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JP6918541B2 - Manufacturing method of screen printing plate - Google Patents
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JP6918541B2 - Manufacturing method of screen printing plate - Google Patents

Manufacturing method of screen printing plate Download PDF

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JP6918541B2
JP6918541B2 JP2017060468A JP2017060468A JP6918541B2 JP 6918541 B2 JP6918541 B2 JP 6918541B2 JP 2017060468 A JP2017060468 A JP 2017060468A JP 2017060468 A JP2017060468 A JP 2017060468A JP 6918541 B2 JP6918541 B2 JP 6918541B2
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metal
insulator
convex portion
electrodeposited
printing plate
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JP2018161806A (en
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章次 石原
章次 石原
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Taiyo Yuden Co Ltd
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Description

本発明は、金属メッシュ部と金属マスク部とを一体に備えたスクリーン印刷版の製造方法に関する。 The present invention relates to a method for manufacturing a screen printing plate in which a metal mesh portion and a metal mask portion are integrally provided.

積層セラミックコンデンサや積層セラミックインダクタ等の電子部品における導体層の作製工程には、スクリーン印刷法による導体ペースト印刷が多用されている。しかしながら、小型化が進む電子部品にあっては外形および厚さが小さい導体層が要求されているため、従前のスクリーン印刷版(メッシュに乳剤で開口部を形成したスクリーン印刷版)ではこの要求を精度面で満足することが難しくなってきている。そのため、最近では、従前のスクリーン印刷版の代わりに、金属メッシュ部と金属マスク部とを一体に備えたスクリーン印刷版が導体層の作製工程で使用されている。 Conductor paste printing by a screen printing method is often used in the process of manufacturing a conductor layer in electronic components such as multilayer ceramic capacitors and multilayer ceramic inductors. However, since electronic components that are becoming smaller and smaller require a conductor layer having a small outer shape and thickness, conventional screen printing plates (screen printing plates in which openings are formed in a mesh with an emulsion) meet this requirement. It is becoming difficult to be satisfied with the accuracy. Therefore, recently, instead of the conventional screen printing plate, a screen printing plate having a metal mesh portion and a metal mask portion integrally used is used in the process of manufacturing the conductor layer.

金属メッシュ部と金属マスク部とを一体に備えたスクリーン印刷版に関し、後記特許文献1には、(1)母材の表面に印刷開口パターン形成用のレジストを形成する工程、(2)母材のレジストで覆われていない表面部分にメッキ処理によってベースメタルを形成する工程、(3)ベースメタルの表面に金属製メッシュを密着する工程、(4)メッキ処理によってベースメタルと金属製メッシュとを接合する工程、(5)接合されたベースメタルおよび金属製メッシュを母型から剥離する工程、(6)ベースメタルの印刷用開口パターンからレジストを剥離する工程、を備える印刷用サスペンドメタルマスクの製造方法が開示されている。 Regarding a screen printing plate in which a metal mesh portion and a metal mask portion are integrally provided, Patent Document 1 described later describes (1) a step of forming a resist for forming a print opening pattern on the surface of a base material, and (2) a base material. The process of forming the base metal by plating on the surface part not covered with the resist, (3) the process of adhering the metal mesh to the surface of the base metal, and (4) the process of attaching the base metal and the metal mesh by plating. Manufacture of a suspended metal mask for printing, which comprises a step of joining, (5) a step of peeling the joined base metal and the metal mesh from the master mold, and (6) a step of peeling the resist from the printing opening pattern of the base metal. The method is disclosed.

しかしながら、後記特許文献1に開示されている製造方法は、前記工程(5)において接合されたベースメタルおよび金属製メッシュを母型から剥離するときにレジストも母型から剥離してしまうため、ベースメタルおよび金属製メッシュを母型から剥離した後にベースメタルの印刷用開口パターンからレジストを剥離する前記工程(6)が必須となる。また、ベースメタルの印刷用開口パターンの内形が小さくなると、前記工程(6)におけるベースメタルの印刷用開口パターンからのレジストの剥離が難しくなるため、剥離不良を生じて印刷用開口パターンにレジストが残存する懸念も生じる。 However, in the manufacturing method disclosed in Patent Document 1 described later, when the base metal and the metal mesh joined in the step (5) are peeled from the master mold, the resist is also peeled off from the master mold, so that the base The step (6) of peeling the metal and the metal mesh from the base metal and then peeling the resist from the printing opening pattern of the base metal is indispensable. Further, when the inner shape of the printing opening pattern of the base metal becomes smaller, it becomes difficult to peel the resist from the printing opening pattern of the base metal in the step (6), so that peeling failure occurs and the resist is applied to the printing opening pattern. There is also a concern that

国際公開第2014/098118号International Publication No. 2014/098118

本発明が解決しようとする課題は、簡易な方法にて所期のスクリーン印刷版を的確に製造できるスクリーン印刷版の製造方法を提供することにある。 An object to be solved by the present invention is to provide a method for manufacturing a screen printing plate capable of accurately manufacturing a desired screen printing plate by a simple method.

前記課題を解決するため、本発明に係るスクリーン印刷版の製造方法は、金属メッシュ部と、開口部を有する金属マスク部とを一体に備えたスクリーン印刷版の製造方法であって、金属基板の外面に前記開口部に対応する絶縁体凸部が一体形成された母型を作製する工程と、1回目の電気鋳造により、前記金属基板の前記絶縁体凸部が存しない外面領域に電着金属箔を形成する工程と、前記母型の前記電着金属箔の外面に金属メッシュを密着させた状態で、2回目の電気鋳造により、前記金属メッシュの表面に電着金属膜を形成し、かつ、前記電着金属膜の一部分に前記電着金属箔を接合して、前記金属メッシュおよび前記電着金属膜から成る前記金属メッシュ部と前記電着金属箔から成る前記金属マスク部との一体化物を作製する工程と、前記一体化物の前記電着金属膜を前記絶縁体凸部の外面から剥離し、かつ、前記電着金属箔を前記金属基板の前記絶縁体凸部が存しない外面領域から抜き出して、前記絶縁体凸部を前記金属基板の外面に残存させたまま前記一体化物を前記母型から離型する工程とを備え、前記1回目の電気鋳造において、前記電着金属箔の厚さを前記絶縁体凸部の厚さよりも大きくなるように形成するIn order to solve the above problems, the method for manufacturing a screen printing plate according to the present invention is a method for manufacturing a screen printing plate in which a metal mesh portion and a metal mask portion having an opening are integrally provided, and is a method for manufacturing a screen printing plate of a metal substrate. By the step of producing a master mold in which the insulator convex portion corresponding to the opening is integrally formed on the outer surface and the first electric casting, the electrodeposited metal is formed on the outer surface region of the metal substrate where the insulator convex portion does not exist. In the step of forming the foil and in a state where the metal mesh is in close contact with the outer surface of the electrodeposited metal foil of the master mold, an electrodeposited metal film is formed on the surface of the metal mesh by the second electric casting, and , The electrodeposited metal foil is joined to a part of the electrodeposited metal film, and the metal mesh portion made of the metal mesh and the electrodeposited metal film and the metal mask portion made of the electrodeposited metal foil are integrated. And the step of peeling the electrodeposited metal film of the integrated product from the outer surface of the insulator convex portion, and removing the electrodeposited metal foil from the outer surface region of the metal substrate where the insulator convex portion does not exist. The metal foil is thickened in the first electrocasting, comprising a step of removing the integrated material from the master mold while leaving the convex portion of the insulator on the outer surface of the metal substrate. The metal is formed so as to be larger than the thickness of the convex portion of the insulator .

