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JP6900671B2 - Manufacturing method of power storage device - Google Patents
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JP6900671B2 - Manufacturing method of power storage device - Google Patents

Manufacturing method of power storage device Download PDF

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JP6900671B2
JP6900671B2 JP2016254075A JP2016254075A JP6900671B2 JP 6900671 B2 JP6900671 B2 JP 6900671B2 JP 2016254075 A JP2016254075 A JP 2016254075A JP 2016254075 A JP2016254075 A JP 2016254075A JP 6900671 B2 JP6900671 B2 JP 6900671B2
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electrode assembly
protruding
pair
portions
protruding portions
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JP2018107021A (en
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和雄 片山
和雄 片山
啓一 前田
啓一 前田
直紀 田口
直紀 田口
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Description

本発明は、ケースと電極組立体とを絶縁する絶縁シートを備える蓄電装置の製造方法に関する。 The present invention relates to a method for manufacturing a power storage device including an insulating sheet that insulates a case and an electrode assembly.

二次電池やキャパシタのような蓄電装置は再充電が可能であり、繰り返し使用することができるため電源として広く利用されている。二次電池として、矩形シート状の正極及び負極が、間にセパレータが介在する状態でそれぞれ複数積層された積層型の電極組立体を備えたものがある。また、帯状の正極及び帯状の負極が、間に帯状のセパレータが存在する状態で巻回された巻回型の電極組立体を備えたものもある。つまり、電極組立体は、正極と負極との間にセパレータを介在させた層状構造を有する。一般に、電極組立体は、絶縁シートによって覆われ、電極組立体を収容するケースから絶縁される。 Power storage devices such as secondary batteries and capacitors are widely used as power sources because they can be recharged and can be used repeatedly. As a secondary battery, there is a battery provided with a laminated electrode assembly in which a plurality of rectangular sheet-shaped positive electrodes and negative electrodes are laminated with a separator interposed therebetween. In addition, there is also one provided with a wound electrode assembly in which a band-shaped positive electrode and a band-shaped negative electrode are wound with a band-shaped separator in between. That is, the electrode assembly has a layered structure in which a separator is interposed between the positive electrode and the negative electrode. Generally, the electrode assembly is covered with an insulating sheet and insulated from the case containing the electrode assembly.

また、正極、負極、及びセパレータが互いにずれて電極組立体の層状構造が崩れることを抑制するため、例えば、特許文献1に記載の蓄電装置では、電極組立体の複数箇所に保持テープを貼っている。 Further, in order to prevent the positive electrode, the negative electrode, and the separator from being displaced from each other and the layered structure of the electrode assembly from collapsing, for example, in the power storage device described in Patent Document 1, holding tapes are attached to a plurality of places of the electrode assembly. There is.

特開2015−53220号公報Japanese Unexamined Patent Publication No. 2015-53220

しかし、特許文献1に記載の蓄電装置を製造する場合、電極組立体に保持テープを貼り拘束する工程と、絶縁シートによって電極組立体を覆う工程とを必要とし、蓄電装置の生産性が低下するという課題があった。 However, when the power storage device described in Patent Document 1 is manufactured, a step of attaching and restraining a holding tape to the electrode assembly and a step of covering the electrode assembly with an insulating sheet are required, and the productivity of the power storage device is lowered. There was a problem.

本発明は、上記課題を解決するためになされたものであり、その目的は、層状構造を有する電極組立体を備える蓄電装置の生産性を向上させることができる蓄電装置の製造方法を提供することにある。 The present invention has been made to solve the above problems, and an object of the present invention is to provide a method for manufacturing a power storage device capable of improving the productivity of a power storage device including an electrode assembly having a layered structure. It is in.

上記問題点を解決するための蓄電装置の製造方法は、異なる極性の電極同士を絶縁した層状構造を有する電極組立体と、前記電極組立体を収容した金属製のケースと、前記電極組立体を覆い、前記ケースと前記電極組立体とを絶縁する絶縁シートと、を備え、前記絶縁シートは、前記電極組立体における積層方向の両面からはみ出し、かつ積層方向に対向した一対のはみ出し部を有し、前記一対のはみ出し部が接合されている蓄電装置の製造方法であって、前記一対のはみ出し部の少なくとも一方に対して、はみ出し方向に引っ張った状態で接合工程を施し、前記一対のはみ出し部を接合することを要旨とする。 A method for manufacturing a power storage device for solving the above problems is to include an electrode assembly having a layered structure in which electrodes having different polarities are insulated from each other, a metal case accommodating the electrode assembly, and the electrode assembly. An insulating sheet that covers and insulates the case and the electrode assembly is provided, and the insulating sheet has a pair of protruding portions that protrude from both sides of the electrode assembly in the stacking direction and face each other in the stacking direction. A method for manufacturing a power storage device in which the pair of protruding portions are joined, the joining step is performed on at least one of the pair of protruding portions in a state of being pulled in the protruding direction, and the pair of protruding portions are joined. The gist is to join.

これによれば、一対のはみ出し部は、少なくとも一方のはみ出し部に積層方向の張力がかかるように接合される。はみ出し部の張力は、絶縁シートの電極組立体を積層方向に拘束する拘束力となり、この拘束力により電極組立体の層状構造の崩れが抑制される。この場合、電極組立体を拘束する工程と、絶縁シートによって電極組立体を覆う工程とを同時に行うため、層状構造を有する電極組立体を備える蓄電装置の生産性を向上させることができる。 According to this, the pair of protruding portions are joined so that tension in the stacking direction is applied to at least one protruding portion. The tension of the protruding portion becomes a binding force that restrains the electrode assembly of the insulating sheet in the stacking direction, and this binding force suppresses the collapse of the layered structure of the electrode assembly. In this case, since the step of restraining the electrode assembly and the step of covering the electrode assembly with the insulating sheet are performed at the same time, the productivity of the power storage device including the electrode assembly having a layered structure can be improved.

また、蓄電装置の製造方法について、前記一対のはみ出し部をまとめて引っ張るのが好ましい。
これによれば、はみ出し部をそれぞれ引っ張る場合と比較して、はみ出し部を引っ張るための装置の数を減らすことができる。
Further, regarding the method of manufacturing the power storage device, it is preferable to pull the pair of protruding portions together.
According to this, the number of devices for pulling the protruding portions can be reduced as compared with the case where the protruding portions are pulled respectively.

また、蓄電装置の製造方法について、前記電極組立体は、積層型の電極組立体であり、前記一対のはみ出し部を積層方向中央で接合するのが好ましい。
これによれば、はみ出し部の張力を積層方向中央に向けることができるため、絶縁シートの電極組立体に対する積層方向の拘束力のバランスを良好にできる。
Further, regarding the method of manufacturing the power storage device, the electrode assembly is a laminated electrode assembly, and it is preferable that the pair of protruding portions are joined at the center in the stacking direction.
According to this, since the tension of the protruding portion can be directed to the center in the stacking direction, the balance of the binding force of the insulating sheet with respect to the electrode assembly in the stacking direction can be improved.

また、蓄電装置の製造方法について、前記電極組立体に対して積層方向の少なくとも一方向から荷重を加えた状態で、前記一対のはみ出し部の少なくとも一方をはみ出し方向に引っ張った状態とするのが好ましい。 Further, as for the manufacturing method of the power storage device, it is preferable that at least one of the pair of protruding portions is pulled in the protruding direction while a load is applied to the electrode assembly from at least one direction in the stacking direction. ..

これによれば、電極組立体には積層方向の復元力(反力)が発生するが、その復元力に対する抗力として絶縁シートにより電極組立体が拘束される。よって、絶縁シートの電極組立体に対する拘束力をより強くできる。 According to this, a restoring force (reaction force) in the stacking direction is generated in the electrode assembly, but the electrode assembly is restrained by the insulating sheet as a drag against the restoring force. Therefore, the binding force of the insulating sheet on the electrode assembly can be made stronger.

