battery 100 is a non-aqueous electrolyte secondary battery, and can be used as, for example, a lithium ion battery. The secondary battery 100 is used for driving a vehicle, for example, and is used for a hybrid vehicle powered by an internal combustion engine such as a gasoline engine or a diesel engine and a motor powered by a rechargeable battery, or an external charge. It will be installed in plug-in hybrid vehicles and electric vehicles that can be used.

二次電池100は、電極体30、ケース体40、正極用外部端子37P、負極用外部端子37N、正極用集電端子10P,20P、負極用集電端子10N,20Nを備える。以下、正極用外部端子37Pおよび負極用外部端子37Nを特に区別しない場合(換言すると、これらに共通する構成について説明する場合、以下同じ)には単に「外部端子37」と表現し、正極用集電端子10Pおよび負極用集電端子10Nを特に区別しない場合には単に「第1集電端子10」と表現し、正極用集電端子20Pおよび負極用集電端子20Nを特に区別しない場合には単に「第2集電端子20」と表現する。 The secondary battery 100 includes an electrode body 30, a case body 40, a positive electrode external terminal 37P, a negative electrode external terminal 37N, a positive electrode current collecting terminal 10P, 20P, and a negative electrode current collecting terminal 10N, 20N. Hereinafter, when the positive electrode external terminal 37P and the negative electrode external terminal 37N are not particularly distinguished (in other words, when the configuration common to these is described, the same applies hereinafter), it is simply expressed as "external terminal 37" and is a collection for the positive electrode. When the current collecting terminal 10P and the negative electrode current collecting terminal 10N are not particularly distinguished, they are simply expressed as "first current collecting terminal 10", and when the positive electrode current collecting terminal 20P and the negative electrode current collecting terminal 20N are not particularly distinguished, they are simply expressed. It is simply expressed as "second current collecting terminal 20".

(ケース体40)
ケース体40は、本体部41と蓋部42とを含み、二次電池100の外観を構成する。本体部41および蓋部42は、アルミニウム等の金属から形成される。本体部41は、有底角筒形状を有し、蓋部42は、本体部41の開口部を塞ぐように設けられる。蓋部42には、外部端子37(正極用外部端子37Pおよび負極用外部端子37N)が取り付けられる。
(Case body 40)
The case body 40 includes a main body portion 41 and a lid portion 42, and constitutes the appearance of the secondary battery 100. The main body 41 and the lid 42 are made of a metal such as aluminum. The main body 41 has a bottomed square tube shape, and the lid 42 is provided so as to close the opening of the main body 41. External terminals 37 (external positive electrode terminal 37P and external negative electrode terminal 37N) are attached to the lid portion 42.

(電極体30)
図2は、二次電池100に備えられる電極体30、第1集電端子10および第2集電端子20を示す斜視図である。図3は、図2中の矢印III線に沿って第1集電端子10および第2集電端子20などを見た際の様子を示す図(側面図)であり、図4は、図2中の矢印IV線に沿って第1集電端子10および第2集電端子20などを見た際の様子を示す図(平面図)であり、図5は、図2中のV−V線に沿った矢視断面図である。図6は、第1集電端子10および第2集電端子20などの分解した様子を示す斜視図である。
(Electrode body 30)
FIG. 2 is a perspective view showing an electrode body 30, a first current collecting terminal 10, and a second current collecting terminal 20 provided in the secondary battery 100. FIG. 3 is a view (side view) showing a state when the first current collector terminal 10 and the second current collector terminal 20 are viewed along the arrow III line in FIG. 2, and FIG. 4 is a view (side view). FIG. 5 is a view (plan view) showing a state when the first current collector terminal 10 and the second current collector terminal 20 are viewed along the arrow IV line in the middle, and FIG. 5 is a VV line in FIG. It is a cross-sectional view taken along the arrow. FIG. 6 is a perspective view showing a disassembled state of the first current collector terminal 10 and the second current collector terminal 20.

図2〜図6を参照して、電極体30は、ケース体40の中に収容される(図1も参照)。電極体30は、複数の正極用集電箔31Pと、複数のセパレータ31Sと、複数の負極用集電箔31Nとの積層体から構成される。電極体30は、これらの巻回体から構成されていてもよい。正極用集電箔31Pは、たとえばアルミニウム箔から形成され、正極用集電箔31Pの両面には正極活物質を含有するペーストが塗布される。負極用集電箔31Nは、たとえば銅箔から形成され、負極用集電箔31Nの両面には負極活物質を含有するペーストが塗布される。 With reference to FIGS. 2 to 6, the electrode body 30 is housed in the case body 40 (see also FIG. 1). The electrode body 30 is composed of a laminate of a plurality of positive electrode current collecting foils 31P, a plurality of separators 31S, and a plurality of negative electrode current collecting foils 31N. The electrode body 30 may be composed of these wound bodies. The positive electrode current collector foil 31P is formed of, for example, an aluminum foil, and a paste containing a positive electrode active material is applied to both surfaces of the positive electrode current collector foil 31P. The negative electrode current collector foil 31N is formed of, for example, a copper foil, and a paste containing a negative electrode active material is applied to both surfaces of the negative electrode current collector foil 31N.

セパレータ31Sは、略矩形形状を有し、多孔質のポリプロピレン樹脂シート等から構成される。正極用集電箔31Pのうちの正極活物質が塗布された領域と、負極用集電箔31Nのうちの負極活物質が塗布された領域とが、セパレータ31Sを介して向かい合う。正極用集電箔31Pのうちの正極活物質が塗布されていない領域は、セパレータ31Sのうちの長手方向における一方の端部から露出し、負極用集電箔31Nのうちの負極活物質が塗布されていない領域は、セパレータ31Sのうちの長手方向における他方の端部から露出する。 The separator 31S has a substantially rectangular shape and is made of a porous polypropylene resin sheet or the like. The region of the positive electrode current collector foil 31P coated with the positive electrode active material and the region of the negative electrode current collector foil 31N coated with the negative electrode active material face each other via the separator 31S. The region of the positive electrode current collecting foil 31P to which the positive electrode active material is not applied is exposed from one end of the separator 31S in the longitudinal direction, and the negative electrode active material of the negative electrode current collecting foil 31N is applied. The unexposed region is exposed from the other end of the separator 31S in the longitudinal direction.

電極体30は、複数の正極用集電箔31Pと、複数のセパレータ31Sと、複数の負極用集電箔31Nとが、上記のように積層されることにより構成される。このように構成された電極体30は(図1参照)、その構成部位として、電極本体部31と、正極用集電箔延出部32Pおよび負極用集電箔延出部32Nとを有する。以下、正極用集電箔延出部32Pおよび負極用集電箔延出部32Nを特に区別しない場合には単に「集電箔延出部32」と表現する。 The electrode body 30 is formed by laminating a plurality of positive electrode current collecting foils 31P, a plurality of separators 31S, and a plurality of negative electrode current collecting foils 31N as described above. The electrode body 30 configured in this way (see FIG. 1) has an electrode main body portion 31, a positive electrode current collecting foil extending portion 32P, and a negative electrode current collecting foil extending portion 32N as its constituent parts. Hereinafter, when the positive electrode current collecting foil extending portion 32P and the negative electrode current collecting foil extending portion 32N are not particularly distinguished, they are simply referred to as “current collecting foil extending portion 32”.

電極本体部31は、正極用集電箔31Pおよび負極用集電箔31Nが、セパレータ31Sを介して積層されている部位である。正極用集電箔延出部32Pは、正極用集電箔31Pが電極本体部31から一方の側に延出している部位であり、負極用集電箔延出部32Nは、負極用集電箔31Nが電極本体部31から他方の側に延出している部位である(図1)。正極用集電箔延出部32Pと負極用集電箔延出部32Nとは、電極本体部31に対してその両外側に延出している。正極用集電箔延出部32Pと負極用集電箔延出部32Nとは、電極本体部31に対してその一方側の(片方の)外側にのみ延出するように構成されていてもよい。 The electrode main body 31 is a portion where the positive electrode current collecting foil 31P and the negative electrode current collecting foil 31N are laminated via the separator 31S. The positive electrode current collecting foil extending portion 32P is a portion where the positive electrode current collecting foil 31P extends from the electrode main body 31 to one side, and the negative electrode current collecting foil extending portion 32N is a negative electrode current collecting foil extending portion 32N. This is a portion where the foil 31N extends from the electrode body 31 to the other side (FIG. 1). The positive electrode current collecting foil extending portion 32P and the negative electrode current collecting foil extending portion 32N extend to both outer sides of the electrode main body portion 31. Even if the positive electrode current collecting foil extending portion 32P and the negative electrode current collecting foil extending portion 32N are configured to extend only to the outside (one side) of the electrode main body 31. Good.

正極用集電箔延出部32Pにおいては、複数枚の正極用集電箔31Pが電極体30の厚み方向に積層されている。正極用集電箔延出部32Pを構成している複数枚の正極用集電箔31Pが収束するように寄せ集められることによって、正極用集電箔延出部32Pの外側先端には、正極用集電箔接続部33Pが形成されている。 In the positive electrode current collecting foil extending portion 32P, a plurality of positive electrode current collecting foils 31P are laminated in the thickness direction of the electrode body 30. By gathering the plurality of positive electrode current collecting foils 31P constituting the positive electrode current collecting foil extending portion 32P so as to converge, a positive electrode is attached to the outer tip of the positive electrode current collecting foil extending portion 32P. A current collector foil connecting portion 33P is formed.