本発明に係るスクリーン印刷版の製造方法によれば、簡易な方法にて所期のスクリーン印刷版を的確に製造することができる。 According to the screen printing plate manufacturing method according to the present invention, the desired screen printing plate can be accurately manufactured by a simple method.

図1(A)および図1(B)は印刷版本体の作製工程の説明図である。1 (A) and 1 (B) are explanatory views of a manufacturing process of a printing plate main body. 図2(A)および図2(B)は母型の作製工程の説明図である。2 (A) and 2 (B) are explanatory views of a process of manufacturing a master mold. 図3は第1の電気鋳造工程の説明図である。FIG. 3 is an explanatory diagram of the first electroforming process. 図4(A)および図4(B)は第1の電気鋳造工程の説明図である。4 (A) and 4 (B) are explanatory views of the first electroforming process. 図5は印刷版本体の金属メッシュを母型の電着金属箔に密着させる工程の説明図である。FIG. 5 is an explanatory diagram of a process of bringing the metal mesh of the printing plate body into close contact with the electrodeposited metal foil of the master mold. 図6は第2の電気鋳造工程の説明図である。FIG. 6 is an explanatory diagram of the second electroforming process. 図7(A)および図7(B)は第2の電気鋳造工程の説明図である。7 (A) and 7 (B) are explanatory views of the second electroforming process. 図8は離型工程の説明図である。FIG. 8 is an explanatory diagram of the mold release process. 図9は仕上げ工程の説明図である。FIG. 9 is an explanatory diagram of the finishing process. 図10(A)〜図10(D)は第1の電気鋳造工程の変形例の説明図である。10 (A) to 10 (D) are explanatory views of a modified example of the first electroforming process.

以下、図1〜図9を用いて、本発明を適用したスクリーン印刷版の製造方法を工程順に説明する。ちなみに、この製造方法により製造されるスクリーン印刷版は、積層セラミックコンデンサや積層セラミックインダクタ等の電子部品における導体層の作製工程にて、スクリーン印刷法によって導体ペースト印刷を行う際に有用なものである。 Hereinafter, a method for manufacturing a screen printing plate to which the present invention is applied will be described in order of steps with reference to FIGS. 1 to 9. By the way, the screen printing plate manufactured by this manufacturing method is useful for performing conductor paste printing by the screen printing method in the process of manufacturing the conductor layer in electronic parts such as multilayer ceramic capacitors and multilayer ceramic inductors. ..

《印刷版本体10の作製工程:図1を参照》
図1(B)に示した印刷版本体10を作製するときには、図1(A)に示したように、外形が矩形状を成す金属メッシュ11を用意し、その外周部分に、外形が矩形枠状を成す補助メッシュ12の内周部分を固着する。図示を省略したが、金属メッシュ11と補助メッシュ12との固着には、高い接着強度が得られる接着剤、好ましくは紫外線硬化型接着剤やシアノアクリレート系接着剤等の接着剤が使用できる。
<< Manufacturing process of printing plate main body 10: See FIG. 1 >>
When manufacturing the printing plate main body 10 shown in FIG. 1 (B), as shown in FIG. 1 (A), a metal mesh 11 having a rectangular outer shape is prepared, and a frame having a rectangular outer shape is provided on the outer peripheral portion thereof. The inner peripheral portion of the auxiliary mesh 12 forming the shape is fixed. Although not shown, an adhesive capable of obtaining high adhesive strength, preferably an adhesive such as an ultraviolet curable adhesive or a cyanoacrylate adhesive, can be used for fixing the metal mesh 11 and the auxiliary mesh 12.

金属メッシュ11は、ステンレスやタングステン等の金属線を格子状に編み込んで構成されており、多数の孔を有している。ちなみに、金属メッシュ11の厚さt2(図7(A)を参照)は好ましくは15〜30μmであり、オープニングは好ましくは20〜35μmである。 The metal mesh 11 is formed by weaving metal wires such as stainless steel and tungsten in a grid pattern, and has a large number of holes. Incidentally, the thickness t2 of the metal mesh 11 (see FIG. 7A) is preferably 15 to 30 μm, and the opening is preferably 20 to 35 μm.

なお、図7(A)に示した金属メッシュ11はカレンダー加工が施されたものであるため、厚さ方向両面の金属線が交差する箇所に平面が形成されている。このカレンダー加工は、金属メッシュ11の厚さt2を小さくすることを主たる目的とした工法であるが、金属メッシュ11に線径が小さな金属線が用いられていてその厚さt2が前記数値範囲内にある場合にはカレンダー加工は必ずしも必要なものではない。 Since the metal mesh 11 shown in FIG. 7A has been subjected to calendar processing, a flat surface is formed at a portion where the metal wires on both sides in the thickness direction intersect. This calendar processing is a construction method whose main purpose is to reduce the thickness t2 of the metal mesh 11, but a metal wire having a small wire diameter is used for the metal mesh 11, and the thickness t2 is within the above numerical range. If it is in, calendar processing is not always necessary.