また、蓄電装置の製造方法について、前記絶縁シートは、前記電極組立体を挟んだ両側に前記一対のはみ出し部を備え、前記電極組立体の両側の前記一対のはみ出し部をそれぞれはみ出し方向に引っ張った状態で接合するのが好ましい。 Further, regarding the method of manufacturing the power storage device, the insulating sheet is provided with the pair of protruding portions on both sides of the electrode assembly, and the pair of protruding portions on both sides of the electrode assembly are pulled in the protruding directions. It is preferable to join in a state.

これによれば、一方にはみ出す一対のはみ出し部に加えて、他方にはみ出す一対のはみ出し部も引っ張られた状態で接合されるため、絶縁シートの電極組立体に対するはみ出し方向の拘束力のバランスを良好にできる。 According to this, in addition to the pair of protruding portions protruding to one side, the pair of protruding portions protruding to the other side are also joined in a pulled state, so that the balance of the binding force in the protruding direction of the insulating sheet with respect to the electrode assembly is good. Can be done.

また、蓄電装置の製造方法について、前記電極組立体の少なくとも一面を開放するように前記絶縁シートで覆うのが好ましい。
これによれば、例えばタブを有する電極組立体に対応することができる。
Further, regarding the method of manufacturing the power storage device, it is preferable to cover at least one surface of the electrode assembly with the insulating sheet so as to open.
According to this, it is possible to correspond to an electrode assembly having a tab, for example.

本発明によれば、層状構造を有する電極組立体を備える蓄電装置の生産性を向上させることができる。 According to the present invention, it is possible to improve the productivity of a power storage device including an electrode assembly having a layered structure.

実施形態の二次電池の分解斜視図。An exploded perspective view of the secondary battery of the embodiment. 二次電池の外観を示す斜視図。The perspective view which shows the appearance of a secondary battery. 電極組立体の構成要素を示す分解斜視図。An exploded perspective view showing the components of the electrode assembly. (a)〜(d)は二次電池の製造工程を説明するための概略平面図。(A) to (d) are schematic plan views for explaining a manufacturing process of a secondary battery. 別例の二次電池の分解斜視図。An exploded perspective view of another example secondary battery.

以下、蓄電装置を二次電池に具体化した実施形態を図1〜図4にしたがって説明する。
図1及び図2に示すように、蓄電装置としての二次電池10は、ケース11を備える。二次電池10は、ケース11に収容された電極組立体12を備える。ケース11は、直方体状の本体部材13と、本体部材13の開口部13aを閉塞する矩形平板状の蓋部材14とを有する。ケース11を構成する本体部材13と蓋部材14は、何れも金属製(例えば、ステンレスやアルミニウム)である。また、本実施形態の二次電池10は、その外観が角型をなす角型電池である。また、本実施形態の二次電池10は、リチウムイオン電池である。
Hereinafter, embodiments in which the power storage device is embodied in a secondary battery will be described with reference to FIGS. 1 to 4.
As shown in FIGS. 1 and 2, the secondary battery 10 as a power storage device includes a case 11. The secondary battery 10 includes an electrode assembly 12 housed in a case 11. The case 11 has a rectangular parallelepiped main body member 13 and a rectangular flat plate-shaped lid member 14 that closes the opening 13a of the main body member 13. The main body member 13 and the lid member 14 constituting the case 11 are both made of metal (for example, stainless steel or aluminum). Further, the secondary battery 10 of the present embodiment is a square battery having a square appearance. Further, the secondary battery 10 of the present embodiment is a lithium ion battery.

二次電池10は、電極組立体12から電気を取り出すための正極端子15と負極端子16を備える。正極端子15と負極端子16は、蓋部材14に所定の間隔をあけて並設された一対の孔14aからケース11の外部に露出される。また、正極端子15及び負極端子16には、ケース11から絶縁するためのリング状の絶縁リング17aがそれぞれ取り付けられている。 The secondary battery 10 includes a positive electrode terminal 15 and a negative electrode terminal 16 for extracting electricity from the electrode assembly 12. The positive electrode terminal 15 and the negative electrode terminal 16 are exposed to the outside of the case 11 through a pair of holes 14a arranged side by side at a predetermined interval in the lid member 14. Further, a ring-shaped insulating ring 17a for insulating from the case 11 is attached to the positive electrode terminal 15 and the negative electrode terminal 16, respectively.

図3に示すように、電極組立体12は、異なる極性の電極として、シート状の正極電極20と、シート状の負極電極21とを備える。正極電極20は、正極金属箔(本実施形態ではアルミニウム箔)22と、その両面に正極活物質を塗布してなる正極活物質層23を有する。負極電極21は、負極金属箔(本実施形態では銅箔)24と、その両面に負極活物質を塗布してなる負極活物質層25を有する。電極組立体12は、正極電極20と負極電極21の間に微多孔性フィルムのセパレータ26を介在させた層状構造を有する積層体である。電極組立体12は、例えば、複数枚の正極電極20と複数枚の負極電極21を交互に積層して構成される。すなわち、電極組立体12は、正極電極20と、負極電極21と、セパレータ26とから構成された組を複数組有する。 As shown in FIG. 3, the electrode assembly 12 includes a sheet-shaped positive electrode 20 and a sheet-shaped negative electrode 21 as electrodes having different polarities. The positive electrode electrode 20 has a positive electrode metal foil (aluminum foil in this embodiment) 22 and a positive electrode active material layer 23 formed by applying a positive electrode active material on both surfaces thereof. The negative electrode electrode 21 has a negative electrode metal foil (copper foil in this embodiment) 24 and a negative electrode active material layer 25 formed by applying a negative electrode active material on both surfaces thereof. The electrode assembly 12 is a laminated body having a layered structure in which a microporous film separator 26 is interposed between the positive electrode 20 and the negative electrode 21. The electrode assembly 12 is configured by, for example, alternately laminating a plurality of positive electrode electrodes 20 and a plurality of negative electrode electrodes 21. That is, the electrode assembly 12 has a plurality of sets composed of the positive electrode 20, the negative electrode 21, and the separator 26.

図3に示すように、正極電極20は、正極金属箔22からなる正極集電タブ28を縁部(一端)に備える。正極集電タブ28は、電極組立体12を構成する各正極電極20において同位置に同一形状で形成されている。また、負極電極21は、負極金属箔24からなる負極集電タブ30を縁部(一端)に備える。負極集電タブ30は、電極組立体12を構成する各負極電極21において同位置に同一形状で形成されている。 As shown in FIG. 3, the positive electrode electrode 20 includes a positive electrode current collecting tab 28 made of a positive electrode metal foil 22 at an edge (one end). The positive electrode current collecting tab 28 is formed at the same position and in the same shape on each positive electrode 20 constituting the electrode assembly 12. Further, the negative electrode electrode 21 is provided with a negative electrode current collecting tab 30 made of a negative electrode metal foil 24 at an edge (one end). The negative electrode current collecting tab 30 is formed at the same position and in the same shape on each negative electrode 21 constituting the electrode assembly 12.