負極用集電箔延出部32Nにおいては、複数枚の負極用集電箔31Nが電極体30の厚み方向に積層されている。負極用集電箔延出部32Nを構成している複数枚の負極用集電箔31Nが収束するように寄せ集められることによって、負極用集電箔延出部32Nの外側先端には、負極用集電箔接続部33Nが形成されている。以下、正極用集電箔接続部33Pおよび負極用集電箔接続部33Nを特に区別しない場合には単に「集電箔接続部33」と表現する(図2〜図6参照)。 In the negative electrode current collecting foil extending portion 32N, a plurality of negative electrode current collecting foils 31N are laminated in the thickness direction of the electrode body 30. A plurality of negative electrode current collector foils 31N constituting the negative electrode current collector foil extension portion 32N are gathered together so as to converge, so that the negative electrode is attached to the outer tip of the negative electrode current collector foil extension portion 32N. A current collector foil connecting portion 33N is formed. Hereinafter, when the positive electrode current collecting foil connecting portion 33P and the negative electrode current collecting foil connecting portion 33N are not particularly distinguished, they are simply referred to as “current collecting foil connecting portion 33” (see FIGS. 2 to 6).

(第1集電端子10および第2集電端子20)
図6に示すように、外部端子37は、ケース体40(図1)の外部に配置され、絶縁体36を介して蓋部42の外表面(上面)上に重ね合わされる。第1集電端子10および第2集電端子20は、ケース体40(図1)の中に配置され、電極体30と外部端子37とを電気的に接続する。
(1st current collector terminal 10 and 2nd current collector terminal 20)
As shown in FIG. 6, the external terminal 37 is arranged outside the case body 40 (FIG. 1) and is superposed on the outer surface (upper surface) of the lid portion 42 via the insulator 36. The first current collecting terminal 10 and the second current collecting terminal 20 are arranged in the case body 40 (FIG. 1), and electrically connect the electrode body 30 and the external terminal 37.

具体的には、正極用集電端子10P,20Pは、正極用外部端子37P(図1)と、正極用集電箔延出部32P(正極用集電箔接続部33P)とを電気的に接続する。正極用集電端子10P,20Pは、正極用集電箔31Pを形成する金属と同じ種類の金属(たとえばアルミニウム、純アルミニウムやアルミニウム合金)から形成される。 Specifically, the positive electrode current collecting terminals 10P and 20P electrically connect the positive electrode external terminal 37P (FIG. 1) and the positive electrode current collecting foil extending portion 32P (positive electrode current collecting foil connecting portion 33P). Connecting. The positive electrode current collecting terminals 10P and 20P are formed of the same type of metal (for example, aluminum, pure aluminum, or aluminum alloy) as the metal forming the positive electrode current collecting foil 31P.

負極用集電端子10N,20Nは、負極用外部端子37N(図1)と、負極用集電箔延出部32N(負極用集電箔接続部33N)とを電気的に接続する。負極用集電端子10N,20Nは、負極用集電箔31Nを形成する金属と同じ種類の金属(たとえば銅、純銅、銅合金)から形成される。 The negative electrode current collecting terminals 10N and 20N electrically connect the negative electrode external terminal 37N (FIG. 1) and the negative electrode current collecting foil extending portion 32N (negative electrode current collecting foil connecting portion 33N). The negative electrode current collector terminals 10N and 20N are formed of the same type of metal (for example, copper, pure copper, copper alloy) as the metal forming the negative electrode current collector foil 31N.

第1集電端子10は、絶縁体35を介して蓋部42の内表面(下面)上に重ね合わされる。導電性のピン部材34を介して外部端子37に電気的に接続される。なお、第1集電端子10とピン部材34とは、一体成型されていてもよい。第1集電端子10は、その構成部位として、基部16と、延在部11〜14とを有する。基部16は、平板状に形成された部分を有し、絶縁体35を介して蓋部42の内表面上に重ね合わされる。 The first current collecting terminal 10 is superposed on the inner surface (lower surface) of the lid portion 42 via the insulator 35. It is electrically connected to the external terminal 37 via the conductive pin member 34. The first current collecting terminal 10 and the pin member 34 may be integrally molded. The first current collecting terminal 10 has a base portion 16 and extending portions 11 to 14 as constituent portions thereof. The base portion 16 has a portion formed in a flat plate shape, and is superposed on the inner surface of the lid portion 42 via an insulator 35.

延在部11〜14は、基部16より遠ざかる方向に延在する。延在部11〜14の各々は、集電箔接続部33の長手方向に沿って平行に延びる形状を有し、延在部11〜14の間にはスリットS1(図8)が形成される。延在部11〜14は、スリットS1(間隙)を隔てて相互に隣り合うように形成され、スリットS1(間隙)を内側から外側に向けて通過するように配置された集電箔接続部33に溶接される(図5)。 The extending portions 11 to 14 extend in a direction away from the base portion 16. Each of the extending portions 11 to 14 has a shape extending in parallel along the longitudinal direction of the current collecting foil connecting portion 33, and a slit S1 (FIG. 8) is formed between the extending portions 11 to 14. .. The extending portions 11 to 14 are formed so as to be adjacent to each other across the slit S1 (gap), and are arranged so as to pass through the slit S1 (gap) from the inside to the outside. Is welded to (Fig. 5).

延在部11〜14の各々は、集電箔接続部33の長手方向に沿って延びる平板部17と、平板部17のうちの集電箔接続部33が配置される側の端部19(図5,図8)から外側に向けて突出する形状を有する凸部18とを有する(図3,図4)。凸部18の外側表面18S(溶接部38が形成されていない領域)は、平坦な平面形状を有している(図8参照)。集電箔接続部33が延在部11〜14に溶接される前の状態においては、平板部17のうちの端部19側に位置する端面と、凸部18の端部19側に位置する端面とは、一つの平面を形成するように滑らかに連続しており、集電箔接続部33の延出方向(図5紙面内の上下方向)に対して平行である(図8参照)。 Each of the extending portions 11 to 14 has a flat plate portion 17 extending along the longitudinal direction of the current collecting foil connecting portion 33 and an end portion 19 of the flat plate portion 17 on the side where the current collecting foil connecting portion 33 is arranged ( It has a convex portion 18 having a shape protruding outward from FIGS. 5 and 8) (FIGS. 3 and 4). The outer surface 18S of the convex portion 18 (the region where the welded portion 38 is not formed) has a flat planar shape (see FIG. 8). In the state before the current collector foil connecting portion 33 is welded to the extending portions 11 to 14, the end face located on the end portion 19 side of the flat plate portion 17 and the end surface located on the end portion 19 side of the convex portion 18 are located. The end face is smoothly continuous so as to form one plane, and is parallel to the extending direction (vertical direction in the paper surface of FIG. 5) of the current collecting foil connecting portion 33 (see FIG. 8).

第2集電端子20は、第1集電端子10と互いに別部材であり、第2集電端子20は、その構成部位として、基部26と、延在部21〜24とを有する。基部26は、平板状に形成された部分を有し、基部16の上面上に重ね合わされる。延在部21〜24は、基部26より遠ざかる方向に延在する。延在部21〜24の各々は、集電箔接続部33の長手方向に沿って延びる形状を有し、延在部21〜24の外側表面28(溶接部38が形成されていない領域)は、平坦な平面形状を有している(図8参照)。 The second current collecting terminal 20 is a separate member from the first current collecting terminal 10, and the second current collecting terminal 20 has a base portion 26 and extending portions 21 to 24 as constituent portions thereof. The base portion 26 has a portion formed in a flat plate shape and is superposed on the upper surface of the base portion 16. The extending portions 21 to 24 extend in a direction away from the base 26. Each of the extending portions 21 to 24 has a shape extending along the longitudinal direction of the current collecting foil connecting portion 33, and the outer surface 28 (the region where the welded portion 38 is not formed) of the extending portions 21 to 24 is formed. , Has a flat planar shape (see FIG. 8).

延在部21〜24の間にはスリットS2(図8)が形成される。延在部21〜24は、スリットS2(間隙)を隔てて相互に隣り合うように形成され、スリットS2(間隙)を内側から外側に向けて通過するように配置された集電箔接続部33に溶接されている(図5)。集電箔接続部33が延在部21〜24に溶接される前の状態においては、延在部21〜24の各々のうちの集電箔接続部33が位置する側の端部29は、集電箔接続部33の延出方向(図5紙面内の上下方向)に対して平行である(図8参照)。 A slit S2 (FIG. 8) is formed between the extending portions 21 to 24. The extending portions 21 to 24 are formed so as to be adjacent to each other across the slit S2 (gap), and are arranged so as to pass through the slit S2 (gap) from the inside to the outside. It is welded to (Fig. 5). In the state before the current collector foil connecting portion 33 is welded to the extending portions 21 to 24, the end portion 29 of each of the extending portions 21 to 24 on the side where the current collecting foil connecting portion 33 is located is. It is parallel to the extending direction (vertical direction in the paper surface of FIG. 5) of the current collecting foil connecting portion 33 (see FIG. 8).

ここで、第1集電端子10の延在部11(第1延在部)と、第2集電端子20の延在部21(第2延在部)とは、1つの集電箔接続部33を挟んで(1つの集電箔接続部33に対して)互いに反対側に位置する(図5)。延在部11および延在部21の双方がこれらの間に位置する集電箔接続部33に溶接されることで、延在部11と、延在部21と、これらの間に位置する集電箔接続部33とを一体化する溶接部38が形成されている。第1集電端子10と第2集電端子20とは、溶接部38を介して一体化されている。 Here, the extending portion 11 (first extending portion) of the first current collecting terminal 10 and the extending portion 21 (second extending portion) of the second current collecting terminal 20 are connected by one current collecting foil. The portions 33 are located on opposite sides of each other (with respect to one current collector foil connecting portion 33) (FIG. 5). By welding both the extending portion 11 and the extending portion 21 to the current collecting foil connecting portion 33 located between them, the extending portion 11 and the extending portion 21 and the collecting located between them are welded to each other. A welded portion 38 that integrates the electric foil connecting portion 33 is formed. The first current collecting terminal 10 and the second current collecting terminal 20 are integrated via a welded portion 38.