補助メッシュ12は、ポリエステルやポリアリレート等の合成樹脂線を格子状に編み込んで構成されており、多数の孔を有している。この補助メッシュ12は金属メッシュ11に張力を付与する役目を果たすものであるため、その厚さに特段の制限はない。 The auxiliary mesh 12 is formed by weaving synthetic resin wires such as polyester and polyarylate in a grid pattern, and has a large number of holes. Since the auxiliary mesh 12 serves to apply tension to the metal mesh 11, there is no particular limitation on its thickness.

そして、図1(B)に示したように、外形が矩形枠状を成す版枠13を用意し、その下面に、図1(A)に示した補助メッシュ12の外周部分を外方に引っ張りながら固着する。図示を省略したが、補助メッシュ12と版枠13との固着には、高い接着強度が得られる接着剤、好ましくは紫外線硬化型接着剤やシアノアクリレート系接着剤等の接着剤が使用できる。 Then, as shown in FIG. 1 (B), a plate frame 13 having a rectangular outer shape is prepared, and the outer peripheral portion of the auxiliary mesh 12 shown in FIG. 1 (A) is pulled outward on the lower surface thereof. While sticking. Although not shown, an adhesive capable of obtaining high adhesive strength, preferably an adhesive such as an ultraviolet curable adhesive or a cyanoacrylate adhesive, can be used for fixing the auxiliary mesh 12 to the plate frame 13.

版枠13は、ステンレスやアルミニウム合金等の金属から成る。この版枠13は、金属メッシュ11および補助メッシュ12を支持する役目を果たすものであり、前記張力によって変形しない剛性を有していれば、その断面形状および断面積に特段の制限はない。 The plate frame 13 is made of a metal such as stainless steel or an aluminum alloy. The plate frame 13 serves to support the metal mesh 11 and the auxiliary mesh 12, and as long as it has rigidity that does not deform due to the tension, there are no particular restrictions on its cross-sectional shape and cross-sectional area.

なお、図1には、印刷版本体10として補助メッシュ12を有するものを示したが、補助メッシュ12は必ずしも必要なものではなく、サイズが大きな金属メッシュ11を用意して、その外周部分を版枠13に直接固着してもよい。 Although FIG. 1 shows a printing plate main body 10 having an auxiliary mesh 12, the auxiliary mesh 12 is not always necessary, and a metal mesh 11 having a large size is prepared and the outer peripheral portion thereof is used as a plate. It may be directly fixed to the frame 13.

《母型20の作製工程:図2を参照》
図2(B)に示した母型20を作製するときには、図2(A)に示したように、外形が矩形状を成す金属基板21を用意し、その外面21aに研磨処理と洗浄処理を施す。研磨処理には電解研磨やバフ研磨を好ましく使用でき、洗浄処理にはアルカリ脱脂洗浄や電解洗浄を好ましく使用できる。
<< Manufacturing process of mother mold 20: See Fig. 2 >>
When producing the master mold 20 shown in FIG. 2 (B), as shown in FIG. 2 (A), a metal substrate 21 having a rectangular outer shape is prepared, and the outer surface 21a is subjected to polishing and cleaning treatments. Give. Electrolytic polishing and buffing can be preferably used for the polishing treatment, and alkaline degreasing cleaning and electrolytic cleaning can be preferably used for the cleaning treatment.

金属基板21は、ステンレス等の金属から成る。この金属基板21の外面21aの外形は、図1(B)に示した金属メッシュ11の露出部分の外形よりも僅かに小さい。この金属基板21は母型20の主体となるものであり、後記密着によって変形しない剛性を有していれば、その厚さに特段の制限はない。 The metal substrate 21 is made of a metal such as stainless steel. The outer shape of the outer surface 21a of the metal substrate 21 is slightly smaller than the outer shape of the exposed portion of the metal mesh 11 shown in FIG. 1 (B). The metal substrate 21 is the main body of the master mold 20, and its thickness is not particularly limited as long as it has rigidity that does not deform due to close contact, which will be described later.

そして、図2(B)に示したように、金属基板21の外面21aに、後記金属マスク部31の開口部31a(図8を参照)に対応する絶縁体凸部22を一体的に形成する。後記金属マスク部31が多数の開口部31aを有する場合には、これら開口部31aと同数および同配列の絶縁体凸部22を金属基板21の外面21aに形成する。 Then, as shown in FIG. 2B, the insulator convex portion 22 corresponding to the opening portion 31a (see FIG. 8) of the metal mask portion 31 described later is integrally formed on the outer surface 21a of the metal substrate 21. .. When the metal mask portion 31 has a large number of openings 31a, the same number and arrangement of the insulator convex portions 22 as those openings 31a are formed on the outer surface 21a of the metal substrate 21.

絶縁体凸部22は、絶縁体材料、好ましくは酸化アルミニウムや二酸化ケイ素や窒化アルミニウム等の絶縁性セラミック材料から成る。勿論、絶縁体材料には、絶縁性セラミック材料の他、シリコンカーバイトやダイヤモンドライクカーボン等の絶縁性を有する材料も使用可能である。ちなみに、絶縁体凸部22の厚さ(符号省略)は好ましくは0.3〜4μmであり、この厚さは、後記電着金属箔EF1の厚さt1(図4(B)を参照)に相当する。また、絶縁体凸部22を図2(B)の上から見たときの外形は、後記金属マスク部31の開口部31aを図8の下から見たときの外形に対応している。例えば、開口部31aを図8の下から見たときの外形が矩形状の場合には、絶縁体凸部22を図2(B)の上から見たときの外形はこれに対応した矩形状である。勿論、絶縁体凸部22を図2(B)の上から見たときの外形には、矩形以外の種々の形状が採用できることは言うまでもない。 The insulator convex portion 22 is made of an insulator material, preferably an insulating ceramic material such as aluminum oxide, silicon dioxide, or aluminum nitride. Of course, as the insulator material, in addition to the insulating ceramic material, a material having an insulating property such as silicon carbide or diamond-like carbon can also be used. Incidentally, the thickness (reference numeral omitted) of the insulator convex portion 22 is preferably 0.3 to 4 μm, and this thickness is referred to the thickness t1 of the electrodeposited metal leaf EF1 described later (see FIG. 4 (B)). Equivalent to. Further, the outer shape of the insulator convex portion 22 when viewed from above in FIG. 2B corresponds to the outer shape when the opening 31a of the metal mask portion 31 described later is viewed from below in FIG. For example, when the outer shape of the opening 31a when viewed from the bottom of FIG. 8 is rectangular, the outer shape of the insulator convex portion 22 when viewed from above of FIG. 2B has a corresponding rectangular shape. Is. Of course, it goes without saying that various shapes other than the rectangle can be adopted as the outer shape of the insulator convex portion 22 when viewed from above in FIG. 2 (B).