各正極電極20は、それぞれの正極集電タブ28が電極組立体12の積層方向Xに沿って列状に配置されるように積層される。同様に、各負極電極21は、それぞれの負極集電タブ30が、正極集電タブ28と重ならないように電極組立体12の積層方向Xに沿って列状に配置されるように積層される。そして、各正極集電タブ28は、図1に示すように、電極組立体12における積層方向Xの一端から他端までの範囲に集められて正極集電群31とされる。正極集電群31には、正極端子15が電気的に接合される。また、各負極集電タブ30も同様に、電極組立体12における積層方向Xの一端から他端までの範囲に集められて負極集電群32とされる。負極集電群32には、負極端子16が電気的に接続される。 The positive electrode electrodes 20 are laminated so that the positive electrode current collecting tabs 28 are arranged in a row along the stacking direction X of the electrode assembly 12. Similarly, the negative electrode electrodes 21 are laminated so that the negative electrode current collecting tabs 30 are arranged in a row along the stacking direction X of the electrode assembly 12 so that the negative electrode current collecting tabs 30 do not overlap with the positive electrode current collecting tabs 28. .. Then, as shown in FIG. 1, each positive electrode current collecting tab 28 is collected in a range from one end to the other end of the stacking direction X in the electrode assembly 12 to form a positive electrode current collecting group 31. The positive electrode terminal 15 is electrically joined to the positive electrode current collecting group 31. Similarly, each negative electrode current collecting tab 30 is also collected in the range from one end to the other end of the stacking direction X in the electrode assembly 12 to form a negative electrode current collecting group 32. The negative electrode terminal 16 is electrically connected to the negative electrode current collecting group 32.

本実施形態の電極組立体12は、6面を有する直方体である。電極組立体12の6面は、電極組立体12の積層方向Xの両面である表面12a,12bと、その2面に連設されるとともに電極組立体12の積層方向Xに直交する4つの側面12c,12d,12e,12fとからなる。側面12eは、正極集電タブ28及び負極集電タブ30が突出する集電側側面である。正極集電タブ28及び負極集電タブ30は、1つの側面12eから同一方向に突出されている。また、側面12fは、側面12eと対向する反対面としての底側側面である。また、側面12c,12dは、側面12e,12fにそれぞれ直交する側面であり、電極組立体12の積層方向Xに直交する幅方向Yに対向する面である。 The electrode assembly 12 of the present embodiment is a rectangular parallelepiped having six faces. The six surfaces of the electrode assembly 12 are the surfaces 12a and 12b that are both sides of the electrode assembly 12 in the stacking direction X, and four side surfaces that are connected to the two surfaces and are orthogonal to the stacking direction X of the electrode assembly 12. It consists of 12c, 12d, 12e, and 12f. The side surface 12e is a current collecting side side surface on which the positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 project. The positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 project in the same direction from one side surface 12e. Further, the side surface 12f is a bottom side surface as an opposite surface facing the side surface 12e. Further, the side surfaces 12c and 12d are side surfaces orthogonal to the side surfaces 12e and 12f, respectively, and are surfaces facing the width direction Y orthogonal to the stacking direction X of the electrode assembly 12.

電極組立体12は絶縁シートとしての絶縁フィルム33で覆われている。絶縁フィルム33は、電極組立体12を金属製のケース11と絶縁するための絶縁性シートであり、例えば、ポリプロピレン(PP)製である。絶縁フィルム33は、1枚の絶縁フィルム33を折り畳み、かつ溶着して袋状に形成されている。 The electrode assembly 12 is covered with an insulating film 33 as an insulating sheet. The insulating film 33 is an insulating sheet for insulating the electrode assembly 12 from the metal case 11, and is made of polypropylene (PP), for example. The insulating film 33 is formed in a bag shape by folding and welding one insulating film 33.

ここで、溶着する前の絶縁フィルム33について説明する。
図4(a)に示すように、絶縁フィルム33は、電極組立体12の表面12aより大きい矩形状の第1領域33aと、電極組立体12の表面12bより大きい矩形状の第2領域33bと、電極組立体12の側面12fより大きい矩形状の第3領域33cとを有する。第1領域33aは、電極組立体12の表面12aの全面を覆う部位であり、第2領域33bは、電極組立体12の表面12bの全面を覆う部位であり、第3領域33cは、電極組立体12の側面12fの全面を覆う部位である。
Here, the insulating film 33 before welding will be described.
As shown in FIG. 4A, the insulating film 33 includes a rectangular first region 33a larger than the surface 12a of the electrode assembly 12 and a rectangular second region 33b larger than the surface 12b of the electrode assembly 12. It has a rectangular third region 33c that is larger than the side surface 12f of the electrode assembly 12. The first region 33a is a portion that covers the entire surface 12a of the electrode assembly 12, the second region 33b is a portion that covers the entire surface 12b of the electrode assembly 12, and the third region 33c is the electrode assembly. It is a portion that covers the entire surface of the side surface 12f of the solid body 12.

第1領域33aは、電極組立体12の表面12aから幅方向Y一方にはみ出したはみ出し部34と、幅方向Y他方にはみ出したはみ出し部35とを含む。第2領域33bは、電極組立体12の表面12bから幅方向Y一方にはみ出したはみ出し部36と、幅方向Y他方にはみ出したはみ出し部37とを含む。第3領域33cは、電極組立体12の側面12fから幅方向Y一方にはみ出したはみ出し部38と、幅方向Y他方にはみ出したはみ出し部39とを含む。電極組立体12の表面12a,12bからのはみ出し部34,36のはみ出し寸法及びはみ出し部35,37のはみ出し寸法は、電極組立体12の積層方向Xの寸法より短い。 The first region 33a includes a protruding portion 34 protruding from the surface 12a of the electrode assembly 12 on one side in the width direction Y, and a protruding portion 35 protruding from the surface 12a in the width direction Y on the other side. The second region 33b includes a protruding portion 36 protruding from the surface 12b of the electrode assembly 12 on one side in the width direction Y, and a protruding portion 37 protruding from the surface 12b in the width direction Y on the other side. The third region 33c includes a protruding portion 38 protruding from the side surface 12f of the electrode assembly 12 on one side in the width direction Y, and a protruding portion 39 protruding from the other side in the width direction Y. The protruding dimensions of the protruding portions 34 and 36 and the protruding dimensions of the protruding portions 35 and 37 from the surfaces 12a and 12b of the electrode assembly 12 are shorter than the dimensions of the electrode assembly 12 in the stacking direction X.

次に、電極組立体12を覆った絶縁フィルム33について説明する。
図1に示すように、絶縁フィルム33は、電極組立体12の側面12cを覆う覆部41を有する。覆部41は、はみ出し部34の根元部分34aと、はみ出し部36の根元部分36aとから構成されている。また、絶縁フィルム33は、覆部41よりも突出した重合部42を有する。重合部42は、はみ出し部34の先端部分である余剰部34bと、この余剰部34bと対向するはみ出し部36の先端部分である余剰部36bとから構成されている。絶縁フィルム33は、はみ出し部34の余剰部34bとはみ出し部36の余剰部36bとを熱溶着した溶着部43を有する。本実施形態の溶着部43は、電極組立体12の積層方向X中央かつ側面12c近傍に位置する。
Next, the insulating film 33 that covers the electrode assembly 12 will be described.
As shown in FIG. 1, the insulating film 33 has a covering portion 41 that covers the side surface 12c of the electrode assembly 12. The covering portion 41 is composed of a root portion 34a of the protruding portion 34 and a root portion 36a of the protruding portion 36. Further, the insulating film 33 has a polymerized portion 42 that protrudes from the covering portion 41. The polymerization portion 42 is composed of a surplus portion 34b which is a tip portion of the protruding portion 34 and a surplus portion 36b which is a tip portion of the protruding portion 36 facing the surplus portion 34b. The insulating film 33 has a welded portion 43 in which the surplus portion 34b of the protruding portion 34 and the surplus portion 36b of the protruding portion 36 are hot-welded. The welded portion 43 of the present embodiment is located at the center of the stacking direction X of the electrode assembly 12 and near the side surface 12c.

