JP6930863B2 - Cleaning composition - Google Patents
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- JP6930863B2 JP6930863B2 JP2017114633A JP2017114633A JP6930863B2 JP 6930863 B2 JP6930863 B2 JP 6930863B2 JP 2017114633 A JP2017114633 A JP 2017114633A JP 2017114633 A JP2017114633 A JP 2017114633A JP 6930863 B2 JP6930863 B2 JP 6930863B2
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- 239000000203 mixture Substances 0.000 title claims description 14
- 238000004140 cleaning Methods 0.000 title claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 18
- 229930195729 fatty acid Natural products 0.000 claims description 18
- 239000000194 fatty acid Substances 0.000 claims description 18
- -1 fatty acid salt Chemical class 0.000 claims description 17
- 239000000839 emulsion Substances 0.000 claims description 7
- 229930182478 glucoside Natural products 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 238000005187 foaming Methods 0.000 description 7
- 230000003020 moisturizing effect Effects 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004475 Arginine Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940100573 methylpropanediol Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、洗浄料組成物に関する。 The present invention relates to a cleaning composition.
従来より、洗浄料として、種々の商品が開発されており、特に高級脂肪酸塩を基剤とするものは、洗浄力に優れ、泡立ちが良く、さっぱりとした感触があるため、洗顔料や全身洗浄料等に用いられている。しかし、その強力な洗浄力により、皮膚に必要な皮脂等まで落としてしまい、洗浄後に肌がかさつき、つっぱるといった問題が生じている。 Conventionally, various products have been developed as cleaning agents, and in particular, those based on higher fatty acid salts have excellent detergency, good foaming, and a refreshing feel, so they are used for washing pigments and whole body cleaning. It is used for fees. However, due to its strong detergency, even sebum and the like necessary for the skin are removed, causing problems such as the skin becoming dry and taut after cleaning.
洗浄後の肌のかさつきや、つっぱり感の改善のために、ジグリセリンのポリオキシプロピレン付加物と併用した例（特許文献１）、植物エキスと併用した例（特許文献２）があるが、いずれも効果が不十分で、問題を解決するには、至っていない。 In order to improve the dryness and tightness of the skin after washing, there are cases in which it is used in combination with a polyoxypropylene adduct of diglycerin (Patent Document 1) and in combination with a plant extract (Patent Document 2). However, the effect is insufficient and the problem has not been solved yet.
本発明は、脂肪酸塩を基剤とするにもかかわらず、泡質が良好で、保湿感を有する洗浄料組成物を提供することを課題とする。 An object of the present invention is to provide a cleaning composition having a good foam quality and a moisturizing sensation despite using a fatty acid salt as a base.
本発明は、下記の（Ａ）〜（Ｃ）を含有する洗浄料組成物を提供する。
（Ａ）高級脂肪酸塩
（Ｂ）メタクリル酸とエチルアクリレートとの架橋コポリマーのエマルション
（Ｃ）グリセリルグルコシド
The present invention provides a cleaning composition containing the following (A) to (C).
(A) Higher fatty acid salt (B) Emulsion of crosslinked copolymer of methacrylic acid and ethyl acrylate (C) Glyceryl glucoside
本発明の洗浄料組成物は、泡立ち、洗浄力、泡質が良好で、保湿感を有しながらもさっぱり感を有するという効果を発揮する。 The cleaning agent composition of the present invention has good foaming, detergency, and foam quality, and exhibits the effects of having a moisturizing feeling and a refreshing feeling.
以下本発明を実施するための形態を説明する。 Hereinafter, embodiments for carrying out the present invention will be described.
本発明で用いる高級脂肪酸塩を構成する高級脂肪酸としては、飽和若しくは不飽和のいずれであってもよく、炭素数８〜２４、特に１０〜２２のものが好ましい。これらの脂肪酸の中でも直鎖飽和脂肪酸を用いることが、好ましい。好ましいものの具体例としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ヤシ油脂肪酸、還元ヤシ油脂肪酸、パーム核脂肪酸などが挙げられる。これらの脂肪酸の中でも、泡立ち、安全性、安定性の面から、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸から選択される１種又は２種以上を含有することが好ましく、特にラウリン酸とミリスチン酸とパルミチン酸の３種を用いることが好ましい。これらの高級脂肪酸と塩を形成するアルカリ剤としては、ナトリウム、カリウムなどのアルカリ金属塩、アンモニウム塩、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、２−アミノ−２−メチルプロパノール、２−アミノ−２−メチルプロパンジオールなどのアルカノールアミン塩、リジン、アルギニンなどの塩基性アミノ酸塩等が挙げられる。これらのうち、特にカリウム、アルギニンが好ましい。 The higher fatty acid constituting the higher fatty acid salt used in the present invention may be saturated or unsaturated, and has 8 to 24 carbon atoms, particularly preferably 10 to 22 carbon atoms. Among these fatty acids, it is preferable to use linear saturated fatty acids. Specific examples of preferable ones include lauric acid, myristic acid, palmitic acid, stearic acid, coconut oil fatty acid, reduced coconut oil fatty acid, palm kernel fatty acid and the like. Among these fatty acids, it is preferable to contain one or more selected from lauric acid, myristic acid, palmitic acid, and stearic acid from the viewpoint of foaming, safety, and stability, and particularly lauric acid and myristic acid. It is preferable to use three kinds of acid and palmitic acid. Examples of the alkaline agent forming a salt with these higher fatty acids include alkali metal salts such as sodium and potassium, ammonium salts, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, and 2-amino-2. − Examples include alkanolamine salts such as methylpropanediol and basic amino acid salts such as lysine and arginine. Of these, potassium and arginine are particularly preferable.