ここで、絶縁性セラミック材料から成る多数の絶縁体凸部22を金属基板21の外面21aに一体的に形成する方法を紹介する。 Here, a method of integrally forming a large number of insulating convex portions 22 made of an insulating ceramic material on the outer surface 21a of the metal substrate 21 will be introduced.

〈第1の方法〉まず、金属基板21の外面21aに、市販のネガ型のフォトレジストシートを貼り付けるか、あるいは、市販のポジ型またはネガ型のフォトレジスト剤を塗工した後、フォトリソグラフィ法によって不必要部分を排除して、多数の絶縁体凸部22に対応した多数の凹部を有するレジストパターンを形成する。続いて、真空蒸着やイオンプレーティングやスパッタリング等の物理気相成長法(PVD法)、あるいは、プラズマCVDや熱CVDや光CVD等の化学気相成長法(CVD法)によって、レジストパターンの多数の凹部内に絶縁性セラミック材料を所望の厚さまで堆積させる。続いて、レジストパターンを金属基板21の外面21aから剥離し取り除いて、多数の絶縁体凸部22のみを金属基板21の外面21aに残存させる。 <First Method> First, a commercially available negative photoresist sheet is attached to the outer surface 21a of the metal substrate 21, or a commercially available positive or negative photoresist agent is applied, and then photolithography is performed. By the method, unnecessary portions are eliminated to form a resist pattern having a large number of concave portions corresponding to a large number of insulating convex portions 22. Subsequently, a large number of resist patterns are formed by a physical vapor deposition method (PVD method) such as vacuum deposition, ion plating, or sputtering, or a chemical vapor deposition method (CVD method) such as plasma CVD, thermal CVD, or optical CVD. Insulating ceramic material is deposited to the desired thickness in the recesses of the. Subsequently, the resist pattern is peeled off from the outer surface 21a of the metal substrate 21 and removed, leaving only a large number of insulator convex portions 22 on the outer surface 21a of the metal substrate 21.

〈第2の方法〉まず、金属基板21の外面21aに、予め用意したマスクシートを貼り付ける。このマスクシートは、多数の絶縁体凸部22に対応した多数の孔を有する。続いて、第1の方法と同様に、物理気相成長法(PVD法)、あるいは、化学気相成長法(CVD法)によって、マスクシートの多数の孔内に絶縁性セラミック材料を所望の厚さまで堆積させる。続いて、マスクシートを金属基板21の外面21aから剥離し取り除いて、多数の絶縁体凸部22のみを金属基板21の外面21aに残存させる。 <Second Method> First, a mask sheet prepared in advance is attached to the outer surface 21a of the metal substrate 21. This mask sheet has a large number of holes corresponding to a large number of insulator protrusions 22. Subsequently, as in the first method, an insulating ceramic material is formed in a large number of holes in the mask sheet by a physical vapor deposition method (PVD method) or a chemical vapor deposition method (CVD method) to obtain a desired thickness. Accumulate until now. Subsequently, the mask sheet is peeled off from the outer surface 21a of the metal substrate 21 and removed so that only a large number of insulator convex portions 22 remain on the outer surface 21a of the metal substrate 21.

《第1の電気鋳造工程:図3および図4を参照》
先に説明した母型20を、図3に示したように、浴液とアノードが収容された浴槽(図示省略)内に入れ、母型20の金属基板21をカソードとして第1の電気鋳造を行う。
<< First electroforming process: see FIGS. 3 and 4 >>
As shown in FIG. 3, the master mold 20 described above is placed in a bathtub (not shown) containing a bath liquid and an anode, and the first electroplating is performed using the metal substrate 21 of the master mold 20 as a cathode. conduct.

第1の電気鋳造を行うときの浴液には、ワット浴やスルファミン酸ニッケル浴やスルファミン酸塩化ニッケル浴等が好ましく使用できる。また、アノードには、ニッケル片またはニッケル粒を入れたチタン製の網状バックや、ニッケル片またはニッケル粒とチタン製の通電ロッドとを入れたポリプロピレン製の網状バック等が好ましく使用できる。さらに、第1の電気鋳造を行うときの電解条件は、ワット浴とスルファミン酸ニッケル浴の場合は、好ましくは、浴温が40〜60℃、アノードおよびカソードの電流密度が1〜4A/dm、電解時間が0.6〜20分である。また、スルファミン酸塩化ニッケル浴の場合は、好ましくは、浴温が25〜70℃、アノードおよびカソードの電流密度が1〜5A/dm、電解時間が0.5〜20分である。 As the bath liquid for performing the first electroforming, a watt bath, a nickel sulfamate bath, a nickel sulfamate bath, or the like can be preferably used. Further, as the anode, a titanium mesh bag containing nickel pieces or nickel grains, a polypropylene mesh bag containing nickel pieces or nickel grains and a titanium energizing rod, or the like can be preferably used. Further, the electrolytic conditions for performing the first electroforming are preferably a bath temperature of 40 to 60 ° C. and an anode and cathode current densities of 1 to 4 A / dm 2 in the case of a watt bath and a nickel sulfamate bath. , The electrolysis time is 0.6 to 20 minutes. In the case of a sulfamate nickel bath, the bath temperature is preferably 25 to 70 ° C., the current densities of the anode and cathode are 1 to 5 A / dm 2 , and the electrolysis time is 0.5 to 20 minutes.