図4(c)に示すように、絶縁フィルム33は、電極組立体12の側面12dを覆う覆部44を有する。覆部44は、はみ出し部35の根元部分35aと、はみ出し部37の根元部分37aとから構成されている。また、絶縁フィルム33は、覆部44よりも突出した重合部45を有する。重合部45は、はみ出し部35の先端部分である余剰部35bと、この余剰部35bと対向するはみ出し部37の先端部分である余剰部37bとから構成されている。絶縁フィルム33は、はみ出し部35の余剰部35bとはみ出し部37の余剰部37bとを熱溶着した溶着部46を有する。本実施形態の溶着部46は、電極組立体12の積層方向X中央かつ側面12d近傍に位置する。 As shown in FIG. 4C, the insulating film 33 has a covering portion 44 that covers the side surface 12d of the electrode assembly 12. The covering portion 44 is composed of a root portion 35a of the protruding portion 35 and a root portion 37a of the protruding portion 37. Further, the insulating film 33 has a polymerized portion 45 that protrudes from the covering portion 44. The polymerization portion 45 is composed of a surplus portion 35b which is a tip portion of the protruding portion 35 and a surplus portion 37b which is a tip portion of the protruding portion 37 facing the surplus portion 35b. The insulating film 33 has a welded portion 46 in which the surplus portion 35b of the protruding portion 35 and the surplus portion 37b of the protruding portion 37 are hot-welded. The welded portion 46 of the present embodiment is located at the center of the stacking direction X of the electrode assembly 12 and near the side surface 12d.

絶縁フィルム33において、覆部41,44には、積層方向X中央に向かう張力が発生している。この張力により、第1領域33a及び第2領域33bが積層方向X中央に向けて引っ張られている。第1領域33a及び第2領域33bは、電極組立体12の表面12a,12bに密着している。 In the insulating film 33, tension is generated in the covering portions 41 and 44 toward the center of the stacking direction X. Due to this tension, the first region 33a and the second region 33b are pulled toward the center of the stacking direction X. The first region 33a and the second region 33b are in close contact with the surfaces 12a and 12b of the electrode assembly 12.

このように絶縁フィルム33は、電極組立体12の側面12eを除く5面を覆っている。そして、絶縁フィルム33によって覆われた電極組立体12は、本体部材13の開口部13aから挿入されて、ケース11内に収容される。 In this way, the insulating film 33 covers five surfaces of the electrode assembly 12, excluding the side surface 12e. Then, the electrode assembly 12 covered with the insulating film 33 is inserted through the opening 13a of the main body member 13 and housed in the case 11.

次に、二次電池10の製造工程、特に絶縁フィルム33によって電極組立体12を覆う手順について詳述する。
まず、図4(a)に示すように、U字状に折り曲げられた絶縁フィルム33の間に電極組立体12を配置する。このとき、絶縁フィルム33の第1領域33aを電極組立体12の表面12aと対向させ、絶縁フィルム33の第2領域33bを電極組立体12の表面12bと対向させ、絶縁フィルム33の第3領域33cを電極組立体12の側面12fと対向させる。これにより、電極組立体12の表面12a,12b及び側面12fの全面が絶縁フィルム33によって覆われた状態となる。また、電極組立体12を絶縁フィルム33の幅方向Y中央に配置することで、第1〜第3領域33a〜33cのはみ出し部34〜39は電極組立体12からはみ出した状態となる。
Next, the manufacturing process of the secondary battery 10, particularly the procedure of covering the electrode assembly 12 with the insulating film 33 will be described in detail.
First, as shown in FIG. 4A, the electrode assembly 12 is arranged between the insulating films 33 bent in a U shape. At this time, the first region 33a of the insulating film 33 faces the surface 12a of the electrode assembly 12, the second region 33b of the insulating film 33 faces the surface 12b of the electrode assembly 12, and the third region of the insulating film 33 faces. 33c is opposed to the side surface 12f of the electrode assembly 12. As a result, the entire surfaces of the surfaces 12a and 12b and the side surfaces 12f of the electrode assembly 12 are covered with the insulating film 33. Further, by arranging the electrode assembly 12 at the center of the insulating film 33 in the width direction Y, the protruding portions 34 to 39 of the first to third regions 33a to 33c are in a state of protruding from the electrode assembly 12.

また、電極組立体12に対し積層方向Xの両方向から荷重Kを加え、絶縁フィルム33の第1領域33aを電極組立体12の表面12aに密着させ、絶縁フィルム33の第2領域33bを電極組立体12の表面12bに密着させる。 Further, a load K is applied to the electrode assembly 12 from both directions of the stacking direction X, the first region 33a of the insulating film 33 is brought into close contact with the surface 12a of the electrode assembly 12, and the second region 33b of the insulating film 33 is set as an electrode. It is brought into close contact with the surface 12b of the solid body 12.

次に、図4(b)に示すように、はみ出し部38,39を電極組立体12の側面12c,12dに沿うように折り曲げる。その後、クランプ51を用いて、はみ出し部34の先端とはみ出し部36の先端とを、一対のはみ出し部34,36としてまとめて保持するとともに、はみ出し方向としての幅方向Y外側に引っ張る。これにより、はみ出し部34,36は張力がかかった状態となる。同様に、クランプ52を用いて、はみ出し部35の先端とはみ出し部37の先端とを、一対のはみ出し部35,37としてまとめて保持するとともに、はみ出し方向としての幅方向Y外側に引っ張る。これにより、はみ出し部35,37は張力がかかった状態となる。なお、はみ出し部34〜37を引っ張る際も、電極組立体12に対して荷重Kを加え続けている。 Next, as shown in FIG. 4B, the protruding portions 38 and 39 are bent along the side surfaces 12c and 12d of the electrode assembly 12. After that, using the clamp 51, the tip of the protruding portion 34 and the tip of the protruding portion 36 are collectively held as a pair of protruding portions 34, 36, and are pulled outward in the width direction Y as the protruding direction. As a result, the protruding portions 34 and 36 are in a state of being tensioned. Similarly, using the clamp 52, the tip of the protruding portion 35 and the tip of the protruding portion 37 are collectively held as a pair of protruding portions 35, 37, and are pulled outward in the width direction Y as the protruding direction. As a result, the protruding portions 35 and 37 are in a state of being tensioned. Even when the protruding portions 34 to 37 are pulled, the load K is continuously applied to the electrode assembly 12.

図4(b)に示すように、一対のはみ出し部34,36の両側には、積層方向Xに対をなすヒーター61,62が配置されている。各ヒーター61,62は、電極組立体12の側面12c近傍の位置にて積層方向Xに移動可能である。また、一対のはみ出し部35,37の両側には、積層方向Xに対をなすヒーター63,64が配置されている。各ヒーター63,64は、電極組立体12の側面12d近傍の位置にて積層方向Xに移動可能である。各ヒーター61〜64の電源はオフである。 As shown in FIG. 4B, heaters 61 and 62 paired in the stacking direction X are arranged on both sides of the pair of protruding portions 34 and 36. Each of the heaters 61 and 62 can be moved in the stacking direction X at a position near the side surface 12c of the electrode assembly 12. Further, heaters 63 and 64 paired in the stacking direction X are arranged on both sides of the pair of protruding portions 35 and 37. Each of the heaters 63 and 64 can be moved in the stacking direction X at a position near the side surface 12d of the electrode assembly 12. The power of each heater 61 to 64 is off.

次に、図4(c)に示すように、一対のはみ出し部34,36をはみ出し方向としての幅方向Y外側に引っ張った状態で、一方のヒーター61を積層方向X中央まで移動させる。ヒーター61ははみ出し部34に接触し、根元部分34aは電極組立体12の側面12cに沿うように折り曲げられる。また、一方のヒーター61の移動と同時に、他方のヒーター62を積層方向X中央まで移動させる。ヒーター62ははみ出し部36に接触し、根元部分36aは電極組立体12の側面12cに沿うように折り曲げられる。 Next, as shown in FIG. 4C, one of the heaters 61 is moved to the center of the stacking direction X while the pair of protruding portions 34, 36 are pulled outward in the width direction Y as the protruding direction. The heater 61 comes into contact with the protruding portion 34, and the root portion 34a is bent along the side surface 12c of the electrode assembly 12. Further, at the same time as the movement of one heater 61, the other heater 62 is moved to the center of the stacking direction X. The heater 62 comes into contact with the protruding portion 36, and the root portion 36a is bent along the side surface 12c of the electrode assembly 12.