本実施の形態においては、第1集電端子10が、延在部11と延在部12とを含んでおり、第2集電端子20の延在部21(第2延在部)は、延在部12の平板部17の外側表面に重なり合うように配置されている。溶接部38は、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29と、延在部11に設けられた凸部18と、これらの間に位置する集電箔接続部33とを一体化している。 In the present embodiment, the first collector terminal 10 includes a an extending portion 1 1 and the extending portion 1 2, extending portion 21 of the second collector terminal 20 (second extending portion) Is arranged so as to overlap the outer surface of the flat plate portion 17 of the extending portion 12. Weld 38, the end portion 29 of the side where the collector foils connecting portion 33 is located out of the extending portion 21 (second extending portion), a convex portion 18 provided on the extending portion 1 1, these The current collector foil connecting portion 33 located between the two is integrated.

図5に示すように、延在部12,22およびこれらの間に位置する集電箔接続部33の関係、延在部13,23およびこれらの間に位置する集電箔接続部33の関係、ならびに、延在部14,24およびこれらの間に位置する集電箔接続部33の関係は、上記の延在部11,21およびこれらの間に位置する集電箔接続部33の関係と同様である。本実施の形態においては、第1集電端子10と第2集電端子20とは、互いに別部材として構成されたものであるところ、4つの溶接部38を介して互いに一体化されている。 As shown in FIG. 5, the relationship between the extending portions 12 and 22 and the current collecting foil connecting portion 33 located between them, and the relationship between the extending portions 13 and 23 and the collecting foil connecting portion 33 located between them. , And the relationship between the extending portions 14, 24 and the current collecting foil connecting portion 33 located between them is the relationship between the extending portions 11 and 21 and the collecting foil connecting portion 33 located between them. The same is true. In the present embodiment, the first current collecting terminal 10 and the second current collecting terminal 20 are configured as separate members from each other, and are integrated with each other via four welded portions 38.

(製造方法)
図7〜図11を参照して以下、二次電池100の製造方法について説明する。図7を参照して、電極体30がまず準備される。具体的には、複数の正極用集電箔31Pと、複数のセパレータ31Sと、複数の負極用集電箔31Nとを積層する。これにより、正極用集電箔31Pおよび負極用集電箔31Nがセパレータ31Sを介して積層されてなる電極本体部31と、正極用集電箔31Pおよび負極用集電箔31Nがそれぞれ電極本体部31に対してその両外側に延出してなる集電箔延出部32(正極用集電箔延出部32Pおよび負極用集電箔延出部32N)とを含む、積層体(電極体30の前躯体)が得られる。積層体においては、正極用集電箔31Pおよび負極用集電箔31Nの双方がそれぞれ電極本体部31に対してその片方の外側に延出してなる集電箔延出部32(正極用集電箔延出部32Pおよび負極用集電箔延出部32N)を含んでいてもよい。
(Production method)
A method for manufacturing the secondary battery 100 will be described below with reference to FIGS. 7 to 11. With reference to FIG. 7, the electrode body 30 is first prepared. Specifically, a plurality of positive electrode current collecting foils 31P, a plurality of separators 31S, and a plurality of negative electrode current collecting foils 31N are laminated. As a result, the electrode main body 31 in which the positive electrode current collecting foil 31P and the negative electrode current collecting foil 31N are laminated via the separator 31S, and the positive electrode current collecting foil 31P and the negative electrode current collecting foil 31N are respectively electrode main body portions. A laminated body (electrode body 30) including a current collecting foil extending portion 32 extending to both outer sides of 31 (a positive electrode collecting foil extending portion 32P and a negative electrode collecting foil extending portion 32N). Forehead) is obtained. In the laminated body, both the positive electrode current collecting foil 31P and the negative electrode current collecting foil 31N extend to the outside of one of the electrode main body 31, respectively (current collecting foil extending portion 32 for the positive electrode (current collecting for the positive electrode)). The foil extending portion 32P and the current collecting foil extending portion 32N for the negative electrode) may be included.

その後、傾斜面を有する治具60により、集電箔延出部32を構成している複数枚の集電箔(正極用集電箔31Pおよび負極用集電箔31N)が収束するように寄せ集められる。集電箔延出部32を構成している複数枚の集電箔によって、集電箔延出部32の外側先端に幅W1(図8)を有する集電箔接続部33(正極用集電箔接続部33Pおよび負極用集電箔接続部33N)が形成される。以上のようにして、電極本体部31、集電箔延出部32および集電箔接続部33を含む、電極体30が準備される。 After that, a jig 60 having an inclined surface brings together a plurality of current collector foils (current collector foil 31P for positive electrode and current collector foil 31N for negative electrode) constituting the current collector foil extending portion 32 so as to converge. Collected. A current collector foil connecting portion 33 (current collector for a positive electrode) having a width W1 (FIG. 8) at the outer tip of the current collector foil extending portion 32 by a plurality of current collecting foils constituting the current collecting foil extending portion 32. The foil connecting portion 33P and the current collecting foil connecting portion 33N for the negative electrode are formed. As described above, the electrode body 30 including the electrode main body portion 31, the current collecting foil extending portion 32, and the current collecting foil connecting portion 33 is prepared.

図8を参照して、次に、第1集電端子10および第2集電端子20が準備される。上述のとおり、第1集電端子10は、間隙(スリットS1)を隔てて相互に隣り合うように形成された延在部11〜14を含み、延在部11〜14は集電箔接続部33の長手方向に沿って延びる形状を有している。延在部11〜14の各々は、集電箔接続部33の長手方向に沿って延びる平板部17と、平板部17のうちの集電箔接続部33が配置される側の端部19(図5,図8)から外側に向けて突出する形状を有する凸部18とを有する(図3,図4)。延在部11は第1の第1延在部に相当し、延在部12は第2の第1延在部に相当している。 With reference to FIG. 8, next, the first current collecting terminal 10 and the second current collecting terminal 20 are prepared. As described above, the first current collecting terminal 10 includes extending portions 11 to 14 formed so as to be adjacent to each other with a gap (slit S1) interposed therebetween, and the extending portions 11 to 14 are current collecting foil connecting portions. It has a shape extending along the longitudinal direction of 33. Each of the extending portions 11 to 14 has a flat plate portion 17 extending along the longitudinal direction of the current collecting foil connecting portion 33 and an end portion 19 of the flat plate portion 17 on the side where the current collecting foil connecting portion 33 is arranged ( It has a convex portion 18 having a shape protruding outward from FIGS. 5 and 8) (FIGS. 3 and 4). The extending portion 11 corresponds to the first first extending portion, and the extending portion 12 corresponds to the second first extending portion.

第2集電端子20は、間隙(スリットS2)を隔てて相互に隣り合うように形成された延在部21〜24を含み、延在部21〜24も集電箔接続部33の長手方向に沿って延びる形状を有している。延在部21は第2延在部に相当し、第2集電端子20は上述のとおり、第1集電端子10とは互いに別部材である。このような構成を備えた第1集電端子10は、レーザー加工やプレス加工などで金属板材に所定幅を有するスリット(スリットS1,S2)を3本形成した後、基部16に相当する部分をL字状に金属板材を折り曲げることで、容易に作製することが可能である。 The second current collecting terminal 20 includes extending portions 21 to 24 formed so as to be adjacent to each other across a gap (slit S2), and the extending portions 21 to 24 are also in the longitudinal direction of the current collecting foil connecting portion 33. It has a shape that extends along. The extending portion 21 corresponds to the second extending portion, and the second current collecting terminal 20 is a separate member from the first current collecting terminal 10 as described above. In the first current collecting terminal 10 having such a configuration, after forming three slits (slits S1 and S2) having a predetermined width in the metal plate material by laser processing or press processing, a portion corresponding to the base portion 16 is formed. It can be easily manufactured by bending the metal plate material into an L shape.

(配置工程)
その後、第1集電端子10の外側に、第2集電端子20が重ね合わされる。この際、延在部12〜14の各々の凸部18は、第2集電端子20に設けられたスリットS2の中に挿入される。延在部11(第1の第1延在部)の凸部18と延在部12(第2の第1延在部)の凸部18との間に、第2集電端子20の延在部21(第2延在部)が配置される。第2集電端子20の延在部21(第2延在部)は、延在部12(第2の第1延在部)の平板部17の外側表面に重なり合うように配置される。第2集電端子20の延在部21〜23を、それぞれ、第1集電端子10の延在部12〜14の外側表面に重なり合うように配置することで、延在部21〜24と延在部11〜14の各々の凸部18との間にスリットが形成される。
(Placement process)
After that, the second current collector terminal 20 is superposed on the outside of the first current collector terminal 10. At this time, each of the convex portions 18 of the extending portions 12 to 14 is inserted into the slit S2 provided in the second current collecting terminal 20. A second current collecting terminal 20 extends between the convex portion 18 of the extending portion 11 (first extending portion) and the convex portion 18 of the extending portion 12 (second first extending portion). The existing portion 21 (second extending portion) is arranged. The extending portion 21 (second extending portion) of the second current collecting terminal 20 is arranged so as to overlap the outer surface of the flat plate portion 17 of the extending portion 12 (second first extending portion). By arranging the extending portions 21 to 23 of the second current collecting terminal 20 so as to overlap the outer surfaces of the extending portions 12 to 14 of the first current collecting terminal 10, they extend to the extending portions 21 to 24, respectively. A slit is formed between each of the convex portions 18 of the existing portions 11 to 14.