第1の電気鋳造の開始段階では、図4(A)に示したように、金属基板21の絶縁体凸部22が存しない外面領域21a1には、絶縁体凸部22の厚さに相当する凹み(符号省略)がある。第1の電気鋳造の終了段階では、図4(B)に示したように、金属基板21の絶縁体凸部22が存しない外面領域21a1に、厚さt1の電着金属箔EF1が形成される。ちなみに、図4(B)には、電着金属箔EF1をその厚さt1が絶縁体凸部22の厚さと略一致するように形成したものであるため、電着金属箔EF1の厚さt1は絶縁体凸部22の厚さ(好ましくは0.3〜4μm)に相当する。 At the start stage of the first electroplating, as shown in FIG. 4A, the outer surface region 21a1 of the metal substrate 21 in which the insulator convex portion 22 does not exist corresponds to the thickness of the insulator convex portion 22. There is a dent (sign omitted). At the final stage of the first electroplating, as shown in FIG. 4B, an electrodeposited metal foil EF1 having a thickness of t1 is formed in the outer surface region 21a1 in which the insulator convex portion 22 of the metal substrate 21 does not exist. NS. Incidentally, in FIG. 4B, since the electrodeposited metal foil EF1 is formed so that the thickness t1 thereof substantially matches the thickness of the insulator convex portion 22, the thickness t1 of the electrodeposited metal foil EF1. Corresponds to the thickness of the insulator convex portion 22 (preferably 0.3 to 4 μm).

《印刷版本体10の金属メッシュ11を母型20の電着金属箔EF1に密着させる工程:図5を参照》
先に説明した印刷版本体10と母型20を用意し、図5に示したように、母型20の電着金属箔EF1の外面(符号省略)に印刷版本体10の金属メッシュ11を相対的に押し付けて、電着金属箔EF1の外面に金属メッシュ11を密着させる。電着金属箔EF1の厚さt1(図4(B)を参照)が絶縁体凸部22の厚さと略一致している場合には、金属メッシュ11は絶縁体凸部22の外面22aにも密着する。電着金属箔EF1の数が多い場合、押し付け力が小さいと十分な密着が得られず、逆に押し付け力が強すぎると金属メッシュ11が変形して部分的に隙間を生じる虞があるため、試行を繰り返して最適な押し付け力を定めることが好ましい。電着金属箔EF1の外面に金属メッシュ11を密着させた後は、金属基板21の外面21aとは反対側の外面から版枠13に向けて掛け渡した図示省略のテープ等の保持具によって、前記密着状態を保持する。
<< Step of bringing the metal mesh 11 of the printing plate body 10 into close contact with the electrodeposited metal foil EF1 of the master mold 20: see FIG. 5 >>
The printing plate main body 10 and the master mold 20 described above are prepared, and as shown in FIG. 5, the metal mesh 11 of the printing plate main body 10 is relative to the outer surface (reference numeral omitted) of the electrodeposited metal foil EF1 of the master mold 20. The metal mesh 11 is brought into close contact with the outer surface of the electrodeposited metal foil EF1. When the thickness t1 of the electrodeposited metal foil EF1 (see FIG. 4B) is substantially the same as the thickness of the insulator convex portion 22, the metal mesh 11 is also applied to the outer surface 22a of the insulator convex portion 22. In close contact. When the number of electrodeposited metal foils EF1 is large, sufficient adhesion cannot be obtained if the pressing force is small, and conversely, if the pressing force is too strong, the metal mesh 11 may be deformed to partially create a gap. It is preferable to repeat the trial to determine the optimum pressing force. After the metal mesh 11 is brought into close contact with the outer surface of the electrodeposited metal foil EF1, a holder such as a tape (not shown) hung from the outer surface opposite to the outer surface 21a of the metal substrate 21 toward the plate frame 13 is used. The close contact state is maintained.

《第2の電気鋳造工程:図6および図7を参照》
先に説明した印刷版本体10と母型20との密着物(符号省略)を、図6に示したように、浴液とアノードが収容された浴槽(図示省略)内に入れ、母型20の金属基板21をカソードとして第2の電気鋳造を行う。
<< Second electroforming process: see FIGS. 6 and 7 >>
As shown in FIG. 6, the contact object (reference numeral omitted) between the printing plate main body 10 and the master mold 20 described above is placed in a bathtub (not shown) containing the bath liquid and the anode, and the master mold 20 is placed. The second electroforming is performed using the metal substrate 21 of the above as a cathode.

第2の電気鋳造を行うときの浴液には、ワット浴やスルファミン酸ニッケル浴やスルファミン酸塩化ニッケル浴等が好ましく使用できる。また、アノードには、ニッケル片またはニッケル粒を入れたチタン製の網状バックや、ニッケル片またはニッケル粒とチタン製の通電ロッドとを入れたポリプロピレン製の網状バック等が好ましく使用できる。さらに、第2の電気鋳造を行うときの電解条件は、ワット浴とスルファミン酸ニッケル浴の場合は、好ましくは、浴温が40〜60℃、アノードおよびカソードの電流密度が0.3〜0.5A/dm、電解時間が5〜30分である。また、スルファミン酸塩化ニッケル浴の場合は、好ましくは、浴温が25〜70℃、アノードおよびカソードの電流密度が0.3〜0.5A/dm、電解時間が5〜30分である。 As the bath liquid for performing the second electroforming, a watt bath, a nickel sulfamate bath, a nickel sulfamate bath, or the like can be preferably used. Further, as the anode, a titanium mesh bag containing nickel pieces or nickel grains, a polypropylene mesh bag containing nickel pieces or nickel grains and a titanium energizing rod, or the like can be preferably used. Further, the electrolytic conditions for performing the second electroforming are preferably a bath temperature of 40 to 60 ° C. and an anode and cathode current densities of 0.3 to 0 in the case of a watt bath and a nickel sulfamate bath. 5 A / dm 2 , electrolysis time is 5 to 30 minutes. In the case of a sulfamate nickel bath, the bath temperature is preferably 25 to 70 ° C., the current densities of the anode and cathode are 0.3 to 0.5 A / dm 2 , and the electrolysis time is 5 to 30 minutes.