各ヒーター61,62が積層方向X中央に達すると、両ヒーター61,62は、一対のはみ出し部34,36を介して対向する。そして、電極組立体12の側面12cを覆うはみ出し部34,36の根元部分34a,36aによって覆部41が形成され、側面12cを覆うことなく余剰となる先端部分は、余剰部34b,36bとなる。一対の余剰部34b,36bは、側面12cから離れるように折り曲げられて重なり重合部42となる。 When the heaters 61 and 62 reach the center of the stacking direction X, the heaters 61 and 62 face each other via the pair of protruding portions 34 and 36. Then, the covering portion 41 is formed by the root portions 34a and 36a of the protruding portions 34 and 36 that cover the side surface 12c of the electrode assembly 12, and the tip portions that become surplus without covering the side surface 12c become the surplus portions 34b and 36b. .. The pair of surplus portions 34b and 36b are bent so as to be separated from the side surface 12c and overlap to form the overlapping portion 42.

この後、ヒーター61,62の電源をオンにする。そして、高温状態となったヒーター61,62をはみ出し部34,36の余剰部34b,36bの根元部分に押し当てて入熱することで熱溶着し、一対の余剰部34b,36bを接合する。これにより、一対の余剰部34b,36bには溶着部43が形成される。なお、ヒーター61,62の移動時やはみ出し部34,36の溶着時にも、電極組立体12に対して荷重Kを加え続けている。このため、絶縁フィルム33の第1領域33aが電極組立体12の表面12aに密着し、絶縁フィルム33の第2領域33bが電極組立体12の表面12bに密着した状態のまま、覆部41及び溶着部43が形成される。 After that, the power of the heaters 61 and 62 is turned on. Then, the heaters 61 and 62 in a high temperature state are pressed against the root portions of the surplus portions 34b and 36b of the protruding portions 34 and 36 to heat, and heat welding is performed to join the pair of surplus portions 34b and 36b. As a result, the welded portion 43 is formed in the pair of surplus portions 34b and 36b. The load K is continuously applied to the electrode assembly 12 even when the heaters 61 and 62 are moved and the protruding portions 34 and 36 are welded. Therefore, the covering portion 41 and the covering portion 41 and the second region 33b of the insulating film 33 remain in close contact with the surface 12b of the electrode assembly 12 while the first region 33a of the insulating film 33 is in close contact with the surface 12a of the electrode assembly 12. The welded portion 43 is formed.

同様に、一対のはみ出し部35,37をはみ出し方向としての幅方向Y外側に引っ張った状態で、一方のヒーター63を積層方向X中央まで移動させる。ヒーター63ははみ出し部35に接触し、根元部分35aは電極組立体12の側面12dに沿うように折り曲げられる。また、一方のヒーター63の移動と同時に、他方のヒーター64を積層方向X中央まで移動させる。ヒーター64ははみ出し部37に接触し、根元部分37aは電極組立体12の側面12dに沿うように折り曲げられる。 Similarly, one heater 63 is moved to the center of the stacking direction X while the pair of protruding portions 35, 37 are pulled outward in the width direction Y as the protruding direction. The heater 63 comes into contact with the protruding portion 35, and the root portion 35a is bent along the side surface 12d of the electrode assembly 12. Further, at the same time as the movement of one heater 63, the other heater 64 is moved to the center of the stacking direction X. The heater 64 comes into contact with the protruding portion 37, and the root portion 37a is bent along the side surface 12d of the electrode assembly 12.

各ヒーター63,64が積層方向X中央に達すると、ヒーター63とヒーター64とは、一対のはみ出し部35,37を介して対向する。そして、電極組立体12の側面12dを覆うはみ出し部35,37の根元部分35a,37aによって覆部44が形成され、側面12dを覆うことなく余剰となる先端部分は、余剰部35b,37bとなる。余剰部35b,36bは、側面12dから離れるように折り曲げられて重なり重合部45となる。 When each of the heaters 63 and 64 reaches the center of the stacking direction X, the heater 63 and the heater 64 face each other via the pair of protruding portions 35 and 37. Then, the covering portion 44 is formed by the root portions 35a and 37a of the protruding portions 35 and 37 covering the side surface 12d of the electrode assembly 12, and the surplus tip portions that do not cover the side surface 12d become the surplus portions 35b and 37b. .. The surplus portions 35b and 36b are bent so as to be separated from the side surface 12d and overlapped to form the overlapping portion 45.

この後、ヒーター63,64の電源をオンにする。そして、高温状態となったヒーター63,64をはみ出し部35,37の余剰部35b,37bの根元部分に押し当てて入熱することで熱溶着し、一対の余剰部35b,37bを接合する。これにより、一対の余剰部35b,37bには溶着部46が形成される。 After that, the power of the heaters 63 and 64 is turned on. Then, the heaters 63, 64 in a high temperature state are pressed against the root portions of the surplus portions 35b, 37b of the protruding portions 35, 37 to heat, and heat welding is performed to join the pair of surplus portions 35b, 37b. As a result, a welded portion 46 is formed on the pair of surplus portions 35b and 37b.

なお、ヒーター63,64の移動時やはみ出し部35,37の溶着時にも、電極組立体12に対して荷重Kを加え続けている。このため、絶縁フィルム33の第1領域33aが電極組立体12の表面12aに密着し、絶縁フィルム33の第2領域33bが電極組立体12の表面12bに密着した状態のまま、覆部44及び溶着部46が形成される。 The load K is continuously applied to the electrode assembly 12 even when the heaters 63 and 64 are moved and when the protruding portions 35 and 37 are welded. Therefore, the covering portion 44 and the covering portion 44 and the second region 33b of the insulating film 33 remain in close contact with the surface 12b of the electrode assembly 12 while the first region 33a of the insulating film 33 is in close contact with the surface 12a of the electrode assembly 12. The welded portion 46 is formed.

こうして溶着部43,46が形成されると、絶縁フィルム33は有底袋状となる。その後、電極組立体12に対し荷重Kを加えること、及びクランプ51,52によってはみ出し部34〜37を引っ張ることを終了する。 When the welded portions 43 and 46 are formed in this way, the insulating film 33 has a bottomed bag shape. After that, the load K is applied to the electrode assembly 12, and the protrusions 34 to 37 are pulled by the clamps 51 and 52.

最後に、図4(d)に示すように、重合部42(溶着部43を有する一対の余剰部34b,36b)を電極組立体12の側面12cに沿うように折り曲げる。本実施形態では、余剰部36bが電極組立体12の側面12cと対向するように折り曲げる。同様に、重合部45(溶着部46を有する一対の余剰部35b,37b)を電極組立体12の側面12dに沿うように折り曲げる。本実施形態では、余剰部37bが電極組立体12の側面12dと対向するように折り曲げる。 Finally, as shown in FIG. 4D, the polymerization portion 42 (a pair of surplus portions 34b and 36b having a welding portion 43) is bent along the side surface 12c of the electrode assembly 12. In the present embodiment, the surplus portion 36b is bent so as to face the side surface 12c of the electrode assembly 12. Similarly, the polymerization portion 45 (a pair of surplus portions 35b, 37b having the welding portion 46) is bent along the side surface 12d of the electrode assembly 12. In the present embodiment, the surplus portion 37b is bent so as to face the side surface 12d of the electrode assembly 12.