また、これらの高級脂肪酸塩は、必ずしも脂肪酸塩として洗浄料組成物に配合する必要はなく、上記高級脂肪酸と塩基とをそれぞれ別個に添加し、組成物中で脂肪酸塩を形成させてもよい。 Further, these higher fatty acid salts do not necessarily have to be added to the cleaning composition as fatty acid salts, and the higher fatty acids and bases may be added separately to form fatty acid salts in the composition.
高級脂肪酸塩の配合量は、１５〜２５質量％が好ましい。１５質量％未満の配合では十分な洗浄力が得られない場合がある。２５質量％を超えて配合すると、結晶の析出や、液状の形態を保てなくなる場合がある。 The blending amount of the higher fatty acid salt is preferably 15 to 25% by mass. Sufficient detergency may not be obtained if the composition is less than 15% by mass. If it is blended in excess of 25% by mass, crystals may precipitate or the liquid form may not be maintained.
本発明で用いるメタクリル酸とエチルアクリレートとの架橋コポリマーのエマルション（アクリレーツコポリマーエマルションと略す場合があります。）は、アルカリで膨潤する水性分散体であり、純分３０％のポリマーのエマルションである。かかるアクリレーツコポリマーエマルションとしては、カーボポールアクアＳＦー１（ノベオン社製）が例示される。 The emulsion of a crosslinked copolymer of methacrylic acid and ethyl acrylate used in the present invention (sometimes abbreviated as acrylates copolymer emulsion) is an aqueous dispersion that swells with alkali and is an emulsion of a polymer having a pure content of 30%. Examples of such an Acrylate copolymer emulsion include Carbopol Aqua SF-1 (manufactured by Noveon Co., Ltd.).
アクリレーツコポリマーエマルションの配合量は、他の成分の種類、量、ｐＨ等により変動されるべきものであり、所望の粘稠性が得られれば、特に限定されない。架橋コポリマー純分として０．０５〜１．０質量％程度配合することが好ましい。０．０５質量％未満の配合では保湿効果が得られない場合がある。１．０質量％を超えて配合すると、洗い流し後のさっぱり感が得られない場合がある。 The blending amount of the Acrylate copolymer emulsion should be varied depending on the type, amount, pH and the like of other components, and is not particularly limited as long as the desired consistency can be obtained. It is preferable to add about 0.05 to 1.0% by mass as the pure content of the crosslinked copolymer. A moisturizing effect may not be obtained if the composition is less than 0.05% by mass. If it is blended in excess of 1.0% by mass, a refreshing feeling after rinsing may not be obtained.
本発明で用いるグリセリルグルコシドは、洗浄料組成物に配合し得るものであれば製造方法は、合成、微生物による発酵法等を問わない。グリセリルグルコシドは、０．０５〜５質量％、好ましくは０．１〜３質量％配合する。０．０５質量％未満の配合では、保湿感が感じられない場合がある。５質量％を超えて配合すると、洗浄後のさっぱり感がなくなる場合がある。 As long as the glyceryl glucoside used in the present invention can be blended in the cleaning composition, the production method may be synthetic, fermentation with microorganisms, or the like. Glyceryl glucoside is blended in an amount of 0.05 to 5% by mass, preferably 0.1 to 3% by mass. If the composition is less than 0.05% by mass, a moisturizing feeling may not be felt. If it is blended in excess of 5% by mass, the refreshing feeling after washing may be lost.
本発明の洗浄料には、上述の成分の他に、通常の洗浄料分野等に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、精製水、油剤、界面活性剤、増粘剤、防腐剤、香料、紫外線吸収剤、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。 In addition to the above-mentioned components, the cleaning agent of the present invention may contain arbitrary components used in the field of ordinary cleaning agents and the like to the extent that the effects of the present invention are not impaired. Specific examples thereof include purified water, oils, surfactants, thickeners, preservatives, fragrances, ultraviolet absorbers, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents and the like.