第2の電気鋳造の開始段階では、図7(A)に示したように、電着金属箔EF1の外面(符号省略)に金属メッシュ11の下面が密着している。図7(A)に示した電着金属箔EF1の厚さt1(図4(B)を参照)が絶縁体凸部22の厚さと略一致している場合には、金属メッシュ11の下面は絶縁体凸部22の外面22aにも密着する。第2の電気鋳造の終了段階では、図7(B)に示したように、金属メッシュ11の表面に電着金属膜EF2が形成されるとともに、電着金属箔EF1の近傍に形成される電着金属膜EF2の一部分によって、電着金属箔EF1が電着金属膜EF2に接合される。ちなみに、ここで形成される電着金属膜EF2の厚さ(符号省略)は好ましくは0.3〜2μmであり、電着金属膜EF2に接合される電着金属箔EF1の厚さt1は先に説明したとおりである。すなわち、第2の電気鋳造工程では、金属メッシュ11および電着金属膜EF2から成る金属メッシュ部32と、電着金属膜EF2と連続した電着金属箔EF1から成る金属マスク部31との一体化物30が作製される。 At the start stage of the second electroforming, as shown in FIG. 7A, the lower surface of the metal mesh 11 is in close contact with the outer surface (reference numeral omitted) of the electrodeposited metal foil EF1. When the thickness t1 of the electrodeposited metal foil EF1 shown in FIG. 7A (see FIG. 4B) substantially matches the thickness of the insulator convex portion 22, the lower surface of the metal mesh 11 is formed. It also adheres to the outer surface 22a of the insulator convex portion 22. At the final stage of the second electroforming, as shown in FIG. 7B, the electrodeposited metal film EF2 is formed on the surface of the metal mesh 11, and the electrodeposition metal film EF2 is formed in the vicinity of the electrodeposited metal foil EF1. The electrodeposited metal foil EF1 is bonded to the electrodeposited metal film EF2 by a part of the metal electrodeposition film EF2. Incidentally, the thickness (reference numeral omitted) of the electrodeposited metal film EF2 formed here is preferably 0.3 to 2 μm, and the thickness t1 of the electrodeposited metal foil EF1 bonded to the electrodeposited metal film EF2 is first. As explained in. That is, in the second electrocasting step, the metal mesh portion 32 made of the metal mesh 11 and the electrodeposited metal film EF2 and the metal mask portion 31 made of the electrodeposited metal film EF2 and the continuous electrodeposited metal foil EF1 are integrated. 30 is made.

《離型工程:図8を参照》
図7(B)に示した一体化物30を作製した後は、印刷版本体10と母型20との密着物を浴槽から取り出し、保持具を外して密着状態の保持を解除する。そして、図8に示したように、一体化物30の電着金属膜EF2を絶縁体凸部22の外面22aから剥離するとともに、電着金属箔EF1を金属基板21の絶縁体凸部22が存しない外面領域21a1から抜き出して、一体化物30を母型20から離型する。
<< Mold release process: see Fig. 8 >>
After producing the integrated product 30 shown in FIG. 7 (B), the material in close contact between the printing plate main body 10 and the mother mold 20 is taken out from the bathtub, and the holder is removed to release the holding of the product in the close contact state. Then, as shown in FIG. 8, the electrodeposited metal film EF2 of the integrated body 30 is peeled off from the outer surface 22a of the insulator convex portion 22, and the electrodeposited metal foil EF1 is present on the insulator convex portion 22 of the metal substrate 21. The integrated product 30 is separated from the master mold 20 by extracting it from the outer surface region 21a1.

この離型により、電着金属箔EF1から成る金属マスク部31に、絶縁体凸部22の厚さおよび外形に略合致した深さおよび内形を有する開口部31aが形成される。また、金属基板21の外面21aに対する絶縁体凸部22の結合力は、金属基板21の外面21aにフォトレジスト製凸部を形成した場合の結合力より遙かに高いため、一体化物30を母型20から離型するときに絶縁体凸部22が金属基板21の外面21aから取れてしまうことはない。 By this release, an opening 31a having a depth and an inner shape substantially matching the thickness and outer shape of the insulator convex portion 22 is formed in the metal mask portion 31 made of the electrodeposited metal foil EF1. Further, since the bonding force of the insulator convex portion 22 to the outer surface 21a of the metal substrate 21 is much higher than the bonding force when the photoresist-made convex portion is formed on the outer surface 21a of the metal substrate 21, the integrated body 30 is used as a mother. When the mold is released from the mold 20, the insulator convex portion 22 does not come off from the outer surface 21a of the metal substrate 21.

《仕上げ工程:図9を参照》
図8に示した離型が完了した後は、図9に示した金属メッシュ部32の外周部分、すなわち、スクリーン印刷に使用されない部分を乳剤部(図示省略)で覆うとともに、図9に示した補助メッシュ12の上面に例えば銀フィルム等の補強フィルム(図示省略)を貼り付けて補強を行う。
<< Finishing process: see Fig. 9 >>
After the mold release shown in FIG. 8 is completed, the outer peripheral portion of the metal mesh portion 32 shown in FIG. 9, that is, the portion not used for screen printing is covered with an emulsion portion (not shown) and shown in FIG. A reinforcing film (not shown) such as a silver film is attached to the upper surface of the auxiliary mesh 12 for reinforcement.

ここで、図3および図4を用いて説明した第1の電気鋳造工程の変形例について、図10を用いて説明する。図4(B)には絶縁体凸部22の厚さ(符号省略)と略一致する厚さt1の電着金属箔EF1を形成する方法を説明したが、絶縁体凸部22の厚さよりも電着金属箔EF1の厚さを大きくなるようにしてもよい。 Here, a modified example of the first electroforming process described with reference to FIGS. 3 and 4 will be described with reference to FIG. FIG. 4B describes a method of forming an electrodeposited metal leaf EF1 having a thickness t1 that substantially matches the thickness of the insulator convex portion 22 (reference numeral omitted), but it is larger than the thickness of the insulator convex portion 22. The thickness of the electrodeposited metal foil EF1 may be increased.