次に、本実施形態の作用について説明する。
一対のはみ出し部34,36を幅方向Y外側に引っ張った状態で熱して接合するため、電極組立体12の側面12cを覆う覆部41には、積層方向X中央に向かう張力が発生する。同様に、一対のはみ出し部35,37を幅方向Y外側に引っ張った状態で熱して接合するため、電極組立体12の側面12dを覆う覆部44には、積層方向X中央に向かう張力が発生する。このため、絶縁フィルム33の第1及び第2領域33a,33bが電極組立体12の表面12a,12bに密着した状態が維持される。
Next, the operation of this embodiment will be described.
Since the pair of protruding portions 34, 36 are heated and joined in a state of being pulled outward in the width direction Y, tension is generated in the covering portion 41 covering the side surface 12c of the electrode assembly 12 toward the center of the stacking direction X. Similarly, since the pair of protruding portions 35 and 37 are heated and joined in a state of being pulled outward in the width direction Y, tension is generated in the covering portion 44 covering the side surface 12d of the electrode assembly 12 toward the center of the stacking direction X. To do. Therefore, the first and second regions 33a and 33b of the insulating film 33 are maintained in close contact with the surfaces 12a and 12b of the electrode assembly 12.

次に、本実施形態の特徴的な効果を記載する。
(1)一対のはみ出し部34,36を幅方向Y外側に引っ張った状態で熱して接合するため、電極組立体12の側面12cを覆う覆部41には、積層方向X中央に向かう張力が発生する。この張力は、第1領域33a及び第2領域33bの電極組立体12を積層方向Xに拘束する拘束力となるため、電極組立体12の層状構造の崩れ(積層ずれ)が抑制される。
Next, the characteristic effects of this embodiment will be described.
(1) Since the pair of protruding portions 34, 36 are heated and joined in a state of being pulled outward in the width direction Y, tension is generated in the covering portion 41 covering the side surface 12c of the electrode assembly 12 toward the center of the stacking direction X. To do. Since this tension acts as a binding force that constrains the electrode assembly 12 in the first region 33a and the second region 33b in the stacking direction X, the collapse (stacking deviation) of the layered structure of the electrode assembly 12 is suppressed.

同様に、一対のはみ出し部35,37を幅方向Y外側に引っ張った状態で熱して接合するため、電極組立体12の側面12dを覆う覆部44には、積層方向X中央に向かう張力が発生する。この張力は、第1領域33a及び第2領域33bの電極組立体12を積層方向Xに拘束する拘束力となるため、電極組立体12の層状構造の崩れ(積層ずれ)が抑制される。 Similarly, since the pair of protruding portions 35 and 37 are heated and joined in a state of being pulled outward in the width direction Y, tension is generated in the covering portion 44 covering the side surface 12d of the electrode assembly 12 toward the center of the stacking direction X. To do. Since this tension acts as a binding force that constrains the electrode assembly 12 in the first region 33a and the second region 33b in the stacking direction X, the collapse (stacking deviation) of the layered structure of the electrode assembly 12 is suppressed.

この場合、電極組立体12を拘束する工程と、絶縁フィルム33によって電極組立体12を覆う工程とを同時に行うため、二次電池10の生産性を向上させることができる。
(2)はみ出し部34とはみ出し部36とをまとめて幅方向Y外側へ引っ張るため、はみ出し部34,36を別々に引っ張る場合と比較して、クランプ51の数を減らすことができる。同様に、はみ出し部35とはみ出し部37とをまとめて幅方向Y外側へ引っ張るため、はみ出し部35,37を別々に引っ張る場合と比較して、クランプ52の数を減らすことができる。
In this case, since the step of restraining the electrode assembly 12 and the step of covering the electrode assembly 12 with the insulating film 33 are performed at the same time, the productivity of the secondary battery 10 can be improved.
(2) Since the protruding portion 34 and the protruding portion 36 are pulled together to the outside in the width direction Y, the number of clamps 51 can be reduced as compared with the case where the protruding portions 34 and 36 are pulled separately. Similarly, since the protruding portion 35 and the protruding portion 37 are pulled together to the outside in the width direction Y, the number of clamps 52 can be reduced as compared with the case where the protruding portions 35 and 37 are pulled separately.

(3)溶着部43,46は積層方向X中央に形成されるため、はみ出し部34〜36の張力を積層方向X中央に向けることができる。よって、絶縁フィルム33の電極組立体12に対する積層方向Xの拘束力のバランスを良好にできる。 (3) Since the welded portions 43 and 46 are formed in the center of the stacking direction X, the tension of the protruding portions 34 to 36 can be directed to the center of the stacking direction X. Therefore, the balance of the binding force of the insulating film 33 with respect to the electrode assembly 12 in the stacking direction X can be improved.

(4)電極組立体12に対して積層方向Xの荷重Kを加えながら絶縁フィルム33で覆う。したがって、電極組立体12には積層方向Xへの復元力が発生するが、その復元力に対する抗力として絶縁フィルム33により電極組立体12が拘束される。よって、絶縁フィルム33の電極組立体12に対する拘束力をより強くできる。 (4) The electrode assembly 12 is covered with the insulating film 33 while applying a load K in the stacking direction X. Therefore, a restoring force in the stacking direction X is generated in the electrode assembly 12, but the electrode assembly 12 is restrained by the insulating film 33 as a drag against the restoring force. Therefore, the binding force of the insulating film 33 on the electrode assembly 12 can be made stronger.

(5)幅方向Y一方にはみ出す一対のはみ出し部34,36と、幅方向Y他方にはみ出す一対のはみ出し部35,37とをそれぞれ引っ張った状態で熱して接合するため、絶縁フィルム33の電極組立体12に対する幅方向Yの拘束力のバランスを良好にできる。 (5) The electrode set of the insulating film 33 is formed by heating and joining the pair of protruding portions 34 and 36 protruding from one side in the width direction Y and the pair of protruding portions 35 and 37 protruding from the other side in the width direction Y, respectively. The balance of the binding force in the width direction Y with respect to the solid 12 can be improved.

(6)電極組立体12の側面12eを開放するように、絶縁フィルム33で電極組立体12を覆うため、側面12eに設けられた正極集電タブ28及び負極集電タブ30を正極端子15及び負極端子16に接続することができる。 (6) In order to cover the electrode assembly 12 with the insulating film 33 so as to open the side surface 12e of the electrode assembly 12, the positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 provided on the side surface 12e are connected to the positive electrode terminal 15 and the negative electrode current collecting tab 30. It can be connected to the negative electrode terminal 16.

(7)覆部41,44を電極組立体12の側面12c,12dに沿わせた状態で、はみ出し部34〜37を熱して接合する。このため、絶縁フィルム33により、積層方向Xに加えて幅方向Yにも電極組立体12を拘束できる。 (7) With the covering portions 41 and 44 along the side surfaces 12c and 12d of the electrode assembly 12, the protruding portions 34 to 37 are heated and joined. Therefore, the insulating film 33 can restrain the electrode assembly 12 not only in the stacking direction X but also in the width direction Y.

なお、上記実施形態は、以下のように変更してもよい。
○ 電極組立体12は、巻回型の電極組立体であってもよい。
○ 正極電極20の正極活物質層23は、正極金属箔22の両面に形成されたが、片面のみに形成されてもよい。負極電極21の負極活物質層25は、負極金属箔24の両面に形成されたが、片面のみに形成されてもよい。
The above embodiment may be changed as follows.
◯ The electrode assembly 12 may be a winding type electrode assembly.
The positive electrode active material layer 23 of the positive electrode electrode 20 is formed on both sides of the positive electrode metal foil 22, but may be formed on only one side. The negative electrode active material layer 25 of the negative electrode electrode 21 is formed on both sides of the negative electrode metal foil 24, but may be formed on only one side.

○ 複数枚の絶縁フィルム33によって電極組立体12を覆う構成としてもよい。
○ 絶縁フィルム33の形状等に応じて、溶着部43,46を設ける面を側面12c及び側面12dの何れか一方のみにしてもよい。
O The electrode assembly 12 may be covered with a plurality of insulating films 33.
○ Depending on the shape of the insulating film 33 and the like, the surface on which the welded portions 43 and 46 are provided may be only one of the side surface 12c and the side surface 12d.