図9を参照して、本実施の形態においては、第1集電端子10と第2集電端子20とが上記のように相互に重なり合うように配置された状態で、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29と、延在部11(第1の第1延在部)に設けられた凸部18とは、各々の外側表面18S,28が略面一となる関係を有している。延在部12〜14および延在部22〜24についても同様である。 With reference to FIG. 9, in the present embodiment, the extending portion 21 (the second) is in a state where the first current collecting terminal 10 and the second current collecting terminal 20 are arranged so as to overlap each other as described above. The end 29 on the side where the current collecting foil connecting portion 33 is located and the convex portion 18 provided on the extending portion 11 (first extending portion) of the two extending portions) are respectively. The outer surfaces 18S and 28 have a substantially flush relationship. The same applies to the extending portions 12 to 14 and the extending portions 22 to 24.

図9および図10に示すように、上記スリット(延在部11〜14の間の間隙(スリットS1)および延在部21〜24の間の間隙(スリットS2))を集電箔接続部33が内側から外側に向けて通過するように、第1集電端子10および第2集電端子20が配置される。以上のような配置工程が完了することで、たとえば延在部11(第1延在部)と延在部21(第2延在部)とが1つの集電箔接続部33に対して互いに反対側に位置するように、第1集電端子10および第2集電端子20が配置される(図10に示す状態が得られる)。延在部12〜14および延在部22〜24についても同様である。 As shown in FIGS. 9 and 10, the slit (the gap between the extending portions 11 to 14 (slit S1) and the gap between the extending portions 21 to 24 (slit S2)) is formed in the current collecting foil connecting portion 33. The first current collecting terminal 10 and the second current collecting terminal 20 are arranged so that the first current collector terminal 10 and the second current collector terminal 20 pass from the inside to the outside. By completing the arrangement process as described above, for example, the extending portion 11 (first extending portion) and the extending portion 21 (second extending portion) are connected to each other with respect to one current collecting foil connecting portion 33. The first current collecting terminal 10 and the second current collecting terminal 20 are arranged so as to be located on opposite sides (the state shown in FIG. 10 can be obtained). The same applies to the extending portions 12 to 14 and the extending portions 22 to 24.

その後、延在部11(第1延在部)と延在部21(第2延在部)とが相互に近づくように第1集電端子10と第2集電端子20とが相対移動(ここではスライド移動)される。延在部12〜14および延在部22〜24についても同様である。幅W2(図9)が集電箔接続部33の長手方向において均等に小さくなることにより、延在部11〜14および延在部21〜24のすべてが、これらの間に位置する集電箔接続部33に均等に接触することができる。 After that, the first current collecting terminal 10 and the second current collecting terminal 20 move relative to each other so that the extending portion 11 (first extending portion) and the extending portion 21 (second extending portion) approach each other. Here, the slide is moved). The same applies to the extending portions 12 to 14 and the extending portions 22 to 24. By reducing the width W2 (FIG. 9) evenly in the longitudinal direction of the current collecting foil connecting portion 33, all of the extending portions 11 to 14 and the extending portions 21 to 24 are located between them. The connection portion 33 can be evenly contacted.

(溶接工程)
図11を参照して、延在部11〜14の各々の凸部18と、延在部21〜24の各々のうちの集電箔接続部33が位置する側の端部29とが、これらの間に位置する集電箔接続部33に接触している状態で、レーザーLを用いたレーザー溶接が実施される。この際、凸部18と端部29との間の隙間を一定(あるいは一定値以下)とするために、上記隙間が小さくなるように第1集電端子10と第2集電端子20とを加圧した状態でレーザー溶接を実施する。
(Welding process)
With reference to FIG. 11, each of the convex portions 18 of the extending portions 11 to 14 and the end portion 29 of each of the extending portions 21 to 24 on the side where the current collecting foil connecting portion 33 is located are these. Laser welding using the laser L is performed in a state of being in contact with the current collecting foil connecting portion 33 located between the two. At this time, in order to make the gap between the convex portion 18 and the end portion 29 constant (or a constant value or less), the first current collecting terminal 10 and the second current collecting terminal 20 are arranged so that the gap becomes small. Laser welding is performed under pressure.

レーザー溶接が実施される際、凸部18の外側表面18Sと延在部21〜24の各々の外側表面28とは、略面一となる関係を有している。延在部11〜14の各々と、延在部21〜24の各々と、これらの間に位置する集電箔接続部33とを一体化する溶接部38(図5)が形成される。第1集電端子10と第2集電端子20とは、溶接部38(本実施の形態においては4つの溶接部38)を介して一体化される。 When laser welding is performed, the outer surface 18S of the convex portion 18 and the outer surface 28 of each of the extending portions 21 to 24 have a substantially flush relationship. Welded portions 38 (FIG. 5) are formed that integrate each of the extending portions 11 to 14, each of the extending portions 21 to 24, and the current collecting foil connecting portion 33 located between them. The first current collecting terminal 10 and the second current collecting terminal 20 are integrated via welded portions 38 (four welded portions 38 in the present embodiment).

本実施の形態においては(図3参照)、溶接部38は、延在部11(第1の第1延在部)の凸部18のうちの長手方向における両端18A,18B以外の部分18Hと、集電箔接続部33と、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29(図5)とを溶接するように設けられている。延在部12〜14および延在部22〜24についても同様である。 In the present embodiment (see FIG. 3), the welded portion 38 is formed with a portion 18H other than both ends 18A and 18B in the longitudinal direction of the convex portion 18 of the extending portion 11 (first extending portion). , The current collecting foil connecting portion 33 and the end portion 29 (FIG. 5) of the extending portion 21 (second extending portion) on the side where the current collecting foil connecting portion 33 is located are provided so as to be welded. There is. The same applies to the extending portions 12 to 14 and the extending portions 22 to 24.

電極体30と一体化された第1集電端子10に、図6中に示すピン部材34、絶縁体35、蓋部42、絶縁体36および外部端子37を組み付ける。外部端子37および蓋部42(図1)と一体となった電極体30を、ケース体40(図1)の本体部41の中に収容し、蓋部42を本体部41に溶接する。蓋部42に設けられた注液孔を通じてケース体41内に電解液を注入し、そのあと注液孔を塞ぐ。以上の工程により、図1中の二次電池100が完成する。 The pin member 34, the insulator 35, the lid 42, the insulator 36, and the external terminal 37 shown in FIG. 6 are assembled to the first current collecting terminal 10 integrated with the electrode body 30. The electrode body 30 integrated with the external terminal 37 and the lid portion 42 (FIG. 1) is housed in the main body portion 41 of the case body 40 (FIG. 1), and the lid portion 42 is welded to the main body portion 41. The electrolytic solution is injected into the case body 41 through the liquid injection hole provided in the lid portion 42, and then the liquid injection hole is closed. Through the above steps, the secondary battery 100 in FIG. 1 is completed.

(作用および効果)
以下、実施の形態1の作用および効果について、図12〜図14に示される比較例と対比しながら説明する。
(Action and effect)
Hereinafter, the actions and effects of the first embodiment will be described in comparison with the comparative examples shown in FIGS. 12 to 14.

図12に示す比較例の場合においては、集電端子50が基部56および複数の延在部51〜55を有しており、隣り合う2つの延在部の間にスリットS3(図13)が形成される。図13に示すように、集電箔接続部33をスリットS3に挿入するに際して、スリットS3の幅W3が狭いと、集電箔接続部33をスリットS3に挿入しにくく、結果として集電端子50を電極体30に組み付けることが困難となる。 In the case of the comparative example shown in FIG. 12, the current collecting terminal 50 has a base 56 and a plurality of extending portions 51 to 55, and a slit S3 (FIG. 13) is provided between two adjacent extending portions. It is formed. As shown in FIG. 13, when the current collecting foil connecting portion 33 is inserted into the slit S3, if the width W3 of the slit S3 is narrow, it is difficult to insert the current collecting foil connecting portion 33 into the slit S3, and as a result, the current collecting terminal 50 Is difficult to assemble to the electrode body 30.

図14を参照して一方で、集電箔接続部33を集電端子50の延在部51〜55にレーザー溶接にて接合するに際して、スリットS3の幅が広いと、すなわち隣り合う2つの延在部間の間隔が広いと、集電箔接続部33と集電端子50の延在部51〜55とを相互に接合することが困難となる。この場合には、溶接用のレーザーLがそのスリットS3を通過して集電端子の内側に位置する集電箔やセパレータに到達し(いわゆるレーザー抜け)、結果として適切な溶接を行なうことが困難となる可能性もある。 On the other hand, when the current collector foil connecting portion 33 is joined to the extending portions 51 to 55 of the current collecting terminal 50 by laser welding, the width of the slit S3 is wide, that is, two adjacent portions. If the distance between the existing portions is wide, it becomes difficult to join the current collecting foil connecting portion 33 and the extending portions 51 to 55 of the current collecting terminal 50 to each other. In this case, the laser L for welding passes through the slit S3 and reaches the current collecting foil or separator located inside the current collecting terminal (so-called laser removal), and as a result, it is difficult to perform proper welding. There is also the possibility of becoming.