本発明の洗浄料は、常法により製造され、固形状、液状、乳液状、クリーム状、ペースト状、ジェル状、軟膏状等の剤型とすることができる。本発明の効果の点から、適度な粘性を有する液状の剤型をとることが好ましい。また本発明の洗浄料は、皮膚洗浄料、毛髪洗浄料として使用することができ、特に皮膚洗浄料として使用することが好ましい。 The cleaning agent of the present invention is produced by a conventional method and can be in a dosage form such as solid, liquid, milky, creamy, paste, gel or ointment. From the viewpoint of the effect of the present invention, it is preferable to take a liquid dosage form having an appropriate viscosity. Further, the cleansing agent of the present invention can be used as a skin cleansing agent and a hair cleansing agent, and is particularly preferably used as a skin cleansing agent.
以下に本発明を実施例を用いて説明するが、本発明の技術的範囲はこれによってなんら限定されるものではない。 Hereinafter, the present invention will be described with reference to examples, but the technical scope of the present invention is not limited thereto.
本発明の実施例及び比較例の評価方法は下記のとおりである。 The evaluation methods of Examples and Comparative Examples of the present invention are as follows.
［評価方法］
専門パネラー３名により、ボディでの使用テストを行い、洗浄料組成物の泡立ち、洗浄力、泡質、保湿感、さっぱり感について、それぞれ絶対評価を行った。評価結果は下記の基準を用いて合議により判定した。
[Evaluation method]
Three expert panelists conducted a use test on the body and absolutely evaluated the foaming, detergency, foam quality, moisturizing feeling, and refreshing feeling of the cleaning agent composition. The evaluation results were judged by consensus using the following criteria.
［評価基準］泡立ち、洗浄力、泡質
◎：非常に良い
○：良い
△：少し悪い
×：悪い
[Evaluation criteria] Foaming, detergency, foam quality ◎: Very good ○: Good △: Slightly bad ×: Bad
［評価基準］保湿感、さっぱり感
◎：強く感じる
○：少し感じる
△：あまり感じない
×：感じない
[Evaluation criteria] Moisturizing feeling, refreshing feeling ◎: Strong feeling ○: A little feeling △: Not much feeling ×: Not feeling
表１、２に、本発明の実施例及び比較例にかかるボディ用洗浄料の処方を示す。洗浄料は定法に従い調製し、評価に供した。 Tables 1 and 2 show the formulations of body cleansers according to Examples and Comparative Examples of the present invention. The cleaning agent was prepared according to a conventional method and used for evaluation.
表１に示した通り、本発明の洗浄料は、高級脂肪酸塩特有の泡立ち、洗浄力の良さとさっぱり感はそのままに、泡質、保湿感に優れた使用感であった。 As shown in Table 1, the cleaning agent of the present invention had excellent foaming quality and moisturizing feeling while maintaining the foaming, good detergency and refreshing feeling peculiar to higher fatty acid salts.
Claims (1)
（Ａ）高級脂肪酸塩
（Ｂ）メタクリル酸とエチルアクリレートとの架橋コポリマーのエマルション
（Ｃ）グリセリルグルコシド A cleaning composition containing the following (A) to (C).
(A) Higher fatty acid salt (B) Emulsion of crosslinked copolymer of methacrylic acid and ethyl acrylate (C) Glyceryl glucoside
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017114633A JP6930863B2 (en) | 2017-06-09 | 2017-06-09 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017114633A JP6930863B2 (en) | 2017-06-09 | 2017-06-09 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2018203703A JP2018203703A (en) | 2018-12-27 |
| JP6930863B2 true JP6930863B2 (en) | 2021-09-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017114633A Active JP6930863B2 (en) | 2017-06-09 | 2017-06-09 | Cleaning composition |
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| Country | Link |
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| JP (1) | JP6930863B2 (en) |
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| JP7850889B2 (en) * | 2021-12-22 | 2026-04-24 | 株式会社希松 | Growth promoter for Döderlein bacilli and selective growth promoter for microorganisms |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR3003861B1 (en) * | 2013-03-26 | 2015-09-04 | Seppic Sa | NOVEL PROCESS FOR THE PREPARATION OF POLYOLS-GLYCOSIDES |
| JP6125896B2 (en) * | 2013-05-14 | 2017-05-10 | 富士フイルム株式会社 | Skin cleanser |
| JP6812099B2 (en) * | 2015-11-19 | 2021-01-13 | クラシエホームプロダクツ株式会社 | Skin cleanser |
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| JP2018203703A (en) | 2018-12-27 |
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