図10(A)は、絶縁体凸部22’の厚さを図4(B)に示した絶縁体凸部22の厚さよりも小さく形成することによって、この絶縁体凸部22’の厚さよりも電着金属箔EF1の厚さt1が大きくなるようにした方法を示す。このようにすると、図10(B)に示したように、電着金属箔EF1の外面(符号省略)に金属メッシュ11の下面を密着させたときに、金属メッシュ11の下面のうちの絶縁体凸部22の外面22aと向き合う部分と絶縁体凸部22の外面22aとの間に隙間が生じるため、この隙間を利用して、図10(C)に示したように、金属メッシュ11の前記部分にも及ぶような電着金属箔EF2’を第2の電気鋳造によって形成することができる。また、図10(D)に示したように、一体化物30を母型20から離型すれば、電着金属箔EF1から成る金属マスク部31に、絶縁体凸部22’の厚さおよび外形に略合致した深さおよび内形を有する開口部31a’を形成することができる。 FIG. 10A shows that the thickness of the insulator convex portion 22'is smaller than the thickness of the insulator convex portion 22 shown in FIG. 4B, so that the thickness of the insulator convex portion 22'is increased. Also shows a method in which the thickness t1 of the electrodeposited metal foil EF1 is increased. In this way, as shown in FIG. 10B, when the lower surface of the metal mesh 11 is brought into close contact with the outer surface (reference numeral omitted) of the electrodeposited metal foil EF1, the insulator of the lower surface of the metal mesh 11 Since a gap is generated between the portion of the convex portion 22 facing the outer surface 22a and the outer surface 22a of the insulator convex portion 22, as shown in FIG. 10 (C), the metal mesh 11 is said to have a gap. An electrodeposited metal foil EF2'that extends to a portion can be formed by a second electroplating. Further, as shown in FIG. 10 (D), when the integrated body 30 is released from the master mold 20, the thickness and outer shape of the insulator convex portion 22'are attached to the metal mask portion 31 made of the electrodeposited metal foil EF1. It is possible to form an opening 31a'with a depth and an internal shape that substantially matches.

図示を省略したが、絶縁体凸部22の厚さを変えずに電着金属箔EF1の厚さを大きくする方法でも、前記同様の電着金属箔EF2’を第2の電気鋳造によって形成することができる。また、前記隙間は、第2の電気鋳造によって金属メッシュ11の表面に形成される電着金属膜EF2’の厚さ以上とすることが好ましい。 Although not shown, a method of increasing the thickness of the electrodeposited metal leaf EF1 without changing the thickness of the insulator convex portion 22 also forms the same electrodeposited metal leaf EF2'by the second electroplating. be able to. Further, it is preferable that the gap is at least the thickness of the electrodeposited metal film EF2'formed on the surface of the metal mesh 11 by the second electroforming.

前述の製造方法では、(1)金属基板21の外面21aに、金属マスク部31の開口部31a(31a’)に対応する絶縁体凸部22(22’)が一体形成された母型20を作製し、(2)1回目の電気鋳造により、金属基板21の絶縁体凸部22(22’)が存しない外面領域21a1に電着金属箔EF1を形成し、(3)母型20の電着金属箔EF1の外面に金属メッシュ11を密着させた状態で、2回目の電気鋳造により、金属メッシュ11の表面に電着金属膜EF2(EF2’)を形成し、かつ、電着金属膜EF2(EF2’)の一部分に電着金属箔EF1を接合して、金属メッシュ11および電着金属膜EF2(EF2’)から成る金属メッシュ部32と電着金属箔EF1から成る金属マスク部31との一体化物30を作製し、(4)一体化物30の電着金属膜EF2(EF2’)を絶縁体凸部22(22’)の外面22aから剥離し、かつ、電着金属箔EF1を金属基板21の絶縁体凸部22(22’)が存しない外面領域21a1から抜き出して、絶縁体凸部22(22’)を金属基板21の外面21aに残存させたまま一体化物30を母型20から離型している。 In the above-mentioned manufacturing method, (1) a master mold 20 in which an insulator convex portion 22 (22') corresponding to an opening 31a (31a') of a metal mask portion 31 is integrally formed on an outer surface 21a of a metal substrate 21 is formed. By (2) the first electric casting, the electrodeposited metal foil EF1 is formed in the outer surface region 21a1 in which the insulator convex portion 22 (22') of the metal substrate 21 does not exist, and (3) the electric metal of the master mold 20 is formed. The electrodeposited metal film EF2 (EF2') is formed on the surface of the metal mesh 11 by the second electric casting with the metal mesh 11 in close contact with the outer surface of the metallized foil EF1, and the electrodeposited metal film EF2 An electrodeposited metal foil EF1 is joined to a part of (EF2'), and a metal mesh portion 32 made of a metal mesh 11 and an electrodeposited metal film EF2 (EF2') and a metal mask portion 31 made of an electrodeposited metal foil EF1 are attached. The integrated material 30 is produced, (4) the electrodeposited metal film EF2 (EF2') of the integrated material 30 is peeled off from the outer surface 22a of the insulator convex portion 22 (22'), and the electrodeposited metal foil EF1 is attached to the metal substrate. The integrated body 30 is removed from the master mold 20 while the insulator convex portion 22 (22') of the metal substrate 21 is extracted from the outer surface region 21a1 where the insulator convex portion 22 (22') does not exist, and the insulator convex portion 22 (22') remains on the outer surface 21a of the metal substrate 21. It is released from the mold.

すなわち、金属基板21の外面21aに絶縁体凸部22(22’)が一体形成された母型20を用いることによって、金属メッシュ11および電着金属膜EF2(EF2’)から成る金属メッシュ部32と電着金属箔EF1から成る金属マスク部31とを一体に備えたスクリーン印刷版を簡易な方法で、かつ、的確に製造することができる。 That is, by using the master mold 20 in which the insulator convex portion 22 (22') is integrally formed on the outer surface 21a of the metal substrate 21, the metal mesh portion 32 composed of the metal mesh 11 and the electrodeposited metal film EF2 (EF2'). A screen printing plate including the metal mask portion 31 composed of the electrodeposited metal foil EF1 and the metal mask portion 31 integrally can be manufactured by a simple method and accurately.

また、金属メッシュ部32と金属マスク部31との一体化物30を母型20から離型しても、絶縁体凸部22(22’)が金属基板21の外面21aから取れてしまうことがないため、母型20を繰り返し使用して同一形態のスクリーン印刷版を製造することができる。つまり、この点においても、スクリーン印刷版を製造が簡易化される。 Further, even if the integrated body 30 of the metal mesh portion 32 and the metal mask portion 31 is separated from the master mold 20, the insulator convex portion 22 (22') is not removed from the outer surface 21a of the metal substrate 21. Therefore, the master mold 20 can be repeatedly used to manufacture a screen-printed plate having the same shape. That is, also in this respect, the production of the screen printing plate is simplified.