これに対して本実施の形態における二次電池100によれば、上記のスリットに対応する部位が、互いに別部材である第1集電端子10と第2集電端子20とによって構成されている。当該構成を備えた二次電池100によれば、複数枚の集電箔の端部(集電箔接続部33)を束ねた状態でスリットに挿入するに際して、スリット幅が可動範囲の中で最大限広くなるように第1集電端子10および第2集電端子20を配置した状態で、集電箔接続部33をスリットに挿入することができ、第1集電端子10および第2集電端子20を電極体30に容易に組み付けることが可能となる。 On the other hand, according to the secondary battery 100 in the present embodiment, the portion corresponding to the slit is composed of the first current collecting terminal 10 and the second current collecting terminal 20 which are separate members from each other. .. According to the secondary battery 100 having this configuration, when the ends of a plurality of current collector foils (current collector foil connection portions 33) are inserted into the slit in a bundled state, the slit width is the maximum in the movable range. With the first current collector terminal 10 and the second current collector terminal 20 arranged so as to be as wide as possible, the current collector foil connection portion 33 can be inserted into the slit, and the first current collector terminal 10 and the second current collector can be inserted. The terminal 20 can be easily assembled to the electrode body 30.

複数枚の集電箔の端部(集電箔接続部33)を束ねた状態で第1集電端子10および第2集電端子20にレーザー溶接にて接合するに際しては、スリット幅が狭くなるように第1集電端子10および第2集電端子20を配置することができるため(たとえば第1集電端子10および/または第2集電端子20がスライド移動させることが可能であるため)、集電箔接続部33と延在部11〜14,21〜24とを相互に容易に接触させることができる。集電箔接続部33と延在部11〜14,21〜24とが接触していることによって、溶接用のレーザーがスリットを通過して第1集電端子10や第2集電端子20の内側に位置する電極体30(集電箔)に到達するという、いわゆるレーザー抜けが発生することもなく、適切な溶接を行なうことができる。 When joining the ends of a plurality of current collector foils (current collector foil connection portions 33) to the first current collector terminal 10 and the second current collector terminal 20 by laser welding, the slit width becomes narrower. Since the first current collecting terminal 10 and the second current collecting terminal 20 can be arranged as described above (for example, because the first current collecting terminal 10 and / or the second current collecting terminal 20 can be slidably moved). , The current collecting foil connecting portion 33 and the extending portions 11-14, 21-24 can be easily brought into contact with each other. When the current collecting foil connecting portion 33 and the extending portions 11 to 14, 21 to 24 are in contact with each other, the laser for welding passes through the slit of the first current collecting terminal 10 and the second current collecting terminal 20. Appropriate welding can be performed without causing so-called laser omission that reaches the electrode body 30 (current collector foil) located inside.

本実施の形態においては、第2集電端子20の延在部21〜23が、それぞれ、第1集電端子10の延在部12〜14の外側表面に重なり合うように配置される。溶接部38が、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29と、延在部11(第1の第1延在部)に設けられた凸部18と、これらの間に位置する集電箔接続部33とを一体化する。延在部12〜14および延在部22〜24についても同様である。 In the present embodiment, the extending portions 21 to 23 of the second current collecting terminal 20 are arranged so as to overlap the outer surfaces of the extending portions 12 to 14 of the first current collecting terminal 10, respectively. The welded portion 38 is attached to the end portion 29 of the extending portion 21 (second extending portion) on the side where the current collecting foil connecting portion 33 is located and the extending portion 11 (first extending portion). The provided convex portion 18 and the current collecting foil connecting portion 33 located between them are integrated. The same applies to the extending portions 12 to 14 and the extending portions 22 to 24.

上記構成に関連して、延在部11〜14の間のスリットS1の幅を実施の形態1の場合よりも広くして、スリットS1の中に第2集電端子20の延在部21〜24を配置することもできる。この場合、延在部11〜14と延在部21〜24とが同一平面上において、電極体30の厚み方向(図1紙面に対して垂直な方向)に交互に並ぶこととなる。この場合であっても、第1集電端子10と第2集電端子20との相対移動によって延在部11〜14,21〜24間に形成されるスリットの幅を増減させることが可能であり、上述と略同様の作用および効果を得ることができる。 In relation to the above configuration, the width of the slit S1 between the extending portions 11 to 14 is made wider than that in the case of the first embodiment, and the extending portion 21 to the second current collecting terminal 20 in the slit S1. 24 can also be arranged. In this case, the extending portions 11 to 14 and the extending portions 21 to 24 are alternately arranged in the thickness direction of the electrode body 30 (the direction perpendicular to the paper surface in FIG. 1) on the same plane. Even in this case, the width of the slit formed between the extending portions 11 to 14, 21 to 24 can be increased or decreased by the relative movement between the first current collecting terminal 10 and the second current collecting terminal 20. Yes, it is possible to obtain substantially the same actions and effects as described above.

一方で上述の実施の形態1においては、第2集電端子20の延在部21〜23が、それぞれ、第1集電端子10の延在部12〜14の外側表面に重なり合うように配置される。当該構成は必須ではないが、当該構成を採用する場合、延在部11〜14と延在部21〜24とが同一平面上において交互に並ぶように構成する場合に比べて、延在部11〜14の間に形成されるスリットの幅を狭くすることができ、結果として、第1集電端子10や第2集電端子20の全体としての幅を小さくすることができ、二次電池100の小型化を図ることが可能となる。また溶接部38が、延在部21〜24の各々の端部29と、延在部11〜14の各々に設けられた凸部18と、これらの間に位置する集電箔接続部33とを一体化するため、必要十分な溶接を実施することが可能である。 On the other hand, in the above-described first embodiment, the extending portions 21 to 23 of the second current collecting terminal 20 are arranged so as to overlap the outer surfaces of the extending portions 12 to 14 of the first current collecting terminal 10, respectively. To. The configuration is not essential, but when the configuration is adopted, the extending portions 11 are compared with the case where the extending portions 11 to 14 and the extending portions 21 to 24 are alternately arranged on the same plane. The width of the slit formed between ~ 14 can be narrowed, and as a result, the width of the first current collecting terminal 10 and the second current collecting terminal 20 as a whole can be reduced, and the secondary battery 100 It is possible to reduce the size of the battery. Further, the welded portion 38 includes an end portion 29 of each of the extending portions 21 to 24, a convex portion 18 provided on each of the extending portions 11 to 14, and a current collecting foil connecting portion 33 located between them. It is possible to carry out necessary and sufficient welding in order to integrate the above.

上述のとおり、実施の形態1においては、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29と、延在部11(第1の第1延在部)に設けられた凸部18とは、各々の外側表面18S,28が略面一となる関係を有している。延在部12〜14および延在部22〜24についても同様である。当該構成は必須ではないが、当該構成によれば、延在部21〜24の各々の端部29と、延在部11〜14の各々に設けられた凸部18とが、溶接時において集電箔接続部33に対して両側から均等に接触ないし圧接されるため、集電箔接続部33が湾曲したり屈曲したりすることがなく、端部29と凸部18とを集電箔接続部33に対して安定して容易に溶接することが可能となる。 As described above, in the first embodiment, the end portion 29 of the extending portion 21 (second extending portion) on the side where the current collecting foil connecting portion 33 is located and the extending portion 11 (first first extending portion) are located. The convex portions 18 provided on the 1 extending portion) have a relationship in which the outer surfaces 18S and 28 are substantially flush with each other. The same applies to the extending portions 12 to 14 and the extending portions 22 to 24. The configuration is not essential, but according to the configuration, the respective end portions 29 of the extending portions 21 to 24 and the convex portions 18 provided on each of the extending portions 11 to 14 are collected at the time of welding. Since the current collector foil connection portion 33 is evenly contacted or pressure-welded from both sides to the current collector foil connection portion 33, the current collector foil connection portion 33 does not bend or bend, and the end portion 29 and the convex portion 18 are connected by the current collector foil. It is possible to stably and easily weld to the portion 33.

上述のとおり、本実施の形態においては(図3参照)、溶接部38は、延在部11(第1の第1延在部)の凸部18のうちの長手方向における両端18A,18B以外の部分18Hと、集電箔接続部33と、延在部21(第2延在部)のうちの集電箔接続部33が位置する側の端部29(図5)とを溶接するように設けられている。延在部12〜14および延在部22〜24についても同様である。 As described above, in the present embodiment (see FIG. 3), the welded portion 38 includes both ends 18A and 18B in the longitudinal direction of the convex portion 18 of the extending portion 11 (first extending portion). 18H, the current collecting foil connecting portion 33, and the end portion 29 (FIG. 5) of the extending portion 21 (second extending portion) on the side where the current collecting foil connecting portion 33 is located are welded. It is provided in. The same applies to the extending portions 12 to 14 and the extending portions 22 to 24.

上記構成に関して、延在部11〜14と、延在部21〜24と、これらの間の集電箔接続部33とを安定して溶接させるためには、延在部11〜14(実施の形態1においては凸部18)と延在部21〜24(端部29)との間の隙間を一定(あるいは一定値以下)にして、上記隙間が小さくなるように第1集電端子10と第2集電端子20とを加圧した状態でレーザー溶接を実施する。溶接の過程では、溶接対象である集電箔接続部33などが固体から液体へと変化し再び固体へと戻るという状態遷移が行なわれるため、上記の隙間の幅も溶接の過程で変化することとなる。 Regarding the above configuration, in order to stably weld the extending portions 11 to 14, the extending portions 21 to 24, and the current collecting foil connecting portion 33 between them, the extending portions 11 to 14 (implemented). In the first embodiment, the gap between the convex portion 18) and the extending portions 21 to 24 (end portion 29) is made constant (or a constant value or less), and the first current collecting terminal 10 and the first current collecting terminal 10 are arranged so that the gap becomes small. Laser welding is performed with the second current collector terminal 20 pressurized. In the welding process, the state transition is performed in which the current collecting foil connection portion 33, which is the object of welding, changes from solid to liquid and then returns to solid, so the width of the above gap also changes during the welding process. It becomes.