○ はみ出し部34〜37の寸法は、溶着部43,46の形成が可能な範囲で変更してもよい。ただし、二次電池10の大型化を抑制するという観点では、余剰部34b〜37bを折り曲げた際に電極組立体12の積層方向Xの端面より外側にはみ出さない程度の寸法にするのが好ましい。 ○ The dimensions of the protruding portions 34 to 37 may be changed within a range in which the welded portions 43 and 46 can be formed. However, from the viewpoint of suppressing the increase in size of the secondary battery 10, it is preferable that the dimensions do not protrude outward from the end face of the electrode assembly 12 in the stacking direction X when the surplus portions 34b to 37b are bent. ..

○ 正極集電タブ28及び負極集電タブ30は、電極組立体12の側面12eに設けられていたが、側面12c,12d,12fに設けてもよい。この場合、正極集電タブ28及び負極集電タブ30が設けられた側面を開放するように、絶縁フィルム33で電極組立体12を覆う。正極集電タブ28及び負極集電タブ30が設けられていない側面に溶着部43,46を適宜設けてもよい。例えば、正極集電タブ28及び負極集電タブ30を側面12cに設け、側面12e,12fに溶着部43,46を設ける場合、はみ出し部34〜37は、積層方向X及び幅方向Yと直交する方向にはみ出す。このように、はみ出し部34〜37は、絶縁フィルム33により電極組立体12が拘束されるようにはみ出していればよい。 The positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 are provided on the side surface 12e of the electrode assembly 12, but may be provided on the side surfaces 12c, 12d, 12f. In this case, the electrode assembly 12 is covered with the insulating film 33 so as to open the side surfaces where the positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 are provided. Welding portions 43 and 46 may be appropriately provided on the side surfaces where the positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 are not provided. For example, when the positive electrode current collecting tab 28 and the negative electrode current collecting tab 30 are provided on the side surface 12c and the welding portions 43 and 46 are provided on the side surfaces 12e and 12f, the protruding portions 34 to 37 are orthogonal to the stacking direction X and the width direction Y. It sticks out in the direction. In this way, the protruding portions 34 to 37 may protrude so that the electrode assembly 12 is constrained by the insulating film 33.

○ はみ出し部34〜37を引っ張るための装置は、クランプ51,52に限定されない。
○ 積層方向X中央からずれた位置ではみ出し部34〜37を引っ張ってもよい。
○ The device for pulling the protruding portions 34 to 37 is not limited to the clamps 51 and 52.
○ The protruding portions 34 to 37 may be pulled at a position deviated from the center of the stacking direction X.

○上記実施形態では、はみ出し部34,36をはみ出し方向としての幅方向Yに引っ張っていたが、例えば、はみ出し部34,36を幅方向Y外側かつ側面12f側に引っ張ってもよい。つまり、はみ出し方向を含む方向であれば、はみ出し部34,36を引っ張る方向を適宜変更してよい。 ○ In the above embodiment, the protruding portions 34 and 36 are pulled in the width direction Y as the protruding direction, but for example, the protruding portions 34 and 36 may be pulled outside the width direction Y and toward the side surface 12f. That is, the direction in which the protruding portions 34 and 36 are pulled may be appropriately changed as long as the direction includes the protruding direction.

○ 上記実施形態では、はみ出し部34とはみ出し部36とをまとめて引っ張り、はみ出し部35とはみ出し部37とをまとめて引っ張っていたが、それぞれ別々に引っ張ってもよい。 ○ In the above embodiment, the protruding portion 34 and the protruding portion 36 are pulled together, and the protruding portion 35 and the protruding portion 37 are pulled together, but they may be pulled separately.

○ 上記実施形態では、はみ出し部34とはみ出し部36の両方を引っ張っていたが、いずれか一方のみを引っ張ってもよい。例えば、はみ出し部34のみを引っ張る場合、ヒーター61をはみ出し部34に接触させながら、積層方向X他端側(はみ出し部36側)まで移動させることで、一対のはみ出し部34,36を熱溶着させる。この場合、覆部41は、はみ出し部34の根元部分34aのみで構成される。また、はみ出し部36全体が余剰部36bとなる。 ○ In the above embodiment, both the protruding portion 34 and the protruding portion 36 are pulled, but only one of them may be pulled. For example, when pulling only the protruding portion 34, the pair of protruding portions 34, 36 are heat-welded by moving the heater 61 to the other end side (the protruding portion 36 side) in the stacking direction while contacting the protruding portion 34. .. In this case, the covering portion 41 is composed of only the root portion 34a of the protruding portion 34. Further, the entire protruding portion 36 becomes a surplus portion 36b.

同様に、上記実施形態では、はみ出し部35とはみ出し部37の両方を引っ張っていたが、いずれか一方のみを引っ張ってもよい。例えば、はみ出し部37のみを引っ張る場合、ヒーター64をはみ出し部37に接触させながら、積層方向X一端側(はみ出し部35側)まで移動させることで、一対のはみ出し部35,37を熱溶着させる。この場合、覆部44は、はみ出し部37の根元部分37aのみで構成される。また、はみ出し部35全体が余剰部35bとなる。 Similarly, in the above embodiment, both the protruding portion 35 and the protruding portion 37 are pulled, but only one of them may be pulled. For example, when pulling only the protruding portion 37, the pair of protruding portions 35, 37 are heat-welded by moving the heater 64 to one end side (the protruding portion 35 side) in the stacking direction while contacting the protruding portion 37. In this case, the covering portion 44 is composed of only the root portion 37a of the protruding portion 37. Further, the entire protruding portion 35 becomes a surplus portion 35b.

○ 上記実施形態では、溶着部43,46は、余剰部34b〜37bの根元部分に形成されていたが、溶着部43,46を形成する範囲は余剰部34b〜37bで適宜変更してもよい。 ○ In the above embodiment, the welded portions 43 and 46 are formed at the root portions of the surplus portions 34b to 37b, but the range in which the welded portions 43 and 46 are formed may be appropriately changed in the surplus portions 34b to 37b. ..

○ 積層方向X中央からずれた位置で溶着部43,46を形成してもよい。
○ 絶縁フィルム33の材料は、ポリプロピレン(PP)に限定されず、ポリフェニレンサルファイド(PPS)など他の材料でもよい。
-The welding portions 43 and 46 may be formed at positions deviated from the center of the stacking direction X.
○ The material of the insulating film 33 is not limited to polypropylene (PP), and other materials such as polyphenylene sulfide (PPS) may be used.

○ 溶着部43,46を形成するための方法は、ヒーター61〜64による熱溶着でなく超音波溶着などの他の溶着方法であってもよい。
○ はみ出し部34〜37を接合するための方法は、溶着に限定されず、接着剤による接合や、絶縁材料製のリベットやホッチキスなどを用いたかしめ接合であってもよい。
○ The method for forming the welded portions 43, 46 may be another welding method such as ultrasonic welding instead of heat welding by heaters 61 to 64.
○ The method for joining the protruding portions 34 to 37 is not limited to welding, and may be joining with an adhesive or caulking joining using a rivet or stapler made of an insulating material.

○ 上記実施形態では、絶縁フィルム33によって電極組立体12を覆う際、電極組立体12に対して積層方向Xの両方向から荷重Kを加えていたが、積層方向Xの一方向からのみ荷重Kを加えてもよい。また、荷重Kを加えなくてもよい。この場合、はみ出し部34〜37を引っ張る際に、第1及び第2領域33a,33bを電極組立体12の表面12a,12bに密着させる。 ○ In the above embodiment, when the electrode assembly 12 is covered with the insulating film 33, the load K is applied to the electrode assembly 12 from both directions of the stacking direction X, but the load K is applied only from one direction of the stacking direction X. May be added. Further, it is not necessary to apply the load K. In this case, when the protruding portions 34 to 37 are pulled, the first and second regions 33a and 33b are brought into close contact with the surfaces 12a and 12b of the electrode assembly 12.