さらに、1回目の電気鋳造において形成される電着金属箔EF1の厚さt1を、絶縁体凸部22の厚さと略一致するように形成するか、あるいは、絶縁体凸部22’の厚さよりも大きくなるように形成することにより、2回目の電気鋳造において金属メッシュ11の表面に形成される電着金属膜EF2(EF2’)の態様、詳しくは金属メッシュ11の下面のうちの絶縁体凸部22の外面22aと向き合う部分における態様を簡単に変化させることができる。 Further, the thickness t1 of the electrodeposited metal foil EF1 formed in the first electroforming is formed so as to substantially match the thickness of the insulator convex portion 22, or is more than the thickness of the insulator convex portion 22'. The aspect of the electrodeposited metal film EF2 (EF2') formed on the surface of the metal mesh 11 in the second electroforming by forming the metal mesh 11 so as to be large, specifically, the insulator convex on the lower surface of the metal mesh 11. The mode of the portion of the portion 22 facing the outer surface 22a can be easily changed.

さらに、金属マスク部31の開口部31a(31a’)の深さおよび内形を、母型20の絶縁体凸部22の厚さおよび外形によって調整できるため、金属マスク部31の開口部31a(31a’)の深さおよび内形の管理が極めて容易であるとともに、所望深さおよび内形の開口部31a(31a’)を金属マスク部31に精度良く形成することができる。 Further, since the depth and inner shape of the opening 31a (31a') of the metal mask portion 31 can be adjusted by adjusting the thickness and outer shape of the insulator convex portion 22 of the master mold 20, the opening 31a of the metal mask portion 31 ( The depth and inner shape of 31a') can be controlled extremely easily, and the desired depth and inner shape of the opening 31a (31a') can be accurately formed in the metal mask portion 31.

10…印刷版本体、11…金属メッシュ、12…補助メッシュ、13…版枠、20…母型、21…金属基板、21a…金属基板の外面、21a1…金属基板の絶縁体凸部が存しない外面領域、22,22’…絶縁体凸部、22a…絶縁体凸部の外面、30…金属メッシュ部と金属マスク部との一体化物、31…金属マスク部、31a,31a’…開口部、EF1…電着金属箔、32…金属メッシュ部、EF2,EF2’…電着金属膜。 10 ... Printing plate body, 11 ... Metal mesh, 12 ... Auxiliary mesh, 13 ... Plate frame, 20 ... Mother mold, 21 ... Metal substrate, 21a ... Outer surface of metal substrate, 21a1 ... Insulator convex part of metal substrate does not exist Outer surface region, 22, 22'... insulator convex portion, 22a ... outer surface of insulator convex portion, 30 ... integral body of metal mesh portion and metal mask portion, 31 ... metal mask portion, 31a, 31a'... opening, EF1 ... Electroplated metal foil, 32 ... Metal mesh part, EF2, EF2'... Electroplated metal film.

Claims (5)

金属メッシュ部と、開口部を有する金属マスク部とを一体に備えたスクリーン印刷版の製造方法であって、
金属基板の外面に前記開口部に対応する絶縁体凸部が一体形成された母型を作製する工程と、
1回目の電気鋳造により、前記母型の前記金属基板の前記絶縁体凸部が存しない外面領域に電着金属箔を形成する工程と、
前記母型の前記電着金属箔の外面に金属メッシュを密着させた状態で、2回目の電気鋳造により、前記金属メッシュの表面に電着金属膜を形成し、かつ、前記電着金属膜の一部分に前記電着金属箔を接合して、前記金属メッシュおよび前記電着金属膜から成る前記金属メッシュ部と前記電着金属箔から成る前記金属マスク部との一体化物を作製する工程と、
前記一体化物の前記電着金属膜を前記絶縁体凸部の外面から剥離し、かつ、前記電着金属箔を前記金属基板の前記絶縁体凸部が存しない外面領域から抜き出して、前記絶縁体凸部を前記金属基板の外面に残存させたまま前記一体化物を前記母型から離型する工程とを備え、
前記1回目の電気鋳造において、前記電着金属箔の厚さを前記絶縁体凸部の厚さよりも大きくなるように形成する、
スクリーン印刷版の製造方法。
A method for manufacturing a screen printing plate in which a metal mesh portion and a metal mask portion having an opening are integrally provided.
A step of producing a master mold in which an insulator convex portion corresponding to the opening is integrally formed on the outer surface of the metal substrate, and
A step of forming an electrodeposited metal foil on an outer surface region of the metal substrate of the master mold in which the insulator convex portion does not exist by the first electroforming.
With the metal mesh in close contact with the outer surface of the electrodeposited metal foil of the master mold, an electrodeposited metal film is formed on the surface of the metal mesh by the second electric casting, and the electrodeposited metal film is formed. A step of joining the electrodeposited metal foil to a part thereof to prepare an integrated product of the metal mesh portion made of the metal mesh and the electrodeposited metal film and the metal mask portion made of the electrodeposited metal foil.
The electrodeposited metal film of the integrated product is peeled off from the outer surface of the convex portion of the insulator, and the electrodeposited metal foil is extracted from the outer surface region of the metal substrate where the convex portion of the insulator does not exist, so that the insulator A step of removing the integrated product from the master mold while leaving the convex portion on the outer surface of the metal substrate is provided.
In the first electrocasting, the electrodeposited metal foil is formed so as to be larger than the thickness of the convex portion of the insulator.
How to make a screen printing plate.
前記金属マスク部の前記開口部の深さおよび内形を、前記絶縁体凸部の厚さおよび外形によって調整する、
請求項1に記載のスクリーン印刷版の製造方法。
The depth and inner shape of the opening of the metal mask portion are adjusted by the thickness and outer shape of the convex portion of the insulator.
The method for manufacturing a screen printing plate according to claim 1.
前記絶縁体凸部を、絶縁体材料を用いて物理気相成長法によって形成する、
請求項1または2に記載のスクリーン印刷版の製造方法。
The insulator convex portion is formed by a physical vapor deposition method using an insulator material.
The method for manufacturing a screen printing plate according to claim 1 or 2.
前記絶縁体凸部を、絶縁体材料を用いて化学気相成長法によって形成する、
請求項1〜3のいずれか1項に記載のスクリーン印刷版の製造方法。
The insulator convex portion is formed by a chemical vapor deposition method using an insulator material.
The method for manufacturing a screen printing plate according to any one of claims 1 to 3.
前記絶縁体材料として絶縁性セラミック材料を用いる、
請求項3または4に記載のスクリーン印刷版の製造方法。
An insulating ceramic material is used as the insulator material.
The method for manufacturing a screen printing plate according to claim 3 or 4.
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