ここで、凸部18と端部29とによって集電箔接続部33が挟持されている領域の全て溶接しようとすると、溶融する溶接対象の体積もその分大きくなり、隙間の幅の変化量も大きくなる。隙間の幅が溶接の過程で大きくなり再び小さくなるというように変化することは、溶接後の溶接部38の状態にも影響がおよぶため、隙間の幅の変化量はできるだけ小さい方が好ましい。 Here, if an attempt is made to weld the entire region where the current collecting foil connecting portion 33 is sandwiched between the convex portion 18 and the end portion 29, the volume of the welded object to be melted increases by that amount, and the amount of change in the width of the gap also increases. growing. The change in the width of the gap so that it increases and decreases again in the process of welding affects the state of the welded portion 38 after welding, so it is preferable that the amount of change in the width of the gap is as small as possible.

したがって本実施の形態においては、溶接部38が、延在部11〜14の各々の凸部18のうちの長手方向における両端18A,18B以外の部分18Hと、集電箔接続部33と、延在部21〜24の各々の端部29(図5)とを溶接するように設けられていることによって、良好で安定した溶接部38を形成することが可能となっている。溶接箇所の近くに存在するセパレータ31Sは熱に弱いが、溶接部38の溶接長を短くすることによって、セパレータ31Sにおよぶ熱影響を小さくすることも可能となる。二次電池100の仕様などに応じて、電気的な接続に必要な溶接部38の溶接長を決定することができる。溶接部38の溶接長はしたがって、二次電池100の仕様などに鑑みつつ、両端18A,18B以外の部分18Hを含む必要十分な値(たとえば10mm)に設定されることが好ましい。 Therefore, in the present embodiment, the welded portion 38 extends from each of the convex portions 18 of the extending portions 11 to 14 to the portions 18H other than the both ends 18A and 18B in the longitudinal direction, and the current collecting foil connecting portion 33. By providing the existing portions 21 to 24 so as to be welded to each end portion 29 (FIG. 5), it is possible to form a good and stable welded portion 38. The separator 31S existing near the welded portion is vulnerable to heat, but by shortening the welding length of the welded portion 38, it is possible to reduce the heat effect on the separator 31S. The welding length of the welded portion 38 required for electrical connection can be determined according to the specifications of the secondary battery 100 and the like. Therefore, the welding length of the welded portion 38 is preferably set to a necessary and sufficient value (for example, 10 mm) including the portions 18H other than both ends 18A and 18B in consideration of the specifications of the secondary battery 100 and the like.

[実験例]
図15を参照して、上述の比較例に基づく比較例1〜3と、上述の実施の形態1に基づく実施例とに関する実験およびその結果について説明する。
[Experimental example]
With reference to FIG. 15, experiments and results relating to Comparative Examples 1 to 3 based on the above-mentioned Comparative Examples and Examples based on the above-mentioned Embodiment 1 will be described.

比較例1〜3および実施例に共通する条件として、正極用集電箔31P(アルミニウム合金箔)の厚みは15μmに設定し、負極用集電箔31N(銅箔)の厚みは10μmに設定した。集電箔接続部33の幅W1(図8)は0.5mmとした。正極側の正極用集電端子10P、正極用集電端子20Pおよび集電端子50については、アルミ製とし、厚みは0.8mmとした。負極側の負極用集電端子10N、負極用集電端子20Nおよび集電端子50については銅製とし、厚みは0.8mmとした。 As conditions common to Comparative Examples 1 to 3 and Examples, the thickness of the positive electrode current collector foil 31P (aluminum alloy foil) was set to 15 μm, and the thickness of the negative electrode current collector foil 31N (copper foil) was set to 10 μm. .. The width W1 (FIG. 8) of the current collector foil connecting portion 33 was set to 0.5 mm. The positive electrode current collecting terminal 10P, the positive electrode current collecting terminal 20P, and the current collecting terminal 50 on the positive electrode side were made of aluminum and had a thickness of 0.8 mm. The negative electrode current collecting terminal 10N, the negative electrode current collecting terminal 20N, and the current collecting terminal 50 on the negative electrode side were made of copper and had a thickness of 0.8 mm.

正極側の溶接条件としては、出力2000W、速度20mm/SECのファイバーレーザーを利用し、走査距離は10mmとした。負極側の溶接条件としては、出力3000W、速度30mm/SECのファイバーレーザーを利用し、走査距離は10mmとした。その他については、図15に示される条件に基づき、比較例1〜3および実施例の各々について二次電池のサンプルを10個作製した。評価1として、集電箔接続部33のスリットに挿入された状態を外観観察し、評価2として、分解した溶接箇所(溶接部38)を外観観察した。 As the welding conditions on the positive electrode side, a fiber laser having an output of 2000 W and a speed of 20 mm / SEC was used, and the scanning distance was set to 10 mm. As the welding conditions on the negative electrode side, a fiber laser having an output of 3000 W and a speed of 30 mm / SEC was used, and the scanning distance was set to 10 mm. For the others, 10 secondary battery samples were prepared for each of Comparative Examples 1 to 3 and Examples based on the conditions shown in FIG. As evaluation 1, the state of being inserted into the slit of the current collecting foil connecting portion 33 was visually observed, and as evaluation 2, the disassembled welded portion (welded portion 38) was visually observed.

(比較例1)
比較例1においては、スリットS3(図13)の幅W3が0.6mmとなるように設定した。評価1に関しては、集電箔接続部33をスリットS3に挿入する際に、2つのサンプルについてはスリットS3を構成している延在部51〜55に集電箔接続部33が衝突し、集電箔接続部33の破損(箔のちぎれ)が生じていることを確認したため、評価1については8/10という結果が得られた。評価2に関しては、集電箔接続部33と延在部51〜55との間の隙間において、レーザー抜けが発生していることは確認されず、評価2については8/8という結果が得られた。これらの結果により、比較例1は、集電箔接続部33に破損が生じる可能性があると言える。
(Comparative Example 1)
In Comparative Example 1, the width W3 of the slit S3 (FIG. 13) was set to be 0.6 mm. Regarding evaluation 1, when the current collecting foil connecting portion 33 is inserted into the slit S3, the current collecting foil connecting portion 33 collides with the extending portions 51 to 55 constituting the slit S3 for the two samples, and the current collecting foil connecting portion 33 collects. Since it was confirmed that the electric foil connecting portion 33 was damaged (the foil was torn), the result of evaluation 1 was 8/10. Regarding evaluation 2, it was not confirmed that laser omission occurred in the gap between the current collector foil connecting portion 33 and the extending portions 51 to 55, and the result of evaluation 2 was 8/8. It was. From these results, it can be said that in Comparative Example 1, the current collecting foil connecting portion 33 may be damaged.

(比較例2)
比較例2においては、スリットS3(図13)の幅W3が0.9mmとなるように設定した。評価1に関しては、集電箔接続部33をスリットS3に挿入する際に、延在部51〜55に集電箔接続部33が衝突することはなく、集電箔接続部33の破損(箔のちぎれ)が生じているものを確認しなかったため、評価1については10/10という結果が得られた。評価2に関しては、集電箔接続部33と延在部51〜55との間の隙間において、レーザー抜けが発生していることを4つのサンプルにおいて確認したため、評価2については6/10という結果が得られた。比較例2はスリットS3の幅W3が比較例1の場合に比べて広いため集電箔接続部33の挿入は容易であるが、延在部51〜55で集電箔接続部33を挟む際にレーザー抜けが高い頻度で発生したものと推察される。
(Comparative Example 2)
In Comparative Example 2, the width W3 of the slit S3 (FIG. 13) was set to be 0.9 mm. Regarding evaluation 1, when the current collecting foil connecting portion 33 was inserted into the slit S3, the current collecting foil connecting portion 33 did not collide with the extending portions 51 to 55, and the current collecting foil connecting portion 33 was damaged (foil). Since we did not confirm the occurrence of tearing), the result of evaluation 1 was 10/10. Regarding evaluation 2, it was confirmed in four samples that laser omission occurred in the gap between the current collector foil connecting portion 33 and the extending portions 51 to 55, so the result of evaluation 2 was 6/10. was gotten. In Comparative Example 2, since the width W3 of the slit S3 is wider than that in Comparative Example 1, the current collecting foil connecting portion 33 can be easily inserted, but when the current collecting foil connecting portion 33 is sandwiched between the extending portions 51 to 55. It is presumed that laser omission occurred frequently.

(実施例)
実施例においては、比較例1,2の場合とは異なり、集電端子として機能する部品が、互いに別部材である第1集電端子10と第2集電端子20との2部品から構成される。結果として、評価1,2の双方において10/10という良好な結果が得られた。したがって実施の形態1に基づく構成によれば、集電端子を電極体に容易に組み付けることができ、かつ集電端子を電極体に容易に接合することが可能な構成を備えた二次電池およびその製造方法とすることが可能であると言える。
(Example)
In the embodiment, unlike the cases of Comparative Examples 1 and 2, the component functioning as the current collecting terminal is composed of two components, the first current collecting terminal 10 and the second current collecting terminal 20, which are separate members from each other. To. As a result, a good result of 10/10 was obtained in both evaluations 1 and 2. Therefore, according to the configuration based on the first embodiment, the secondary battery and the secondary battery having a configuration in which the current collecting terminal can be easily assembled to the electrode body and the current collecting terminal can be easily joined to the electrode body. It can be said that the manufacturing method can be used.