○ 上記実施形態では、余剰部36bが電極組立体12の側面12cと対向するように重合部42を折り曲げ、余剰部37bが電極組立体12の側面12dと対向するように重合部45を折り曲げていたが、重合部42,45の処理方法はこれに限定されない。 ○ In the above embodiment, the polymerization portion 42 is bent so that the surplus portion 36b faces the side surface 12c of the electrode assembly 12, and the polymerization portion 45 is bent so that the surplus portion 37b faces the side surface 12d of the electrode assembly 12. However, the treatment method of the polymerization portions 42 and 45 is not limited to this.

例えば、余剰部34bが電極組立体12の側面12cと対向するように重合部42を折り曲げたり、余剰部35bが電極組立体12の側面12dと対向する方向に折り曲げたりしてもよい。また、溶着部43,46よりも幅方向Y外側の位置で、重合部42,45を切断して取り除いてもよい。 For example, the overlapping portion 42 may be bent so that the surplus portion 34b faces the side surface 12c of the electrode assembly 12, or the surplus portion 35b may be bent in the direction facing the side surface 12d of the electrode assembly 12. Further, the polymerization portions 42 and 45 may be cut and removed at a position Y outside the welding portions 43 and 46 in the width direction.

○ 上記実施形態では、はみ出し部38,39を電極組立体12の側面12c,12dに沿うように折り曲げた後、はみ出し部34〜37を溶着していたが、はみ出し部34〜37を溶着した後に、はみ出し部38,39を折り曲げてもよい。この場合、図5に示すように、重合部42,45を折り曲げる際に、溶着されたはみ出し部38,39を重合部42,45の折り曲げ方向と同方向に折り曲げる。その後、はみ出し部38,39において電極組立体12の側面12c,12dからはみ出した部分を側面12c,12dに沿うように折り曲げる。 ○ In the above embodiment, after the protruding portions 38 and 39 are bent along the side surfaces 12c and 12d of the electrode assembly 12, the protruding portions 34 to 37 are welded, but after the protruding portions 34 to 37 are welded. , The protruding portions 38, 39 may be bent. In this case, as shown in FIG. 5, when the overlapping portions 42 and 45 are bent, the welded protruding portions 38 and 39 are bent in the same direction as the bending direction of the overlapping portions 42 and 45. After that, in the protruding portions 38 and 39, the portions protruding from the side surfaces 12c and 12d of the electrode assembly 12 are bent along the side surfaces 12c and 12d.

○ 蓄電装置は、例えばキャパシタなど、二次電池以外の蓄電装置にも適用可能である。
○ 二次電池10は、リチウムイオン二次電池でもよいし、他の二次電池であってもよい。要は、正極用の活物質と負極用の活物質との間をイオンが移動するとともに電荷の授受を行うものであればよい。
○ The power storage device can also be applied to a power storage device other than a secondary battery, such as a capacitor.
○ The secondary battery 10 may be a lithium ion secondary battery or another secondary battery. In short, it suffices as long as the ions move between the active material for the positive electrode and the active material for the negative electrode and transfer charges.

10…蓄電装置としての二次電池、11…ケース、12…電極組立体、12a,12b…面としての表面、20…電極としての正極電極、21…電極としての負極電極、33…絶縁シートとしての絶縁フィルム、34〜37…はみ出し部、X…積層方向。 10 ... Secondary battery as a power storage device, 11 ... Case, 12 ... Electrode assembly, 12a, 12b ... Surface as a surface, 20 ... Positive electrode as an electrode, 21 ... Negative electrode as an electrode, 33 ... As an insulating sheet Insulating film, 34 to 37 ... Overhanging portion, X ... Laminating direction.

Claims (5)

異なる極性の電極同士を絶縁した層状構造を有する電極組立体と、
前記電極組立体を収容した金属製のケースと、
前記電極組立体を覆い、前記ケースと前記電極組立体とを絶縁する絶縁シートと、を備え、
前記絶縁シートは、前記電極組立体における積層方向の両面からはみ出し、かつ積層方向に対向した一対のはみ出し部を有し、前記一対のはみ出し部が接合されている蓄電装置の製造方法であって、
前記電極組立体は、積層型の電極組立体であって、前記積層方向の両面である表面に連設されるとともに前記積層方向に直交する4つの側面を有し、前記側面のうちの1面が前記電極組立体における正極集電タブおよび負極集電タブが突出するタブ突出面となっており、
前記一対のはみ出し部の少なくとも一方に対して、前記絶縁シートを前記電極組立体の前記表面に密着させつつはみ出し方向に引っ張った状態で前記はみ出し部の根元部分を前記電極組立体の前記側面に沿うように折り曲げて前記一対のはみ出し部を接合する接合工程を施し、前記タブ突出面を除く前記電極組立体の5面が前記絶縁シートによって覆われた前記電極組立体を前記ケース内に収容することを特徴とする蓄電装置の製造方法。
An electrode assembly having a layered structure in which electrodes of different polarities are insulated from each other,
A metal case containing the electrode assembly and
An insulating sheet that covers the electrode assembly and insulates the case and the electrode assembly is provided.
The insulating sheet is a method for manufacturing a power storage device, which has a pair of protruding portions that protrude from both sides in the stacking direction and face each other in the stacking direction in the electrode assembly, and the pair of protruding portions are joined to each other.
The electrode assembly is a laminated electrode assembly, and has four side surfaces that are connected to both surfaces in the stacking direction and are orthogonal to the stacking direction, and one of the side surfaces. Is a tab protruding surface on which the positive electrode current collecting tab and the negative electrode current collecting tab in the electrode assembly project.
The root portion of the protruding portion is along the side surface of the electrode assembly in a state where the insulating sheet is brought into close contact with the surface of the electrode assembly and pulled in the protruding direction with respect to at least one of the pair of protruding portions. The electrode assembly is housed in the case in which five surfaces of the electrode assembly excluding the tab protruding surface are covered with the insulating sheet by performing a joining step of joining the pair of protruding portions by bending as described above. A method for manufacturing a power storage device.
前記一対のはみ出し部をまとめて引っ張る請求項1に記載の蓄電装置の製造方法。 The method for manufacturing a power storage device according to claim 1, wherein the pair of protruding portions are pulled together. 記一対のはみ出し部を前記積層方向中央で接合する請求項1又は請求項2に記載の蓄電装置の製造方法。 Method for manufacturing a power storage device according to claim 1 or claim 2 for joining before Symbol pair of protruding portions in the stacking direction center. 前記電極組立体に対して前記積層方向の少なくとも一方向から荷重を加えた状態で、前記一対のはみ出し部の少なくとも一方をはみ出し方向に引っ張った状態とする請求項1〜請求項3の何れか一項に記載の蓄電装置の製造方法。 While applying a load from at least one direction of the stacking direction with respect to the electrode assembly, any one of claims 1 to 3, state pulled in the direction protruding at least one of the pair of protruding portions The method for manufacturing a power storage device according to the item. 前記絶縁シートは、前記電極組立体を挟んだ両側に前記一対のはみ出し部を備え、
前記電極組立体の両側の前記一対のはみ出し部をそれぞれはみ出し方向に引っ張った状態で接合する請求項1〜請求項4の何れか一項に記載の蓄電装置の製造方法。
The insulating sheet is provided with the pair of protrusions on both sides of the electrode assembly.
The method for manufacturing a power storage device according to any one of claims 1 to 4, wherein the pair of protruding portions on both sides of the electrode assembly are joined in a state of being pulled in the protruding direction.
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