[実施の形態2]
図16を参照して、実施の形態2における二次電池の製造方法について説明する。上述の実施の形態1における配置工程においては(図8〜図10)、第1集電端子10の外側に第2集電端子20が重ね合わされ、その後、第1集電端子10と第2集電端子20との間に形成されているスリットの内側に集電箔接続部33が挿通される。
[Embodiment 2]
The method for manufacturing the secondary battery according to the second embodiment will be described with reference to FIG. In the arrangement step according to the first embodiment (FIGS. 8 to 10), the second current collector terminal 20 is superposed on the outside of the first current collector terminal 10, and then the first current collector terminal 10 and the second current collector terminal 10 and the second current collector terminal 20 The current collector foil connecting portion 33 is inserted inside the slit formed between the current terminal 20 and the current collector terminal 20.

図16に示すように、配置工程としては、集電箔接続部33を第1集電端子10のスリットS1に挿通した後に、第1集電端子10に第2集電端子20を重ね合わせてもよい。当該構成によっても、上述の実施の形態1と同様の作用および効果を得ることができる。 As shown in FIG. 16, in the arrangement step, after the current collecting foil connecting portion 33 is inserted into the slit S1 of the first current collecting terminal 10, the second current collecting terminal 20 is superposed on the first current collecting terminal 10. May be good. With this configuration, the same actions and effects as those in the first embodiment can be obtained.

[実施の形態3]
図17および図18を参照して、実施の形態3における二次電池およびその製造方法について説明する。上述の実施の形態1においては、第2集電端子20が基部26(図6)を備え、延在部21〜24がL字状の基部26から延在するように形成されている。本実施の形態の第2集電端子20Aは、平板状の基部27と、基部27から垂れ下がるように形成された延在部21〜24とを備えている。
[Embodiment 3]
The secondary battery and the method for manufacturing the secondary battery according to the third embodiment will be described with reference to FIGS. 17 and 18. In the first embodiment described above, the second current collecting terminal 20 is provided with a base portion 26 (FIG. 6), and the extending portions 21 to 24 are formed so as to extend from the L-shaped base portion 26. The second current collecting terminal 20A of the present embodiment includes a flat plate-shaped base portion 27 and extending portions 21 to 24 formed so as to hang down from the base portion 27.

実施の形態1の場合では、基部26を利用して第2集電端子20の第1集電端子10に対する位置決めを容易に行なうことが可能であるところ、本実施の形態のような第2集電端子20Aの構成であっても、溶接時に第2集電端子20Aを支持ないし位置決めする部材を適宜設けるなどすることによって容易に溶接を実施することが可能であり、上述の実施の形態1と同様の作用および効果を得ることができる。 In the case of the first embodiment, it is possible to easily position the second current collector terminal 20 with respect to the first current collector terminal 10 by using the base 26, but the second current collector as in the present embodiment. Even with the configuration of the electric terminal 20A, welding can be easily performed by appropriately providing a member for supporting or positioning the second current collecting terminal 20A at the time of welding. Similar actions and effects can be obtained.

[実施の形態4]
図19および図20を参照して、実施の形態4における二次電池およびその製造方法について説明する。本実施の形態においては、第1集電端子10Bの延在部11〜13を構成している平板部17が、長手方向における途中部分において湾曲しており、延在部11〜13の上端に比べて下端の方が内側に寄った構成を有している。
[Embodiment 4]
The secondary battery and the method for manufacturing the secondary battery according to the fourth embodiment will be described with reference to FIGS. 19 and 20. In the present embodiment, the flat plate portions 17 constituting the extending portions 11 to 13 of the first current collecting terminal 10B are curved in the middle portion in the longitudinal direction, and are formed at the upper ends of the extending portions 11 to 13. Compared to this, the lower end has a structure closer to the inside.

第2集電端子20Bの延在部21〜23についても同様に、延在部21〜23が、長手方向における途中部分において湾曲しており、延在部21〜23の下端(基部27側の部分)に比べて上端の方が内側に寄った構成を有している。溶接箇所が集電箔接続部33の内側に潜り込むように配置されている場合であっても、上述の実施の形態1と同様の作用および効果を得ることができる。 Similarly, regarding the extending portions 21 to 23 of the second current collecting terminal 20B, the extending portions 21 to 23 are curved in the middle portion in the longitudinal direction, and the lower end of the extending portions 21 to 23 (on the base 27 side). It has a structure in which the upper end is closer to the inside than the part). Even when the welded portion is arranged so as to sneak inside the current collector foil connecting portion 33, the same operation and effect as in the first embodiment can be obtained.

以上、実施の形態について説明したが、上記の開示内容はすべての点で例示であって制限的なものではない。本開示の技術的範囲は特許請求の範囲によって示され、特許請求の範囲と均等の意味および範囲内でのすべての変更が含まれることが意図される。 Although the embodiments have been described above, the above disclosure contents are examples in all respects and are not restrictive. The technical scope of the present disclosure is indicated by the scope of claims, and is intended to include all modifications within the meaning and scope equivalent to the scope of claims.

10,10B 第1集電端子、10N,10P,20N,20P,50 集電端子、11,12,13,14,21,22,23,24,51,55 延在部、16,26,27,56 基部、17 平板部、18 凸部、18A,18B 両端、18H 部分、18S,28 外側表面、19,29 端部、20,20A,20B 第2集電端子、30 電極体、31 電極本体部、31N 負極用集電箔、31P 正極用集電箔、31S セパレータ、32 集電箔延出部、32P 正極用集電箔延出部、32N 負極用集電箔延出部、33 集電箔接続部、33N 負極用集電箔接続部、33P 正極用集電箔接続部、34 ピン部材、35,36 絶縁体、37 外部端子、37N 負極用外部端子、37P 正極用外部端子、38 溶接部、40 ケース体、41 本体部、42 蓋部、60 治具、100 二次電池、L レーザー、S1,S2,S3 スリット、W1,W2,W3 幅。 10,10B 1st current collection terminal, 10N, 10P, 20N, 20P, 50 current collection terminal, 11,12,13,14,21,22,23,24,51,55 Extended part, 16,26,27 , 56 base, 17 flat plate, 18 convex, 18A, 18B both ends, 18H part, 18S, 28 outer surface, 19,29 end, 20, 20A, 20B second current collecting terminal, 30 electrode body, 31 electrode body Unit, 31N negative electrode current collector foil, 31P positive electrode current collector foil, 31S separator, 32 current collector foil extension section, 32P positive electrode current collector foil extension section, 32N negative electrode current collector foil extension section, 33 current collector Foil connection part, 33N negative electrode collector foil connection part, 33P positive electrode collector foil connection part, 34 pin member, 35, 36 insulator, 37 external terminal, 37N negative electrode external terminal, 37P positive electrode external terminal, 38 welding Part, 40 case body, 41 main body part, 42 lid part, 60 jigs, 100 secondary batteries, L laser, S1, S2, S3 slits, W1, W2, W3 width.

Claims (8)

正極用および負極用の集電箔がセパレータを介して積層されてなる電極本体部と、正極用および負極用の前記集電箔がそれぞれ前記電極本体部に対してその外側に延出してなる集電箔延出部と、前記集電箔延出部を構成している複数枚の前記集電箔によって前記集電箔延出部の外側先端に形成された集電箔接続部とを含む、電極体と、
前記集電箔接続部の長手方向に沿って延びる形状を有する第1延在部を含み、前記第1延在部が前記集電箔接続部に溶接された第1集電端子と、
前記長手方向に沿って延びる形状を有する第2延在部を含み、前記第2延在部が前記集電箔接続部に溶接された、前記第1集電端子と互いに別部材である第2集電端子と、を備え
記第1集電端子は、第1の間隙を隔てて相互に隣り合うように形成され、前記第1の間隙を内側から外側に向けて通過するように前記集電箔接続部が配置される第1の前記第1延在部と第2の前記第1延在部とを含み、
前記第2集電端子は、第2の間隙を隔てて相互に隣り合うように形成され、前記第2の間隙を内側から外側に向けて通過するように前記集電箔接続部が配置される第1の前記第2延在部と第2の前記第2延在部とを含み、
第1の前記第1延在部と第1の前記第2延在部とが相互に対向し、
第2の前記第1延在部と第2の前記第2延在部とが相互に対向し、
第1の前記第1延在部と第2の前記第2延在部とがこれらの間で前記集電箔接続部を挟んだ状態で、第1の前記第1延在部と第2の前記第2延在部と前記集電箔接続部とが溶接部を介して一体化されており、前記第1集電端子と前記第2集電端子とは前記溶接部を介して一体化されている、
二次電池。
An electrode main body portion in which current collector foils for a positive electrode and a negative electrode are laminated via a separator, and a collection in which the current collector foils for a positive electrode and a negative electrode extend outward from the electrode main body portion, respectively. A current collector foil extending portion and a current collecting foil connecting portion formed at an outer tip of the current collecting foil extending portion by a plurality of the current collecting foils constituting the current collecting foil extending portion are included. With the electrode body,
A first current collecting terminal including a first extending portion having a shape extending along the longitudinal direction of the current collecting foil connecting portion, and the first extending portion being welded to the current collecting foil connecting portion.
A second member that includes a second extending portion having a shape extending along the longitudinal direction, and the second extending portion is welded to the current collecting foil connecting portion, and is a member separate from the first current collecting terminal. Equipped with a current collector terminal
The first collector terminal before Symbol is at a first gap is formed so as to be adjacent to each other, the collector foil connecting portion is arranged to pass outwardly of said first gap from the inside The first extending portion and the second extending portion of the first extending portion are included.
The second current collecting terminal is formed so as to be adjacent to each other across the second gap, and the current collecting foil connecting portion is arranged so as to pass through the second gap from the inside to the outside. Including the first said second extending part and the second said second extending part,
The first extending portion and the first extending portion 2 face each other, and the first extending portion and the first extending portion face each other.
The second first extending portion and the second second extending portion face each other,
In a state where the first extending portion and the second second extending portion sandwich the current collecting foil connecting portion between them, the first extending portion and the second extending portion integrated the second extending portion and the collector foil connecting portion are integrated through a welding unit, wherein the first collector terminal and the second collector terminal via the weld Has been
Secondary battery.
第1の前記第1延在部は、前記長手方向に沿って延びる平板部と、前記平板部のうちの前記集電箔接続部が配置される側の端部から外側に向けて突出する形状を有する凸部とを有し、
第2の前記第2延在部は、第2の前記第1延在部の外側表面に重なり合うように配置され、
前記溶接部は、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の端部と、前記集電箔接続部と、第1の前記第1延在部に設けられた前記凸部とを一体化している、
請求項1に記載の二次電池。
The first extending portion has a shape that projects outward from a flat plate portion extending along the longitudinal direction and an end portion of the flat plate portion on the side where the current collecting foil connecting portion is arranged. Has a convex part and has
The second extending portion is arranged so as to overlap the outer surface of the second extending portion.
The welded portion is formed on the end of the second second extending portion on the side where the current collecting foil connecting portion is located, the current collecting foil connecting portion, and the first first extending portion. It is integrated with the provided convex portion,
The secondary battery according to claim 1.
第2の前記第2延在部のうちの前記集電箔接続部が位置する側の前記端部と、第1の前記第1延在部に設けられた前記凸部とは、各々の外側表面が略面一となる関係を有している、
請求項2に記載の二次電池。
The end of the second extending portion on the side where the current collecting foil connecting portion is located and the convex portion provided on the first extending portion are outside of each. The surface has a substantially flush relationship,
The secondary battery according to claim 2.
前記溶接部は、前記凸部のうちの前記長手方向における両端以外の部分と、前記集電箔接続部と、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の前記端部とを溶接するように設けられている、
請求項2または3に記載の二次電池。
The welded portion is located at a portion of the convex portion other than both ends in the longitudinal direction, the current collecting foil connecting portion, and the current collecting foil connecting portion of the second extending portion. Provided to weld the end on the side,
The secondary battery according to claim 2 or 3.
二次電池の製造方法であって、
正極用および負極用の集電箔がセパレータを介して積層されてなる電極本体部と、正極用および負極用の前記集電箔がそれぞれ前記電極本体部に対してその外側に延出してなる集電箔延出部と、前記集電箔延出部を構成している複数枚の前記集電箔によって前記集電箔延出部の外側先端に形成された集電箔接続部とを含む、電極体を準備する工程と、
第1延在部を含み、前記第1延在部が前記集電箔接続部の長手方向に沿って延びる形状を有する第1集電端子と、第2延在部を含み、前記第2延在部が前記長手方向に沿って延びる形状を有する、前記第1集電端子と互いに別部材である第2集電端子とを準備する工程を備え、
前記第1集電端子は、第1の間隙を隔てて相互に隣り合うように形成された、第1の前記第1延在部と第2の前記第1延在部とを含み、
前記第2集電端子は、第2の間隙を隔てて相互に隣り合うように形成された、第1の前記第2延在部と第2の前記第2延在部とを含み、
前記二次電池の製造方法はさらに、
第1の前記第1延在部と第1の前記第2延在部とが相互に対向し、第2の前記第1延在部と第2の前記第2延在部とが相互に対向し、前記集電箔接続部が前記第1の間隙および前記第2の間隙を内側から外側に向けて通過し、第1の前記第1延在部と第2の前記第2延在部とが前記集電箔接続部に対して互いに反対側に位置するように、前記第1集電端子および前記第2集電端子を配置する配置工程と、
第1の前記第1延在部と第2の前記第2延在部とが相互に近づくように前記第1集電端子と前記第2集電端子とを相対移動させることによって、第1の前記第1延在部および第2の前記第2延在部の双方を前記集電箔接続部に接触させる工程と、
第1の前記第1延在部および第2の前記第2延在部の双方が前記集電箔接続部に接触している状態でレーザー溶接を実施して第1の前記第1延在部、第2の前記第2延在部および前記集電箔接続部を一体化する溶接部を形成することで、前記第1集電端子と前記第2集電端子とを前記溶接部を介して一体化させる溶接工程と、を備える、
二次電池の製造方法。
It is a method of manufacturing secondary batteries.
An electrode main body portion in which current collector foils for a positive electrode and a negative electrode are laminated via a separator, and a collection in which the current collector foils for a positive electrode and a negative electrode extend outward from the electrode main body portion, respectively. A current collector foil extending portion and a current collecting foil connecting portion formed at an outer tip of the current collecting foil extending portion by a plurality of the current collecting foils constituting the current collecting foil extending portion are included. The process of preparing the electrode body and
A first current collecting terminal including a first extending portion and having a shape in which the first extending portion extends along the longitudinal direction of the collecting foil connecting portion, and a second extending portion including the second extending portion. A step of preparing the first current collecting terminal and the second current collecting terminal, which are separate members from each other, having a shape in which the existing portion extends along the longitudinal direction is provided.
The first current collecting terminal includes a first extending portion and a second extending portion formed so as to be adjacent to each other with a first gap.
The second current collecting terminal includes a first second extending portion and a second second extending portion formed so as to be adjacent to each other with a second gap in between.
The method for manufacturing the secondary battery further
The first extending portion and the first second extending portion face each other, and the second first extending portion and the second second extending portion face each other. Then, the current collector foil connecting portion passes through the first gap and the second gap from the inside to the outside, and becomes the first extending portion and the second extending portion. The first current collector terminal and the second current collector terminal are arranged so that the current collector terminals are located on opposite sides of the current collector foil connection portion.
The first by moving the first current collecting terminal and the second current collecting terminal relative to each other so that the first extending portion and the second extending portion come close to each other. A step of bringing both the first extending portion and the second second extending portion into contact with the current collector foil connecting portion, and
Laser welding is performed in a state where both the first extending portion and the second extending portion are in contact with the current collector foil connecting portion, and the first extending portion is formed. By forming a welded portion that integrates the second extending portion and the current collecting foil connecting portion, the first current collecting terminal and the second current collecting terminal are connected to each other via the welded portion. It is equipped with a welding process to integrate.
How to manufacture a secondary battery.
第1の前記第1延在部は、前記長手方向に沿って延びる平板部と、前記平板部のうちの前記集電箔接続部が配置される側の端部から外側に向けて突出する形状を有する凸部とを有し、
前記配置工程は、
第2の前記第2延在部を第2の前記第1延在部の外側表面に重なり合うように配置することで、第2の前記第2延在部と前記凸部との間にスリットを形成する工程と、
前記集電箔接続部が前記スリットを内側から外側に向けて通過するように、前記第1集電端子および前記第2集電端子を配置する工程と、を含み、
前記溶接工程においては、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の端部と第1の前記第1延在部に設けられた前記凸部との双方が前記集電箔接続部に接触している状態で前記レーザー溶接が実施され、前記溶接部の形成によって、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の前記端部と、前記集電箔接続部と、第1の前記第1延在部に設けられた前記凸部とが一体化される、
請求項5に記載の二次電池の製造方法。
The first extending portion has a shape that projects outward from a flat plate portion extending along the longitudinal direction and an end portion of the flat plate portion on the side where the current collecting foil connecting portion is arranged. Has a convex part and has
The placement step is
By arranging the second extending portion so as to overlap the outer surface of the second extending portion, a slit is formed between the second extending portion and the convex portion. The process of forming and
The step of arranging the first current collecting terminal and the second current collecting terminal so that the current collecting foil connecting portion passes through the slit from the inside to the outside is included.
In the welding step, the end portion of the second extending portion on the side where the current collecting foil connecting portion is located and the convex portion provided on the first extending portion. The laser welding is performed in a state where both are in contact with the current collecting foil connecting portion, and the formation of the welded portion positions the current collecting foil connecting portion of the second extending portion. The end portion on the side, the current collecting foil connecting portion, and the convex portion provided on the first extending portion are integrated.
The method for manufacturing a secondary battery according to claim 5.
前記レーザー溶接が実施される際、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の前記端部と、第1の前記第1延在部に設けられた前記凸部とは、各々の外側表面が略面一となる関係を有している、
請求項6に記載の二次電池の製造方法。
When the laser welding is performed, the end portion of the second extending portion on the side where the current collecting foil connecting portion is located and the first extending portion are provided. The convex portions have a relationship in which their outer surfaces are substantially flush with each other.
The method for manufacturing a secondary battery according to claim 6.
前記溶接部は、前記凸部のうちの前記長手方向における両端以外の部分と、前記集電箔接続部と、第2の前記第2延在部のうちの前記集電箔接続部が位置する側の前記端部とを溶接するように設けられる、
請求項6または7に記載の二次電池の製造方法。
The welded portion is located at a portion of the convex portion other than both ends in the longitudinal direction, the current collecting foil connecting portion, and the current collecting foil connecting portion of the second extending portion. Provided to weld the end on the side,
The method for manufacturing a secondary battery according to claim 6 or 7.
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